CN101578090B - Make-up remover cosmetic compositions - Google Patents
Make-up remover cosmetic compositions Download PDFInfo
- Publication number
- CN101578090B CN101578090B CN200780041031XA CN200780041031A CN101578090B CN 101578090 B CN101578090 B CN 101578090B CN 200780041031X A CN200780041031X A CN 200780041031XA CN 200780041031 A CN200780041031 A CN 200780041031A CN 101578090 B CN101578090 B CN 101578090B
- Authority
- CN
- China
- Prior art keywords
- esters
- fatty acid
- compositions
- weight
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
A make-up remover composition is provided which includes a blend of non-saccharide polyhydric alcohol fatty acid triester(s) and saccharide alcohol fatty acid tetraester(s) 5 with oil that effectivelyremoves makeup under moist conditions such as with wet hands.
Description
1. invention field
The present invention relates to render a service the cosmetic composition for removing makeup of raising.Specifically, the present invention relates to the compositions of makeup removing under wet or wet condition.
2. background technology
A key areas in cosmetics market is the product that is used to remove ornaments and formal dress.It is many women's everyday problem that the pigment of eye shadow cream, mascara, kermes, lip pomade and face powder is removed.This problem is through comprising that the preparation of acting material is resolved through solvent action or through emulsifying.Yet such cleaning agent has shortcoming usually, and promptly they must not be separated effectively to play a role away from water.The effective makeup removing of (that is, with wet hands) use agent will be easily for the individual in can or taking a shower in shower.Surprisingly, find to comprise non-sugar polyol fatty acid three esters and sugar alcohol fatty acid four esters and effectively remove ornaments and formal dress, and do not have problem of phase separation and impaired makeup removing efficient with the admixture of specific ratios and with the preparation (for example with wet hands) under wet condition of oily fusion.
The people's such as Shimizu that on August 18th, 2005 announced United States Patent (USP) publication has been described a kind of Cleasing compositions No. 2005/0180942, and it contains the nonionic surfactant that is selected from various fatty acid glycerides in the oil base material, and has specific IOB value.It is reported that said preparation is anti-to be separated.
The United States Patent (USP) publication of the Tomokuni that on July 15th, 2004 announced has been described a kind of Cleasing compositions No. 2004/0136943; It comprises (A) oil ingredient; (B) hydrophilic nonionic surfactant, (C) lipotropy amphiphile, (D) water-soluble solvent and (E) water.It is reported that said composition has the isotropic liquid phase that shows bicontinuous structure.Said composition is described in the removal greasy dirt and water solublity dirt aspect shows outstanding detergency and has rinsability highly.
Surprisingly; Have been found that; Contain specific ratios non-sugar polyol fatty acid three esters and sugar alcohol fatty acid four esters, anhydrous basically compositions makeup removing under moist or wet condition is very effective, represented the good practicality to the compositions user simultaneously.
Summary of the invention
One aspect of the present invention is a stable cleaning composition, and it comprises but is not limited to:
A.5 to 40% weight, mix total liquid macrogol C14 to the C22 fatty acid ester of IOB value in 0.60 to 1.15 scope;
B. at least a of wherein said cithrol is non-sugar polyol fatty acid three esters, and the other a kind of of said cithrol is sugar alcohol fatty acid four esters;
C. wherein said three esters and four esters exist with 1.0 to 3.0 ratio ranges;
D.30 to the liquid oil of 70% weight; With
The water content of e. maximum 5% weight.
Another aspect of the present invention is that this method includes but not limited to following step from the method for skin makeup removing:
The compositions that a. will comprise following substances is applied to skin:
I.5 to 40% weight, mix total liquid macrogol C14 to the C22 fatty acid ester of IOB value in 0.60 to 1.15 scope;
Ii. at least a of wherein said cithrol is non-sugar polyol fatty acid three esters, and the other a kind of of said cithrol is sugar alcohol fatty acid four esters;
Iii. wherein said three esters and four esters exist with 1.0 to 3.0 ratio ranges;
The liquid oil of iv.30 to 70% weight; With
The water content of v. maximum 5% weight
Said compositions is kept the time of effectively loosening, dissolving and/or disperseing the cosmetic composition on skin; With
C. water rinses said compositions from skin.
Detailed Description Of The Invention
All publications that this paper mentions and patent application, patent and other lists of references are incorporated into its integral body by reference.
