CN101547844A - Packaging for high moisture bar soap - Google Patents

Packaging for high moisture bar soap Download PDF

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Publication number
CN101547844A
CN101547844A CNA2007800444388A CN200780044438A CN101547844A CN 101547844 A CN101547844 A CN 101547844A CN A2007800444388 A CNA2007800444388 A CN A2007800444388A CN 200780044438 A CN200780044438 A CN 200780044438A CN 101547844 A CN101547844 A CN 101547844A
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CN
China
Prior art keywords
soap
fungicide
paper board
bar
thermoplastic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007800444388A
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Chinese (zh)
Other versions
CN101547844B (en
Inventor
G·张
刘吉泉
C·R·萨尔瓦多
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
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Publication date
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Publication of CN101547844A publication Critical patent/CN101547844A/en
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Publication of CN101547844B publication Critical patent/CN101547844B/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/28—Applications of food preservatives, fungicides, pesticides or animal repellants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Pest Control & Pesticides (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Detergent Compositions (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Abstract

The present invention discloses a packaging for high moisture bar soap compositions to address a number of potential problems associated with high moisture bar soap compositions, such as minimizing moisture loss, inhibiting mold growth on paperboard material used in the packaging, and preventing the development of colored stains on the bar soap and packaging resulting from chemical reaction between the high moisture bar soap and the paperboard, especially recycled paperboard. The bar soap packaging comprises a laminate material comprising a paperboard material, a thermoplastic material disposed on at least one side of the paperboard material, and a fungicide. Further provided is a method of inhibiting the growth of mold on a paperboard package which can result from storage of a high moisture bar soap composition in the paperboard package by treating the paperboard package with a fungicide comprising chlorothalonil and p- tolyl diiodomethyl sulfone, and then packaging the high moisture bar soap composition in the treated paperboard package.

Description

The packing that is used for high moisture bar soap
Invention field
The present invention relates to be used for the packing of the high moisture bar soap composite of cleaning skin.
Background of invention
Soap slab remains the general product form that is used for cleaning skin.Those skilled in the art uses the term soap to name the resultant of reaction of carboxylic acid and alkali (being typically metal hydroxides or carbonate).Gained salt not only has the polarity water-wet side but also have nonpolar lipophilic end, and this helps in the presence of water removing from skin or other surface and deoils and other apolar substance.
Usually, can cast by frame/die casting or by rolling/prepare soap slab.The method of making soap slab needs " colloid " quality and the excessive elasticity of drying steps to eliminate soap blank usually, and these character exist when high moisture levels usually.Therefore, the finished product soap slab will have the moisture (being water) of lower content usually, described moisture by the weight of described soap slab usually about 10% to about 14% scope.Yet, developed about obtaining to comprise high moisture levels for example by the weight of described soap slab technology at least about the soap slab of 15% water.With regard to preparation and method efficient, the soap slab with high moisture levels is desirable.Yet after the storage, high moisture bar soap is tending towards running into many potential problemes in the carton package of routine.These problems comprise moisture loss (through evaporation or suck in the carton package material), in grow mold on the carton package material and because of high moisture bar soap and cardboard chemical reaction coloured spot of generation on soap slab and packing take place between the Reclaimed board especially.
Therefore, still need to develop a kind of packing that is used for high moisture bar soap, to alleviate the problem that moisture loss, fungus growth and dyestuff shift.
Summary of the invention
The present invention relates to be used for the packing of high moisture bar soap composite, solving the many potential problemes relevant, as minimize moisture loss, mould fungus inhibition in the growth on the cardboard that is used to pack and prevent from chemical reaction especially to take place at soap slab with pack the coloured spot of generation between the Reclaimed board because of high moisture bar soap and cardboard with the high moisture bar soap composite.Soap slab product of the present invention comprises: (a) comprise the bar soap packaging of laminated material and (b) comprise by the weight of the described bar composition bar composition at least about 15% water.The laminated material of bar soap packaging comprises paper board material, be arranged on thermoplastic material and fungicide at least one side of paper board material.Paper board material can be made by cellulose fibre (original paper pulp or regenerated paper pulp).The Reclaimed board material is preferred.Thermoplastic material is preferably the polypropylene material of biaxial orientation.Fungicide is preferably selected from the group of being made up of following: carbendazim, Bravo, p-methylphenyl diiodomethyl sulfone, thiabendazole and their compound.
