CN101550304B - Environment-friendly marine antifouling coating for finishing boat - Google Patents
Environment-friendly marine antifouling coating for finishing boat Download PDFInfo
- Publication number
- CN101550304B CN101550304B CN200810088860XA CN200810088860A CN101550304B CN 101550304 B CN101550304 B CN 101550304B CN 200810088860X A CN200810088860X A CN 200810088860XA CN 200810088860 A CN200810088860 A CN 200810088860A CN 101550304 B CN101550304 B CN 101550304B
- Authority
- CN
- China
- Prior art keywords
- weight parts
- coating
- antifouling
- antifouling coating
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 49
- 239000011248 coating agent Substances 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 5
- 239000010959 steel Substances 0.000 claims abstract description 5
- 239000003973 paint Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000002966 varnish Substances 0.000 claims description 13
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 8
- 239000012046 mixed solvent Substances 0.000 claims description 8
- 230000007613 environmental effect Effects 0.000 claims description 7
- 238000005507 spraying Methods 0.000 claims description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 6
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 6
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000049 pigment Substances 0.000 abstract description 4
- 239000002519 antifouling agent Substances 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract 1
- 229940112669 cuprous oxide Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- 108700012359 toxins Proteins 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 description 9
- 239000010949 copper Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 7
- 239000002574 poison Substances 0.000 description 7
- 231100000614 poison Toxicity 0.000 description 7
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical group O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000007761 roller coating Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- -1 silicate compound Chemical class 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a boat bottom antifouling coating used in a fishing boat, in particular to a marine antifouling coating containing an antifouling agent system without cuprous oxide and other internationally non-permissible toxins, reaching the national environment-friendly requirements and having about one-year antifouling validity. The marine antifouling coating is characterized by comprising acrylic resin, composite antifouling agents, pigments, fillers, anti-sedimentation agents, solvents, and the like. The coating is suitable to be used at the boat bottom of a steel fishing boat or a wood fishing boat as the antifouling coating, can effectively prevent the boat bottom from fouling by marine organisms within one year, has low price, and is environment-friendly and constructed conveniently.
Description
Technical field
The present invention relates to a kind of antifouling paint, especially refer to a kind of compound stain control agent system that contains, poison material of cuprous and other the international forbiddings of oxygen-freeization, the antifouling phase of the left and right sides is imitated the fishing boat marine antifouling coating one year to reach the tool of national requirements for environmental protection.
Background technology
Antifouling varnish is a kind of special coating, it progressively is discharged into low-down speed by the activeconstituents (toxic agent) that will be comprised and suppresses in the seawater and stop marine life adhering to and grow on ocean steel constructions such as boats and ships, thereby the smooth and coating of maintenance hull outside surface is intact, under the prerequisite that guarantees the normal speed of a ship or plane, reduce oil consumption to greatest extent and prolong the work-ing life of coating, reduce unnecessary expenditures for maintenance.
Used main stain control agent is Red copper oxide (Cu before the fishing boat antifouling varnish
2O), organotin (TBT) and DDT class.Because tributyl tin compound TBT that is added and DDT class poison material content reach 1ppm and can cause the shellfish teratogenesis, organic tin and DDT antifouling varnish have caused significant damage to the marine eco-environment.International Maritime Organizaton (IMO) forbids TBT and DDT using and forbid that boats and ships use TBT and DDT antifouling varnish in antifouling varnish.China's signed " Convention of Stockholm ", requirements of convention is forbidden production and the use of DDT in antifouling varnish, in February, 2006, honour an agreement in Stockholm office and United Nations Development Programme's combination weave of State Environmental Protection Administration held " China is used for the DDT that antifouling varnish produces and substitutes the project initiation meeting ", on country layer, support the enforcement of " Chinese DDT POPs eliminates strategy ", and begin to limit the use of DDT in antifouling varnish in 2006, forbade DDT using and forbid that boats and ships use the DDT antifouling varnish in antifouling varnish in 2008.
International Maritime Organizaton also can limit Red copper oxide (Cu in 2012 after banning use of organotin (TBT) and DDT poison material
2O) use, therefore, the cuprous (Cu of development of new oxygen-freeization
2O) the low-cost antifouling varnish that fishing boat uses that is applicable to has practical significance.
