CN101469150A - Ink set for ink jet recording and method for ink jet recording - Google Patents
Ink set for ink jet recording and method for ink jet recording Download PDFInfo
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- CN101469150A CN101469150A CNA2008101885134A CN200810188513A CN101469150A CN 101469150 A CN101469150 A CN 101469150A CN A2008101885134 A CNA2008101885134 A CN A2008101885134A CN 200810188513 A CN200810188513 A CN 200810188513A CN 101469150 A CN101469150 A CN 101469150A
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Abstract
Disclosed is a five-color ink set for ink jet recording, which can realize good images excellent in lightfastness and waterfastness, as well as particularly in hue. The five-color ink set for ink jet recording comprises a cyan ink composition, a magenta ink composition, a yellow ink composition, a green ink composition and an orange ink composition, wherein the cyan ink composition comprises C.I. Pigment Blue 15 : 3 or C.I. Pigment Blue 15 : 4, the magenta ink composition comprises C.I. Pigment Red 122, C.I. Pigment Red 202, C.I. Pigment Red 209 or C.I. Pigment Violet 19, the yellow ink composition comprises C.I. Pigment Yellow 213, the green ink composition comprises C.I. Pigment Green 7 or C.I. Pigment Green 36, and the orange ink composition comprises C.I. Pigment Orange 64, C.I. Pigment Orange 43 or C.I. Pigment Orange 71.
Description
Technical field
The present invention relates to a kind of ink for inkjet recording group, described ink group comprises cyan composition, yellow ink composition, magenta ink composition, green ink composition and orange composition for ink.
Background technology
Ink-vapor recording is wherein to make the drop flight of composition for ink and be deposited on for example printing process to print on the paper of recording medium.This method is characterised in that, can be with relatively cheap equipment high speed printing high resolving power and high-quality image.
The composition for ink that is used for ink-vapor recording comprises the water as main ingredient usually, and the wetting agent that adds the tinting material component in the entry and for example be used to prevent stop up purpose glycerine for example.Water-soluble dye is for example considered their high colourity level, and their abundant available types, and their solubleness in water are widely used as the tinting material that is used for ink composition for inkjet recording so far.
On the other hand, dyestuff is for example poor on photostabilization and the water tolerance in various performances sometimes.Therefore, use the print of dyestuff-base ink compositions printing to have poor photostabilization and water tolerance.Though water tolerance improves by the ink-jet specific record paper that use contains the ink absorption layer, the water tolerance of the print on common paper has the space of improvement.
Pigment is better than dyestuff on photostabilization and water tolerance, and considers and improve photostabilization and water tolerance, pigment is studied as the utilization that is used for the tinting material of ink composition for inkjet recording recently.Pigment is insoluble in water usually.Therefore, when pigment being used for water-base ink compositions, before the preparation of composition for ink, should provide the following step: pigment is mixed with resin that is called dispersion agent etc., and this mixture is added to the water, with this stabilized with mixture be dispersed in the water.
In addition, conduct is used for the use of the tinting material of ink for inkjet recording for pigment, pigment is better than dyestuff on photostabilization and water tolerance, but on the other hand, the quantity of the kind of available coloured material is less than the quantity of the kind of available coloured material in the dyestuff in the pigment.When pigment is actually used in ink for inkjet recording, except that photostabilization and water tolerance, also should study form and aspect satisfactorily.For example, Japanese Patent discloses 345080/2000 and has proposed to have the yellow ink composition of combination that excellent sunproof specific pigment and two kinds have the specific pigment of excellent color developing a kind of comprising.In addition, Japanese Patent discloses the 120956/1998 ink group that has proposed a kind of combination of cyan, magenta and the yellow ink composition that contains specific pigment, described ink group can be implemented on photostabilization and the water tolerance, and excellent good image on form and aspect particularly.
In addition, WO1999/005230 has proposed a kind of ink group, this ink group comprises cyan composition, magenta ink composition, yellow ink composition and black ink composition, and the combination of other orange composition for ink and green ink composition.The ink advantage of being claimed is, can be implemented on photostabilization and the water tolerance, and excellent good image on form and aspect particularly.
