CN101521963B - Flexible PCT heating element and method of manufacturing the heating element - Google Patents

Abstract

A flexible PTC heating element, wherein parts of an electrode and a PTC resistance body are sunk in a flexible base material and the flexible base material is formed of a resin foam body or a rubber material having an irregular shape on the surface thereof, or an extendably deforming part is provided at least on either of the electrode and the PTC resistance body and the flexible base material hasan adhesiveness and the flexible base material or a flexible coating material has an extension resisting part.

Description

Flexible PCT heater and manufacture method thereof

The application please day be on June 16th, 2003 in being, application number is 03814070.5, and denomination of invention is divided an application for the Chinese patent application of " flexible PCT heater and manufacture method thereof ".

Technical field

The present invention relates to be used for vehicle seat heater or hand held heater etc., have flexibility, can be installed in arbitrary surface in shape, and have the flexible PCT heater and the manufacture method thereof of automatic temperature-adjusting regulatory function.

Background technology

The structure of PTC heater of the prior art is shown among Figure 42 A, the B.Existing P TC heater has a pair of comb poles (hereinafter referred to as electrode) 201,202 on base material 200, and is in by it to the PTC resistance 203 (hereinafter referred to as resistance) on the electric position.Base material 200 is formed by the material that does not have flexibility or shortage flexibility fully of pottery or metallic plate of handling through insulating or polyester film etc.Electrode 201,202 obtains by printing, dry conductive paste.Resistance 203 obtains by printing, dry PTC composition printing ink (hereinafter referred to as PTC printing ink).Then, cover with base material 200 and with cladding material 204 pairs of electrodes 201,202 and PTC203 that base material 200 has an identical material, thereby protect.In addition, Figure 42 A is the figure that a part of resistance 203, cladding material 204 openings are shown.

Adopting under the situation of polyester film as base material 200, cladding material 204, on cladding material 204, polyethylene kind hot-melt resin in advance for example bonds.Base material 200, electrode 201,202, resistance 203 and cladding material 204 is bonding by it.PTC resistance is in the prior art as over-current protecting element or small-sized and have a heater of special shape use so that under the situation of the mechanical stress that does not apply bending etc., fix, for example, be used for motor vehicle car door mirror etc. remove reveal, defrosting.In addition, in practicality, need to be used for terminal to electricity, but not shown in the drawings.

As the PTC printing ink that forms resistance 203, the conductive material of matrix polymer that can be by will comprising crystalline polymer and carbon black, metal dust, graphite etc. is dispersed in the solvent and forms.This printing ink is opened clear 56-13689 communique, spy the spy and is opened flat 6-96843 communique, spy and open in the flat 8-120182 communique etc. open.

Resistance 203 has with temperature rising resistance value and rises, and when arriving a certain temperature, and resistance value sharply increases and carries out the characteristic that automatic temperature-adjusting is regulated.This resistance-temperature characteristic is called PTC (positive temperature coefficient Positive Temperature Coefficient) characteristic.Resistance with this ptc characteristics is called PTC resistance.This characteristic can be thought the volumetric expansion of crystalline polymer to cause the conductive path of conductive material to cut off because the temperature rising makes, is accompanied by this situation, and resistance rises, and shows this characteristic therefrom.

But existing P TC heater owing to form on the base material 200 of aforesaid shortage flexibility, therefore can not be assembled in the automotive seat, is unsuitable for the purposes of health and is unsuitable for being installed on the curve form object of handle etc.

If the flexibility resin film of resin or elastomer etc. is used for base material 200, then can forms the PTC heater that temporarily has flexibility.But, under the situation of the mechanical stress that applies elongation etc., exist in the possibility that broken string or be full of cracks take place on electrode 201,202 or the resistance 203.Ptc characteristics is because the long-pending variation of the hot body of crystalline polymer makes the chain state variation of conductive material produce.Thus, can imagine easily that the physics of base material and the variation of mechanical dimension have remarkable influence to the characteristic of PTC resistance.Therefore, also untappedly go out to have flexibility and durable PTC heater under the practical environment of the load that applies alternating bending.

Disclosure of an invention

Flexibility PTC heater of the present invention has the electrode of printing formation and gives the PTC resistance of electricity by it, and has following any formation.

1) part of electrode and PTC resistance is immersed in the flexible parent metal.

2) flexible parent metal is made of foamed resin or the elastomeric material that the surface is provided with concaveconvex shape.

3) at least 1 side in electrode and the PTC resistance is provided with the elongation strain part.

4) flexible parent metal has caking property, and flexible parent metal or flexible cladding material have the elongation control part.

Brief description of drawings

Figure 1A is for showing the part plane of the opening figure according to the PTC heater formation of the invention process form 1.

Figure 1B is the profile of X-Y position of the PTC heater of Figure 1A.

Fig. 2 is the profile according to the PTC heater of the invention process form 2.

Fig. 3 is the profile according to the PTC heater of the invention process form 3.

Fig. 4 is the profile according to the PTC heater of the invention process form 4.

Fig. 5 is the profile according to the PTC heater of the invention process form 6.

Fig. 6 A is the part plane of the opening figure according to the PTC heater of the invention process form 7.

Fig. 6 B is the profile of X-Y position of the PTC heater of Fig. 6 A.

Fig. 7 is the profile according to the PTC heater of the invention process form 8.

Fig. 8 is the profile according to the PTC heater of the invention process form 9.

Fig. 9 A is the part plane of the opening figure according to the PTC heater of the invention process form 11.

Fig. 9 B is the profile of X-Y position of the PTC heater of Fig. 9 A.

Figure 10 is the part plane of the opening figure according to the PTC heater of the invention process form 12.

Figure 11 A is the part plane of the opening figure according to the PTC heater of the invention process form 13.

Figure 11 B is the profile of X-Y position of the PTC heater of Figure 11 A.

Figure 12 is the part plane of the opening figure according to the PTC heater of the invention process form 14.

Figure 13 is the part plane of the opening figure according to the PTC heater of the invention process form 15.

Figure 14 A is the part plane of the opening figure according to the PTC heater of the invention process form 16.

Figure 14 B is the profile of X-Y position of the PTC heater of Figure 14 A.

Figure 15 A is the part plane of the opening figure according to the PTC heater of the invention process form 17.

Figure 15 B is the profile of X-Y position of the PTC heater of Figure 15 A.

Figure 16 is the part plane of the opening figure according to the PTC heater of the invention process form 18.

Figure 17 is the part plane of the opening figure according to the PTC heater of the invention process form 19.

Figure 18 is the part plane of the opening figure according to the PTC heater of the invention process form 20.

Figure 19 A is the part plane of the opening figure according to the PTC heater of the invention process form 21.

Figure 19 B is the profile of X-Y position of the PTC heater of Figure 19 A.

Figure 20 A is the part plane of the opening figure according to the PTC heater of the invention process form 22.

Figure 20 B is the profile of pith of the PTC heater of Figure 20 A.

Figure 21 is the part plane of the opening figure according to the PTC heater of the invention process form 23.

Figure 22 is the part plane of the opening figure according to the PTC heater of the invention process form 24.

Figure 23 A is the part plane of the opening figure according to the PTC heater of the invention process form 25.

Figure 23 B is the profile of X-Y position of the PTC heater of Figure 23 A.

Figure 24 is the profile according to the pith of the PTC heater of the invention process form 26.

Figure 25 A is the part plane of the opening figure according to the PTC heater of the invention process form 27.

Figure 25 B is the profile of X-Y position of the PTC heater of Figure 25 A.

Figure 26 is the profile according to the PTC heater of the invention process form 28.

Figure 27 is the figure according to the deformation pattern of the PTC heater of the invention process form 28.

Figure 28 is the profile according to the PTC heater of the invention process form 29.

Figure 29 A is the part plane of the opening figure according to the PTC heating element structure of the invention process form 30.

Figure 29 B is the profile of X-Y position of the PTC heater of Figure 29 A.

Figure 30 A is the part plane of the opening figure according to the PTC heater of the invention process form 31.

Figure 30 B is the profile of X-Y position of the PTC heater of Figure 30 A.

Figure 31 A is the figure according to the flexibility fiber base material image of the PTC heater of the invention process form 31.

Figure 31 B is when the flexibility fiber base material is out of shape among Figure 31 A, the figure of peristome change of shape apperance.

Figure 32 A is the part plane of the opening figure according to the PTC heater of the invention process form 32.

Figure 32 B is the profile of X-Y position of the PTC heater of Figure 32 A.

Figure 33 A is the part plane of the opening figure according to the PTC heater of the invention process form 33.

Figure 33 B is the profile of X-Y position of the PTC heater of Figure 33 A.

Figure 34 A is the part plane of the opening figure according to the PTC heater of the invention process form 34.

Figure 34 B is the profile of X-Y position of the PTC heater of Figure 34 A.

Figure 34 C is the profile that Figure 34 B pith amplifies.

Figure 35 A is the part plane of the opening figure according to the PTC heater of the invention process form 35.

Figure 35 B is the profile of X-Y position of the PTC heater of Figure 35 A.

Figure 36 is the part plane of the opening figure according to the PTC heater of the invention process form 36.

Figure 37 is the part plane of the opening figure according to the PTC heater of the invention process form 37.

Figure 38 A is the part plane of the opening figure according to the PTC heater of the invention process form 38.

Figure 38 B is the profile of X-Y position of the PTC heater of Figure 38 A.

Figure 39 A is the part plane of the opening figure according to the PTC heater of the invention process form 39.

Figure 39 B is the profile of X-Y position of the PTC heater of Figure 39 A.

Figure 40 A is the part plane of the opening figure according to the PTC heating element structure of the invention process form 40.

Figure 40 B is the profile of X-Y position of the PTC heater of Figure 40 A.

Figure 41 is in the invention process form 41, is assembled with the profile of the seat of flexibility PTC heater.

Figure 42 A is the part plane of the opening figure of existing P TC heater.

Figure 42 B is the profile of X-Y position of the PTC heater of Figure 42 A.

The optimised form that carries out an invention

Below form of implementation of the present invention is described.In addition, enclose identical symbol for same structure and describe, and omit its detailed description.

(form of implementation 1)

Figure 1A is for showing the part plane of the opening figure according to the PTC heater of the invention process form 1.Figure 1B is the profile of X-Y position.Flexibility base material (hereinafter referred to as base material) 1 has gas barrier property and water proofing property and is impregnated with the liquid of printing ink etc.For example, constitute by applying polyurethanes hot-melt film on the surface of the polyester non-woven fabric that forms by long fibre.The conductive particle of comb poles (hereinafter referred to as electrode) 2 by silk screen printing and dry silver or carbon black etc. is dispersed in the conductive paste that forms in the resin solution and obtains.PTC resistance (hereinafter referred to as resistance) 3 is by carrying out PTC printing ink silk screen printing and dry the acquisition.In addition, conductive paste and PTC printing ink all comprise the resinae adhesive with flexibility, and the printed article that therefore dry back forms keeps flexibility to a certain degree.Flexibility cladding material (hereinafter referred to as cladding material) 4 has gas barrier property and water proofing property, by base material 1 is all covered and guard electrode 2 and resistance 3.Cladding material 4 constitutes by applying polyesters hot-melt film on the surface of the polyester non-woven fabric that is formed by long fibre, and is bonding in polyesters hot-melt film side and base material 1.

PTC printing ink is for example made according to following order.With the compatibility of crystalline resin, carbon black, chemical cross-linking agent or the coupling agent etc. of the ethylene-vinyl acetate copolymer of scheduled volume and polyvinyl resin etc. give reagent measure according to the rules carry out mixing.After this, heat-treat, obtain mixing thing.Then, it is pulverized, and the flexibility adhesive of this crushed material and acrylonitrile-butadiene rubber class binding agent etc. is carried out mixing crushing with 3 rollers.Further it is diluted, obtain PTC printing ink thus with solvent.

In addition, in this form of implementation, electrode 2 is constituted comb shape.By such formation, can carry out giving effectively to resistance 3.

Constitute by this, a part that constitutes the material of electrode 2 and resistance 3 is immersed in the base material 1.In addition, the degree of dipping is many more, and then the vibration durability of PTC heater is good more.So-called vibration durability refers to an aspect as the flexible appraisal of automotive seat heater, is to be that the semi-round ball imagination of 165mm is people's knees with diameter, repeatedly from the automotive seat surface by depressing 50mm.Even this evaluation requires practical going up to apply 1,000,000 times or vibration number that it is above, resistance change still is 10% or below it.

By using the polyester film mode the same that does not have the liquid infiltration performance to make the PTC heater, when carrying out above-mentioned evaluation, in the time of about 300,000 times, because the comb poles broken string causes resistance value to rise with this form of implementation.Relative therewith, the PTC heater in this form of implementation that has adopted the base material 1 with liquid infiltration performance can reach target clearly.Reach 10% until resistance change, adding the shake frequency number is 1,300,000 times.In addition, the PTC heater that the base material that keeps the higher short fiber of performance to form by dipping by further use is made is 3,000,000 times until adding the shake frequency number, and its performance is still good.Hence one can see that, easy more dipping conductive paste of basis material and PTC printing ink, and vibration durability is excellent more.

