JP2010126515A - Hair cosmetic - Google Patents
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- JP2010126515A JP2010126515A JP2008306076A JP2008306076A JP2010126515A JP 2010126515 A JP2010126515 A JP 2010126515A JP 2008306076 A JP2008306076 A JP 2008306076A JP 2008306076 A JP2008306076 A JP 2008306076A JP 2010126515 A JP2010126515 A JP 2010126515A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 26
- 239000004359 castor oil Substances 0.000 claims abstract description 21
- 235000019438 castor oil Nutrition 0.000 claims abstract description 21
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000000443 aerosol Substances 0.000 claims description 11
- 239000003380 propellant Substances 0.000 claims description 11
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000003595 mist Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000003921 oil Substances 0.000 abstract description 5
- 229920006318 anionic polymer Polymers 0.000 abstract 1
- 125000002348 vinylic group Chemical group 0.000 abstract 1
- -1 methyl-1-propyl Chemical group 0.000 description 46
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 40
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- 239000000203 mixture Substances 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 11
- 239000011550 stock solution Substances 0.000 description 10
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 8
- 229920006322 acrylamide copolymer Polymers 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 6
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 6
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000003676 hair preparation Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 229940114077 acrylic acid Drugs 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 3
- 239000008266 hair spray Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- OUUCZGCOAXRCHN-UHFFFAOYSA-N 1-hexadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC OUUCZGCOAXRCHN-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229940048053 acrylate Drugs 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UVHQXWILFGUDTA-LNKPDPKZSA-N (z)-4-ethoxy-4-oxobut-2-enoic acid;methoxyethene Chemical compound COC=C.CCOC(=O)\C=C/C(O)=O UVHQXWILFGUDTA-LNKPDPKZSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、セット性及び再整髪性に優れた毛髪化粧料に関する。 The present invention relates to a hair cosmetic excellent in setting properties and re-styling properties.
従来、整髪に用いるエアゾール式毛髪化粧料は、毛髪セット用ポリマーの固着力を用いて、髪を固定するものが一般的であるが、一度毛髪を固定した後、ヘアスタイルが崩れると再度毛髪を固定(以下、「再整髪」という)することができず、仕上がった髪がごわつく、硬いなどの不満が生じている。 Conventionally, aerosol hair cosmetics used for hair styling are generally those that fix the hair using the fixing strength of the hair setting polymer, but once the hair is fixed, if the hair style breaks down, the hair is re-attached. The hair cannot be fixed (hereinafter referred to as “re-haircut”), and the finished hair is stiff or stiff.
一方、ヘアワックスなどのスタイリング剤では、髪を油の粘着力で保持することから、髪は固まることなく自然な仕上がりが得られ、再整髪も可能であるが、油による粘着力はべたつきの原因となる。しかもヘアワックスの固着力は毛髪セット用ポリマーの固着力に比べて極めて弱く、思いどおりのヘアスタイルを長時間保持することは難しい。 On the other hand, styling agents such as hair wax hold the hair with the adhesive strength of oil, so that the hair can be naturally finished without stiffening and re-styling is possible, but the adhesive strength due to oil is the cause of stickiness It becomes. Moreover, the fixing strength of the hair wax is extremely weak compared to the fixing strength of the hair setting polymer, and it is difficult to maintain the desired hairstyle for a long time.
そこで、毛髪セット用ポリマーと油剤を含有し、一定以上の粘着力を有する毛髪化粧料が、頭髪を固めずに自然なまとまりを付与でき、ヘアスタイルの保持性に優れるものとして提案されている(特許文献1)。しかし、このものは、粘着性が十分でないため、再整髪性が低く、思いどおりのヘアスタイルを長時間保持することは難しいという問題があった。 Therefore, hair cosmetics containing a hair set polymer and an oil agent and having a certain level of adhesive strength have been proposed as being capable of imparting a natural unit without solidifying the hair and having excellent hairstyle retention ( Patent Document 1). However, since this product does not have sufficient tackiness, there is a problem that it is difficult to maintain a desired hairstyle for a long time because of low re-styling properties.
また、N-置換(メタ)アクリルアミド単量体とこれ以外の不飽和単量体との共重合体を毛髪化粧料の基剤として使用した、粘着性が低くべたつきの発生が抑制された毛髪化粧料が提案されている(特許文献2)。しかしながら、この技術は粘着性を低く抑えることを目的としたものであり(段落[0003])、実際に、当該文献に記載された毛髪化粧料は粘着性が低く、セット性にも劣るものである。 In addition, hair makeup using a copolymer of an N-substituted (meth) acrylamide monomer and other unsaturated monomers as a base for hair cosmetics with low tackiness and reduced stickiness. A fee has been proposed (Patent Document 2). However, this technique is intended to keep the tackiness low (paragraph [0003]). In fact, the hair cosmetics described in this document have low tackiness and poor setability. is there.