The invention still further relates to a kind of inhibition and in carton package, preserve the method for the fungus growth that produces because of the high moisture bar soap composite.Mould fungus inhibition, especially mould species aspergillus sydowii and/or penicillium chrysogenum, the method of growing on the carton package of storage high moisture bar soap composite may further comprise the steps: handle carton package with the fungicide that comprises Bravo and p-methylphenyl diiodomethyl sulfone, then the high moisture bar soap composite is packaged in the carton package of handling.
Detailed Description Of The Invention
As used herein, term " high moisture bar soap " is meant the weight that comprises by described bar composition at least about 15%, preferably at least about the bar composition of 20% water.
Packing
Bar soap packaging of the present invention comprises laminated material, and described laminated material comprises paper board material, thermoplastic material and fungicide.With thermoplastic material setting (preferred lamination) at least one side of paper board material.Can thermoplastic material be applied (preferred lamination) via several different methods such as adhesives, hot adhesion etc. on a side of paper board material.Fungicide can be arranged at least one side of paper board material and/or in the process of making paper board material and directly be attached in the paper board material.
In one embodiment, paper board material is folded into carton or carton configuration to hold described high moisture bar soap composite.At this on the one hand, paper board material will have towards the inboard of carton or carton interior with towards the outside around the external environment condition of carton or carton.In one embodiment, by adhesives thermoplastic material is laminated on the inboard of paper board material.If carton or carton comprise any figure in the outside of carton or carton, then with described graphic printing to the outside of paper board material.Then, fungicide is applied on the printed pattern in the paper board material outside.
Suitable paper board material comprises the material of being made by fiber such as cellulose fibre.This type of material is well known in the art and preferably has the weight of about 200 gram/sq ms (" gsm ") to about 500gsm.
Can be used for suitable thermoplastic material of the present invention and comprise polypropylene (as the polypropylene (" BOPP ") of biaxial orientation), polyethylene, polyethylene terephthalate (" PET "), polyester, polyvinylchloride (" PVC ") and their combination.Preferably select used thermoplastic material to postpone the moisture loss of bar composition after storage.Also preferred impermeable water of thermoplastic material or aqueous vapor are absorbed by cardboard thereby postpone water.Also preferably select thermoplastic material to prevent on soap slab and packing, producing coloured spot because of chemical reaction especially takes place between the Reclaimed board for high moisture bar soap and cardboard.Thermoplastic material will have about 5 μ m usually to about 100 μ m, and preferred about 10 μ m are to about 50 μ m, and more preferably from about 12 μ m to the thickness of about 25 μ m.In one embodiment, thermoplastic material is the polypropylene (" BOPP ") with biaxial orientation of 18 μ m thickness.
Can be used for suitable fungicide of the present invention and comprise Bravo, p-methylphenyl diiodomethyl sulfone, carbendazim, thiabendazole and their compound.A kind of preferred fungicide is carbendazim, and it is can trade name INTACE B-350 commercially available from Intace S.A..Another kind of preferred fungicide comprises the compound of Bravo and p-methylphenyl diiodomethyl sulfone, and it is can trade name INTACEB-6773 commercially available from Intace S.A..Should be appreciated that many other suitable fungicides are known in the art, and the tabulation of aforementioned fungicide only is a limiting examples.Usually fungicide is attached on the side of paper board material or directly is attached in the paper board material, the content of described fungicide for about 500ppm to about 10,000ppm, preferably about 1000ppm is about 5000ppm extremely, and 1500ppm about 3000ppm extremely more preferably from about.
Bar composition
Bar composition of the present invention comprises water, soap and other optional member.
