CN101570665A - High brightness coating agent for leathers and stones and preparation method thereof - Google Patents

High brightness coating agent for leathers and stones and preparation method thereof Download PDF

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Publication number
CN101570665A
CN101570665A CNA2009100594988A CN200910059498A CN101570665A CN 101570665 A CN101570665 A CN 101570665A CN A2009100594988 A CNA2009100594988 A CN A2009100594988A CN 200910059498 A CN200910059498 A CN 200910059498A CN 101570665 A CN101570665 A CN 101570665A
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weight part
agent
brightening agent
raw material
brightening
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CN101570665B (en
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蒋发学
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Jiang Wei
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Abstract

The invention provides a high brightness coating agent for leathers and stones and a preparation method thereof. The coating agent is made from the following self-made materials and marketable raw materials by weight part: 1.44-13.44 parts of oil lubricating brightening agent, 2.40-22.40 parts of waterproof brightening agent, 9.75-91.00 parts of mixed wax liquid brightening agent, 6.93-64.68 parts of natural resin brightening agent, 6.00-56.00 parts of nitro paint brightening agent, 1.20-11.20 part of emulsification accelerating agent, 0.08-0.77 parts of toughening agent, 0.55-5.12 parts or 1.10-10.25 parts of emulsifying agent, 0.00-2.62 parts of dye and 0.82-7.67 parts of spice.

