CN101555338A - Polyvinyl chloride plastics specifically used for environment-friendly household power wire - Google Patents
Polyvinyl chloride plastics specifically used for environment-friendly household power wire Download PDFInfo
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- CN101555338A CN101555338A CNA2009100984654A CN200910098465A CN101555338A CN 101555338 A CN101555338 A CN 101555338A CN A2009100984654 A CNA2009100984654 A CN A2009100984654A CN 200910098465 A CN200910098465 A CN 200910098465A CN 101555338 A CN101555338 A CN 101555338A
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- polyvinyl chloride
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- power wire
- household power
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Abstract
The invention relates to a polyvinyl chloride plastics specifically used for an environment-friendly household power wire, which contains components with the following weight contents: 50 percent of 1300-type polyvinyl chloride resin powder, 4 percent of plasticizer-epoxidized soybean oil (ESO), 30 percent of plasticizer-trioctyl trimellitate (TOTM), 4 percent of Ca-Zn complex stabilizer (Ca-Zn), 2 percent of flame retardant-diantimony trioxide (Sb2O3), 8 percent of filling agent-nanoscale calcium carbonate (CaCO3), 0.8 percent of lubricant-polyethylene wax, and 1.2 percent of processing modifier-methacrylic acid polyester (ACR-401). On the premise of guaranteeing the excellent physical performance of the existing polyvinyl chloride plastics, the content of harmful substances thereof is in accordance with the latest rule of EU ROHS instruction and special environmental protection requirements of part top-ranking home-appliance producers in the world on the household power wire.
Description
Technical field
The invention belongs to a kind of polyvinyl chloride resin modification plastics, be specifically related to the igelite of a kind of environment-friendly household supply lead special use.
Background technology
At present, the ROHS of European Union instruction exports in the related products in Europe except regulation: Cd＜100ppm, Pb, Hg, Cr
+ 6, outside six kinds of objectionable impurities limit value content such as PBBs, PBDEs＜1000ppm (each), consider again recently to adopt Norway POHS instruction and Denmark to be about to the Reach rules (having increased the kind of restrictive substance) of proposition.The part world top household electrical appliances manufacturers is as PANASONIC, Sharp, Korea S's Samsung, LG, Sweden Electrolux etc. also limit in addition and use TBBP-A (tetrabromobisphenol), PFOS (Perfluorooctane sulfonates and other), PAHS (polycyclic aromatic compound), DBP, DEHP, materials such as BBP, HBCDD.
Chinese patent once disclosed a kind of " environmental protection polyvinyl chloride " (China, publication number CN1459468A, open day 2003.12.03), it is made up of polyvinyl chloride resin (TK-1000), light weight calcium (CCR), heavy calcium (LT-2500), plasticizer (DINP), interior lubrication prescription (6A), outer lubrication prescription (SA-1807), epoxy soybean oil (B-22), calcium zinc stabilizer (SA-180), calcium zinc stabilizer (SP-1745), antioxidant (1010), anti UV agent (UV).It can reach very high safety standard requirements and environmental requirement, greatly reduces the content of heavy metal simultaneously, but should not be as domestic power supply line raw material.
Chinese patent once disclosed a kind of " environmental protection polyvinyl chloride electrical wire and cable plastic formulation " (China, publication number CN1923885A, open day 2007.03.07), it forms (weight percent) polyvinyl chloride (PVC) RESINS by following composition proportion: 50%, and softening agent: 30%, stablizer: 2.5%, flame retardant: 2%, weighting agent: 10%, modification agent: 3.5%, processing aid: 2%.It meets the environmental requirement that present countries in the world propose every profession and trade, but is difficult to satisfy the requirement of domestic power supply line.
That Chinese patent once disclosed was a kind of " environment-friendly type polychloroethylene plastic formula for electrical appliance plug (China; publication number CN1970615A; an open day 2007.05.30); it forms (weight percent) polyvinyl chloride (PVC) RESINS by following composition proportion: 62%, softening agent: 24%, stablizer: 2.5%; flame retardant: 2%; environmental stress resistance modification agent: 7%, lubricant: 0.5%, electrical isolation properties-correcting agent: 2%.It is used for the electrical engineering and electric apparatus plug, can not be used for the domestic power supply line.
That Chinese patent once disclosed was a kind of " environment protection PVC power cable material and preparation method thereof (China; publication number CN101266845A; an open day 2008.09.17); it is formed by the feedstock production of following weight part; wherein: 100 parts of polyvinyl chloride, softening agent DINP50-60 part, one package stabilizer 6-7 part; lubricant 1-2 part, calcene 20-30 part.It also is difficult to satisfy the requirement of domestic power supply line.
In view of above background, under the prerequisite that guarantees the existing good physical of polyvinyl chloride supply lead plastics, it is very urgent solving the too high problem of its harmful substance contents.Be necessary to develop the product that meets the ROHS of European Union instruction polyvinyl chloride supply lead plastics that makes new advances.
Summary of the invention
The object of the present invention is to provide the igelite of a kind of environment-friendly household supply lead special use, it is under the prerequisite that guarantees existing igelite good physical, and wherein the component content of objectionable impurities meets the ROHS of European Union and instructs the special environmental requirement of the top household electrical appliances of the up-to-date regulation and part world manufacturers to the domestic power supply line.
For achieving the above object, the present invention take technical scheme as follows: the igelite of a kind of environment-friendly household supply lead special use, the weight content of its each component is: the hot fat of 1300 type polyvinyl chloride resin powder 50%, softening agent epoxy soybean oil (ESO) 4%, softening agent tri trimellitate (TOTM) 30%, calcium-zinc composite stabilizing agent (Ca-Zn) 4%, fire retardant antimonous oxide (Sb
2O
3) 2%, weighting agent nanometer grade calcium carbonate (CaCO
3) 8%, lubricant polyethylene wax 0.8%, the polynary ester of modifier methacrylic acid (ACR-401) 1.2%.
