CN101472549B - Aerosol type cosmetic hair preparations - Google Patents
Aerosol type cosmetic hair preparations Download PDFInfo
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- CN101472549B CN101472549B CN200780022321XA CN200780022321A CN101472549B CN 101472549 B CN101472549 B CN 101472549B CN 200780022321X A CN200780022321X A CN 200780022321XA CN 200780022321 A CN200780022321 A CN 200780022321A CN 101472549 B CN101472549 B CN 101472549B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P5/00—Drugs for disorders of the endocrine system
- A61P5/02—Drugs for disorders of the endocrine system of the hypothalamic hormones, e.g. TRH, GnRH, CRH, GRH, somatostatin
- A61P5/04—Drugs for disorders of the endocrine system of the hypothalamic hormones, e.g. TRH, GnRH, CRH, GRH, somatostatin for decreasing, blocking or antagonising the activity of the hypothalamic hormones
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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Abstract
An aerosol type cosmetic hair preparation characterized in that a raw ethanol solution containing 0.1-15 mass% N-methacryloyloxyethyl-N,N-dimethylammonium a-N-methylcarboxybetaine/alkyl methacrylate copolymer and an aerosol propellant comprising a liquefied petroleum gas having an initial internal pressure as measured at 20 DEG C of 0.15-0.2 MPa have been packed in such a mixing proportion that the raw ethanol solution/aerosol propellant ratio by mass is in the range of 40/60 to 50/50. Also provided is an aerosol type cosmetic hair preparation characterized in that a raw ethanol solution containing 0.1-15 mass% polyvinylcaprolactam and an aerosol propellant comprising a liquefied petroleum gas having an initial internal pressure as measured at 20 DEG C of 0.15- 0.2 MPa have been packed in such a mixing proportion that the raw ethanol solution/aerosol propellant ratio by mass is in the range of 40/60 to 50/50. Based on the results of a detailed investigation made again on behaviors of hair-spray users, the hair sprays which can be comfortably used are provided.
Description
Technical field
The present invention relates to aerosol hair cosmetics.Say in further detail, relate to by jet power being relaxed and being adjusted to the hair fixing spray (hair set spray) that appropriate dynamics (gesture い) is improved usability and solved its subsidiary problem.
Background technology
In the market demand of modeling agent, hair spray (hair spray) is the popular important hair cosmetic composition that influences that is keeping certain demand always, do not receiving hair style.
Meanwhile, hair sprays using one of the important factors is the quality of spray mist (fog qualitative), which carried out a variety of studies.
For example; Put down in writing a kind of hair spray in the patent documentation 1; It is through compression gases such as further adding carbon dioxide in the liquid gas of propellant; Stock solution and liquid gas are filled with 95 to 5～75 to 25 mass ratio, the initial stage intrinsic pressurely is adjusted to 25 ℃ of down 0.2～0.5MPa, thereby has good mist matter.But; The injection dynamics of this hair spray spraying is strong; And the typing power under the situation that has cooperated the setting agent resin is indeterminate with the typing retentivity, and further because the mass ratio of liquid gas is less with respect to stock solution, thereby aerocolloidal clogging is also troubling.
Put down in writing a kind of aerosol spray compositions in the patent documentation 2; It is through containing water-insoluble organo-silicon compound 0.05～10 quality %, lower alcohol 1～60 quality %, water 3～50 quality %, propellant 25～90 quality %; Thereby has homogeneous and careful mist matter; And have lubricated sense of touch, wherein as propellant, use mixture, or the use dimethyl ether separately of liquefied petroleum gas and dimethyl ether.But the injection dynamics of spraying is indeterminate, and then owing to cooperated water, typing power or typing retentivity can not meet the demands.
Put down in writing in the patent documentation 3; Contain solid, shaped or paste oiliness composition, aqueous oiliness composition, have thin film and form macromolecular compound, nonionic surfactant, the water of ability, the vaporific hair cosmetic composition of spray; The spraying of spraying is careful, and hair is not clamminess, and soft sense of touch is arranged; Bring into play good constancy and haircuting property again, the atomize when using dimethyl ether in the propellant during ejection is desirable especially.But the injection dynamics of spraying is indeterminate, and then owing to cooperated water, typing power or typing retentivity can not meet the demands.
