CN101489960B - 用于制备四氟丙烯和五氟丙烯的催化生产方法 - Google Patents

用于制备四氟丙烯和五氟丙烯的催化生产方法 Download PDF

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Publication number
CN101489960B
CN101489960B CN200780026549.6A CN200780026549A CN101489960B CN 101489960 B CN101489960 B CN 101489960B CN 200780026549 A CN200780026549 A CN 200780026549A CN 101489960 B CN101489960 B CN 101489960B
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hfc
catalyst
product mixture
pentafluoropropene
minutes
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Chinese (zh)
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CN101489960A (zh
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M·J·纳帕
V·N·M·劳
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Chemours Co FC LLC
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EI Du Pont de Nemours and Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200780026549.6A 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法 Active CN101489960B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210144189.2A CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83093906P 2006-07-13 2006-07-13
US60/830,939 2006-07-13
PCT/US2007/015751 WO2008008350A2 (en) 2006-07-13 2007-07-11 Catalytic production processes for making tetrafluoropropenes and pentafluoropropenes

Related Child Applications (1)

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CN201210144189.2A Division CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

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CN101489960A CN101489960A (zh) 2009-07-22
CN101489960B true CN101489960B (zh) 2014-03-05

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CN201210144189.2A Active CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

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Country Link
US (2) US7982073B2 (enExample)
EP (3) EP2041054B1 (enExample)
JP (1) JP5764291B2 (enExample)
CN (2) CN101489960B (enExample)
ES (1) ES2523694T3 (enExample)
RU (1) RU2451659C2 (enExample)
WO (1) WO2008008350A2 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8377327B2 (en) * 2006-06-27 2013-02-19 E I Du Pont De Nemours And Company Tetrafluoropropene production processes
US8232435B2 (en) 2006-09-05 2012-07-31 E I Du Pont De Nemours And Company 1,2,3,3,3-pentafluoropropene production processes
KR101394583B1 (ko) 2006-10-03 2014-05-12 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법
CN103553871A (zh) * 2006-10-31 2014-02-05 纳幕尔杜邦公司 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法
FR2932799B1 (fr) * 2008-06-18 2010-08-13 Arkema France Procede de preparation de composes fluores
US8487145B2 (en) 2009-06-03 2013-07-16 E I De Pont De Nemours And Company Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene
JP5620478B2 (ja) 2009-06-03 2014-11-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ ２，３，３，３−テトラフルオロプロペンを製造するための触媒および方法
CN102686542A (zh) 2009-12-23 2012-09-19 阿克马法国公司 1233xf到1234yf的催化气相氟化
US9492816B2 (en) 2010-05-03 2016-11-15 Arkema Inc. Dehydrofluorination of pentafluoroalkanes to form tetrafluoroolefins
US8513474B2 (en) * 2010-06-24 2013-08-20 Honeywell International Inc. Process for the manufacture of fluorinated olefins
US8263817B2 (en) * 2010-07-06 2012-09-11 E I Du Pont De Nemours And Company Synthesis of 1234YF by selective dehydrochlorination of 244BB
US9724684B2 (en) * 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
GB2492847A (en) * 2011-07-15 2013-01-16 Mexichem Amanco Holding Sa A process for reducing TFMA content in R-1234
WO2013099856A1 (ja) * 2011-12-28 2013-07-04 旭硝子株式会社 ２，３，３，３－テトラフルオロプロペンの精製方法、精製装置および製造方法
GB201207666D0 (en) * 2012-05-02 2012-06-13 Mexichem Amanco Holding Sa Process
KR101500655B1 (ko) * 2013-09-17 2015-03-12 한국과학기술연구원 금속불소화물 촉매 제조방법 및 이를 이용한 탈불산화 방법
GB2519572B (en) 2013-10-25 2015-12-30 Mexichem Amanco Holding Sa Process for isomerising (hydro)(halo)fluoroalkenes
CA2939239C (en) * 2014-02-13 2022-10-04 Fram Group IP, LLC Composition for and method of making an insulator for a spark plug
WO2016025288A1 (en) 2014-08-14 2016-02-18 The Chemours Company Fc, Llc Process for the production of e-1,3,3,3-tetrafluoropropene (hfc-1234ze) by dehydrofluorinatiokl
GB2540427B (en) 2015-07-17 2017-07-19 Mexichem Fluor Sa De Cv Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
GB201615197D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
GB201615209D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
CN108014827A (zh) * 2017-12-12 2018-05-11 西安近代化学研究所 一种高比表面纳米氟氧铬催化剂的制备方法
GB2580623A (en) 2019-01-17 2020-07-29 Mexichem Fluor Sa De Cv Method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5679875A (en) * 1992-06-05 1997-10-21 Daikin Industries, Ltd. Method for manufacturing 1,1,1,2,3-pentafluoropropene 1,1,1,2,3-pentafluoropropane