Water
Bar composition of the present invention comprises weight by described composite at least about 15%, more preferably at least about 20%, and more preferably at least about 25% water.The content of water can also be higher by the weight of described bar composition, for example 30%, 35% or even 40%, but be not more than usually about 60%, preferably be not more than about 55%, more preferably no more than about 50%.
Should be appreciated that the water yield will be lost during the process of preparation bar composition, i.e. evaporation.And in case prepare finished product, owing to water evaporates, packing (as cardboard case) suction on every side etc., water can further lose from bar composition.Bar composition is packaged in reduce in the packing of the present invention because of evaporating after preserving or absorbing damage by water vector in the packing.
Soap
Bar composition of the present invention will comprise by the weight of described composite about 40% usually to about 84%, and preferred about 45% to about 75%, more preferably from about 50% to about 65% soap.Term used herein " soap " has its general implication, i.e. the alkali metal salt or the alkanol ammonium salts of alkane or alkene monocarboxylic acid.What be applicable to the object of the invention is sodium cation, magnesium cation, potassium cationic, calcium cation, an ethanol ammonium cation, diethanol ammonium cation and triethanol ammonium cation, or their combination.Usually, soda soap can be used in the composite of the present invention, but about 1% to about 25% soap can be the compound of ammonium soaps, potash soap, magnesium soap, calcium soap or these soaps.Can be used for soap of the present invention is about 12 to 22 carbon atoms that have of knowing, and preferred about 12 to the alkanoic acid of about 18 carbon atoms or the alkali metal salt of alkenoic acid.They also can be described to have about 12 to the alkane of about 22 carbon atoms or the alkali metal carboxylate of alkene.
The soap that is assigned fatty acid distribution of coconut oil can provide the lower end of broad molecular weight range.Those soaps that are assigned arachisoil or rapeseed oil aliphatic acid or their hydrogenated derivatives can provide the upper end of broad molecular weight range.
The preferred soap that is assigned butter and vegetable fatty acids that uses.More preferably, vegetable oil is selected from the group of being made up of following: palm oil, cocounut oil, palm-kernel oil, palmitic stearin acid and hydrogenation rice bran oil or their compound, because these are present in the fat of easier acquisition.Especially preferred is palmitic stearin acid, palm-kernel oil and/or cocounut oil.The ratio of aliphatic acid in coconut oil soap with at least 12 carbon atoms is about 85%.When using the compound of cocounut oil and fat (as butter, palm oil or non-tropical macadamia nut oil or fat, wherein main chain is long is C16 and higher), this ratio will be bigger.
A kind of preferred soap is a soda soap, and described soda soap contains has an appointment 50% to about 80%, more preferably from about 35% to about 40% butter; 0% to about 60%, more preferably 0% to about 50% palm stearines; 0% to about 40%, more preferably 0% to about 35% palm oil; With about 10% to about 35%, more preferably from about 15% to about 30% the palm-kernel oil or the compound of coconut oil.
According to the acceptable standard in market, described soap can comprise degree of unsaturation.Usually avoid excessive degree of unsaturation.
Can prepare soap by the pan boiling method or the modern continuous soapmaking method of classics, wherein use method well known to those skilled in the art, make natural fat and oil as butter or cocounut oil or their equivalent and alkali metal hydroxide saponification.Alternatively, can by with in alkali metal hydroxide or the carbonate and aliphatic acid such as lauric acid (C12), myristic acid (C14), palmitic acid (C16) or stearic acid (C18) prepare soap.
In one embodiment, bar composition will comprise the soap that is made by continuous soapmaking method.Then, via vacuum flash drying method, the soap that will comprise about 30% water is processed into soap bar.Described soap bar preferably comprises about 85% anhydrous soap (50% butter/30% palmitic stearin acid/20% palm-kernel oil (or 20% cocounut oil)), about 0.2% free citric acid, about 0.2% sodium citrate, about 0.05% DPTA four sodium, about 0.05% HEDP four sodium, about 0.6% sodium chloride, about 1% glycerine and about 12% to about 18% water, and surplus is nonsaponifiable material.These degrees are by the weight of described soap bar.Then, in the operation of rolling, use soap bar to be prepared as follows described finished product bar composition.
