CN106269268B - A method of microfine fluorite is recycled in flotation from tailing - Google Patents
A method of microfine fluorite is recycled in flotation from tailing Download PDFInfo
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- CN106269268B CN106269268B CN201610944057.6A CN201610944057A CN106269268B CN 106269268 B CN106269268 B CN 106269268B CN 201610944057 A CN201610944057 A CN 201610944057A CN 106269268 B CN106269268 B CN 106269268B
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- fluorite
- flotation
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- aqueous solution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/002—Inorganic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/006—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/005—Dispersants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/007—Modifying reagents for adjusting pH or conductivity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
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- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Paper (AREA)
Abstract
A method of particle fluorite is recycled in flotation from tailing, includes the following steps:After tailing is milled to mineral monomer dissociation, pH regulators are made using sulfuric acid, waterglass makees dispersant, and methyl orchid makees inhibitor with soluble starch, and vegetable oil acid makees collecting agent and recycles to obtain fluorite hair concentrate to microfine fluorite first time flotation;Then fluorite hair concentrate is made into pH regulators using sodium hydroxide, larch extract makees inhibitor with Congo red, and oxidized paraffin wax soap makees collecting agent second of flotation of progress and recycles to obtain fluorite concentrate.Can preferably solve that fluorite grade is low, granularity is fine, concentrate grade requires high technical problem using the present invention, especially to disseminated grain size in tailing fluorite mineral that are thin, failing monomer dissociation recycling, concentrate grade and the rate of recovery can be taken into account.
Description
One, technical field
The present invention relates to a kind of recovery method of fluorite, especially a kind of side of the recycling of the flotation from tailing microfine fluorite
Method.
Two, background technology
With the development of industry, gradually deficient and price constantly increases fluorite resource, some heaps are stored in micro- in Tailings Dam
Fine-grained disseminated grain low-grade fluorite becomes valuable secondary resource;But due to these low-grade fine-grained disseminated grain fluorite tailings have it is poor,
Carefully, miscellaneous feature not only needs suitable technological process, while also needing to rational medicament to recycle current secondary resource
System could recycle it.As can these secondary resources are fully recycled, only Mining Enterprises do not provide economic effect
Benefit, while being also the meaning that fluorite industrial expansion has reality.
Three, invention content
The method of flotation that the purpose of the present invention is to provide a kind of from tailing recycling microfine fluorite, can preferably solve
Fluorite grade is low, granularity is fine, concentrate grade requires high technical problem, especially thin to disseminated grain size in tailing, fail list
The recycling of the fluorite mineral of body dissociation, can take into account concentrate grade and the rate of recovery.
The present invention reaches above-mentioned purpose using following technical scheme:A kind of side of the recycling of the flotation from tailing microfine fluorite
Method includes the following steps:
(1) after dissociating tailing ore grinding to mineral monomer, pH regulators are made using sulfuric acid, waterglass makees dispersant, methyl
Blue to make inhibitor with soluble starch, vegetable oil acid makees collecting agent and recycles to obtain fluorite hair concentrate for the first time to microfine fluorite;So
Fluorite hair concentrate is made into pH regulators using sodium hydroxide afterwards, larch extract makees inhibitor with Congo red, and oxidized paraffin wax soap is made
Collecting agent carries out second of flotation and recycles to obtain fluorite concentrate;
(2) it when first time flotation is recycled, after tailing ore grinding to mineral monomer is dissociated, is firstly added sulfuric acid and makees pH adjustment
Agent, add water glass make dispersant and then methylate orchid and soluble starch make inhibitor, it is last again plus vegetable oil acid makees collecting
Agent is scanned four selected recycling microfine fluorites by one roughing and obtains fluorite hair concentrate three times,
When (3) second of flotation are recycled, sodium hydroxide tune pH value is added to be 10.5~11 fluorite hair concentrate pulp, larch
Tannin extract makees inhibitor with Congo red, and oxidized paraffin wax soap makees collecting agent and sweeps to obtain fluorite concentrate twice by the way that one roughing four times is selected,
The total dosage of medicament is:
600~1000g/t of sulfuric acid
1500~2000g/t of waterglass
200~250g/t of methyl orchid
150~250g/t of soluble starch
1000~1200g/t of vegetable oil acid
500~600g/t of sodium hydroxide
350~400g/t of larch extract
Congo red 150~200g/t
200~300g/t of oxidized paraffin wax soap,
In use, being first configured to following mass percentage concentration %:
Unless otherwise stated, percentage of the present invention is mass percent, and the sum of each component content percentage is
100%.
