CN101589717A - The sustained-release synergistic avermectin microemulsion that is used for paddy rice - Google Patents
The sustained-release synergistic avermectin microemulsion that is used for paddy rice Download PDFInfo
- Publication number
- CN101589717A CN101589717A CNA2009100326005A CN200910032600A CN101589717A CN 101589717 A CN101589717 A CN 101589717A CN A2009100326005 A CNA2009100326005 A CN A2009100326005A CN 200910032600 A CN200910032600 A CN 200910032600A CN 101589717 A CN101589717 A CN 101589717A
- Authority
- CN
- China
- Prior art keywords
- avermectin
- surface tension
- microemulsion
- paddy rice
- synergist
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005660 Abamectin Substances 0.000 title claims abstract description 59
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 title claims abstract description 55
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 31
- 235000009566 rice Nutrition 0.000 title claims abstract description 31
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 30
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 13
- 238000013268 sustained release Methods 0.000 title claims abstract description 9
- 239000012730 sustained-release form Substances 0.000 title claims abstract description 9
- 240000007594 Oryza sativa Species 0.000 title 1
- 241000209094 Oryza Species 0.000 claims abstract description 31
- 239000004611 light stabiliser Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- -1 polyoxyethylene Polymers 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 6
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002480 mineral oil Substances 0.000 claims abstract description 5
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 5
- 239000003960 organic solvent Substances 0.000 claims abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 3
- 239000012895 dilution Substances 0.000 claims abstract description 3
- 238000010790 dilution Methods 0.000 claims abstract description 3
- 239000000194 fatty acid Substances 0.000 claims abstract description 3
- 229930195729 fatty acid Natural products 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 2
- YXGOYRIWPLGGKN-UHFFFAOYSA-N 2,3-ditert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=C(O)C=CC(O)=C1C(C)(C)C YXGOYRIWPLGGKN-UHFFFAOYSA-N 0.000 claims description 2
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 2
- 229930003268 Vitamin C Natural products 0.000 claims description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 2
- 235000019154 vitamin C Nutrition 0.000 claims description 2
- 239000011718 vitamin C Substances 0.000 claims description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 10
- 239000003905 agrochemical Substances 0.000 abstract description 9
- 241000238631 Hexapoda Species 0.000 abstract description 8
- 230000000857 drug effect Effects 0.000 abstract description 8
- 238000009736 wetting Methods 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 6
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 5
- 229950008167 abamectin Drugs 0.000 abstract description 5
- 239000007921 spray Substances 0.000 abstract description 5
- 239000000243 solution Substances 0.000 abstract description 4
- 241000196324 Embryophyta Species 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 2
- 238000006303 photolysis reaction Methods 0.000 description 15
- 235000014347 soups Nutrition 0.000 description 14
- 239000003814 drug Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 239000000693 micelle Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 4
- 239000004495 emulsifiable concentrate Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 2
- 241000426497 Chilo suppressalis Species 0.000 description 2
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 244000037666 field crops Species 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 230000015843 photosynthesis, light reaction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241001468227 Streptomyces avermitilis Species 0.000 description 1
- 241001655322 Streptomycetales Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The sustained-release synergistic avermectin microemulsion that is used for paddy rice, combined by the certain mass ratio by Avermectin, organic solvent, calcium dodecyl benzene sulfonate, alkylphenol-polyethenoxy (10) ether, polyoxyethylene (20) sorbitan fatty acid ester, surface tension synergist, light stabilizer, antifreezing agent, dilution water, wherein the surface tension synergist is imitated profit, mineral oil, azone by the outstanding person and is constituted.The present invention rationally uses ionic and nonionic surface active agent, carry out the science preparation with abamectin solution, surface tension synergist, light stabilizer, antifreezing agent and water, form the emulsion of stable oil-in-water type, can wetting soon spread behind the rice leaf through atomizers spray, improve the dose of holding of target plant, strengthen drug effect, reduce the agricultural chemicals usage amount, guarantee control efficiency, reduce the pollution of agricultural chemicals environment to insect.
Description
Technical field
The present invention establishes and a kind of micro-emulsion insecticide of preventing and treating rice grub, particularly a kind of can be at the wetting spread of paddy rice leaf surface, slow down the synergistic avermectin microemulsion of photodissociation.