Inorganic salts
Randomly, can in bar composition of the present invention, use the liquid water content of inorganic salts to help to keep higher in the composite of the present invention.Inorganic salts help in conjunction with the water in the bar composition, thereby anti-sealing is by evaporation or the loss of other approach.Bar composition of the present invention comprises by the weight of described composite about 1% to about 15%, and preferred about 2% to about 12%, and 2.5% to about 10.5% inorganic salts more preferably from about.Suitable inorganic salts comprise magnesium nitrate, tricresyl phosphate magnesium, calcium chloride, natrium carbonate, aluminum sodium sulfate, dibasic sodium phosphate, sodium hexametaphosphate, Magnesium succinate sodium, sodium tripolyphosphate, aluminium sulphate, aluminium chloride, aluminium chlorohydrate, hydration aluminium choride zirconium, hydration aluminium choride zirconium glycine complexes, zinc sulphate, ammonium chloride, ammonium phosphate, calcium acetate, calcium nitrate, calcium phosphate, calcium sulphate, ferric sulfate, magnesium chloride, magnesium sulphate etc.Preferred inorganic salts comprise sodium tripolyphosphate, magnesium salts (as magnesium sulphate) and/or tetra sodium pyrophosphate.When as the composition in the bar composition of the present invention that comprises soap, magnesium salts is tending towards changing into magnesium soap in finished product.In the present invention, sodium tripolyphosphate, magnesium salts (so magnesium soap) and/or tetra sodium pyrophosphate are preferred.Sodium tripolyphosphate also is preferred, because when bar composition is used for cleaning skin by the customer, it can be tending towards promoting generation lathery.
Carbohydrate structurant
Optional but preferably comprise carbohydrate structurant and be used as composition in the bar composition of the present invention.Carbohydrate structurant is tending towards helping the liquid water content that keeps higher in the composite of the present invention.Be suitable for comprising living starch (corn, rice, potato, wheat etc.), pregelatinized starch, carboxymethyl cellulose, acrylic acid/isodecyl vinyl acetate cross-linked polymer (stabylene), acrylic polymers, carrageenan, xanthans, carbowax, polyethylene oxide etc. as the carbohydrate structurant of composition in the composite of the present invention.Preferred carbohydrate structurant comprises living starch and/or pregelatinized starch.
The carbohydrate structurant that preferably is incorporated in the bar composition is a starch.The described starch starch of making a living, or be pregelatinized starch.Alternatively, can use living starch and modification during the preparation bar composition, so that described starch becomes gelatine or gelatine partially or completely.Pregelatinized starch be as bar composition composition of the present invention and before adding by the starch of gelatine.No matter preferred gelation starch is the part or the starch of complete gelationization, because it can provide the dermal sensation beneficial effect of enhancing, as provides soft and smooth dermal sensation.The pregelatinized starch that is preferably used as composition in the composite of the present invention is can be from the commercially available PREGEL-A M 0300 of peak, Tianjin starch development corporation, Ltd. (Tianjin Tingfung Starch Development Co.Ltd.) of Chinese Tianjin.
The content of carbohydrate structurant in composite of the present invention is generally about 1% to about 20%, preferred about 2% to about 17% by the weight of described composite, and more preferably from about 4% to about 15%.
Bar composition of the present invention can also comprise the additional optional composition, as wetting agent (for example glycerine or sorbierite), free fatty acid, synthetic surfactant, cationic polymer, brightener, silicon dioxide etc.The examples of such optional composition is described in greater detail in common unsettled U.S. Patent Application Serial Number of submitting on June 15th, 2,006 11/453,767 and the U.S. Provisional Application sequence number of submitting on June 6th, 2,006 60/811,545.
Other optional member in the bar composition of the present invention comprises: spices; Sequestering agent, as edetic acid (EDTA) four sodium, EHDP or their compound, content counts 0.01% to 1% by the weight of described composite, preferred 0.01% to 0.05% usually; And colorant, opacifier and pearling agent, as titanium dioxide; All these compositions all can be used for strengthening the outward appearance or the aesthetic of product.