The present invention's has the prominent advantages that:
1, using secondary separation technological process, separation for the first time does not directly acquire final concentrate, only obtains fluorite hair concentrate,
Hair concentrate reduces separating difficulty, realizes effective recycling of microfine fluorite ore, obtain by detaching acquisition final concentrate again
High fluorite concentrate grade and high-recovery.
2, using nontoxic inhibitor inexpensive, selectively good to gangue mineral, inhibiting effect is strong, tailing is preferably solved
The technical issues of middle microfine fluorite difficulty recycling.
3, dosing is few, nontoxic and pollution-free.
Four, specific implementation mode
Technical scheme of the present invention is described further by the following examples.
Embodiment 1
1. raw mineral materials:
Raw material is fluorite tailing, in ore fluorite content be 13.86%, silicone content 23.57%, calcium oxide 12.78%.
Material phase analysis shows that valuable mineral is mainly fluorite mineral in tailing, and impure mineral is mainly with quartz, calcite and aluminum silicon mineral
Form exists.
2. floating agent and operating condition:
Sulfuric acid 600g/t
Waterglass 1500g/t
Methyl orchid 200g/t
Soluble starch 150g/t
Vegetable oil acid 1000g/t
Sodium hydroxide 500g/t
Larch extract 350g/t
Congo red 150g/t
Oxidized paraffin wax soap 200g/t,
When first time flotation is recycled, after tailing ore grinding to mineral monomer is dissociated, sulfuric acid 600g/t tune pH values of pulp is used first
To after 6~6.5, add water dispersant glass 1500g/t first, then methylate orchid 200g/t and soluble starch 150g/t works press down
Preparation, finally plus vegetable oil acid 1000g/t is scanned four selected recycling microfine fluorites by one roughing and obtains fluorite hair three times
Concentrate,
When second of flotation is recycled, sodium hydroxide 500g/t tune pH value is added to be 10.5~11 fluorite hair concentrate pulp, so
Afterwards plus larch extract 350g/t and Congo red 150g/t makees inhibitor, and finally plus oxidized paraffin wax soap 200g/t passes through as collecting agent
One roughing four times is selected to sweep to obtain fluorite concentrate twice;
It is tested using process above and agentia condition, the results showed that the microfine fluorite in tailing can be effectively recycled,
Be 13.86% to mine fluorite grade, silicone content 23.57%, calcium oxide 12.78% under the conditions of, recycled by secondary flotation,
It is 97.05% to obtain grade, the fluorite concentrate that the rate of recovery is 81.26%.
Embodiment 2
1. raw mineral materials:
Raw material is fluorite tailing, in ore fluorite content be 15.47%, silicone content 22.60%, calcium oxide 10.21%.
Material phase analysis shows that valuable mineral is mainly fluorite mineral in tailing, and impure mineral is mainly with quartz, calcite and aluminum silicon mineral
Form exists.
2. floating agent and operating condition:
Sulfuric acid 800g/t
Waterglass 1700g/t
Methyl orchid 220g/t
Soluble starch 180g/t
Vegetable oil acid 1100g/t
Sodium hydroxide 550g/t
Larch extract 380g/t
Congo red 170g/t
Oxidized paraffin wax soap 250g/t,
When first time flotation is recycled, after tailing ore grinding to mineral monomer is dissociated, sulfuric acid 800g/t tune pH values of pulp is used first
To after 6~6.5, add water dispersant glass 1700g/t first, then methylate orchid 220g/t and soluble starch 180g/t works press down
Preparation, finally plus vegetable oil acid 1100g/t is scanned four selected recycling microfine fluorites by one roughing and obtains fluorite hair three times
Concentrate,
When second of flotation is recycled, sodium hydroxide 550g/t tune pH value is added to be 10.5~11 fluorite hair concentrate pulp, so
Afterwards plus larch extract 380g/t and Congo red 170g/t makees inhibitor, and finally plus oxidized paraffin wax soap 250g/t passes through as collecting agent
One roughing four times is selected to sweep to obtain fluorite concentrate twice;
It is tested using process above and agentia condition, the results showed that the microfine fluorite in tailing can be effectively recycled,
Be 15.47% to mine fluorite grade, silicone content 22.60%, calcium oxide 10.21% under the conditions of, recycled by secondary flotation,
It is 97.23% to obtain grade, the fluorite concentrate that the rate of recovery is 82.74%.
