CN101560065B - Preparation method for colored ice-patterned glass - Google Patents
Preparation method for colored ice-patterned glass Download PDFInfo
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- CN101560065B CN101560065B CN2009100225127A CN200910022512A CN101560065B CN 101560065 B CN101560065 B CN 101560065B CN 2009100225127 A CN2009100225127 A CN 2009100225127A CN 200910022512 A CN200910022512 A CN 200910022512A CN 101560065 B CN101560065 B CN 101560065B
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Abstract
The invention relates to a preparation method for colored ice-patterned glass, the method uses ion diffusion colored glass to prepare colored ice-patterned glass, making up the defect of monotonous color of ice-patterned glass and improving the visual and decoration effects of the ice-patterned glass. The colored ice-patterned glass prepared by the method in the invention has diverse colors, actual and natural coloring and visual effects, convenient operation, low energy consumption, saved energy, and is suitable for mass production with good decoration effect and high production added value.
Description
Technical field
The present invention relates to a kind of manufacture method of ice glass, particularly a kind of preparation method of colored ice-patterned glass.
Background technology
The frost flower ambetti belongs to secondary processing glass, is commonly called as art of architecture light non-reflecting glass again.Be widely used in indoor and outdoor ambetti, artwork glass, glass light fixture, tea glass, high-grade wine-bottle, makeup vial etc.Decorative pattern nature, forever, do not repeat, product is sparkling and crystal-clear bright.The manufacturing of frost flower ambetti is to make base material with former of sheet glass, adopts specific technology, material, means to copy out light diffuse scattering ambetti just as beautiful pattern as " frost flower " on the surface of glass." frost flower " ambetti in process of production, at first glass substrate will be carried out surperficial frosting (frosted or sandblast) handles, make it make transparent and lighttight smooth non-reflecting glass earlier, can make like this when following one technology applies hide glue, the surface of glue layer and glass hacking is combined securely, through reasonable time, behind the hide glue dry shrinkage, numerous glass particles is come off from glass pane surface, and make beautiful " frost flower " pattern.Therefore, ice glass is generally transparent white.
Introduced a kind of " whole embossment ice glass " among the CN 2368845Y, the essence of this patented technology scheme is as carrier (base material) with sandblast or ice glass, sticking thereon can complying with again needs to constitute various geometric metal-coated membrane plastic glue strips, and then add folded one deck glass in a corresponding side, make the metal-coated membrane plastic glue strip between sandblast or ice glass and added glass, sealing around remaking.As seen, it is a kind of figured plate glass of hollow that this technical scheme provides, and does not relate to the technical intelligence of how to make ice glass itself.CN 1277163A has introduced a kind of " artistic ice glass manufacture craft ", it is to spray to hide glue on glass equably, after treating that surperficial selenium is done, discolour silica gel (is commonly called as siccative, color has green thin out red after the moisture absorption) spreading is being coated with counted on glass by hide glue, treat behind the certain hour discolour silica gel to be collected, uncover the hide glue that is coated onto glass surface again.The ice glass of producing with this technical scheme is not an ice glass truly, but a kind of principle by multiple film transfer printing is at the frost flower pattern that stays on glass.This pattern is difficult to be combined as a whole securely with glass, can take off as frost flower patterns such as humidity, water pouring and take off; Wiping or the permanent irradiation of burning sun when being unable to undergo to clean; True, the natural vision weak effect of frost flower.CN 1218894C is a raw material with gelatine, carpenter's glue, reuse glue, and through the ice glass of certain prepared, prepared frost flower can not take off and take off, is rich in true and natural visual effect, and manufacture craft is simple.But the ice glass color of this method preparation mostly is transparent whites, the color dullness, and decorative effect is poor.CN 2204796Y discloses a kind of ice glass plate that is equipped with metal plating, be to be equipped with the layer of metal plated film having the rough glass surface of frost flower, this metal coating increases the luminous emissivity on ice glass surface greatly, light is produced the emission of different directions, make that sheet glass can be within sweep of the eye bigger, have brighter, translucent, diffuse effect, more increased its decorative effect as finishing material.But metallic diaphragm and rough frost flower bonding properties are relatively poor, and the stereoeffect of frost flower can be under some influence behind the plated film.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above-mentioned prior art, provide a kind of color abundant, preparation technology is simple, easy to operate, energy consumption is low, save energy, the preparation method of the colored ice-patterned glass that is suitable for producing in enormous quantities, various according to the colored ice-patterned glass color that preparation method of the present invention makes, be rich in true and natural painted and visual effect, good decorating effect, added value of product height.
