CN105461235A - Double-sided colored glaze glass processing method and glaze thereof - Google Patents
Double-sided colored glaze glass processing method and glaze thereof Download PDFInfo
- Publication number
- CN105461235A CN105461235A CN201510929136.5A CN201510929136A CN105461235A CN 105461235 A CN105461235 A CN 105461235A CN 201510929136 A CN201510929136 A CN 201510929136A CN 105461235 A CN105461235 A CN 105461235A
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- glaze
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- layer glaze
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention creates and provides a double-sided colored glaze glass processing method. The method includes the steps of printing a preset pattern on a glass surface with half-molten block glaze as the first layer of glaze through the silk-screen printing process, fully coating the second layer of glaze, without molten blocks, on the glass surface with the first layer of glaze through the silk-screen printing process after the first layer of glaze is dried, conducting tempering or semi-tempering after the second layer of glaze is dried, then washing away the second layer of glaze not attached to the glass surface. By means of the method, the defects of a conventional colored glaze glass processing mode and the limitation of color monotony can be broken, and the effect of the double-sided colored glaze pattern of the large-area single glass is achieved.
Description
Technical field
The invention belongs to glass post-processing preparing technical field, is specifically related to a kind of glass and the working method thereof with Double-glazed colored pattern effect, provides a kind of glaze being applicable to this Double-glazed colored pattern effect glass processing simultaneously.
Background technology
Colored glazed glass is by inorganic glaze, is printed onto glass surface, then drying, tempering or thermalization processing treatment, glaze is forever sintered in glass surface and obtains a kind of wear-resisting, the decorative glasses product of acid and alkali-resistance.This product has very high functional and ornamental.It has many distinct colors and decorative pattern, building field is widely used on indoor decoration and decoration door to colored glazed glass in the market, its basic structure is on glass-base, stamp one deck or multilayer colored glaze, but bright in luster by the glazed colour layer face glass after compound, good decoration function can be played, but traditional colored glazed glass only has one side to have color, from one side, beautiful appearance, be shading from another side, pattern is intensely dark.
Having some in prior art makes glass obtain the working method of double-side pattern.A kind of is by carrying out colored glaze on the glass of aluminizing, recycling dealumination agent will directly not washed off by the aluminium lamination that colored glaze covers, to obtain one side be minute surface one side is the dichroic glass of colored glaze, as patent CN104985972A, but the aluminium lamination of this scheme one side can only be silver color minute surface, color is more single, and due to aluminium lamination stone flour costliness, is caused cost increase considerably by the aluminium lamination directly washed off; Another kind is by interlayer again after two panels glass colored glaze, realizes glass tow sides color all attractive in appearance, as patent CN202319150U, but this kind of method only can as double-layer interlayer glass, glass is from great, and production cost is high, and is not suitable for the compound use with other glass.
Summary of the invention
The invention, for solving the problems of the prior art, provides a kind of Double-glazed colored glass and working method thereof, colored glazed glass processing mode defect of can breaking the normal procedure and the single restriction of color, obtains the effect of big area monolithic glass Double-glazed colored pattern.
A kind of Double-glazed colored glass processing method that the invention provides, comprise the steps: to adopt silk-screen printing technique, half fritted glaze is printed in glass surface as the first layer glaze according to predetermined pattern, after described the first layer glaze is dried, again adopt silk-screen printing technique full figure second layer glaze not containing frit on the above-mentioned glass surface being coated with the first layer glaze, after described second layer glaze is dried, carry out tempering or half tempered process, then wash away not bonding with glass surface second layer glaze.Wherein, in tempering or half tempered process, frit in described the first layer glaze will be softened to thawing, by bonding with glass surface for described the first layer glaze, second layer glaze is carried out bonding with the first layer glaze simultaneously, after tempering or half tempered process complete, then there is not adhesive effect in the part that described second layer glaze directly contacts with glass surface, can be washed away easily, thus obtain the double-deck colored glaze effect of predetermined pattern on the glass surface, observe from glass two sides, the pattern effect of different colored glaze can be obtained.
Wherein, described half fritted glaze refers to the fritted glaze of frit content below 95%, frit in half fritted glaze is clear frit, described the first layer glaze can adopt half generally commercially available fritted glaze, the softening temperature of frit is preferably 570-630 DEG C, and the granularity of described the first layer glaze is preferably more than 300 orders.
