CN110561862A - Novel environment-friendly flame-retardant wood profile and manufacturing method thereof - Google Patents
Novel environment-friendly flame-retardant wood profile and manufacturing method thereof Download PDFInfo
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- CN110561862A CN110561862A CN201910948973.0A CN201910948973A CN110561862A CN 110561862 A CN110561862 A CN 110561862A CN 201910948973 A CN201910948973 A CN 201910948973A CN 110561862 A CN110561862 A CN 110561862A
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- retardant
- layer
- flame
- base material
- wood
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 291
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 254
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 43
- 239000002023 wood Substances 0.000 title claims description 75
- 239000000758 substrate Substances 0.000 claims abstract description 61
- 238000012545 processing Methods 0.000 claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000007613 environmental effect Effects 0.000 claims abstract description 9
- 239000010410 layer Substances 0.000 claims description 266
- 238000007731 hot pressing Methods 0.000 claims description 99
- 239000000463 material Substances 0.000 claims description 80
- 239000012790 adhesive layer Substances 0.000 claims description 70
- 230000003014 reinforcing effect Effects 0.000 claims description 45
- 238000013329 compounding Methods 0.000 claims description 21
- 239000012792 core layer Substances 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 230000017525 heat dissipation Effects 0.000 claims description 12
- 239000011094 fiberboard Substances 0.000 claims description 7
- 239000011120 plywood Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 210000001145 finger joint Anatomy 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 34
- 230000000694 effects Effects 0.000 abstract description 26
- 239000013043 chemical agent Substances 0.000 abstract description 15
- 238000002485 combustion reaction Methods 0.000 abstract description 7
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 230000002787 reinforcement Effects 0.000 description 11
- 238000001035 drying Methods 0.000 description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- 238000005034 decoration Methods 0.000 description 8
- 238000004321 preservation Methods 0.000 description 8
- 239000000123 paper Substances 0.000 description 7
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000002341 toxic gas Substances 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- 239000012757 flame retardant agent Substances 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 238000000053 physical method Methods 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000007605 air drying Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- -1 shaving board Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
- B27D1/04—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
-
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- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
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- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/08—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
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- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
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- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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- B32B2255/00—Coating on the layer surface
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- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
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- B32B2264/102—Oxide or hydroxide
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
Abstract
The application provides an embodiment provides a fire-retardant wooden section bar of novel environmental protection and manufacturing method thereof, from top to bottom includes the fire-retardant veneer of first fire-retardant veneer, substrate layer, the second that bonds each other in proper order, is at least the upper strata portion of the thickness direction of substrate layer is formed with fire-retardant enhancement layer, first fire-retardant veneer the fire-retardant veneer of second is the aluminium oxide sticker. The flame retardant effect is good, the production cost is relatively low, and the combustion process (flame retardant process) is relatively safe and preferable; the processing process of the manufacturing method is free of chemical agent addition and pollutant formation, is relatively environment-friendly, and has relatively high production efficiency while achieving relatively high flame retardant effect.
Description
Technical Field
The application relates to the technical field of flame-retardant wooden sectional materials, in particular to a novel environment-friendly flame-retardant wooden sectional material, and also relates to a manufacturing method of the flame-retardant wooden sectional material.
Background
The wood material is a natural material, has excellent visual, tactile, auditory and other environmental characteristics, has excellent strength-to-weight ratio and is incomparable with other materials (such as wood plastics, straw shavings, stone materials, metal materials and the like). The wood material is often used for interior decoration of houses, public places and vehicles, and the flame retardant property of the wood material is an important index of wood products.
the fire retardant wood profiles of the prior art generally comprise 3 forms: the first one is to compound the wood material with the physical flame retardant material, such as the wear resistant flame retardant floor disclosed in chinese patent 201120279673.7, which achieves a certain flame retardant effect by bonding the alumina wear resistant paper on the surface of the wood substrate; the second is to perform densification and impregnation treatment on a wood material, such as a compressed flame retardant profile disclosed in chinese patent 201210457197.2, which achieves the flame retardant effect of the wood profile by performing densification treatment on a fast growing wood and then impregnating a chemical flame retardant agent; the third is to dip the wood material into the fire retardant agent, for example, in the fire retardant and wear resistant solid wood composite floor disclosed in chinese patent 200720187592.8, the solid wood material is dipped into the fire retardant agent and then bonded with the alumina wear resistant layer (the alumina particles in the wear resistant layer are mainly used for wear resistance).
For the first flame-retardant section and the flame-retardant method thereof, the flame-retardant effect only depends on the flame-retardant effect of the aluminum oxide wear-resistant paper, the flame-retardant effect is not good if the amount of aluminum oxide of the aluminum oxide wear-resistant paper is insufficient, and the manufacturing cost is too high if the amount of aluminum oxide is sufficient; for the second and third flame-retardant section bars and the flame-retardant method thereof, although various flame-retardant additives can achieve good flame-retardant effect, part of flame-retardant agents can form toxic gas during combustion (namely flame-retardant), so that the risk of fire is improved, meanwhile, the dipping treatment time for dipping the flame-retardant agents is longer, and the drying and curing time after treatment is also relatively longer, so that the production period is long and the production efficiency is low.