Embodiment 3
1. raw mineral materials:
Raw material is fluorite tailing, in ore fluorite content be 18.67%, silicone content 24.63%, calcium oxide 8.16%.
Material phase analysis shows that valuable mineral is mainly fluorite mineral in tailing, and impure mineral is mainly with quartz, calcite and aluminum silicon mineral
Form exists.
2. floating agent and operating condition:
Sulfuric acid 1000g/t
Waterglass 2000g/t
Methyl orchid 250g/t
Soluble starch 250g/t
Vegetable oil acid 1200g/t
Sodium hydroxide 600g/t
Larch extract 400g/t
Congo red 200g/t
Oxidized paraffin wax soap 300g/t,
When first time flotation is recycled, after tailing ore grinding to mineral monomer is dissociated, sulfuric acid 1000g/t tune pH values of pulp is used first
To after 6~6.5, add water dispersant glass 2000g/t first, then methylate orchid 250g/t and soluble starch 250g/t works press down
Preparation, finally plus vegetable oil acid 1200g/t is scanned four selected recycling microfine fluorites by one roughing and obtains fluorite hair three times
Concentrate,
When second of flotation is recycled, sodium hydroxide 600g/t tune pH value is added to be 10.5~11 fluorite hair concentrate pulp, so
Afterwards plus larch extract 400g/t and Congo red 200g/t makees inhibitor, and finally plus oxidized paraffin wax soap 300g/t passes through as collecting agent
One roughing four times is selected to sweep to obtain fluorite concentrate twice;
It is tested using process above and agentia condition, the results showed that the microfine fluorite in tailing can be effectively recycled,
Be 18.67% to mine fluorite grade, silicone content 24.63%, calcium oxide 8.16% under the conditions of, recycled by secondary flotation,
It is 97.34% to obtain grade, the fluorite concentrate that the rate of recovery is 85.70%.
Claims (2)
1. a kind of method of the recycling of the flotation from tailing microfine fluorite, which is characterized in that this method comprises the following steps, flotation
Recycling carries out at twice:
(1)When first time flotation is recycled, after tailing ore grinding to mineral monomer is dissociated, it is firstly added sulfuric acid and makees pH regulators, then
Add waterglass make dispersant and then methylate orchid and soluble starch make inhibitor, it is last again plus vegetable oil acid to make collecting agent logical
It crosses one roughing and scans four selected recycling microfine fluorites three times and obtain fluorite hair concentrate,
(2)When second of flotation is recycled, sodium hydroxide tune pH value is added to be 10.5~11 fluorite hair concentrate pulp, larch extract
Make inhibitor with Congo red, oxidized paraffin wax soap makees collecting agent and scans to obtain fluorite concentrate twice by the way that one roughing four times is selected,
The total dosage of medicament is:
600~1000 g/t of sulfuric acid
1500~2000 g/t of waterglass
200~250 g/t of methyl orchid
150~250 g/t of soluble starch
1000~1200 g/t of vegetable oil acid
500~600 g/t of sodium hydroxide
350~400 g/t of larch extract
Congo red 150~200 g/t
200~300 g/t of oxidized paraffin wax soap.
2. a kind of method of the recycling of the flotation from tailing microfine fluorite according to claim 1, which is characterized in that use
When, first it is configured to following mass percentage concentration %:
10~20% aqueous solution of sulfuric acid
10~20% aqueous solution of waterglass
1~2% aqueous solution of methyl orchid
1~2% aqueous solution of soluble starch
Vegetable oil acid stoste is added
10~20% aqueous solution of sodium hydroxide
1~2% aqueous solution of larch extract
Congo red 1~2% aqueous solution
1~2% aqueous solution of oxidized paraffin wax soap.
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