CN107189586A - A kind of anti-fouling paint of long antifouling life - Google Patents
A kind of anti-fouling paint of long antifouling life Download PDFInfo
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- CN107189586A CN107189586A CN201710513816.8A CN201710513816A CN107189586A CN 107189586 A CN107189586 A CN 107189586A CN 201710513816 A CN201710513816 A CN 201710513816A CN 107189586 A CN107189586 A CN 107189586A
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- fouling paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-fouling paint, present invention paint is prepared from by the raw material of following parts by weight：30~40 parts of acrylic emulsion, 10~20 parts of polyacrylic acid zinc resin is fluorinated 0.5~1 part of multi-walled carbon nanotube, 5~10 parts of dispersions of polyurethanes, 1~3 part of silane coupler, 0.2~2 part of anti-fouling agent, 5~8 parts of titanium dioxide, 1~5 part of hydroquinones, 1~2 part of accelerator, 0.5~2 part of antioxidant.Anti-fouling paint film of the present invention is smooth, difficult for drop-off, and Corrosion Protection preferably, is applicable not only to ship, significantly, service life had a extensive future anti-fouling effect more than 5 years.
Description
Technical field
The present invention relates to technical field of chemical paint, especially a kind of anti-fouling paint.
Background technology
Marine fouling organism attachment can cause ship resistance increase, pipeline obstruction, heat transmission equipment thermal conductivity reduce and
The problems such as aquaculture catch is reduced, produces and seriously endangers and huge economic loss；Marine anti-pollution technology is to be used to prevent
Marine fouling organism is attached to the technology on marine structure surface, and the main anti-pollution measure used at present is application nonpolluting coating,
Including antifouling formulation coating and pollution release type coating.
The principle of antifouling formulation coating is to produce poisoning or inhibitory action to marine fouling organism by discharging anti-fouling agent, from
And prevent that it is stained marine structure surface, a kind of antifouling paint containing triphenyltin disclosed in GB1457590,
A kind of Cu disclosed in CN1015318412The hollow sub-micro balls of O be applied to low-toxicity marine antifouling paint preparation method and
A kind of antifouling paint of ship and marine facility disclosed in CN101805546A is containing anti-fouling agents such as tin, copper, due to organic
Tin, basic copper carbonate etc. are built up in marine environment can have a strong impact on ecological environment, be gradually prohibited from using or limited and use；
Development of new anti-fouling agent is one of important channel of the green anti-soil technology of development, but Eupatorium adenophorum disclosed in CN101525508
Extraction of substance is as oleanolic acid disclosed in the application of anti-fouling paint antifoulant, CN101485321 in marine antifoulant is prepared
Using, and other organic compound anti-fouling agents, such as triphenylboron pyridine alkane, 4,5- dichloro- -2- n-octyl -4- isothiazole
Quinoline -3- ketone and N- cyclopropyl-N '-(1,1- dimethyl ethyl) -6- (methyl thio) -1,3,5-triazines -2,4- diamines, are present
The problem of anti-fouling effect is undesirable is used alone, it is necessary to cuprous oxide with the use of there could be preferable antifouling property, and
It can still cause environmental pollution when the marine sites such as harbour are largely built up.
Pollution release type nonpolluting coating is by designing special surface characteristic, marine fouling organism is difficult on its surface
Adhere to realize antifouling purpose, a kind of low-surface-energy that a kind of room curing silicon rubber disclosed in US4910252 is made is antifouling
In a kind of silicon-fluororesin low surface energy anti-fouling paint disclosed in coating and US6265515, low-surface-energy characteristic can prevent barnacle,
The attachment of the marine growths such as mussel, but little is acted on to marine growths such as diatoms, it can further promote other biologies attached after diatom attachment
, cause antifouling paint to fail；A kind of dimension-adjustable porous micro-structured surface antifouling material disclosed in CN102399487A,
A kind of surface disclosed in CN102417792A have the anti-fouling material of cross regular microstructure preparation method and
A kind of preparation method of spherical protuberances micro-structure surface anti-fouling material, passes through the microcosmic of particular design disclosed in CN101691466A
Structure can effectively reduce the attachment site of fouling organism, prevent sea organism attachment, but also exist that service life is shorter can not
The problem of meeting practical application.
Thus, it is necessary to a kind of anti-fouling paint of the antifouling life with good anti-fouling effect and with length is researched and developed, with
Meet the demand of practical application.
The content of the invention
For the above-mentioned problems in the prior art, it is an object of the invention to provide a kind of anti-fouling paint and its preparation side
Method, the anti-fouling paint of especially a kind of long antifouling life and its preparation, to solve the problem of prior art antifouling life is short.
Long antifouling life of the present invention refers to：Antifouling life is more than 5 years.