Disclosure of Invention
The first technical purpose of the invention is to overcome the problems of poor flame retardant effect of the flame retardant wood section bar in the prior art or toxic gas generation in the flame retardant process, thereby providing a novel environment-friendly flame retardant wood section bar with good flame retardant effect, relatively low production cost and relatively safe combustion process (flame retardant process); the second technical objective of the present invention is to overcome the problem of adding a large amount of chemical agents in the manufacturing method of the flame-retardant wood profile in the prior art, and to provide a manufacturing method of a novel environment-friendly flame-retardant wood profile, wherein the processing process of the manufacturing method is relatively environment-friendly without adding chemical agents and forming pollutants, and has relatively high production efficiency while achieving relatively high flame-retardant effect.
For realizing the above-mentioned first technical purpose, an embodiment of this application provides a fire-retardant wooden section bar of novel environmental protection, from top to bottom include the fire-retardant veneer of first fire-retardant veneer, substrate layer, second that bond each other in proper order, at least the upper strata portion of the thickness direction of substrate layer is formed with fire-retardant enhancement layer, first fire-retardant veneer the fire-retardant veneer of second is the aluminium oxide sticker.
By means of the structure, the novel environment-friendly flame-retardant wood sectional material utilizes the substrate layer with relatively large air-dry density and is matched with the first flame-retardant adhesive layer and the second flame-retardant adhesive layer to form a relatively effective flame-retardant effect by the upper flame-retardant reinforcing layer formed on the upper layer of the substrate layer in the thickness direction; meanwhile, the substrate layer with relatively high air-dry density, the first flame-retardant adhesive layer and the second flame-retardant adhesive layer have physical flame-retardant effects, so that no toxic gas is generated in the combustion process, and the flame-retardant adhesive layer is relatively safe.
As a preferable technical solution, a lower flame-retardant reinforcing layer is further formed at a lower layer portion in the thickness direction of the base material layer, and a core layer is formed at a middle layer portion in the thickness direction of the base material layer, and the upper flame-retardant reinforcing layer, the core layer, and the lower flame-retardant reinforcing layer are naturally connected thickness portions of the same material and different densities.
As a preferable technical scheme, the thickness of the upper flame-retardant reinforcing layer accounts for 5% -10% of the total thickness of the base material layer, and the thickness of the lower flame-retardant reinforcing layer accounts for 5% -10% of the total thickness of the base material layer.
As a preferred technical scheme, the upper flame-retardant reinforced layer has the air-dry density of not less than 1000kg/m3The lower flame-retardant reinforcing layer has an air-dry density of not less than 1000kg/m3The thickness portion of (2).
As a preferable technical scheme, the air-dried density of the core layer is not less than 800kg/m3The thickness portion of (a).
As a preferred technical solution, the upper flame retardant is reinforcedThe layer and the lower flame-retardant reinforcing layer have the air dry density of 1000kg/m3-1500kg/m3The core layer has an air dry density of 800kg/m3-900kg/m3The thickness portion of (a).
As a preferable technical scheme, the novel environment-friendly flame-retardant wood profile further comprises a first wood skin layer bonded on the surface of the first flame-retardant adhesive layer and a second wood skin layer bonded on the bottom surface of the second flame-retardant adhesive layer.
As a preferable technical scheme, the thickness of the first wood skin layer and the thickness of the second wood skin layer are both 0.3mm-0.5 mm.
As a preferred technical scheme, the novel environment-friendly flame-retardant wood profile further comprises a decorative layer bonded on the surface of the first wood skin layer and a balance layer bonded on the bottom surface of the second wood skin layer.
As a preferable technical solution, a heat dissipation layer is provided on the decoration layer, and the heat dissipation layer is a metal coating.
As a preferred technical scheme, the substrate layer is one of medium/high density fiber board, multilayer plywood, three-layer plywood, shaving board, solid wood board, finger joint board and laminated wood.
In order to achieve the second technical object, a second embodiment of the present application provides a method for manufacturing a novel environmentally friendly flame retardant wood profile, which includes the following steps:
S1, processing the base material, in the processing step of the base material, the base material layer is processed by hot pressing, so that the upper flame-retardant reinforced layer is formed on at least the upper layer part of the base material layer in the thickness direction, and the air-dried density of the upper flame-retardant reinforced layer is not less than 1000kg/m3;
S2, compounding, wherein in the compounding step, a first flame-retardant adhesive layer, a base material layer and a second flame-retardant adhesive layer are sequentially placed from top to bottom, and the base material layer and the second flame-retardant adhesive layer are obtained after the base material processing step, and the first flame-retardant adhesive layer, the base material layer and the second flame-retardant adhesive layer are subjected to hot-pressing compounding at the hot-pressing temperature of 100-150 ℃.