Put down in writing a kind of aerosol hair cosmetics in the patent documentation 4; It contains (A) polyhydric alcohol 0.1～5 quality %, (B) methacrylic amphoteric resin or pyrrolidinone compounds non-ionic resin, (C) fluid oil 0.1～3 quality % more than 2 kinds; The mass ratio (B)/(A) of composition (A) and composition (B) is in 3～15 scope; The amount of using water in the compositions be below the 2 quality % stock solution, comprise the propellant of liquid gas and dimethyl ether; Is that 40/60～70/30 scope is mixed with its mixing quality than (stock solution)/(propellant), thus high typing power excellent with the sense of preserving moisture, do not produce and peel off or stop up.But the injection dynamics of spraying is indeterminate, and the typing retentivity can not meet the demands.
On the other hand, use vaporific aerosol spray, in patent documentation 5, put down in writing, the invention of mainly considering from the viewpoint of aerosol spray container (spout of actuator (actuator)) as haircuting.
Patent documentation 1: TOHKEMY 2000-343007
Patent documentation 2: TOHKEMY 2001-335426
Patent documentation 3: TOHKEMY 2003-246712
Patent documentation 4: TOHKEMY 2004-143092
Patent documentation 5: japanese kokai publication hei 10-236550
Summary of the invention
The inventor etc. are conceived to the importance of hair spray, begin to carry out the research of essence with regard to how making convenient use of user.Simultaneously, observed in detail the hair spray operating position of user, the result recognizes the following fact.
(1) much human is pushed aerosol button bit by bit and is sprayed simultaneously, does not perhaps push up hill and dale, weakens the injection dynamics of spraying and uses.
(2) some people is blocked with hands in order not to be sprayed onto on the face, perhaps face is carried on the back the injection that turns round.
(3) if reduce the injection dynamics of spraying; So particularly under the situation that has cooperated the setting agent resin; Problem with spray nozzle clogging; This should solve through aerosol container, if the button that adopt to lower stops up, then has and feels to spray injection dynamics loud, spraying sensuously the trend liked of the person of being used by force and not.
Recognize consumingly according to the above fact; Though from make mist matter careful, prevent the viewpoint of the obstruction of nozzle, the obstruction of hair fixing spray when particularly having prevented to cooperate the setting agent resin simultaneously; Hair spray has the trend that strengthens the injection dynamics basically, but the dynamics of spraying may not necessarily obtain happy usability by force.In addition, its dynamics is crossed the hair style that also can cause by force after user is worried can not keep finalizing the design.
The inventor etc. are in view of above-mentioned viewpoint; Fundamentally restudied the hobby of user,, be different from the viewpoint of aerosol container in order to provide real use comfortable hair spray; From the research that deepens continuously of the viewpoint of content prescription, the result has accomplished the present invention.
The object of the present invention is to provide and to make user really feel to use comfortable hair spray; A kind of aerosol hair cosmetics is provided; It can guarantee to make user to feel the injection dynamics of spraying easy to use; Simultaneously mist matter is also very excellent, and do not have the problem of spray nozzle clogging, also has excellent effect aspect Hairsetting power and the Hairsetting retentivity.
Promptly; The present invention provides a kind of aerosol hair cosmetics; It is characterized in that; The N-methylacryoyloxyethyl N that will contain 0.1-15 quality %, the ethanol stock solution of N-Dimethyl Ammonium-α-N-methyl carboxybetaine-alkyl methacrylate copolymer and comprise the initial stage intrinsic pressure be 20 ℃ down the aerosol propellant of the liquefied petroleum gas of 0.15～0.2MPa according to the mixing quality of ethanol stock solution and aerosol propellant than filling for the scope of ethanol stock solution/aerosol propellant=40/60～50/50.
In addition; The present invention provides a kind of aerosol hair cosmetics; It is characterized in that, will contain 0.1～15 quality % Vinylcaprolactam homopolymer ethanol stock solution and comprise the initial stage intrinsic pressure be 20 ℃ down the aerosol propellant of the liquefied petroleum gas of 0.15～0.2MPa according to the mixing quality of ethanol stock solution and aerosol propellant than filling for the scope of ethanol stock solution/aerosol propellant=40/60～50/50.
In addition, the present invention provides above-mentioned aerosol hair cosmetics, it is characterized in that said aerosol hair cosmetics is the hair fixing spray.