At present, fishing boat is to be matrix resin with vinylformic acid, pitch, chlorinated rubber, silicate with antifouling paint substantially, with Red copper oxide (Cu
2O) be main stain control agent.The vinylformic acid that this invention is selected for use cooperates Gum Rosin, the hydrolysis rate of release of control stain control agent.Compound organic stain control agent that the present invention adopts, by cuprous thiocyanate (CuSCN), copper pyrithione, m-tetrachlorophthalodinitrile is formed, and can progressively discharge along with the hydrolysis of resin to ooze out, and effectively prevents the apposition growth of all kinds of marine lifes.
Therefore, domestic coating variety does not also have the cuprous (Cu of a kind of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison material, have environmental protection characteristic, easy construction, the fishing boat ship bottom anti-fouling paint with characteristics of the present invention, and coating price of the present invention is cheap, can satisfy term effect, has application prospect.As ZL97121813.7 described " non-toxic anti-pollution paint for sea " is to be main resin binder with silicate, and organic stain control agent that is added and kind of the present invention and content are all inequality.ZL98119956.9 described " silicate compound anti-fouling paint " also is to be main resin binder with silicate, adds the antifouling composition identical with the present invention.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental protection characteristic that has, the cuprous (Cu of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison expect, can be used for the antifouling varnish of steel, wooden fishing vessels hull bottom.
The present invention also provides the preparation method of described antifouling paint.
The object of the present invention is achieved like this:
Environment-friendly marine antifouling coating for finishing boat wherein comprises following composition: prescription by weight is:
(1) acrylic resin: 15～20 weight parts;
(2) rosin: 15～20 weight parts;
(3) compound organic stain control agent: 20～30 weight parts;
(4) pigment: talcum powder 2～3 weight parts, zinc oxide 8～12 weight parts, iron oxide red 3～5 weight parts;
(5) mixed solvent is: dimethylbenzene 10～20 weight parts, N-BUTYL ACETATE 5～10 weight parts;
(6) anti-settling agent: organobentonite 2～4 weight parts;
Compound organic stain control agent material described in the present invention is: cuprous thiocyanate (CuSCN) 5～10 weight parts, copper pyrithione 5～10 weight parts, m-tetrachlorophthalodinitrile 5～8 weight parts.
The preparation method of the environment-friendly marine antifouling coating for finishing boat described in the present invention may further comprise the steps:
Acrylic resin and rosin all are dissolved in the mixed solvent, and fully dissolving adds compound organic stain control agent, color stuffing, anti-settling agent successively, stirs, high speed dispersion high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
Environment-friendly marine antifouling coating for finishing boat described in the present invention, general application 2～3 roads during such paint spraying, coating thickness need reach 100～200 μ m, when film thickness reaches specified requirement, can reach effective anti-fouling effect.The construction of different methods such as available airless spraying, brushing or roller coating.
Embodiment
Below the present invention will be described in detail by two specific exampless:
Embodiments of the invention one are " 858 vinylformic acid ship bottom anti-fouling paint ", and prescription by weight is:
(1) acrylic resin: 20 weight parts
(2) rosin: 15 weight parts
(3) compound organic stain control agent: cuprous thiocyanate (CuSCN) 10 weight parts, copper pyrithione 5 weight parts, m-tetrachlorophthalodinitrile 5 weight parts
(4) pigment: talcum powder 3 weight parts, zinc oxide 10 weight parts, iron oxide red 3 weight parts
(5) mixed solvent is: dimethylbenzene 20 weight parts, N-BUTYL ACETATE 5 weight parts
(6) anti-settling agent: organobentonite 2 grams
The preparation method is as follows:
Earlier vinylformic acid and Gum Rosin all are dissolved in the mixed solvent, fully dissolving adds compound organic stain control agent, color stuffing, anti-settling agent successively, stirs, high speed dispersion high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
This coating detects result such as table one according to standard GB/T 6822-1986 " ship bottom anti-fouling paint general technical specifications "
The key technical indexes of table one, " 858 vinylformic acid ship bottom anti-fouling paint "
858 vinylformic acid ship bottom anti-fouling paints of the present invention have following performance characteristics:
1, adopts the cuprous (Cu of oxygen-freeization
2O) and the organotin (TBT) of international forbidding and DDT poison expect to have environmental protection characteristic.