Japanese Patent discloses 283017/2006, color developing and color reproduction scope, the color reproduction of red area particularly, can form image by the ink group that use contains first ink and second ink enlarges, described first ink has and is being not less than 450nm and less than the maximum absorption wavelength in the scope of 500nm, described second ink has and is being not less than 500nm and is being not more than maximum absorption wavelength in the scope of 570nm, described ink group satisfies by formula B/A=and is not less than 0.7 and be not more than the requirements of 1.0 expressions, and wherein A represents that first ink and second ink are being not less than 450nm and are being not more than the maximum absorbance of the total absorbance in the wavelength region of 570nm; And B represents that first ink and second ink are being not less than 450nm and are being not more than the minimum absorbancy of the total absorbance in the wavelength region of 570nm.Above publication has also been described can form the image with good gray scale (gradation).
Summary of the invention
The inventor finds now, method for color ink-jetting record, the ink group of combination that contains yellow ink composition, magenta ink composition, cyan composition, green ink composition and the orange composition for ink of specific pigment can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect, and do not need to use multiple pigment as yellow ink pigment.The present invention is based on that such discovery carries out.
Therefore, an object of the present invention is to provide a kind of ink for inkjet recording group, described ink group can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
According to the present invention, a kind of ink for inkjet recording group is provided, described ink group comprises cyan composition, magenta ink composition, yellow ink composition, green ink composition and orange composition for ink, wherein
Described cyan composition comprises and is selected from the pigment Blue 15 by C.I.: 3 and the C.I. pigment Blue 15: at least a pigment in 4 groups of forming is as tinting material,
Described magenta ink composition comprises at least a pigment that is selected from the group of being made up of C.I. pigment red 122, C.I. Pigment red 202, C.I. Pigment red 209 and C.I. pigment violet 19 as tinting material,
Described yellow ink composition comprises C.I. Pigment Yellow 73 213 as tinting material,
Described green ink composition comprises at least a pigment that is selected from the group of being made up of C.I. pigment Green 7 and C.I. pigment green 36 as tinting material, and
Described orange composition for ink comprises at least a pigment that is selected from the group of being made up of C.I. pigment orange 64, C.I. pigment orange 43 and C.I. pigment orange 71 as tinting material.
According to another aspect of the present invention, a kind of ink-vapor recording method is provided, described method comprises the drop that sprays composition for ink, and this drop is deposited to the step to print on the recording medium, wherein uses at least a composition for ink that comprises in the above ink group.
According to the present invention, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
Embodiment
Ink group according to the present invention comprises cyan composition, magenta ink composition, yellow ink composition, green ink composition and orange composition for ink, and each of these composition for ink contains the specific pigment as tinting material.To each composition for ink that constitute according to ink group of the present invention be described.
The yellow ink composition
Be used for yellow ink composition according to ink group of the present invention and contain C.I. Pigment Yellow 73 213 as tinting material.This contains the yellow ink composition of yellow ultramarine and being used in combination of magenta ink composition, cyan composition, green ink composition and the orange composition for ink that will describe subsequently, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
Particularly, it should be noted that, according to the present invention,, and do not use multiple yellow ultramarine only by using the yellow ink composition only contain as the C.I. Pigment Yellow 73 213 of yellow ultramarine, for example, do not use have excellent sunproof yellow ultramarine (for example, C.I. pigment Yellow 12 8 or C.I. Pigment Yellow 73 110) with have the combination of the yellow ultramarine (for example, the C.I. Pigment Yellow 73 74) of excellent color developing, can be created on photostabilization and the water tolerance, and special good image excellent on form and aspect.This is wonderful, and is advantage of the present invention.In addition, owing to do not need to use the yellow ink composition that contains multiple pigment, the present invention be advantageous in that the preparation of composition for ink and the practice of ink-vapor recording are simple.
The yellow ink composition that uses among the present invention comprises water and at least with paint.The amount that joins the pigment in the composition for ink can be implemented on photostabilization and the water tolerance, and suitably determines in the scope that excellent good figure measures like this on form and aspect.Yet preferably, the add-on of pigment for example is, is not more than 6 weight %.