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2461523A (en) * 1946-12-04 1949-02-15 Du Pont Dehydrofluorination of polyfluoroalkanes
US3258500A (en) 1959-08-17 1966-06-28 Du Pont Process for fluorinating halohydro-carbons
DE3676804D1 (de) * 1986-01-22 1991-02-14 Atochem North America Verfahren zur umwandlung eines 1,1,1-trifluoralkans in ein 1,1-difluoralken.
US4828818A (en) 1987-03-13 1989-05-09 Allied-Signal Inc. Chromium aerogel method of producing same and fluorinating process utilizing same
US5036036A (en) 1989-06-13 1991-07-30 E. I. Du Pont De Nemours And Company Chromium oxide catalyst composition
US5396000A (en) * 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
JP4378779B2 (ja) * 1998-07-17 2009-12-09 ダイキン工業株式会社 含フッ素エタンの製造方法
US6124510A (en) * 1998-07-21 2000-09-26 Elf Atochem North America, Inc. 1234ze preparation
CN106634852A (zh) * 2002-10-25 2017-05-10 霍尼韦尔国际公司 含有氟取代烯烃的组合物
JP4864879B2 (ja) * 2004-04-29 2012-02-01 ハネウェル・インターナショナル・インコーポレーテッド １，３，３，３−テトラフルオロプロペンの合成方法
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US7388117B2 (en) 2005-11-01 2008-06-17 E.I. Du Pont De Nemours And Company Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
US7476771B2 (en) 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7423188B2 (en) 2005-11-01 2008-09-09 E. I. Du Pont De Nemours And Company Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7722781B2 (en) 2006-06-27 2010-05-25 E.I. Du Pont De Nemours And Company Tetrafluoropropene production processes
US7420094B2 (en) * 2006-09-05 2008-09-02 E.I. Du Pont De Nemours And Company Catalytic isomerization processes of 1,3,3,3-tetrafluoropropene for making 2,3,3,3-tetrafluoropropene

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5679875A (en) * 1992-06-05 1997-10-21 Daikin Industries, Ltd. Method for manufacturing 1,1,1,2,3-pentafluoropropene 1,1,1,2,3-pentafluoropropane

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Publication number Publication date
EP2041054B1 (en) 2014-08-27
US20100004492A1 (en) 2010-01-07
JP5764291B2 (ja) 2015-08-19
RU2451659C2 (ru) 2012-05-27
CN102690165B (zh) 2015-08-19
EP2041054A2 (en) 2009-04-01
WO2008008350A3 (en) 2008-03-13
CN101489960A (zh) 2009-07-22
ES2523694T3 (es) 2014-11-28
CN102690165A (zh) 2012-09-26
EP2386533A1 (en) 2011-11-16
EP2386534A1 (en) 2011-11-16
RU2009104933A (ru) 2010-08-20
US7982073B2 (en) 2011-07-19
WO2008008350A2 (en) 2008-01-17
JP2009542812A (ja) 2009-12-03
US20110237845A1 (en) 2011-09-29
US8148586B2 (en) 2012-04-03

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Effective date of registration: 20180105

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Patentee before: E. I. du Pont de Nemours and Co.

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