One aspect of the present invention is a stable cleaning composition, and it comprises but is not limited to:
A.5 to total liquid macrogol C14 to C22 fatty acid ester of 40% weight; Preferably, minimum is 7 or 10 or 15% and be 25 or 30 or 35% to the maximum; Has the mixing IOB value in 0.60 to 1.15 scope; Preferably, mix the IOB value and be at least 0.65 or 0.70 and be 1.0 or 1.05 or 1.10 to the maximum;
B. at least a of wherein said cithrol is non-sugar polyol fatty acid three esters, and the other a kind of of said cithrol is sugar alcohol fatty acid four esters;
C. wherein said three esters and four esters exist with 1.0 to 3.0 ratio ranges; Preferably, said ratio is at least 1.2,1.4 or 1.6 and be 2.7,2.5 or 2.3 to the maximum;
D.30 to the liquid oil of 70% weight; Preferably, minimum is 30 or 40 or 50% and be 55 or 60% to the maximum; With
The water content of e. maximum 5% weight; Preferably less than 4,3,2,1.5 or 1%.
Stability is defined as Cleasing compositions and under about 23-25C, showed as homogenizing at least 30 days and do not have situation about significantly being separated.
Advantageously, polyol fatty acid three esters are glycerol C14 to C22 fatty acid esters, and preferably this ester is PEG-10 to 30 derivant, and more preferably this fatty acid ester is C16 to C20.
Advantageously, sugar alcohol fatty acid four esters are C14 to C22 fatty acid esters.Preferred this four ester is PEG-20 to 40 derivant, and more preferably this fatty acid ester is C16 to C20.
In preferred embodiments, four ester concentration scopes are 5 to 15% weight; Preferred minimum is 7.5% and is 12.5% to the maximum, and three ester concentration scopes are 2 to 10% weight; Preferred minimum is 4% and is 7.5% to the maximum.In further preferred embodiment, polyol fatty acid three esters comprise PEG-20 glycerol three isostearates, and sugar alcohol fatty acid four esters comprise sorbitol polyoxyethylene ether-30 tetraoctyl stearate.Most preferably, at least 50,60,70,80 or 90% weight of total polyol fatty acid three esters is PEG-20 glycerol three isostearates.Most preferably, at least 50,60,70,80 or 90% weight of total sugar alcohol fatty acid four esters is sorbitol polyoxyethylene ether-30 tetraoctyl stearates.
The present invention is that this method includes but not limited to following step from the method for skin makeup removing on the other hand:
The compositions that a. will comprise following substances is applied to skin:
I.5 to 40% weight, mix total liquid macrogol C14 to the C22 fatty acid ester of IOB value in 0.60 to 1.15 scope;
At least a of the wherein said cithrol of ii is non-sugar polyol fatty acid three esters, and the other a kind of of said cithrol is sugar alcohol fatty acid four esters;
Iii. wherein said three esters and four esters exist with 1.0 to 3.0 ratio ranges;
The liquid oil of iv.30 to 70% weight; With
The water content of v. maximum 5% weight
Said compositions is kept the time of effectively loosening, dissolving and/or disperseing the cosmetic composition on skin; With
C. water rinses said compositions from skin.
Preferably, the inventive method further is included in the step of makeup removing under the wet condition.Most preferably, said wet condition comprises one or more that are selected from following condition: use and conditions of similarity in use or the shower in the wet hands of use, the shower.
The IOB value:
The term " IOB (inorganic/organic balanced) " that this paper uses refers to show the equilibrated index of hydrophilic-hydrophobicity, and is calculated as IOB=[inorganic value]/[organic value] in the present invention.In addition; Inorganic value and organic value can be confirmed (FUJITA based on organic conceptional diagram; Makoto: " Prediction of OrganicCompounds and Organic Conceptional Diagram (prediction of organic compound and organic conceptional diagram) "; Kagaku no Ryoiki (chemical field), 11 (10), 719-725 (1957)).
Among the present invention, importantly control the IOB of PEG fatty acid ester mixture of ingredients.Mixing IOB can be preferably in 0.6 to 1.15 scope, more preferably 0.75 to 1.0 scope.Be lower than 0.6 if mix IOB, then the water rinsability reduces, and shows viscosity.Therefore, it is not preferred being lower than 0.6 mixing IOB.Surpass 1.15 if mix IOB, then find to be separated or muddy, so that outward appearance and makeup removing degradation in efficiency, it is not preferred therefore being higher than 115 mixing IOB.