Description

High brightness leather stone material finishing agent and preparation method thereof
Technical field
The present invention and leather, stone material auxiliary agent, especially relevant with brightening agent, the finishing agent of leather, stone material.
Technical background
Existing leather agent such as glossy dose, brightening agent etc., all add imported raw materials such as cohune wax after, add other raw materials again to make not only function singleness, and price height; Existing stone material lustering agent, domestic brand use valency 5-8 unit/m 2, imported product uses valency 15-30 unit/m 2, price is all higher.
Summary of the invention
Purpose of the present invention is to provide a kind of raw material to be easy to get to domestic outer city/market, township, and with low cost, the high brightness leather of diverse in function, stone material finishing agent are embrocated test paper.
The present invention is achieved in that
High brightness leather of the present invention, stone material finishing agent are to be made by the worked materials and the marketable material of following weight parts:
Glossy brightening agent 1.44-13.44
Waterproof brightening agent 2.40-22.40
Blended wax liquid brightening agent 9.75-91.00
Natural resin brightening agent 6.93-64.48
Nitro paint brightening agent 6.00-56.00
Emulsification promotor 1.20-11.20
Toughner 0.08-0.77
Emulsifying agent 0.55-5.12 or 1.10-10.25
Dyestuff 0.00-2.62
Spices 0.82-7.67
The prescription of high brightness leather of the present invention, stone material finishing agent is as follows: weight part table one
Figure A20091005949800051
The prescription of glossy brightening agent is as follows: weight part table two
Figure A20091005949800052
The prescription of waterproof brightening agent is as follows: weight part table three
Figure A20091005949800053
The prescription of blended wax liquid brightening agent is as follows: weight part table four
The prescription of natural resin brightening agent is as follows: weight part table five
Figure A20091005949800062
The prescription of nitro paint brightening agent is as follows: weight part table six
Figure A20091005949800063
The prescription of emulsification promotor is as follows: weight part table seven
Figure A20091005949800071
The method of processing product of the present invention is as follows:
1. earlier go out various raw materials, and after bulk, coarse grain shape raw material pulverized, adding solvent, emulsification promotor were made glossy brightening agent, waterproof brightening agent, blended wax liquid brightening agent, natural resin brightening agent, nitro paint brightening agent respectively by the formula ratio scale.Then, five kinds of brightening agents are mixed, stir after 2-3 minute, add toughner, emulsifying agent, spices continues to stir 3-5 minute, makes colourless high brightness leather, stone material finishing agent emulsion.
2. when system is with the look emulsion, weigh oil-soluble colourant earlier, 10 fens ethanol that will take out from blended wax liquid brightening agent again add, and mix thoroughly, dissolve, and then colorant are added in the mixed emulsion, stir.
3. filtration emulsion is removed mechanical impurity, measures, packs.
4. when preparation high brightness leather, stone material test paper, the cotton paper that intensity is high is cut into long 16 centimetres, wide 10 centimetres paper piece and changes into two layers earlier, by five layers of overlapping of every bag, puts into mixed emulsion and soaks again, press go unnecessary emulsion after, sealing, packing.
The present invention, raw material is easy to get, price is low, diverse in function, clothing, dust are not stained with in rapid drying.With emulsion of the present invention or after wiping away paper wiping leather, stone material, furniture, vehicle enclosure, can remove slight dirt, appropriate waterproof prevents or delaying retrogradation, increases gloss.Raw materials cost 8.5-9 of the present invention unit/kilogram.
Embodiment:
White oil claims Liquid Paraffin again, obtains the lubricating oil distillate of medium viscosity by black petroleum products through underpressure distillation, and precision work is made again.Select 7~No. 18 white oils of industrial goods for use.In this agent, play glossy, glossiness-giving effect.
Methyl Hydrogen Polysiloxane Fluid claims silicone oil again.Select the industrial goods of 350~800 li pools of viscosity for use.In this agent, make the waterproof brightening agent.
Ceresine has another name called Microcrystalline Wax.Selecting fusing point for use is 60 ℃~80 ℃ synthetic ceresine.It can with the paraffin compatibility, the coarse-grain state when changing wax crystal is again one of main raw material of blended wax liquid brightening agent.
Beeswax, selecting fusing point for use is 58 ℃-62 ℃ industrial goods.In this agent, play profit leather, enhanced shine.It is one of main raw material of blended wax liquid brightening agent.
Paraffin contains Chinese wax and yellow wax.Selecting fusing point for use is 48 ℃-66 ℃ industrial goods.The price of paraffin is lower, but shows coarse-grain during crystallization, and no saponification value can not be saponified into emulsion.Therefore, a certain amount of ceresine must be added and emulsification promotor changes its shortcoming.It is one of main raw material of blended wax liquid brightening agent.
Shellac: claim lac again, the product that discolors claims the white spirit lacquer again, is the main raw material of natural resin brightening agent.
Rosin: claim ripe rosin or ripe perfume (or spice) again.Select I, II level industry rosin for use.It is the main raw material of natural resin brightening agent, can cooperate stearic acid to promote the paraffin saponification again.