It is that succeed in developing in order to solve the problem that prior art exists a kind of meets the environmental protection polyvinyl chloride supply lead plastics that the ROHS of European Union instruction is used for the domestic power supply line, compare with existing igelite as domestic power supply line raw material, under the prerequisite that guarantees existing igelite good physical, make its harmful substance contents minimum, satisfy the whole world requirement more and more higher at present, meet the Europe and the whole world from now on to the production process of all Industrial products and this megatrend of environmental requirement of final product to environmentfriendly products.
Embodiment
The igelite of a kind of environment-friendly household supply lead special use, the weight content of its each component is: the hot fat 30% of 1300 types-polyvinyl chloride resin powder 50%, epoxy soybean oil 4%, tri trimellitate, calcium-zinc composite stabilizing agent 4%, antimonous oxide) 2%, nanometer grade calcium carbonate 8%, polyethylene wax 0.8%, the polynary ester 1.2% of ACR-401-methacrylic acid.Mix by said ratio, as the raw material of environment-friendly household supply lead.
It is as follows that the igelite proportioning (percentage by weight) of the present invention and the special use of existing domestic power supply line forms contrast:
The relevant The performance test results contrast with existing domestic power supply line special-purpose polychloroethylene plastics of the present invention is as follows:
By detected result as can be known: the present invention compared with prior art under the prerequisite of the good physical that guarantees existing igelite, makes its harmful substance contents minimum.The present invention detects by harmful substance contents CTI, meets the ROHS of European Union and instructs the special environmental requirement of the top household electrical appliances of the up-to-date regulation and part world manufacturers to the domestic power supply line.
Claims (1)
1, the igelite of a kind of environment-friendly household supply lead special use, it is characterized in that: the weight content of its each component is: the hot fat 30% of 1300 types-polyvinyl chloride resin powder 50%, epoxy soybean oil 4%, tri trimellitate, calcium-zinc composite stabilizing agent 4%, antimonous oxide) 2%, nanometer grade calcium carbonate 8%, polyethylene wax 0.8%, the polynary ester 1.2% of ACR-401-methacrylic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100984654A CN101555338A (en) | 2009-05-08 | 2009-05-08 | Polyvinyl chloride plastics specifically used for environment-friendly household power wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100984654A CN101555338A (en) | 2009-05-08 | 2009-05-08 | Polyvinyl chloride plastics specifically used for environment-friendly household power wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101555338A true CN101555338A (en) | 2009-10-14 |
Family
ID=41173632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009100984654A Pending CN101555338A (en) | 2009-05-08 | 2009-05-08 | Polyvinyl chloride plastics specifically used for environment-friendly household power wire |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101555338A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102127275A (en) * | 2011-03-16 | 2011-07-20 | 上海元琦能源科技发展有限公司 | Composition for flame-retardant polyvinyl chloride (PVC) plastic foam board, product prepared from same, and preparation method thereof |
| CN102161804A (en) * | 2011-04-26 | 2011-08-24 | 广东华声电器股份有限公司 | -R type polrvinyl chloride wire and cable insulation material |
| CN102456432A (en) * | 2010-10-29 | 2012-05-16 | 嘉兴市天信电线有限公司 | Lead for ultrasonic welding and preparation method thereof |
| CN102911463A (en) * | 2012-11-15 | 2013-02-06 | 东莞市祺龙电业有限公司 | High-temperature resistant flame-retardant environment-friendly PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN106752053A (en) * | 2016-12-26 | 2017-05-31 | 张家港市大能塑料制品有限公司 | A kind of formula of environmentally friendly class plastic grain |
-
2009
- 2009-05-08 CN CNA2009100984654A patent/CN101555338A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102456432A (en) * | 2010-10-29 | 2012-05-16 | 嘉兴市天信电线有限公司 | Lead for ultrasonic welding and preparation method thereof |
| CN102456432B (en) * | 2010-10-29 | 2013-08-21 | 嘉兴市天信电线有限公司 | Lead for ultrasonic welding and preparation method thereof |
| CN102127275A (en) * | 2011-03-16 | 2011-07-20 | 上海元琦能源科技发展有限公司 | Composition for flame-retardant polyvinyl chloride (PVC) plastic foam board, product prepared from same, and preparation method thereof |
| CN102127275B (en) * | 2011-03-16 | 2012-11-14 | 上海元琦能源科技发展有限公司 | Composition for flame-retardant polyvinyl chloride (PVC) plastic foam board, product prepared from same, and preparation method thereof |
| CN102161804A (en) * | 2011-04-26 | 2011-08-24 | 广东华声电器股份有限公司 | -R type polrvinyl chloride wire and cable insulation material |
| CN102161804B (en) * | 2011-04-26 | 2013-02-13 | 广东华声电器股份有限公司 | -R type polrvinyl chloride wire and cable insulation material |
| CN102911463A (en) * | 2012-11-15 | 2013-02-06 | 东莞市祺龙电业有限公司 | High-temperature resistant flame-retardant environment-friendly PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN102911463B (en) * | 2012-11-15 | 2014-09-17 | 东莞市祺龙电业有限公司 | High-temperature resistant flame-retardant environment-friendly PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN106752053A (en) * | 2016-12-26 | 2017-05-31 | 张家港市大能塑料制品有限公司 | A kind of formula of environmentally friendly class plastic grain |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20091014 |