Ratio that can be through regulating PEG fatty acid ester composition or other surfactants is so that whole system is haze-freely confirmed the mixing IOB that are fit at about 30 ℃.Through carrying out based on the concrete IOB of the individual composition of the blending ratio of selection and the calculating of ratio thus; Use following equation, wherein a, b, c refer to individual PEG fatty acid ester composition or other surfactants a, b and c (this equation can be used for more complex surfaces activating agent admixture through the similar fashion expansion):
Wt.%}/{ wt.%} of the wt.%+c of the wt.%+b of a of wt.%+IOB (c) * c of wt.%+IOB (b) * b of mixing IOB=.{IOB (a) * a
Compositions:
Polyhydric alcohol will preferably be present in the compositions of the present invention.These polyhydric alcohol can be monomeric or polymeric.The monomer polyhydric alcohol can have 1 to 20 carbon atom and 2 to 10 hydroxyls.The exemplary monomer polyhydric alcohol comprises glycerin, propylene glycol; Glycerol; 1, the 4-butanediol; 1,3 butylene glycol; 1, the 2-butanediol; 1-6-hexanediol, 1, the 2-hexanediol; The 3-methyl isophthalic acid, the 3-butanediol; The 2-methyl isophthalic acid, ammediol, Sorbitol and composition thereof.
The polymerized polyalcohol example has polypropylene glycol, Polyethylene Glycol, dipropylene glycol, diglycerol, polyglycereol, trimethylene glycol, dipentaerythritol and combination thereof.Particularly preferably be dipropylene glycol and Polyethylene Glycol, latter's molecular weight ranges is about 200 to about 5000, preferred about 300 to about 1000.
The amount of polyhydric alcohol can respectively do for oneself composition weight about 0.5 to about 20%, preferred about 1 to about 15%, best about 2 to about 10%.
Important component of the present invention is three isostearate components of glycerol.Advantageously, this ester is oxyalkylated ester, every mole of glycerin comprise 1 to about 50, preferred about 5 to about 40, more preferably from about 15 to about 30 and best about 20 mole of alkoxy monomers.The alkoxylate monomer is the C2-C5 alkyl diol normally.These comprise ethylene glycol, propylene glycol, butanediol and composition thereof.Said mixture can be random copolymer or block copolymer.Illustration purpose presented for purpose of illustration only, suitable ester comprises POE-20 glycerol three isostearates; POE-15 glycerol three isostearates; POE-10 glycerol three isostearates; POE-5 glycerol three isostearates; POP-20 glycerol three isostearates; POP-15 glycerol three isostearates; POP-5 glycerol three isostearates; POE-POP-10,10-glycerol three isostearates; POE-POP-5,10-glycerol three isostearates and composition thereof.Term POE and POP are the abbreviations of polyoxyethylene and polyoxypropylene.For example, POE, POP-10,10-glycerol three isostearates represent that 10 moles of ethylene oxide and 10 moles of PPOX polymerizations go into glycerol three isostearates.For the present invention's POE-20 glycerol three isostearates most preferably.This material can obtain by trade mark Uniox GT-20 IS, is sold by Nippon Oil&Fat Company.
The amount that is used for three isostearates of glycerol of the present invention is preferably about 0.5 to about 30%, preferred about 2 to about 20%, best about 5 to about 15% of composition weight.
Another important component of the present invention is sugar alcohol fatty acid four ester components.Advantageously, this ester is oxyalkylated ester, and every mole of sugar alcohol comprises 1 to about 50, preferred about 5 to about 40, more preferably from about 15 to about 30 and best about 20 mole of alkoxy monomers.Said alkoxylate monomer is the C2-C5 alkyl diol normally.These comprise ethylene glycol, propylene glycol, butanediol and composition thereof.Said mixture can be random copolymer or block copolymer.Illustration purpose presented for purpose of illustration only, suitable ester comprises sorbitol polyoxyethylene ether-4 four oleate, sorbitol polyoxyethylene ether-6 four oleate, sorbitol polyoxyethylene ether-30 4 oleate, sorbitol polyoxyethylene ether-40 4 oleate, sorbitol polyoxyethylene ether-60 4 oleate, the hard ester acid esters of sorbitol polyoxyethylene ether-60 4, sorbitol polyoxyethylene ether-20 tetraoctyl stearate, sorbitol polyoxyethylene ether-30 tetraoctyl stearate, sorbitol polyoxyethylene ether-40 tetraoctyl stearate, sorbitol polyoxyethylene ether-50 tetraoctyl stearate and analog.For the present invention most preferably is sorbitol polyoxyethylene ether-30 tetraoctyl stearate.This material can obtain by trade mark UnioxST-30 IS, is sold by Nippon Oil&Fat Company.