Nitro paint claims zapon varnish again, is the main raw material of nitro paint brightening agent.Select the zapon varnish of tool quick-drying and glossiness 〉=90% for use.
Stearic acid: have another name called stearic acid.Select fusing point 70-71 ℃ 1-3 level industrial goods for use.It has waterproof, bright character, is again one of main raw material of emulsification promotor.
Turps: select industrial goods for use, make solvent.
Rosin claims industrial naptha again No. 200.Select industrial goods for use.In this agent, make solvent, thinner, siccative.
Polyoxyethylenated castor oil: belonging to nonionogenic tenside, is the good emulsifying agent (also available non-ionic type dodecyl phenol polyethenoxy ether---polyoxyethylene nonylphenol ether, but consumption increases doubly) of oil, Wax, selects industrial goods for use.
Dibutyl phthalate (or dioctyl ester): select industrial goods for use, make toughner.
Dyestuff by required color and luster, is selected oil-soluble colourant for use, carry out the color and luster compatibility again after, make various color and luster emulsions.
Embodiment one
The present invention is made by the worked materials and the commercial raw material of following weight part:
Glossy brightening agent 7.20
Waterproof brightening agent 12.00
Blended wax liquid brightening agent 48.75
Natural resin brightening agent 34.65
Nitro paint brightening agent 30.00
Emulsification promotor 6.00
Toughner 0.38
Emulsifying agent 2.75~5.49
Nigrosine 1.40
Spices 4.11
The preparation method of this enforcement is:
1. it is standby to reserve 10 parts of ethanol from blended wax liquid brightening agent prescription.
2. weigh various brightening agents, emulsification promotor by formula ratio, standby.
3. 10 parts of ethanol will reserving are added in the bottle that fills 1.4 parts of aniline black dyestuffses, mix mill base, and are standby.
4. with 5 kinds of brightening agents, toughner, emulsifier mix, stir after 2~3 minutes, add spices, mill base, restir 3~50 minutes just obtains black high brightness leather, stone material finishing agent emulsion, weighing, sealing, packing.
Embodiment two:
The present invention is made by the worked materials and the commercial raw material of following weight part:
Glossy brightening agent 13.44
Waterproof brightening agent 22.40
Blended wax liquid brightening agent 91.00
Natural resin brightening agent 64.68
Nitro paint brightening agent 56.00
Emulsification promotor 11.20
Toughner 0.77
Emulsifying agent 3.84~7.69
Spices 7.67
The preparation method of present embodiment and embodiment are together.
Embodiment three:
Glossy brightening agent 8.64
Waterproof brightening agent 14.40
Blended wax liquid brightening agent 58.50
Natural resin brightening agent 47.58
Nitro paint brightening agent 36.00
Emulsification promotor 7.20
Toughner 0.46
Emulsifying agent 3.30~6.00
Spices 4.93
The preparation method of present embodiment and embodiment are together.
Embodiment four:
Glossy brightening agent 10.08
Waterproof brightening agent 16.80
Blended wax liquid brightening agent 68.25
Natural resin brightening agent 48.51
Nitro paint brightening agent 42.00
Emulsification promotor 8.40
Toughner 0.54
Emulsifying agent 3.63~7.26
Coffee-like oil-soluble colourant 1.96
Spices 5.75
The preparation method of present embodiment and embodiment are together.
Once with joining product be coated with polish shoes, fur clothing, leather sofa, stone material, porcelain decorative sheet, automobile case, effect be all good.
Once how tame leather beauty salon, stone material manufacturing enterprise tried out consistent the reflection in the city with product of the present invention: " easy to use, the glossiness height, wiping effect is good ", and require the supply of material.
The contriver once with 4 formulation products of the present invention and commercially available Chinese brand name, joint venture using Chinese and foreign investment's product, the international quality authentication product of tool and one newly appear on the market product totally 4 representative comparing property of brand embrocate test, and do trial sheet, its result such as following table with SS-82 type photoelectric glossmeter:
Table eight
Figure A20091005949800111
Once the emerging stone material in Chengdu ten thousand company was provided with 4 formulation products of the present invention 5 kinds homemade, import stone materials (containing marble, granite) carry out the scene to be embrocated and notes down, and its glossiness changes as following table:
Table nine
Figure A20091005949800121
Annotate: 1. surveying instrument is a SS-82 type photoelectricity flash ranging meter
2. in the table eight, brand 1 is a Chinese brand name, and brand 2 is certain joint venture using Chinese and foreign investment's product, and brand 3 obtains international quality authentication product for certain, and brand 4 is certain product that newly appears on the market.
3, comparative is embrocated test (table eight), and the glossiness of 1-4 product is all above commercially available brand.
4, embrocate stone material (table nine), remove 2 #, 4 #After embrocating Galaxy Black, glossiness subtracts outside (≤0.4 °) slightly, and the glossiness of other stone materials all increases or significantly increases.
5, the market price of brand 1 〉=220 yuan/kilogram, 45~60 yuan/kilogram of the Chengdu prices of commercially available stone care agent.Only 8.5 yuan-9 yuan/kilogram of the raw material valencys of product of the present invention are 1/5~1/6 of commercially available stone care agent, are 1/24 of leather maintaining agent (Chinese brand name).The market profit margin is huge.