According to the present invention, can provide to make user feel aerosol hair cosmetics easy to use.
That is, keeping for user is suitable intensity and the injection dynamics (the weak degree of the injection dynamics of spraying) that feels comfortably cool, and mist matter is also very excellent simultaneously.The problem of the spray nozzle clogging that does not cause by the setting agent resin in addition.Further, also very outstanding aspect Hairsetting power and Hairsetting retentivity, though the injection dynamics of spraying a little less than, the bed knife of hair style is identical and can make user very satisfied with in the past.
The specific embodiment
Below specify the present invention.
The N-methylacryoyloxyethyl N that uses among the present invention, N-Dimethyl Ammonium-α-N-methyl carboxybetaine-alkyl methacrylate copolymer is known acrylic compounds Amphiphatic high polymer.This macromolecule conduct has the setting agent resin of thin film formation ability and cooperates.As what put down in writing in the above-mentioned patent documentation 1～4, there are very many macromolecules in the setting agent resin that in aerosol hair cosmetics, cooperates.Yet, in the present invention, in miscellaneous setting agent resin, optionally used N-methylacryoyloxyethyl N, N-Dimethyl Ammonium-α-N-methyl carboxybetaine-alkyl methacrylate copolymer.The Arrcostab of special preferable methyl alkyl acrylate partly is C
18H
37The copolymer of (stearyl).As commercially available article, can preferably use RAM RESIN-4000 (Osaka Organic Chemical Industry Co., Ltd.).
On the other hand, the Vinylcaprolactam homopolymer that uses among the present invention of second is known non-ionic resin, as commercially available article, and preferred Luviskol (Le PVC ス コ-Le) Plus (BASF AG).
In the total amount of stock solution of in aerosol, filling and propellant gas, the use level of above-mentioned setting agent resin is 0.1～15 quality %.Less than 0.1 quality % then may not necessarily give full play to the effect of Hairsetting power and Hairsetting retentivity sometimes.In addition, surpass 15 quality %, then aspect spray nozzle clogging, can not give full play to effect of the present invention sometimes.Preferred especially is 0.5～10 quality % with respect to the stock solution total amount of filling in the aerosol.In addition, in the present invention,, when spraying, also can recover even it is unusual clogging or jet mode (pattern) temporarily to occur.
Above-mentioned setting agent resin is matched with in the stock solution as alcoholic solution usually.Ethanol is the primary solvent of stock solution, except, also cooperating separately in addition cooperating as the setting agent resin solution.
The actual amount "-f " flag real branch of the above-mentioned setting agent resin in the preferred final ethanol stock solution) be 5～10 quality %.
In addition, the ethanol content in the stock solution of using among the present invention can be adjusted into 60～99.5 quality % usually with respect to the stock solution total amount.Be preferably 70～80.0 quality %.
In the stock solution of using among the present invention; Purpose according to product; Except above-mentioned setting agent resin and ethanol, only otherwise damage effect of the present invention, can add the composition that can cooperate in the common hair cosmetic composition; For example, medicaments such as oil component, surfactant, water soluble polymer, chelating agen, antioxidant, UV absorbent, antiseptic, vitamin, hormone, spice etc. such as silicone based, hydro carbons, esters.
In the scope of not damaging effect of the present invention, can add above-mentioned other setting agent resin outside must composition.
The aerosol propellant of using among the present invention be the initial stage intrinsic pressure be 20 ℃ of down liquefied petroleum gas of 0.15～0.2MPa.The preferred initial stage is intrinsic pressure to be 20 ℃ of 0.15～0.18MPa down.Initial stage is intrinsic pressure be 20 ℃ down the liquefied petroleum gas of 0.15～0.2MPa can be modulated to arbitrarily the initial stage through the composition that changes liquefied petroleum gas intrinsic pressure.
In aerosol spray in the past, in order to ensure jetting stability and mist matter, intrinsic pressure being generally about 20 ℃ of following 0.25～0.4MPa of the initial stage of propellant, relative with it, in the present invention, the initial stage is intrinsic pressure to be the essential condition that differs widely with it.In addition, can bring into play following remarkable result through the jet power of intrinsic pressure acquisition of initial stage of the present invention: though under the low temperature about 5 ℃ no matter utilization rate how also can keep almost certain value, until also keeping at last almost certain stable emitted dose.