The amount that is used for sugar alcohol fatty acid four esters of the present invention is about 5 to about 15% and preferred about 7.5 to about 12.5% of a composition weight.
Various nonionics and amphoteric emulsifier can be as optional other components of the present invention.Nonionic emulsifier is usually based on the hydrophobe unit, for example has about 10 and to the aliphatic alcohol of about 22 carbon atoms or fatty acid, alkyl chain, has about 6 alkyl phenols to about 12 carbon atoms, anhydrosorbitol and composition thereof.Common and the hydrophilic unit condensation of these hydrophobes, particularly 1 to about 50, preferred about 10 to about 30 moles oxirane, expoxy propane, epoxy butane or its mixture.Exemplary materials has the POE-20 sorbitan monolaurate; The POE-20 cetyl ether; The POE-7 glyceryl cocoate; The POE-15 stearyl ether; The POE-10 stearyl ether; POE-15 palmityl ether and combination thereof.Other useful nonionic things have alkyl polyglycoside, for example can be available from the decyl polydextrose of Henkel Corporation.Another kind of nonionic emulsifier is the long chain tertiary amine oxide.Example comprises dimethyl dodecyl amine oxide, dimethyl cetyl amine oxide; Two (2-hydroxyl) myristyl amine oxide, dimethyldecylamine oxide and combination thereof.
Can also use amphoteric emulsifier, for example betanin and sulfobetaines.The example that is fit to comprises cocamido propyl betaine, coconut oleoyl amine sulfobetaines, dodecyldimethylammonium hydroxide inner salt, cetyl dimethyl betaine and combination thereof.
The amount of nonionic or amphoteric emulsifier can each naturally composition weight about 0.1 to about 10%, preferred about 0.2 to about 5%, best about 0.3 to about 2%.
Can also comprise skin benefit agent in the compositions.One type is fatty acid ester, acids and the alcohols with 10 to 22 carbon atoms.The example that is fit to comprises stearyl alcohol, spermol, isooctadecanol, lauryl alcohol, myristyl alcohol, palmityl alcohol, oleyl alcohol 、 behenyl alcohol and/or its acid and mixture.The representative of fatty acid ester is C2 to the C6 straight chain and the branched alkyl ester of stearic acid, isostearic acid, lauric acid, myristic acid, (Palmic acid), oleic acid He behenic acid.Exemplary materials is different n-nonanoic acid isotridecyl ester, three (2-ethylhexanoate), isopropyl myristate, isostearic acid iso stearyl ester, capric acid/Trivent OCG and combination thereof.Be used for plant derivation ester of the present invention and comprise Oleum Helianthi, safflower oil, Oleum Gossypii semen, Oleum Glycines, Testa oryzae oil, sterin and combination thereof.
The amount of these materials can be about 0.1 to about 30%, preferred about 0.5 to about 25%, best about 2 to about 20% of a composition weight.
Anion emulsifier generally is not included in the present composition.These compositionss are not intended to produce foam.Therefore, any amount of the anion emulsifier of existence be composition weight 0 to 5%, preferred 0 to 2%, more preferably 0 to 1%, best to exist less than 0.05 or 0.01%.
Oil phase according to emulsion compositions of the present invention can contain above-mentioned natural and synthetic ester, hydrocarbon and silicone oil.Amount when each of these materials exists can be about 20 to about 80%, preferred about 25 to about 75%, best about 30 to about 70% of a composition weight.
Silicone oil can be volatility or non-volatile kind.Volatile silicone oils is the polydimethylsiloxane of ring-type or straight chain normally, contains 3 to 9, preferred 4 to 5 siloxanes atoms.What the straight chain type was famous is polydimethylsiloxane (CTFA title), and cyclic type famous be Cyclomethicone.But latter's commercial sources is available from Dow Corning Corporation, trade mark DC 244, DC245, DC 344 and DC 345.In Japan, they can trade mark SH-245 available from Dow CorningToray.