また、再整髪が可能な毛髪化粧料として、毛髪セット用ポリマーとポリオール溶剤とを一定比率で含有し、更に可塑剤として特定の非イオン界面活性剤を含有する組成物を原液とするエアゾール化粧料(特許文献3)、1価分岐鎖アルコール、毛髪固定用高分子及び特定の非イオン界面活性剤を含有する透明毛髪化粧料(特許文献4)が提案されている。しかしながら、これらのものも、粘着性が十分でなく、思いどおりのヘアスタイルを長時間保持することは難しい。 In addition, as a hair cosmetic capable of re-styling, an aerosol cosmetic comprising a composition containing a polymer for hair setting and a polyol solvent in a certain ratio and further containing a specific nonionic surfactant as a plasticizer. (Patent Document 3) A transparent hair cosmetic (Patent Document 4) containing a monovalent branched alcohol, a hair fixing polymer and a specific nonionic surfactant has been proposed. However, these products are not sufficiently tacky, and it is difficult to maintain a desired hairstyle for a long time.
従って本発明は、セット性及び再整髪性に優れ、しかもべたつき、ごわつきが少ない毛髪化粧料を提供することを目的とする。 Accordingly, an object of the present invention is to provide a hair cosmetic that is excellent in setability and re-styling properties, and that is less sticky and less stiff.
本発明者らは、特定の毛髪セット用ポリマーと特定の可塑剤を組合せ、かつ特定の成分の含有量を抑制した霧状に吐出して使用する毛髪化粧料が、上記要求を満たすものであることを見出した。 The inventors of the present invention have a hair cosmetic composition that combines a specific hair set polymer and a specific plasticizer and that is used by discharging in a mist form with a specific content suppressed, and satisfies the above requirements. I found out.
本発明は、次の成分(A)及び(B)を含有し、更に成分(C)及び/又は成分(D)を含有するか、又はいずれも含有せず、成分(C)の含有量の成分(B)の含有量に対する質量比(C)/(B)が0〜1、成分(D)の含有量の成分(A)の含有量に対する質量比(D)/(A)が0〜0.2であり、かつ成分(B)及び成分(C)の合計含有量の成分(A)の含有量に対する質量比〔(B)+(C)〕/(A)が0.8〜3である霧状に吐出して使用する毛髪化粧料を提供するものである。 The present invention contains the following components (A) and (B), and further contains component (C) and / or component (D) or none of them, and the content of component (C) The mass ratio (C) / (B) to the content of the component (B) is 0 to 1, and the mass ratio (D) / (A) of the content of the component (D) to the content of the component (A) is 0 to 0. A mist in which the mass ratio [(B) + (C)] / (A) of the total content of component (B) and component (C) to content of component (A) is 0.8 to 3 The present invention provides a hair cosmetic material that is used by being discharged onto the skin.
(A) ビニル系アニオン性毛髪セット用ポリマー
(B) 30℃で液体である、ポリオキシアルキレンアルキルエーテル又はポリオキシアルキレン硬化ヒマシ油
(C) 30℃で固体である、ポリオキシアルキレンアルキルエーテル又はポリオキシアルキレン硬化ヒマシ油
(D) 炭素数14〜20の1価脂肪族分岐アルコール
(A) Vinyl-based anionic hair set polymer
(B) Polyoxyalkylene alkyl ether or polyoxyalkylene hydrogenated castor oil that is liquid at 30 ° C
(C) Polyoxyalkylene alkyl ether or polyoxyalkylene hydrogenated castor oil that is solid at 30 ° C.
(D) Monovalent aliphatic branched alcohol having 14 to 20 carbon atoms
本発明の霧状に吐出して使用する毛髪化粧料は、セット性及び再整髪性に優れ、かつべたつき、ごわつきが少ない。 The hair cosmetic composition used by being discharged in the form of a mist of the present invention is excellent in setability and re-styling properties, and is less sticky and stiff.
成分(A)のビニル系アニオン性毛髪セット用ポリマーとしては、以下のものが挙げられる。 Examples of the vinyl-based anionic hair setting polymer of component (A) include the following.