Background technology
Avermectin is that a class that Japanese Kitasato Kenkyusho (JP) 9-1, Shirokane 5-chome, Minato-ku, Tokyo 108, Japan and Merck company at first develop has desinsection, kills ten hexa-atomic Macrocyclic lactone compounds of mite, eelworm-killing activity, extracts the metabolite that separates by streptomycete (Streptomycesavermitilis) fermentation back.Avermectin put goods on the market as agricultural chemicals in 1985, and up to the present, Avermectin control spectrum comprises that insects such as Acarina, coleoptera, Homoptera and Lepidoptera, the evil mite in the arthropods has 84 kinds more than at least.This insecticide utmost point is insoluble in water, and commercially available majority is the missible oil formulation, and aromatic solvent wherein exists that environmental pollution is serious, poisoning is big, produce the uneasy congruent shortcoming of storing, has limited use in some countries.10mg/L registration amount with Avermectin control diamond-back moth and beet armyworm in the agricultural chemicals electronic documentation of the Ministry of Agriculture is reference, the Avermectin preparation that China produces is when concentration is 10mg/L, the surface tension of its solution all is far longer than the critical surface tension 36.7mN/m of paddy rice, be difficult to wetting spread on rice leaf well, most soups that spray tumble with the form of drop, reduced the probability that insect contacts with soup, most of soups flow in the environment, increased the degraded pressure of environment, polluted environment, the huge waste that has caused resource is (referring to document 1, " some soup difficulties are in paddy rice; the analysis of causes of wheat and the wetting spread of wild cabbage " Pesticide Science journal, Vol.4 No.2 (2002) is p.75-80).Simultaneously, Avermectin sees that light can decompose rapidly by oxidation and photooxidation mechanism, and under the simulated solar irradiation, the photodissociation half life period is about 18.84h-59.24h, and the light degradation half life period is 12h in the water; In soil, the illumination degrading half life period be 21h (referring to document 2, " Determination of sunscreen compounds in tropicalsunscreen product " Chromatoggraphy, Vol.519 (1999), p.117-124; Document 3, " synergistic effect that ultraviolet absorber suppresses the Avermectin photodissociation and diamond-back moth is prevented and treated " ecological magazine, Vol.25 No.2 (2006), p.185-188).Be the peak period of paddy rice medication August-October, Avermectin uses the back to form the medicine film, under solar light irradiation, (be mainly ultraviolet ray), improved the photodissociation speed of Avermectin greatly, make that the land for growing field crops lasting period short, increase peasant's medication number of times and unit control cost virtually, thereby cause it to promote difficulty in the land for growing field crops.
Avermectin is a kind of biopesticide, induces insect to develop immunity to drugs than chemical pesticide is easier.In agricultural chemicals, add in general mineral oil, azone, outstanding imitate sharp or other surface tension synergist help improving soup to the insect cuticle penetrance (referring to document 4, " bleeding agent is to beta-cypermethrin virulence and three kinds of Ultrastructural influences of lepidoptera pest epicuticle " insect journal, Vol.51No.2 (2008), p.216-221; Document 5, " 3 kinds of auxiliary agents are to the synergistic effect of beta-cypermethrin " Jiangsu agricultural journal, Vol.24 No.6 (2008) p.820-825), thereby reduces dosage, improves control efficiency, and helps overcoming the pesticide resistance that insect produces medicament.Simultaneously very easily add light stabilizer in the agricultural chemicals of photodissociation, reduce the decomposition rate after Avermectin forms the medicine film, delay the rate of release of Avermectin, thereby improve the photostability of Avermectin preparation, improve drug effect in Avermectin etc.
Critical surface tension is the most important empirical parameter that characterizes low-energy solid moistened surface character, as long as surface tension be equal to or less than the liquid of critical surface tension could be on this solid spontaneous sprawling (referring to document 4, " surfactant science and application " p.193-223).Surfactant can reduce the surface tension of liquid, and the surfactant concentration in the soup that field spray uses must just can make droplet be held by the blade face rapidly above critical micelle concentration and stay.This just requires to select and rationally uses surfactant, surface tension synergist, light stabilizer, Avermectin and water are mixed equably, form stable water oil-packaging type micro-emulsion agent, simultaneously its photostability strengthens, surface tension is less than the critical surface tension of paddy rice, and the surfactant in the soup is greater than critical micelle concentration, so that can be on paddy rice wetting spread, increase the liquid holdup of rice leaf, under the prerequisite that reduces consumption of organic solvent and effective ingredient consumption, improve drug effect.
Up to the present, do not see that be used on the paddy rice can wetting well rice leaf, the preparation that can delay the Avermectin photodissociation simultaneously again comes out.
