CN101536697A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
- Publication number
- CN101536697A CN101536697A CN200910137458A CN200910137458A CN101536697A CN 101536697 A CN101536697 A CN 101536697A CN 200910137458 A CN200910137458 A CN 200910137458A CN 200910137458 A CN200910137458 A CN 200910137458A CN 101536697 A CN101536697 A CN 101536697A
- Authority
- CN
- China
- Prior art keywords
- profenofos
- worm prestige
- indenes worm
- pesticidal combination
- days
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal composition, the active ingredients of which are indoxacarb and profenofos; the mass proportion of the indoxacarb and the profenofos is 10:1-1:50, and the better proportion thereof is 5:1-1:20. After the indoxacarb and the profenofos are compounded, the insecticidal composition has obvious synergized actions and is used for the control of insects in crops such as fruit trees, cotton, rice, vegetables and the like, especially lepidoptera insects.
Description
Technical field
The present invention relates to a kind of composition pesticide, especially contain the Pesticidal combination of indenes worm one-tenth and Profenofos.
Background technology
In recent years, because single drug and the medication of non-science have caused many insects that the agricultural chemicals of current use has been produced resistance,, become a great problem of chemical control as diamond-back moth, prodenia litura etc.Simultaneously, frequent dispenser causes peasant burden to increase the weight of and increasing environmental pollution again.Therefore, be badly in need of the insecticide new varieties of efficient, low toxicity, environmental protection.
Indenes worm prestige (indoxacarb) is a kind of Xin Xing oxadiazine insecticides, and its insecticidal mechanism is by the sodium-ion channel in the blocking-up insect nerve cell, makes the nerve cell loss of function of insect and is benumbed, and the coordination ability descends, and is final dead.Medicament works by contacting or get to eat to enter in the polypide, does not have cross resistance with other insecticide.To agriculture and garden crop pests such as vegetables, beet, cotton, fruit tree, tea tree, potato, gardening, flowers, active high as lepidoptera pests such as beet armyworm, tomato moth, imported cabbageworm, cotton bollworms, and each instar larvae all had good control efficiency.Simultaneously, as safe as a house to natural enemy insect, residual low in crop, be the desirable medicament that can be used for control of insect in the non-polluted farm product production.But indenes worm prestige is relatively poor to the quick-acting of control of insect, and the use cost height, has therefore limited it to a certain extent and has applied.
Profenofos is a kind of broad-spectrum organic insecticide, and mechanism of action is to suppress cholinesterase in the insect bodies, destroys the normal nerve impulse conduction of insect, make insect excitement, paralysis death, it has permeability preferably on plant leaf blade, have and tag, stomach toxicity and cross conduction effect, having immediate effect property.Lepidoptera pests such as cotton bollworm, cabbage caterpillar, diamond-back moth there is good control efficiency, safe for human and animal and environment, being applicable to the Lepidoptera class pest on the crops such as control vegetables, fruit tree, cotton, ornamental plants and paddy rice, is selective insecticide comparatively desirable in the integrated control.But the lasting effect of Profenofos is relatively poor, and when using separately, insect is easy to generate pesticide resistance.
In view of this, the necessary efficient insecticide composition that uses on a kind of suitable agricultural that provides.
Summary of the invention
The objective of the invention is to: provide use on a kind of suitable agricultural, antagonism property of medicine insect has the efficient insecticide composition of outstanding control efficiency.
For solving the problems of the technologies described above, the inventor is by a large amount of biologicall test screenings, and unexpected discovery indenes worm prestige and Profenofos are composite with certain proportion, and insects such as antagonism property of medicine diamond-back moth have significant synergies.
On the basis of above-mentioned discovery, through composition is carried out symphyogenetic quantitative analysis, formed technical scheme of the present invention, promptly be a kind of active ingredient, be another active ingredient with Profenofos with indenes worm prestige, the mass ratio of indenes worm prestige and Profenofos is 10: 1～1: 50, and ratio is 5: 1～1: 20 preferably.
The present composition can be prepared into known method and be fit to any one formulation that agricultural is used, and reasonable formulation is wetting powder, missible oil, suspending agent, aqueous emulsion, microemulsion etc., and the total content of active ingredient is 5%-60% in the preparation.