Claims (9)

1. high brightness leather, stone material finishing agent and preparation method thereof.It is to be made by the worked materials of following weight parts and commercial raw material:
Glossy brightening agent 1.44-13.44
Waterproof brightening agent 2.40-22.40
Blended wax liquid brightening agent 9.75-91.00
Natural resin brightening agent 6.93-64.68
Nitro paint brightening agent 6.00-56.00
Emulsification promotor 1.20-11.20
Emulsifying agent 0.55-5.12 or 1.10-10.25
Toughner 0.08-0.77
Dyestuff 0.00-2.62
Spices 0.82-7.67
2, according to described material of claim 1 and raw material, it is characterized in that: glossy brightening agent is made up of the white oil of 0.90-8.40 weight part and the rosin of 0.54-5.04 weight part.
3. according to described material of claim 1 and raw material, it is characterized in that: the waterproof brightening agent is made up of the Methyl Hydrogen Polysiloxane Fluid of 0.60-5.60 weight part and the ethanol of 1.80-16.80 weight part.
4. according to described material of claim 1 and raw material, it is characterized in that: blended wax liquid brightening agent is the ceresine by the 0.38-3.50 weight part, 0.52-4.90 the beeswax of weight part, 0.60-5.60 the paraffin of weight part, 1.50-14.00 the turps of weight part, the ethanol of the rosin of 2.25-21.00 weight part and 4.50-42.00 weight part is formed.
5. according to described material of claim 1 and raw material, it is characterized in that: the natural resin brightening agent is the shellac by the 0.45-4.20 weight part, and the turps of the rosin of 0.90-8.40 weight part (1-2 level), 2.58-24.08 weight part and the ethanol of 3.00-28.00 weight part are formed.
6. according to described material of claim 1 and raw material, it is characterized in that: the nitro paint brightening agent is the zapon varnish by the 1.80-16.80 weight part, and the turps of the rosin of 1.20-11.20 weight part and 3.00-28.00 weight part is formed.
7. according to described material of claim 1 and raw material, it is characterized in that: emulsification promotor is the rosin by the stearic acid of 0.32-2.94 weight part, 0.23-2.10 weight part, and the ethanol of the turps of 0.29-2.66 weight part and 0.38-3.50 weight part is formed.
8. according to the described raw material of claim 1, it is characterized in that: toughner is the dibutyl phthalate (or two sad) of 0.08-0.77 weight part;
Emulsifying agent is the polyoxyethylenated castor oil of 0.55-5.12 weight part or the dodecyl phenol polyethenoxy ether (0P) of 1.10-10.04 weight part;
Dyestuff is the oil-soluble colourant of 0.00-2.62 weight part;
Spices is the oily cosmetics essence of 0.82-7.67 weight part.
9. according to claim 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 described preparation methods, it is characterized in that comprising the steps:
(1) with ceresine, beeswax, paraffin, shellac, rosin, be ground into particulate, standby.
(2) go out various raw materials by the formula ratio scale, add solvent, emulsification promotor, make various brightening agents.
(3) 5 kinds of brightening agents are mixed, stir after 2-3 minute, adding emulsifying agent, toughner, spices, dyestuff are made for milk sap.Or band look emulsion.
(4) filter emulsion, remove mechanical impurity, metering, packing, sealing.
(5) system high brightness leather, stone material cleansing tissue pack.
CN200910059498A 2009-06-03 2009-06-03 High brightness coating agent for leathers and stones and preparation method thereof Expired - Fee Related CN101570665B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101892331A (en) * 2010-07-24 2010-11-24 廖顺南 Method for performing antique treatment on leather surface
CN102226061A (en) * 2011-05-19 2011-10-26 江苏力宝建材工业有限公司 Preparation method of cloud paraffin
CN104559801A (en) * 2013-10-28 2015-04-29 昆山科尼电子器材有限公司 High-temperature bonding wax for pressuring polish of silicon wafer and preparation method of high-temperature bonding wax
CN106244027A (en) * 2016-07-28 2016-12-21 苏州海迈汽车防护材料有限公司 Have and efficiently add lustre to and the automobile polish of hydrophobic interaction
CN108587822A (en) * 2018-04-18 2018-09-28 佛山慧创正元新材料科技有限公司 A kind of aerial fog type leather and fur products decontamination brightener
CN109536043A (en) * 2018-11-13 2019-03-29 武汉市科达云石护理材料有限公司 Stone material cerul oiliness suspension and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1309794C (en) * 2005-04-18 2007-04-11 蒋发学 Preservative agent for shining leather and stone

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101892331A (en) * 2010-07-24 2010-11-24 廖顺南 Method for performing antique treatment on leather surface
CN102226061A (en) * 2011-05-19 2011-10-26 江苏力宝建材工业有限公司 Preparation method of cloud paraffin
CN104559801A (en) * 2013-10-28 2015-04-29 昆山科尼电子器材有限公司 High-temperature bonding wax for pressuring polish of silicon wafer and preparation method of high-temperature bonding wax
CN106244027A (en) * 2016-07-28 2016-12-21 苏州海迈汽车防护材料有限公司 Have and efficiently add lustre to and the automobile polish of hydrophobic interaction
CN108587822A (en) * 2018-04-18 2018-09-28 佛山慧创正元新材料科技有限公司 A kind of aerial fog type leather and fur products decontamination brightener
CN109536043A (en) * 2018-11-13 2019-03-29 武汉市科达云石护理材料有限公司 Stone material cerul oiliness suspension and preparation method thereof

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