By means of the manufacturing method, the density of the base material layer is improved through physical hot-pressing treatment, and the first flame-retardant adhesive layer and the second flame-retardant adhesive layer are bonded on the upper surface and the lower surface of the base material layer through the physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method is free of chemical agent addition and pollutant formation, and is relatively environment-friendly. Meanwhile, the chemical agent impregnated flame-retardant treatment method needs longer impregnation treatment time, longer secondary drying and health preservation treatment time, and the manufacturing method of the technical scheme of the application only needs twice hot-pressing treatment, and then the novel environment-friendly flame-retardant wooden section bar of the technical scheme of the application is subjected to timing treatment without drying and health preservation treatment, so that the flame-retardant treatment time is shortened, and therefore, the relatively higher flame-retardant effect is achieved, and the relatively higher production efficiency is achieved.
as a preferable technical scheme, in the step of processing the base material, the hot pressing temperature of the upper hot pressing plate is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s.
As a preferable technical solution, in the step of treating the base material, the base material layer is treated by hot pressing to form three thickness portions with different densities in a thickness direction, wherein the three thickness portions are an upper flame-retardant reinforcing layer, a core layer and a lower flame-retardant reinforcing layer, and the air-dried densities of the upper flame-retardant reinforcing layer and the lower flame-retardant reinforcing layer are not less than 1000kg/m3The air-dry density of the core layer is not less than 800kg/m3。
As a preferred technical scheme, in the step of processing the base material, the hot pressing temperature of the upper hot pressing plate and the lower hot pressing plate is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s.
As preferred technical scheme in the compound step, from top to bottom place first wooden cortex, first fire-retardant veneer, warp in proper order the processing step of substrate layer, the fire-retardant veneer of second, the wooden cortex of second, and will first wooden cortex first fire-retardant veneer the substrate layer the fire-retardant veneer of second the hot-pressing of second wooden cortex is compound.
In order to achieve the second technical object, a third embodiment of the present application provides a method for manufacturing a novel environment-friendly flame-retardant wooden profile, which comprises sequentially placing a first flame-retardant coating, a substrate layer, and a second flame-retardant coating from top to bottom, and performing hot-pressing compounding on the first flame-retardant coating, the substrate layer, and the second flame-retardant coating, wherein the hot-pressing temperature of the upper and lower hot-pressing plates is 100 ℃ to 150 ℃, the hot-pressing pressure is 7.0MPa to 12.0MPa, and the hot-pressing time is 50s to 400 s.
In summary, the novel environment-friendly flame-retardant wooden profile disclosed by the application utilizes the substrate layer with relatively large air-drying density by the upper flame-retardant reinforcing layer formed on the upper layer in the thickness direction of the substrate layer, and is matched with the first flame-retardant adhesive layer and the second flame-retardant adhesive layer to form a relatively effective flame-retardant effect; meanwhile, the substrate layer with relatively high air-dry density, the first flame-retardant adhesive layer and the second flame-retardant adhesive layer have physical flame-retardant effects, so that no toxic gas is generated in the flame-retardant process, and the flame-retardant adhesive layer is relatively safe. According to the manufacturing method of the novel environment-friendly flame-retardant wood profile, the density of the base material layer is improved through physical hot-pressing treatment, and the first flame-retardant adhesive layer and the second flame-retardant adhesive layer are bonded on the upper surface and the lower surface of the base material layer through the physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method is free of chemical agent addition, free of pollutant formation and relatively environment-friendly. Meanwhile, the chemical agent impregnated flame-retardant treatment method needs longer impregnation treatment time, longer secondary drying and health preservation treatment time, and the manufacturing method of the technical scheme of the application only needs twice hot-pressing treatment, and then the novel environment-friendly flame-retardant wooden section bar of the technical scheme of the application is subjected to timing treatment without drying and health preservation treatment, so that the flame-retardant treatment time is shortened, and therefore, the relatively higher flame-retardant effect is achieved, and the relatively higher production efficiency is achieved.
