Low grade fluorite and barite flotation separation method
One, technical field
The present invention relates to a kind of floatation separating method for mineral, particularly a kind of low grade fluorite and barite floatation separating method for mineral.
Two, background technology
Existing fluorite and barite recovery method generally is to adopt the inhibitor of waterglass as silicoide both at home and abroad, and oleic acid or enuatrol reclaim as the collecting agent of fluorite mineral; Barite then more adopts gravitational separation equipment to reclaim, and also has the method for floating of employing to reclaim.But when fluorite and barite occurred simultaneously with associated mineral, present general single recovery fluorite or barite mineral were so not only wasted resource, and have been increased the storage pressure of mine tailing; When particularly grade has only 30% left and right sides fluorite and barite to occur with the associated mineral form, do not see the report that relevant fluorite and barite reclaims simultaneously at present.
Three, summary of the invention
The object of the present invention is to provide a kind of low grade fluorite and barite flotation separation method, it can reclaim fluorite and barite simultaneously, obtains higher fluorite, barite grade and the rate of recovery.
The present invention achieves the above object by the following technical solutions: a kind of low grade fluorite and barite flotation separation method, adopt the inhibitor of waterglass as silicoide and calcium carbonate mineral, make fluorite, bar collecting agent with oleic acid, may further comprise the steps and regime of agent:
(1) slurry pH is 6~7 during flotation,
(2) with starch, sodium sulphate, hydrochloric acid and calgon medicament inhibitor as the barite mineral,
(3) in the floatation process, after adding waterglass to ore mill dissociates ore ore grinding to mineral monomer, adding oleic acid again carries out bulk flotation to fluorite, barite to the flotation device and gets bulk concentrate, the inhibitor that adds barite then suppresses barite, through 7~8 selected fluorite concentrates that get, cleaner tailings gets the barite concentrate by reverse flotation again
(4) dosing is:
Waterglass 300~400g/t
Oleic acid is roughly selected 400~500g/t and is scanned 100~200g/t
Selected 50~the 60g/t of starch
Selected 500~the 700g/t of sodium sulphate
Selected 300~the 400g/t of hydrochloric acid
Selected 300~the 350g/t of calgon.
During use, described medicament is mixed with following concentration expressed in percentage by weight earlier:
Waterglass 10~20% aqueous solution
The direct stoste of oleic acid is added
Starch 1~5% aqueous solution
Sodium sulphate 5~10% aqueous solution
Hydrochloric acid 10~20% aqueous solution
Calgon 5~10% aqueous solution
Outstanding advantage of the present invention is:
1, low-grade fluorite and barite be can reclaim simultaneously, and higher fluorite, barite grade and the rate of recovery obtained.
2, flowage structure of the present invention is simple, and dosing is few, and less energy consumption can reclaim resource comprehensive.
Four, the specific embodiment
Embodiment 1
1. raw mineral materials:
Fluorite content is 33.92% in the used ore, and barite is 35.33%, the gangue mineral dioxide-containing silica is 13.67%, and other has a small amount of calcium carbonate to exist.
2. floating agent and operating condition:
Waterglass 300g/t 10% aqueous solution
The direct stoste of oleic acid 500g/t is added
Starch 50g/t 1% aqueous solution
Sodium sulphate 500g/t 5% aqueous solution
Hydrochloric acid 300g/t 10% aqueous solution
Calgon 300g/t 5% aqueous solution
With sulfuric acid pH values of pulp is transferred to 6~7 during flotation, in the floatation process, at first add after waterglass to ore mill dissociates ore ore grinding to mineral monomer, adding oleic acid again carries out bulk flotation to fluorite, barite to the flotation device and gets bulk concentrate, the inhibitor that adds barite then suppresses barite, through seven selected fluorite concentrates that get, cleaner tailings then gets the barite concentrate by reverse flotation again.Carried out 100t/d industry expanding test in a year by above-mentioned technological parameter, show and adopt above technology and medicament condition effectively will hang down product fluorite, barite recovery, giving ore deposit fluorite content is 33.92%, barite is under 35.33% condition, through one roughing scan for twice and seven times selected, flotation concentrate fluorite grade is 95.8%, and the rate of recovery reaches 78.5%; It is 92.3% that cleaner tailings gets grade by reverse flotation again, and the rate of recovery reaches 75.2% barite concentrate
Embodiment 2
1. raw mineral materials
Fluorite content is 40.14% in the ore, and barite is 34.67%, dioxide-containing silica 15.78%, calcium carbonate content 3.54%.
2. floating agent and operating condition:
Waterglass 400g/t 10% aqueous solution
The direct stoste of oleic acid 700g/t is added
Starch 60g/t 5% aqueous solution
Sodium sulphate 700g/t 10% aqueous solution
Hydrochloric acid 400g/t 20% aqueous solution
Calgon 350g/t 10% aqueous solution
Slurry pH is 6~7 during flotation; In the floatation process, at first add after waterglass to ore mill dissociates ore ore grinding to mineral monomer, adding oleic acid again carries out bulk flotation to fluorite, barite to the flotation device and gets bulk concentrate, the inhibitor that adds barite then suppresses barite, through eight selected fluorite concentrates that get, cleaner tailings gets the barite concentrate by reverse flotation again.Carried out the 150t/d pilot production by above-mentioned technological parameter, show and adopt above technology and medicament condition effectively fluorite, barite to be reclaimed, giving ore deposit fluorite content is 40.14%, barite is under 34.67% condition, through one roughing scan for twice and eight times selected, flotation concentrate fluorite grade is 95.21%, and the rate of recovery reaches 75.5%; Cleaner tailings again reverse flotation to get grade be 93.27%, the rate of recovery reaches 79.73% barite concentrate.