For up to above-mentioned purpose, the present invention is adopted the following technical scheme that：
The present invention provides a kind of anti-fouling paint, especially a kind of anti-fouling paint of long antifouling life, the anti-fouling paint by
The raw material of following parts by weight is prepared from：
In the present invention, the fluorination multi-walled carbon nanotube can be prepared using method disclosed in prior art, for example
The fluoro-gas that can be produced using polytetrafluoroethylene PTFE high temperature pyrolysis prepares fluorine as fluorization agent and multi-wall carbon nano-tube tube reaction
Multi-walled carbon nano-tube.
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of acrylic emulsion for 30 parts~40 parts, for example, 30
Part, 32 parts, 34 parts, 35 parts, 36 parts, 38 parts or 40 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of polyacrylic acid zinc resin are 10 parts~20 parts, for example
For 10 parts, 11 parts, 12 parts, 14 parts, 15 parts, 17 parts or 20 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of fluorination multi-walled carbon nanotube are 0.5~1 part, for example
For 0.5 part, 0.6 part, 0.7 part, 0.75 part, 0.8 part, 0.9 part or 1 part etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of dispersions of polyurethanes for 5 parts~10 parts, for example, 5
Part, 6 parts, 7 parts, 8 parts or 10 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of silane coupler are 1 part~3 parts, for example, 1 part,
1.5 parts, 2 parts or 3 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of anti-fouling agent are 0.2~2 part, for example, 0.2 part,
0.4 part, 0.5 part, 1 part, 1.5 parts or 2 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of titanium dioxide are 5 parts~8 parts, for example, 5 parts, 6 parts,
6.5 parts, 7 parts or 8 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of hydroquinones are 1 part~5 parts, for example, 1 part, 2
Part, 3 parts, 3.5 parts, 4 parts or 5 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of accelerator are 1 part~2 parts, for example, 1 part, 1.5
Part or 2 parts etc..
In the present invention, in the raw material of the anti-fouling paint, the parts by weight of antioxidant for 0.5 part~2 parts, for example, 0.5
Part, 1 part, 1.5 parts, 1.8 parts or 2 parts etc..
As the optimal technical scheme of anti-fouling paint of the present invention, the anti-fouling paint by following parts by weight raw material
It is prepared from：
As the further preferred technical scheme of anti-fouling paint of the present invention, the anti-fouling paint is by following parts by weight
Raw material be prepared from：
Preferably, the mass ratio of the acrylic emulsion and fluorination multi-walled carbon nanotube is 70:1.
Preferably, the mass ratio of the polyacrylic acid zinc resin and fluorination multi-walled carbon nanotube is 35:1.
Preferably, the anti-fouling agent is sodium methyl silicate.
Preferably, the accelerator is cobalt iso-octoate or zinc Isoocatanoate.
Preferably, the antioxidant is three monooctyl esters or three last of the ten Heavenly stems esters.
Compared with the prior art, the present invention has the advantages that：
1st, the present invention is by adding the fluorination multi-walled carbon nanotube of appropriate level, and adds polyacrylic acid zinc resin and propylene
Yogurt liquid and dispersions of polyurethanes etc. are used cooperatively, and can cooperate with improves the antifouling life of anti-fouling paint, has prepared a kind of production
The anti-fouling paint of antifouling life, the service life of anti-fouling paint of the invention is more than 5 years, and good antifouling effect, application prospect
It is wide.
2nd, anti-fouling paint film of the present invention is smooth, difficult for drop-off, and Corrosion Protection is good.
Embodiment
Technical scheme is further illustrated below by embodiment.
Embodiment 1
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following parts by weight：
Embodiment 2
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following parts by weight：
Embodiment 3
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following parts by weight：
Embodiment 4
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following parts by weight：
Embodiment 5
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following mass fraction：
Embodiment 6
The present embodiment provides a kind of anti-fouling paint, and the anti-fouling paint is prepared from by the raw material of following mass fraction：
Comparative example 1
In addition to without fluorination multi-walled carbon nanotube, other each raw material components and addition are same as Example 1.
Comparative example 2
In addition to the acrylic emulsion by polyacrylic acid zinc resin replacement for equivalent, other each raw material components and addition and reality
Apply example 1 identical.
By the paint of embodiment 1~6 and comparative example 1~2 on glued board, then it is dipped in seawater, inspects periodically
The contaminated degree of glued board, if not polluting completely, 0 is recorded as by pollution level, if being contaminated completely, will pollute journey
Degree is recorded as 100, and testing result is shown in Table 1：
Table 1
By table 1, the service life of anti-fouling paint of the invention is more than 5 years.
Applicant states that the present invention illustrates the method detailed of the present invention, but not office of the invention by above-described embodiment
It is limited to above-mentioned method detailed, that is, does not mean that the present invention has to rely on above-mentioned method detailed and could implemented.Art
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention
Addition, selection of concrete mode etc., within the scope of all falling within protection scope of the present invention and being open.