For achieving the above object, the technical solution used in the present invention is:
The first step: the preparation of mat glass: at first, select flawless (line), immaculate glass except that toughened glass as glass gob; Select for use a surface of 100～150 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.5 meter/minute or 0.1～2 rev/min, the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 200～250 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 200～300 mesh sieves after 2～5 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust==0～5: 3～15: 3～5: 5～8: 8～15: 1～5: 1～2: 0～2 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 3～5 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 5～10 ℃/min is warming up to 500～600 ℃ again, is incubated to turn off power supply after 5～30 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and mantoquita that the surface is unnecessary or silver salt and washes off and promptly get ion diffusion mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 0～3.5%, 2～4% gelatine, 0.5～1% hide glue and 94～97.5% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 35～45%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.1～0.5mm, glass gob is placed 20～25 ℃ then, humidity is in 20～30% the environment, to place 8～24 hours; Temperature is risen to 28～35 ℃ again, humidity is 10%, be incubated 5～10 hours, temperature is risen to 45～60 ℃ again, humidity is 0～5%, is incubated 3～5 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Glass gob of the present invention is sheet glass, container glass or vial.
The present invention utilizes ion diffusion colored glass to prepare colored ice-patterned glass, has remedied the shortcoming of ice glass color dullness, has increased the visual effect and the decorative effect of ice glass.The ice glass color of the inventive method preparation is various, be rich in true and natural painted and visual effect, and easy to operate, and energy consumption is low, and save energy is suitable for producing good decorating effect, added value of product height in enormous quantities.
Embodiment
Embodiment 1, the first step: the preparation of mat glass: at first, select flawless (line), immaculate sheet glass except that toughened glass as glass gob; Select for use a surface of 120 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.5 meter/minute, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 250 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 200 mesh sieves after 5 hours stand-by again; CuCl: SnO: FeSO wherein
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust=12: 4: 5: 10: 3: 2: 2 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 4 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 8 ℃/min is warming up to 500 ℃ again, is incubated to turn off power supply after 15 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and the mantoquita that the surface is unnecessary and washes off and promptly get cupric ion and spread red mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatine of mass percent 2%, 0.5% hide glue and 97.5% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 38%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.4mm, glass gob is placed 23 ℃ then, humidity is in 30% the environment, to place 12 hours; Temperature is risen to 30 ℃ again, humidity is 10%, is incubated 8 hours, temperature is risen to 55 ℃ again, is incubated 3 hours, this process mesogloea gradually explosion come off, treat glue-line come off clean after, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Embodiment 2, the first step: the preparation of mat glass: at first, select flawless (line), immaculate sheet glass except that toughened glass as glass gob; Select for use a surface of 150 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.5 meter/minute, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 240 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 260 mesh sieves after 3 hours stand-by again; CuCl: SnO: FeSO wherein
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust=15: 5: 8: 12: 4: 1: 1 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 5 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 5 ℃/min is warming up to 530 ℃ again, is incubated to turn off power supply after 25 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and the mantoquita that the surface is unnecessary and washes off and promptly get cupric ion and spread red mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 1%, 4% gelatine, 1% hide glue and 94% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 42%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.2mm, glass gob is placed 25 ℃ then, humidity is in 28% the environment, to place 18 hours; Temperature is risen to 32 ℃ again, humidity is 10%, is incubated 6 hours, temperature is risen to 50 ℃ again, humidity is 1%, is incubated 4 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Embodiment 3, the first step: the preparation of mat glass: at first, select flawless (line), immaculate transparent container glass except that toughened glass as glass gob; Select for use a surface of 130 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.1 rev/min, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 200 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
4(FeSO
47H
2O) stir in the compound, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 300 mesh sieves after 2 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
4(FeSO
47H