meanwhile, the manufacturing method of the novel environment-friendly flame-retardant wood profile improves the density of the base material layer through physical hot-pressing treatment, and bonds the first and second flame-retardant adhesive layers on the upper and lower surfaces of the base material layer through the physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with the modification treatment of chemical agents, the method is free of chemical agent addition and pollutant formation, and is relatively environment-friendly. Meanwhile, the chemical agent impregnated flame-retardant treatment method needs longer impregnation treatment time, longer secondary drying and health preservation treatment time, and the manufacturing method of the technical scheme of the application only needs twice hot-pressing treatment, and then the novel environment-friendly flame-retardant wooden section bar of the technical scheme of the application is subjected to timing treatment without drying and health preservation treatment, so that the flame-retardant treatment time is shortened, and therefore, the relatively higher flame-retardant effect is achieved, and the relatively higher production efficiency is achieved.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this application, illustrate embodiments of the invention and, together with the description, serve to explain the invention and not to limit the invention. In the drawings:
Fig. 1 is a schematic structural diagram of a novel environment-friendly flame-retardant wood profile in example 1 of the present invention;
Fig. 2 is a schematic structural diagram of the novel environment-friendly flame-retardant wood profile of embodiment 2 of the invention;
Fig. 3a is a graph showing the correspondence between the hot pressing temperature and the thickness of the upper and lower fire-retardant reinforcing layers in the method for manufacturing the novel environment-friendly fire-retardant wooden profile of embodiment 2 of the present invention;
Fig. 3b is a corresponding relationship diagram between the hot pressing temperature and the densities of the upper and lower flame-retardant reinforcing layers in the method for manufacturing the novel environment-friendly flame-retardant wooden profile of embodiment 2 of the invention;
FIG. 4 is a comparison chart of the process parameters and the results of the flame retardant property tests of the novel environment-friendly flame retardant wood profile manufactured by the manufacturing method of the embodiment 1-4 of the invention;
In the above drawings: 100-a substrate layer, 200-a first flame-retardant adhesive layer, 300-a second flame-retardant adhesive layer, 400-a first veneer layer, 500-a second veneer layer, 600-a decorative layer, 700-a balance layer, 800-a heat dissipation layer, 110-an upper flame-retardant enhancement layer, 120-a core layer and 130-a lower flame-retardant enhancement layer.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Example 1: referring to the figure, the novel environment-friendly flame-retardant wood profile sequentially comprises a first flame-retardant adhesive layer 200, a base material layer 100 and a second flame-retardant adhesive layer 300 which are bonded with each other from top to bottom, wherein an upper flame-retardant reinforcing layer 110 is formed on an upper layer part of the base material layer 100 in the thickness direction. Wherein, the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 are both aluminum oxide adhesive paper. Specifically, the upper flame-retardant reinforced layer 110 of the present application refers to an air-dried density of not less than 1000kg/m3Preferably, its air-dry density is 1000kg/m3-1500kg/m3(e.g., 1200 kg/m)3)。
With the above structure, the novel environment-friendly flame-retardant wood profile of the embodiment utilizes the upper flame-retardant enhancement layer 110 formed on the upper layer (the surface layer and the part below the surface layer) in the thickness direction of the substrate layer 100, so as to form a relatively effective flame-retardant effect by matching the substrate layer 100 with the first flame-retardant adhesive layer and the second flame-retardant adhesive layers 200 and 300, wherein the substrate layer 100 has a relatively high air-drying density; meanwhile, the substrate layer 100 with relatively high air-dry density and the first and second flame-retardant adhesive layers 200 and 300 have physical flame-retardant effects, so that no toxic gas is generated in the combustion process (flame-retardant process), and the flame-retardant effect is relatively safe.
In the present embodiment, the substrate layer 100 is one of a medium/high density fiberboard, a plywood, a three-layer plywood, a shaving board, a solid wood board, a finger-jointed board, and a laminated wood. The thickness of the substrate layer 100 is designed to be 6mm, 8mm, 10mm, 12mm and the like according to the design requirement of a product, and the thickness of the upper flame-retardant reinforcing layer 110 accounts for 5% -10% of the total thickness of the substrate layer 100. Theoretically, the larger the thickness of the upper flame-retardant reinforcing layer 110 is, the better the flame-retardant effect thereof is, that is, the upper flame-retardant reinforcing layer 110 can occupy the whole thickness of the base material layer 100, but from the aspects of production efficiency, material loss rate (material thickness loss), the correspondence between the thickness of the upper flame-retardant base material layer 110 and the flame-retardant effect, and the like, the preferable minimum thickness of the upper flame-retardant reinforcing layer 110 is 5% of the total thickness of the base material layer 100, and the preferable maximum thickness is 10% of the total thickness of the base material layer 100. That is, when the thickness of the substrate layer 100 is 10mm, the thickness of the upper flame-retardant reinforcing layer 110 should be 0.5mm to 1 mm.
The first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 are melamine stickers added with aluminum oxide particles, and are bonded with the substrate layer 100 through the viscosity of the first flame-retardant adhesive layer after being heated and melted. Preferably, the first flame-retardant coating 200 is a melamine sticker which is added with aluminum oxide particles and has a quantitative weight of 45 grams per square meter, and the second flame-retardant coating is a melamine sticker which is added with aluminum oxide particles and has a quantitative weight of 30 grams per square meter or 33 grams per square meter.
For the convenience of surface decoration, it is preferable that a first wooden skin layer 400 is adhesively provided on the surface of the first flame retardant coating 200 and a second wooden skin layer 500 is adhesively provided on the bottom surface of the second flame retardant coating 300. The surface of the first flame-retardant layer 200 is a surface opposite to the bonding surface to which the substrate layer 100 is bonded, and the bottom surface of the second flame-retardant layer 300 is a surface opposite to the bonding surface to which the substrate layer 100 is bonded. The adhesion between the first wooden skin layer 400 and the second wooden skin layer 500 and the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 is realized by the viscosity of the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 after heating and melting. In this embodiment, the first and second wood skin layers 400 and 500 are rotary-cut wood skins having a thickness of 0.3mm to 0.5mm (preferably 0.5 mm). The effect of setting up first wooden cortex 400, second wooden cortex 500 is the roughness that improves the surface and the back of this application technical scheme's novel fire-retardant wooden section bar of environmental protection to do benefit to the setting of decorative cover.