Summary of the invention
Technical problem to be solved by this invention is, overcomes the deficiencies in the prior art, and a kind of sustained-release synergistic avermectin microemulsion that is used for paddy rice is provided, and realized modularization pipe row.
The technical solution adopted for the present invention to solve the technical problems is as follows: a kind of sustained-release synergistic avermectin microemulsion that is used for paddy rice is characterized in that being combined by its mass ratio by following component:
The component mass ratio
Avermectin: 1%-5%,
Organic solvent: 10%-40%,
Calcium dodecyl benzene sulfonate: 0.8%-2.5%,
Alkylphenol-polyethenoxy (10) ether: 1%-5%,
Polyoxyethylene (20) sorbitan fatty acid ester: 1%-7.5%,
Surface tension synergist: 1.5%-5%,
Light stabilizer: 0.4%-2%,
Antifreezing agent: 1%-2%,
Dilution water: surplus,
Wherein, described surface tension synergist is mixed by first boosting components, second boosting components, and described first boosting components is the outstanding profit of imitating, and second boosting components is one or more in mineral oil, azone, the piperonyl butoxide;
Described light stabilizer is one or more the mixture in butylhydroxy anisole, ditert-butylhydro quinone, vitamin C, the dibutyl hydroxy toluene.
The using method of avermectin micro-emulsion of the present invention is as follows: according to actual needs to microemulsion thin up of the present invention, but the least concentration of Avermectin is 8.91mg/L, can bring into play its drug effect well in order to make avermectin micro-emulsion avermectin micro-emulsion of the present invention, can save consumption again, recommend to use the concentration of Avermectin to be 9mg/L-90mg/L.During use, with sprayer avermectin micro-emulsion of the present invention is sprayed onto on the rice plant blade and gets final product.
Beneficial effect of the present invention is as follows:
One, rationally uses ionic and nonionic surface active agent, carry out the science preparation, form the emulsion of stable oil-in-water type with abamectin solution, surface tension synergist, light stabilizer, antifreezing agent and water.Experiment shows: when the concentration of Avermectin in the microemulsion was 8.91mg/L, the surface tension of soup no longer changed, and was 23.94mN/m.And the critical surface tension of the target plant paddy rice that the present invention is suitable for is 36.7mN/m.Therefore, as long as the concentration of Avermectin is greater than 8.91mg/L among the present invention, its surface tension is just less than the critical surface tension of paddy rice, can wetting soon spread behind the rice leaf through atomizers spray, improve the dose of holding of target plant, strengthen drug effect, reduce the agricultural chemicals usage amount, guarantee control efficiency, reduce the pollution of agricultural chemicals environment to insect;
Two,, find that light stabilizer can delay the photolysis speed of Avermectin, thereby the lasting period of having improved Avermectin reduces the agricultural chemicals usage amount by the decomposition rate of research Avermectin to light.Even the intense light irradiation weather in August-October also can use by aforesaid method, thereby avoids Avermectin to lose efficacy because of intense light irradiation.
Three, storage and transportation are convenient in the stable performance of avermectin micro-emulsion of the present invention, can at room temperature preserve 2 years;
Four, the field use can be according to the actual conditions dilute with water, preparation and easy to use.
Description of drawings
Fig. 1 is the photodissociation Test Drawing of Avermectin under uviol lamp.
20-30 ℃ of photolysis chamber control room temperature, adopt the artificial light source uviol lamp to shine, carry out sample detecting respectively at irradiation back 1h, 2h, 4h, 8h, 16h, 24h.As can be seen from Figure 1 the photodissociation of Avermectin meets first _ order kinetics equation, C
t=76.881e
-0.1708t(R
2=0.9969), the photodissociation half life period is 2.46h, and the photodissociation process of adding light stabilizer 1 and light stabilizer 2 also meets first _ order kinetics equation, and its equation is respectively C
t=79.093e
-0.0841t(R
2=0.9940), the photodissociation half life period is 3.17h and C
t=89.622e
-0.0494t(R
2=0.9957), the photodissociation half life period is 3.70h.The interpolation of light stabilizer makes the photodissociation half life period of Avermectin prolong 28.86% and 50.41% respectively.
Fig. 2 is the coordinate diagram that concerns that the method for surfactant critical micelle concentration and the mensuration critical surface tension value that proposes according to Zisman is measured the paddy rice critical surface tension in the surface tension, soup of the synergistic avermectin microemulsion variable concentrations soup of the present invention measured according to the method for GB-5549-90.