Claims (8)
1. a kind of anti-fouling paint, it is characterised in that the anti-fouling paint is prepared from by the raw material of following parts by weight：
2. anti-fouling paint according to claim 1, it is characterised in that the anti-fouling paint by following parts by weight raw material
It is prepared from：
3. anti-fouling paint according to claim 1 or 2, it is characterised in that the anti-fouling paint is by following parts by weight
Raw material is prepared from：
4. the anti-fouling paint according to claim any one of 1-3, it is characterised in that the acrylic emulsion and many walls of fluorination
The mass ratio of CNT is 70:1.
5. the anti-fouling paint according to claim any one of 1-4, it is characterised in that the polyacrylic acid zinc resin and fluorination
The mass ratio of multi-walled carbon nanotube is 35:1.
6. the anti-fouling paint according to claim any one of 1-5, it is characterised in that the anti-fouling agent is sodium methyl silicate.
7. the anti-fouling paint according to claim any one of 1-6, it is characterised in that the accelerator be cobalt iso-octoate or
Zinc Isoocatanoate.
8. the anti-fouling paint according to claim any one of 1-7, it is characterised in that the antioxidant be three monooctyl esters or
Three last of the ten Heavenly stems esters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710513816.8A CN107189586A (en) | 2017-06-29 | 2017-06-29 | A kind of anti-fouling paint of long antifouling life |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710513816.8A CN107189586A (en) | 2017-06-29 | 2017-06-29 | A kind of anti-fouling paint of long antifouling life |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189586A true CN107189586A (en) | 2017-09-22 |
Family
ID=59880693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710513816.8A Pending CN107189586A (en) | 2017-06-29 | 2017-06-29 | A kind of anti-fouling paint of long antifouling life |
Country Status (1)
| Country | Link |
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| CN (1) | CN107189586A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109036871A (en) * | 2018-09-03 | 2018-12-18 | 河南克莱威纳米碳材料有限公司 | A kind of lithium-ion capacitor negative electrode material and preparation method thereof and a kind of lithium-ion capacitor |
| WO2019113717A1 (en) * | 2017-12-13 | 2019-06-20 | Universidad Técnica Federico Santa María | Nanostructured paint for reducing microbial corrosion |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616560A (en) * | 2004-10-12 | 2005-05-18 | 朱松年 | Environment protection anti-foulant material and anti-fouling paint |
| CN101555374A (en) * | 2008-04-11 | 2009-10-14 | 上海海悦涂料有限公司 | Aluminum boat antifouling paint |
| CN105499092A (en) * | 2015-11-30 | 2016-04-20 | 东南大学 | Transparent super-amphiphobic surface layer and layer-by-layer in-situ spraying reaction preparation method |
| CN105602380A (en) * | 2016-03-28 | 2016-05-25 | 中国船舶重工集团公司第七二五研究所 | Antifouling material with directionally arranged acicular filler and preparation method thereof |
| CN105802449A (en) * | 2016-05-01 | 2016-07-27 | 深圳市中科宏业科技有限公司 | Water-based thermal isolation and heat insulation anti-corrosion paint and preparation method thereof |
| CN105925088A (en) * | 2016-05-27 | 2016-09-07 | 广西梧州龙鱼漆业有限公司 | Antifouling paint |
-
2017
- 2017-06-29 CN CN201710513816.8A patent/CN107189586A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616560A (en) * | 2004-10-12 | 2005-05-18 | 朱松年 | Environment protection anti-foulant material and anti-fouling paint |
| CN101555374A (en) * | 2008-04-11 | 2009-10-14 | 上海海悦涂料有限公司 | Aluminum boat antifouling paint |
| CN105499092A (en) * | 2015-11-30 | 2016-04-20 | 东南大学 | Transparent super-amphiphobic surface layer and layer-by-layer in-situ spraying reaction preparation method |
| CN105602380A (en) * | 2016-03-28 | 2016-05-25 | 中国船舶重工集团公司第七二五研究所 | Antifouling material with directionally arranged acicular filler and preparation method thereof |
| CN105802449A (en) * | 2016-05-01 | 2016-07-27 | 深圳市中科宏业科技有限公司 | Water-based thermal isolation and heat insulation anti-corrosion paint and preparation method thereof |
| CN105925088A (en) * | 2016-05-27 | 2016-09-07 | 广西梧州龙鱼漆业有限公司 | Antifouling paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019113717A1 (en) * | 2017-12-13 | 2019-06-20 | Universidad Técnica Federico Santa María | Nanostructured paint for reducing microbial corrosion |
| CN109036871A (en) * | 2018-09-03 | 2018-12-18 | 河南克莱威纳米碳材料有限公司 | A kind of lithium-ion capacitor negative electrode material and preparation method thereof and a kind of lithium-ion capacitor |
| CN109036871B (en) * | 2018-09-03 | 2020-11-17 | 河南克莱威纳米碳材料有限公司 | Lithium ion capacitor negative electrode material, preparation method thereof and lithium ion capacitor |
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Application publication date: 20170922 |