CN101555374B - Aluminum boat antifouling paint - Google Patents
Aluminum boat antifouling paint Download PDFInfo
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- CN101555374B CN101555374B CN2008100896292A CN200810089629A CN101555374B CN 101555374 B CN101555374 B CN 101555374B CN 2008100896292 A CN2008100896292 A CN 2008100896292A CN 200810089629 A CN200810089629 A CN 200810089629A CN 101555374 B CN101555374 B CN 101555374B
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- weight parts
- antifouling
- paint
- antifouling paint
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- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 46
- 239000003973 paint Substances 0.000 title claims abstract description 33
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims abstract description 11
- 230000007613 environmental effect Effects 0.000 claims abstract description 8
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 20
- 238000000576 coating method Methods 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000011717 all-trans-retinol Substances 0.000 claims description 10
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 10
- 239000004411 aluminium Substances 0.000 claims description 9
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 claims description 9
- 239000002966 varnish Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 6
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- FHCZILHPOKONMM-RGMNGODLSA-N [Zn].C(CC)N[C@@H](CCO)C(=O)O Chemical compound [Zn].C(CC)N[C@@H](CCO)C(=O)O FHCZILHPOKONMM-RGMNGODLSA-N 0.000 claims description 5
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 229940043810 zinc pyrithione Drugs 0.000 claims description 5
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 231100000614 poison Toxicity 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 6
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000945 filler Substances 0.000 abstract description 4
- 239000000446 fuel Substances 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract 1
- 229940112669 cuprous oxide Drugs 0.000 abstract 1
- 230000007096 poisonous effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 239000002574 poison Substances 0.000 description 6
- -1 vinylformic acid silica alkane Chemical class 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- KOBKUSXTVUSJEU-UHFFFAOYSA-N copper;prop-2-enoic acid Chemical compound [Cu].OC(=O)C=C KOBKUSXTVUSJEU-UHFFFAOYSA-N 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an aluminum boat antifouling paint relating to a novel ocean antifouling paint which contains a composite antifouling compound system, does not contain cuprous oxide and other internationally prohibited poisonous paint and meets the requirements of national environmental protection. The aluminum boat antifouling paint is characterized by comprising zinc acrylate resin, composite antifouling compound, paint, filling agents, anti-settling agents, solvents, and the like. The aluminum boat antifouling paint can be used as antifouling paint for ocean engineering or boat bottoms, can be applied to the surface of an aluminum basal body, can effectively prevent marine lives from befouling the boat bottom in one to two years, has the property of environmental protection and convenient construction, can prevent the cruising speed of the boat from being influenced, and saves fuel.
Description
Technical field
The present invention relates to a kind of antifouling paint, relate in particular to a kind of aluminium ship ship bottom anti-fouling paint, cuprous and other the international poison material forbidden of oxygen-freeization reach national requirements for environmental protection.
Background technology
The sail in a mighty ocean primary difficult problem that run into of boats and ships is exactly marine life adhering to stained hull bottom.Surplus the marine organisms of now tentatively verifying reach 20 ten thousand kinds, part biological is with the fixed object apposition growth, and the underwater hull bottom is the main base of biological attachment, and marine life adheres to ship's navigation and brought very big harm.Up to 20 kilograms, they increase the hull bottom roughness to China Nanhai area marine organisms at growth busy season every square metre of adhesion amount, reduce the speed of a ship or plane, increase fuel oil consumption.According to statistics, the fuel cost flower that half is arranged every year was the deceleration that causes was lost efficacy in compensation owing to antifouling varnish on, and ten thousand tons of ocean-going freighters of a bow if hull bottom adheres to the stained of 10% area, can bring 1,000,000 dollars loss.And, antifouling paint antirust for recoat also will spend a large amount of depressed places that accounts for and take and remuneration.Therefore, develop efficient antifouling paint, be the most important problem of marine finish research field always.
Antifouling varnish is a kind of special coating, it progressively is discharged into low-down speed by the activeconstituents (toxic agent) that will be comprised and suppresses in the seawater and stop marine life adhering to and grow on ocean steel constructions such as boats and ships, thereby the smooth and coating of maintenance hull outside surface is intact, under the prerequisite that guarantees the normal speed of a ship or plane, reduce oil consumption to greatest extent and prolong the work-ing life of coating, reduce unnecessary expenditures for maintenance.
