CN101514299A - Compound diesel - Google Patents

Compound diesel Download PDF

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Publication number
CN101514299A
CN101514299A CNA2009100146394A CN200910014639A CN101514299A CN 101514299 A CN101514299 A CN 101514299A CN A2009100146394 A CNA2009100146394 A CN A2009100146394A CN 200910014639 A CN200910014639 A CN 200910014639A CN 101514299 A CN101514299 A CN 101514299A
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parts
diesel
additive
compound
hexahydroaniline
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CNA2009100146394A
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CN101514299B (en
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陈庆军
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Abstract

The invention discloses a compound diesel, composed of the following raw materials: 15-20 parts of water, 8-12 parts of methanol, 30-35 parts of diesel, 9-12 parts of oleic acid, 21-28 parts of solvent oil, 4-7 parts of No.1 additives and 0.5-1.5 parts of No.2 additives by weight. The invention overcomes the defects that the prior emulsified diesel fuel has non-transparent milky color, and the prior methanol diesel and emulsified diesel can not be mixed with pure diesel and has insufficient dynamic property and terrible odor and has the advantages of good use effects, low cost, energy saving and environmental protection, etc.

Description

A kind of compound diesel
Technical field
The present invention relates to a kind of compound diesel.
Background technology
As everyone knows, diesel oil is one of most important Nonrenewable energy resources, because it is non-renewable, along with the development of society, the diesel oil resource sharply reduces, and seeks the substitute of diesel oil or prepares the effective measure that economical and practical diesel fuel complex additive is the alleviation problem.
There are multiple diesel fuel complex additive, compound diesel etc. in the prior art, but more or less all have following shortcoming: 1, can not mix use with pure diesel oil; 2, be short of power; 3, smell is bad 4, cost is higher.
Summary of the invention
At above-mentioned prior art, for solving the problem of diesel oil resource worsening shortages, consider from economy, result of use etc. are many-sided, the invention provides a kind of energy-conserving and environment-protective, stable practical compound diesel.
The present invention is achieved by the following technical solutions:
A kind of compound diesel is made up of following raw material, and each raw materials in part by weight is: water 15-20 part, methyl alcohol 8-12 part, diesel oil 30-35 part, oleic acid 9-12 part, solvent oil 21-28 part, an additive 4-7 part, No. two additive 0.5-1.5 parts.
Described solvent oil is No. 200 solvent oils.
A described additive is made up of the raw material of following parts by weight: polyoxyethylene octylphenol ether 3.5-7 part, polyoxyethylene nonylphenol ether 2.6-4 part, hexahydroaniline 3-6 part, many thanomins 1.7-3 part, straight chain alcohol 20-27 part, branched-chain alcoho 30-38 part, sodium hydroxide 13-20 part, isooctyl ester nitrate 2-4 part, ferrocene 0.5-1 part, 1 part of 2,6 ditertiary butyl p cresol, 0.5 part of benzotriazole.
Described many thanomins are a kind of several combinations in thanomin, diethanolamine, the trolamine.
Described straight chain alcohol is a kind of or several combination in propyl carbinol, nonylcarbinol, the n-Octanol.
Described branched-chain alcoho is a kind of or several combination in isooctyl alcohol, Virahol, the primary isoamyl alcohol.
Described No. two additives are made up of the raw material of following parts by weight: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
A kind of preparation method of compound diesel is characterized in that, step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, many thanomins, straight chain alcohol, branched-chain alcoho, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 30~60 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 10~30 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, solvent oil mix with an additive, stir 60~120 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
Compound diesel of the present invention has following excellent properties:
1, true to nature: outward appearance is as diesel oil, and is limpid transparent, haze-free, and (the sort of oyster white of not having oil in water emulsion of the prior art fully), the user easily accepts.
2, refuse water: after the fixed ratio (emulsification is fused) of water in the compound diesel after the configuration, add water again and can not add, only can be sunken to the oil in water emulsion bottom.
3, stable: no change, not stratified, can satisfy user's needs fully.