Further, for ensureing the printing effect of silk screen printing and good adhesive effect, in described the first layer glaze, the content of frit is 60%-80%.If frit content is too low, then may cause stability bonding between two-layer glaze, easily cause the partial exfoliation of second layer glaze in cleaning process, if frit too high levels, the sharpness of screen printed pattern will be affected on the one hand, on the other hand, pattern edge may be caused unintelligible due to too much glaze melting in toughening process.
Wherein, for ensureing the stable of colored glaze pattern and adhesive effect, the print thickness of described the first layer glaze is preferably 5-30 μm, and the print thickness that described second layer glaze is positioned at the upper part of described the first layer glaze is preferably 10-40 μm.
Wherein, the temperature of described tempering or half tempered process is 670-730 DEG C.
Further, after described the first layer glaze is dried, the process of the glass being coated with described the first layer glaze being carried out half tempered can also be comprised, and then carry out the operation of second layer glaze coating, the disadvantageous effect that may cause the integrity of the first layer glaze in the process of printing second layer glaze can be avoided like this.
The invention additionally provides a kind of special glaze being applicable to second layer printing in aforesaid method, by weight, comprising: turps 10-50 part, Terpineol 350 10-50 part, ethyl cellulose 3-10 part, pigment 5-20 part.
Preferably, described turps and Terpineol 350 account for 90% ± 3% of glaze gross weight, and described ethyl cellulose accounts for 3% ± 1% of glaze gross weight.
Preferably, described turps and Terpineol 350 weight ratio is therebetween 1:(1 ± 0.2).
Wherein, described pigment can be selected according to color demand, and as black in ferromanganese, selenium ruby, cadmium red, iron oxide red, chrome green, cobalt blue, cadmium selenium Huang, titanium white etc., preferred largest particle controls more than 300 orders.
A kind of Double-glazed colored glass that the invention provides has following structure: on the glass surface, has the first glazed colour layer of specific pattern, is coated with the second glazed colour layer in described first glazed colour layer periphery.
Wherein, the thickness of described first glazed colour layer is 5-30 μm, and the thickness of described second glazed colour layer is 10-40 μm.Frit is passed through bonding between described glass surface and the first glazed colour layer and between the first glazed colour layer and the second glazed colour layer.
The beneficial effect of the invention is: (1) breaks the normal procedure colored glazed glass processing mode defect and the single restriction of color, and can obtain the effect of big area monolithic glass Double-glazed colored pattern, the pattern of Double-glazed colored and color effects are controlled flexibly; (2) without the need to carrying out the process such as plated film (as aluminium lamination) in advance to glass surface, conventional screen printing technique is adopted to realize, simple to operate, cost-saving; (3) second glazed colour layers adopt special glaze, both can realize the stable adhesion between two glazed colour layers, are simultaneously that bonding part is convenient to wash at itself and glass surface, Easy dosing and with low cost; (4) realize the stable adhesion of two-layer glaze in tempering or half tempered process simultaneously, realize Double-glazed colored effect, while saving operation, improve the safety performance of glass.
Accompanying drawing explanation
Fig. 1 is the structural representation after the first glazed colour layer printing;
Fig. 2 is the structural representation after the second glazed colour layer printing;
Fig. 3 is a kind of structural representation of the invention Double-glazed colored glass.
Wherein, 1-glass; 2-first glazed colour layer; 3-second glazed colour layer.
Embodiment
Below by being further described the invention by reference to the accompanying drawings.The concrete scheme described in the following examples is only the content in order to the invention is described, and is not used in the restriction to the invention.For sake of convenience, eliminate the process prescription that other are non-essential or conventional in describing the embodiments of the present, as the selection etc. chosen, print speed, angle of printing net in the cleaning process to glass surface, screen printing process, these conditions are considered to those skilled in the art and easily debug and know.
Cover 90 ° of white dark circles dot patterns of arrangement for 30% and carry out embodiment explanation.
Cleaning glass surface and after drying, adopt silk-screen printing technique, half fritted glaze is printed in glass surface (Fig. 1) as the first layer glaze according to predetermined pattern, and print thickness is 5-30 μm.In described the first layer glaze, the content of frit is 60%-80%, and the softening temperature of frit is 570-630 DEG C, and granularity is preferably more than 300 orders, can adopt half generally commercially available fritted glaze, as white 9001 glaze that Shandong Zibo Fu Lu novel material company limited produces.Suitable frit content and granularity can ensure the printing effect of silk screen printing and good adhesive effect, if frit content is too low, then may cause stability bonding between two-layer glaze, easily cause the partial exfoliation of second layer glaze in cleaning process, if frit too high levels, to the sharpness of screen printed pattern be affected on the one hand, and on the other hand, pattern edge may be caused unintelligible due to too much glaze melting in toughening process.
