CN1636542A - Aerosol hair cosmetics - Google Patents
Aerosol hair cosmetics Download PDFInfo
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- CN1636542A CN1636542A CN 200410090468 CN200410090468A CN1636542A CN 1636542 A CN1636542 A CN 1636542A CN 200410090468 CN200410090468 CN 200410090468 CN 200410090468 A CN200410090468 A CN 200410090468A CN 1636542 A CN1636542 A CN 1636542A
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Abstract
To provide an aerosol-type hair cosmetic imparting the hair with gloss, smooth touch and dry touch, excellent in moisture resistance, and also high in setting power and set holding power. The aerosol-type hair cosmetic comprises a stock solution comprising (A) a specific long-chain alkyl-modified acrylate silicone-based copolymer[ e.g. (acrylate/stearyl acrylate/dimethicone methacrylate) copolymer ], (B) a specific amphoteric resin as film-forming agent[ e.g. (methacryloyloxyethyl carboxybetaine/alkyl methacrylate) copolymer ] and (C) a lower alcohol, and a propellant( especially LPG ).
Description
Technical field
The present invention relates to aerosol hair cosmetics.In more detail, relate to and giving hair luster, slick thoughts and feelings, in the time of dry feeling, excellent moisture resistance, the aerosol hair cosmetics of typing power, typing retentivity excellence.
Background technology
In the past, in the cosmetics of Hair grooming,, be fixed as the cooperation that purpose has been studied various resins (macromolecular compound) with Hairsetting.But the existing hair cosmetic composition that cooperates resin if increase amount of resin in order to increase pull-out capacity, though improved constancy, has produced the sense of hardening thereupon and has increased, and the problem of smooth feeling reduction.
On the other hand, in order to give gloss or smooth, and reduce the sense of hardening that causes because of resin, studied resin and oil content combination cooperation etc. (referring to for example, the spy opens flat 8-92044 communique).But,, exist and reduce the original typing power of these compositions, gloss or the slick power of giving, the problem that mutual feature is reduced if cooperate resin and oil content simultaneously.
Summary of the invention
The object of the present invention is to provide and give hair luster, smooth feeling, dry feeling, while excellent moisture resistance, typing power, the aerosol hair cosmetics of typing retentivity excellence.
According to the present invention, aerosol hair cosmetics is provided, it is characterized in that containing and comprise following ingredients (A), (B) and stock solution (C) and spray:
(A) (1) contains following formula (I), (II) and (III)
[in the formula (I), R
0The alkyl of expression carbon number 14～24; In the formula (III), n represents 3～30 number] the long chain alkyl modified acrylate polysiloxanes analog copolymer of represented construction unit and/or
(A) (2) following general formula (IV)
[in the formula (IV), R
1Identical or different, be selected from R
2, hydrogen atom contains the group of primary amine, or descends the represented carboxyl-functional base that contains pyrrolidone-base of formula V
Condition is, and in the formula V, R
5The expression hydrogen atom, the alkyl of carbon number 1～6, or alkali metal; F is identical or different, is the straight or branched alkylidene of carbon number 1～12; N is 0 or 2; n
1, n
2Be respectively 0 or 1; B is-NR
9(R
9Be the alkyl of hydrogen atom or carbon number 1～6), sulphur atom or oxygen atom; Condition is, when n is 0 and n
2Be 1 o'clock n
1Be 1, when n is 2 and n
2Be 1 o'clock n
1Be 0 or 1, when n is 2 and n
2Be 0 o'clock n
1Be 0}; Herein, at least one R
1Be above-mentioned carboxyl-functional base or its ester derivant that contains pyrrolidone-base; R
2Identical or different, be selected from alkyl, aryl, or thiazolinyl, R
3And R
4Identical or different, be selected from alkyl, aryl, end-blocking or not end capped polyoxyalkylenes, alkaryl, arylalkenyl, or alkenyl; L is 0～50,000 integer; M is 0～100 integer] represented organo-silicon compound,
(B) following general formula (VI)
[in the formula (VI), a: b: c=(10～90): (0～50): (90～10) (mass ratio); R represents the alkyl of carbon number 1～24; Z represents CH
2COO
-Or O
-Quality mean molecule quantity (Mw) is 2～300,000] represented amphoteric resin and
(C) lower alcohol.