Matrix used material mainly is steel ship and wooden boat before the antifouling varnish, and along with the development of shipbuilding industry, aluminium matter ship engenders, requires can not contain Red copper oxide (Cu in the antifouling varnish
2O), can not cause galvanic corrosion, make hull corrosion occur, therefore, the antifouling varnish system proposed new requirement because of oozing out of cupric ion.In addition, boats and ships waterline position, long-term Exposure to Sunlight and alternation of wetting and drying, Red copper oxide (Cu
2O) easy oxygenolysis and lose anti-fouling effect also is not suitable for adding.International Maritime Organizaton also can limit Red copper oxide (Cu in 2012 after banning use of organotin (TBT) and DDT poison material
2O) use, therefore, the cuprous (Cu of development of new oxygen-freeization
2O) antifouling varnish is urgent and necessary.
At present, each big paint company is to be matrix resin with vinylformic acid copper, zinc acrylate resin or vinylformic acid silica alkane, with Red copper oxide (Cu substantially
2O) be main stain control agent.The zinc acrylate resin that this invention is selected for use, consider the universal of antifouling varnish, especially at aluminium matter hull and waterline position, monomer, initiator, solubility promoter etc. have been carried out meticulous selection, and conditions such as temperature of reaction, reaction times, monomer dropping speed are optimized, filter out the best synthesis technique of acrylic resin at last, synthesized required zinc acrylate resin.Compound organic stain control agent that the present invention adopts, by cuprous thiocyanate (CuSCN), Zinc Pyrithione, Seanine211 (4,5-two chloro-2-n-octyls-3-isothiazole copper), zineb Zineb (the two dithio first propylhomoserin zinc of ethylene) forms, can progressively discharge along with the hydrolysis of resin and ooze out, effectively prevent the apposition growth of all kinds of marine lifes.
Therefore, domestic coating variety does not also have the cuprous (Cu of a kind of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison material, has environmental protection characteristic, easy construction, aluminium ship special use antifouling varnish with characteristics of the present invention.As ZL97121813.7 described " non-toxic anti-pollution paint for sea " is to be main resin binder with silicate, and organic stain control agent that is added and kind of the present invention and content are all inequality.ZL98119956.9 described " silicate compound anti-fouling paint " also is to be main resin binder with silicate, adds the antifouling composition identical with the present invention.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental protection characteristic that has, the cuprous (Cu of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison expect the ship bottom anti-fouling paint of aluminium matter matrix surface special use.
The present invention also provides the preparation method of described antifouling paint.
The object of the present invention is achieved like this:
Aluminum boat antifouling paint wherein comprises following composition: prescription by weight is:
(1) zinc acrylate resin: 20～40 weight parts
(2) compound organic stain control agent: 20～30 weight parts
(3) face, filler: talcum powder 2～3 weight parts, zinc oxide 8～12 weight parts
(4) mixed solvent is: dimethylbenzene 10～20 weight parts, N-BUTYL ACETATE 5～10 weight parts
(5) dispersion agent is: methoxyl group ester propyl propionate solution 0.2～0.5 weight part
(6) anti-settling agent: organobentonite 2～4 weight parts
Compound organic stain control agent material described in the present invention is: cuprous thiocyanate (CuSCN) 5～10 weight parts, Zinc Pyrithione 5～10 weight parts, Seanine 211 (4,5-two chloro-2-n-octyls-3-isothiazole copper) 2～5 weight parts, zineb Zineb (the two dithio first propylhomoserin zinc of ethylene) 2～5 weight parts.
The preparation method of the aluminum boat antifouling paint described in the present invention, may further comprise the steps: make zinc acrylate resin all be dissolved in the mixed solvent, fully dissolving, add successively and mix organic stain control agent, dispersion agent, face, filler, anti-settling agent, stir, high speed dispersion, high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
The coating process of the aluminum boat antifouling paint described in the present invention:
General application 3～4 roads, coating thickness need reach 200～300 μ m, the construction of different methods such as available airless spraying, brushing or roller coating.High solid, one build of airless spraying can reach 100 μ m.When film thickness reaches specified requirement, can reach effective anti-fouling effect.