・クロトン酸、マレイン酸、マレイン酸モノエステル、イタコン酸のいずれかを構成単位として含むアニオン性の皮膜形成性ポリマー:
クロトン酸、マレイン酸、マレイン酸モノエステル、イタコン酸のいずれかを構成単位として含んでいれば特に限定されないが、ビニルエーテル類、ビニルエステル類の1種以上と共重合されているもの、あるいは更に加水分解によりビニルアルコール単位を構成するものが好ましい。例えば、メチルビニルエーテル/マレイン酸アルキルコポリマー(ISP社製のガントレッツES-225,同ES-425,同SP-215等)、酢酸ビニル/クロトン酸コポリマー(ナショナル・スターチ社製のレジン28-1310等)、酢酸ビニル/クロトン酸/ネオデカン酸ビニルコポリマー(ナショナル・スターチ社製のレジン28-2930等)、酢酸ビニル/クロトン酸/プロピオン酸ビニルコポリマー(BASF社製のルビセットCAP等)、ビニルアルコール/イタコン酸コポリマー(クラレ社製のKM-118等)がより好ましく、メチルビニルエーテル/マレイン酸アルキルコポリマー、酢酸ビニル/クロトン酸コポリマー、酢酸ビニル/クロトン酸/ネオデカン酸ビニルコポリマー、酢酸ビニル/クロトン酸/プロピオン酸ビニルコポリマーが更に好ましい。
An anionic film-forming polymer containing any one of crotonic acid, maleic acid, maleic acid monoester, and itaconic acid as a structural unit:
It is not particularly limited as long as it contains any one of crotonic acid, maleic acid, maleic acid monoester, and itaconic acid as a structural unit, but it is copolymerized with one or more of vinyl ethers and vinyl esters, or further hydrolyzed. Those constituting vinyl alcohol units by decomposition are preferred. For example, methyl vinyl ether / alkyl maleate copolymer (ISP Gantrez ES-225, ES-425, SP-215, etc.), vinyl acetate / crotonic acid copolymer (National Starch resin 28-1310, etc.) , Vinyl acetate / crotonic acid / vinyl neodecanoate copolymer (resin 28-2930 manufactured by National Starch Co., Ltd.), vinyl acetate / crotonic acid / vinyl propionate copolymer (rubiset CAP manufactured by BASF, etc.), vinyl alcohol / itaconic acid Copolymers (KM-118 manufactured by Kuraray Co., Ltd.) are more preferable, such as methyl vinyl ether / alkyl maleate copolymer, vinyl acetate / crotonic acid copolymer, vinyl acetate / crotonic acid / neodecanoic acid copolymer, vinyl acetate / crotonic acid / vinyl propionate. More preferred are copolymers.
・(メタ)アクリル酸を構成単位として含むアニオン性の皮膜形成性ポリマー:
(メタ)アクリル酸を構成単位として含むビニルポリマーであれば特に限定されないが、(メタ)アクリル酸アルキルエステルあるいはN-アルキル(メタ)アクリルアミドの1種以上と共重合されているものが好ましい。より好ましくは、アクリル酸/エチルアクリレート/N-t-ブチルアクリルアミドコポリマー(BASF社製のウルトラホールド8,ウルトラホールド・ストロング等)、オクチルアクリルアミド/アクリル酸コポリマー(ナショナル・スターチ社製のアンフォーマーV-42等)、アクリレート/メタクリレート/アクリル酸/メタクリル酸コポリマー(ユニオンカーバイド社製のアマホールドDR25等)、アクリレーツ/ジアセトンアクリルアミドコポリマー(互応化学工業社製のプラスサイズL9540B(当該ポリマーの2-アミノ-2-メチル-1-プロピルアルコール中和物)等)、アクリレーツ/C1-18アルキルアクリレーツ/C1-8アルキルアクリルアミドコポリマー(互応化学工業社製のプラスサイズL9909B(当該ポリマーの2-アミノ-2-メチル-1-プロピルアルコール中和物)等)が挙げられ、アクリレート/メタクリレート/アクリル酸/メタクリル酸コポリマー、アクリレーツ/ジアセトンアクリルアミドコポリマー、アクリレーツ/C1-18アルキルアクリレーツ/C1-8アルキルアクリルアミドコポリマーがより好ましい。
An anionic film-forming polymer containing (meth) acrylic acid as a structural unit:
Although it will not specifically limit if it is a vinyl polymer which contains (meth) acrylic acid as a structural unit, The thing copolymerized with 1 or more types of (meth) acrylic-acid alkylester or N-alkyl (meth) acrylamide is preferable. More preferably, acrylic acid / ethyl acrylate / Nt-butylacrylamide copolymer (BASF Ultrahold 8, Ultrahold Strong, etc.), octylacrylamide / acrylic acid copolymer (National Starch Anformer V-42) ), Acrylate / methacrylate / acrylic acid / methacrylic acid copolymer (Amahold DR25 manufactured by Union Carbide, etc.), acrylates / diacetone acrylamide copolymer (plus size L9540B manufactured by Kyoyo Chemical Co., Ltd. (2-amino-2 of the polymer) -Methyl-1-propyl alcohol neutralized product)), acrylates / C 1-18 alkyl acrylates / C 1-8 alkyl acrylamide copolymer (plus size L9909B (2-amino-2 of the polymer) In methyl-1-propyl alcohol Acrylate / methacrylate / acrylic acid / methacrylic acid copolymers, acrylates / diacetone acrylamide copolymers, and acrylates / C 1-18 alkyl acrylates / C 1-8 alkyl acrylamide copolymers are more preferred.