After described the first layer glaze is dried at 100-200 DEG C, glass can be carried out half tempered process at 670-730 DEG C, or do not carry out half tempered process, directly again adopt silk-screen printing technique full figure second layer glaze (Fig. 2) not containing frit on the above-mentioned glass surface being coated with the first layer glaze, the print thickness that described second layer glaze is positioned at the upper part of described the first layer glaze is 10-40 μm.
Described second layer glaze preferably adopts the special glaze of following formula: by weight, comprising: turps 10-50 part, Terpineol 350 10-50 part, ethyl cellulose 3-10 part, pigment 5-20 part.Preferably, described turps and Terpineol 350 account for 90% ± 3% of glaze gross weight, and described ethyl cellulose accounts for 3% ± 1% of glaze gross weight.Also preferred, described turps and Terpineol 350 weight ratio is therebetween 1:(1 ± 0.2).Wherein, described pigment can be selected according to color demand, and as black in ferromanganese, selenium ruby, cadmium red, iron oxide red, chrome green, cobalt blue, cadmium selenium Huang, titanium white etc., preferred largest particle controls more than 300 orders.Exemplary second layer glaze formula is as follows: 45 parts, turps, Terpineol 350 45 parts, ethyl cellulose 3 parts, black 7 parts of ferromanganese.
After drying at described second layer glaze 100-200 DEG C, glass is carried out tempering or half tempered process at 670-730 DEG C, then washes away not bonding with glass surface second layer glaze, the glass of Double-glazed colored effect can be had as shown in Figure 3.
As the contrast of this case, the commercially available common glaze not containing frit is adopted by second layer glaze to carry out the preparation of Double-glazed colored glass, adopt with the identical preparation process of said process, the Double-glazed colored glass pattern marginal sharpness obtained reduces, and the pattern of second layer glaze exists partial exfoliation phenomenon, simultaneously after tempering or half tempered, in the process that second layer glaze is cleaned, part glaze not easily cleans up, and needs local special disposal just can reach cleaning performance thoroughly.
The foregoing is only the preferred embodiment of the invention; not in order to limit the invention; within all spirit in the invention and principle, any amendment done, equivalent replacement, improvement etc., within the protection domain that all should be included in the invention.
Claims (10)
1. a Double-glazed colored glass processing method, comprise the steps: to adopt silk-screen printing technique, half fritted glaze is printed in glass surface as the first layer glaze according to predetermined pattern, after described the first layer glaze is dried, again adopt silk-screen printing technique full figure second layer glaze not containing frit on the above-mentioned glass surface being coated with the first layer glaze, after described second layer glaze is dried, carry out tempering or half tempered process, then wash away not bonding with glass surface second layer glaze.
2. a kind of Double-glazed colored glass processing method according to claim 1, it is characterized in that, in described the first layer glaze, frit is clear frit, and softening temperature is preferably 570-630 DEG C.
3. a kind of Double-glazed colored glass processing method according to claim 1, it is characterized in that, the granularity of described the first layer glaze is preferably more than 300 orders.
4. a kind of Double-glazed colored glass processing method according to claim 1, it is characterized in that, in described the first layer glaze, the content of frit is 60%-80%.
5. a kind of Double-glazed colored glass processing method according to claim 1, is characterized in that, the print thickness of described the first layer glaze is 5-30 μm, and the print thickness that described second layer glaze is positioned at the upper part of described the first layer glaze is 10-40 μm.
6. a kind of Double-glazed colored glass processing method according to claim 1, it is characterized in that, described the first layer glaze can also comprise the process of the glass being coated with described the first layer glaze being carried out half tempered, and then carry out the operation of second layer glaze coating after drying.
7. a kind of Double-glazed colored glass processing method according to claim 1 or 6, is characterized in that, the temperature of described tempering or half tempered process is 670-730 DEG C.
8. a kind of Double-glazed colored glass processing method according to claim 1, it is characterized in that, described second layer glaze, by weight, comprising: turps 10-50 part, Terpineol 350 10-50 part, ethyl cellulose 3-10 part, pigment 5-20 part.
9. a kind of Double-glazed colored glass processing method according to claim 8, it is characterized in that, described turps and Terpineol 350 account for 90% ± 3% of glaze gross weight, and described ethyl cellulose accounts for 3% ± 1% of glaze gross weight.