The example of non-volatile silicone oil has the alkylsiloxane of gathering, polyoxyethylene alkyl aryl radical siloxane and polyether siloxane copolymer.But the example of polydimethylsiloxane is the DC200 series of commercial sources available from Dow Corning.But gather alkylsiloxane and be commercial sources available from General Electric Company, trade mark is SF 1075 aminomethyl phenyl fluids for example.But useful polyether siloxane copolymer commercial sources is available from General Electric Company, trade mark SF-1066.
Be fit to hydrocarbon of the present invention and comprise mineral oil, isoparaffin and polyalphaolefin (those that for example, can trade mark Permethyl 99A or 101 obtain) and polyisobutylene.
Usually, the present composition will need thickening agent or viscosifier.These materials can about 0.001 to about 10%, preferred about 0.01 to about 5%, the best about 0.1 amount existence to about 0.5% weight.Exemplary materials has natural gum, for example xanthan gum, chondrus ocellatus Holmes polysaccharide, guar gum, pectin, sodium carboxymethyl cellulose, hydroxy alkyl cellulose and alkylcellulose and any combination thereof.Useful polymeric type thickening agent can comprise cross-linked acrylic acid or methacrylate polymer, for example Noveon sell with the Carbopol trade mark those.Also can use the emulsifying agent/thickening agent of combination, be exemplified as material such as PemulenTR2
.
In some cases, the present composition possibly need opacifier and/or pearling agent (pearlizers).What be used in particular for this purpose is diglycol stearate; Titanium dioxide; The Muscovitum of coating of titanium dioxide (for example Timiron
); Lattice body (lattices) is phenylethylene ethylene/propenoic acid ester copolymer (for example Acusol
OP301) and composition thereof for example.
Antiseptic also adds in the preparation usually.Representative materials comprises phenoxyethanol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, ethylenediaminetetraacetic acid (EDTA) salt, benzyl alcohol, iodo propinyl butyl carbamate, DMDM Hydantoin and combination thereof.The weight range of these materials can be the about 0.0001 any value to about 1% scope of composition weight.
Optional accessory constituent can comprise coloring agent, aromatic, promotion composition (promotionalingredients), respectively does for oneself and effectively realizes its amount of function separately.Typical promotion composition comprises vitamin, for example retinyl palmitate, tocopherol acetate and nicotiamide.Other promoter (promotionals) comprise conjugated linoleic acid, ceramide, pentapeptide and combination thereof.Remover (exfoliants) be can also use, for example silicon dioxide and polyethylene powders comprised.
More describe the present invention in detail through following non-limiting example now.These embodiment only are illustrative purpose, are not to limit the present invention by any way.Physical test method is described below:
Except in operation embodiment and comparative example or other clear and definite indicated places, amount or ratio or reaction condition, the physical property of material and/or all numerals of purposes of describing material in this description are interpreted as being modified by speech " pact ".
The term that uses in this description " comprises " that expection comprises the existence of indication characteristic, integral body (integer), step, component, but does not get rid of the existence or the increase of one or more characteristics, integral body, step, component or its combination.
Except as otherwise noted, all percentage ratios expections are by weight among this description and the embodiment.
Embodiment 1
Use following program to prepare a series of the present invention (A to D) and corresponding comparative example (A1 to D1) respectively, render a service with non-sugar polyol fatty acid three esters of a series of specific ratios in the evaluation water-in-oil emulsion and the makeup removing of sugar alcohol fatty acid four ester admixtures according to table 1 and 2.Unload cosmetic method (MUR) test and relate to following program.Bio Skin Plate (from BEAULAX, Co.Ltd., Tokyo, Japan) sample is cut into 3 * 4cm piece.The base material color of each piece is measured twice with Minolta spectrophotometer CM-2002.Amount is applied to each piece of Bio SkinPlate sample with the ring of 3cm diameter for the lip pomade of 0.0080g.After 5 minutes, the lip pomade color is through spectrophotometer measurement, with after washing.Then 0.2ml specimen solution is applied to the lip pomade ring.Rub counterclockwise then sample blocks 10 times is subsequently with finger friction 10 times counterclockwise.Use about 37 ℃ tap water rinsing 30 seconds.After five rinsings, measure the color of lip pomade mottle then once more.Convert measured value into change color percentage ratio then.Use three times multiple meansigma methods.Test formulations and result are reported in following table.