The pH of 1% solution that is dissolved in the bar composition of the present invention of water is generally about 7 to about 12, preferred about 8 to about 11, and more preferably from about 9 to about 10.
The outward appearance of bar composition can be transparent, semi-translucent or opaque as described in the present invention.In one embodiment, described bar composition is opaque.
Can comprise the common unsettled U.S. Patent Application Serial Number 11/453 that is specified in submission on June 15th, 2006 because of being packaged in the suitable high moisture bar soap composite that obtains beneficial effect in the bar soap packaging of the present invention, those bar compositions in the U.S. Provisional Application sequence number of submitting on June 6th, 767 and 2,006 60/811,545.
The customer can use cleansing bar soap composition of the present invention to come cleaning skin during taking a shower or washing.
The method of mould fungus inhibition growth
The invention still further relates to the especially method of the mould of some kind such as aspergillus sydowii and/or penicillium chrysogenum growth of a kind of mould fungus inhibition, described mould can grow on the carton package that holds the high moisture bar soap composite.It is found that for growing, mould species aspergillus sydowii and/or penicillium chrysogenum especially are a problem on the carton package that holds the high moisture bar soap composite.This type of mould species can be resisted fungicide commonly used on the carton package material usually, as carbendazim.
Also it is found that, with the fungicide that comprises Bravo and p-methylphenyl diiodomethyl sulfone compound handle the cardboard packing effectively mould fungus inhibition on carton package, grow, the mould of some kind especially is as aspergillus sydowii and/or penicillium chrysogenum.This fungicide material is can trade name INTACEB-6773 commercially available from Intace S.A..
In one embodiment, said method comprising the steps of: handle carton package with the fungicide that comprises Bravo and p-methylphenyl diiodomethyl sulfone; Use described packing to preserve to comprise by the weight of described bar composition bar composition at least about 15% water.
Embodiment
It below is the limiting examples that is housed in the cleansing bar soap composition in the bar soap packaging of the present invention.The amount of every kind of composition is the approximate weight percentum by the weight of described bar composition.
Composition Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Soap bar a 58.00％ 58.00％ 58.00％ 58.00％
Give birth to cornstarch 12.09％ 8.76％ 6.54％ 3.20％
Magnesium sulphate --- 3.00％ 5.00％ 8.00％
Dye solution 0.50％ 0.02％ 0.02％ 0.02％
Spices 0.90％ 0.90％ 0.90％ 0.90％
Sodium tripolyphosphate 2.50％ 2.50％ 2.50％ 2.50％
Titanium dioxide 0.50％ 0.50％ 0.50％ 0.50％
Palm-kernel oil aliphatic acid 0.75％ 0.75％ 0.75％ 0.75％
The moisture loss that is similar to during the processing (1％) (1％) (1％) (1％)
The liquid water content that is similar in the finished product 20％-25％ 20％-25％ 20％-25％ 20％-25％
Composition Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Soap bar a 58.00％ 58.00％ 54.00％ 54.00％
Give birth to cornstarch 3.54％ 4.50％ 9.25％ 9.25％
Magnesium sulphate 8.00％ --- --- ---
Tetra sodium pyrophosphate --- 8.00％ 8.00％ 8.00％
Dye solution 0.50％ 0.50％ 0.50％ 0.50％
Spices 0.90％ 0.90％ 0.90％ 0.90％
Sodium tripolyphosphate 2.50％ 2.50％ 2.50％ 2.50％
Titanium dioxide 0.50％ 0.50％ 0.50％ 0.50％
Palm-kernel oil aliphatic acid 0.75％ 0.75％ 1.50％ 0.75％
Laureth-3-sodium sulphaste --- --- --- 0.75％
The moisture loss that is similar to during the processing (1％) (1％) (1％) (1％)
The liquid water content that is similar in the finished product 20％-25％ 20％-25％ 20％-25％ 20％-25％
Composition Embodiment 9 Embodiment 10 Embodiment 11 Embodiment 12
Soap bar a 58.00％ 58.00％ 54.00％ 54.00％
Glycerine --- --- 3.00％ 3.00％
Give birth to cornstarch --- 12.50％ 17.00％ 12.50％
Tetra sodium pyrophosphate 8.00％ --- --- 3.00％
Brightener 0.02％ 0.02％ --- ---
Spices 0.90％ 1.20％ 1.40％ 1.40％