10. a kind of Double-glazed colored glass processing method according to claim 8, it is characterized in that, described turps and Terpineol 350 weight ratio is therebetween 1:(1 ± 0.2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510929136.5A CN105461235A (en) | 2015-12-11 | 2015-12-11 | Double-sided colored glaze glass processing method and glaze thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510929136.5A CN105461235A (en) | 2015-12-11 | 2015-12-11 | Double-sided colored glaze glass processing method and glaze thereof |
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| CN105461235A true CN105461235A (en) | 2016-04-06 |
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| CN201510929136.5A Pending CN105461235A (en) | 2015-12-11 | 2015-12-11 | Double-sided colored glaze glass processing method and glaze thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106830697A (en) * | 2017-03-09 | 2017-06-13 | 曾志明 | A kind of method for preparing safety glass |
| CN108249778A (en) * | 2018-02-07 | 2018-07-06 | 中建八局装饰工程有限公司 | A kind of double chromatography colored glazed glass production methods |
| CN110386763A (en) * | 2018-04-23 | 2019-10-29 | 焦作飞鸿安全玻璃有限公司 | A kind of processing method of printed on both sides tempered glass |
| CN112225466A (en) * | 2020-09-04 | 2021-01-15 | 天津耀皮工程玻璃有限公司 | Screen printing 1.5mm circular point same-surface double-color curved toughened glass and manufacturing process thereof |
| CN113213773A (en) * | 2021-04-22 | 2021-08-06 | 浙江欣昱科技有限公司 | Multi-layer internal spraying forming method for glaze in cosmetic glass bottle and glass bottle thereof |
| CN114605087A (en) * | 2022-03-21 | 2022-06-10 | 杭州杰奇玻璃材料有限公司 | Processing method for manufacturing soft-vision energy-saving glass by adopting glaze printing technology |
| CN116102265A (en) * | 2021-11-09 | 2023-05-12 | 南京伟胜天成玻璃有限公司 | Method for manufacturing colored glaze glass |
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| CN1733640A (en) * | 2005-07-22 | 2006-02-15 | 上海耀华皮尔金顿玻璃股份有限公司 | Glazed glass possessing solid and active pattern and its production process |
| CN103641325A (en) * | 2013-11-27 | 2014-03-19 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Vacuum glass preparation technology |
| CN104046121A (en) * | 2014-07-04 | 2014-09-17 | 繁昌县朱氏印务有限责任公司 | Tempered glass ink formula |
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2015
- 2015-12-11 CN CN201510929136.5A patent/CN105461235A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1733640A (en) * | 2005-07-22 | 2006-02-15 | 上海耀华皮尔金顿玻璃股份有限公司 | Glazed glass possessing solid and active pattern and its production process |
| CN103641325A (en) * | 2013-11-27 | 2014-03-19 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Vacuum glass preparation technology |
| CN104046121A (en) * | 2014-07-04 | 2014-09-17 | 繁昌县朱氏印务有限责任公司 | Tempered glass ink formula |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106830697A (en) * | 2017-03-09 | 2017-06-13 | 曾志明 | A kind of method for preparing safety glass |
| CN108249778A (en) * | 2018-02-07 | 2018-07-06 | 中建八局装饰工程有限公司 | A kind of double chromatography colored glazed glass production methods |
| CN110386763A (en) * | 2018-04-23 | 2019-10-29 | 焦作飞鸿安全玻璃有限公司 | A kind of processing method of printed on both sides tempered glass |
| CN110386763B (en) * | 2018-04-23 | 2022-05-24 | 焦作飞鸿安全玻璃有限公司 | Processing method of double-sided printing toughened glass |
| CN112225466A (en) * | 2020-09-04 | 2021-01-15 | 天津耀皮工程玻璃有限公司 | Screen printing 1.5mm circular point same-surface double-color curved toughened glass and manufacturing process thereof |
| CN113213773A (en) * | 2021-04-22 | 2021-08-06 | 浙江欣昱科技有限公司 | Multi-layer internal spraying forming method for glaze in cosmetic glass bottle and glass bottle thereof |
| CN113213773B (en) * | 2021-04-22 | 2022-03-25 | 浙江欣昱科技有限公司 | Multi-layer internal spraying forming method for glaze in cosmetic glass bottle and glass bottle thereof |
| CN116102265A (en) * | 2021-11-09 | 2023-05-12 | 南京伟胜天成玻璃有限公司 | Method for manufacturing colored glaze glass |
| CN114605087A (en) * | 2022-03-21 | 2022-06-10 | 杭州杰奇玻璃材料有限公司 | Processing method for manufacturing soft-vision energy-saving glass by adopting glaze printing technology |
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