Table 1 formulation Example of the present invention
| Composition | Prescription A (the present invention) | Prescription B (the present invention) | Prescription C (the present invention) | Prescription D (the present invention) |
| Phase A | ||||
| Mineral oil | Until 100 | Until 100 | Until 100 | Until 100 |
| Tricaprylin | 7.50 | 15.00 | 10.00 | 15.00 |
| Isopropyl myristate | 12.5 | 5.00 | 10.00 | - |
| Cyclomethicone | - | - | - | 5.00 |
| Dipropylene glycol | 3.00 | 3.00 | 3.00 | 3.00 |
| Phenoxyethanol | 0.40 | 0.40 | 0.40 | 0.40 |
| Tocopherol acetate | 0.20 | 0.20 | 0.20 | 0.20 |
| Phase B | ||||
| PEG-20 glycerol three isostearates | 11.00 | 10.00 | 9.50 | 10.00 |
| Sorbitol polyoxyethylene ether-30 tetraoctyl stearate | 5.00 | 5.00 | 4.50 | 5.00 |
| Sorbitan isostearate | 1.50 | 0.75 | 1.25 | 1.50 |
| PEG-20 castor oil hydrogenated isostearate | 1.50 | 0.75 | 1.25 | 1.50 |
| Phase C | ||||
| ?Methylgluceth-10 | 0.50 | 0.50 | 0.50 | 0.50 |
| Deionized water | 0.096 | 1.5 | - | 1.5 |
| Test result | ||||
| Makeup removing rate (%) | 74.53 | 72.12 | 78.47 | 72.39 |
Table 2 comparative formula embodiment
| Composition | Prescription A1 (contrast) | Prescription B1 (contrast) | Prescription C1 (contrast) | Prescription D1 (contrast) |
| Phase A | ||||
| Mineral oil | Until 100 | Until 100 | Until 100 | Until 100 |
| Tricaprylin | 7.50 | 15.00 | 10.00 | 15.00 |
| Isopropyl myristate | 12.5 | 5.00 | 10.00 | - |
| Cyclomethicone | - | - | - | 5.00 |
| Dipropylene glycol | 3.00 | 3.00 | 3.00 | 3.00 |
| Phenoxyethanol | 0.40 | 0.40 | 0.40 | 0.40 |
| Tocopherol acetate | 0.20 | 0.20 | 0.20 | 0.20 |
| Phase B | ||||
| PEG-20 glycerol three isostearates | 16.00 | 15.00 | 14.00 | 15.00 |
| Sorbitol polyoxyethylene ether-30 tetraoctyl stearate | - | - | - | - |
| Sorbitan isostearate | 1.50 | 0.75 | 1.25 | 1.50 |
| PEG-20 castor oil hydrogenated isostearate | 1.50 | 0.75 | 1.25 | 1.50 |
| Phase C | ||||
| Methylgluceth-10 | 0.50 | 0.50 | 0.50 | 0.50 |
| Deionized water | 0.096 | 1.5 | - | 1.5 |
| Test result | ||||
| Makeup removing rate (%) | 65.75 | 59.55 | 60.94 | 57.02 |
Result based on report in the table 1 and 2 proves with corresponding comparative sample and compares that sample of the present invention is the most effective.
The program of example embodiment in the test chart:
Each prescription of 10g in the table 1 and 2 mixed with 3g water prepare sample, wherein this test condition simulation condition of removing ornaments and formal dress with wet hands.The MUR test description in before chapters and sections.
The program of example embodiment in the preparation table:
Be prepared as follows the prescription in the table 1 and 2:
Component is blended together to be shown the oil phase of phase A in the composition table.Oil phase is once abundant fusion, and the surfactant that will be shown phase B in then will showing is added into main body mutually.After fully mixing, the Methylgluceth-10 that will be shown phase C in will show at last is added into the main body admixture, continues stirring until main body admixture become homogenizing and clarification.
Aforementioned specification and embodiment have described selected embodiment of the present invention.In view of the above, those skilled in the art can expect changing and adjustment, and it is all within scope of the present invention and spirit.
Claims (11)
1. stable, anhydrous makeup removing agent personal care composition basically, said composition comprises:
A.5 to 40% weight, mix total liquid macrogol C14 to the C22 fatty acid ester of IOB value in 0.60 to 1.15 scope;
B. at least a of wherein said cithrol is non-sugar polyol fatty acid three esters, and the other a kind of of said cithrol is sugar alcohol fatty acid four esters; Wherein said polyol fatty acid three esters are that glycerol C14 to C22 fatty acid ester and wherein said sugar alcohol fatty acid four esters are C14 to C22 fatty acid esters;
C. wherein said three esters and four esters exist with 1.0 to 3.0 ratio ranges;
D.30 to the liquid oil of 70% weight; With
The water content of e. maximum 5% weight.