According to the present invention, can provide and give hair luster, slick thoughts and feelings, in the time of dry feeling, excellent moisture resistance, typing power, the aerosol hair cosmetics of typing retentivity excellence.
The aerosol hair cosmetics that the present invention relates to can be used as and gives hair luster, smooth feeling, and in the time of dry feeling, excellent moisture resistance, typing power, the hair arrangement product of typing retentivity excellence use.
The specific embodiment
The hair cosmetic composition that the present invention relates to is made up of stock solution and spray, in the stock solution of first mode, contains following (A) composition, promptly (A) (1) and/or (A) (2), (B) and (C) composition as must composition.
Long chain alkyl modified acrylate polysiloxanes analog copolymer as (A) (1) composition contains following formula (I), (II) and (III) represented construction unit.
In the above-mentioned formula (I), R
0Expression carbon number 14～24, preferred especially 16～22 alkyl.In the formula (III), n represents 3～300 number in addition.
Composition (A) (1) is by said structure unit (I), (II) and (III) copolymer that forms of copolymerization, but copolymerization mode is not particularly limited, and for example can be block copolymer, random copolymer, and graft copolymers etc. are mode arbitrarily.
Composition (A) (1) is a known compound, for example as " polysiloxanes KP561P[SHIN-ETSU HANTOTAI chemical industry (strain) system; (ア Network リ レ one Star/stearyl acrylate ester/methacrylic acid polydimethylsiloxane) copolymer] etc. commercially available, can suit to use.
As the organo-silicon compound of above-mentioned (A) (2) composition, represent by following general formula (IV).
In above-mentioned general formula (IV), R
1Identical or different, expression R
2(aftermentioned), hydrogen atom contains the group of primary amine, the carboxyl-functional base that contains pyrrolidone-base that perhaps following formula V is represented, but at least one R
1It is this carboxyl-functional base or its ester derivant that contains pyrrolidone-base;
R
2Identical or different, be selected from alkyl, aryl, perhaps thiazolinyl;
R
3And R
4Identical or different, be selected from alkyl, aryl, end-blocking or not end capped polyoxyalkylenes, alkaryl, arylalkenyl, or alkenyl;
L is 0～50,000 integer;
M is 0～100 integer.
In the above-mentioned formula V, R
5The expression hydrogen atom, the alkyl of carbon number 1～6, perhaps alkali metal;
F is identical or different, the straight or branched alkylidene of expression carbon number 1～12;
N is 0 or 2; n
1, n
2(condition is, when n is 0 and n to be respectively 0 or 1
2Be 1 o'clock n
1Be 1, when n is 2 and n
2Be 1 o'clock n
1Be 0 or 1, when n is 2 and n
2Be 0 o'clock n
1Be 0);
B is-NR
9(R
9Be the alkyl of hydrogen atom or carbon number 1～6), sulphur atom or oxygen atom.
Among the present invention, preferably use in the above-mentioned formula (IV) R
1, R
2, R
3, R
4Represent independently that respectively (condition is at least one R for the alkyl of carbon number 1～6
1Be the carboxyl-functional base that contains pyrrolidone-base or its ester derivant shown in the above-mentioned formula V) chemical compound.
As the organo-silicon compound of mentioned component (A) (2), be known compound, for example can use disclosed chemical compound in the flat 11-504665 communique of special table.In addition, commercially available as " MONASIL-PCA " (Mona Industry Incorporated, U.S.) etc., also can suit to use.Being somebody's turn to do " MONASIL-PCA ", is the polysiloxane compound (Mw=6000, degree of modification 1%) of the represented 2-pyrrolidone-5-carboxylic acid's modification of following formula (VII).
The composition (A) (1) and/or (A) use level of (2) though be not particularly limited, with respect to whole former liquid measures, are preferably 0.001～10 quality %, more preferably 0.01～1 quality %.Less than 0.001 quality % is difficult to give enough gloss of hair and smooth feeling, on the other hand, if surpass 10 quality %, can cause stickness again.Can use a kind of or the above composition (A) (1) of two kinds or its and/or (A) (2) arbitrarily.
As the amphoteric resin of composition (B), be the formation composition of overlay film, be by the copolymer shown in the following general formula (VI).
In the above-mentioned formula (VI), a: b: c :=(10～90): (0～50): (90～10) (mass ratio).
