CN101503902B - Environment-friendly fire-retardant indoor decoration materials with 3d pattern - Google Patents

Environment-friendly fire-retardant indoor decoration materials with 3d pattern Download PDF

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CN101503902B
CN101503902B CN2008101658592A CN200810165859A CN101503902B CN 101503902 B CN101503902 B CN 101503902B CN 2008101658592 A CN2008101658592 A CN 2008101658592A CN 200810165859 A CN200810165859 A CN 200810165859A CN 101503902 B CN101503902 B CN 101503902B
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resin
rete
heat fusing
environment
building material
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CN101503902A (en
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金相术
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MILE TECH Co Ltd
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MILE TECH Co Ltd
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Abstract

The present invention relates to an environment-friendly flame-resisting interior decorating building material which is provided with three-dimensional pattern, and especially to a flame-resisting interior decorating building material which is formed with a thermal melting film layer on two surfaces of inorganic plate and is sequentially overlapped with an oxhide substrate layer and a printing pattern sheet layer on the thermal melting film layer. The flame-resisting interior decorating building material according to the invention effectively settles the problem of formaldehyde carcinogen caused by the using of prior melamine resin or urea resin adhesive through the thermal melting layer. The flame-resisting interior decorating building material is an environment-friendly building material without the generation of noxious gases of dioxin, etc. The production cost is low, and the operating method is simple. The operation can be executed after simply inserting a thermal melting film in a laminating process without additionally preparing an adhesive coating device. The excellent binding force can be kept in low temperature. As the environment-friendly flame-resisting interior decorating building material can be prepared in short time, the productbility is increased. The low cost satisfies the economic property. The water resistance is excellent and the distortion phenomenon is not generated. The environment-friendly flame-resisting interior decorating building material of the invention is an excellent flame-resisting interior decorating building material.