The adjuvant that uses in the composition of the present invention comprises that solvent, emulsifier, dispersant, wetting agent, stabilizing agent, antifreezing agent, thickener, pH regulator agent, bleeding agent etc. and other are of value to the known substance that active ingredient is stablized and drug effect is brought into play in storing and using, all be the various compositions of using or allow use in the pesticidal preparations always, be not particularly limited, concrete composition and consumption require to determine by simple experiment according to prescription.
Product described in the invention can the finished product preparation form provide, and promptly each material mixes in the composition, and the composition of composition also can provide with single agent form, directly directly mixes in bucket or jar before the use, is diluted to required concentration then.
Pesticidal combination of the present invention is mainly used in insect, the especially control of Lepidoptera class pest of crops such as fruit tree, cotton, paddy rice, vegetables.
Compared with prior art, the beneficial effect of the present invention's generation is: (1) is compared with single agent, and this Pesticidal combination has tangible synergy to lepidoptera pest, has improved control efficiency; (2) can significantly reduce the field dosage, effectively reduce environmental pollution and residue of pesticide, and reduce and produce and use cost; (3) mechanism of action of active ingredient is different in the Pesticidal combination, the generation that helps overcoming pest resistance He delay pest resistance to insecticide; (4) compare with the single agent of indenes worm prestige, quick-acting obviously improves; (5) compare with the agent of Profenofos list, better lasting effect is arranged.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.
The combination of active principles of different agricultural chemicals is made agricultural chemicals, is a kind of mode effectively and efficiently of exploitation at present and development novel pesticide.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing usually.But be specially which kind of effect, unpredictable, have only by a large amount of tests and just can know.Compound synergic is well filled a prescription, owing to obviously improved actual control efficiency, reduced the usage amount of agricultural chemicals, thereby delayed the generation of pest resistance to insecticide widely, and be the important means of integrated control.
The present composition is an active ingredient with indenes worm prestige and Profenofos, and combination antagonism diamond-back moth has obvious role in synergism between them, and is not only the simple addition of two kinds of medicament effects, specifically is illustrated with following biologicall test example.
Biologicall test example 1: the composite toxicity test of indenes worm prestige and Profenofos to diamond-back moth
Subjects: resistance diamondback moth larvae (measure, to the resistance of gamma cyhalothrin more than 500 times) through pesticide resistance
Test method: with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".Select the third-instar larvae of growth uniformity, the culture dish that the diameter of the fresh artificial feed of access storing 10 grams is 9 centimetres, every ware connects 10, every processing connects 5 wares, sprays under 50PSI pressure with the Potter spray tower, sprays a ware at every turn, 1 milliliter of every ware spraying liquid, blank spray equivalent clear water.General each processing is provided with 6 concentration gradients.The culture dish of handling is put into 25 ℃, 12H/12H illumination box cultivate, checked borer population anyway, and calculated lethality in 72 hours.Carry out statistical analysis with the DPS data processing software, calculate the LC of each medicament
50, press the abundant method of Sun Yun then and calculate co-toxicity coefficient (CTC).
When CTC≤80, then the composition performance is for antagonism, and when 80＜CTC＜120, then the composition performance is for summation action, and when CTC 〉=120, then the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ reagent agent EC
50) * 100
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) of mixture] * 100
Measurement result shows, the proportioning of indenes worm prestige and Profenofos has obvious synergistic effect between 10: 1～1: 50 the time, and in the time of especially between 5: 1～1: 20, synergistic effect is more obvious, and co-toxicity coefficient is more than 180, and experimental data sees also table 1.