R represents the alkyl of carbon number 1～24.
Z represents CH
2COO
-Or O
-
The average quality mean molecule quantity (Mw) of composition (B) is 2～300,000.
The form of copolymer is not particularly limited, and for example can be block copolymer, random copolymer, and graft copolymers etc. are form arbitrarily.
Composition (B) is a known compound, as the commercial goods, " RAM レ ジ Application " シ リ-ズ (Osaka organic chemistry industry (strain) system) is arranged, " ユ カ Off オ one マ one " シ リ-ズ, " ダ イ ヤ Off オ one マ one " シ リ one ズ (being Mitsubishi Chemical's (strain) system) can suit to use these products.Can enumerate goods shown below particularly, but be not limited to these illustrations.
(i) " RAM レ ジ Application-4000 " (Osaka organic chemistry industry (strain) system: (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (alcoholic solution of entity composition 30%).In the above-mentioned general formula (IV), about 50: 20: 30 of a: b: c=, R represents C
18H
37, Z represents CH
2COO
-
(ii) " ユ カ Off オ one マ one WPS " (Mitsubishi Chemical's (strain) system): (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (alcoholic solution of entity composition 30%).In the above-mentioned general formula (VI), b is 0, about 50: 50 of a: c=, and R is mainly C
4H
9, Mw=is about 150,000, and Z represents CH
2COO
-
(iii) " ダ イ ヤ Off オ one マ one Z-772 " (Mitsubishi Chemical's (strain) system): (ア Network リ レ one Star/lauryl acrylate/stearyl acrylate ester/methacrylic acid ethylamine oxide) copolymer (alcoholic solution of entity composition 30%).In the above-mentioned general formula (VI), b is 0, a/c=about 80 or more than it, R is CH
3～C
18H
37, Z represents O
-
The use level of composition (B), though be not particularly limited, with respect to whole former liquid measures, the entity composition is preferably 0.1～15 quality %, more preferably 0.5～10 quality %.Less than 0.1 quality % is difficult to give hair finalize the design fully power and typing vitality, on the other hand, cooperates if surpass 15 quality %, peels off easily.Can use a kind or 2 kinds or its above composition (B), perhaps use its alcoholic solution (using ethanol dilution).
As the lower alcohol of composition (C), alcohol that can illustration carbon number 1～6 especially preferably uses ethanol.Lower alcohol constitutes the main component of solvent in the stock solution, and it is 20～99 quality % that its use level is preferably with respect to whole former liquid measures, more preferably 70～98 quality %.
Except that above-mentioned necessary composition, in the scope of harmless the present application effect, can at random cooperate the composition that can in the stock solution of aerosol hair cosmetics, add usually in the stock solution.As this constituents, can illustration water, volatile oil (low boiling chain organic silicone oil or cyclic organic oil, low boiling isoparaffin class hydrocarbon ils etc.), spice etc., but be not limited to these illustrations.
The dosage form of stock solution can be arbitrarily, it can be solvable system, emulsion type, the powder disperse system, 2 of oil-water is mutually, oil-water-powder 3 series of strata etc., be packaged into aerosol type so long as can pressurize with spray, any can, also can add various additives as hair foam (typing use hair mousse), vigour bromhidrosis colloidal sol (Hairsetting liquid), hairs such as hair spray arrangement product use.
As spray, can use separately with propane, butane and iso-butane are the liquefied petroleum gas (LPG) of main component, dimethyl ether and carbon dioxide, compression gases such as nitrogen etc. or use its mixture.Wherein, preferred especially liquefied petroleum gas (LPG).
The match ratio of stock solution and spray, as long as adjust to respect to 5～95 mass parts stock solutions, spray is that 95～5 mass parts are just passable, preferably adjusts to respect to 30～70 mass parts stock solutions, spray is 70～30 mass parts.
The preparation of the aerosol hair cosmetics that the present invention relates to is not particularly limited.For example, adding composition (B) in the composition (C) and mixing, in the solution that further adds adding ingredient arbitrarily therein as required and form, adding is dissolved in solution in the low boiling oil (low boiling chain organosilicon wet goods) with composition (A) (1) and/or composition (A) (2), be filled into aerosol with in the container, in conjunction with after, add spray, obtain aerosol hair cosmetics goods of the present invention.