Description

The environment-friendly fire-retardant indoor decoration building materials that possess space pattern
Technical field
The present invention relates to a kind of environment-friendly fire-retardant indoor decoration building materials that possess space pattern.
Background technology
Along with paying attention to popularizing of healthy with beautiful Well-Being culture, the stakeholder can be covered harmful material and be enjoyed the material that is of value to human body at being applicable to building indoor decoration building materials environmentally friendly for building have carried out continual development.The harmful substance that indoor/outdoor decoration building materials, cement and lacquer etc. generated in architecture construction can give rise to diseases, because this new house syndrome (Sick House Syndrome) has become social concern at present, therefore press for and develop environmentally friendly building materials.
And the toxic gas that is generated during recently along with building generation large-sized fire causes huge life disaster, and difficult combustion indoor decoration building materials are subjected to people's favor day by day.
The manufacture method of existing difficult combustion indoor decoration building materials is, using behind the directly stacked ox-hide base material that is impregnated with phenolic resins on the inanimate matter board, perhaps, perhaps use fire resistant decorative board (High PressureMelamine) to be bonded to the first-class method of inanimate matter board by cold-press process at normal temperatures carrying out thermmohardening behind coating liquid phase polyurethane series or the binder liquid on the above-mentioned inanimate matter board.Below said method is described further.
Though the method for the directly stacked ox-hide base material that is impregnated with phenolic resins is simple on inanimate matter board, its cohesive force a little less than, and resin impregnating ox-hide substrate layer is thick more, the pernicious gas that produces during fire alarm is many more.
The method of carrying out thermmohardening behind adhesive stripe-coating liquid on the inanimate matter board is, behind surface applied binding agent or polyurethane series of inanimate matter board, the ox-hide base material that is impregnated with phenolic resins placed carry out thermmohardening by hot pressing mode again on the above-mentioned inanimate matter board and handle.At this moment, the unit pressure 5-15kg/cm of above-mentioned hot pressing process 2, hot pressing 60-240 second under 110-130 ℃ temperature.After disposing, above-mentioned thermmohardening carries out again being applied to various uses after the UV coating is handled.
Because this method is coated to the liquid phase binding liquid on the inanimate matter board, therefore when the thermmohardening operation, be under pressure influence and make binding liquid immerse the inanimate matter layer and reduce cohesive force, polyurethane series material then produces a lot of toxic gases when fire alarm takes place.
Be bonded on the inanimate matter board by cold-press process at normal temperatures after also can making fire resistant decorative board earlier.Paper wood after the printing is immersed in the melmac, after being immersed in brown paper in cresol resin or the phenolic resins, being layered in the paper wood after the printing on the brown paper that has flooded above-mentioned cresol resin or phenolic resins in addition, moulding promptly can be made into fire resistant decorative board.At this moment, make-up machine makes the Steam Press method carry out the product combination.The fire resistant decorative board of making through said process is bonded to inanimate matter board at normal temperatures by chilling press (cold press former).Yet said method is subjected to the thickness deviation influence that the lip-deep inorganic matter of above-mentioned inanimate matter board caused easily and the imperfect bonding phenomenon takes place.
And, after being heated, the resin that uses as binding agent in the said method can discharge harmful mortality formaldehyde carcinogen, therefore can cause the fatal problem on environment or the health.
Therefore, press for and develop a kind of difficulty combustion indoor decoration building materials with adhesive layer of following properties, the close environment and the useful human body of above-mentioned adhesive layer are much better than existing adhesive layer, also can not discharge toxic gas during fire alarm.
In order to solve above-mentioned prior art problems, applicant of the present invention has found out the method for utilizing the heat fusing film in the process of studying at the adhesive layer that possesses close environment and useful human body, and logins to disclose in No. 351938 in (Korea S) utility model and a kind ofly stack gradually the furniture art work of making behind heat fusing rete and the metallic film on particieboard (Particle board) or MDF inanimate matter flaggy.But the impact strength of above-mentioned material is more weak.
Applicant of the present invention finds when researching and solving scheme at above-mentioned prior art problems, two surperficial stacked ox-hide base materials at inanimate matter board, and between above-mentioned inanimate matter board and ox-hide layer, form the heat fusing rete, also outstanding cohesive force and mechanical strength can have been given play at the difficulty combustion indoor decoration building materials made of colding pressing after the upper layer double exposure of the above-mentioned ox-hide layer brush pattern segments during at low temperature, its tack coat belongs to environmentally friendly, also can not produce toxic gas during burning.
Summary of the invention
The environment-friendly fire-retardant indoor decoration building materials of toxic gas do not take place when the purpose of this invention is to provide a kind of the burning.
To achieve these goals, two surfaces that the present invention specifically is provided at inanimate matter board go up to form the heat fusing retes, and are stacking gradually the ox-hide substrate layer and possess the difficulty combustion indoor decoration building materials of the flower-pattern layer of decorative pattern on above-mentioned heat fusing rete.
The difficult combustion of the present invention indoor decoration building materials can solve by using existing melmac or urea resin adhesive to produce the problem of formaldehyde carcinogen effectively by forming the heat fusing rete, the environmentally friendly building materials of toxic gases such as bioxin can not take place when being a kind of the burning, low production cost not only, operational method is also very simple, needn't prepare the binding agent coating device in addition can insert the heat fusing film simply and carry out operation in lamination process, also can keep good cohesive force at low temperature, improved productivity owing to making in the short time, cheap cost has satisfied economy, the stacked ox-hide base material on the two sides of plate, have excellent mechanical intensity and resistance to water, resistance to water is good, phenomenon is not distorted, embodying beautiful appearance by space pattern, is a kind of very excellent senior difficult combustion indoor decoration building materials.
Description of drawings
Fig. 1 is the environment-friendly fire-retardant indoor decoration building material map of one embodiment of the invention;
Fig. 2 is the environment-friendly fire-retardant indoor decoration building material map of another embodiment of the present invention;
Fig. 3 is the environment-friendly fire-retardant indoor decoration building material map of another embodiment of the present invention;
Fig. 4 is the environment-friendly fire-retardant indoor decoration building material map of another embodiment of the present invention.