2, can be used for steel fishing boat hull bottom, the protection phase with 1-2 imitates, and low price, is a kind of economical ship bottom anti-fouling paint of better performances.
3, well attached with the hull bottom coating, have excellent physical and mechanical properties.
4, paint film keeps smooth surface, can keep ship's speed unaffected, fuel saving.
5, easy construction, the construction of different methods such as available airless spraying, brushing or roller coating.High solid, one build of airless spraying can reach 100 μ m.
6, have good drying property, the four seasons all can use, and can construct under various weather condition.
Embodiments of the invention two are " 828 vinylformic acid ship bottom anti-fouling paint ", and prescription by weight is:
(1) acrylic resin: 15 weight parts
(2) rosin: 20 weight parts
(3) compound organic stain control agent: cuprous thiocyanate (CuSCN) 10 weight parts, copper pyrithione 5 weight parts, m-tetrachlorophthalodinitrile 6 weight parts
(4) pigment: talcum powder 3 weight parts, zinc oxide 10 weight parts, iron oxide red 3 weight parts
(5) mixed solvent is: dimethylbenzene 20 weight parts, N-BUTYL ACETATE 8 weight parts
(6) anti-settling agent: organobentonite 2 grams
The preparation method is as follows:
Earlier vinylformic acid and Gum Rosin all are dissolved in the mixed solvent, fully dissolving adds compound organic stain control agent, dispersion agent, color stuffing, anti-settling agent successively, stirs, high speed dispersion high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
This coating detects result such as table two according to standard GB/T 6822-1986 " ship bottom anti-fouling paint general technical specifications "
The key technical indexes of table two, " 828 vinylformic acid ship bottom anti-fouling paint "
828 acrylic acid ship bottom anti-fouling paints of the present invention have following characteristic of property:
1, adopts the cuprous (Cu of oxygen-freeization2O) and the organotin (TBT) of international forbidding and DDT poison expect to have environmental protection characteristic.
2, can be used for the wooden fishing vessels hull bottom, have the protection phase effect of 1-2, and low price, be a kind of economical ship bottom anti-fouling paint of better performances.
3, well attached with the hull bottom coating, have good physical and mechanical properties.
4, paint film keeps smooth surface, can keep ship speed unaffected, fuel saving.
5, easy construction, the construction of the distinct methods such as available airless spraying, brushing or roller coating. High solid, one build of airless spraying can reach 100 μ m.
6, have good drying property, the four seasons all can use, and can construct under various weather conditions.
Claims (4)
1. environment-friendly marine antifouling coating for finishing boat, described coating are that oxygen-freeization is cuprous and reach the marine antifouling coating that antifouling one year phase of tool of national requirements for environmental protection imitates, and it is characterized in that prescription comprises following composition:
(1) acrylic resin: 15～20 weight parts;
(2) rosin: 15～20 weight parts;
(3) compound organic stain control agent: 20～30 weight parts;
Wherein compound organic stain control agent is by cuprous thiocyanate, and copper pyrithione and m-tetrachlorophthalodinitrile constitute;
(4) color stuffing: talcum powder 2～3 weight parts, zinc oxide 8～12 weight parts, iron oxide red 3～5 weight parts;
(5) mixed solvent is: dimethylbenzene 10～20 weight parts, N-BUTYL ACETATE 5～10 weight parts;
(6) anti-settling agent: organobentonite 2～4 weight parts;
This coating is applicable to steel or wooden fishing vessels hull bottom position as antifouling varnish, can effectively prevent marine life stained to hull bottom in 1 year.
2. environment-friendly marine antifouling coating for finishing boat according to claim 1 is characterized in that, compound organic stain control agent material is: cuprous thiocyanate 5～10 weight parts, copper pyrithione 5～10 weight parts, m-tetrachlorophthalodinitrile 5～8 weight parts.