これらの中でもメチルビニルエーテル/マレイン酸アルキルコポリマー、アクリレーツ/ジアセトンアクリルアミドコポリマー、アクリレーツ/C1-18アルキルアクリレーツ/C1-8アルキルアクリルアミドコポリマーがより好ましく、さらには、アクリレーツ/ジアセトンアクリルアミドコポリマーが特に好ましい。 Among these, methyl vinyl ether / alkyl maleate copolymers, acrylates / diacetone acrylamide copolymers, acrylates / C 1-18 alkyl acrylates / C 1-8 alkyl acrylamide copolymers are more preferred, and acrylates / diacetone acrylamide copolymers are particularly preferred. preferable.
成分(A)の含有量は、高いセット力と再整髪性を得る観点から、全組成中の0.6〜20質量%、更には1〜10質量%、特に1.4〜7質量%が好ましい。なお、本発明の霧状に吐出して使用する毛髪化粧料が、エアゾール原液と噴射剤からなるエアゾール式毛髪化粧料である場合、各成分の含有量に関する限り、「全組成」とは、噴射剤を含まないエアゾール原液の全組成をいうものとする。 The content of the component (A) is preferably from 0.6 to 20% by mass, more preferably from 1 to 10% by mass, and particularly preferably from 1.4 to 7% by mass, based on the total composition, from the viewpoint of obtaining high setting power and re-styling properties. In addition, when the hair cosmetic composition used by discharging in the form of a mist of the present invention is an aerosol hair cosmetic composition comprising an aerosol stock solution and a propellant, as far as the content of each component is concerned, the “total composition” The total composition of an aerosol stock solution that does not contain an agent is meant.
成分(B)は、可塑剤として成分(A)と混合することで粘着性を生じさせるものである。成分(B)のうちポリオキシアルキレンアルキルエーテルとしては、ポリオキシエチレンラウリルエーテル(付加モル数3〜9)、ポリオキシエチレンポリオキシプロピレン(4)セチルエーテル(ポリオキシエチレンの付加モル数1〜10)、ポリオキシエチレンオレイルエーテル(付加モル数4〜13)、ポリオキシエチレンアルキル(sec-C11-15)エーテル(付加モル数5〜9)、ポリオキシエチレンアルキル(sec-C12-14)エーテル(付加モル数5〜9)などが挙げられ、ポリオキシアルキレン硬化ヒマシ油としてはポリオキシエチレン硬化ヒマシ油(付加モル数5〜50)などが挙げられる。具体的には、ポリオキシエチレン(3)ラウリルエーテル、ポリオキシエチレン(4)ラウリルエーテル、ポリオキシエチレン(6)ラウリルエーテル、ポリオキシエチレン(9)ラウリルエーテル;ポリオキシエチレン(1)ポリオキシプロピレン(4)セチルエーテル、ポリオキシエチレン(10)ポリオキシプロピレン(4)セチルエーテル;ポリオキシエチレン(4)オレイルエーテル、ポリオキシエチレン(8)オレイルエーテル、ポリオキシエチレン(13)オレイルエーテル;ポリオキシエチレン(7)セチル−ステアリルエーテル;ポリオキシエチレン(5)アルキル(sec-C11-15)エーテル、ポリオキシエチレン(7)アルキル(sec-C11-15)エーテル、ポリオキシエチレン(9)アルキル(sec-C11-15)エーテル;ポリオキシエチレン(5)アルキル(sec-C12-14)エーテル、ポリオキシエチレン(7)アルキル(sec-C12-14)エーテル、ポリオキシエチレン(9)アルキル(sec-C12-14)エーテルなどが挙げられる。また成分(B)のうちポリオキシアルキレン硬化ヒマシ油としては、ポリオキシエチレン(5)硬化ヒマシ油、ポリオキシエチレン(10)硬化ヒマシ油、ポリオキシエチレン(20)硬化ヒマシ油、ポリオキシエチレン(30)硬化ヒマシ油、ポリオキシエチレン(40)硬化ヒマシ油、ポリオキシエチレン(50)硬化ヒマシ油などが挙げられる。 Ingredient (B) is one that causes tackiness when mixed with ingredient (A) as a plasticizer. Among the components (B), examples of the polyoxyalkylene alkyl ether include polyoxyethylene lauryl ether (addition mole number 3 to 9), polyoxyethylene polyoxypropylene (4) cetyl ether (addition mole number 1 to 10 of polyoxyethylene). ), Polyoxyethylene oleyl ether (addition mole number 4-13), polyoxyethylene alkyl (sec-C11-15) ether (addition mole number 5-9), polyoxyethylene alkyl (sec-C12-14) ether ( Addition mole number 5-9) etc. are mentioned, As polyoxyalkylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil (addition mole number 5-50) etc. are mentioned. Specifically, polyoxyethylene (3) lauryl ether, polyoxyethylene (4) lauryl ether, polyoxyethylene (6) lauryl ether, polyoxyethylene (9) lauryl ether; polyoxyethylene (1) polyoxypropylene (4) cetyl ether, polyoxyethylene (10) polyoxypropylene (4) cetyl ether; polyoxyethylene (4) oleyl ether, polyoxyethylene (8) oleyl ether, polyoxyethylene (13) oleyl ether; polyoxy Ethylene (7) cetyl-stearyl ether; polyoxyethylene (5) alkyl (sec-C11-15) ether, polyoxyethylene (7) alkyl (sec-C11-15) ether, polyoxyethylene (9) alkyl (sec -C11-15) ether; polyoxyethylene (5) alkyl (sec-C12-14) ether, polyoxyethylene (7) alkyl sec-C12-14) ether, polyoxyethylene (9) alkyl (sec-C12-14) ether. Among the component (B), as polyoxyalkylene hydrogenated castor oil, polyoxyethylene (5) hydrogenated castor oil, polyoxyethylene (10) hydrogenated castor oil, polyoxyethylene (20) hydrogenated castor oil, polyoxyethylene ( 30) hydrogenated castor oil, polyoxyethylene (40) hydrogenated castor oil, polyoxyethylene (50) hydrogenated castor oil, and the like.