In addition, constitute fusing point that the polyurethanes hot-melt film of base material 1 has the conductive paste that forms electrode 2 or form resistance 3 PTC printing ink baking temperature or below it.Specifically, the baking temperature of conductive paste or PTC printing ink is 150 ℃, and hot-melt film's fusing point is about 120 ℃.Therefore, under applying hot-melt film's temperature, conductive paste and PTC printing ink have flowability, can be immersed in the base material 1.

In addition, base material 1 and the cladding material 4 that is all had gas barrier property and water proofing property around electrode 2 and the resistance 3 covers.Therefore, can prevent positively that it from contacting with extraneous gas as the oxygen of worsening reason, steam, moisture etc., provides reliability high PTC heater.

(form of implementation 2)

Fig. 2 is the profile that shows according to the PTC heater of form of implementation 2.Structure except that base material is identical with form of implementation 1.In addition, the flexibility cladding material is not shown goes out.The nonwoven fabrics (hereinafter referred to as nonwoven fabrics) 5 that base material has been adjusted by dipping forms.Nonwoven fabrics 5 is by heat resistance fiber nonwoven fabrics (hereinafter referred to as nonwoven fabrics) 6 is immersed in the resin-coated material in right amount, and dry obtain.In addition, nonwoven fabrics 6 is the polyester non-woven fabric of fiber orthogonal fiber formation.On nonwoven fabrics 5, obtain electrode 2 by printing dry conductive paste, and further form resistance 3 by the dry PTC printing ink of printing thereon.

Base material is formed by nonwoven fabrics 5, can prevent that conductive paste and PTC resistance printing ink from seeing through, and implements good silk screen printing when making.Thus, coating weight and resistance value are positively managed.The printing coating weight exists with ... the printing condition of the mesh of version and the viscosity of this printing ink etc.In addition, the surface texture of base material 1, promptly surface smoothing, dipping property etc. also are a greater impact.Therefore, after adjusting by an amount of dip coated material, to the surface, republish, be coated with conductive paste and PTC printing ink.Thus, can guarantee stable coating weight often, the PTC with suitable quality is provided heater.In addition, by on coating material, using the flexibility resin, also can not damage the flexibility of PTC heater.

In addition, the electrode 2 on the nonwoven fabrics 5 and resistance 3 forms a part and is immersed in the polyester non-woven fabric structure as base material.Thus, can keep vibration durability.

As implement described in the form 1, vibration durability is excellent more when adopting the base material that floods conductive paste and PTC printing ink easily more.But pickup is many more, and then the coating weight of conductive paste and PTC printing ink is big more, and cost will improve.In addition, it is big that the deviation of coating becomes, and is difficult to bring into play the ptc characteristics with reproducibility.Therefore for to guarantee suitable coating weight, preferably pickup is regulated.In this form of implementation, the nonwoven fabrics of having been adjusted by dipping 5 constitutes base material, and the coating weight of conduction paste and PTC is adjusted.

In addition, in this form of implementation, be long stapled polyester non-woven fabric as the nonwoven fabrics 6 of the bottom substrate of nonwoven fabrics 5, but be not limited only to this.Also can use the natural fiber of the synthetic fibers of polypropylene or nylon etc. or cotton etc.

In addition, as coating material, the latex of preferred acrylic resin, polyurethanes resin, amide-type resin, esters resin, ester polyurethane resinoid, silicon resinoid etc.These resins have flexibility, its latex with resinous principle emulsification, be dispersed in water or the organic solvent and form.These materials are good to the caking property of polyesters nonwoven fabrics, and dried product has thermal endurance, and PTC printing ink is not had adverse influence.Particularly, therefore be more preferably owing to polyurethanes, ester class, silicon resinoid can improve ptc characteristics.

(form of implementation 3)

Fig. 3 has shown the profile according to the PTC heater of form of implementation 3.In addition, the cladding material of not shown flexibility in the drawings.The aspect different with form of implementation 2 is to adopt the adjusted nonwoven fabrics of dipping (hereinafter referred to as nonwoven fabrics) 7 to replace nonwoven fabrics 5.Nonwoven fabrics 7 is to attach hot-melt film's (hereinafter referred to as film) 8 to constitute on the heat resistance fiber nonwoven fabrics (hereinafter referred to as nonwoven fabrics) 6 of polyester etc.

Constitute hot-melt film's 8 control conductive paste and saturating machine and the coating weights of PTC printing ink on nonwoven fabrics 6 by this.Thus, can obtain the little flexibility PTC heater of stable quality deviation.In addition, the thermal property of film 8 also is attached on the PTC resistance.Therefore, according to the kind of film 8, the characteristic of PTC is enhanced.And, therefore can provide long-term reliability high flexibility PTC heater because electrode 2 and PTC resistance 3 pass through film 8 further positively from the extraneous gas crested.

In addition, in this form of implementation, adopt the hot adhesion film in order to adjust saturating machine.If but attaching the hot adhesion film simply, when using with film like, conductive paste and PTC printing ink are to the dipping reduction as the nonwoven fabrics 6 of base material, and the result makes vibration durability reduce.Therefore behind adhered film 8 on the nonwoven fabrics 6, heat-treat at film 8 fusing points or the temperature more than it, make film 8 with the surface configuration of nonwoven fabrics 6 fully molten and, and a part be penetrated in the nonwoven fabrics 6 and use.In this way, Yin Shua conductive paste and PTC printing ink also form a part and are immersed in structure in the nonwoven fabrics 6 thereon, can keep vibration durability.

In addition, as film 8, preferably adopt ethylene-vinyl acetate resinoid, polyurethanes resin, esters resin, ester polyurethane resinoid.Illustrated resinae coating material is the same in these films 8 and the form of implementation 2 has flexibility, and PTC printing ink is had no adverse effect.When particularly adopting polyurethanes, ester polyurethane resinoid, can improve ptc characteristics, therefore preferred.

(form of implementation 4)

Fig. 4 is the profile according to the PTC heater of form of implementation 4.In addition, not shown flexibility cladding material.The difference of this form of implementation and form of implementation 3 is, as the heat resistant fibre nonwoven fabrics that forms the substrate of flooding the nonwoven fabrics of adjusting 9, is the stepped construction with spunbonded nonwoven 10 and spun-laced fabric 11 applying formation.

Can the sound to take place when the distortion relative with independent spunbonded nonwoven 10, by with itself and spun-laced fabric 11 applyings, then can prevent this phenomenon.In addition, can improve touching performance to the sense of PTC heater additional volume.

Spunbonded type and jet net-spraying method are the kinds of nonwoven fabrics manufacture method.Spunbonded nonwoven is behind direct fabrics, makes fiber that hot adhesion take place mutually on the point (dot) of hot-rolling (embossing), and combination forms thus; Spun-laced fabric makes the fiber formation that interweaves mutually under High-Pressure Water.Because spun-laced fabric 11 is soft and fluffy, therefore can prevent the sound.

In addition, also can make fiber interweaving form needle punched fabric replacement spun-laced fabric 11 with weaving with pin.

In addition, in this form of implementation, be suitable for the stepped construction of fitting and forming as the spunbonded nonwoven of heat resistant fibre nonwoven fabrics and spun-laced fabric or needle punched fabric with in the form of implementation 3.When this heat resistance fiber nonwoven fabrics is applicable to form of implementation 2, also can obtain same effect.

(form of implementation 5)

The difference of this form of implementation and form of implementation 4 is that spunbond with the chemical adhesion replacement, in addition, the employing adhesive is fitted with name a person for a particular job spun-laced fabric or needle punched fabric 11.In addition, chemical adhesion is with binding agent (resin) that fiber is adhered to one another, is a kind of manufacture method of nonwoven fabrics.

Because spunbonded nonwoven forms resin fusion, combination with heat, therefore must increase at this position thickness, perhaps promotes crystallization.Therefore, the flexibility of raw material itself reduces sometimes.On the other hand, carry out chemical adhesion with point,, can not damage the flexibility of raw material itself by the binding agent that selection has flexibility by binding agent.Thus, can obtain to have the base material of flexibility.In this form of implementation, the nonwoven fabrics of all types can further obtain the nonwoven fabrics that the high dipping of flexibility is adjusted by using adhesive spots in conjunction with formation.In addition, as binding agent, preferably use polyurethanes resin, acrylic resin.

(form of implementation 6)

Shown profile among Fig. 5 according to the PTC heater of form of implementation 6.In this form of implementation,, adopt the surface to go up additional foamed resin or the sheet rubber that the convex-concave shape is arranged as flexibility base material (hereinafter referred to as base material) 12.Form electrode 2 and resistance 3 by printing in its surface.In addition, the not shown in the drawings flexibility cladding material that forms thereon.Foamed resin has continuous bubble separately.If be independent bubble, its cross section must form the surface with convex-concave shape, after this can directly use.In addition, if be continuous bubble, the back is adjusted on the surface used by being coated with coating material etc. from the teeth outwards.Foamed resin is for example formed by polyurethane or olefin hydrocarbons thermoplasticity elastic body foam etc.Under the situation for sheet rubber, for example, can form the convex-concave shape from the teeth outwards by additional woven design when being shaped.

By above-mentioned any structure, make the cross section of printing from the teeth outwards, the dry electrode 2 that forms, resistance 3 form the convex-concave shape, seem the state that dwindles.Therefore, electrode 2, PTC resistance specific elongation stress have surplus.Thus, even under the situation of base material 12 elongations, also can reduce the stress that is applied on electrode 2 and the resistance 3.In addition, in this form of implementation, 12 pairs of elongations of base material are unrestricted, and therefore, preferred not shown flexibility cladding material has the effect of restriction elongation.

(form of implementation 7)

Fig. 6 A, B are respectively plane graph, the profile of the part opening of form of implementation 7, not shown in the drawings flexibility cladding material.Flexibility base material 13 is that applying resin web 15 forms on the surface of foamed resin 14.Resin web 15 for example is made of the fiber of polyester, polypropylene or polyamide etc.

Constitute by this, the electrode 2 of printing formation and resistance 3 are had surplus by additional convex-concave cross sectional shape to elongation stress from the teeth outwards.In addition, resin web 15 has limited elongation.Electrode 2 and resistance 3 have been protected thus.And by selecting the material of resin web 15, the electrode 2 and the resistance 3 that are formed by printing form impregnated structures, can obtain the strong flexibility PTC foaming body of vibration durability.

In addition, by replacing foamed resin 14 also can obtain same effect with sheet rubber.

(form of implementation 8)

Fig. 7 is the profile according to the PTC heater of form of implementation 8.Flexibility cladding material (hereinafter referred to as cladding material) 16 is coated with formation by adopting polyester resin class latex.Cladding material 16 has the caking property with flexibility base material 1.Other formation is the same with form of implementation 4.Perhaps also applicable in embodiment 1-3.

In this form of implementation, be coated with by adopting resinae latex, electrode 2 and resistance 3 are intercepted with outside atmosphere.As the solvent of resinae latex, in most cases adopt water, the drying of resinae latex can or be implemented below it at 100 ℃.Therefore, resistance value takes place and changes in the PTC resistance of manufacturing hardly, has stable ptc characteristics, can obtain to have the flexibility PTC heater of good vibration performance.

(form of implementation 9)

Fig. 8 is the profile according to the PTC heater of form of implementation 9.Flexibility cladding material 17 constitutes by the hot melt film (hereinafter referred to as film) 19 of fitting on polyesters nonwoven fabrics (hereinafter referred to as nonwoven fabrics) 18.Nonwoven fabrics 18 is formed by spun-laced fabric etc.Film 19 is formed by polyesters hot melt film etc.Across film 19, make that flexibility base material 1, electrode 2, resistance 3 and nonwoven fabrics 18 are bonding.The same in the formation of base material 1 and the form of implementation 4 also can have the formation identical with form of implementation 1-3.

By this formation, can obtain the good vibration performance, and electrode 2 and resistance 3 be intercepted the mechanical strength of having added nonwoven fabrics 18 simultaneously on the PTC heater with outside atmosphere by film 19.

(form of implementation 10)

Cross-sectional configuration according to the PTC heater of form of implementation 10 is the same with form of implementation 9.In this form of implementation, replace cladding material 17, adopt the foamed resin that illustrates as base material in the form of implementation 7, perhaps on sheet rubber, be coated with binding agent.Explanation to other structure is the same with form of implementation 9.