The explanation of the main symbol of figure
10: inanimate matter board
20: the heat fusing film
30: the ox-hide substrate layer that has flooded phenolic resins
30 ': the cellophane layer that has flooded phenolic resins
40: the printed patterns lamella
50: mirror board
The specific embodiment
The difficult combustion of the present invention indoor decoration building materials form the heat fusing rete on two surfaces of inanimate matter board, the ox-hide substrate layer of phenolic resins, melmac or urea resin has been flooded in configuration on above-mentioned heat fusing rete, and the printed patterns lamella of melmac or urea resin has been flooded in configuration on above-mentioned ox-hide substrate layer.
Below in conjunction with accompanying drawing the difficult combustion of the present invention indoor decoration building materials are described further.
Fig. 1 is the environment-friendly fire-retardant indoor decoration building material map of one embodiment of the invention.On as a surface of the inanimate matter board (10) of base material, form heat fusing rete (20), on above-mentioned heat fusing rete (20), stack gradually ox-hide substrate layer (30) that has flooded phenolic resins and the printed patterns lamella (40) that has flooded melmac or urea resin, on another surface of above-mentioned inanimate matter board (10), stack gradually heat fusing rete (20), flooded the ox-hide substrate layer (30) of phenolic resins and flooded the printed patterns lamella (40) of melmac or urea resin.
The base material of the difficult combustion of the present invention indoor decoration building materials can use all available inanimate matter boards usually, specifically can use to be bonded on the fused film of the present invention and can to embody inanimate matter board as the bond effect of product.The preferred inanimate matter board that comprises materials such as sodium, potassium, magnesium, iron, aluminium, hydroxyl and fluorine that uses more preferably uses the magnesium plate.At this moment, thickness can be adjusted along with the purposes of this plate, is preferably 15mm.
Above-mentioned heat fusing rete of the present invention has fusion at a certain temperature after supercooling process and possess the characteristic (thermoplasticity) of cohesive force, and use as binding agent, can be when bonding have the mirror board of convex-concave surface, as the filler of filling each concavo-convex space and keep concaveconvex shape.Above-mentioned heat fusing film has been owing to possessed the film form, therefore can apply equably and needn't add solvent (volatile organic matter) or other material, for having solved effectively along with the close environmentally conscious materials of the problem of noxious material is discharged in the organic solvent volatilization.
Preferred above-mentioned heat fusing film uses the film form.Above-mentioned heat fusing film more can be brought into play excellent bond effect when substrate layer described later belongs to metal.When being bonded in metal on by mode of heating phenolic resins, epoxy resin or polyurethane resin, different dilatancy will cause twisted phenomena in the past.Specifically, expand and the contraction of above-mentioned resin bed after metal level is heated.Yet the convergent force diversity ratio between heat fusing film of the present invention and the metal level is less, and phenomenon therefore can not be distorted.And can not appear at the present invention as the polluter of resin greatest problem in the past yet, fire the indoor decoration building materials thereby constituted difficulty with environment compatibility and useful human body.
Above-mentioned heat fusing film can use all general industrial heat fused film, uses after preferably can being selected from the one or more mixture in ethylene-vinyl acetate copolymer resin, polyvinyl resin, ethylene-ethyl acrylate copolymer resin, vinyl acetate resin and the polyvinyl butyral resin.
Above-mentioned ox-hide substrate layer of the present invention (30) is layered on the above-mentioned heat fusing rete and enhance mechanical strength, can play the effect of uniform outer surface smoothness because used inanimate matter board has surface roughness, also can be immersed in carry out behind the phenolic resins stacked.Shown in Fig. 2 and 4,, can use glassine paper (30 ') to substitute above-mentioned ox-hide substrate layer and carry out stacked in order to improve flame retardancy and to improve stability.
At this moment, in order to realize environment compatibility purpose of the present invention, preferably make the content of phenolic resins account for 25-35 weight % with respect to above-mentioned ox-hide base material.
Above-mentioned printed patterns lamella of the present invention can embody other function of the beautiful outward appearance of indoor decoration building materials and flame retardancy and so on, preferably can use the printed patterns scraps of paper, can also use decorative pattern wood, fabric, print film and metallic film etc.Wherein, decorative pattern wood not only itself can form a layer, can also be folded thereon the surface peening ply of paper that has flooded melmac for the problem that solves surperficial scratch and so on.Only used a small amount of melmac in order to realize the present invention to pursue the purpose of environmentally friendly indoor decoration building materials, preferably its content accounts for 45-55 weight % with respect to surface peening paper.In order on above-mentioned surface peening paper, to add difficult combustion function, can impregnation of phosphoric acid salt, the additive of boron, halogen, antimony and nitrogen and so on.
At this moment, the outer patterns on two sides can be used distinct patterns.
As shown in Figure 3, on above-mentioned printed patterns lamella (40), comprise mirror board (50) in addition in order to give indoor decoration building material surface match volume with pattern.Above-mentioned mirror board is a kind of mould version, can take light
Figure G2008101658592D00051
Unglazed
Figure G2008101658592D00052
And different shape such as embossing, on above-mentioned mirror board, carry out behind the various patterns of carved pattern pattern and so on when stacked, the engraving position will in the thermmohardening process, form embossment with cloudy the quarter generation match volume.
The difficult combustion of the present invention indoor decoration building materials are made by hot pressing process behind each layer stacked.At this moment, the unit pressure of above-mentioned hot pressing process is 40-60kg/cm 2, under 120-150 ℃ press temperature (presstemperature), kept 20-25 minute, dismantle by cooling or thermal processing method again behind the hot pressing process.The difficulty combustion indoor decoration building materials that use said method to make can be applied to purposes such as the door of kitchen sink cabinet and wallboard.
The difficulty combustion indoor decoration building materials that use said method to make can solve owing to use existing melmac or urea resin adhesive to produce the problem of formaldehyde carcinogen effectively by forming the heat fusing rete, the environmentally friendly building materials of toxic gases such as bioxin can not take place when being a kind of the burning, low production cost not only, operational method is also very simple, needn't prepare the binding agent coating device in addition can insert the heat fusing film simply and carry out operation in lamination process, also can keep good cohesive force at low temperature, improved productivity owing to making in the short time, cheap cost has satisfied economy, have excellent mechanical intensity and resistance to water, resistance to water is good, phenomenon is not distorted, embodying beautiful appearance by space pattern, is a kind of very excellent senior difficult combustion indoor decoration building materials.

