CN101503594B - Quick-drying single component novel 685 resin paint composition - Google Patents
Quick-drying single component novel 685 resin paint composition Download PDFInfo
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- CN101503594B CN101503594B CN2009100244077A CN200910024407A CN101503594B CN 101503594 B CN101503594 B CN 101503594B CN 2009100244077 A CN2009100244077 A CN 2009100244077A CN 200910024407 A CN200910024407 A CN 200910024407A CN 101503594 B CN101503594 B CN 101503594B
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- resin
- resin paint
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- 229920005989 resin Polymers 0.000 title claims abstract description 39
- 239000011347 resin Substances 0.000 title claims abstract description 39
- 239000003973 paint Substances 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title claims description 12
- 238000001035 drying Methods 0.000 title abstract 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 229920000180 alkyd Polymers 0.000 claims description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 7
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical group CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a quick drying single-component novel 685 resin paint compound. The 685 resin paint compound comprises the following components by weight percentage: 20 to 65 percent of modified resin, 20 to 59.95 percent of pigment filler, 0.01 to 20 percent of organic solvent, and 0.05 to 0.40 percent of special crosslinking agent. The single-component modified resin is taken as the main resin which is used for producing the 685 resin paint. The 685 resin paint compound has the advantages of no extra drying curing agent needed, higher natural drying speed, higher hardness, more convenient construction, stable storage, single-can package, and the like, and also maintains the other advantages of the 685 resin paint. In addition, the paint does not contain free TDI, has low VOC content, meets the national standards and laws and regulations concerning safety, environmental protection, and the like, has the characteristics of safety, environmental protection, and the like, and is an ideal substitute for dual-component 685 resin paint.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of 685 resin paint compositions.
Background technology
Woodwork coating is the main raw of indoor woodenware and furniture decoration, finishing, and single national usage quantity in 2007 reaches 400,000 tons.Woodwork coating can be divided into five big classes such as nitro, alkyd, polyester, urethane, natural fats and oils by filmogen.Typical products is 685 resin paints in polyurethane coating, accounts for 30% share in woodwork coating market.
685 resin paints are a kind of dual-component polyurethane wood lacquer coating that China's coating industry begins to promote May nineteen sixty-eight, are to be the first component with toluene diisocyanate modification short oil alkyd, are component B with the hydroxyl short-oil alkyd.Press 2: 1 or 1: 1 mixing and stirring during construction.Construction can be brushed, is coated with, spraying or roller coating.Compare with natural oil-based paint, have fast do, characteristics such as hardness height.But, containing more free TDI in the first component, serious country, the industry standard of surpassing brought injury and influence to human body and environment.Simultaneously, cause construction inconvenient owing to belong to two-pack.
Summary of the invention
The objective of the invention is in order to overcome the shortcoming of existing 685 resin paints, the new 685 resin paint compositions of a kind of storage-stable, single jar of packing, easy construction, no free TDI, safety and environmental protection are provided.
Purpose of the present invention can reach by following measure:
The new 685 resin paint compositions of a kind of fast dried single-component mainly are made up of following components in weight percentage: modified resin 20%～65%, color stuffing 20%～59.95%, organic solvent 0.01%～20%, special linking agent 0.05%～0.40%; Its preferred proportioning is: modified resin 40%～60%, color stuffing 25%～40%, organic solvent 10%～20%, special linking agent 0.1%～0.3%.
Composition of the present invention can only be made up of said components, also can contain 0.1%～5.0% auxiliary agent.No matter but which kind of forms each component sum of the present composition satisfied 100%.
The modified resin that the present invention adopts is selected from one or more in polyurethane-modified alkyd, acrylic modified alkyd, epoxide modified alkyd or the phenylethene modified alkyd, more preferably polyurethane-modified alkyd or acrylic modified alkyd.Modified resin itself has from the characteristic of doing, and in the present invention, the mutual synergy between modified resin and special glue connection Liu and the solvent has been avoided the free of TDI, makes rate of crosslinking accelerate simultaneously, and the speed of doing certainly increases greatly; But also find that this combination can effectively contain the volatilization of VOC, make the VOC content of final paint far below existing 685 resin paints.
Color stuffing is selected from one or more in titanium dioxide, talcum powder, phthalocyanine blue, phthalein viridescent or the red.
Organic solvent is selected from one or more in 200 solvent oils, acetate butyl or the turps.
The present invention also can be as the case may be or particular requirement, increases various auxiliary agents in composition, as flow agent or dispersion agent etc.Wherein flow agent such as silicone oil, butyl cellulose etc.; Dispersion agent such as paraffin class or metallic soap class etc.
Special linking agent of the present invention is selected diethyl malonate for use.
Production method of the present invention is that color stuffing, organic solvent, special linking agent (perhaps also comprising auxiliary agent) are joined in the modified resin, disperses and grinding forms.
The present invention is that employing single-component modified resin is matrix resin, produce 685 resin paints, having does not need extra oven dry and adds solidifying agent, seasoning speed is faster, hardness is higher, construction is more convenient, storage-stable, single jar of many-sided advantage such as packing, and has kept other advantage of 685 resin paints.Key is not contain free TDI in the lacquer, and VOC content is low, meets the standard and the laws and regulations of aspects such as national security, environmental protection, has characteristics such as safety, environmental protection, is the desirable substitute products of two-pack 685 resin paints.