Embodiment
Below the present invention will be described in detail by a specific examples:
Embodiments of the invention one are " 859 aluminum boat antifouling paint ", and prescription by weight is:
(1) zinc acrylate resin: 30 weight parts
(2) compound organic stain control agent: 22 weight parts, cuprous thiocyanate (CuSCN) 10 weight parts wherein, Zinc Pyrithione 5 weight parts, Seanine 211 (4,5-two chloro-2-n-octyls-3-isothiazole copper) 3 weight parts, zineb Zineb (the two dithio first propylhomoserin zinc of ethylene) 4 weight parts
(3) pigment: talcum powder 3 weight parts, zinc oxide 10 weight parts, blue 0.2 weight part of phthalein cyanogen
(4) mixed solvent is: dimethylbenzene 15 weight parts, N-BUTYL ACETATE 5 weight parts
(5) dispersion agent is: methoxyl group ester propyl propionate solution 0.2 gram
(6) anti-settling agent: organobentonite 2 grams
The preparation method is as follows:
Earlier zinc acrylate resin all is dissolved in the mixed solvent, fully dissolving adds compound organic stain control agent, dispersion agent, face, filler, anti-settling agent successively, stirs, high speed dispersion high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
This coating detects result such as table one according to standard GB/T6822-1986 " ship bottom anti-fouling paint general technical specifications "
The key technical indexes of table one, " 859 aluminum boat antifouling paint "
| Test item | Technical indicator | Check data |
| Color and outward appearance | Blue look | Conformance with standard |
| Viscosity (being coated with-4,25 ℃), S | 60-80 | 60 |
| Proportion, g/cm 3 | About 1.72 | 1.72 |
| Fineness, μ m | ≤ 80 | 60 |
| Time of drying, h | Surface drying≤4, do solid work≤24 | Surface drying 4 does solid work 24 |
| Sticking power (drawing the circle method), level | 1-2 | 1 |
| Snappiness, mm | 1 | 1 |
| Shock strength, cm | 〉=40 | 50 |
| Solids content, % | 〉=60 | 62 |
| Theoretical lacquer amount, the Kg/m of using 2. the road | 0.304 | Conformance with standard |
| Standard film thickness, μ m/ road | 〉=80 | 100 |
| Antifouling property | The antifouling phase of 1-2 imitates | Conformance with standard |
| Dynamic antifouling property | 〉=3 cycles | Through 3 periodic tests: 859 universal ship bottom antifouling coating model paint films are intact, do not have bubbles, come off, the surperficial no marine life of model adheres to. |
| Shelf lives, a | 〉=1 | Conformance with standard |
859 aluminum boat antifouling paints of the present invention have following performance characteristics:
1, adopts the cuprous (Cu of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison expect to have environmental protection characteristic.
2, can be used for aluminium matter hull bottom, the protection phase with 1-2 imitates.
3, well attached with the hull bottom coating, have excellent physical and mechanical properties, even the shipping high speed navigation can not come off yet, highest speed can reach 40 joints.
4, paint film keeps smooth surface, can keep ship's speed unaffected, fuel saving.
5, easy construction, the construction of different methods such as available airless spraying, brushing or roller coating.High solid, one build of airless spraying can reach 100 μ m.
6, have good drying property, the four seasons all can use, and can construct under various weather condition.
859 aluminum boat antifouling paints of the present invention have following novelty:
1, adopts compound organic stain control agent system first, its material is: cuprous thiocyanate (CuSCN) 5～10 weight parts, Zinc Pyrithione 5～10 weight parts, Seanine211 (4,5-two chloro-2-n-octyls-3-isothiazole copper) 2～5 weight parts, zineb Zineb (the two dithio first propylhomoserin zinc of ethylene) 2～5 weight parts.Cuprous (the Cu of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison expect to have environmental protection characteristic.
2, adopt the cuprous (Cu of zinc acrylate resin and oxygen-freeization first
2O) system has prevented oozing out of high density cupric ion, has avoided the electrochemical reaction of copper and aluminium matter base material, is specifically designed to aluminium matter hull bottom, and the protection phase with 1-2 imitates.
3, Pei Fang unique design and resin-pigment ratio content make 859 aluminum boat antifouling paints have excellent physical and mechanical properties, even the shipping high speed navigation can not come off yet, highest speed can reach 40 joints.
Claims (3)
1. aluminum boat antifouling paint, its contain compound stain control agent system and oxygen-freeization cuprous, and reach the marine antifouling coating of national requirements for environmental protection, it is characterized in that: prescription comprises following composition:
(1) zinc acrylate resin: 20～40 weight parts
(2) compound organic stain control agent: 20～30 weight parts
(3) color stuffing: talcum powder 2～3 weight parts, zinc oxide 8～12 weight parts
(4) mixed solvent is: dimethylbenzene 10～20 weight parts, N-BUTYL ACETATE 5～10 weight parts
(5) dispersion agent is: 0.2～0.5 weight part
(6) anti-settling agent: organobentonite 2～4 weight parts;
Wherein, compound organic stain control agent is: cuprous thiocyanate 5～10 weight parts, Zinc Pyrithione 5～10 weight parts, Seanine 211 molecule titles 4, two dithio first propylhomoserin zinc 2～5 weight parts of 5-two chloro-2-n-octyls-3-isothiazole copper 2～5 weight parts and zineb Zineb molecule title ethylene; This coating is applicable to that oceanographic engineering or hull bottom position use as antifouling varnish, can be used for aluminium matter matrix surface, can effectively prevent marine life stained to hull bottom in 1-2.