Preferably will join in the composition for ink with the form of paint with dispersible pigment dispersion, described dispersible pigment dispersion is by preparing colo(u)rant dispersion by means of dispersion agent or tensio-active agent in aqueous medium.Preferred dispersing agent comprises the dispersion agent that generally is used for the preparation of dispersible pigment dispersion, for example, and polymeric dispersant.
The example of preferred polymeric dispersant comprises synthetic polymer.The example of this synthetic polymer comprises: polyvinyl alcohol; Polyvinylpyrolidone (PVP); Acrylic resin, for example, polyacrylic acid, vinylformic acid/acrylonitrile copolymer, potassium acrylate/acrylonitrile copolymer, vinyl-acetic ester/acrylate copolymer and acrylic acid/esters multipolymer; Styrene/acrylic resinoid, for example styrene/acrylic acid co-polymer, styrene/methacrylic acid multipolymer, styrene/methacrylic acid/acrylate copolymer, vinylbenzene/alpha-methyl styrene/acrylic copolymer and vinylbenzene/alpha-methyl styrene/acrylic acid/esters multipolymer; Vinylbenzene/maleic acid; Vinylbenzene/maleic anhydride copolymers; Vinyl naphthalene/acrylic copolymer; Vinyl naphthalene/maleic acid; Vinyl acetate copolymer, for example, vinyl acetate/ethylene copolymer, vinyl-acetic ester/fatty acid vinyl (fatty acid vinyl)/ethylene copolymer, vinyl-acetic ester/maleate copolymer, vinyl-acetic ester/Ba Dousuan multipolymer and vinyl-acetic ester/acrylic copolymer; And the salt of above polymkeric substance.In them, especially preferably have the monomer of hydrophobic group and the monomeric multipolymer of possess hydrophilic property group, and the polymer of monomers that in its molecular structure, has hydrophobic group and hydrophilic radical simultaneously, for example styrene/acrylic acid co-polymer or its salt.
In a preferred embodiment of the invention, the yellow ink composition comprises organic solvent.Organic solvent is low boiling point organic solvent preferably, and its preferred embodiment comprises methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, sec-butyl alcohol, the trimethyl carbinol, isopropylcarbinol and Pentyl alcohol.Monohydroxy-alcohol is particularly preferred.Low boiling point organic solvent has the effect that shortening is used for dry composition for ink time necessary.
In a preferred embodiment of the invention, be used for composition for ink of the present invention and preferably further comprise high boiling organic solvent.The example of preferred high boiling organic solvent comprises: polyvalent alcohol, for example ethylene glycol, glycol ether, triglycol, polyoxyethylene glycol, polypropylene glycol, propylene glycol, butyleneglycol, 1,2,6-hexanetriol, 2 mercapto ethanol, hexylene glycol, glycerine, trimethylolethane and TriMethylolPropane(TMP); The alkyl oxide of polyvalent alcohol, for example, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triglycol list ether and triglycol monobutyl ether; Urea; 2-Pyrrolidone; The N-N-methyl-2-2-pyrrolidone N-; 1,3-dimethyl-2-imidazolone and trolamine.
Based on composition for ink, the amount of the low boiling point organic solvent of adding is preferably 0.5 to 10 weight %, more preferably 1.5 to 6 weight %.Based on composition for ink, the amount of the high boiling organic solvent of adding is preferably 0.5 to 40 weight %, more preferably 2 to 20 weight %.
In a preferred embodiment of the invention, yellow ink composition according to the present invention can comprise tensio-active agent.Preferred surfactants comprises: for example, anion surfactant (for example, the ammonium salt of Sodium dodecylbenzene sulfonate, sodium laurate (sodium laurylate) and polyoxyethylene alkyl ether sulfate salt) and nonionogenic tenside (for example, Voranol EP 2001, polyxyethylated ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl phenyl ether, polyoxyethylene alkyl amine and polyoxyethylene alkylamide).They can use separately or with two or more form of mixtures.In addition, can also use acetylenediol (OLFINE Y, Surfynol 82, Surfynol 104, Surfynol440, Surfynol 465 and Surfynol 485 (above all prods by Air Products andChemicals Inc. produce)).