Sodium tripolyphosphate 2.50％ 2.50％ 2.50％ ---
Titanium dioxide 0.50％ 0.50％ 0.50％ 0.50％
Palm-kernel oil aliphatic acid 0.75％ 0.75％ --- ---
NaLS --- --- 0.10％ 0.10％
Pregelatinized starch b 4.50％ --- --- ---
Trichlorocarbanilide --- --- 0.60％ 0.60％
Dye solution 0.50％ 0.50％ 0.50％ 0.50％
The moisture loss that is similar to during the processing (1％) (1％) (1％) (1％)
The liquid water content that is similar in the finished product 20％-25％ 20％-25％ 20％-25％ 20％-25％
aThe soap bar that is used for these embodiment has following proximate composition: about 85% anhydrous soap (palm-kernel oil of palmitic stearin acid/20% of 50% butter/30% (or cocounut oil of 20%)), about 0.2% free citric acid, about 0.2% sodium citrate, about 0.05% DPTA four sodium, about 0.05% HEDP four sodium, about 0.6% sodium chloride, about 1% glycerine and about 12% to about 18% water, surplus is nonsaponifiable material.These degrees are by the weight of described soap bar.
bPregelatinized starch can trade name PREGEL-A M 0300 derives from peak, the Tianjin starch development corporation, Ltd. of Chinese Tianjin.
In these embodiments, soap bar can make via relating to the conventional approach of mixing step and vacuum drying step.Then soap bar is joined in the mixer.Then spices, brightener and titanium dioxide composition are joined in the mixer, and mixed about 10 to 15 seconds.Then, will join in the mixer and mixed about 30 to 45 seconds such as compositions such as water, inorganic salts (as sodium tripolyphosphate, tetra sodium pyrophosphate and/or magnesium sulphate), free fatty acid (as palm-kernel oil aliphatic acid), carbohydrate structurant (as giving birth to starch or pregelatinized starch), dye solution and trichlorocarbanilides.This soap compound is handled, to obtain the finished product bar composition via rolling, the compacting and the imprint step of routine.Then, the finished product bar composition is contained in the bar soap packaging of the present invention.
Dimension disclosed herein and value are not intended to be understood that strictly to be limited to described exact value.On the contrary, except as otherwise noted, dimension that each is such or value are meant the numerical value of being quoted and center on the scope that is equal on the function of this numerical value.For example, the dimension that is disclosed as " 40mm " is intended to expression " about 40mm ".
The All Files of quoting in detailed Description Of The Invention is all incorporated this paper into way of reference in relevant portion.Should not be interpreted as admitting that for quoting of any file it is relevant prior art of the present invention.When any implication of term in any implication of term among the present invention or definition and the file of incorporating into way of reference or when defining contradiction, should obey the implication or the definition of giving this term in the present invention.
Though casehistory and described specific embodiments of the present invention it is obvious to those skilled in the art that and can make a plurality of other changes and modification under the situation that does not deviate from the spirit and scope of the invention.Therefore, claims all such changes and modification of being intended to be included in the scope of the present invention.

Claims (14)

1. soap slab product, described soap slab product comprises:
(a) comprise the bar soap packaging of laminated material, it is characterized in that described laminated material also comprises:
(i) paper board material;
(ii) be arranged on the thermoplastic material at least one side of described paper board material; With
(iii) fungicide; With
(b) be contained in bar composition in the described bar soap packaging, described bar composition comprises the weight at least 15% by described bar composition, preferred 20% water.
2. soap slab product as claimed in claim 1 wherein is arranged on described fungicide at least one side of described paper board material and/or directly is attached in the described paper board material.