3. according to the preparation method of each described environment-friendly marine antifouling coating for finishing boat among the claim 1-2, it is characterized in that, may further comprise the steps:
Acrylic resin and rosin all are dissolved in the mixed solvent, and fully dissolving adds compound organic stain control agent, color stuffing, anti-settling agent successively, stirs, high speed dispersion high speed dispersion once more after the grinding; After detecting viscosity, fineness, obtain coating.
4. according to each described environment-friendly marine antifouling coating for finishing boat among the claim 1-2, it is characterized in that coating thickness need reach 100～200 μ m during such paint spraying, when film thickness reaches specified requirement, can reach effective anti-fouling effect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810088860XA CN101550304B (en) | 2008-04-02 | 2008-04-02 | Environment-friendly marine antifouling coating for finishing boat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810088860XA CN101550304B (en) | 2008-04-02 | 2008-04-02 | Environment-friendly marine antifouling coating for finishing boat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101550304A CN101550304A (en) | 2009-10-07 |
| CN101550304B true CN101550304B (en) | 2011-04-20 |
Family
ID=41154803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810088860XA Expired - Fee Related CN101550304B (en) | 2008-04-02 | 2008-04-02 | Environment-friendly marine antifouling coating for finishing boat |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101550304B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805546B (en) * | 2010-03-26 | 2011-11-30 | 秦皇岛玻璃工业研究设计院 | Antifouling paint for ship and marine facility |
| CN102311693A (en) * | 2010-07-05 | 2012-01-11 | 上海海鹰粘接科技有限公司 | Antifouling coating used for environmental protection type ship and preparation method thereof |
| CN103122187B (en) * | 2011-11-18 | 2015-10-07 | 中国科学院兰州化学物理研究所 | ionic liquid modified marine antifouling paint |
| CN102807797B (en) * | 2012-05-23 | 2014-10-15 | 浙江省海洋开发研究院 | Efficient marine antifouling coating and broad-spectrum controlled-release antifouling agent for same |
| CN103408983A (en) * | 2013-07-09 | 2013-11-27 | 中国船舶重工集团公司第七二五研究所 | Environment-friendly antifouling paint taking silver behenate as main antifouling agent and preparation method thereof |
| CN103396513B (en) * | 2013-07-24 | 2016-03-02 | 华南理工大学 | A kind of preparation method of main chain fracture type polyacrylic acid silane ester resin and application |
| CN104911904A (en) * | 2015-05-14 | 2015-09-16 | 巢湖市大江渔具有限公司 | Antifouling paint for fishing net |
| CN104804595A (en) * | 2015-05-22 | 2015-07-29 | 中国船舶重工集团公司第七二五研究所 | Preparation method of novel marine antifouling coating |
| CN109385158A (en) * | 2018-09-12 | 2019-02-26 | 安徽康瑞高科新材料技术工程有限公司 | A kind of anti-pollution flashover coating and preparation method thereof |
| CN109536028A (en) * | 2018-11-27 | 2019-03-29 | 徐州力奥新能源设备有限公司 | A kind of formula of the antifouling paint of new energy equipment |
| CN110437689A (en) * | 2019-08-09 | 2019-11-12 | 江苏海晟涂料有限公司 | A kind of low-surface-energy environment-friendly type marine antifouling coating |
| CN112029356B (en) * | 2020-09-05 | 2022-04-12 | 安徽省金盾涂料有限责任公司 | Copper-free high-solid-content environment-friendly corrosion-resistant antifouling paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104213A (en) * | 1986-06-20 | 1987-12-30 | 天津大学 | Antipollution technology for ocean ship by means of controlling drug-releasing |
| CN1119665A (en) * | 1994-08-23 | 1996-04-03 | 大日本涂料株式会社 | Antifouling paint composition |
| CN1218820A (en) * | 1997-11-28 | 1999-06-09 | 化学工业部海洋化工研究院 | Non-toxic anti-pollution paint for sea |
-
2008
- 2008-04-02 CN CN200810088860XA patent/CN101550304B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104213A (en) * | 1986-06-20 | 1987-12-30 | 天津大学 | Antipollution technology for ocean ship by means of controlling drug-releasing |
| CN1119665A (en) * | 1994-08-23 | 1996-04-03 | 大日本涂料株式会社 | Antifouling paint composition |