成分(B)の含有量は、高いセット力と再整髪性を得る観点から、全組成中の1〜30質量%、更には1.6〜16質量%、特に2〜10質量%が好ましい。 The content of the component (B) is preferably 1 to 30% by mass, more preferably 1.6 to 16% by mass, and particularly preferably 2 to 10% by mass in the total composition from the viewpoint of obtaining high setting power and re-styling properties.
また、成分(A)と成分(B)の含有比率は、高いセット力と再整髪性を得る点から、質量比で(B)/(A)=45/55〜75/25、特に50/50〜70/30の範囲に調整することが好ましい。 In addition, the content ratio of the component (A) and the component (B) is (B) / (A) = 45/55 to 75/25, particularly 50 / It is preferable to adjust to the range of 50-70 / 30.
本発明の毛髪化粧料には、更に成分(C)として、30℃で固体のポリオキシアルキレンアルキルエーテル又はポリオキシアルキレン硬化ヒマシ油を少量含有させることもできる。かかる成分(C)は成分(B)と同様、可塑剤として機能するものであるが、経時で成分(C)自体が析出することによる粘着性低下を回避し、セット持ちや再整髪性に優れたものとする観点より、成分(C)の含有量の成分(B)の含有量に対する質量比(C)/(B)は0〜1に制限され、好ましくは0〜0.8、より好ましくは0〜0.6に制限される。 The hair cosmetic composition of the present invention may further contain a small amount of polyoxyalkylene alkyl ether or polyoxyalkylene hydrogenated castor oil that is solid at 30 ° C. as component (C). This component (C) functions as a plasticizer like the component (B), but avoids a decrease in adhesiveness due to the precipitation of the component (C) itself over time, and is excellent in set holding and re-styling. In view of the above, the mass ratio (C) / (B) of the content of component (C) to the content of component (B) is limited to 0 to 1, preferably 0 to 0.8, more preferably 0. Limited to ~ 0.6.
また、成分(B)及び成分(C)の合計含有量の成分(A)の含有量に対する質量比〔(B)+(C)〕/(A)は、高いセット力と再整髪性を得る観点から、0.8〜3であり、更には0.9〜2.5、特に1〜2が好ましい。 Moreover, the mass ratio [(B) + (C)] / (A) of the total content of the component (B) and the component (C) to the content of the component (A) obtains a high setting power and re-styling property. From a viewpoint, it is 0.8-3, Furthermore, 0.9-2.5, especially 1-2 are preferable.
かかる成分(C)のうち30℃で固体のポリオキシアルキレンアルキルエーテルとしては、ポリオキシエチレンラウリルエーテル(付加モル数12以上)、ポリオキシエチレンポリオキシプロピレン(4)セチルエーテル(ポリオキシエチレンの付加モル数20以上)ポリオキシエチレンオレイルエーテル(付加モル数30以上)、ポリオキシエチレンアルキル(sec-C11-15)エーテル(付加モル数30以上)、ポリオキシエチレンアルキル(sec-C12-14)エーテル(付加モル数30以上)などが挙げられ、30℃で固体のポリオキシアルキレン硬化ヒマシ油としてはポリオキシエチレン硬化ヒマシ油(付加モル数60以上)などが挙げられる。具体的には、ポリオキシエチレン(12)ラウリルエーテル、ポリオキシエチレン(30)オレイルエーテル、ポリオキシエチレン(10)セチルエーテル、ポリオキシエチレン(6)ステアリルエーテル、ポリオキシエチレン(13)セチル−ステアリルエーテル、ポリオキシエチレン(20)ポリオキシプロピレン(4)セチルエーテル、ポリオキシエチレン(30)アルキル(sec-C11-15)、ポリオキシエチレン(30)アルキル(sec-C12-14)エーテルなどが挙げられ、成分(C)のうち30℃で固体のポリオキシアルキレン硬化ヒマシ油としては、ポリオキシエチレン(60)硬化ヒマシ油、ポリオキシエチレン(80)硬化ヒマシ油、ポリオキシエチレン(100)硬化ヒマシ油などが挙げられる。 Among these components (C), solid polyoxyalkylene alkyl ethers at 30 ° C. include polyoxyethylene lauryl ether (addition mole number 12 or more), polyoxyethylene polyoxypropylene (4) cetyl ether (addition of polyoxyethylene) Mole number 20 or more) polyoxyethylene oleyl ether (addition mole number 30 or more), polyoxyethylene alkyl (sec-C11-15) ether (addition mole number 30 or more), polyoxyethylene alkyl (sec-C12-14) ether (Addition mole number 30 or more) etc. are mentioned, As polyoxyalkylene hydrogenated castor oil solid at 30 degreeC, polyoxyethylene hydrogenated castor oil (addition mole number 60 or more) etc. are mentioned. Specifically, polyoxyethylene (12) lauryl ether, polyoxyethylene (30) oleyl ether, polyoxyethylene (10) cetyl ether, polyoxyethylene (6) stearyl ether, polyoxyethylene (13) cetyl-stearyl Ether, polyoxyethylene (20) polyoxypropylene (4) cetyl ether, polyoxyethylene (30) alkyl (sec-C11-15), polyoxyethylene (30) alkyl (sec-C12-14) ether, etc. Among the component (C), the polyoxyalkylene hydrogenated castor oil that is solid at 30 ° C. includes polyoxyethylene (60) hydrogenated castor oil, polyoxyethylene (80) hydrogenated castor oil, polyoxyethylene (100) hydrogenated castor oil. Examples include oil.
本発明の毛髪化粧料には、更に成分(D)として、炭素数14〜20の1価脂肪族分岐アルコールを少量含有させることもできるが、成分(A)との分離による粘着性の低下を回避し、セット力、セット持ち及び再整髪性に優れたものとする観点から、成分(D)の含有量の成分(A)の含有量に対する質量比(D)/(A)は0〜0.2に制限され、好ましくは0〜0.1、より好ましくは0〜0.05に制限される。 The hair cosmetic composition of the present invention can further contain a small amount of a monovalent aliphatic branched alcohol having 14 to 20 carbon atoms as the component (D), but the adhesiveness is reduced due to separation from the component (A). The mass ratio (D) / (A) of the content of the component (D) to the content of the component (A) is 0 to 0.2 from the viewpoint of avoiding and having excellent setting power, set holding and re-hairing properties. To 0, preferably 0 to 0.1, more preferably 0 to 0.05.
かかる成分(D)としては、イソミリスチルアルコール、イソパルミチルアルコール、イソステアリルアルコール、イソアラキルアルコールが挙げられる。 Examples of the component (D) include isomyristyl alcohol, isopalmityl alcohol, isostearyl alcohol, and isoaralkyl alcohol.
本発明の毛髪化粧料には、更に溶媒としてエタノール及び/又は水が含有されることが好ましい。これらの含有量は、化粧料に含まれるポリマーや可塑剤の溶解性や噴霧状態を良好にする観点から、全組成中の4〜98.4質量%が好ましく、更には30〜98質量%、特に50〜95質量%が好ましい。 The hair cosmetic composition of the present invention preferably further contains ethanol and / or water as a solvent. The content thereof is preferably 4 to 98.4% by mass, more preferably 30 to 98% by mass, particularly 50% from the viewpoint of improving the solubility and spray state of the polymer and plasticizer contained in the cosmetic. -95 mass% is preferable.
また、本発明の毛髪化粧料は、通常の毛髪化粧料に使用される各種成分、例えば、カチ
オン界面活性剤、アニオン界面活性剤、前記以外の非イオン界面活性剤、両性界面活性剤
、pH調整剤、ビタミン類、蛋白質、アミノ酸類、生薬類、防腐剤、紫外線吸収剤、酸化防
止剤、着色剤等を、目的に応じて含有することができる。
The hair cosmetic composition of the present invention includes various components used in normal hair cosmetics, such as cationic surfactants, anionic surfactants, nonionic surfactants other than those described above, amphoteric surfactants, pH adjustment. Agents, vitamins, proteins, amino acids, herbal medicines, preservatives, ultraviolet absorbers, antioxidants, colorants and the like can be contained according to the purpose.
本発明の毛髪化粧料は、エアゾール式スプレー又はポンプ式スプレーの形態とすることができる。 The hair cosmetic composition of the present invention can be in the form of an aerosol spray or a pump spray.
本発明の毛髪化粧料をエアゾール式毛髪化粧料とする場合は、更に噴射剤を用いる。エアゾール式毛髪化粧料は、噴射剤以外の成分(以下原液とする)と噴射剤とを耐圧容器に充填することにより製造される。 When the hair cosmetic composition of the present invention is an aerosol hair cosmetic composition, a propellant is further used. Aerosol hair cosmetics are manufactured by filling a pressure-resistant container with components other than a propellant (hereinafter referred to as a stock solution) and a propellant.