Embodiment
Embodiment 1
The Polyurethane modified alkyd resin is accounted for 59.95%, and titanium dioxide accounts for 30%, and turps accounts for 10%, and diethyl malonate accounts for 0.05%.Color stuffing, organic solvent, special linking agent are joined in the modified resin, disperse, grind.
Embodiment 2
Acrylic acid modified alkyd resin accounts for 49.9%, and titanium dioxide accounts for 20%, and talcum powder accounts for 10%, and phthalocyanine blue accounts for 2%, 200 solvent oil and accounts for 18%, and diethyl malonate accounts for 0.1%.The preparation method is with embodiment 1.
Embodiment 3
Acrylic acid modified alkyd resin accounts for 45.8%, and titanium dioxide accounts for 25%, and talcum powder accounts for 20%, and phthalocyanine blue accounts for 7%, and diethyl malonate accounts for 0.2%, and silicone oil accounts for 2%.The preparation method is with embodiment 1.
Above-mentioned each routine gained resin paint and conventional grease lacquer and existing 685 resin paints are done performance comparison, the results are shown in Table 1.
Table 1 painting performance synopsis
Claims (4)
1. new 685 resin paint compositions of fast dried single-component is characterized in that mainly being made up of following components in weight percentage:
Modified resin 20～65%
Color stuffing 20～59.95%
Organic solvent 0.01～20%
Special linking agent 0.05～0.4%
Wherein said special linking agent is a diethyl malonate; Described modified resin is selected from one or more in polyurethane-modified alkyd, acrylic modified alkyd, epoxide modified alkyd or the phenylethene modified alkyd.
2. the new 685 resin paint compositions of fast dried single-component according to claim 1 is characterized in that the weight percent of each component is:
Modified resin 40～60%
Color stuffing 25～40%
Organic solvent 10～20%
Special linking agent 0.1～0.3%.
3. the new 685 resin paint compositions of fast dried single-component according to claim 1 and 2 is characterized in that described color stuffing is selected from one or more in titanium dioxide, talcum powder, phthalocyanine blue, phthalein viridescent or the red.
4. the new 685 resin paint compositions of fast dried single-component according to claim 1 and 2 is characterized in that described organic solvent is selected from one or more in 200 solvent oils, acetate butyl or the turps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100244077A CN101503594B (en) | 2009-02-23 | 2009-02-23 | Quick-drying single component novel 685 resin paint composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100244077A CN101503594B (en) | 2009-02-23 | 2009-02-23 | Quick-drying single component novel 685 resin paint composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101503594A CN101503594A (en) | 2009-08-12 |
| CN101503594B true CN101503594B (en) | 2010-10-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100244077A Active CN101503594B (en) | 2009-02-23 | 2009-02-23 | Quick-drying single component novel 685 resin paint composition |
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| Country | Link |
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| CN (1) | CN101503594B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891997A (en) * | 2010-07-02 | 2010-11-24 | 漳州鑫展旺化工有限公司 | Over-solidified crylic acid colored paint and preparation method thereof |
| CN102344742A (en) * | 2011-03-17 | 2012-02-08 | 三棵树涂料股份有限公司 | Novel environment-friendly enamel for metal handicrafts |
| CN112341927A (en) * | 2020-11-04 | 2021-02-09 | 雅图高新材料股份有限公司 | Quick-drying single-component plastic primer and preparation method thereof |
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2009
- 2009-02-23 CN CN2009100244077A patent/CN101503594B/en active Active
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| Publication number | Publication date |
|---|---|
| CN101503594A (en) | 2009-08-12 |
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Owner name: JIANGSU CHAMPION COATINGS TECHNOLOGY GROUP CO., LT Free format text: FORMER NAME: JIANGSU CHAMPION COATING MATERIAL INDUSTRY LTD. |
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Address after: 211219, No. 777, Ping'an West Road, Lishui Industrial Park, Nanjing, Jiangsu Patentee after: JIANGSU CHAMPION GROUP PAINT Co.,Ltd. Address before: Lishui County, Nanjing City, Jiangsu province 211200 Honglan Town Industrial Park Patentee before: Jiangsu Champion Coating Material Industry Ltd. |
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Effective date of registration: 20170825 Address after: Honglan Town Industrial Park, Lishui District of Nanjing City, Jiangsu province 211299 Patentee after: MOUMOU HOLDING GROUP Co.,Ltd. Address before: 211219, No. 777, Ping'an West Road, Lishui Industrial Park, Nanjing, Jiangsu Patentee before: JIANGSU CHAMPION GROUP PAINT Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A quick drying one component new 685 resin paint composition Effective date of registration: 20221026 Granted publication date: 20101013 Pledgee: Jiangsu SINOSURE technology microfinance Co.,Ltd. Pledgor: MOUMOU HOLDING GROUP Co.,Ltd. Registration number: Y2022980019559 |
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Granted publication date: 20101013 Pledgee: Jiangsu SINOSURE technology microfinance Co.,Ltd. Pledgor: MOUMOU HOLDING GROUP Co.,Ltd. Registration number: Y2022980019559 |
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