Aerosol hair cosmetics of the present invention, in stock solution as sense of touch improving agent selection component (A) (1) and/or (A) (2), form agent selection component (B) as overlay film, it is cooperated in comprising the stock solution of composition (C) as solvent, by the combination spray, can obtain to obtain when giving hair luster or smooth thoughts and feelings excellent moisture resistance, typing power, the typing retentivity is the aerosol hair cosmetics of excellent effect extremely.
Embodiment
Enumerate embodiment below and describe the present invention, but the present invention is not limited to this.Use level is except that specifying, this composition is represented with quality % with respect to the system that cooperates.
Embodiment 1～7 and comparative example 1～5
According to the prescription of the cooperation shown in the following table 1 preparation hair spray stock solution.Pack into this stock solution of 45 mass parts in the aerosol can and add a cover.Then, fill 55 mass parts liquefied petroleum gas, obtain hair spray.In the Table I, composition (B) uses the alcoholic solution of entity composition 30% in addition.
It as test specimen, according to following evaluation criterion, is estimated smoothness, gloss, dry feeling, typing power, typing retentivity.The results are shown in the Table I.
[smooth feeling]
By special volunteer (20), on its hair, use various test specimens, for the dried hair of coating, estimate smooth feeling according to following metewand.
(metewand)
A:16 name or its above smooth feeling excellence of answering
B:11～15 an answer smooth feeling excellence
C:5～10 an answer smooth feeling excellence
D:4 name or its following smooth feeling excellence of answering
[gloss]
By special volunteer (20), on its hair, use various test specimens, for the dried hair of coating, estimate gloss according to following metewand.
(metewand)
A:16 name or its above gloss excellence of answering
B:11～15 an answer gloss excellence
C:5～10 an answer gloss excellence
D:4 name or its following gloss excellence of answering
[dry feeling]
By special volunteer (20), on its hair, use various test specimens, for the dried hair of coating, estimate dry feeling according to following metewand.
(metewand)
The dry feeling excellence is not clamminess in A:16 name or its above answer
B:11～15 answer is not clamminess, the dry feeling excellence
C:5～10 answer is not clamminess, the dry feeling excellence
The dry feeling excellence is not clamminess in D:4 name or its following answer
[typing power]
At long 15cm, be coated with the 0.5g test specimen equably on the hair bundle of heavy 1g, be rolled into the rod of diameter 2cm, in 45 ℃ hot room, placed 6 hours, make its bone dry.After the drying, untie the hair rod, bundle of hair is squeezed the integrated value of the stress when broken and estimate on rheometer as typing power.This typing power value is high more, illustrates that fixedly the power of hair is strong.
[typing retentivity]
At long 15cm, be coated with the 0.5g test specimen equably on the hair bundle of heavy 1g, be rolled into the rod of diameter 2cm, in 45 ℃ hot room, placed 6 hours, make its bone dry.After the drying, untie the hair rod, measure the outward appearance length (L of hair
1).Then the hair bundle is hung in 25 ℃ of temperature, in the constant-temperature constant-humidity environment of humidity 90%, takes out after 3 hours, measure the outward appearance length (L of hair bundle again
2), obtain typing by following formula and keep effect.This value is more near 100, and typing keeps effect high more.