2. the compositions of claim 1, wherein said polyol fatty acid three esters are PEG-10 to 30 derivants.
3. the compositions of claim 2, wherein said polyol fatty acid three esters are C16 to C20.
4. the compositions of claim 1, wherein said four esters are PEG-20 to 40 derivants.
5. the compositions of claim 4, wherein said sugar alcohol fatty acid four esters are C16 to C20.
6. the compositions of claim 1, the concentration range of wherein said four esters is 5 to 15% weight.
7. the compositions of claim 3, the concentration range of wherein said three esters is 2 to 10% weight.
8. the compositions of claim 1, wherein said polyol fatty acid three esters are PEG-20 glycerol three isostearates, and said sugar alcohol fatty acid four esters are sorbitol polyoxyethylene ether-30 tetraoctyl stearates.
9. one kind is used for from the method for skin makeup removing, and this method comprises the steps:
A. the compositions with claim 1 is applied to skin;
Said compositions is kept the time of effectively loosening, dissolving and/or disperseing the cosmetic composition on skin; With
C. water rinses said compositions from skin.
10. the method for claim 9, this method further are included in the step of makeup removing under the wet condition.
11. the method for claim 10, wherein said wet condition comprise that one or more are selected from following condition: use in use or the shower in the wet hands of use, the shower.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0621993.5A GB0621993D0 (en) | 2006-11-04 | 2006-11-04 | Make-up remover cosmetic compositions |
| GB0621993.5 | 2006-11-04 | ||
| PCT/EP2007/061590 WO2008052956A1 (en) | 2006-11-04 | 2007-10-29 | Make-up remover cosmetic compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101578090A CN101578090A (en) | 2009-11-11 |
| CN101578090B true CN101578090B (en) | 2012-04-25 |
Family
ID=37547339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780041031XA Expired - Fee Related CN101578090B (en) | 2006-11-04 | 2007-10-29 | Make-up remover cosmetic compositions |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5361730B2 (en) |
| KR (1) | KR20090086393A (en) |
| CN (1) | CN101578090B (en) |
| GB (1) | GB0621993D0 (en) |
| WO (1) | WO2008052956A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010090111A (en) * | 2008-09-10 | 2010-04-22 | L'oreal Sa | Cleansing composition |
| JP5630801B2 (en) * | 2009-03-31 | 2014-11-26 | 株式会社コーセー | Cleaning composition |
| JP5588125B2 (en) * | 2009-06-01 | 2014-09-10 | 東邦化学工業株式会社 | Cleanser for makeup cleansing |
| GB201215054D0 (en) | 2012-08-23 | 2012-10-10 | Unilever Plc | Mild foaming make-up remover composition |
| CN104666235A (en) * | 2015-02-11 | 2015-06-03 | 上海彤颜实业有限公司 | Cleansing lotion with capabilities of replenishing water and dispelling dirt |
| US20160367959A1 (en) * | 2015-06-18 | 2016-12-22 | Avon Products, Inc. | Multiphase Compositions |
| GB201600778D0 (en) * | 2016-01-15 | 2016-03-02 | Croda Int Plc | Composition,emulsion,method and use |
| JP6045734B1 (en) * | 2016-02-29 | 2016-12-14 | 株式会社 資生堂 | Cleansing cosmetics |
| EP3727602B1 (en) * | 2017-12-22 | 2021-11-24 | LVMH Recherche | Oil-in-water emulsified cosmetic |
| CN109248105A (en) * | 2018-09-29 | 2019-01-22 | 广州艾蓓生物科技有限公司 | A kind of makeup removing stick and preparation method thereof |
| CN113230170B (en) * | 2021-05-21 | 2022-06-10 | 上海新高姿化妆品有限公司 | Double-continuous-phase cleansing oil with effects of cleaning and nourishing skin and preparation method thereof |
| WO2024095919A1 (en) * | 2022-10-31 | 2024-05-10 | 花王株式会社 | Cleaning agent composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1642519A (en) * | 2002-03-26 | 2005-07-20 | 花王株式会社 | Cleansing cosmetic |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2977568B2 (en) * | 1989-11-17 | 1999-11-15 | 鐘紡株式会社 | Cleansing cosmetics |