Claims (3)

1. environment-friendly fire-retardant indoor decoration building materials is characterized in that:
On as a surface of the magnesium plate of base material, form the heat fusing rete, this heat fusing rete is to be selected from ethylene-vinyl acetate copolymer resin, polyvinyl resin, the ethylene-ethyl acrylate copolymer resin, more than one mixture in vinyl acetate resin and the polyvinyl butyral resin, on described heat fusing rete, stack gradually the ox-hide substrate layer of the phenolic resins that has flooded 25~35 weight % that account for the ox-hide substrate layer and flooded the printed patterns lamella of melmac or urea resin
Another surface at described magnesium plate stacks gradually the heat fusing rete, flooded 25~35 weight % that account for the ox-hide substrate layer phenolic resins the ox-hide substrate layer and flooded the printed patterns lamella of melmac or urea resin, wherein, described heat fusing rete is the more than one mixture that is selected from ethylene-vinyl acetate copolymer resin, polyvinyl resin, ethylene-ethyl acrylate copolymer resin, vinyl acetate resin and the polyvinyl butyral resin.
2. environment-friendly fire-retardant indoor decoration building materials is characterized in that:
On as a surface of the magnesium plate of base material, form the heat fusing rete, this heat fusing rete is the more than one mixture that is selected from ethylene-vinyl acetate copolymer resin, polyvinyl resin, ethylene-ethyl acrylate copolymer resin, vinyl acetate resin and the polyvinyl butyral resin, on described heat fusing rete, stack gradually the cellophane layer that has flooded phenolic resins and flooded the printed patterns lamella of melmac or urea resin
Another surface at described magnesium plate stacks gradually the heat fusing rete, flooded 25~35 weight % that account for the ox-hide substrate layer phenolic resins the ox-hide substrate layer and flooded the printed patterns lamella of melmac or urea resin, wherein, described heat fusing rete is the more than one mixture that is selected from ethylene-vinyl acetate copolymer resin, polyvinyl resin, ethylene-ethyl acrylate copolymer resin, vinyl acetate resin and the polyvinyl butyral resin.
3. environment-friendly fire-retardant indoor decoration building materials according to claim 1 is characterized in that, also comprise the mirror board that possesses space pattern having flooded on the printed patterns lamella of melmac or urea resin.
CN2008101658592A 2008-02-05 2008-09-25 Environment-friendly fire-retardant indoor decoration materials with 3d pattern Expired - Fee Related CN101503902B (en)

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KR20-2008-0001750 2008-02-05
KR20080001750 2008-02-05
KR2020080001750 2008-02-05

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176884A (en) * 1996-07-16 1998-03-25 普雷马克Rwp控股公司 Method of coating melamine resin on laminating paper
US5989668A (en) * 1998-10-16 1999-11-23 Nelson; Thomas J. Waterproof laminate panel
CN1436660A (en) * 2002-02-07 2003-08-20 普雷马克Rwp控股公司 Compositely formable decorative laminate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176884A (en) * 1996-07-16 1998-03-25 普雷马克Rwp控股公司 Method of coating melamine resin on laminating paper
US5989668A (en) * 1998-10-16 1999-11-23 Nelson; Thomas J. Waterproof laminate panel
CN1436660A (en) * 2002-02-07 2003-08-20 普雷马克Rwp控股公司 Compositely formable decorative laminate

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Inventor after: Jin Xiangxie

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