2O): water: glycerine: dextrin=2: 8: 3: 6: 9: 4: 2 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 3 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 7 ℃/min is warming up to 580 ℃ again, is incubated to turn off power supply after 5 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and mantoquita that the surface is unnecessary and silver salt and washes off and promptly get copper silver ion and spread brown mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 2%, 3% gelatine, 0.5% hide glue and 94.5% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 35%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.5mm, glass gob is placed 20 ℃ then, humidity is in 23% the environment, to place 16 hours; Temperature is risen to 28 ℃ again, humidity is 10%, is incubated 10 hours, temperature is risen to 58 ℃ again, humidity is 3%, is incubated 5 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Embodiment 4, the first step: the preparation of mat glass: at first, select flawless (line), immaculate transparent container glass except that toughened glass as glass gob; Select for use a surface of 100 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.6 rev/min, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 230 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 280 mesh sieves after 4 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust=3: 12: 4: 6: 15: 5: 1: 1 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 3 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 9 ℃/min is warming up to 550 ℃ again, is incubated to turn off power supply after 20 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and the mantoquita that the surface is unnecessary and washes off and promptly get mantoquita and silver salt and wash off and promptly get copper silver ion and spread brown mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 3.5%, 2% gelatine, 0.5% hide glue and 94% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 40%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.3mm, glass gob is placed 24 ℃ then, humidity is in 20% the environment, to place 20 hours; Temperature is risen to 33 ℃ again, humidity is 10%, is incubated 7 hours, temperature is risen to 47 ℃ again, humidity is 5%, is incubated 4 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Embodiment 5, the first step: the preparation of mat glass: at first, select flawless (line), immaculate transparent dressing product vial except that toughened glass as glass gob; Select for use a surface of 140 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 1.5 rev/mins, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 210 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 230 mesh sieves after 5 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust=5: 3: 4: 7: 11: 2: 1: 1 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 5 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 10 ℃/min is warming up to 600 ℃ again, is incubated to turn off power supply after 10 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and mantoquita that the surface is unnecessary and silver salt and washes off and promptly get copper silver ion and spread yellowish brown mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 0.8%, 2.5% gelatine, 0.7% hide glue and 96% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 45%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.1mm, glass gob is placed 22 ℃ then, humidity is in 25% the environment, to place 8 hours; Temperature is risen to 35 ℃ again, humidity is 10%, is incubated 5 hours, temperature is risen to 45 ℃ again, humidity is 2%, is incubated 3 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
Embodiment 6, the first step: the preparation of mat glass: at first, select flawless (line), immaculate transparent dressing product vial except that toughened glass as glass gob; Select for use a surface of 110 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 2 rev/mins, and the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 220 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
4(FeSO
47H
2O), stir in the compound of coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 250 mesh sieves after 4 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
4(FeSO
47H
2O): water: glycerine: dextrin: coal dust=1: 10: 4: 6: 8: 1: 2: 2 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 4 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 6 ℃/min is warming up to 560 ℃ again, is incubated to turn off power supply after 30 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and the mantoquita that the surface is unnecessary and washes off and promptly get mantoquita and silver salt and wash off and promptly get copper silver ion and spread brown mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 0.7%, 3.5% gelatine, 0.8% hide glue and 95% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 36%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.5mm, glass gob is placed 21 ℃ then, humidity is in 27% the environment, to place 24 hours; Temperature is risen to 31 ℃ again, humidity is 10%, is incubated 9 hours, temperature is risen to 60 ℃ again, humidity is 4%, is incubated 5 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
The present invention utilizes ion diffusion colored glass to prepare colored ice-patterned glass, has remedied the shortcoming of ice glass color dullness, has increased the visual effect and the decorative effect of ice glass.In addition, the ice glass of the present invention preparation can also carry out reprocessing such as hot bending, and adapting to the demand of varying environment, and the hot bending process can not exert an influence to goods color and frost flower.The colored ice-patterned glass color of the present invention preparation is various, be rich in true and natural painted and visual effect, and easy to operate, and energy consumption is low, and save energy is suitable for producing good decorating effect, added value of product height in enormous quantities.