Typing retentivity={ (15-L
2)/(15-L
1) * 100
Table I
| Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| (stock solution) | - | ????- | ????- | ????0.1 | ????0.1 | ????0.1 | ??0.1 | ????0.1 |
| (alkyl acrylate/stearyl acrylate base ester/acrylic acid polydimethylsiloxane) copolymer (" polysiloxanes KP561 ") (composition (A) (1)) | ||||||||
| 2-pyrrolidone-5-carboxylic acid's modified organic silicon chemical compound (chemical compound of formula (VII) expression) " MONASIL-PCA " (composition (A) (2)) | - | ????- | ????- | ????- | ????0.1 | ????- | ??- | ????- |
| Methyl phenyl silicone (" polysiloxanes KF56 ") | 0.1 | ????- | ????- | ????- | ????- | ????- | ??- | ????- |
| The 2 ethyl hexanoic acid cetyl ester | - | ????0.1 | ????- | ????- | ????- | ????- | ??- | ????- |
| Polydimethylsiloxane (" polysiloxanes KF96A-6 ") | - | ????- | ????0.1 | ????- | ????- | ????- | ??- | ????- |
| (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (" RAM レ ジ Application-4000 ") (composition (B)) | 30 | ????30 | ????30 | ????- | ????- | ????30 | ??- | ????- |
| (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (" ユ カ Off オ one マ one WPS ") (composition (B)) | - | ????- | ????- | ????- | ????- | ????- | ??30 | ????- |
| (ア Network リ レ one Star/acrylic acid Lauryl Ester/stearyl acrylate base ester/methacrylic acid ethylamine oxide) copolymer (" ダ イ ヤ Off オ one マ one Z-772 " (composition (B)) | - | ????- | ????- | ????- | ????- | ????- | ??- | ????30 |
| (alkyl acrylate/diacetyl acrylamide) copolymer A MP (" プ ラ ス サ イ ズ L9948B ", the alcoholic solution of entity composition 40%) | - | ????- | ????- | ????22.5 | ????22.5 | ????- | ??- | ????- |
| Ethanol (composition (C)) | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| The smooth feeling of hair | C | ????D | ????C | ????A | ????A | ????A | ??A | ????A |
| The gloss of hair | B | ????A | ????B | ????A | ????A | ????A | ??A | ????A |
| The dry feeling of hair | C | ????D | ????C | ????A | ????A | ????A | ??A | ????A |
| Typing power | 185 | ????175 | ????180 | ????223 | ????215 | ????216 | ??213 | ????193 |
| The typing retentivity | 75 | ????77 | ????76 | ????50 | ????40 | ????97 | ??96 | ????95 |
Table I-continuous
| Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
| (stock solution) | 0.1 | ??0.1 | ??0.1 | ??0.1 |
| (alkyl acrylate/stearyl acrylate base ester/acrylic acid polydimethylsiloxane) copolymer (" polysiloxanes KP561 ") (composition (A) (1)) | ||||
| 2-pyrrolidone-5-carboxylic acid's modified organic silicon chemical compound (chemical compound of formula (VII) expression) " MONASIL-PCA " (composition (A) (2)) | - | ??- | ??- | ??0.1 |
| Methyl phenyl silicone (" polysiloxanes KF56 ") | - | ??- | ??- | ??- |
| The 2 ethyl hexanoic acid cetyl ester | - | ??- | ??- | ??- |
| Polydimethylsiloxane (" polysiloxanes KF96A-6 ") | - | ??- | ??- | ??- |
| (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (" RAM レ ジ Application-4000 ") (composition (B)) | 30 | ??- | ??- | ??30 |
| (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer (" ユ カ Off オ one マ one WPS ") (composition (B)) | - | ??30 | ??- | ??- |
| (ア Network リ レ one Star/acrylic acid Lauryl Ester/stearyl acrylate base ester/methacrylic acid ethylamine oxide) copolymer (" ダ イ ヤ Off オ one マ one Z-772 " (composition (B)) | - | ??- | ??30 | ??- |
| (alkyl acrylate/diacetyl acrylamide) copolymer A MP (" プ ラ ス サ イ ズ L9948B ", the alcoholic solution of entity composition 40%) | - | ??- | ??- | ??- |
| Ethanol (composition (C)) | Surplus | Surplus | Surplus | Surplus |
| The smooth feeling of hair | A | ??A | ??A | ??A |
| The gloss of hair | A | ??A | ??A | ??A |
| The dry feeling of hair | A | ??A | ??A | ??A |
| Typing power | 218 | ??215 | ??195 | ??216 |
| The typing retentivity | 94 | ??93 | ??95 | ??93 |
Claims (4)
1, contain and comprise following three kinds of compositions (A), (B) and the aerosol hair cosmetics that forms of stock solution (C) and spray:
(A) (1) contains following formula (I), (II) and (III)
[in the formula (I), R
0The alkyl of expression carbon number 14～24; In the formula (III), n represents 3～30 number] the long chain alkyl modified acrylate polysiloxanes analog copolymer of represented construction unit and/or