By this structure, can obtain the good vibration performance, in electrode 2 and resistance 3 and outside atmosphere obstruct, flexibility, the soft feeling of foamed resin or sheet rubber can be additional to the PTC heater.Particularly under the situation that adopts foamed resin, PTC resistance forms higher adiabatci condition.Therefore, the warm of human body can be felt to be controlled in the proper range, improve the heating temp of PTC resistance simultaneously, can suppress the saturated electric power that is consumed when stable.

(form of implementation 11)

Fig. 9 A, B are respectively plane graph, the profile according to the part opening of the PTC heater of form of implementation 11.In this form of implementation, on whole PTC heater,, concaveconvex shape 20 is set by Carving Machining.So-called Carving Machining, the hot plate that refers to by having convex-concave surface carries out coining, makes cross sectional shape form the processing method of convex-concave shape.In addition, in this form of implementation, flexibility base material 1 also can have printing ink dipping property.That is, the flexible membrane who forms by ethylene-vinyl acetate resinoid, polyurethanes resin, esters resin, ester polyurethane resinoid etc. can be, also base material the same among the form of implementation 1-4 can be.

Constitute by this, in the time of can be to PTC heater additional flexibility, elongation be had surplus.In addition, form the convex-concave shape, can make the resistance value of PTC resistance stable in early days by machinery or hot mode.

(form of implementation 12)

Figure 10 is the plane graph according to the part opening of the PTC heater of form of implementation 12.In form of implementation 11, added the convex-concave shape by Carving Machining, but what adopt is loop bonding (seam) processing in this form of implementation.Other formations are the same with form of implementation 11.The same with Carving Machining, by additional loop bonding processing part 21, to PTC heater additional flexibility.In addition, limited the elongation of PTC heater, so protected electrode 2 and resistance 3 by loop bonding processing part 21.In addition,, cover, electrode 2 and resistance 3 are protected, make it not influenced by outside atmosphere by adopting the resinae latex described in the form of implementation 8 though make seam open by loop bonding processing.

As mentioned above, according to form of implementation 1-5,8-12, the part of electrode 2 and resistance 3 is immersed in the flexibility base material is configured.In addition, according to form of implementation 6,7, make the cross section of electrode 2 and resistance 3 form concaveconvex shape.Therefore, can improve vibration durability, obtain the flexibility PTC heater of stabilizing quality.

In addition, by adopting the nonwoven fabrics that floods adjustment as the flexibility base material, the ptc characteristics that can provide performance to have reproducibility can suppress the flexibility PTC heater that useless cost improves.

(form of implementation 13)

Figure 11 A has shown the plane graph of part opening of the PTC heater of this form of implementation, and Figure 11 B is the profile of X-Y position.Flexibility base material (hereinafter referred to as base material) 1 has flooded the solution of printing ink etc.For example, be the base material that is provided with peristome 32 on the polyester non-woven fabric that forms of long fibre.In addition, resistance 3 is not comprehensive setting, but is cut apart setting, is provided with peristome 32 between resistance 3.Peristome 32 can perforation making on base material 1 in advance.32 places do not dispose resistance 3 at peristome, with peristome 32 as crooked position, to PTC heater additional flexibility.In addition, this PTC heater is being applicable under the situation of seat, can improving the seat tactility and the flexibility in following time.In addition, by with the combination of peltier-element etc., blow out cold wind by peristome 32, can increase comfortableness.

In addition, in this form of implementation, also can be to the main electrode of electrode 2 incision otch, perhaps implement the Carving Machining the same with form of implementation 11 at the electrode 2 that is positioned at peristome 32 crooked positions.Thus, can further improve flexibility.

(form of implementation 14)

In form of implementation 14 of the present invention, adopt Figure 12 to describe.The orthogonal fiber nonwoven fabrics (hereinafter referred to as nonwoven fabrics) 36 that constitutes the flexibility base material is formed by polyester fiber, has a plurality of peristomes 37.Corresponding to the fiber width of nonwoven fabrics 36, on nonwoven fabrics 36, form comb poles (hereinafter referred to as electrode) 2 and PTC resistance (hereinafter referred to as resistance) 3 by printing.Electrode 2 and resistance 3 are to be immersed in the intrastitial state of nonwoven fabrics 36, and promptly the state with one one velamen coating of polyester long fibre forms.Thus, nonwoven fabrics 36 forms the extremely excellent structure of vibration durability, constitutes the strong base material of hot strength.In addition, the conduction of the main electrode 38 of preferred electrode 2 paste pickup is more than auxiliary electrode 39.Under the situation of base material of no liquid dipping property that is polyester film etc.,, need to strengthen the printing width of main electrode 2 for the current potential that prevents main electrode 2 descends.In this form of implementation, by the pickup of increase conduction paste, and do not widen printing width, can prevent that current potential from descending.In addition, not shown in the drawings flexibility cladding material.

3 of auxiliary electrode 39 and resistance need necessary minimal coating weight just enough.Therefore, preferred impregnating resin latex is also dry in right amount on the printing of nonwoven fabrics 36 in advance, and pickup is regulated.As mentioned above, many more to the pickup of base material, vibration durability improves more.But pickup increases more, and conduction is stuck with paste and the coating weight of PTC printing ink increases more, makes cost improve.In addition, the coating deviation becomes big, has the problem of the ptc characteristics that is difficult to bring into play reproducibility.Therefore, for guaranteeing suitable coating weight, preferably regulate pickup.At this, can adopt mode illustrated in form of implementation 2 and 3.

In addition, in the bonding of nonwoven fabrics 36 crossover sites, preferably implement by the thermal recovery binding agent.When adopting heat to carry out clinkering, this position thickness increases, and is configured as one, has promoted crystallization simultaneously, thereby fixing.When adopting binding agent, adopt binding agent with flexibility, for example polyurethanes, acrylic copolymer etc. can be brought into play the flexibility of nonwoven fabrics 36 raw material itself.Under situation, need not binding agent for the base material with self-adhesive power of cotton fiber etc.Under the situation that adopts this fiber material, by on planar orthogonal direction, disposing fiber in advance, after this adopt current expansion fiber spacing, peristome is set, can make nonwoven fabrics 36 thus.

(form of implementation 15)

In form of implementation 15 of the present invention, adopt Figure 13 to describe.Be that with the difference of Figure 12 the main electrode 38 among Figure 12 is made of the metal conductive wire 40 of copper cash etc., produces the nonwoven fabrics 36 that is assembled with conductor wire 40.Conductor wire 40 and stick with paste the auxiliary electrode 39 forms by conduction and carry out conducting by the fixing conduction paste of dipping in the nonwoven fabrics around the conductor wire 40.

As mentioned above, the main electrode 38 in the form of implementation 14 is to be arranged so that current potential can not take place on its length direction to be reduced.But, because being stuck with paste by silver, main electrode 38 constitutes, and it is big more therefore to heat size, and it is high more that cost becomes.Therefore, by main electrode being changed into conductor wire 40,, also more cheap even under the larger-size situation of heating.

In addition, this structure with a plurality of peristomes 37 when adopt covering whole cladding material, for example resin film etc., can not damaged flexibility yet.Therefore, if the resinae coating material of employing resin latex etc., is capped around electrode 2 and the resistance 3 under the state of residual peristome 37 as the flexibility cladding material.Thus, electrode 2, resistance 3 can be isolated with extraneous gas, reliability improves.

As the resinae coating material, can adopt the latex of acrylic resin, polyurethanes resin, amide-type resin, esters resin, ester polyurethane resinoid, silicon resinoid etc.Because these latex are dispersed in resinous principle emulsification in water or the organic solvent and form, therefore good with the caking property of polyester non-woven fabric, and attached and its flexibility, its dried product also has thermal endurance, and PTC printing ink is had no adverse effect.Particularly polyurethanes, ester class, silicon resinoid latex have the effect of improving ptc characteristics, are effective.

In addition, in this form of implementation, the flexibility base material also needn't only limit to long stapled polyester non-woven fabric.The natural fiber of the synthetic fibers of polypropylene or nylon etc. or cotton etc. also can.

(form of implementation 16)

Adopt Figure 14 A for form of implementation 16 of the present invention, B describes.Be that with the difference of Figure 13 the mode with thermo-contact on the PTC heater disposes the moisture absorption body 41 with peristome.

Moisture absorption body 41 is moisture absorption under the situation more than the adsorption equilibrium vapour pressure in the water in air partial vapour pressure.In addition, if temperature rises, then emit steam and regenerate.In this form of implementation, when regeneration moisture absorption body 41, adopt the PTC heater.Be under the state of regenerating moisture absorption once more at moisture absorption body 41.And the steam that regeneration the time is emitted utilizes when humidification.Thus, as dehumidifying, humidification apparatus, the PTC heater can be utilized as its regeneration thermal source.By utilizing the PTC heater, its heating temp is set at the regeneration temperature of moisture absorption body 41.In this way,, therefore can improve the reliability of moisture absorption body 41, safe dehumidifying, humidification apparatus is provided owing to can not make moisture absorption body 41 overheated.In the time of in the seat that this dehumidifying, humidification apparatus is mounted to automotive seat etc., except having the heating effect the same, also can remove steam, and can regenerate to this effect repeatedly with form of implementation 13 to 15.

Moisture absorption body 41 is by making water-absorbing resins carry out imbibition, drying with solution state on the heat-resistant nonwovens of peristome and after adhering to water-absorbing resins on the nonwoven fabrics, absorb the hygroscopic agent aqueous solution and dry the acquisition on water-absorbing resins having.Heat-resistant nonwovens is made by the material with absorbency of polyester etc.Hygroscopic agent is formed by the inorganic salts of calcium chloride etc.

As general hygroscopic agent, known have silica gel, zeolite, a calcium chloride etc.The hygroscopic capacity maximum of silica gel, zeolite can reach about 50% of deadweight, and is relative therewith, and the inorganic salts maximum of calcium chloride etc. can reach 3 times of deadweight.Although inorganic salts has strong like this hygroscopic capacity, not too to use, its reason is owing to moisture absorption forms liquid.But inorganic salts can even moisture absorption forms liquid, also can remain solid state by water-absorbing resins by remaining in the water-absorbing resins.

As water-absorbing resins, preferably adopt any resin of polyvinyl alcohol analog copolymer, polyurethanes copolymer, polyalkylene oxide analog copolymer etc.The general acrylic copolymer that is adopted absorbs water, but absorbs the electrolyte aqueous solution as the inorganic salts aqueous solution hardly.Even above-mentioned copolymer also absorbs fully to electrolyte aqueous solution.In addition, as inorganic salts,, therefore preferred owing to lithium chloride, calcium chloride etc. have stronger moisture absorption.In addition, also lithium chloride, calcium chloride etc. can be used in combination.By with these water-absorbing resins and inorganic salts combination, can obtain the hygroscopic capacity of 1.5 times of its deadweights.

In addition, in other form of implementation, have at PTC resistance under the situation of peristome, also can make it constitute the same with this form of implementation moisture absorption body 41 that has.

(form of implementation 17)

Plane graph and profile that Figure 15 A, B have shown respectively according to the PTC heater part opening of form of implementation 17.The netted base material of flexibility (hereinafter referred to as base material) 51 has deformable peristome, and has printing ink dipping property.Base material 51 is formed by the material of cotton or polyester etc., and is netted.Flexibility support base material (hereinafter referred to as base material) 52 has not through performance of printing ink, passes through hot melt or bonding and combination on base material.Base material 52 has as the function of the barrier material that does not pass through printing ink and the function that forms PTC heater skeleton.In addition, base material 51 and base material 52 form the flexibility base material together.Base material 52 be on the foaming body of spun-laced fabric (nonwoven fabrics), stockinette material or polyurathamc etc., flood formation such as resin latex for example, applied and made material of printing ink by handling.The order amount of paying (weight per unit area) of spun-laced fabric is little, even dipping printing ink can not fixedly be planar, and forms the structure that keeps dipping printing ink along the fiber grain.The stockinette material is behind dipping rubber-like latex on the spun-laced fabric, by the material that interweaves, drying forms.By with this base material 51 and base material 52 combinations, constitute comb poles (hereinafter referred to as electrode) 2, PTC resistance (hereinafter referred to as resistance) 3 and flexibility cladding material (hereinafter referred to as cladding material) 4 thereon.For electrode 2, resistance 3, the same with form of implementation 1.Cladding material 4 is for example the same with form of implementation 8, is formed by the dry film of resin latex etc.

In this form of implementation, be to dispose base material 52 in the bottom of the base material 51 that is printed with electrode 2 and resistance 3.As the raw material of base material 51, though adopt polyester or cotton or the blending product of the two, material itself has the to a certain degree printing ink dipping property of difference.Polyester is an oleophylic, and cotton is hydrophilic.Therefore, independent base material 51 can make printing ink leak.Base material 52 can prevent that this printing ink from leaking, and improves silk screen printing.In addition, ptc characteristics is mainly produced by the resistance 3 that keeps being immersed in the base material 51.