As can be seen from Figure 2, when AVM concentration is 8.91mg/L, the table in the microemulsion soup Surface-active agent has reached critical micelle concentration. Therefore as long as the concentration of avermectin micro-emulsion of the present invention is big In 8.91mg/L, the surfactant concentration in the soup has just surpassed critical micelle concentration, and soup Surface tension less than the critical surface tension of rice leaf. The AVM concentration of recommendation of the present invention 9mg/L one 90mg/L, soup this moment wet spreading well on rice leaf can be given full play to Drug effect can be saved medication again.
Embodiment
With reference to the accompanying drawings and in conjunction with example the present invention is described in further detail.But the invention is not restricted to given example.
The present invention provides composition embodiment 1-12, referring to table 1-table 4, wherein the surface tension synergist is mixed by first boosting components, second boosting components, first boosting components is the outstanding profit of imitating, second boosting components is one or both of mineral oil, azone, and the mass ratio of first boosting components and second boosting components is 0.5～9: 1.
The present invention gives avermectin micro-emulsion and the comparison (table 5) of holding dose of abamectin emulsifiable concentrate on rice leaf, as can be seen from the table the concentration of 1.8% avermectin micro-emulsion 5.63mg/L-90mg/L on the paddy rice hold dose all the utmost point be significantly higher than 1.8% abamectin emulsifiable concentrate 10mg/L and on paddy rice, hold dose.Table 6, table 7 be respectively 1.8% avermectin micro-emulsion to rice-stem borer and 5% avermectin micro-emulsion to the drug effect of rice leaf roller relatively (converting water 750kg spray application) by per hectare, therefrom the avermectin micro-emulsion drug effect of testing used dosage all is better than abamectin emulsifiable concentrate as can be seen.
Table 1
Table 2
Table 3
Table 4
The retention volume of table 5 1.8% avermectin micro-emulsion on rice leaf
Annotate: data are mean+SD in the table, and the lowercase of back and capitalization are illustrated respectively in the significance of difference on 0.05 and 0.01 level.(down together)
Table 6 1.8% avermectin micro-emulsion is to the control efficiency of striped rice borer
2008.06 Gaochun
Table 7 5% avermectin micro-emulsion is to the control efficiency of rice leaf roller
2008.08 Gaochun
Claims (4)
1, a kind of sustained-release synergistic avermectin microemulsion that is used for paddy rice is characterized in that being combined by its mass ratio by following component:
The component mass ratio
Avermectin: 1%-5%,
Organic solvent: 10%-40%,
Calcium dodecyl benzene sulfonate: 0.8%-2.5%,
Alkylphenol-polyethenoxy (10) ether: 1%-5%,
Polyoxyethylene (20) sorbitan fatty acid ester: 1%-7.5%,
Surface tension synergist: 1.5%-5%,
Light stabilizer: 0.4%-2%,
Antifreezing agent: 1%-2%,
Dilution water: surplus,
Wherein, described surface tension synergist is mixed by first boosting components, second boosting components, and described first boosting components is the outstanding profit of imitating, and second boosting components is one or both of mineral oil, azone;
Described light stabilizer is one or more the mixture in butylhydroxy anisole, ditert-butylhydro quinone, vitamin C, the dibutyl hydroxy toluene.
2, the sustained-release synergistic avermectin microemulsion that is used for paddy rice according to claim 1 is characterized in that described described solvent is one or more the mixture in cyclohexanone and methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, acetone, ethyl acetate, dimethyl formamide, the dimethylbenzene.
3, the sustained-release synergistic avermectin microemulsion that is used for paddy rice according to claim 1 is characterized in that described antifreezing agent is an ethylene glycol.