Claims (2)
1. the preparation method of a colored ice-patterned glass is characterized in that:
The first step: the preparation of mat glass: at first, select flawless, immaculate glass except that toughened glass as glass gob; Select for use a surface of 100～150 purpose diamond sand to carry out wet-milling then, the gait of march of glass gob is controlled at 0.5 meter/minute or 0.1～2 rev/min, the rotating speed that the frosted dish of silicon carbide is installed is controlled to be 200～250 rev/mins, makes a surface of glass gob form uneven surface; At last the glass gob after the frosted is cleaned, obtain mat glass after the oven dry;
Second step: the preparation of ion diffusion mat glass: preparation ion diffusion slurry, water, glycerine, dextrin are put into beaker and mixed, then it is joined AgNO
3, CuCl, SnO, FeSO
47H
2Stir in the compound of O coal dust, after waiting to stir, this slurry being poured in the ball grinder into ball milling, to cross 200～300 mesh sieves after 2～5 hours stand-by again; AgNO wherein
3: CuCl: SnO: FeSO
47H
2O: water: glycerine: dextrin: coal dust=0～5: 3～15: 3～5: 5～8: 8～15: 1～5: 1～2: 0～2 mass ratio, and then the slurry that makes evenly spread upon on the frosting of the mat glass that has prepared, smearing thickness is controlled at the 0.1-30 micron, treat to go in the retort furnace after the slurry seasoning, speed with 3～5 ℃/min is raised to 400 ℃ from room temperature, is incubated 30 minutes; Speed with 5～10 ℃/min is warming up to 500～600 ℃ again, is incubated to turn off power supply after 5～30 minutes, and it is cooled to below 50 ℃ with furnace temperature, takes out glass and mantoquita that the surface is unnecessary or silver salt and washes off and promptly get ion diffusion mat glass;
The 3rd step: the preparation of colored ice-patterned glass: the reuse glue of the gelatin of mass percent 0～3.5%, 2～4% gelatine, 0.5～1% hide glue and 94～97.5% is mixed the back add in 90 ℃ the hot water, stirring becomes glue, the mass concentration of control glue is 35～45%, it is in 90 ℃ pond or the groove 1～2 hour that the container that will fill glue again is put in water temperature, stand-by; Then, be 25 ℃ in temperature, glue is uniformly coated on painted of ion diffusion mat glass, coating thickness is 0.1～0.5mm, glass gob is placed 20～25 ℃ then, humidity is in 20～30% the environment, to place 8～24 hours; Temperature is risen to 28～35 ℃ again, humidity is 10%, be incubated 5～10 hours, temperature is risen to 45～60 ℃ again, humidity is 0～5%, is incubated 3～5 hours, this process mesogloea gradually explosion come off, after treating that glue-line comes off totally, promptly obtain colored ice-patterned glass, the film that comes off is as the reuse glue reuse.
2. the preparation method of colored ice-patterned glass according to claim 1, it is characterized in that: said glass gob is sheet glass or container glass.
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| CN103317796B (en) * | 2013-05-31 | 2015-02-25 | 陕西科技大学 | Preparation method of thermal insulation composite material |
| CN105314881A (en) * | 2014-06-04 | 2016-02-10 | 刘从荡 | Artistic glue-etched glass making technology |
| US9809493B2 (en) * | 2015-04-27 | 2017-11-07 | Ford Global Technologies, Llc | Surface treatment of glass bubbles |
| CN105601127B (en) * | 2015-12-29 | 2017-11-07 | 陕西科技大学 | A kind of color method of devitrified glass |
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| CN1277163A (en) * | 1999-06-10 | 2000-12-20 | 姚长领 | Making process of glass work with frostwork |
| CN1528693A (en) * | 2003-10-04 | 2004-09-15 | 常熟市日月建材有限公司 | Process for treating ice-flower glass |
| CN1559948A (en) * | 2004-03-10 | 2005-01-05 | 关兴杰 | Method for producing decorating tile of glass with ice flowers pattern |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1277163A (en) * | 1999-06-10 | 2000-12-20 | 姚长领 | Making process of glass work with frostwork |
| CN1528693A (en) * | 2003-10-04 | 2004-09-15 | 常熟市日月建材有限公司 | Process for treating ice-flower glass |
| CN1559948A (en) * | 2004-03-10 | 2005-01-05 | 关兴杰 | Method for producing decorating tile of glass with ice flowers pattern |
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| CN101560065A (en) | 2009-10-21 |
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