| JPH10236922A (en) * | 1997-02-25 | 1998-09-08 | Kao Corp | Cleanser composition |
| JP4638018B2 (en) * | 2000-03-30 | 2011-02-23 | 株式会社コーセー | Oily cleaning agent |
| WO2002017864A1 (en) * | 2000-08-31 | 2002-03-07 | The Procter And Gamble Company | Pre-shampoo conditioning composition |
| JP2003095919A (en) * | 2001-09-27 | 2003-04-03 | Kose Corp | Oil-base cleansing material |
| JP4373103B2 (en) * | 2003-02-10 | 2009-11-25 | 花王株式会社 | Transparent liquid oily composition |
| JP2004018451A (en) * | 2002-06-14 | 2004-01-22 | Shiseido Co Ltd | Gel-like composition |
| JP2005002047A (en) * | 2003-06-12 | 2005-01-06 | Kanebo Cosmetics Inc | Oily cleansing cosmetic |
| JP4325463B2 (en) * | 2004-03-31 | 2009-09-02 | 日油株式会社 | Cleansing cosmetics |
| JP2006176469A (en) * | 2004-12-24 | 2006-07-06 | Kao Corp | Oily cleanser |
| GB0504134D0 (en) * | 2005-03-01 | 2005-04-06 | Unilever Plc | Make-up remover cosmetic compositions |
| FR2898047B1 (en) * | 2006-03-06 | 2010-12-24 | Oreal | CLEANSING GELIFYING COMPOSITION |
| JP4871090B2 (en) * | 2006-10-12 | 2012-02-08 | 花王株式会社 | Cleansing cosmetics |
-
2006
- 2006-11-04 GB GBGB0621993.5A patent/GB0621993D0/en not_active Ceased
-
2007
- 2007-10-29 CN CN200780041031XA patent/CN101578090B/en not_active Expired - Fee Related
- 2007-10-29 WO PCT/EP2007/061590 patent/WO2008052956A1/en active Application Filing
- 2007-10-29 KR KR1020097009016A patent/KR20090086393A/en not_active Application Discontinuation
- 2007-10-29 JP JP2009535064A patent/JP5361730B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1642519A (en) * | 2002-03-26 | 2005-07-20 | 花王株式会社 | Cleansing cosmetic |
Non-Patent Citations (2)
| Title |
|---|
| JP平3-161428A 1991.07.11 |
| JP特开2004-18451A 2004.01.22 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5361730B2 (en) | 2013-12-04 |
| WO2008052956A1 (en) | 2008-05-08 |
| KR20090086393A (en) | 2009-08-12 |
| CN101578090A (en) | 2009-11-11 |
| GB0621993D0 (en) | 2006-12-13 |
| JP2010508323A (en) | 2010-03-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101578090B (en) | Make-up remover cosmetic compositions | |
| CN102088949B (en) | Ester compounds for use in personal care products | |
| KR101421749B1 (en) | Personal care compositions | |
| CN104918595A (en) | Cosmetic composition | |
| MXPA04011178A (en) | Conditioning shampoo composition. | |
| TW200534871A (en) | Oily cleansing composition | |
| JP2007320872A (en) | Hair cosmetic product | |
| JP5709167B2 (en) | Gel cleansing cosmetic | |
| WO2010065297A1 (en) | Compositions having a plurality of discrete emulsions | |
| CN101686917B (en) | Personal care composition with cocoa butter and dihydroxypropyl ammonium salts | |
| WO2007033453A1 (en) | Multifunctional cosmetic composition, process for preparing said cosmetic composition and cosmetic product | |
| CN1853601B (en) | Cosmetic composition for removing makeup | |
| JP6062538B2 (en) | Compositions that provide shine and methods of use | |
| JP2003160448A (en) | Thready hair cosmetic | |
| JP7112068B2 (en) | Oily cleansing cosmetics | |
| JP4763474B2 (en) | Oily skin cleansing material | |
| JP3931295B2 (en) | Emulsified cosmetic for hairdressing | |
| JP6909179B2 (en) | Oily cosmetics | |
| CN101878020B (en) | Alpha or beta hydroxy acid adducts of oil | |
| JP5777859B2 (en) | Emulsified composition | |
| JP6284463B2 (en) | Emulsifying shaving agent | |
| JP7215377B2 (en) | cleansing composition | |
| EP3582746B1 (en) | Cosmetic lotion | |
| JP5686938B2 (en) | Oily skin cleanser | |
| CN116322611A (en) | Moisturizing no-rinse makeup removal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120425 Termination date: 20201029 |