When this application technical scheme's novel fire-retardant wooden section bar of environmental protection is as a novel laminate flooring wallboard, can bond through the surface at first wooden cortex 400 and set up decorative layer 600, bond at the bottom surface of second wooden cortex 500 and set up balanced layer 700 and realize. The decorative layer 600 is a decorative layer including decorative paper and wear-resistant paper, and the balance layer 700 is melamine balance paper in the prior art.
when this application technical scheme's novel fire-retardant wooden section bar of environmental protection is as a novel laminate flooring wallboard, can bond through the surface at first wooden cortex 400 and set up decorative layer 600, bond at the bottom surface of second wooden cortex 500 and set up balanced layer 700 and realize. The decorative layer 600 is a veneer made by rotary cutting or slicing, and has a thickness of 0.2mm-6mm, and the balance layer 700 is a rotary cut veneer with a thickness of 0.2mm-0.5 mm.
In particular, a heat dissipation layer 800 may also be disposed on top of the decoration layer 600, the heat dissipation layer 800 being a metal coating. The heat dissipation layer 800 may be a metal spray coating, such as a metal spray coating with alumina particles, which is sprayed on the decoration layer 600 through a spraying process. The heat dissipation layer 800 may also be an aluminum oxide sticker, and at this time, the heat dissipation layer 800 is attached on the decoration layer 600 by hot pressing.
The novel environment-friendly flame-retardant wood profile is produced by the following manufacturing method:
s1, a step of processing the base material, in the step of processing the base material, the base material layer 100 is processed by hot pressing, so that the upper flame-retardant reinforced layer 110 is formed on the base material layer 100 at least on the upper layer of the thickness direction of the base material layer, and the air-dried density of the upper flame-retardant reinforced layer 110 is not less than 1000kg/m3;
s2, compounding, wherein in the compounding step, the first flame-retardant adhesive layer 200, the base material layer 100 obtained in the base material processing step and the second flame-retardant adhesive layer 300 are sequentially placed from top to bottom, and the first flame-retardant adhesive layer 200, the base material layer 100 and the second flame-retardant adhesive layer 300 are compounded in a hot pressing mode, wherein the hot pressing temperature is 100-150 ℃.
By means of the manufacturing method, the density of the base material layer is improved through physical hot-pressing treatment, and the first and second flame-retardant adhesive layers 200 and 300 are bonded on the upper surface and the lower surface of the base material layer 100 through the physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method is free of chemical agent addition and pollutant formation, and is relatively environment-friendly. Meanwhile, the chemical agent impregnated flame-retardant treatment method needs longer impregnation treatment time, longer secondary drying and health preservation treatment time, and the manufacturing method of the technical scheme of the application only needs twice hot-pressing treatment, and then the novel environment-friendly flame-retardant wooden section bar of the technical scheme of the application is subjected to timing treatment without drying and health preservation treatment, so that the flame-retardant treatment time is shortened, and therefore, the relatively higher flame-retardant effect is achieved, and the relatively higher production efficiency is achieved.
In the step of treating the substrate, the hot pressing temperature (temperature of the upper hot pressing plate) is 100 ℃ to 150 ℃, the hot pressing pressure is 7.0MPa to 12.0MPa, the hot pressing time is 50s to 400s, the temperature of the lower hot pressing plate is normal temperature, but the temperature of the lower hot pressing plate is about 60 ℃ under the influence of the upper hot pressing plate. As will be known to those skilled in the art, the density and thickness of the upper flame-retardant reinforcing layer 110 can be controlled by controlling the hot-pressing temperature (upper hot-pressing plate temperature), the hot-pressing pressure, and the hot-pressing time. For example, the substrate layer 100 is a composite multilayer plate with a thickness of 10mm, and has an initial water content of 12% -16%:
(1) The hot pressing temperature (the temperature of the upper hot pressing plate) is 100 ℃, the hot pressing pressure is 7.0MPa, the hot pressing time is 50s, and after the step of processing the base material, the upper flame-retardant reinforcing layer 110 with the thickness of about 0.5mm +/-0.5 mm and the density of about 1000kg/m for thin film cultivation is formed on the upper layer of the base material layer 100;
(2) after the step of processing the base material, the upper flame-retardant enhancement layer 110 is formed on the upper substrate layer 100, wherein the hot pressing temperature (the temperature of the upper hot pressing plate) is 150 ℃, the hot pressing pressure is 12.0MPa, the hot pressing time is 400s, and the thickness of the upper flame-retardant enhancement layer is about 1mm +/-0.5 mm, and the density of the upper flame-retardant enhancement layer is about 1500kg/m for +/-50 kg/m;
(3) The hot pressing temperature (temperature of the upper hot pressing plate) is 120 ℃, the hot pressing pressure is 10.0MPa, the hot pressing time is 200s, and after the step of processing the base material, the upper flame-retardant reinforcing layer 110 with the thickness of about 0.8mm +/-0.5 mm and the density of about 1200kg/m for thin film rice and 50kg/m for thin film rice and thin film rice is formed on the upper flame-retardant reinforcing layer 100.
It should be noted that the composite multi-layer board is formed by laminating and compounding the cut-log skin layer and the adhesive, and therefore, in this embodiment, the density of the upper flame-retardant reinforcing layer 110 is the air-dried density with the cut-log skin layer and the adhesive as a whole.