In addition, correspondingly with this net-like pattern on base material 51 mainly print electrode 2 and resistance 3, in base material 51, make electrode 2 and resistance 3 form the state that is keeping with 3 dimension shapes appropriateness dippings.Therefore, can give play to the flexibility the same, even base material 51 is being applied as the state of elongation simultaneously, because the distortion of netted peristome makes the variation of resistance value be limited in the Min. with form of implementation 1.As in the prior art, because that electrode 2 and resistance 3 are printed as is plane, therefore not only can not give play to flexibility, and for example when 5% elongation strain, resistance value 1 order of magnitude that rises.Relative therewith, according to the PTC heater of this form of implementation, when 5% elongation strain, resistance change is suppressed in 30%.

In addition,, adopt the spun-laced fabric or the foamed resin that keep dipping printing ink with 3 dimension shapes, form printing ink not by layer as base material 52.By this structure, the conduction by base material 51 is stuck with paste or PTC printing ink does not form planarly, but disperses keeping with 3 dimension shapes.By this structure, the suffered influence of ptc characteristics of the PTC printing ink that dipping in the base material 52 can kept is suppressed to minimum, can keep flexibility simultaneously.

At this, the implication of the deformability peristome of base material 51 is described.

Even from being cancellate netted in appearance, but comprise constitute this netted fiber be relaxed state or for having the state of 3 dimension bonding points.Therefore, so netted base material extends easily by the distortion of peristome, and has aeolotropic when elongation.

When on auto use chair, being suitable for the PTC heater, requiring it on the Width of seat, to extend, and do not require relatively that therewith it extends on depth direction.This is owing to have such characteristic as the leather or the fabric itself of the cladding material of seat, and when the PTC heater does not have than its bigger flexibility, will produce the discomfort of support etc. when being present.Therefore the flexibility PTC heater of this form of implementation satisfies this condition owing to adopt the base material 51 with above-mentioned character.In addition, the shape of opening portion is not defined as square, can be the arbitrary shape of circle or ellipse etc. yet.Wherein the peristome shape is preferably formed and is diamond shape.By this structure, with respect to elongation strain, electrode 2, resistance 3 least are subjected to stress influence, because the netted distortion of diamond shape has realized elongation in appearance, have therefore improved the stability of resistance value.

At this, the conduction of electrode 2 and resistance 3 is stuck with paste or printing ink adheres on every side or with the state that interweaves at the bonding point place attached to lax fiber.Therefore, when peristome is out of shape, keep bonding easily between mutually attached to the material of formation electrode 2 on the fiber and resistance 3.That is, there is the gap in the base material 51 that constitutes of the spun-laced fabric that is for example formed by blend fabric cotton or cotton and polyester and is relaxed state between fiber.Electrode 2 and resistance 3 in this printing and configuration are not membranaceous, but to keep gap and lax state to form printed article.Thus, applying under the situation of elongation strain, electrode 2 and resistance 3 self do not extend along with network structure, and by its anamorphic stretching.

For vibration durability or to the durable reliability aspect of the outside deterioration factor of oxygen etc., the same with form of implementation 1 is good.

In addition, base material 51 and base material 52 are the hot melt knot property film that adopts the material of polyurethane or polyester etc. to form, caking property nonwoven fabrics (bonding core) or fit with binding agent.By this structure, can simply base material 51 and base material 52 be engaged.Therefore base material 51 is netted, even when adopting hot melt knot property film, must form and is not comprehensively but the bond state of part.That is, these materials have the bonding point with the corresponding part of net-like pattern of base material 51, therefore do not damage flexibility.In addition, by adopting caking property nonwoven fabrics or binding material to carry out further to increase flexibility under the situation of part bonding.

In addition, the printing ink of base material 52 is not by adopting the resinae coating material to form top layer film shape, perhaps making by attaching hot melt knot film by layer.By this structure, can be specifically and easily form printing ink by the layer.As the resinae coating material, preferred polyester resinoid, acrylonitrile-butadiene rubber resinoid, polyester-polyurethane esters resin, styrene butadiene rubbers resinoid, ether-based polyurethane resinoid, polyurethanes resin etc.The compatibility of these resins and conductive paste and PTC printing ink is good, can give play to the own ptc characteristics that PTC resistance has.On the other hand, the remarkable deterioration ptc characteristics of a part of resinae coating material of propylene class or silicon class etc.

In addition, to need only required minimal coating weight just enough for conductive paste and PTC printing ink.Therefore, preferably regulate pickup on the base material 51 by the mode of form of implementation 2,3 in advance.

(form of implementation 18)

Figure 16 is the plane graph according to the part opening of the PTC heater of this form of implementation 18.The netted base material of flexibility (hereinafter referred to as base material) the 56th, the orthogonal fiber type nonwoven fabrics that the polyester long fibre is formed carry out with the biasing shape that scale (cutting sth. askew) forms.Thereby peristome has diamond shape.Structure in addition is the same with form of implementation 17.In addition, have the peristome of fine square shape, be included into the category of netted base material at this used orthogonal fiber type nonwoven fabrics.

Even be orthogonal fiber type nonwoven fabrics such at the base material that is not having the elongation allowance vertically, in a lateral direction, this structure by the operation of biasing shape scale, also can be guaranteed elongation.Orthogonal fiber type nonwoven fabrics has the peristome of fine square shape, by the operation of biasing shape scale, the peristome shape can be formed diamond shape.It is transversely being applied under the situation of elongation, and elongation strain does not take place in electrode 2 and resistance 3 that dipping is keeping yet, and base material 56 distortion in appearance, performance elongation effect.Adopting under the situation that lacks netted base material printing ink dipping property, that do not form 3 dimension grid electrodes 2 and resistance 3, on framework, form the grid of electrode 2 and resistance 3 attached to netted base material.Even in this case, the structure of the base material 56 by being suitable for this form of implementation, the resistance change in the time of can be with 5% elongation strain is suppressed in 30%.In addition, under the situation that adopts the described netted base material of flexibility with printing ink dipping property of form of implementation 17, the variation of resistance value can be suppressed in about 10%.

(form of implementation 19)

Figure 17 is the profile according to the PTC heater of this form of implementation 19.Be with the difference of Figure 15 B in the form of implementation 17, the elongation limiting material 57 of the main electrode elongation (vertically) of restriction electrode 2 is set below flexibility support base material 52 at least.Elongation limiting material 57 for example is the resin web of braid shape etc., as elongation control assembly performance function.Because the main electrode of electrode 2 is supplied with certain current potential to the branch electrode, if the therefore potential change at this position is difficult to then to realize that the heating of the homogeneous of PTC heater distributes.For this reason, need and to be limited in the Min. owing to the resistance change that the main electrode elongation strain causes.Under elongation limiting material 57 situation about constituting by braid shape resin web, by weaving direction to vertically, transversely elongation regulates.Thus, the longitudinal tensile strain of main electrode is limited in 2%, the longitudinal tensile strain of branch electrode is limited in 5%, adopt base material 51 to make resistance value stable, on the other hand, the undercapacity of base material 51 is remedied, can obtain the strong flexibility PTC heater of softness and fracture strength.In addition, the numerical value of above-mentioned elongation is the guarantee value that extends in vertical, the horizontal practicality of leather, if satisfy this value, then can guarantee the flexibility in the practicality.In addition, except with the resin web of braid shape as elongation limiting material 57, silk can also be sewed up, implement sewing processing.

As flexibility cladding material 4, also can adopt the nonwoven fabrics that is impregnated with the resinae coating material.Particularly, can be by after once property ground bond with hot melt knot material or binding material on electrode 2, the resistance 3, coating resin class coating material is produced the coated film of homogeneous.By this structure, can pass through nonwoven fabrics, regulate the coating weight of resinae coating material.In addition, according to the kind of resin-coated material, its comparative electrode 2 and resistance 3 coating performances are poor sometimes, are difficult to produce uniformly and film.In this case, by making between it, can obtain to film uniformly across nonwoven fabrics.In addition, as the kind of resinae coating material, can be used alone or in combination the flexibility support base material.

(form of implementation 20)

Figure 18 is the profile according to the PTC heater of the invention process form 20.It is with difference according to Figure 15 B of form of implementation 17, adopts leather 58 as the flexibility cladding material.For example have close-burning resinae coating material by employing, electrode 2 and resistance 3 directly bond on leather 58.By this structure, can make resistance 3 and leather 58 form the state of thermo-contact, the heat that resistance 3 sends is sent to leather 58 well by the heat efficiency.Therefore, can obtain fast heat, the high flexibility PTC heater of province's energy.In addition and since can with leather 58 integrated processing, therefore can omit installation to seat or handle.

In addition, also can adopt artificial leather to replace leather 58.

(form of implementation 21)

Figure 19 A, B are respectively plane graph and the profile according to the part opening of the PTC heater of form of implementation 21.Difference between this form of implementation and the form of implementation 17 is that the configuration section of resistance 3 is provided with through hole 59.By through hole 59 is set, can avoid incidental voltage concentration phenomenon on the part of resistance 3 on the configuration section of resistance 3.In addition,, therefore can prevent incidental steam when being close to use, obtain to have the flexibility PTC heater of comfortable tactility with human body owing to can air be moved by through hole 59.In addition, through hole 59 around for example can cover by resinae coating material etc.

(form of implementation 22)

Figure 19 A, B are respectively according to the plane graph of the part opening of the PTC heater of form of implementation 22 and the profile of portion of terminal.According to the structure that the PTC heater of this form of implementation is had, be on PTC heater, portion of terminal 66 to be set according to form of implementation 17.Portion of terminal 66 is that the conductivity thin material (hereinafter referred to as thin material) 67 that adopts conductive adhesive (hereinafter referred to as binding agent) 68 to be electrically connected Copper Foils etc. on the end of comb poles (hereinafter referred to as electrode) 2 forms.In addition, on the other end of thin material 67, be connected with lead 70 by soldering 69.In addition, portion of terminal 66, electrode 2, PTC resistance (hereinafter referred to as resistance) 3 around be covered with flexibility cladding material 4.Other structure is the same with form of implementation 17, has therefore omitted its explanation.

For example, by making silver stick with paste on the dry electrode 2 that forms directly welding lead.Therefore,, form terminal part 66, then with thin material 67 and lead 70 welding in case the end of thin material 67 with electrode 2 bondd by binding agent 68.In this way, electrode 2 and lead 70 are electrically connected.At this moment, by adopting the netted base material of flexibility (hereinafter referred to as base material) 51, when formation electrode 2 was immersed in the base material 51, binding agent 68 invaded the structure in its peristome.In addition, make binding agent 68 and thin material 67 planar bondings.By this structure, except have with form of implementation 17 described effects, also electrode 2 and lead 70 firmly can be electrically connected.In addition, the making of portion of terminal 66 can be carried out after producing electrode 2 and resistance 3.Therefore,, portion of terminal 66 needn't be made, terminal can be only on qualified product, made existing under the underproof situation of printing.In addition, the cladding material 4 with gas barrier property and water proofing property not only is covered with electrode 2, resistance 3, and be covered with terminal part 66 around.Therefore can prevent effectively that it from contacting with extraneous gas as the oxygen of deterioration factor, steam, moisture etc., can obtain the high PTC heater of reliability.

In addition, preferably on a surface of the Copper Foil that uses as thin material 67, carry out the asperities processing.Thus, by by the face of asperitiesization, make binding agent 68 and thin material 67 bond more firmly.Further preferably on the face beyond the adhesive surface, carry out Nickel Plating Treatment.By Nickel Plating Treatment, can improve the corrosion resistance of thin material 67.

In addition, the portion of terminal in this form of implementation 66 also is suitable for constituting when being electrically connected in other form of implementation and uses.

(form of implementation 23)

Figure 21 is the plane graph according to the part opening of the PTC heater of form of implementation 23.According to the PTC heater of this form of implementation, the wire netting that the copper that conductivity thin material 71 has adopted copper or carried out Nickel Plating Treatment forms.In addition, thin material 71 has through hole 72.Basic structure in addition is identical with form of implementation 22.

By this structure, make conductive adhesive 68 be in the inside of through hole 72.Therefore, the structure that binding agent 68 and thin material 71 form as one, contact area is bigger.Make thus to be electrically connected firmly, and improve mechanical strength.

In addition, as thin material 71, the also available Copper Foil that mechanically is provided with through hole replaces wire netting.

(form of implementation 24)

Figure 22 is the plane graph according to the part opening of the PTC heater of form of implementation 24.In this form of implementation, the fixing conductivity thin material 67 on base material 51 of the adhesive method by bonding or stitching etc. in advance prints electrode 2 in overlapping mode on the end of thin material 67, electrode 2 and thin material 67 are electrically connected.

By this structure, can not adopt conductive adhesive, electrode 2 and thin material 67 are electrically connected.Therefore, can low-cost production's portion of terminal 66.Structure in addition is identical with form of implementation 22.

In addition, thin material 67 is by caking property nonwoven fabrics with peristome and base material 51 clampings, and is fixing by the hot melt knot, also can wear out the caking property nonwoven fabrics and make its fusion when lead 70 is installed, and welds.By this structure, when making portion of terminal 66, by fixing thin material 67, the raising operability.In addition, when adopting coating material, can produce filming of homogeneous as the flexibility cladding material.In addition, also the material with through hole described in the form of implementation 23 can be used as thin material 67.

(form of implementation 25)

Figure 23 A, B are respectively plane graph and the profile according to the part opening of the PTC heater of form of implementation 25.In the drawings, the surface from electrode 2 is provided with the through hole that connects the netted base material 51 of flexibility, flexibility support base material (hereinafter referred to as base material) 73.Then,, electrode 2 and thin material 67 are riveted, be electrically connected thus by grommets 74 by this through hole.In addition, base material 73 has the retractility that is formed by elasticity material.Other structure is identical with form of implementation 22.

By this structure, because base material 73 has retractility, and electrode 2 and thin material 67 be always maintained under the state of crimping, make be electrically connected stable.

In addition, although omit in the drawings, the flexibility cladding material not only covers electrode 2, resistance 3, and will cover around the grommets 74.

(form of implementation 26)

Figure 24 is the profile according to the portion of terminal of the PTC heater of the invention process form 26.In this form of implementation, with base material 51 and base material 52 bondings the time, make thin material 67 in advance between base material 51 and base material 52 and in the position of printing electrode 2 end, fix.Electrode 2 is that the peristome by base material 51 is bonded on the thin material 67 and makes.In addition, lead 70 is worn out base material 51 and fusion, installs by welding.Structure in addition is identical with form of implementation 24.

When making portion of terminal 66, when bonding substrates 51 and base material 52, just finish the fixing of thin material 67, so operability improves by this structure.In addition, can produce firm and practical portion of terminal 66.

In addition, can adopt Copper Foil, have any in the Copper Foil, wire netting of through hole as thin material 67.No matter how thick these materials are, also can be absorbed by base material 52, therefore can stably carry out silk screen printing.

(form of implementation 27)

Figure 25 A, B are respectively plane graph and the profile according to the part opening of the PTC heater of form of implementation 27.According to the PTC heater of this form of implementation, has the structure that elongation control assembly (hereinafter referred to as parts) 86 is set on the PTC of form of implementation 17 heater.Parts 86 are bonded on the netted base material of flexibility (hereinafter referred to as base material) 51 by binding agent etc., the elongation of restriction base material 51.For example, form by mesh grid 88 grades.In addition, also can adopt flexibility barrier material (hereinafter referred to as barrier material) 82 to replace flexibility support base material 52.Barrier material 82 is combined on the base material 51 by modes such as hot melt knot or bondings, on base material 51 with membranaceous dipping and maintenance.In this form of implementation, base material 51 plays a role as PTC heater skeleton.Base material 51 and base material 82 form the flexibility base material.In addition, barrier material 82 has the member 86 as hot melt knot film concurrently.Also mesh grid 88 and base material 51 can be carried out the hot melt knot.Other structure is the same with form of implementation 17, has omitted its explanation at this.

According to the PTC heater of this form of implementation, can reach and the same effect described in the form of implementation 17.In addition, the elongation that 86 pairs of members are printed with the base material 51 of comb poles (hereinafter referred to as electrode) 2 and PTC resistance (hereinafter referred to as resistance) 3 limits, it can be elongated to more than the predetermined elongation, therefore can obtain the higher flexibility PTC heater of reliability.

In addition, as barrier material 82, the preferred hot melt knot film that adopts has at least at the conductive paste of making electrode 2 or makes the baking temperature of PTC printing ink of resistance 3 or the thermal endurance more than it.Barrier material 82 mesh grid 88 that on base material 51, bonds.Conductive paste and the drying process of PTC printing ink after silk screen printing were implemented 30 minutes at 150 ℃ respectively, improved production performance thus.These materials do not fuse under this temperature conditions, can keep shape.As this hot melt knot film, polyesters and polyurethanes resin are arranged.For example be ether type, carboxyl type etc., have the polyurethane resin film of 170-180 ℃ of fusing point.This polyurethane resin film passes through between the hot-rolling by making it between base material 51 and mesh grid 88, by barrier material 82 bonding substrates 51 and mesh grid 88.Barrier material 82 forms on base material 51 in the film, and a part of hot melt knot forms dipping, hold mode in base material 51.In addition, polyurethane resin film flexibility is abundant, gives PTC heater flexibility.

In addition, barrier material 82 is not limited to hot melt knot film.Can be used alone or in combination the latex of polyester resin as the resinae coating material, polyacrylic acid resinoid, acrylonitrile-butadiene class rubber, polyester-polyurethane resinoid, styrene-butadiene class rubber, polyurethanes resin etc.These latex have flexibility, and can not cause adverse effect to ptc characteristics.In addition, can regulate the printing ink saturating machine of base material 51 more effectively.In addition, also can and with hot melt knot film and resinae coating material.

In addition, as flexibility cladding material 4, preferred adopt with electrode 2 and resistance 3 contacted sides on the film of sandwich construction of configuration polyesters hot melt knot film.For example adopt the sandwich construction film that stacked polyurethanes resin or ethylene-vinyl acetate resinoid etc. form on polyesters hot melt knot film.Thus, can obtain to have flexibility, gases such as air, steam are had barrier properties the high flexibility PTC resistance of reliability that resistance to water improves.This structure is also applicable to other form of implementation.

In addition, preferably fit in advance on the printing position of the main electrode 2A of the electrode 2 thermal endurance hot melt knot film of polyurethane etc. prints then.

Main electrode 2A is designed to will supply with as much as possible the current potential of electrode 2B and remains equipotential.But, also having because elongation strain causes some resistance change, its result produces electric potential gradient, may cause the uneven situation of heating.Therefore, by with main electrode 2A vertically be configured to not take place as much as possible in the vertical elongation strain, when being limited in elongation in 3% by elongation limiting member 86, resistance change can be suppressed in 30%.This value can be thought the practical value that goes up no problem.In addition, by on the printing position of main electrode 2A, attaching thermal endurance hot adhesion film,, resistance change can be suppressed in 15% by cyclic extension.Can obtain like this because the PTC heater that resistance change is little, long-term reliability is high that this elongation strain caused.This structure also is applicable to other form of implementation.

(form of implementation 28)

Figure 26 is the profile according to the PTC heater of the invention process form 28.

In PTC heater, form elongation limiting member (hereinafter referred to as member) 86 by bonding member (hereinafter referred to as member) 87 and mesh grid 88 according to this form of implementation.In addition, a side of having printed electrode 2 and resistance 3 at base material 51 is provided with member 86.Member 87 is formed by the hot adhesion film of for example polyester etc.Member 87 applying mesh grid 88 on base material 51 forms.Basic structure in addition is identical with form of implementation 27.

So-called mesh grid refers to polyester fiber is woven into predetermined shape (braid), can be made into the product with various peristome shapes.In this form of implementation, when being used for member 86, realize elongation owing to can pass through the displacement of diamond shape, therefore preferred.By braiding, also can have the elongation restriction, so that elongation can be more than predetermined elongation.On the other hand, through under the state of longitudinal direction, the transverse fiber that interweaves on this fiber can be produced various patterns to fabric thus at fiber.The peristome of this fabric mostly is cuboid greatly and has concave and convex plane, and perhaps fiber itself has burr mostly.Therefore, under the situation that fabric is used as base material 51, there is difficult point at the silk screen printing aspect of performance.On the other hand, mesh grid is by weaving the fine fibre that carrot-free resin is made, and makes between fiber mutually smooth and given play to flexibility.Therefore, few at concave-convex surface, compare printing ink dipping property shortage with fabric, thus aspect silk screen printing than fabric excellence.Therefore, but mesh grid also double as be that base material 51 uses.In this case, designs simplification can be reduced cost.

In this structure, member 86 mesh grid 88 that on base material 51, bonds, the mechanical property of additional mesh grid 88 on base material 51 thus.Mesh grid 88 also can select elongation in the vertical little, the product that elongation in the horizontal is big.As member 87, can adopt binding material.In this case, by using mesh grid 88, make base material 51 maintain in its allowable elongation, the electrode 2 and the resistance 3 of printing also maintain in the predetermined elongation strain scope on base material 51.

Figure 27 has shown the deformation pattern of base material 51.Because the peristome 51A that this base material 51 also has diamond shape, the fibrous septum is constant, and extends by distortion.In addition, base material 51 and mesh grid 88 also are not limited to the structure that bonds at bonding point.Thus, can obtain the abundant PTC heater of flexibility.

(form of implementation 29)

Figure 28 is the profile according to the PTC heater of form of implementation 29 of the present invention.

In this form of implementation, resistance 3 is printed on the resiliency base material (hereinafter referred to as base material) 89, and this base material 89 has dispersion and remains non-membranaceous printing ink dipping property, the structure that the electrode 2 that is provided with on formation and the base material 51 electrically contacts.In addition, base material 89 has 3 dimension fibrous reticular structures, and the intertwined point of fiber is resin-bonded with the flexibility of acrylic resin or polyurethane resin etc.Yin Shua resistance 3 is not membranaceous thereon, forms the state that disperses, floods, remains in the base material 89.In addition, other structure is identical with form of implementation 27.

In this structure, because therefore electrode 2 and resistance 3 impregnated being arranged in the different base material with flexibility form the heater that is rich in flexibility.In addition, resistance 3 is disperseed to remain non-membranaceous in base material 89, has high resistance value under this state.Thus, even electrically contact with electrode 2, also heating hardly.If make base material 89 compressions in this additional some load, then resistance 3 becomes predetermined resistance value, is energized and generates heat.That is,, can form the structure of only generating heat in the part that applies load by being designed to utilize load certain or more than it to reach predetermined resistance.In addition, resistance 3 has the automatic temperature-adjusting controlled function, therefore can be designed to rich fast hot heater, and the novel heater that can be had fast hot and load detecting function simultaneously.In the time of in using it for the automotive seat heater, when on people's seat, can only make the part heating of the load that has applied this people, can be made into the heater that province can excellent performance.In addition, electrode 2 can be made metal forming, for example is applied to have bigger heating area, in the electric blanket etc.In this case, owing to can only make this position heating by human body, therefore becoming province can the high heater of performance.

(form of implementation 30)

Figure 29 A, B are respectively the plane graph and the profile of the part opening of the PTC heater that shows form of implementation 30.

In this form of implementation, on base material 51, residual peristome 51A and be provided with electrode 2 and the resistance 3 that dipping keeps.That is, the part at peristome 51A is not provided with electrode 2 and resistance 3.Other structure is identical with form of implementation 27.

By this structure, make base material 51 and electrode 2, resistance 3 form integral structures, when can obtain distortion by base material 51 and can realize apparent elongation, because the also extremely excellent heater of the resistance value stability that elongation strain causes.And then the residual peristome 51A that base material 51 is arranged can be made into the novel heater that peristome 51A is used as the through hole that air is passed through.

As concrete manufacture method, at first the hot melt knot has the aqueous solution or the water-disintegrable resin film that hot melt is tied performance on base material 51.This film for example is polyvinyl alcohol or carboxymethyl cellulose.On its back side, form electrode 2 and resistance 3 by printing.After this,, remove film, all flexibility cladding materials 4 that covers on two surfaces by in water, flooding.

When adopting aqueous coating material, can be made into the state of the peristome 51A of residual base material 51 as cladding material 4.In this way, can obtain to be rich in flexibility, the heater of resistance value excellent in stability.In addition, adopting under the situation of flexibility hot melt knot property resin film as cladding material 4, the usable resins filling opening 51A of portion makes.Particularly under the situation that adopts crystalline resin as hot melt knot property resin, the thermal characteristics by the ptc characteristics of giving resistance 3 adds crystalline resin can obtain the novel flexibility PTC heater with ptc characteristics.

In addition, in all forms of implementation, a side of length that all constitutes the main electrode of electrode 2 is configured in the vertical, and a side of the length of branch electrode is configured in transversely.Thus, as a whole, preferred designed flexibility PTC heater extends 0-3% on vertically under the load of 5kgf, when transversely extending 3-10%, and it has 15kgf or its above fracture strength.By this structure, even when for example being arranged in the inside of seat under the human body seat etc., also can obtain to have comfortable tactility, promptly having should gratifyingly take one's seat sense and the high heater of reliability.

In addition, have in the form of implementation of flexibility cladding material, preferably applying mechanical stress, for example under Shen Chang the state flexibility cladding material is set in design.As mentioned above, the flexibility cladding material is formed by resinae coating material and hot melt knot film.By like this flexibility cladding material being applied mechanical stress, can reduce the resistance value of PTC heater, improve ptc characteristics simultaneously.So-called good ptc characteristics refers to bigger with respect to temperature and resistance value rising degree.For example corresponding 20 ℃, the ratio of 50 ℃ resistance value is bigger.After just making, the crystalline resin in the PTC resistance or the orientation of conductive particle are unordered.In contrast, for example when applying elongation, on this direction, produce crystalline orientation, thereby can bring into play the thermal characteristics of resin itself, simultaneously because crystalline orientation thinks that conductive particle also can be orientated phenomenon.But this state is removed by thermal cycle.At this moment, the heater that has extended returns to original size.For keeping this state that improves ptc characteristics, fill flexibility cladding material 4 as resin at the peristome 51A that applies the base material 51 that mechanical stress produces.When base material 51 shrank thus, flexibility cladding material 4 had stoped this shrinkage phenomenon.Thus, become the state that has kept residual mechanical stress, kept good ptc characteristics.Improve ptc characteristics by such mode, when the inferior conduct of situation of for example automotive seat etc. is used near the heater of human body,, therefore have very important significance owing to forced down heating temp.

In addition, as the flexibility cladding material, polyesters hot melt knot property film is excellent aspect long-term reliability.For example, carry out in the heat-resistant experiment of resistance value estimation of stability under 80 ℃ of atmosphere, use under the hot melt knot property film situation in addition, resistance value shows the tendency that reduces.Relative therewith, under the situation that adopts polyesters, during certain, demonstrate the tendency that resistance value descends, but after this, form the pattern that resistance value rises.Be set at during this period heater life-span guaranty period.After adopting this mode to guarantee the life-span, resistance value rises.Show that promptly the end of lifetime fail safe at heater raises, this is very important aspect to heater.

In addition, in whole form of implementation, heating element structure is made by screen printing mode, but also can be suitable for transfer printing mode or ink-jetting style as printing process.In two modes, all different with screen printing mode, can adjust the coating weight of printing ink, as required minimal coating weight, can reduce cost and improve the flexibility of PTC heater.In addition, can also suppress the resistance value deviation.

(form of implementation 31)

Figure 30 A, B are respectively the plane graph and the profile of the part opening of the PTC heater that shows form of implementation 31.

Flexibility fiber base material (hereinafter referred to as base material) 91 has deformable peristome, and has printing ink dipping property.Base material 91 is that the material by cotton or polyester etc. forms, the netted base material of spunbonded type that interweaves and form by current.Flexibility barrier material (hereinafter referred to as barrier material) 82 is combined on the base material 91 by modes such as hot melt knot or bondings, has not through performance of printing ink.In addition, electrode 93 is set on the two ends of Width of short of PTC resistance (hereinafter referred to as resistance) 3.Base material 91 and base material 82 form the flexibility base material.Other structure is identical with form of implementation 17, has therefore omitted its explanation.

By this structure, be formed on the following covering barrier material 82 of base material 91, in a part of base material 91, keep the structure of barrier material 82 simultaneously.So when making electrode 93 and resistance 3, can be when preventing that printing ink from leaking, the dip coated amount of regulating printing ink.In addition, have in employing under the situation of hot melt knot property film as barrier material 82 of the fusing point lower than the baking temperature of electrode 93 and resistance 3, barrier material 82 fuses, remains in the base material 91, and the two forms as one.

In addition, on base material 91, print electrode 93 and resistance 3, be formed on the states that appropriateness dipping in the base material 91 keeps electrodes 93 and resistance 3 corresponding to its peristome pattern.Therefore can keep flexibility,, be suppressed in the Min. by the variation of peristome distortion adjustable resistance value even apply under the state of elongation at base material 91 simultaneously.Figure 31 A has shown the peristome of base material 91 with image, the variation of peristome shape when Figure 31 B has shown distortion with image.Thus, when 5% transverse extension distortion, resistance change can be suppressed in 20%.

In this form of implementation, base material 91 is for example for having the spun bond nonwoven fabric of peristome, and it is formed by cotton or polyester and interweave by current and forms.Base material 91 has gap and lax between fiber, be not membranaceous at electrode 92 and resistance 3 of this printing configuration, forms printed article having under gap or the lax state.Thus, even when applying elongation strain, electrode 92 and resistance 3 self is not also along with the network structure elongation, and is extending by this distortion.This effect is identical with form of implementation 17.

The relation of the dipping of electrode and resistance and vibration durability etc. is identical with form of implementation 17 in base material 91, has therefore omitted its explanation.

In addition, as base material 91, be the netted base material of the peristome that has to a certain degree size at this.But also can use orthogonal fiber type nonwoven fabrics with smaller opening portion.This nonwoven fabrics former state lacks the elongation performance in the horizontal, if but (oblique) scale of moderately setovering can be guaranteed its transverse extension performance.Regardless of different kinds of, in base material 91, have peristome, can with the bonding point limit of barrier material 82 in required Min., thereby keep the flexibility of base material 91.In addition, by the peristome shape is formed deformable shape, can guarantee to extend performance.In addition, this structure provides the level and smooth printing surface that is suitable for printing, and can keep barrier material 82 effectively.As the peristome shape, be more preferably diamond shape.Explanation for this structure is identical with form of implementation 18.

(form of implementation 32)

Figure 32 A, B be respectively the PTC heater that shows form of implementation 32 the part opening plane graph and see profile under the situation of terminal part from the direction of arrow.

Conductivity thin material (hereinafter referred to as thin material) 67 is made of Copper Foil etc., and the asperities processing has been carried out on the surface, therefore bonded flux 69 in advance on the end.With base material 91 and barrier material 82 applyings the time, make thin material 67 mediate settings.Below thin material 67, bond fixing by barrier material 82.Under this state, if from the conductive paste of upper print electrode 93, the peristome that has by base material 91 then, conductive paste contacts with thin material 67.Thus, make electrode 93 and thin material 67 be electrically connected.After this, after resistance 3 is set, cover, make heater with the flexibility cladding material (hereinafter referred to as cladding material) 4 of the hot melt of polyesters knot property film etc.The taking-up of lead 70 is additional solder flux on the end of lead 70, when making cladding material 4 fusions by Welding iron, makes solder flux 69 heating and meltings of the thin material 67 of bottom.Then, at once it is combined with lead 70.The position of combination as resin mold (omitting among the figure), is made portion of terminal 66.Structure in addition is identical with form of implementation 31.

By this structure, have the effect the same with form of implementation 31.In addition, form thin material 67 planar bonding, fixing between base material 91 and barrier material 82 of portion of terminal 66, all intercept around it simultaneously with extraneous gas.Be that the bottom covers barrier material 82, top covers cladding material 4, is covered with the binder course of barrier material 82 and cladding material 4 on every side.Thus, constitute portion of terminal 66 tough and that reliability is high.In addition, by the peristome of base material 91, make electrode 93 and thin material 67 be electrically connected.In addition, owing on thin material 67, form solder flux 69 in advance, therefore thin material 67 is engaged with lead 70.

In addition, the structure of portion of terminal 66 has the same structure with form of implementation 22-26.

(form of implementation 33)

Figure 33 A, B be respectively the PTC heater that shows the invention process form 33 the part opening plane graph and see profile under the situation of terminal part from the direction of arrow.

In this form of implementation, paste flux pattern (hereinafter referred to as pattern) 69A is before forming electrode 93 by printing, prints paste flux and its drying is made in the position that electrode 93 ends are set in advance.After this, print electrode 93 and resistance 3 and dry, flexibility cladding material 4 further is set.With the overlapping position of the electrode 93 of pattern 69A as waveform shape, increased the bonding point of the two, can positively be electrically connected.In addition, other structure is identical with form of implementation 32.

In this structure, pattern 69A and the structures of on base material 91, flooding with electrode 93 the same formation appropriateness.Therefore, pattern 69A is tough.In addition, electrode 93 and pattern 69A, pattern 9A and lead 70 positively are electrically connected respectively.In addition, be to improve the caking property of base material 91 and pattern 69A, also can on the printing surface of the pattern 69A of base material 91, implement the pre-treatment of chemical plating processing etc. in advance.

In addition, when in form of implementation 22-26, being useful in the paste flux pattern in this form of implementation, also can obtain same effect.

In addition,, the hot melt knot property resin film identical can be adopted, in addition, the resinae coating material can also be used with form of implementation 27 as barrier material 82.In addition, also can and with hot melt knot property resin film and resinae coating material.

In addition,, can use the polyesters heat adhesiveness film the same, in addition, can also use sandwich construction with form of implementation 27 as cladding material 4, wherein with polyesters heat adhesiveness film as the innermost layer that contacts with resistance 3 with electrode 93.Perhaps also can fit and use with other nonwoven fabrics.

(form of implementation 34)

Figure 34 A, B be respectively the flexibility PTC heater that shows form of implementation 34 the part opening plane graph and at the profile of X-Y position.Flexibility base material (hereinafter referred to as base material) 102 has the printing ink impermeability.Base material 102 is to squeeze out the film that polyurethane resin forms with the T mould on the fiber base material (hereinafter referred to as base material) 103 that nonwoven fabrics such as jet net-spraying method, spunbonded type form, and its hot melt knot is formed.The material of base material 103 is a polyester.On the face of the film 104 of base material 102, have conductive paste and the dry a pair of comb poles (hereinafter referred to as electrode) 2 that forms by printed silver paste etc.Electrode 2 comprises main electrode 2A and branch electrode 2B respectively, and vertically as one man being configured with the roller coiling direction with base material 103 main electrode 2A.On branch electrode 2B, have by printing PTC printing ink and the dry PTC resistance (hereinafter referred to as resistance) 3 that forms.In addition, adopt flexibility cladding material (hereinafter referred to as cladding material) 116 that electrode 2 and resistance 3 are covered.Cladding material 116 is that the hot melt property tied resin film (hereinafter referred to as film) 114 and fiber base material (hereinafter referred to as base material) 115 hot melts knot with braid etc. of peristome are formed.Cladding material 116 is by the film 104 hot melts knot of film 114 with electrode 2, resistance 3 and base material 102.That is, electrode 2 and resistance 3 is capped on every side fully.In addition, contained base material 115 is to be formed by braid with peristome etc. in cladding material 116, and its surface has concaveconvex structure.Therefore, as shown in figure 34, the face that electrode 2 and resistance 3 and base material 115 join, when hot melt is tied transfer printing the convex-concave structure of base material 115.

As a key element of the flexibility PTC heater of practicality, can enumerate softness and guarantee elongation.As application example, comprise the automotive seat heater that it is assembled in the vehicle-mounted seat and uses.The skin-material of automotive seat will be paid attention to design performance, can be made of natural or synthetic leather or fabric.After this, the mode of joining with the back side with this skin-material disposes the automotive seat heater.In this automotive seat, very importantly under being assembled with the state of heater, there is not the sense of discomfort when taking one's seat.Sense of discomfort described herein comprises very hard sensation and uneven etc.Therefore, as the automotive seat heater, need guarantee to have or flexibility it more than and elongation equal with skin-material.

Be in the natural leather of highest level as skin-material, transversely than easier elongation on vertically.Particularly, under the load of 7.5kgf, vertically the elongation on is about 2%, and elongation transversely is about 5%.This elongation characteristics is the same with people's skin, therefore, as skin-material, adopts the seat of natural leather to have good riding comfort.In addition, synthetic leather and fabric also can imitate it.

In order to realize the elongation characteristics of this vertical and horizontal in the PTC heater, form and configuration direction with base material 103,115 in this form of implementation are provided with.

The base material that uses in base material 102 and the cladding material 116 103,115 is formed by nonwoven fabrics or braid etc., generally is manufactured into the roller shape.This base material 103,115 is gone up to exist it is processed required hot strength to a certain degree at coiling direction (with it as vertically).On the other hand, with vertical quadrature transversely, on as the point-like of spunbonded nonwoven by hot pressing the product of figurationization, have hot strength with vertically same degree.In addition, the current that pass through as spunbonded nonwoven as spun-laced fabric interweave and make and interweave and the nonwoven fabrics of figurationization mutually between the fiber, with vertically on compare, have quite low hot strength in the horizontal.

Adopting nonwoven fabrics or braid etc. as base material 103,115 o'clock thus, base material 103,115 is as in the vertical elongation control assembly performance function.These materials have hot strength to a certain degree on coiling direction.Therefore, with coiling direction as vertical configuration fiber base material 103,115.By such structure, can coincide with the longitudinal tensile strain characteristic of natural leather.Then, by attaching film 104 on base material 103, film 104 is as horizontal elongation control assembly performance function.That is, in base material 103, adopt the nonwoven fabrics of spun-laced fabric etc. or have the netted nonwoven fabrics of peristome.Attaching film 104 then, further form electrode 2 and resistance 3, and additional cover material 116, can increase intensity transversely step by step.By such mode, can obtain to approach the transversely equal elongation characteristics of natural leather.That is, apply flexibly base material 103 original vertically on elongation characteristics, simultaneously to transversely mainly limiting to a certain degree elongation by attaching film 104 or film 114.