4, dissolve each other: these characteristics are most important factors that can diesel oil emulsification be promoted on a large scale, if can not dissolve each other, popularization is impossible.Compound diesel of the present invention can mix with pure diesel oil arbitrarily, and does not influence result of use, never degenerates, and is user-friendly to greatly and production and sales etc.
5, practicality: energy-conservation more than 10~20%, tail gas clean-up rate 30%, cost is low, produces and need not special-purpose specific installation, and the golden eggs space is arranged.
Contain multiple catalytically active material in the compound diesel of the present invention, metal ion not has the usefulness of multiple excellence:
One, this oil product has stabilization;
Two, this oil product has not stratified, not degreasing, not emulsive effect;
Three, this oil product makes combustion flame obviously brighten, shorten, can realize abundant burning by optimizing the oil plant carbon-chain structure;
Four, this oil product does not have carbon deposit, guarantees the original normal compressionization of power, reduces oil consumption;
Five, the condensation point of this oil product is low, and good fluidity can be realized abundant atomizing, makes burning more abundant;
Six, this oil product has the decomposition combustion aid function: compound diesel of the present invention contains certain hydroxide material, under the combustion high temperature condition, especially in the combustion chamber of power through high temperature and catalysis, can decompose hydrogen and oxygen, they are to participate in active atom of incendiary and free radical, can promote burning and make fuel discharge bigger heat energy.
The present inventor is through concentrating on studies for many years, carries out various tests and produces in batches on probationly, invented this " water-in-oil " type environment-friendly energy-saving diesel fuel, and through evidence, it has following multiple effect:
1, cracking energization effect; Water is made up of hydrogen-oxygen, and high-temperature can cracking go out the hydrogen participation burning higher 3.5 times than diesel oil energy down.
2, energy-conservation oxygen supply effect: cracked oxygen is combustion-supporting for burning has increased the oxygen adding, makes its burning more abundant, and is more energy-conservation.
3, effect of micro-explosion: during water vapor, can break through oil film when producing the steam than self big 1700 times of volume, oil is atomized once again, thus more abundant burning.
4, water-gas effect: water vapour with fail incendiary CO and be converted to CO 2And a large amount of heat releases.
5, environmental protection effect: emulsifying combustion can reduce the fume emission degree more than 62%.
Compound diesel of the present invention can be all carries out operation in higher Sealing Arrangement of level of automation and pipeline, do not have the discharging of " three wastes " such as waste gas, waste water, waste residues in the whole process flow, and is minimum to surrounding environment influence.
Its raw material source of the present invention is extensive, and cost is low: diesel oil itself can be bought everywhere, and water can be gathered materials on the spot, methyl alcohol, the local procurement of chemical industry auxiliary material.Principle is easily purchased preparation, and price is clear and definite, and wherein the diesel oil wholesale price is clear, and water price is clear, and economic benefit comes into plain view.
The present invention has overcome the opaque milky defective of color of former diesel oil emulsification, overcome former methanol diesel-oil, diesel oil emulsification can not with pure diesel oil blended defective, methanol diesel-oil, the insufficient shortcoming of diesel oil emulsification dynamic property before having overcome have overcome methanol diesel-oil, diesel oil emulsification smell defect of bad.The present invention has good, the advantages such as cost is low, energy-conserving and environment-protective of result of use.
Embodiment
Embodiment 1: prepare a kind of compound diesel
Prescription is: 20 parts in water, 10 parts of methyl alcohol, 32 parts of diesel oil, 9 parts of oleic acid, 21 parts of 200# solvent oils, 7 parts of additives, 1 part of No. two additive.
Wherein, the prescription of an additive is: 7 parts of polyoxyethylene octylphenol ethers, 4 parts of polyoxyethylene nonylphenol ethers, 4 parts of hexahydroaniline, 3 parts of thanomins, 27 parts of n-Octanols, 38 parts of isooctyl alcohol, 13 parts in sodium hydroxide, 2 parts of isooctyl ester nitrates, 0.5 part of ferrocene, 2,1 part of 6-ditertbutylparacresol, 0.5 part of benzotriazole.
The prescription of No. two additives is: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
Step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, thanomin, n-Octanol, isooctyl alcohol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 30 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 30 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, 200# solvent oil mix with an additive, stir 120 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
Embodiment 2: prepare a kind of compound diesel
Prescription is: 20 parts in water, 10 parts of methyl alcohol, 32 parts of diesel oil, 9 parts of oleic acid, 21 parts of 200# solvent oils, 7 parts of additives, 1 part of No. two additive.
Wherein, the prescription of an additive is: 7 parts of polyoxyethylene octylphenol ethers, 4 parts of polyoxyethylene nonylphenol ethers, 4 parts of hexahydroaniline, 3 parts of thanomins, 27 parts of propyl carbinols, 38 parts of Virahols, 13 parts in sodium hydroxide, 2 parts of isooctyl ester nitrates, 0.5 part of ferrocene, 2,1 part of 6-ditertbutylparacresol, 0.5 part of benzotriazole.
The prescription of No. two additives is: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
Step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, thanomin, propyl carbinol, Virahol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 60 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 10 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, 200# solvent oil mix with an additive, stir 60 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
Embodiment 3: prepare a kind of compound diesel
Prescription is: 20 parts in water, 10 parts of methyl alcohol, 32 parts of diesel oil, 9 parts of oleic acid, 21 parts of 200# solvent oils, 7 parts of additives, 1 part of No. two additive.
Wherein, the prescription of an additive is: 7 parts of polyoxyethylene octylphenol ethers, 4 parts of polyoxyethylene nonylphenol ethers, 4 parts of hexahydroaniline, 3 parts of trolamines, 27 parts of positive certain herbaceous plants with big flowers alcohol, 38 parts of primary isoamyl alcohol, 13 parts in sodium hydroxide, 2 parts of isooctyl ester nitrates, 0.5 part of ferrocene, 2,1 part of 6-ditertbutylparacresol, 0.5 part of benzotriazole.
The prescription of No. two additives is: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
Step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, trolamine, positive certain herbaceous plants with big flowers alcohol, primary isoamyl alcohol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 45 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 20 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, 200# solvent oil mix with an additive, stir 90 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
Embodiment 4: prepare a kind of compound diesel
Prescription is: 15 parts in water, 12 parts of methyl alcohol, 30 parts of diesel oil, 12 parts of oleic acid, 28 parts of 200# solvent oils, 6 parts of additives, 0.5 part of No. two additive.
Wherein, the prescription of an additive is: 3.5 parts of polyoxyethylene octylphenol ethers, 2.6 parts of polyoxyethylene nonylphenol ethers, 6 parts of hexahydroaniline, 1.7 parts of trolamines, 20 parts of positive certain herbaceous plants with big flowers alcohol, 30 parts of primary isoamyl alcohol, 20 parts in sodium hydroxide, 4 parts of isooctyl ester nitrates, 1 part of ferrocene, 2,1 part of 6-ditertbutylparacresol, 0.5 part of benzotriazole.
The prescription of No. two additives is: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
Step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, trolamine, positive certain herbaceous plants with big flowers alcohol, primary isoamyl alcohol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 45 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 20 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, 200# solvent oil mix with an additive, stir 90 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
Embodiment 5: prepare a kind of compound diesel
Prescription is: 18 parts in water, 8 parts of methyl alcohol, 35 parts of diesel oil, 10 parts of oleic acid, 25 parts of 200# solvent oils, 4 parts of additives, 1.5 parts of No. two additives.
Wherein, the prescription of an additive is: 5 parts of polyoxyethylene octylphenol ethers, 3.5 parts of polyoxyethylene nonylphenol ethers, 3 parts of hexahydroaniline, 2.4 parts of trolamines, 24 parts of positive certain herbaceous plants with big flowers alcohol, 34 parts of primary isoamyl alcohol, 17 parts in sodium hydroxide, 3 parts of isooctyl ester nitrates, 0.7 part of ferrocene, 2,1 part of 6-ditertbutylparacresol, 0.5 part of benzotriazole.
The prescription of No. two additives is: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
Step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, trolamine, positive certain herbaceous plants with big flowers alcohol, primary isoamyl alcohol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 45 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 20 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, 200# solvent oil mix with an additive, stir 90 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.

Claims (8)

1. compound diesel, it is characterized in that: be made up of following raw material, each raw materials in part by weight is: water 15-20 part, methyl alcohol 8-12 part, diesel oil 30-35 part, oleic acid 9-12 part, solvent oil 21-28 part, an additive 4-7 part, No. two additive 05-1.5 parts.
2. a kind of compound diesel according to claim 1 is characterized in that: described solvent oil is No. 200 solvent oils.
3. a kind of compound diesel according to claim 1 is characterized in that, a described additive is made up of the raw material of following parts by weight: polyoxyethylene octylphenol ether 3.5-7 part, polyoxyethylene nonylphenol ether 2.6-4 part, hexahydroaniline 3-6 part, many thanomins 1.7-3 part, straight chain alcohol 20-27 part, branched-chain alcoho 30-38 part, sodium hydroxide 13-20 part, isooctyl ester nitrate 2-4 part, ferrocene 0.5-1 part, 1 part of 2,6 ditertiary butyl p cresol, 0.5 part of benzotriazole.
4. a kind of compound diesel according to claim 3 is characterized in that: described many thanomins are a kind of several combinations in thanomin, diethanolamine, the trolamine.
5. a kind of compound diesel according to claim 3 is characterized in that: described straight chain alcohol is a kind of or several combination in propyl carbinol, nonylcarbinol, the n-Octanol.
6. a kind of compound diesel according to claim 3 is characterized in that: described branched-chain alcoho is a kind of or several combination in isooctyl alcohol, Virahol, the primary isoamyl alcohol.
7. a kind of compound diesel according to claim 1 is characterized in that, described No. two additives are made up of the raw material of following parts by weight: 30 parts of hexahydroaniline, 50 parts of butylacetates, 20 parts of methylcarbonates.
8. the preparation method of claim 1 or 3 or 7 described a kind of compound diesels is characterized in that step is as follows:
(1) additive of preparation: get polyoxyethylene octylphenol ether, polyoxyethylene nonylphenol ether, hexahydroaniline, many thanomins, straight chain alcohol, straight chain alcohol, sodium hydroxide, isooctyl ester nitrate, ferrocene, 2,6-ditertbutylparacresol and benzotriazole, mix, stir and got final product in 30~60 minutes;
(2) No. two additives of preparation: get hexahydroaniline, butylacetate and methylcarbonate, mix, stir and got final product in 10~30 minutes;
(3) water intaking, methyl alcohol, diesel oil, oleic acid, solvent oil mix with an additive, stir 60~120 minutes, and be limpid bright to color, adds additive again No. two, continues to stir 20 minutes, promptly gets compound diesel.
CN 200910014639 2009-03-03 2009-03-03 Compound diesel Expired - Fee Related CN101514299B (en)

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Cited By (18)

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CN101768478A (en) * 2010-03-05 2010-07-07 北京雄韬伟业能源科技发展有限公司 Vehicle low-carbon biodiesel
CN102181312A (en) * 2011-03-29 2011-09-14 汪青 Microemulsion diesel oil and preparation method thereof
CN102504890A (en) * 2011-11-08 2012-06-20 焦作市新生生物化工有限公司 Composite methanol diesel and preparation method thereof
CN102517101A (en) * 2011-12-23 2012-06-27 江苏玖尚燃油发展有限公司 Automobile methanol diesel fuel and preparation method thereof
CN102585942A (en) * 2012-03-19 2012-07-18 刘少君 Concentration emulsified diesel fuel and preparation method thereof
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN102703144A (en) * 2012-06-29 2012-10-03 从德强 Diesel ester and preparation method thereof
CN102876397A (en) * 2012-10-26 2013-01-16 滕春合 Nano composite diesel oil and preparation method thereof
CN103074129A (en) * 2013-01-25 2013-05-01 西北师范大学 Preparation method of methanol microemulsion diesel oil
CN103305293A (en) * 2013-07-08 2013-09-18 太原理工大学 F-T diesel methanol mixed fuel and preparation method thereof
CN103911182A (en) * 2013-01-09 2014-07-09 刘粤荣 Multicomponent formula combined biological fuel oil and preparation method thereof
CN103911183A (en) * 2013-01-09 2014-07-09 刘粤荣 Multicomponent formula combined biodiesel and preparation method thereof
CN103937570A (en) * 2014-04-24 2014-07-23 朱文雷 Novel mixed diesel oil processing method
CN104650998A (en) * 2015-02-05 2015-05-27 刘杰 Alcohol ether diesel oil and preparation method thereof
CN105838456A (en) * 2015-01-13 2016-08-10 赵惠霖 High-cleanness diesel and preparation method thereof
CN106520225A (en) * 2016-12-20 2017-03-22 墨宝股份有限公司 Novel fuel with energy saving and emission reducing effects and preparation method thereof
CN110747024A (en) * 2019-12-02 2020-02-04 重庆正涛新能源科技有限公司 Micro-emulsified diesel oil and preparation method thereof
CN111793511A (en) * 2020-07-14 2020-10-20 张建国 Environment-friendly mixed biodiesel

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CN1888029A (en) * 2006-07-24 2007-01-03 韩福生 Clean environment protection synthetic diesel oil
CN100489071C (en) * 2006-10-13 2009-05-20 北京中天醇能源技术有限公司 Methanol modifier and application thereof
CN101368115A (en) * 2008-10-10 2009-02-18 上海龙津石油有限公司 Methanol diesel oil for automobile

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CN101768478B (en) * 2010-03-05 2013-02-06 北京雄韬伟业能源科技发展有限公司 Vehicle low-carbon biodiesel
CN101768478A (en) * 2010-03-05 2010-07-07 北京雄韬伟业能源科技发展有限公司 Vehicle low-carbon biodiesel
CN102181312A (en) * 2011-03-29 2011-09-14 汪青 Microemulsion diesel oil and preparation method thereof
CN102181312B (en) * 2011-03-29 2013-06-05 汪青 Microemulsion diesel oil and preparation method thereof
CN102504890A (en) * 2011-11-08 2012-06-20 焦作市新生生物化工有限公司 Composite methanol diesel and preparation method thereof
CN102517101A (en) * 2011-12-23 2012-06-27 江苏玖尚燃油发展有限公司 Automobile methanol diesel fuel and preparation method thereof
CN102517101B (en) * 2011-12-23 2014-05-14 江苏玖尚燃油发展有限公司 Automobile methanol diesel fuel and preparation method thereof
CN102585942A (en) * 2012-03-19 2012-07-18 刘少君 Concentration emulsified diesel fuel and preparation method thereof
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN102643692B (en) * 2012-05-08 2014-04-16 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN102703144A (en) * 2012-06-29 2012-10-03 从德强 Diesel ester and preparation method thereof
CN102876397A (en) * 2012-10-26 2013-01-16 滕春合 Nano composite diesel oil and preparation method thereof
CN103911183A (en) * 2013-01-09 2014-07-09 刘粤荣 Multicomponent formula combined biodiesel and preparation method thereof
CN103911182A (en) * 2013-01-09 2014-07-09 刘粤荣 Multicomponent formula combined biological fuel oil and preparation method thereof
CN103911183B (en) * 2013-01-09 2016-02-03 刘粤荣 Biofuel of a kind of polynary formula combination and preparation method thereof
CN103074129A (en) * 2013-01-25 2013-05-01 西北师范大学 Preparation method of methanol microemulsion diesel oil
CN103305293A (en) * 2013-07-08 2013-09-18 太原理工大学 F-T diesel methanol mixed fuel and preparation method thereof
CN103937570A (en) * 2014-04-24 2014-07-23 朱文雷 Novel mixed diesel oil processing method
CN105838456A (en) * 2015-01-13 2016-08-10 赵惠霖 High-cleanness diesel and preparation method thereof
CN104650998A (en) * 2015-02-05 2015-05-27 刘杰 Alcohol ether diesel oil and preparation method thereof
CN106520225A (en) * 2016-12-20 2017-03-22 墨宝股份有限公司 Novel fuel with energy saving and emission reducing effects and preparation method thereof
CN110747024A (en) * 2019-12-02 2020-02-04 重庆正涛新能源科技有限公司 Micro-emulsified diesel oil and preparation method thereof
CN111793511A (en) * 2020-07-14 2020-10-20 张建国 Environment-friendly mixed biodiesel

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