Table 1 different disposal is to the Toxicity Determination result of diamond-back moth
| Handle | LC 50 (μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| Profenofos | 52.31 | 100 | - | - |
| Indenes worm prestige | 9.29 | 563.06 | - | - |
| Indenes worm prestige 10: Profenofos 1 | 8.13 | 643.41 | 521.03 | 123.51 |
| Indenes worm prestige 5: Profenofos 1 | 5.87 | 891.14 | 485.90 | 183.47 |
| Indenes worm prestige 1: Profenofos 1 | 7.36 | 710.75 | 331.58 | 214.45 |
| Indenes worm prestige 1: Profenofos 5 | 16.35 | 319.90 | 177.26 | 180.66 |
| Indenes worm prestige 1: Profenofos 10 | 18.30 | 285.88 | 142.17 | 201.23 |
| Indenes worm prestige 1: Profenofos 20 | 21.36 | 244.97 | 122.15 | 200.71 |
| Indenes worm prestige 1: Profenofos 30 | 36.74 | 142.41 | 114.94 | 123.95 |
| Indenes worm prestige 1: Profenofos 50 | 38.62 | 135.47 | 109.19 | 124.22 |
Biologicall test example 2: the composite toxicity test of indenes worm prestige and Profenofos to rice leaf roller
Subjects: resistance rice leaf roller larvae (measure, to the resistance of desinsection list more than 50 times) through pesticide resistance
Test method: select 3 instar larvaes of growth uniformity, put into the culture dish of 9 centimetres of diameters, 10 larvas of every ware are repeated 3 times.Culture dish is placed on Potter spray tower article carrying platform central authorities, and medicament is pressed concentration from low to high, each spraying liquid 2mL, pressure 2kg/cm
2The spray medicine after the sedimentation time be 30 seconds, with running water as blank.Add 2% agar 30mL in raising bottle, insert 5-6 sheet fresh light green rice leaf in tillering stage, the larva after the processing is inserted immediately and raises in the bottle, 10 larvas of every bottle graft, bottleneck seals with preservative film, places (27 ± 1) ℃, and the photoperiod is (illumination: raise under condition dark) in 16: 8.Check result behind the chemicals treatment 48h.Data statistics mode and judgment criteria are tested with diamond-back moth.
Measurement result shows, indenes worm prestige and Profenofos are composite to be between 10: 1～1: 50 the time in proportioning, to the activity of rice leaf roller, have obvious synergistic effect, in the time of especially between 5: 1～1: 20, synergistic effect is more obvious, co-toxicity coefficient is more than 180, and experimental data sees also table 2.
Table 2 different disposal is to the Toxicity Determination result of rice leaf roller
| Handle | LC 50 (μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| Profenofos | 55.36 | 100 | - | - |
| Indenes worm prestige | 11.24 | 492.50 | - | - |
| Indenes worm prestige 10: Profenofos 1 | 8.11 | 682.61 | 456.81 | 149.44 |
| Indenes worm prestige 5: Profenofos 1 | 6.99 | 792.02 | 427.12 | 185.45 |
| Indenes worm prestige 1: Profenofos 1 | 7.69 | 719.97 | 296.35 | 243.09 |
| Indenes worm prestige 1: Profenofos 5 | 16.35 | 338.65 | 165.49 | 204.76 |
| Indenes worm prestige 1: Profenofos 10 | 17.36 | 318.93 | 135.76 | 235.02 |
| Indenes worm prestige 1: Profenofos 20 | 23.68 | 233.82 | 118.74 | 197.01 |
| Indenes worm prestige 1: Profenofos 30 | 34.87 | 158.85 | 112.73 | 140.93 |
| Indenes worm prestige 1: Profenofos 50 | 39.10 | 141.69 | 107.73 | 131.52 |
Pesticidal combination of the present invention can be prepared into known method and be fit to any one formulation that agricultural is used, and reasonable formulation is wetting powder, missible oil, water dispersible granules, suspending agent, aqueous emulsion and microemulsion.Below describe with specific embodiment, all the prescription in percentage be mass percent.The processing technology of the various preparations of the present composition is prior art, can change to some extent according to different situations.
Embodiment 1:22% indenes worm prestige Profenofos wetting powder
Indenes worm prestige 20%
Profenofos 2%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon black 10%
Kaolin complements to 100%
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, promptly get 22% indenes worm prestige Profenofos wetting powder.
This embodiment is applied to prevent and treat rice-stem borer.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 85.3%, 95.0%, 94.7% behind the medicine with 22% indenes worm prestige Profenofos wetting powder.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1500 times by 3500 times and 40% Profenofos missible oil, and 1 day preventive effect is respectively 73.5%, 51.1% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 77.0%, 84.5% and 83.9%, 80.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of striped rice borer significantly better than single agent.
Embodiment 2:20% indenes worm prestige Profenofos suspension emulsion
Indenes worm prestige 15%
Profenofos 5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
The newborn 0206B of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 3%
Xanthans 1%
Bentonite 1%
Glycerine 1%
Water complements to 100%.
The ratio of each component such as indenes worm prestige, dispersant, wetting agent and water in prescription mixed, after grinding, under high speed shear, add the mixture of Profenofos and agricultural newborn 0206B, fully mix, obtain 20% indenes worm prestige Profenofos suspension emulsion.