| CN1218820A (en) * | 1997-11-28 | 1999-06-09 | 化学工业部海洋化工研究院 | Non-toxic anti-pollution paint for sea |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101550304A (en) | 2009-10-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101550304B (en) | Environment-friendly marine antifouling coating for finishing boat | |
| CN101555374B (en) | Aluminum boat antifouling paint | |
| CN101550306A (en) | Universal ship bottom antifouling coating | |
| CN102807796B (en) | Novel environment-friendly anti-fouling coating paint for ocean | |
| KR100880841B1 (en) | Antifouling paint composition | |
| KR20080047589A (en) | Marine antifouling coating compositions | |
| CN101550305B (en) | Long-life self-polishing antifouling coating | |
| CN102807797B (en) | Efficient marine antifouling coating and broad-spectrum controlled-release antifouling agent for same | |
| EP2785804B1 (en) | Waterborne antifouling coating composition | |
| CN101696340B (en) | Strippable anti-fouling paint | |
| CN102618137A (en) | Green and environment-friendly antifouling paint for fishing boats, and fouling-panel testing method | |
| CN103788780B (en) | A kind of have an antifouling paint of cracking resistance for the hull bottom brushing of steel boats and ships | |
| CN102977744A (en) | Nano-composite marine anti-fouling coating material and preparation method thereof | |
| CN104761991A (en) | Environmental-protection type multi-element collaborative marine anti-fouling coating | |
| CN104403448A (en) | Nano cuprous oxide and nano silver compounded sea anti-fouling paint | |
| CN104693867A (en) | Tin-free self-polishing anti-fouling paint, anti-fouling paint protective layer, underwater anti-fouling protective layer and application of anti-fouling paint | |
| CN107541129A (en) | A kind of nano combined antifouling paint and preparation method thereof | |
| CN101824261B (en) | Micro-gel surface marine antifouling paint | |
| CN104610851A (en) | Preparation method of anti-fouling coating | |
| CN102504697B (en) | High-efficiency tin-free self-polishing antifouling paint composition and application thereof | |
| CN104610852A (en) | Anti-fouling coating | |
| AU2021105323A4 (en) | Capsaicin environmentally-friendly antifouling coating and preparation method thereof | |
| CN104817913B (en) | Long-acting environment-friendly ship bottom antifouling paint, strippable antifouling paint and ship bottom antifouling treatment method | |
| CN106281020A (en) | A kind of Wuxi, without the environment-friendly type marine antifouling coating of copper and preparation method and application | |
| CN104087102A (en) | Antifouling paint for ships |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANGHAI HAIYUE PAINT CO., LTD. Owner name: KUNSHAN HAIYUE COATING CO., LTD. Free format text: FORMER OWNER: SHANGHAI HAIYUE PAINT CO., LTD. Effective date: 20110708 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 200081 18/F, JIALAN BUILDING, NO. 2261, SICHUAN NORTH ROAD, SHANGHAI TO: 215341 NO. 1021, HUANGPU ROAD, QIANDENG TOWN, KUNSHAN CITY, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110708 Address after: Huangpu road Kunshan City Qiandeng Town of Jiangsu province No. 1021 215341 Co-patentee after: SHANGHAI HAIYUE PAINT Co.,Ltd. Patentee after: KUNSHAN HAIYUE PAINT Co.,Ltd. Address before: 200081 Shanghai city North Sichuan Road No. 2261 Granville building 18 floor Patentee before: SHANGHAI HAIYUE PAINT Co.,Ltd. |
|
| C56 | Change in the name or address of the patentee |
Owner name: HAIYUE PAINT (KUNSHAN) CO., LTD. Free format text: FORMER NAME: KUNSHAN HAIYUE COATING CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: Huangpu road Kunshan City Qiandeng Town of Jiangsu province No. 1021 215341 Patentee after: HAIYUE PAINT (KUNSHAN) Co.,Ltd. Patentee after: SHANGHAI HAIYUE PAINT Co.,Ltd. Address before: Huangpu road Kunshan City Qiandeng Town of Jiangsu province No. 1021 215341 Patentee before: KUNSHAN HAIYUE PAINT Co.,Ltd. Patentee before: SHANGHAI HAIYUE PAINT Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110420 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |