CN101509188A - Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof - Google Patents

Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof Download PDF

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Publication number
CN101509188A
CN101509188A CNA2009100472016A CN200910047201A CN101509188A CN 101509188 A CN101509188 A CN 101509188A CN A2009100472016 A CNA2009100472016 A CN A2009100472016A CN 200910047201 A CN200910047201 A CN 200910047201A CN 101509188 A CN101509188 A CN 101509188A
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China
Prior art keywords
finishing agent
excitated
negative oxygen
oxygen ion
milled
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Granted
Application number
CNA2009100472016A
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Chinese (zh)
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CN101509188B (en
Inventor
蔡再生
许云生
陈少梅
曾德祥
陈玉梅
葛凤燕
赵亚萍
杨宗倡
骆永成
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SHANGHAI YIFURUI INDUSTRY Co Ltd
Donghua University
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SHANGHAI YIFURUI INDUSTRY Co Ltd
Donghua University
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Priority to CN2009100472016A priority Critical patent/CN101509188B/en
Publication of CN101509188A publication Critical patent/CN101509188A/en
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Publication of CN101509188B publication Critical patent/CN101509188B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention relates to a fulling finishing agent having excited negative oxygen ions, a preparation method and application thereof, and the components of the agent comprise: a nano-tourmaline active modification finishing agent CLQ, a surfactant I, a non-ion surfactant II and water, based on the weight percent of: 30-50%:15-20%:10-15%:the balance; the preparation method comprises the step of: mixing uniformly the nano-tourmaline active modification finishing agent CLQ, the surfactant I, the non-ion surfactant II and the water at room temperature to obtain the fulling finishing agent having the excited negative oxygen ions; the method is applied to the fulling finishing technologies of fiber products. The fiber product subjected to the treatment of the inventive fulling finishing agent is less in fuds and plumped in hand felling; the generation amount of the negative ions is 2500-3500 per cm<3>; the invention emits a far infrared ray having a wavelength of 4mum-14mum at body temperature as well as is simple in the preparation method and suitable for industrial production.

Description

A kind of milled finishing agent, preparation method and application with excitated negative oxygen ion
Technical field
The invention belongs to milled finishing agent and its production and application preparation field, particularly relate to a kind of milled finishing agent, preparation method and application with excitated negative oxygen ion.
Background technology
The purpose of woollen sweater fulling milling mainly is for the inherent quality of improving the woollen sweater product and appearance effect.Fulling milling can make the fabric quality tight, contraction in length, and weight per square meter and thickness increase, the powerful raising, elasticity and warmth retention property strengthen; Its surface of woollen sweater through fulling milling manifests one deck fine hair, makes the outward appearance grace, the abundant softness of feel, and color and luster is soft.In addition, the fine hair that fulling milling produces plays desalination and covers effect original some fault of woollen sweater, makes its unlikely fabric face that is exposed to significantly.
People are slow-witted of a specified duration in the room that heating installation or air-conditioning are arranged, and will feel under the weather, concentrate on brains expand, tired out, even can cause respiratory tract infection, this is because airborne anion rareness in the sealing room of a specified duration.If you walk the place that The trees make a pleasant shade in the countryside, just can feel relaxed and joyful; If be near forest, the waterfall, to suffer from bronchitis, heart disease, neurasthenic patient and can think that illness alleviates, this is because a large amount of anions is arranged.These anions to activating human body cells, strengthen physical function, improve immunity, stable mood, alleviate anxiety and sense of fatigue has positive role and effect.
Summary of the invention
Technical problem to be solved by this invention provides a kind of milled finishing agent, preparation method and application with excitated negative oxygen ion, and the fibre fuds fuddled of handling through milled finishing agent of the present invention is few, good hand feeling; Anion-generating capacity 2500-3500/cm 3Launching wavelength under body temperature is the far infrared of 4 μ m-14 μ m; And the preparation method is simple, is suitable for suitability for industrialized production.
A kind of milled finishing agent of the present invention with excitated negative oxygen ion, component comprises: nano-tourmaline activity modifying finishing agent CLQ, surfactant I, non-ionic surface active agent II, water, its percentage by weight is: 30~50%:15~20%:10~15%: surplus.
Described nano-tourmaline activity modifying finishing agent CLQ is peaking worker Co., Ltd of a Hangzhou section product.
Described surfactant I is selected from one or both the mixture in sodium alkyl benzene sulfonate ABS, sulfonate type anion surfactant LS, detergent 209, Lei Mibang, the Igepon T.
Described non-ionic surface active agent II is selected from C14 alcohol (high-carbon fatty alcohol C 14H 29OH), C16 alcohol (high-carbon fatty alcohol C 16H 33OH), C18 alcohol (high-carbon fatty alcohol C 18H 37OH), a kind of in the stearic acid.
A kind of preparation method with milled finishing agent of excitated negative oxygen ion of the present invention comprises:
Nano-tourmaline activity modifying finishing agent CLQ, surfactant I, non-ionic surface active agent II, water, its percentage by weight is: 30~50%:15~20%:10~15%: surplus, at room temperature mix, and promptly get the milled finishing agent of excitated negative oxygen ion.
A kind of milled finishing agent with excitated negative oxygen ion of the present invention is applied to the fulling milling finishing technique of fibre,
Concrete steps comprise:
Wetting (bath raio 1:20~25 of fibre, 35 ℃~45 ℃ of temperature, handled 5~10 minutes) → (bath raio is 1:25~35 to the processing of anion fulling milling, milled finishing agent (5~8) weight % with excitated negative oxygen ion, 35~50 ℃, pH value 5~10 is carried out 20~35min) → cleaning → dehydration → oven dry in fulling mill or laundry drum.
Described fibre is wool, cashmere, camel hair, the rabbit hair, yak hair, Xue Telanmao etc. and blending essence, the slubbing class sweater that comprises above-mentioned fiber.
Finishing agent of the present invention combines with the azelon that contains the activity group with grafting or crosslinked mode, and washing fastness is good, and finishing agent can discharge anion under illumination.From the structure of finishing agent, finishing technique coordination aspect is considered, guarantees that finishing agent and fiber have good reactivity, does not influence dyeability again.This finishing agent arrangement knitted underwear also has far-infrared transmitting function except that anion generation, fulling milling function are arranged.
Beneficial effect
Adopt fulling milling running product of the present invention, spin tests such as grinding south test center of institute, China Preventive Medicial Science Institute through Shanghai, fuds fuddled is few, good hand feeling; Anion-generating capacity 2500-3500/cm 3Launching wavelength under body temperature is the far infrared of 4 μ m-14 μ m.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
Sweater goods: wool sweater
Anion fulling milling treatment process: wetting (the bath raio 1:20 of wool sweater, 35 ℃ of temperature, 5~10 minutes time) → (bath raio is 1:25~35 to the processing of anion fulling milling, milled finishing agent 5 weight % with excitated negative oxygen ion, 40 ℃, pH value 6 is carried out 30min in XPG-2 type fulling mill or laundry drum) → cleaning → dehydration → oven dry.
The component of anion fulling agent and weight percentage are:
Nano-tourmaline activity modifying finishing agent CLQ 30%
Sodium alkyl benzene sulfonate ABS 18%
Stearic acid 10%
Water 42%
Embodiment 2
Sweater goods: cotton: Mo Daier: cashmere is the knitted underwear of 5:4:1
Anion fulling milling treatment process: wetting (the bath raio 1:25 of knitted underwear, 35 ℃ of temperature, 5~10 minutes time) → (bath raio is 1:35 to the processing of anion fulling milling, milled finishing agent 5 weight % with excitated negative oxygen ion, 35 ℃, pH value 6.5 is carried out 30min in XPG-2 type fulling mill or laundry drum) → cleaning → dehydration → oven dry.
The component of anion fulling agent and weight percentage are:
Nano-tourmaline activity modifying finishing agent CLQ 30%
Detergent 209 15%
C14 alcohol (high-carbon fatty alcohol C 14H 29OH) 10%
Water 45%
Embodiment 3
Sweater goods: rabbit hair blouse
Anion fulling milling treatment process: wetting (the bath raio 1:20 of wool sweater, 35 ℃ of temperature, 5~10 minutes time) → (bath raio is 1:30 to the processing of anion fulling milling, milled finishing agent 8 weight % with excitated negative oxygen ion, 45 ℃, pH value 6.5. in XPG-2 type fulling mill or laundry drum, carry out 35min) → cleaning → dehydration → oven dry.
The component of anion fulling agent and weight percentage are:
Nano-tourmaline activity modifying finishing agent CLQ 50%
Sulfonate type anion surfactant LS 18%
C16 alcohol (high-carbon fatty alcohol C 16H 33OH) 15%
Water 17%
Embodiment 4
Sweater goods: wool: yak hair is the sweater of 6:4
Anion fulling milling treatment process: wetting (the bath raio 1:25 of wool sweater, 40 ℃ of temperature, 5~10 minutes time) → (bath raio is 1:30 to the processing of anion fulling milling, milled finishing agent 6 weight % with excitated negative oxygen ion, 45 ℃, pH value 6.8 is carried out 30min in XPG-2 type fulling mill or laundry drum) → cleaning → dehydration → oven dry.
The component of anion fulling agent and weight percentage are:
Nano-tourmaline activity modifying finishing agent CLQ 35%
Lei Mibang 15%
C18 alcohol (high-carbon fatty alcohol C 18H 37OH) 10%
Water 40%

Claims (7)