This embodiment is applied to prevent and treat the wild cabbage beet armyworm.By 4000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 87.6%, 90.7%, 94.9% behind the medicine with 20% indenes worm prestige Profenofos suspension emulsion.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1500 times by 3500 times and 40% Profenofos missible oil, and 1 day preventive effect is respectively 78.4%, 48.0% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 78.3%, 85.4% and 87.8%, 83.4% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of beet armyworm significantly better than single agent.Can also doublely control the cabbage caterpillar on the wild cabbage.
Embodiment 3:6% indenes worm prestige Profenofos microemulsion
Indenes worm prestige 1%
Profenofos 5%
N-Methyl pyrrolidone 3%
Isopropyl alcohol 15%
The newborn 500# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 3%
The newborn 1601# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 3%
Water complements to 100%
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under agitation, oil phase is mixed with water, make 18% indenes worm prestige Profenofos microemulsion.
This embodiment is applied to prevent and treat the cotton cotton bollworm.By 1000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 82.4%, 91.9%, 87.3% behind the medicine with 6% indenes worm prestige Profenofos microemulsion.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and 1 day preventive effect is respectively 76.4%, 52.1% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 86.9%, 79.2% and 76.1%, 85.3% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of cotton cotton bollworm significantly better than single agent.
Embodiment 4:42% indenes worm prestige Profenofos missible oil
Indenes worm prestige 2%
Profenofos 40%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Dimethylbenzene complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 42% indenes worm prestige Profenofos missible oil.
This embodiment is applied to prevent and treat apple small leaf pretty young woman.By 4000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 75.8%, 92.7%, 94.1% behind the medicine with 42% indenes worm prestige Profenofos missible oil.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and 1 day preventive effect is respectively 77.5%, 50.4% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 77.2%, 80.4% and 83.9%, 84.2% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to apple small leaf pretty young woman's preventive effect, quick-acting and lasting effect significantly better than single agent.
Embodiment 5:15% indenes worm prestige Profenofos aqueous emulsion
Indenes worm prestige 7.5%
Profenofos 7.5%
N-Methyl pyrrolidone 10%
Calcium dodecyl benzene sulfonate 5%
The newborn 600# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 5%
Water complements to 100%
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high speed shear stirs, oil phase is mixed with water, make 15% indenes worm prestige Profenofos aqueous emulsion.
This embodiment is applied to prevent and treat the paddy rice rice leaf roller.By 2500 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 86.2%, 95.3%, 93.0% behind the medicine with 15% indenes worm prestige Profenofos aqueous emulsion.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and 1 day preventive effect is respectively 78.9%, 53.7% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 86.4%, 87.9% and 76.1%, 79.4% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of paddy rice rice leaf roller significantly better than single agent.
Embodiment 6:27% indenes worm prestige Profenofos missible oil
Indenes worm prestige 3%
Profenofos 24%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Dimethylbenzene complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 27% indenes worm prestige Profenofos missible oil.
This embodiment is applied to prevent and treat the blue or green diamond-back moth in Shanghai.By 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 84.8%, 91.7%, 95.0% behind the medicine with 27% indenes worm prestige Profenofos missible oil.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and 1 day preventive effect is respectively 75.8%, 48.5% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 83.5%, 88.6% and 76.8%, 82.7% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of diamond-back moth significantly better than single agent.
Embodiment 7:52% indenes worm prestige Profenofos missible oil
Indenes worm prestige 2%
Profenofos 50%
N-Methyl pyrrolidone 5%
The newborn 1601# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 5%
The newborn 500# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 5%
Dimethylbenzene complements to 100%.
Active component, emulsifier and the solvent ratio in prescription is added in the mixing kettle, stir, make 52% indenes worm prestige Profenofos missible oil.
This embodiment is applied to prevent and treat the wild cabbage prodenia litura.By 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 81.7%, 94.4%, 95.1% behind the medicine with 52% indenes worm prestige Profenofos suspending agent.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and 1 day preventive effect is respectively 76.4%, 48.1% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 84.3%, 89.4% and 75.4%, 80.1% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of prodenia litura significantly better than single agent.
Embodiment 8:51% indenes worm prestige Profenofos missible oil
Indenes worm prestige 1%
Profenofos 50%
N-Methyl pyrrolidone 3%
The newborn 1601# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 5%
The newborn 500# of farming (Jiangsu Zhongshang Chemical Co., Ltd.) 5%
Dimethylbenzene complements to 100%.