2. preparation method according to the aluminum boat antifouling paint described in the claim 1, may further comprise the steps: make zinc acrylate resin all be dissolved in the mixed solvent, fully dissolving, add compound organic stain control agent, dispersion agent, color stuffing, anti-settling agent successively, stir, high speed dispersion, high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
3. the coating process according to the aluminum boat antifouling paint described in the claim 1 is characterized in that, general application 3～4 roads during such paint spraying, and coating thickness need reach 200～300 μ m, when film thickness reaches specified requirement, can reach effective anti-fouling effect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100896292A CN101555374B (en) | 2008-04-11 | 2008-04-11 | Aluminum boat antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100896292A CN101555374B (en) | 2008-04-11 | 2008-04-11 | Aluminum boat antifouling paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101555374A CN101555374A (en) | 2009-10-14 |
| CN101555374B true CN101555374B (en) | 2011-03-16 |
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ID=41173665
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100896292A Expired - Fee Related CN101555374B (en) | 2008-04-11 | 2008-04-11 | Aluminum boat antifouling paint |
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|---|---|---|---|---|
| CN103013265B (en) * | 2012-12-19 | 2015-09-16 | 浙江飞鲸漆业有限公司 | Aquiculture net cage antifouling paint |
| CN103897092B (en) * | 2014-03-24 | 2017-01-04 | 海洋化工研究院有限公司 | The preparation of acrylic acid zinc-type self polishing copolymer antifouling paint matrix resin and application |
| CN104087102A (en) * | 2014-07-28 | 2014-10-08 | 广西梧州龙鱼漆业有限公司 | Antifouling paint for ships |
| CN104263162B (en) * | 2014-09-19 | 2016-03-30 | 苏州云舒新材料科技有限公司 | A kind of deck in ship structure water resistant coating and preparation method thereof |
| CN104231815A (en) * | 2014-09-30 | 2014-12-24 | 济宁利特纳米技术有限责任公司 | Functionalized antifouling anticorrosive graphene paint as well as preparation method and painting method thereof |
| CN104356817A (en) * | 2014-12-10 | 2015-02-18 | 李永志 | Coating |
| CN104817913B (en) * | 2015-05-15 | 2017-05-17 | 上海海悦涂料有限公司 | Long-acting environment-friendly ship bottom antifouling paint, strippable antifouling paint and ship bottom antifouling treatment method |
| CN105295631A (en) * | 2015-11-18 | 2016-02-03 | 上海大学 | Fluorine-modified zinc acrylate antifouling coating material and preparation method thereof |
| CN107189586A (en) * | 2017-06-29 | 2017-09-22 | 顾渊 | A kind of anti-fouling paint of long antifouling life |
| CN107779020A (en) * | 2017-10-30 | 2018-03-09 | 海南科维功能材料有限公司 | A kind of environmentally friendly fishing net is without copper protective rubber, protective coating and its dip-coating method |
| CN110724424B (en) * | 2019-10-14 | 2022-03-25 | 浙江海洋大学 | Antifouling coating for marine mesh wire and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1218820A (en) * | 1997-11-28 | 1999-06-09 | 化学工业部海洋化工研究院 | Non-toxic anti-pollution paint for sea |
| CN1709925A (en) * | 2005-04-18 | 2005-12-21 | 中国海洋大学 | Resin of zinc acrylate or copper acrylate containing capsaicin function group, its preparation and use |
-
2008
- 2008-04-11 CN CN2008100896292A patent/CN101555374B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1218820A (en) * | 1997-11-28 | 1999-06-09 | 化学工业部海洋化工研究院 | Non-toxic anti-pollution paint for sea |
| CN1709925A (en) * | 2005-04-18 | 2005-12-21 | 中国海洋大学 | Resin of zinc acrylate or copper acrylate containing capsaicin function group, its preparation and use |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101555374A (en) | 2009-10-14 |
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