In addition, in this form of implementation, the jog 113 that forms on electrode 2 and resistance 3 and base material 115 contacted surfaces is partly brought into play function as elongation strain.That is, in this form of implementation, the structure that electrode of making by coating 2 and resistance 3 do not form even coating, and by inhomogeneous coating, make have distribution, the deformability state.Thus, the mechanical stress that is applied to elongation on electrode 2 and the resistance 3 etc. can be limited in the Min., realize elongation by its distortion.So-called inhomogeneous, refer to the part that setting is not printed, the perhaps local coating weight that increases perhaps makes coated face form male and fomale(M﹠F) etc. by the plane.In this form of implementation, form convex-concave surface by coated face with electrode 2 and resistance 3, compare the surplus that elongation is set with the plane, resistance 3 improves with respect to the resistance value stability of elongation.

In addition, electrode 2 and resistance 3 itself have flexibility, and formation can also be important corresponding to the pattern of elongation.In this form of implementation, in electrode 2 and resistance 3, preferably contain resin or elastomer.That is, in conductive paste that forms these parts or PTC printing ink, add resin or elastomer as adhesive.In addition, as conductive paste, the preferred silver that is combined with carbon black that adopts is stuck with paste.In addition, contained adhesive is preferably the low saturated copolymer polyester resin of crystallinity in the conductive paste.This is that it has flexibility owing to compare with common crystalline polyester.When usually cooperating carbon black, the ratio resistance of conductive paste can increase, but laminar or form the short fiber shape and can prevent to increase than resistance by the shape of silver is formed a part from coccoid, even apply elongation simultaneously, also can the rejection ratio resistance value increase.In addition, by sneaking into carbon black, can suppress the silver migration that produces by DC power supply.

Aforesaid PTC printing ink is prepared in such a way.At first, mixing carbon black in as the ethylene-vinyl acetate copolymer (EVA) of crystalline resin, and carry out chemical crosslinking.Use modified propylene nitrile-butadiene rubber (modification NBR) as adhesive the crushed material that its pulverizing obtains, as dilution, twist with the fingers pressure, make its printing inkization with 3 rollers with high boiling organic solvent.By carrying out chemical crosslinking behind the mixing carbon black in EVA, the cohesive force of EVA and carbon black improves.In addition, the affinity of the adhesive of this crushed material and modification NBR etc. improves.Thus, the resistance 3 of the state that combined by adhesive of the crosslinked crushed material that forms EVA and carbon black.Because adhesive and crosslinked crushed material have flexibility, so resistance 3 is rich in flexibility.In addition, the two thermal expansion is reflected in the ptc characteristics as the EVA of crystalline resin and adhesive, so resistance 3 has the high PTC characteristic.

In addition,, adopt the base material 103 with film 104 bondings respectively as base material 102 and cladding material 116, and engaged will with the base material 115 of the film 114 of base material 103 or film 104 hot melts knot.By this structure, film 104 can prevent that printing ink leaks when printing, improves the intensity of base material 103 and 115 simultaneously.In addition, electrode 2 between film 104 and film 114 and resistance 3 intercept and are sealed with extraneous gas.Thus, can obtain the high PTC heater of long-term reliability.Particularly, as the material of film 104, adopt a kind of or these mixtures of material in polyurethanes, olefines or the styrene analog thermoplastic elastomer.Because this elastomer extends easily, therefore give PTC heater flexibility.In addition, the structure of preferably mixing adhesion resin or forming by stacked elastomer and adhesion resin.Thus, can improve the caking property between electrode 2, resistance 3 and the base material 102, and improve vibration durability.In addition, as the material of film 114, can adopt olefine kind resin.Adhesion resin for example is the polyethylene etc. of the polar group that imported carboxyl or ether etc. in molecular skeleton.Particularly, be maleic anhydride modified or acrylic acid modified polyethylene, the thermoplastic elastomer (TPE) of perhaps same modification etc.

In addition, in this form of implementation, be provided with base material 103,115, but also can only be provided with wherein a kind of as elongation control part performance function.

(form of implementation 35)

Figure 35 A, B be respectively the PTC heater that shows form of implementation 35 the part opening plane graph and at the profile of X-Y position.The PTC heater of this form of implementation replaces base material 103,115, has base material 117,118 respectively.Have the structure the same in addition with form of implementation 34.Base material 117 is to load on 7.5kgf or below it when transverse extension 5%, and the load during longitudinal tensile strain 5% is the fiber base material that 7.5kgf or its above nonwoven fabrics or braid A etc. form.Base material 118 is that load when vertical, transverse extension 5% is all at the fiber base material of 7.5kgf or braid B below it, that have the diamond shape peristome, that extend by distortion etc.

To laterally form than vertical stretchy nonwoven fabrics or braid A etc., the base material 117 of the elongation characteristics on having vertically with vertically, laterally all the film 104 or the film 114 of elongation are fitted on the both direction.Thus, utilize the elongation characteristics transversely of the base material 118 that on vertical, horizontal both direction, extends formation such as low braid B, can realize elongation characteristics equal with natural leather or more than it.Base material 118 will have been given play to flexibility by biasing takes place between the fiber, but utilization here is to hinder this biasing phenomenon by attaching film 114 elongation characteristics is reduced.Thus, as with the heater of Body contact, for example as the automotive seat heater, do not have sense of discomfort in the time of can obtaining to take one's seat, and under the load that repeats, have the PTC heater of strong practicality.

Particularly as the nonwoven fabrics of base material 117, have the jet net-spraying method nonwoven fabrics of peristome or dispose in the vertical under the situation of nonwoven fabrics of continuous fiber in employing, the elongation on can limiting vertically more effectively.Disposed the example of the nonwoven fabrics of continuous fiber in the vertical, for example for adopting hot press printing technology to make vertical continuous fiber hot melt knot at the formed spunbonded nonwoven of spun-laced fabric.Spun-laced fabric is owing to be in the vertical short fiber to be orientated and to interweave to form, therefore originally transversely and vertically all have stretchy character.But, by attaching film 104 thereon, make itself and short fiber bonding that vertically goes up orientation, form as continuous fiber.Therefore, the elongation strengths on making is vertically increased sharply, and becoming is difficult to elongation.On the other hand, be unordered in the orientation of spun bond nonwoven fabric middle short fiber, make short fiber form the hot melt knot with point-like mutually by heat.This is called as hot padding.Under this state, even attaching film 104 can not obtain the such reinforced effects of spun-laced fabric.In this case, by cooperating the intensity of continuous fiber on can strengthening vertically effectively in the vertical.This structure also can obtain better reinforced effects applicable to time in the spun-laced fabric.In addition, also go in the base material 118.

In addition, in this form of implementation, adopt fiber base material 117, on cladding material 116 sides, adopt base material 118, but also can use on the contrary in base material 102 sides.

In addition, the base material 117 that constitutes base material 102 vertically on the main electrode 2A of configured electrodes 2, can improve the reliability of main electrode 2A thus, can obtain the little PTC heater that distributes that generates heat.

(form of implementation 36)

Figure 36 is the plane graph according to the part opening of the PTC heating element structure of the invention process form 36.In this form of implementation, the branch electrode 2C of electrode 2 transversely has a waveform shape base material 102.Structure in addition is identical with form of implementation 34.Branch electrode 2C can easily make by screen printed pattern is made waveform shape.

By this structure, make waveform shape branch electrode 2C mutually between guiding path PTC resistance 3 in be the shortest path, one side and what make diamond shape is oblique.Therefore, the guiding path path that promptly generates heat is lowered with respect to the stress load of elongation.In addition, the branch electrode 2C of waveform shape has allowance for elongation with respect to elongation till waveform forms linearity.Therefore, for being delayed that the stress of the elongation of branch electrode 2C applies.That is, wavy branch electrode 2C is as elongation strain portion performance function.If it is arranged in the scope of transverse extension of base material 102 or cladding material 116, can increase substantially the reliability of an electrode 2C with respect to elongation.

In addition, also can obtain same effect even the structure of branch electrode 2C is applicable in other the form of implementation.

(form of implementation 37)

Figure 37 is the plane graph of demonstration according to the part opening of the PTC heating element structure of the invention process form 37.In this form of implementation, as the sub of resistance 3, pre-soaked PTC printing ink and make its dry PTC resistance corpus fibrosum (hereinafter referred to as corpus fibrosum) 124 that obtains on fiber material 123 with peristome, extending distortion.In addition, electrode 2 and corpus fibrosum 124 are electrically connected in the following way.At first, make the solvent evaporation in forming the conductive paste of electrode 2 and the uncured electrode 2 of drying regime contact with corpus fibrosum 124.After this, it is carried out hot pressing, make and when electrode 2 solidifies corpus fibrosum 124 is carried out the hot melt knot.Other structure is the same with form of implementation 34.

By this structure, by the distortion of corpus fibrosum 124, can under the state that PTC resistance self is increased hardly stress, realize elongation, therefore the resistance change with respect to elongation can be suppressed in the Min..That is, corpus fibrosum 124 is partly brought into play function as elongation strain.

In addition, as the sub of corpus fibrosum 124, also the printed patterns of PTC resistance can be formed the net-like pattern of uncoated part with diamond shape.By this structure, also can obtain to have PTC heater with above-mentioned the same resistance value stability.

(form of implementation 38)

Figure 38 A, B have shown respectively according to the plane graph of the part opening of the flexibility PTC heater of form of implementation 38 with at the profile of X-Y position.In this form of implementation, as the flexibility base material, employing be that the back side is bonded with reticular fibre material flexibility resin film 104, that have peristome (hereinafter referred to as base material) 125.Wherein flood conductive paste and PTC printing ink by making, can form electrode 2, resistance 3 respectively.That is, constitute and form of implementation 17 similar structures.In addition, in Figure 38 A, B, omitted the flexibility cladding material.

Compare with Figure 15 A, the mesh of base material 125 is thicker in the structure of form of implementation 17.Therefore by this structure, except electrode 2, resistance 3 were immersed in the base material 125, electrode 2 and resistance 3 were configured with the state of high concentration, part dipping on base material 125.This uneven distribution is partly brought into play function as the elongation strain described in enforcement form 34.Therefore, it has effect, the effect the same with form of implementation 34-37.

(form of implementation 39)

Figure 39 A, B have shown respectively according to the plane graph of the part opening of the flexibility PTC heater of form of implementation 38 with at the profile of X-Y position.In this form of implementation,, on the film 104 of base material 102, has electrode 2 and resistance 3 having adhesive film 104 formation base materials 102 on the fiber base material of peristome (hereinafter referred to as the base material) 129.That is, in form of implementation 38, use the constituent material of flexibility base material on the contrary.

In this form of implementation, base material 129 is formed by the fiber with peristome, and therefore the same with form of implementation 17, base material 129 is partly brought into play function as elongation strain.Thus, obtain effect, the effect the same with form of implementation 34-38.

In addition, in this form of implementation in used film 104 and the form of implementation 4 used hot melt knot property film 4 different.Hot melt knot property film 8 is that crystallinity height, densification and the firm film by polyester film etc. forms, so is conducted electricity the influence of used solvent in paste and the PTC printing ink hardly.Thus, has barriers function for printing ink etc.On the other hand, even the film in this form of implementation 104 has crystallinity, degree of crystallization is so not high yet.Thereby as film, it is not fine and close, and solvent is immersed in the film 104 easily.In addition, if consider the temperature of conductive paste and PTC ink setting is located at about 130 ℃ to 150 ℃, then will be subjected to the influence of organic solvent at this temperature thin-film 104.Phenomenon is for expanding more generally.

Print electrode 2 and resistance 3 before state under, the film 104 of hot melt knot on base material 129 has and the part of base material 129 hot melts knot and the free part do not tied with base material 129 hot melts.Because base material 129 promotes it is extremely effective for the diffusive evaporation of solvent, therefore seldom be subjected to the influence of the solvent of conductive paste and PTC printing ink with the film 104 at the position of base material 129 hot melts knot.On the other hand, not with the free part of film 104 hot melts knots, described in enforcement form 34, all be subjected to the influence of the solvent of conductive paste and PTC printing ink during till its drying.So-called free part refers to the position suitable with the opening portion of base material 129.For example, producing under the situation about expanding, the electrode 2 and the resistance 3 at this position form the protuberance cross sectional shape.Owing to form protuberance, on the electrode 2 at this position and resistance 3, applied elongation, and to compare with the position of base material 129 hot melts knot, this thickness of filming is thinner.