[in the formula (IV), R
1Identical or different, be selected from R
2, hydrogen atom contains the group of primary amine, or descends the represented carboxyl-functional base that contains pyrrolidone-base of formula V
Condition is, and in the formula V, R
5The expression hydrogen atom, the alkyl of carbon number 1～6, or alkali metal; F is identical or different, is the straight or branched alkylidene of carbon number 1～12; N is 0 or 2; n
1, n
2Be respectively 0 or 1; B is-NR
9(R
9Be the alkyl of hydrogen atom or carbon number 1～6), sulphur atom or oxygen atom; Condition is, when n is 0 and n
2Be 1 o'clock n
1Be 1, when n is 2 and n
2Be 1 o'clock n
1Be 0 or 1, when n is 2 and n
2Be 0 o'clock n
1Be 0}; Herein, at least one R
1Be above-mentioned carboxyl-functional base or its ester derivant that contains pyrrolidone-base; R
2Identical or different, be selected from alkyl, aryl, or thiazolinyl, R
3And R
4Identical or different, be selected from alkyl, aryl, end-blocking or not end capped polyoxyalkylenes, alkaryl, arylalkenyl, or alkenyl; L is 0～50,000 integer; M is 0～100 integer] represented organo-silicon compound,
(B) following general formula (VI)
[in the formula (VI), a: b: c=(10～90): (0～50): (90～10) (mass ratio); R represents the alkyl of carbon number 1～24; Z represents CH
2COO
-Or O
-Quality mean molecule quantity (Mw) is 2～300,000] represented amphoteric resin and
(C) lower alcohol.
2, the described aerosol hair cosmetics of claim 1, wherein stock solution contains the composition (A) of 0.001～10 quality %, the composition of 0.1～15 quality % (B), the lower alcohol of the composition of 20～99 quality % (C).
3, claim 1 or 2 described aerosol hair cosmetics, wherein lower alcohol is an ethanol.
4, any described aerosol hair cosmetics in the claim 1～3, wherein spray is a liquefied petroleum gas.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003393017A JP4067102B2 (en) | 2003-11-21 | 2003-11-21 | Aerosol hair cosmetics |
| JP2003393016A JP4067101B2 (en) | 2003-11-21 | 2003-11-21 | Aerosol hair cosmetics |
| JP393016/2003 | 2003-11-21 | ||
| JP393017/2003 | 2003-11-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1636542A true CN1636542A (en) | 2005-07-13 |
| CN1636542B CN1636542B (en) | 2011-07-27 |
Family
ID=34863398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410090468 Active CN1636542B (en) | 2003-11-21 | 2004-11-18 | Aerosol hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1636542B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288634B (en) * | 2008-06-06 | 2010-06-09 | 山东大学 | Noctilucent nutrient hair cream and preparation method thereof |
| CN101472549B (en) * | 2006-07-25 | 2012-03-21 | 株式会社资生堂 | Aerosol type cosmetic hair preparations |
| CN104203209A (en) * | 2012-03-30 | 2014-12-10 | 株式会社高丝 | Hair cosmetic |
| CN115802999A (en) * | 2020-09-14 | 2023-03-14 | 株式会社漫丹 | Aerosol spray hair cosmetic |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2737660B1 (en) * | 1995-08-11 | 1997-09-12 | Oreal | COSMETIC COMPOSITION WITH FIXING AND / OR CONDITIONING POWDER CONTAINING A PARTICULAR ACRYLIC COPOLYMER |
| US6645478B2 (en) * | 2001-06-22 | 2003-11-11 | L'oreal S.A. | Reshapable hair styling composition comprising (meth)acrylic copolymers of four or more monomers |
| US6667378B2 (en) * | 2001-06-22 | 2003-12-23 | L'oreal, S.A. | Reshapable hair styling composition comprising heterogeneous (meth)acrylic copolymer particles |
-
2004
- 2004-11-18 CN CN 200410090468 patent/CN1636542B/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101472549B (en) * | 2006-07-25 | 2012-03-21 | 株式会社资生堂 | Aerosol type cosmetic hair preparations |
| CN101288634B (en) * | 2008-06-06 | 2010-06-09 | 山东大学 | Noctilucent nutrient hair cream and preparation method thereof |
| CN104203209A (en) * | 2012-03-30 | 2014-12-10 | 株式会社高丝 | Hair cosmetic |
| CN115802999A (en) * | 2020-09-14 | 2023-03-14 | 株式会社漫丹 | Aerosol spray hair cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1636542B (en) | 2011-07-27 |
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