4, the sustained-release synergistic avermectin microemulsion that is used for paddy rice according to claim 1 is characterized in that, in the described surface tension synergist, the mass ratio of first boosting components and second boosting components is 0.5～9: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100326005A CN101589717B (en) | 2009-07-02 | 2009-07-02 | Sustained-release synergistic avermectin microemulsion for paddy rice |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100326005A CN101589717B (en) | 2009-07-02 | 2009-07-02 | Sustained-release synergistic avermectin microemulsion for paddy rice |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101589717A true CN101589717A (en) | 2009-12-02 |
| CN101589717B CN101589717B (en) | 2012-08-22 |
Family
ID=41404746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100326005A Expired - Fee Related CN101589717B (en) | 2009-07-02 | 2009-07-02 | Sustained-release synergistic avermectin microemulsion for paddy rice |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101589717B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102132698A (en) * | 2010-01-21 | 2011-07-27 | 中化化工科学技术研究总院 | Green solvent for pesticide and application of green solvent |
| CN102450253A (en) * | 2010-10-15 | 2012-05-16 | 华北制药集团爱诺有限公司 | Avermectin suspension concentrate and preparation method thereof |
| CN105410026A (en) * | 2015-12-28 | 2016-03-23 | 浙江农林大学 | Insecticidal composition for controlling whiteflies, and use thereof |
| CN109452269A (en) * | 2018-12-21 | 2019-03-12 | 硅羿科技（上海）有限公司 | Avermectin emulsion formulations and preparation method and application |
| CN111374127A (en) * | 2020-02-28 | 2020-07-07 | 安徽瑞然生物药肥科技有限公司 | Low-volatility coated insecticidal abamectin composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1555699A (en) * | 2004-01-08 | 2004-12-22 | 金中北 | Aqueous emulsion green pesticide and its formula design and preparation method |
| CN1586199A (en) * | 2004-07-19 | 2005-03-02 | 马韵升 | High concentration abamectin pest killing micro emulsion |
| CN101268778A (en) * | 2008-04-28 | 2008-09-24 | 淮安市农业科学研究院 | Photostable avermectin composition and preparation thereof |
-
2009
- 2009-07-02 CN CN2009100326005A patent/CN101589717B/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102132698A (en) * | 2010-01-21 | 2011-07-27 | 中化化工科学技术研究总院 | Green solvent for pesticide and application of green solvent |
| CN102450253A (en) * | 2010-10-15 | 2012-05-16 | 华北制药集团爱诺有限公司 | Avermectin suspension concentrate and preparation method thereof |
| CN105410026A (en) * | 2015-12-28 | 2016-03-23 | 浙江农林大学 | Insecticidal composition for controlling whiteflies, and use thereof |
| CN105410026B (en) * | 2015-12-28 | 2018-07-03 | 浙江农林大学 | Prevent Pesticidal combination of Bemisia tabaci and application thereof |
| CN109452269A (en) * | 2018-12-21 | 2019-03-12 | 硅羿科技（上海）有限公司 | Avermectin emulsion formulations and preparation method and application |
| CN111374127A (en) * | 2020-02-28 | 2020-07-07 | 安徽瑞然生物药肥科技有限公司 | Low-volatility coated insecticidal abamectin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101589717B (en) | 2012-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101589717B (en) | Sustained-release synergistic avermectin microemulsion for paddy rice | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| Zhu et al. | Photodegradation of emamectin benzoate and its influence on efficacy against the rice stem borer, Chilo suppressalis | |
| CN101133738A (en) | Insecticidal composition containing fipronil for corps | |
| CN104054732A (en) | Agricultural acaricide and water suspension composition | |
| CN103283774B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN104957161A (en) | Microemulsion containing emamectin benzoate and lufenuron | |
| CN101233856A (en) | Emamectin-benzoate and cyhalothrin microemulsion | |
| CN108294000A (en) | A kind of Pesticidal combination of brominated worm fluorobenzene bisamide and methoxyfenozide | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN102224825A (en) | Pesticide composition containing sulfoxaflor and nereistoxin compound | |
| CN102232385A (en) | Insecticidal composition containing clothianidin and abamectin | |
| CN101480177B (en) | Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof | |
| CN102228044B (en) | Insecticidal composition containing sufluoxime | |
| CN101422155B (en) | Insecticide and miticide composition | |
| CN102960353A (en) | Insecticidal and acaricidal composition containing metaflumizone and flufenzine | |
| CN102258025A (en) | Insecticidal composition containing flonicamid and chlorfenapyr | |
| CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
| CN102210312A (en) | Acaricidal composition containing abamectin and fenazaquin | |
| CN102246778A (en) | Efficiency enhanced insecticidal composition, and application thereof | |
| CN101554158A (en) | Emamectin-benzoate and methomyl microemulsion and preparation method thereof | |
| CN102550581A (en) | Ultralow-volume concentrate containing chlorfluazuron | |
| CN102318636A (en) | A kind of Synergistic insecticidal compositions | |
| CN100399902C (en) | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides | |
| CN101961009B (en) | Flubendiamide insecticidal microemulsion and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120822 |