噴射剤としては、液化石油ガス(LPG)、ジメチルエーテル(DME)、炭酸ガス、窒素ガス、これらの混合物等が挙げられる。また、HFC-152a等の代替フロンを使用することもできる。噴射剤の量は、良好な作業性、整髪性、再整髪性と共に、良好な噴射特性と粘着特性を得るために、原液と噴射剤の質量比で、原液/噴射剤=5/95〜80/20、更には30/70〜70/30、更には40/60〜60/40の範囲が好ましい。また、耐圧容器内の圧力が良好な噴射特性と良好な粘着特性を得るためには20℃の温度で0.12〜0.45MPaになるように調整するのが好ましい。 Examples of the propellant include liquefied petroleum gas (LPG), dimethyl ether (DME), carbon dioxide gas, nitrogen gas, and mixtures thereof. Alternatively, alternative CFCs such as HFC-152a can be used. In order to obtain good jetting properties and adhesive properties, as well as good workability, hair styling properties, and re-styling properties, the amount of the propellant is the stock solution / propellant mass ratio: stock solution / propellant = 5 / 95-80 / 20, further 30/70 to 70/30, more preferably 40/60 to 60/40. In order to obtain good jetting characteristics and good adhesive characteristics, the pressure in the pressure vessel is preferably adjusted to be 0.12 to 0.45 MPa at a temperature of 20 ° C.
原液は、30℃における粘度が15mPa・s以下、特に10mPa・s以下であるのが、原液を微細な液滴として噴射するために好ましい。なお、ここでの粘度とは、ブルックフィールド型粘度計(ローター BLアダプター,回転数30rpm,60秒間,30℃)により測定した値をいう。 The stock solution has a viscosity of 15 mPa · s or less, particularly 10 mPa · s or less, at 30 ° C., in order to eject the stock solution as fine droplets. Here, the viscosity is a value measured by a Brookfield viscometer (rotor BL adapter, rotation speed 30 rpm, 60 seconds, 30 ° C.).
耐圧容器に使用するバルブは、ステム径φ0.33〜0.46mm,ハウジング径φ0.33〜0.65mm×ベーパータップ径φ0〜0.64mmが好ましい。水を含む処方系では、特にステム径φ0.33〜0.42mm、ハウジング径φ0.33〜0.42mm、かつベーパータップ無しが好ましく、非水系では、特にステム径φ0.40〜0.46mm、ハウジング径φ0.42〜0.65mm×ベーパータップ径φ0.33〜0.46mmが好ましい。 The valve used in the pressure vessel preferably has a stem diameter of 0.33 to 0.46 mm, a housing diameter of 0.33 to 0.65 mm, and a vapor tap diameter of 0 to 0.64 mm. In the prescription system containing water, it is particularly preferable that the stem diameter is 0.33 to 0.42 mm, the housing diameter is 0.33 to 0.42 mm, and there is no vapor tap, and in the non-aqueous system, particularly the stem diameter is φ0.40 to 0.46 mm, the housing diameter is φ0. .42 to 0.65 mm × vapor tap diameter φ0.33 to 0.46 mm is preferable.
実施例1〜7及び比較例1〜6
表1に示す各成分をエタノールに溶解してヘアスプレー原液を調製し、噴射剤としてのLPG(0.15MPa,20℃)と共に、原液/噴射剤(質量比)=47/53で、下記バルブ及びボタンを備えたエアゾール容器に充填して、エアゾール式毛髪化粧料(ヘアスプレー)を製造した。容器内の圧力は20℃で0.23Mpaであった。
バルブ:ステム径φ0.41mm,ハウジング径φ0.64mm×ベーパータップ径φ0.41mm
ボタン:口径φ0.46mm(MB,コンケープ)
(日本プリシジョンバルブ社)
Examples 1-7 and Comparative Examples 1-6
Each component shown in Table 1 is dissolved in ethanol to prepare a hair spray stock solution, and with LPG (0.15 MPa, 20 ° C.) as a propellant, stock solution / propellant (mass ratio) = 47/53, the following valves and An aerosol container with a button was filled to produce an aerosol hair cosmetic (hair spray). The pressure in the container was 0.23 MPa at 20 ° C.
Valve: Stem diameter φ0.41mm, Housing diameter φ0.64mm x Vapor tap diameter φ0.41mm
Button: caliber φ0.46mm (MB, cape)
(Nippon Precision Valve)
(評価方法)
専門パネラー10人により、各ヘアスプレーを用いて髪をセットし、「セット性」、「べたつきのなさ」及び「ごわつきのなさ」について官能評価を行った。
更に、スプレー施術後、25℃、65%の環境で9時間経過後、「再整髪性」についても官能評価を行った。なお、評価は以下の基準に従って行い、10人の評価点の平均値で示した。
(Evaluation methods)
Ten professional panelists set their hair using each hair spray and performed a sensory evaluation on "setability", "no stickiness" and "no stickiness".