The loading of liquefied petroleum gas is 50～60 quality % in the total amount of stock solution and propellant gas.The ethanol stock solution and the mixing quality ratio of aerosol propellant that are filled in the aerosol can do; Ethanol stock solution/aerosol propellant=40/60～50/50; Through adopting this mixing quality ratio, in injection dynamics, the typing power of spraying, aspect the adhesive force of hair, can bring into play excellent especially effect.
Aerosol hair cosmetics of the present invention can be enclosed in above-mentioned constituent and use the conventional method manufacturing in the aerosol can, as hair spray commercialization rightly.Especially preferably cooperate the setting agent resin more than the 0.5 quality %, as the hair fixing spray of the usefulness of haircuting and commercialization with respect to the stock solution total amount.
Embodiment
Below enumerate embodiment and comparative example the present invention more specifically is described.But the present invention does not receive the qualification of these embodiment.Use level all is quality %.
According to the prescription of the cooperation shown in [table 1] modulation hair spray stock solution.Stock solution is filled in the aerosol can, valve is installed.Afterwards, fill specific compressed petroleum gas, obtain hair spray.
As sample,, estimate ejection (the injection dynamics of spraying), mist matter (careful property, uniformity), typing power, typing retentivity, clogging with it according to following metewand.The result is shown in [table 1].
(1) ejection (the injection dynamics of spraying)
Special judge group through 10 people carries out sensory evaluation to the injection dynamics of the spraying of hair spray coating process.
< metewand >
◎: being evaluated as the more weak special judge group number of the injection dynamics of spraying is 9～10 people.
Zero: being evaluated as the more weak special judge group number of the injection dynamics of spraying is 6～8 people.
△: being evaluated as the more weak special judge group number of the injection dynamics of spraying is 3～5 people.
*: being evaluated as the more weak special judge group number of the injection dynamics of spraying is below 2 people.
(2) mist matter (careful property, uniformity)
Special judge group through 10 people carries out sensory evaluation to the mist matter of hair spray coating process.
< metewand >
◎: being evaluated as the good special judge group number of mist matter is 9～10 people.
Zero: being evaluated as the good special judge group number of mist matter is 6～8 people.
△: being evaluated as the good special judge group number of mist matter is 3～5 people.
*: being evaluated as the good special judge group number of mist matter is below 2 people.
(3) typing power
For Hairsetting power, estimate through sensory test with pieces.
< experimental technique >
Coating 0.5g sample on the pieces that Beaulax (PVC ユ-ラ Star Network ス) system black healthy hair 3g (length 16cm) is used as hair; For dried pieces under the room temperature; Through 10 women specially judge group carry out sensory test, assessing hair typing power.During evaluation, everyone marks according to following scoring benchmark, adds up to 10 people's mark, carries out the evaluation of each sample according to following metewand.
< scoring benchmark >
5 minutes: Hairsetting power was most suitable.
4 minutes: Hairsetting power was suitable.
3 minutes: Hairsetting power was common.
2 minutes: Hairsetting power was improper.
1 minute: Hairsetting power was very improper.
< metewand >
◎: total points is more than 40 minutes.
Zero: total points is more than 30 minutes, less than 40 minutes.
△: total points is more than 20 minutes, less than 30 minutes.
*: total points less than 20 minutes.
(4) typing retentivity
For the Hairsetting retentivity, estimate the curly hair retentivity under high humility.
< experimental technique >
As hair, Beaulax is made the pieces that the black healthy hair is adjusted into length 15cm, heavy 1g, it flood 15 minutes in sample after, twist in to make on the rod of diameter 2cm and perm, then under 50 ℃, made it partial desiccation in 1 hour.Afterwards, at room temperature, made it Hue in 1 hour after, unload rod, only take out pieces, under 25 ℃, the environment of humidity 90%, keep 3 hours after, measure the curly hair retentivity.
At this moment, the pieces length when perming just to take off is Lo, and the length of pieces is Ln after n hour, according to computes curly hair retentivity.Identical test repeats 4 times, calculates 4 times meansigma methods.