In addition, generally carry out so-called heat ageing and handle in the PTC heater, remove the thermal migration that adds man-hour, the crystallization degree of perhaps regulating as the crystalline resin of PTC resistance components comes the stable electrical resistance.In addition, also can be undertaken the crystalline resin implementation orientation as the PTC resistance components by the mechanical stress of elongation etc., make conductive particle produce configuration more simultaneously, the mechanical aging that resistance value is reduced is handled.Although the burin-in process process of heat, mechanical aging is different, the result of gained is but very similar.That is, resistance value is stable.In said structure, form protuberance, have by inference and aging same effect by solvent.The product that printing forms on the polyester film face makes resistance value be reduced to about 1/2 by heat ageing, in contrast, the product of said structure have with preliminary phase than near 1/2 resistance value, even also less take place than this higher resistance change by heat ageing.

In addition, this coating thickness heterogeneity performance is partly brought into play function as the elongation strain described in enforcement form 38.

Thus, even by elongation or heat, also can obtain the flexibility PTC heater of resistance value excellent in stability.

In addition, in this form of implementation, the flexibility resin B that film 104 also can the flexibility Resin A of chemical change take place by being subjected to conductive paste and PTC solvent and chemical change do not take place is mixed and to be constituted.

In this form of implementation, be to adopt fiber base material 129 to describe with peristome.As base material 129, adopt fiber denser as spun-laced fabric, when not having the nonwoven fabrics of big peristome, adopting as the film 104 of above-mentioned structure is effective being provided with aspect the inhomogeneity.That is, as the film 104 of above-mentioned structure in, the flexibility Resin A keeps original state, on the other hand, the flexibility resin B expands or by mixing with a part of solvent, change in volume or caking property takes place improve.By this state variation, make to produce inhomogenous crawling phenomenon on electrode 2 and the resistance 3, obtain to have flexibility PTC heater with form of implementation 38 the same effects.

In addition, be mainly resin, can enumerate copolyester, maleic anhydride modified polyethylene, EVA (ethylene-vinyl acetate copolymer), EEA (ethylene-methyl methacrylate ethyl ester copolymer) etc. particularly with functional group as the flexibility Resin A.

As the flexibility resin B, be mainly the resin of high crystalline, can enumerate for example polyethylene, polypropylene, straight chain shape polyester etc.

(form of implementation 40)

Figure 40 A, B have shown respectively according to the plane graph of the part opening of the flexibility PTC heater of form of implementation 40 with at the profile of X-Y position.This form of implementation has the structure about the same with form of implementation 34.In form of implementation 34, the convex-concave portion 113 that electrode 2 and resistance 3 form on the face that joins with base material 115 is as elongation strain portion performance function.This elongation strain portion is not set in this form of implementation, and between film 104 and electrode 2, resistance 3 configuration adhesion resin 141.Perhaps also can make in the film 104 and contain adhesion resin.Adhesion resin is formed by the material described in the form of implementation 34.In addition, base material 103 or base material 115 are as elongation control assembly performance function.Base material 103 and base material 115 are made of nonwoven fabrics or braid etc.Thus, can improve the caking property of electrode 2, resistance 3 and base material 102, required above elongation does not take place, so vibration durability be improved.

More than the flexibility PTC heater according to the invention process form has been carried out various explanations, implement but the intrinsic structure of each form of implementation also can be combined in other form of implementation, this combination also within the scope of the invention.

(form of implementation 41)

Figure 41 is the pie graph of the seat device that is assembled with flexibility PTC heater in the invention process form 41.Flexibility PTC heater (hereinafter referred to as calandria) 158 is configured between epidermis 156 and the cushion part 155.Adding under the heat run in the winter time, by making its heating to calandria 158 energisings, conduct heat to epidermis 156, makes epidermis 156 become warm.After epidermis 156 is warm, also warm by conduction and the feasible passenger who takes one's seat of radiation.

In this structure, calandria 158 can be any structure described in the form of implementation 1-40.Because these structures are rich in flexibility,, also can keep good characteristic even therefore the passenger sits down, applies crooked load repeatedly.In addition, owing to adopt PTC resistance to constitute, therefore can automatically control temperature.

In addition, if be suitable for PTC heater, can form the product that province can the property excellence according to form of implementation 29.

In addition, as shown in figure 41, dehumidifying forced draft fan (hereinafter referred to as forced draft fan) 150 and dehumidification portion 151 can be set also on seat body (hereinafter referred to as seat) 154.Forced draft fan 150 comprises multi blade fan etc.Dehumidification portion 151 for example has the sorbing material of zeolite, silica gel, titanium silicate, activated alumina etc.In addition, the calandria under this situation 158 is suitable for the product with through hole of form of implementation 13-15 or form of implementation 21 etc.The air that 151 pairs of forced draft fans 150 of dehumidification portion are sent dehumidifies.The air that will dehumidify in ventilation road 153 is directed in the cushion part 155 of polyurethane foam resin of seat 154 etc.Epidermis 156 is covered with cushion part 155, and the squit hole (hereinafter referred to as the hole) 157 of ejection 153 dehumidified air of supplying with from the ventilation road is set.

By this structure, in the running, dehumidification portion 151 can dehumidify to the air that forced draft fan 150 is sent.The air that dehumidified arrives cushion part 155 from dehumidification portion 151 by ventilation road 153, from hole 157 ejections of epidermis 156.When the passenger took one's seat on seat 154, the air that dehumidified blowed to buttocks from passenger's back of the body center, and further blows to lower limb.Thus, to spraying the air that dehumidified with the contacted zone of human body surface.Therefore, make sweat gasification, drying, capture heat of gasification,, make the passenger cosily take one's seat even, eliminate the feeling of oppression and heat of sweat owing to make sunshine in summer and also can experience the cooling sense under the state that epidermis 156 temperature rise from skin surface.

In addition, in the seat device according to this form of implementation, the air that blows out from ventilation road 153 blows on the epidermis 156 by calandria 158.By this structure, to compare with the situation that adopts warm wind to heat, the temperature of epidermis 156 becomes higher.And this rate of rise in temperature is also fast, has improved comfortableness.In addition, during the dehumidifying of 158 pairs of calandrias wind pass through also not produce obstacle.In addition, after arriving steady state, by the low wet wind of 157 ejection high temperature from the hole, calandria 158 make the part sweating the sweat drying of human body, can have feeling of oppression and heat ground thus and do not heat.

In addition, ventilation road 13 preferably is made of the non-hygroscopic material of polyurethane resin etc.By this structure, make that the air of the high temperature low humidity that dehumidification portion produces is non-hygroscopic on the ventilation road, and blow to human body.Thus, by making the sweat gasification of surface,, increased the effect that prevents feeling of oppression and heat simultaneously because the contention heat of gasification makes human body have refrigerant sense.

In addition, ventilation road 153 has branch preferably as shown in figure 41 on cushion part 155.By this structure, make and in the relative broad range of passenger-back center and buttocks, supply with dehumidified air equably, and increase comfortableness.

Utilizability on the industry

In flexibility PTC heater according to the present invention, has following any structure.

1) part of electrode and PTC resistance is immersed in the flexible parent metal.

2) flexible parent metal is made of foamed resin or the elastomeric material that the surface is provided with concaveconvex shape.

3) at least 1 side in electrode and the PTC resistance is provided with the elongation strain part.

4) flexible parent metal has caking property, and flexible parent metal or flexible cladding material have the part of restriction elongation.

Therefore its flexibility is abundant, and the vibration durability excellence.This heater is applicable in automotive seat heater etc.

The explanation of referenced drawings symbol

1,12,13 flexibility base materials

2 comb poles

3PTC resistance

4,16,17 flexibility cladding materials

5,7,9 dippings are adjusted nonwoven fabrics

6 heat resistance fiber nonwoven fabrics

8,19 hot melts knot film

10 spunbonded nonwovens

11 spun-laced fabrics

14 foamed resins

15 resin web

18 polyesters nonwoven fabrics

20 convex forms

21 loop bonding processing parts

32,37,51A peristome

36 orthogonal fiber nonwoven fabrics

2A, 38 main electrodes

2B, 2C, 39 auxiliary electrodes

40 conductor wires

41 moisture absorption bodies

51, the netted base material of 56 flexibilities

52 flexibility support base materials

57 elongation limiting materials

58 leathers

59 through holes

66 portion of terminal

67,71 conductivity thin materials

68 conductive adhesives

69 solder flux

The 69A paste flux

70 leads

72 through holes

82 flexibility barrier materials

86 elongation limiting members

87 engagement members

88 mesh grids

89 resiliency base materials

91 flexibility fiber materials

93 electrodes

102 flexibility base materials

103,115,117,118,129 fiber base materials

104 films

113 convex-concave portions

114 hot melts knot property resin film

123 fiber materials

124PTC resistance corpus fibrosum

125 reticular fibre base materials

141 adhesion resins

150 forced draft fans

151 dehumidification portion

153 ventilation roads

154 seats

155 cushion part

156 epidermises

157 squit holes

158 flexibility PTC heaters

200 base materials

201,202 comb poles

203PTC resistance

204 cladding materials

Claims (19)

1. flexibility PTC heater, it has

By the electrode of printing formation,

Form by printing, give the PTC resistance of electricity by described electrode,

Flexible parent metal, it is made of any in the elastomeric material that is provided with concaveconvex shape on foamed resin that is provided with concaveconvex shape from the teeth outwards and the surface, and is provided with described electrode and described PTC resistance from the teeth outwards,

At least cover described electrode and described PTC resistance, and the flexibility cladding material that engages with described flexibility base material.

2. flexibility PTC heater as claimed in claim 1, wherein said flexibility base material further contain with described foamed resin and described elastomeric material in the resin web of any applying.

3. flexibility PTC heater as claimed in claim 1, wherein said electrode is a comb shape, the branch electrode that it has main electrode and is electrically connected with described main electrode and described PTC resistance, and have the elongation control assembly of the longitudinal tensile strain that limits described main electrode at least.

4. flexibility PTC heater as claimed in claim 3, wherein said elongation control assembly is formed by braiding shape resin web.

5. flexibility PTC heater as claimed in claim 1, it has one of at least elongation control assembly of elongation of restriction described flexibility base material and described flexibility cladding material.

6. flexibility PTC heater as claimed in claim 1 further possesses the moisture absorption body with peristome, and described moisture absorption body contacts with described PTC resistance heat.

7. flexibility PTC heater as claimed in claim 1, wherein said electrode is a comb shape, the branch electrode that it has main electrode and is electrically connected with described main electrode and described PTC resistance, one side of the length of described main electrode is configured in the vertical, one side of the length of described branch electrode is configured in transversely, described as a whole flexibility PTC heater extends 0-3% on vertical under the load of 5kgf, transversely extended 3%～10% o'clock, described flexibility PTC heater has 15kgf or its above fracture strength.

8. flexibility PTC heater as claimed in claim 1 wherein is provided with the extremely surperficial through hole in the back side that connects the flexibility heater.

9. flexibility PTC heater as claimed in claim 1, it further has portion of terminal, and the one end is electrically connected with described electrode, and the other end is electrically connected with lead simultaneously, and described flexibility cladding material covers described portion of terminal.

10. flexibility PTC heater as claimed in claim 9, wherein said portion of terminal have the conductivity thin material and with an end of described conductivity thin material and the conductive adhesive material of described electrode engagement.

11. flexibility PTC heater as claimed in claim 9, it further has the caking property nonwoven fabrics of fixing described portion of terminal, and described flexibility cladding material covers described caking property nonwoven fabrics.

12. flexibility PTC heater as claimed in claim 9, wherein said portion of terminal is configured in the surface of described flexibility base material, and the part of described electrode forms in the mode on the end that overlaps described portion of terminal.

13. flexibility PTC heater as claimed in claim 9, wherein said portion of terminal is configured in the described flexibility base material, coating forms the conductive paste of described electrode on described flexibility base material, makes the part of described electrode form on an end of described portion of terminal.

14. flexibility PTC heater as claimed in claim 9 wherein has the paste flux that has formed pattern in the position of the described electrode of printing of described portion of terminal.

15. flexibility PTC heater as claimed in claim 9, a described end of wherein said portion of terminal is connected with described electrode by conductive adhesive or grommets, and the other end of described portion of terminal connects described flexibility cladding material and is connected with lead by solder flux.

16. flexibility PTC heater as claimed in claim 1, wherein said flexibility base material comprise the 1st flexibility base material and the 2nd flexibility base material, the 2nd flexibility base material is formed by the resiliency base material with printing ink dipping property that keeps with non-membranaceous dispersion;

Described PTC resistance is formed on described the 2nd flexibility base material,

Described electrode is formed on the 1st flexibility base material,

Described electrode and described PTC resistance electrically contact,

The flexibility cladding material covers all.

17. flexibility PTC heater as claimed in claim 1, the containing one of at least of wherein said electrode and described PTC resistance as the resin of adhesive with as in the elastomer of adhesive any.

18. flexibility PTC heater as claimed in claim 1, wherein said electrode contains silver and carbon.

19. flexibility PTC heater as claimed in claim 1, wherein said PTC resistance contains the mixing cross-linking agent and the elastomer of crystalline resin and carbon black.

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