In the compounding step, any one of the pressing and pasting compounding processes in the prior art can be adopted, for example, the hot pressing temperature is 120 ℃, the hot pressing pressure is not applied, and the hot pressing time is 8s-20 s. The compounding step is mainly to make the first and second flame retardant adhesive layers 200,300 melt to form viscosity by hot pressing so as to be adhered to the upper and lower surfaces of the substrate layer 100.
when the novel environment-friendly flame-retardant wood profile is used as a novel reinforced/composite floor/wallboard, in the compounding step, a first wood skin layer 400, a first flame-retardant adhesive layer 200, a substrate layer 100 subjected to the substrate treatment step, a second flame-retardant adhesive layer 300 and a second wood skin layer 500 are sequentially placed from top to bottom, the first wood skin layer 400, the first flame-retardant adhesive layer 200, the substrate layer 100, the second flame-retardant adhesive layer 300 and the second wood skin layer 500 are subjected to hot-pressing compounding, and the hot-pressing compounding process is the same as that described above; then, the decorative layer 600 and the heat dissipation layer 800 are placed on the composite blank, the balance layer 700 is placed under the decorative layer, and the composite process is repeated again.
Example 2: the difference between embodiment 1 and embodiment 2 is that, referring to fig. 2, the substrate layer 100 further includes a core layer 120 and a lower flame-retardant reinforcing layer 130 located below the upper flame-retardant reinforcing layer 110, the core layer 120, and the lower flame-retardant reinforcing layer 130 are naturally connected thickness portions made of the same material, an air-dry density of the lower flame-retardant reinforcing layer 130 is not less than 1000kg/m for cultivation, and an air-dry density of the core layer 120 is not less than 800kg/m for cultivation. Specifically, the dry densities of upper and lower flame-retardant reinforcing layers 110,130 are from 1000kg/m to 1500kg/m, and the dry density of core layer 120 is from 800kg/m to 900 kg/m.
borrow by above-mentioned structure, the fire-retardant wooden section bar of novel environmental protection of this embodiment, it is through forming the fire-retardant enhancement layer 110 in the relatively great upper fire-retardant enhancement layer 110 of density, the relatively less sandwich layer 120 of density, the relatively great lower fire-retardant enhancement layer 130 of density in the thickness direction of substrate layer 100 to compare with the technical scheme of embodiment 1, can realize the fire-retardant technical purpose in the back of the fire-retardant wooden section bar of novel environmental protection. Meanwhile, compared with the technical scheme that only the upper flame-retardant enhancement layer is formed or the substrate layer 100 is integrally processed into the upper flame-retardant enhancement layer, the high-density thickness layer clamps the low-density thickness layer, and is matched with the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300, so that the flame-retardant effect of the wood section can be greatly improved.
The novel environment-friendly flame-retardant wood profile is produced by the following manufacturing method:
And S1, processing the base material, wherein in the step of processing the base material, the base material layer is processed by hot pressing to form three thickness parts with different densities in the thickness direction, the three thickness parts are an upper flame-retardant reinforcing layer 110, a core layer 120 and a lower flame-retardant reinforcing layer 130 respectively, wherein the air-dry densities of the upper flame-retardant reinforcing layer 110 and the lower flame-retardant reinforcing layer 130 are not lower than 1000kg/m for carrying out the thin film ingot, and the air-dry density of the core layer 120 is not lower than 800kg/m for carrying out the thin film ingot.
S2, compounding, wherein in the compounding step, the first flame-retardant adhesive layer 200, the substrate layer 100 after the substrate processing step and the second flame-retardant adhesive layer 300 are sequentially placed from top to bottom, and the first flame-retardant adhesive layer 200, the substrate layer 100 and the second flame-retardant adhesive layer 300 are compounded in a hot pressing manner at the hot pressing temperature of 100-150 ℃.
In the step of processing the base material, the hot pressing temperature is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s. For example, the substrate layer 100 is a high-density fiber board with a thickness of 8mm, and has an initial water content of 12% -16%:
(1) The hot pressing temperature (temperature of the upper and lower hot pressing plates) is 100 ℃, the hot pressing pressure is 7.0MPa, the hot pressing time is 50s, and after the step of processing the substrate, the upper flame retardant reinforcement layer 110 formed on the upper layer of the substrate layer 100 has a thickness of about 0.4mm ± 0.2mm, a density of about 1000kg/m cultivation ± 50kg/m cultivation, the lower flame retardant reinforcement layer 130 formed on the upper layer of the substrate layer 100 has a thickness of about 7.2mm ± 0.2mm, a density of about 800kg/m cultivation ± 50kg/m cultivation, a thickness of about 0.4mm ± 0.2mm, a density of about 1000kg/m cultivation ± 50kg/m cultivation, and the density of the core layer 120 is unchanged in the manufacturing method (1) due to the relatively high density of the high density fiberboard itself.