Curly hair retentivity (%)={ (15-Ln)/(15-Lo) } * 100
< evaluation criterion >
◎: the curly hair retentivity is more than 80%
Zero: the curly hair retentivity is more than 50%, less than 80%
△: the curly hair retentivity is more than 30%, less than 50%
*: the curly hair retentivity is a less than 30%
(5) clogging
Each 20 in each sample of embodiment, comparative example after 40 ℃ of held 24 hours, 5 ℃ of held 24 hours, was sprayed 10 seconds afterwards.Carry out this circulation and use up until sample, if 1 does not occur clogging (even pushing the state that actuator does not have the content ejection yet) yet and then is judged to be zero, even have only 1 clogging to occur, then be judged to be *.
[table 1]
| Above-mentioned stock solution | 40 | 40 | 50 | 40 | 50 | 15 | 45 | 50 |
| Liquefied petroleum gas (0.15MPa is under 20 ℃) | 60 | - | - | 60 | - | - | 55 | 50 |
| Liquefied petroleum gas (0.18MPa is under 20 ℃) | - | 60 | 50 | - | - | 85 | - | - |
| Liquefied petroleum gas (0.25MPa is under 20 ℃) | - | - | - | - | 50 | - | - | - |
| Ejection (the injection dynamics of spraying) | ◎ | ○ | ○ | ◎ | × | △ | ◎ | ◎ |
| Mist matter (careful property, uniformity) | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ○ | △ |
| Typing power | ◎ | ○ | ◎ | ○ | ◎ | ○ | ◎ | ◎ |
| The typing retentivity | ◎ | ◎ | ◎ | ○ | ◎ | △ | × | ◎ |
| Stop up | ○ | ○ | ○ | ○ | ○ | ○ | × | × |
*1:RAM RESIN-4000 (Osaka Organic Chemical Industry Co., Ltd.)
*2:Luviskol Plus (BASF AG)
*3:PLAS-SIZE (プ ラ ス サ イ ズ) L9948B (mutual induction KCC)
Can know that according to The above results embodiments of the invention are ejection (the injection dynamics of spraying), mist matter (careful property, uniformity), typing power, typing retentivity, stop up the hair fixing spray that various aspects are all very excellent, user all is satisfied with, can be sprayed as snug as a bug in a rug various aspects.
Below enumerate other embodiment of the present invention.These all are at ejection (the injection dynamics of spraying), mist matter (careful property, uniformity), typing power, typing retentivity, stop up the hair spray that various aspects have excellent effect.
[embodiment 5: vaporific hair fixing spray]
< stock solution prescription >
Polyoxyethylene oleoyl ether (5EO) 0.2
Dimethyl polysiloxane (6CS) 0.2
RAM RESIN-4000 20 (actual amount 6)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 40 quality % and liquefied petroleum gas (0.20MPa is under 20 ℃) 60 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 6: vaporific hair fixing spray]
< stock solution prescription >
Polyoxyethylene oleoyl ether (5EO) 0.2
Dimethyl polysiloxane (6CS) 0.2
RAM RESIN-4000 20 (actual amount 6)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 45 quality % and liquefied petroleum gas (0.18MPa is under 20 ℃) 55 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 7: vaporific hair fixing spray]
< stock solution prescription >
Polyoxyethylene oleoyl ether (5EO) 0.2
Dimethyl polysiloxane (6CS) 0.2
Luviskol Plus 35 (actual amount 14)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 50 quality % and liquefied petroleum gas (0.20MPa is under 20 ℃) 50 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 8: vaporific hair fixing spray]
< stock solution prescription >
Polyoxyethylene oleoyl ether (5EO) 0.2
Dimethyl polysiloxane (6CS) 0.2
Luviskol Plus 15 (actual amount 6)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 40 quality % and liquefied petroleum gas (0.15MPa is under 20 ℃) 60 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 9: vaporific hair fixing spray]
< stock solution prescription >
PCA simethicone 0.1
MONAIL PCA (ユ ニ ケ マ manufactured)
Stearyl modified propylene acyl group silicone 0.1
KP56P (Shin-Etsu Chemial Co., Ltd's manufacturing)
RAM RESIN-4000 20 (actual amount 6)
Single Roxburgh Rose Fruit extract 0.01
(Rosa?roxburghii?fruit?extraxt)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 40 quality % and liquefied petroleum gas (0.18MPa is under 20 ℃) 60 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 10: vaporific hair fixing spray]
< stock solution prescription >
RAM RESIN-4000 20 (actual amount 6)
Luviskol Plus 10 (actual amount 4)
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 40 quality % and liquefied petroleum gas (0.15MPa is under 20 ℃) 60 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
[embodiment 11: vaporific hair fixing spray]
< stock solution prescription >
RAM RESIN-4000 20 (actual amount 6)
Caulis Sacchari sinensis extract 0.01
Oil-soluble hydrolyzed vegetable protein 0.01
POE (9) POP (2) dimethyl ether 0.1
Spice 0.03
Ethanol all the other (adding up to 100 quality %)
Above-mentioned stock solution 40 quality % and liquefied petroleum gas (0.15MPa is under 20 ℃) 60 quality % are filled in the aerosol can with well-established law, obtain vaporific hair fixing spray.