3. the described soap slab product of each claim as described above, wherein said fungicide is selected from the group of being made up of following: Bravo, p-methylphenyl diiodomethyl sulfone, carbendazim, thiabendazole and their compound.
4. soap slab product as claimed in claim 3, wherein said fungicide comprise Bravo and p-methylphenyl diiodomethyl sulfone.
5. soap slab product as claimed in claim 3, wherein said fungicide comprises carbendazim.
6. the described soap slab product of each claim as described above, wherein with described fungicide with 500ppm to 10, the content of 000ppm is applied on the described paper board material.
7. the described soap slab product of each claim as described above, wherein said thermoplastic material is selected from the group of being made up of following: polypropylene, polyethylene, polyethylene terephthalate, polyester, polyvinylchloride and their compound, preferably wherein said thermoplastic material are the polypropylene of biaxial orientation.
8. the described soap slab product of each claim as described above, wherein said thermoplastic material has the thickness of 5 μ m to 100 μ m, preferably has the thickness of 10 μ m to 50 μ m.
9. the described soap slab product of each claim as described above wherein is laminated to described thermoplastic material at least one side of described paper board material by adhesives.
10. the described soap slab product of each claim as described above, wherein said paper board material has the outside and inboard, described thermoplastic material is arranged on the described inboard of described paper board material, and described fungicide is arranged on the described outside of described paper board material.
11. a mould fungus inhibition is holding the method for growing on the carton package of bar composition, described bar composition comprises the water by the weight at least 15% of described bar composition, and described method is characterised in that described method also comprises:
(a) with comprising that the fungicide of Bravo and p-methylphenyl diiodomethyl sulfone handles described carton package; And
(b) described bar composition is packaged in the carton package of described processing.
12. method as claimed in claim 11, wherein said carton package comprise the thermoplastic material at least one side that is arranged on described carton package.
13. as claim 11 or 12 described methods, wherein said thermoplastic material is selected from the group of being made up of following: polypropylene, polyethylene, polyethylene terephthalate, polyester, polyvinylchloride and their compound, preferably wherein said thermoplastic material are the polypropylene of biaxial orientation.
14. as the described method of claim 11 to 13, but the growth of wherein said method mould fungus inhibition kind, and described mould species is selected from the group of being made up of following: aspergillus sydowii, penicillium chrysogenum and their compound.
CN2007800444388A 2006-12-01 2007-11-29 Packaging for high moisture bar soap Active CN101547844B (en)

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EP2202358A1 (en) * 2008-12-29 2010-06-30 Kompetenzzentrum Holz GmbH Impregnated paper with antimicrobial properties
WO2011037819A1 (en) * 2009-09-22 2011-03-31 Sonoco Development, Inc. Paperboard containing a biocide and method for making the same

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WO1997022684A1 (en) * 1995-12-20 1997-06-26 The Procter & Gamble Company Pour molded personal cleansing bar
RU2233784C2 (en) * 1999-01-15 2004-08-10 Унилевер Нв Soap wrapper
JP4358345B2 (en) * 1999-03-09 2009-11-04 オカモト株式会社 Polypropylene film and multilayer film thereof
FR2816478B1 (en) * 2000-11-10 2004-01-30 Richard C Johnson HALOSULFONE-BASED FUNGICIDE COMPOSITION, PARTICULARLY FOR PACKAGING
CL2004001164A1 (en) * 2003-05-23 2005-05-20 Colgate Palmolive Co METHOD FOR WRAPPING PRODUCTS THAT HAVE A LARGER DIMENSION AND A LOWER DIMENSION, THAT INCLUDES PROVIDING A ROLL OF SHEETED MATERIAL; CUT LOTS OF EDGE OF SUCH ROLL; ENTER THE MODIFIED SHEET MATERIAL AND SEAL THE FINS
ES2333031T3 (en) * 2004-07-06 2010-02-16 International Paper Company PAPER SUBSTRATES CONTAINING AN ANTIMICROBIAL COMPOUND AND METHODS OF MANUFACTURING AND USING THEMSELVES.

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MX2009005785A (en) 2009-06-10
CA2669936A1 (en) 2008-06-05

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