(2) After the step of processing the substrate, an upper flame-retardant reinforcement layer 110 is formed on the upper layer of the substrate layer 100 with a thickness of about 0.7mm ± 0.2mm and a density of about 1500kg/m ± 50kg/m, an upper flame-retardant reinforcement layer 110 is formed with a thickness of about 6.2mm ± 0.2mm and a density of about 900kg/m ± 50kg/m, and a lower flame-retardant reinforcement layer 130 is formed with a thickness of about 0.7mm ± 0.2mm and a density of about 1500kg/m ± 50kg/m, because the high-density fiberboard has a relatively high density, in the manufacturing method (2), although the densities of the upper flame-retardant reinforcement layer 110, the core layer 120 and the lower flame-retardant reinforcement layer 130 are increased, the ratio of the thicknesses of the upper flame-retardant reinforcement layer 110 and the lower flame-retardant reinforcement layer 130 to the total thickness is smaller than that in embodiment 1, about 8.5%.
(3) The hot pressing temperature (temperature of the upper and lower hot pressing plates) is 120 ℃, the hot pressing pressure is 10.0MPa, the hot pressing time is 200s, and after the step of processing the substrate, the upper flame retardant reinforcement layer 110 formed on the upper layer of the substrate layer 100 has a thickness of about 0.5mm ± 0.2mm, a density of about 1200kg/m for ± 50kg/m for cultivation, the core layer 120 formed on the upper layer of the substrate layer 100 has a thickness of about 6.0mm ± 0.2mm, a density of about 870kg/m for ± 50kg/m for cultivation, and the lower flame retardant reinforcement layer 130 formed on the lower layer of the upper layer of the substrate layer 100 has a thickness of about 0.5mm ± 0.2mm, a density of about 1200kg/m for ±.
In the treatment processes (1) to (3) of the steps of the substrate treatment of the present embodiment, the corresponding graph of the hot pressing temperature and the thicknesses of the upper and lower flame-retardant reinforcing layers 110,130 is shown in fig. 3a, and the corresponding graph of the hot pressing temperature and the densities of the upper and lower flame-retardant reinforcing layers 110,130 is shown in fig. 3 b.
The specific process of the compounding step in this example was the same as that described in example 1.
Example 3: the manufacturing method of the novel environment-friendly flame-retardant wood profile in the embodiment 3 and the embodiment 2 is different in that the first flame-retardant adhesive layer 200, the base material layer 100 and the second flame-retardant adhesive layer 300 are sequentially placed from top to bottom, and the first flame-retardant adhesive layer 200, the base material layer 100 and the second flame-retardant adhesive layer 300 are hot-pressed and compounded, wherein the hot-pressing temperature is 150 ℃, the hot-pressing pressure is 10.0MPa, and the hot-pressing time is 200 s. In this embodiment, the substrate layer 100 is a solid wood sheet (poplar wood sheet with an air-dried density of 0.5 kg/m) with a thickness of 16mm, and the substrate layer 100, the first and second flame-retardant adhesive layers 200 and 300 are obtained by one-time hot-pressing and compounding and reinforcing.
Example 4: the manufacturing method of the novel environment-friendly flame-retardant wood profile in the embodiment 4 is different from the manufacturing method of the novel environment-friendly flame-retardant wood profile in the embodiment 2 in that the decoration layer 600, the first wood skin layer 400, the first flame-retardant adhesive layer 200, the base material layer 100, the second flame-retardant adhesive layer 300, the second wood skin layer 500 and the balance layer 700 are sequentially arranged from top to bottom, the hot pressing temperature (the temperature of the upper hot pressing plate and the lower hot pressing plate) is 150 ℃, the hot pressing pressure is 12.0MPa, and the hot pressing time is 400 s. After the hot pressing process is completed, the heat dissipation layer 800 is sprayed on the decoration layer 600.
The new flame-retardant wood profiles prepared by the manufacturing methods in examples 1, 2, 3 and 4 are classified by using detector combustion performance of GB 8624-2012 classification of combustion performance of building materials and products, and a comparison graph of process parameters and results of flame-retardant performance test is shown in fig. 4. Wherein, the comparison group 1 is a composite multilayer board without flame retardant treatment, the comparison group 2 is a composite multilayer board (the flame retardant agent is ammonium polyphosphate solution with the concentration of 35 wt% -45 wt%) with flame retardant dipping treatment, and the comparison group 3 is a high-density fiberboard without flame retardant treatment.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, it should be noted that, for those skilled in the art, many modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (10)
1. The utility model provides a fire-retardant wooden section bar of novel environmental protection, its characterized in that includes first fire-retardant coating (200), substrate layer (100), the fire-retardant coating of second (300) that bond each other from top to bottom in proper order, is at least the upper strata portion of the thickness direction of substrate layer (100) is formed with fire-retardant enhancement layer (110), first fire-retardant coating (200) the fire-retardant coating of second (300) are the aluminium oxide sticker.
2. The novel environment-friendly flame-retardant wood profile as claimed in claim 1, wherein a lower flame-retardant reinforcing layer (130) is further formed at the lower layer part of the substrate layer (100) in the thickness direction, a core layer (120) is formed at the middle layer part of the substrate layer (100) in the thickness direction, and the upper flame-retardant reinforcing layer (110), the core layer (120) and the lower flame-retardant reinforcing layer (130) are naturally connected and have different thicknesses made of the same material.