Industrial usability
Through the present invention, the injection dynamics (the weak degree of spray injection power) of keeping injection can be provided though, simultaneously mist matter injection dynamics also excellent, that can solve the spray nozzle clogging phenomenon spraying due to the setting agent resin more weak can fully satisfy aspect the bed knife of hair style, make user feel easy-to-use and comfortable hair spray.
Claims (4)
1. a vaporific hair fixing spray is characterized in that,
Ethanol stock solution and aerosol propellant are filled for the scope of ethanol stock solution/aerosol propellant=40/60～50/50 according to the mixing quality ratio,
Said ethanol stock solution contains the N-methylacryoyloxyethyl N of 0.1～15 quality %, N-Dimethyl Ammonium-α-N-methyl carboxybetaine-alkyl methacrylate copolymer,
It is 20 ℃ of liquefied petroleum gas of 0.15～0.2MPa down that said aerosol propellant comprises the initial stage intrinsic pressure,
It is the weak degree of suitable intensity and the injection dynamics that the feels comfortably cool injection dynamics of promptly spraying that this vaporific hair fixing spray is kept for user, and mist matter is also very excellent simultaneously, and does not have spray nozzle clogging.
2. a vaporific hair fixing spray is characterized in that,
Ethanol stock solution and aerosol propellant are filled for the scope of ethanol stock solution/aerosol propellant=40/60～50/50 according to the mixing quality ratio,
Said ethanol stock solution contains the Vinylcaprolactam homopolymer of 0.1～15 quality %,
It is 20 ℃ of liquefied petroleum gas of 0.15～0.2MPa down that said aerosol propellant comprises the initial stage intrinsic pressure,
It is the weak degree of suitable intensity and the injection dynamics that the feels comfortably cool injection dynamics of promptly spraying that this vaporific hair fixing spray is kept for user, and mist matter is also very excellent simultaneously, and does not have spray nozzle clogging.
3. a hair fixing method is characterized in that,
Ethanol stock solution and aerosol propellant are filled for the scope of ethanol stock solution/aerosol propellant=40/60～50/50 according to the mixing quality ratio,
Said ethanol stock solution contains the N-methylacryoyloxyethyl N of 0.1～15 quality %, N-Dimethyl Ammonium-α-N-methyl carboxybetaine-alkyl methacrylate copolymer,
It is 20 ℃ of liquefied petroleum gas of 0.15～0.2MPa down that said aerosol propellant comprises the initial stage intrinsic pressure,
It is the weak degree of suitable intensity and the injection dynamics that the feels comfortably cool injection dynamics of promptly spraying that this vaporific hair fixing spray is kept for user, and mist matter is also very excellent simultaneously, and does not have spray nozzle clogging.