1. milled finishing agent with excitated negative oxygen ion, component comprises: nano-tourmaline activity modifying finishing agent CLQ, surfactant I, non-ionic surface active agent II, water, its percentage by weight is: 30~50%:15~20%:10~15%: surplus.
2. a kind of milled finishing agent with excitated negative oxygen ion according to claim 1 is characterized in that: described surfactant I is selected from one or both the mixture in sodium alkyl benzene sulfonate ABS, sulfonate type anion surfactant LS, detergent 209, Lei Mibang, the Igepon T.
3. a kind of milled finishing agent with excitated negative oxygen ion according to claim 1 is characterized in that: described non-ionic surface active agent II selects high-carbon fatty alcohol C 14H 29OH, high-carbon fatty alcohol C 16H 33OH, high-carbon fatty alcohol C 18H 37A kind of in OH, the stearic acid.
4. preparation method with milled finishing agent of excitated negative oxygen ion comprises:
With nano-tourmaline activity modifying finishing agent CLQ, surfactant I, non-ionic surface active agent II, water, its percentage by weight is: 30~50%:15~20%:10~15%: surplus, at room temperature mix, and promptly get the milled finishing agent of excitated negative oxygen ion.
5. the milled finishing agent with excitated negative oxygen ion is applied to the fulling milling finishing technique of fibre.
6. a kind of milled finishing agent with excitated negative oxygen ion according to claim 5 is applied to the fulling milling finishing technique of fibre, it is characterized in that: concrete steps comprise,
(1) fibre is wetting
With bath raio 1:20~25, water is medium, and 35 ℃-45 ℃ of temperature were handled 5~10 minutes;
(2) the anion fulling milling is handled
With step (1) fibre is 1:25~35 with the bath raio, and water is medium, has the milled finishing agent 5 weight %~8 weight % of excitated negative oxygen ion, and 35 ℃~50 ℃, pH value 5~10 is carried out 20~35min in fulling mill or laundry drum;
(3) then through cleaning dehydration, oven dry.
7. a kind of milled finishing agent with excitated negative oxygen ion according to claim 6 is used the fulling milling finishing technique with fibre, and it is characterized in that: described step (1) fibre is wool, cashmere, camel hair, the rabbit hair, yak hair, Xue Telanmao and blending essence, slubbing class sweater.
CN2009100472016A 2009-03-06 2009-03-06 Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof Expired - Fee Related CN101509188B (en)

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CN101509188B CN101509188B (en) 2012-08-08

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102995388A (en) * 2012-12-10 2013-03-27 上海水星家用纺织品股份有限公司 Preparation method of water-washable anion wool fiber and application in home textile product
CN103361966A (en) * 2013-07-25 2013-10-23 宁波康赛妮毛绒制品有限公司 Active negative oxygen ion cashmere yarn after-treatment method
CN103643514A (en) * 2013-12-06 2014-03-19 成路凯尔服装(苏州)有限公司 After-finishing method of active negative oxygen ion cashmere yarns
CN108149417A (en) * 2018-02-23 2018-06-12 上海嘉芮实业有限公司 The manufacture craft and its product of a kind of fulling milling method of woolen knitting ready-made clothes and the strong fulling milling knitted fabric of the wool including this method

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876459A (en) * 1973-06-29 1975-04-08 Dow Corning Treatment of fibres
CN1093401A (en) * 1993-04-06 1994-10-12 贾莉俊 Detergent for washing woollen sweater with shrink-proof and softening function
CN1141438C (en) * 2000-11-16 2004-03-10 戴彦彤 Health-care far infrared and negative oxygen ion fabric and its preparing process
CN1272500C (en) * 2004-07-26 2006-08-30 荆玉堂 Tuomalin function fabric and its preparing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102995388A (en) * 2012-12-10 2013-03-27 上海水星家用纺织品股份有限公司 Preparation method of water-washable anion wool fiber and application in home textile product
CN102995388B (en) * 2012-12-10 2015-11-25 上海水星家用纺织品股份有限公司 A kind ofly wash the preparation method of anion wool fiber and the application in home textile product thereof
CN103361966A (en) * 2013-07-25 2013-10-23 宁波康赛妮毛绒制品有限公司 Active negative oxygen ion cashmere yarn after-treatment method
CN103643514A (en) * 2013-12-06 2014-03-19 成路凯尔服装(苏州)有限公司 After-finishing method of active negative oxygen ion cashmere yarns
CN108149417A (en) * 2018-02-23 2018-06-12 上海嘉芮实业有限公司 The manufacture craft and its product of a kind of fulling milling method of woolen knitting ready-made clothes and the strong fulling milling knitted fabric of the wool including this method
CN108149417B (en) * 2018-02-23 2020-06-09 上海嘉芮实业有限公司 Fulling method of wool knitted garment, manufacturing process of wool strong fulling knitted fabric comprising fulling method and product of wool strong fulling knitted fabric

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