Active component, emulsifier and the solvent ratio in prescription is added in the mixing kettle, stir, make 52% indenes worm prestige Profenofos missible oil.
This embodiment is applied to prevent and treat the paddy rice rice leaf roller.By 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 80.6%, 95.5%, 93.1% behind the medicine with 51% indenes worm prestige Profenofos suspending agent.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1000 times by 3500 times and 20% Profenofos microemulsion, and the preventive effect of 7 days and 15 days is respectively 82.4%, 87.3% and 75.2%, 81.8% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Profenofos is obvious, to preventive effect, quick-acting and the lasting effect of rice leaf roller significantly better than single agent.
Claims (6)
1, a kind of Pesticidal combination is characterized in that: contain indenes worm prestige and Profenofos in the described Pesticidal combination, the mass ratio of described indenes worm prestige and Profenofos is 10: 1～1: 50.
2, Pesticidal combination according to claim 1 is characterized in that: the mass ratio of indenes worm prestige and Profenofos is 5: 1～1: 20.
3, according to each described Pesticidal combination in the claim 1 to 2, it is characterized in that: indenes worm prestige and the Profenofos gross mass percentage composition in Pesticidal combination is 5%-60%.
4, according to each described Pesticidal combination in the claim 1 to 3, it is characterized in that: also contain the pesticidal preparations auxiliary element in the described Pesticidal combination, so that Pesticidal combination is made the formulation that suitable agricultural is used.
5, Pesticidal combination according to claim 5 is characterized in that: the formulation of described Pesticidal combination is wetting powder, missible oil, suspending agent, aqueous emulsion or microemulsion.
6, Pesticidal combination according to claim 1, the application in the crop pest control.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910137458A CN101536697A (en) | 2009-04-24 | 2009-04-24 | Insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910137458A CN101536697A (en) | 2009-04-24 | 2009-04-24 | Insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101536697A true CN101536697A (en) | 2009-09-23 |
Family
ID=41120269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910137458A Pending CN101536697A (en) | 2009-04-24 | 2009-04-24 | Insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101536697A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674002A (en) * | 2012-05-08 | 2012-09-19 | 东莞市腾宇龙机械能源科技股份有限公司 | Insole printing machine provided with automatic feeding mechanism |
-
2009
- 2009-04-24 CN CN200910137458A patent/CN101536697A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674002A (en) * | 2012-05-08 | 2012-09-19 | 东莞市腾宇龙机械能源科技股份有限公司 | Insole printing machine provided with automatic feeding mechanism |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101480191B (en) | Insecticidal composition | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN102626110B (en) | Indoxacarb-containing complex pesticide composition | |
| CN101836641B (en) | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate | |
| CN105076185A (en) | Insecticide composition with chlorfenapyr and neonicotinoid insecticides, and preparation and application of insecticide composition | |
| CN105145663B (en) | A kind of plant pesticide composition containing nimbin and eucalyptus oil | |
| CN104488949A (en) | Dinotefuran-containing insecticidal combination | |
| CN101485329B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN101637158A (en) | Insecticidal composition with synergistic action | |
| CN101473816B (en) | Avermectin microcapsule suspending agent | |
| CN101406192A (en) | Compositional acaricide and uses thereof | |
| CN104273174B (en) | Pesticide granules containing dinotefuran and diazinon | |
| CN103651552B (en) | Ultra-low-volume liquor containing chlorfenapyr | |
| CN101444221B (en) | Composite containing oxadiazines and pyrromonazole pesticide | |
| CN104186547B (en) | A kind of granular pesticide containing humic acid and clothianidin | |
| CN101700034B (en) | Pesticide composition | |
| CN103070186B (en) | Insecticidal composition containing thiamethoxam and application of insecticidal composition | |
| CN101653124A (en) | Synergistic pesticide composition and application thereof | |
| CN101536697A (en) | Insecticidal composition | |
| CN101642121A (en) | Complex composition containing lufenuron | |
| CN107114392A (en) | Bio-insecticidal composition comprising destruxins | |
| CN101653138A (en) | Binary compound insecticidal composition containing indoxacarb | |
| CN102771511A (en) | Insecticidal composition containing fosthiazate | |
| CN103053580B (en) | Insecticidal composition of indoxacarb and pyridaben | |
| CN106973922A (en) | A kind of composition pesticide containing destruxins and pleocidin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090923 |