Furthermore, after the spray treatment, after 9 hours in an environment of 25 ° C. and 65%, a sensory evaluation was also performed on “re-hair styling”. The evaluation was performed according to the following criteria, and was shown as the average value of 10 evaluation points.
(評価基準)
5:非常に良い。
4:良い。
3:やや良い。
2:やや悪い。
1:悪い。
(Evaluation criteria)
5: Very good.
4: Good.
3: Slightly good.
2: Slightly bad.
1: Bad.
表1に示す各実施例の原液組成をエタノールで2質量倍に希釈し、容器に封入してポンプスプレーとした(三谷バルブ社製のZ-155-120のスプレイヤーを使用)。これらのポンプスプレーについて、「セット性」、「再整髪性」、「べたつきのなさ」及び「ごわつきのなさ」の評価を行い、いずれも良好な結果を得た。 The stock solution composition of each Example shown in Table 1 was diluted 2 mass times with ethanol and sealed in a container to obtain a pump spray (using a sprayer Z-155-120 manufactured by Mitani Valve). These pump sprays were evaluated for “setting property”, “re-hairing property”, “non-stickiness” and “non-stickiness”, and good results were obtained.
Claims (3)
(A) ビニル系アニオン性毛髪セット用ポリマー
(B) 30℃で液体である、ポリオキシアルキレンアルキルエーテル又はポリオキシアルキレン硬化ヒマシ油
(C) 30℃で固体である、ポリオキシアルキレンアルキルエーテル又はポリオキシアルキレン硬化ヒマシ油
(D) 炭素数14〜20の1価脂肪族分岐アルコール Component (B) containing the following components (A) and (B) and further containing component (C) and / or component (D) or none of them, and component (C) content The mass ratio (C) / (B) to content of 0 to 1, the mass ratio (D) / (A) of content of component (D) to content of component (A) is 0 to 0.2, And the mass ratio [(B) + (C)] / (A) of the total content of the component (B) and the component (C) to the content of the component (A) is discharged in a mist form of 0.8-3. Hair cosmetic used.
(A) Vinyl-based anionic hair set polymer
(B) Polyoxyalkylene alkyl ether or polyoxyalkylene hydrogenated castor oil that is liquid at 30 ° C
(C) Polyoxyalkylene alkyl ether or polyoxyalkylene hydrogenated castor oil that is solid at 30 ° C.
(D) Monovalent aliphatic branched alcohol having 14 to 20 carbon atoms
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Cited By (3)
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JP2017019728A (en) * | 2015-07-07 | 2017-01-26 | 株式会社マンダム | Hairdressing agent composition and method for producing hairdressing agent composition |
JP2017206478A (en) * | 2016-05-20 | 2017-11-24 | 株式会社マンダム | Hairdressing agent composition |
WO2019044276A1 (en) * | 2017-08-28 | 2019-03-07 | 株式会社マンダム | Aerosol spray hairdressing agent composition and aerosol spray hairdressing agent |
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JP2002370946A (en) * | 2001-06-18 | 2002-12-24 | Kanebo Ltd | Atomized hair cosmetic |
JP2003246712A (en) * | 2002-02-22 | 2003-09-02 | Kanebo Ltd | Misty hair cosmetic |
JP2007031385A (en) * | 2005-07-28 | 2007-02-08 | Mandom Corp | Aerosol spraying-type composition for hair |
JP2007145878A (en) * | 2003-08-06 | 2007-06-14 | Kao Corp | Aerosol cosmetic |
JP2008290973A (en) * | 2007-05-24 | 2008-12-04 | Mandom Corp | Foamy hair-dressing cosmetic |
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JPH06504792A (en) * | 1991-11-21 | 1994-06-02 | ロレアル | aerosol hair lacquer |
JP2002370946A (en) * | 2001-06-18 | 2002-12-24 | Kanebo Ltd | Atomized hair cosmetic |
JP2003246712A (en) * | 2002-02-22 | 2003-09-02 | Kanebo Ltd | Misty hair cosmetic |
JP2007145878A (en) * | 2003-08-06 | 2007-06-14 | Kao Corp | Aerosol cosmetic |
JP2007031385A (en) * | 2005-07-28 | 2007-02-08 | Mandom Corp | Aerosol spraying-type composition for hair |
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JP2017019728A (en) * | 2015-07-07 | 2017-01-26 | 株式会社マンダム | Hairdressing agent composition and method for producing hairdressing agent composition |
JP2017206478A (en) * | 2016-05-20 | 2017-11-24 | 株式会社マンダム | Hairdressing agent composition |
WO2019044276A1 (en) * | 2017-08-28 | 2019-03-07 | 株式会社マンダム | Aerosol spray hairdressing agent composition and aerosol spray hairdressing agent |
JPWO2019044276A1 (en) * | 2017-08-28 | 2019-11-07 | 株式会社マンダム | Aerosol spray hair styling composition and aerosol spray hair styling agent |
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