3. The novel environment-friendly flame-retardant wood profile as claimed in claim 2, wherein the thickness of the upper flame-retardant reinforcing layer (110) accounts for 5-10% of the total thickness of the substrate layer (100), and the thickness of the lower flame-retardant reinforcing layer (130) accounts for 5-10% of the total thickness of the substrate layer (100).
4. The novel environment-friendly flame-retardant wood profile as claimed in claim 2, wherein the upper flame-retardant reinforcing layer (110) has an air-dry density of not less than 1000kg/m3The lower flame-retardant reinforcing layer (130) has an air-dry density of not less than 1000kg/m3The air-dried density of the core portion in the thickness direction of the base material layer (100) is not less than 800kg/m3。
5. The novel environment-friendly flame-retardant wood profile as claimed in claim 1, further comprising a first wood skin layer (400) adhered to the surface of the first flame-retardant veneer layer (200), and a second wood skin layer (500) adhered to the bottom surface of the second flame-retardant veneer layer (300).
6. the novel environmentally friendly flame retardant wood profile as claimed in claim 5, further comprising a decorative layer (600) adhered to the surface of the first wood skin layer (400), and a balance layer (700) adhered to the bottom surface of the second wood skin layer (500).
7. the novel environment-friendly flame retardant wood profile as claimed in claim 5, wherein the decorative layer (600) is provided with a heat dissipation layer (800), and the heat dissipation layer (800) is a metal coating.
8. The novel environmentally friendly flame retardant wood profile according to any one of claims 1 to 7, wherein the substrate layer (100) is one of medium/high density fiber board, multilayer plywood, three-layer plywood, wood shaving board, solid wood board, finger joint board and laminated wood.
9. The manufacturing method of the novel environment-friendly flame-retardant wood profile is characterized by comprising the following steps of:
s1, a step of processing the base material, in the step of processing the base material, the base material layer (100) is processed by hot pressing, so that the base material layer (100) forms an upper flame-retardant reinforced layer (110) at least at the upper layer part of the thickness direction of the base material layer, and the air-dried density of the upper flame-retardant reinforced layer (110) is not less than 1000kg/m3;
S2, compounding, wherein in the compounding step, a first flame-retardant adhesive layer (200), a base material layer (100) and a second flame-retardant adhesive layer (300) are sequentially placed from top to bottom, and the base material layer (100) and the second flame-retardant adhesive layer (300) are obtained after the base material processing step, and the first flame-retardant adhesive layer (200), the base material layer (100) and the second flame-retardant adhesive layer (300) are subjected to hot-pressing compounding at the hot-pressing temperature of 100-150 ℃.
10. The manufacturing method of the novel environment-friendly flame-retardant wood profile is characterized by sequentially placing a first flame-retardant adhesive layer (200), a base material layer (100) and a second flame-retardant adhesive layer (300) from top to bottom, and performing hot-pressing compounding on the first flame-retardant adhesive layer (200), the base material layer (100) and the second flame-retardant adhesive layer (300), wherein the hot-pressing temperature is 100-150 ℃, the hot-pressing pressure is 7.0-12.0 MPa, and the hot-pressing time is 50-400 s.
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CN201910948973.0A CN110561862A (en) | 2019-10-08 | 2019-10-08 | Novel environment-friendly flame-retardant wood profile and manufacturing method thereof |
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CN111272514A (en) * | 2020-03-25 | 2020-06-12 | 龙泉市亿龙竹木开发有限公司 | Production process and processing equipment of fireproof bamboo board |
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CN101293368A (en) * | 2007-04-23 | 2008-10-29 | 德华集团控股股份有限公司 | Method for producing recombined face-side flame-proof composite floor board |
KR101788541B1 (en) * | 2017-05-15 | 2017-10-23 | 주식회사 스타코리아 | Manufacturing method for eco-friendly flooring having high fire prevention and flame retardant |
CN210792340U (en) * | 2019-10-08 | 2020-06-19 | 红木枋家居科技(湖州)有限公司 | Novel environment-friendly flame-retardant wood profile |
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CN101293368A (en) * | 2007-04-23 | 2008-10-29 | 德华集团控股股份有限公司 | Method for producing recombined face-side flame-proof composite floor board |
KR101788541B1 (en) * | 2017-05-15 | 2017-10-23 | 주식회사 스타코리아 | Manufacturing method for eco-friendly flooring having high fire prevention and flame retardant |
CN210792340U (en) * | 2019-10-08 | 2020-06-19 | 红木枋家居科技(湖州)有限公司 | Novel environment-friendly flame-retardant wood profile |
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CN111272514A (en) * | 2020-03-25 | 2020-06-12 | 龙泉市亿龙竹木开发有限公司 | Production process and processing equipment of fireproof bamboo board |
CN111272514B (en) * | 2020-03-25 | 2022-11-22 | 龙泉市亿龙竹木开发有限公司 | Production method and processing equipment of fireproof bamboo board |
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