4. a hair fixing method is characterized in that,
Ethanol stock solution and aerosol propellant are filled for the scope of ethanol stock solution/aerosol propellant=40/60～50/50 according to the mixing quality ratio,
Said ethanol stock solution contains the Vinylcaprolactam homopolymer of 0.1～15 quality %,
It is 20 ℃ of liquefied petroleum gas of 0.15～0.2MPa down that said aerosol propellant comprises the initial stage intrinsic pressure,
It is the weak degree of suitable intensity and the injection dynamics that the feels comfortably cool injection dynamics of promptly spraying that this vaporific hair fixing spray is kept for user, and mist matter is also very excellent simultaneously, and does not have spray nozzle clogging.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006201480A JP5235049B2 (en) | 2006-07-25 | 2006-07-25 | Aerosol hair cosmetics |
| JP201480/2006 | 2006-07-25 | ||
| PCT/JP2007/000635 WO2008012938A1 (en) | 2006-07-25 | 2007-06-14 | Aerosol type cosmetic hair preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101472549A CN101472549A (en) | 2009-07-01 |
| CN101472549B true CN101472549B (en) | 2012-03-21 |
Family
ID=38981254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780022321XA Expired - Fee Related CN101472549B (en) | 2006-07-25 | 2007-06-14 | Aerosol type cosmetic hair preparations |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5235049B2 (en) |
| KR (1) | KR101412020B1 (en) |
| CN (1) | CN101472549B (en) |
| TW (1) | TWI388340B (en) |
| WO (1) | WO2008012938A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010037273A (en) * | 2008-08-05 | 2010-02-18 | Shiseido Co Ltd | Trigger aerosol type hair cosmetic |
| JP5557234B2 (en) * | 2009-07-17 | 2014-07-23 | 株式会社 資生堂 | Aerosol hair cosmetics |
| JP5670652B2 (en) * | 2010-06-15 | 2015-02-18 | 株式会社ダイゾー | Aerosol products |
| KR101738473B1 (en) | 2015-09-22 | 2017-05-23 | 한국콜마주식회사 | Hair styling composition of aerosol type ejected with ice sherbet-like feeling and method for preparing thereof |
| JP7304736B2 (en) * | 2019-05-13 | 2023-07-07 | シャープ株式会社 | Aerosol composition and aerosol spray can filled with the same |
| KR102063889B1 (en) * | 2019-05-22 | 2020-01-08 | 양숙현 | Spray composition for improving head skin comprising houttuynia cordata ingredient |
| JP7309300B2 (en) * | 2019-09-25 | 2023-07-18 | 株式会社マンダム | aerosol spray hair conditioner |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19820949A1 (en) * | 1998-05-11 | 1999-11-18 | Basf Ag | Hair spray composition with good application properties |
| JP2001064634A (en) * | 1999-08-30 | 2001-03-13 | Daizo:Kk | Aerosol composition and aerosol product using the same |
| JP2002308738A (en) * | 2001-04-05 | 2002-10-23 | Kao Corp | Hair cosmetic |
| CN1636542A (en) * | 2003-11-21 | 2005-07-13 | 株式会社资生堂 | Aerosol hair cosmetics |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4013872A1 (en) * | 1990-04-30 | 1991-10-31 | Basf Ag | HAIRFESTING AND HAIR CARE |
| JP3782335B2 (en) * | 2001-11-02 | 2006-06-07 | 株式会社資生堂 | Spray hair cosmetics |
| JP4067102B2 (en) * | 2003-11-21 | 2008-03-26 | 株式会社資生堂 | Aerosol hair cosmetics |
-
2006
- 2006-07-25 JP JP2006201480A patent/JP5235049B2/en active Active
-
2007
- 2007-06-14 WO PCT/JP2007/000635 patent/WO2008012938A1/en active Application Filing
- 2007-06-14 KR KR1020087022664A patent/KR101412020B1/en active IP Right Grant
- 2007-06-14 CN CN200780022321XA patent/CN101472549B/en not_active Expired - Fee Related
- 2007-06-21 TW TW096122246A patent/TWI388340B/en not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19820949A1 (en) * | 1998-05-11 | 1999-11-18 | Basf Ag | Hair spray composition with good application properties |
| JP2001064634A (en) * | 1999-08-30 | 2001-03-13 | Daizo:Kk | Aerosol composition and aerosol product using the same |
| JP2002308738A (en) * | 2001-04-05 | 2002-10-23 | Kao Corp | Hair cosmetic |
| CN1636542A (en) * | 2003-11-21 | 2005-07-13 | 株式会社资生堂 | Aerosol hair cosmetics |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200817038A (en) | 2008-04-16 |
| JP5235049B2 (en) | 2013-07-10 |
| TWI388340B (en) | 2013-03-11 |
| WO2008012938A1 (en) | 2008-01-31 |
| CN101472549A (en) | 2009-07-01 |
| KR20090033414A (en) | 2009-04-03 |
| KR101412020B1 (en) | 2014-06-26 |
| JP2008024676A (en) | 2008-02-07 |
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