The example of other preferred surfactant comprises commercially available silicone surfactant BYK-347 and BYK-348 (above two kinds of products are produced by BYK Japan K.K.).
In case of necessity, can add other additive, for example, pH regulator agent, sanitas and mould inhibitor.
Magenta ink composition
Be used for magenta ink composition according to ink group of the present invention comprise be selected from the group of forming by C.I. pigment red 122, C.I. Pigment red 202, C.I. Pigment red 209 and C.I. pigment violet 19 at least a pigment as tinting material.The magenta ink composition that comprises the C.I. pigment red 122 in these pigment is particularly preferred.The magenta ink composition and the above yellow ink composition that comprise this specific magenta pigment, and being used in combination of the cyan composition that will describe subsequently, green ink composition and orange composition for ink, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
The magenta ink composition that constitutes the ink group among the present invention comprises water and at least with paint.The amount that joins the pigment in the composition for ink can be implemented on photostabilization and the water tolerance, and suitably determines in the scope of excellent good figure amount like this on form and aspect.Yet preferably, the add-on of pigment for example is, is not more than 6 weight %.
The same with the yellow ink composition, preferably the form of magenta ink composition pigment with dispersible pigment dispersion joined in the composition for ink, described dispersible pigment dispersion is by preparing colo(u)rant dispersion by means of dispersion agent or tensio-active agent in aqueous medium.Preferred dispersing agent comprises the dispersion agent that generally is used for the preparation of dispersible pigment dispersion, for example, and polymeric dispersant.
The same with the yellow ink composition, for example preferably contain organic solvent, tensio-active agent, pH regulator agent, sanitas and mould inhibitor according to magenta ink composition of the present invention.Its specific examples and add-on can be identical with in the yellow ink composition those.
The cyan composition
Being used for cyan composition according to ink group of the present invention comprises and be selected from the pigment Blue 15 by C.I.: 3 and the C.I. pigment Blue 15: at least a pigment of 4 groups of forming is as tinting material.Comprise the C.I. pigment Blue 15 in these pigment: 4 cyan composition is particularly preferred.Comprise the cyan composition of this specific green pigment and above yellow ink composition, above magenta ink composition, and being used in combination of the green ink composition that will describe subsequently and orange composition for ink, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
The cyan composition that constitutes the ink group among the present invention comprises water and at least with paint.The amount that joins the pigment in the composition for ink can be implemented on photostabilization and the water tolerance, and suitably determines in the scope of excellent good figure amount like this on form and aspect.Yet preferably, the add-on of pigment for example is, is not more than 6 weight %.
The same with the yellow ink composition, preferably cyan composition pigment is joined in the composition for ink with the dispersible pigment dispersion form, described dispersible pigment dispersion is by preparing colo(u)rant dispersion by means of dispersion agent or tensio-active agent in aqueous medium.Preferred dispersing agent comprises the dispersion agent that generally is used for the preparation of dispersible pigment dispersion, for example, and polymeric dispersant.
The same with the yellow ink composition, cyan composition according to the present invention for example preferably contains, organic solvent, tensio-active agent, pH regulator agent, sanitas and mould inhibitor.Its specific examples and add-on can be identical with in the yellow ink composition those.
The green ink composition
Be used for green ink composition according to ink group of the present invention comprise be selected from the group of forming by C.I. pigment Green 7 and C.I. pigment green 36 at least a pigment as tinting material.The green ink composition that comprises the C.I. pigment green 36 in these pigment is particularly preferred.Comprise the green ink composition of this specific veridian and above yellow ink composition, above magenta ink composition, above cyan composition, and being used in combination of the orange composition for ink that will describe subsequently, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
The green ink composition that constitutes the ink group among the present invention comprises water and at least with paint.The amount that joins the pigment in the composition for ink can be implemented on photostabilization and the water tolerance, and suitably determines in the scope of excellent good figure amount like this on form and aspect.Yet preferably, the add-on of pigment for example is, is not more than 6 weight %.
The same with the yellow ink composition, preferably the form of green ink composition pigment with dispersible pigment dispersion joined in the composition for ink, described dispersible pigment dispersion is by preparing colo(u)rant dispersion by means of dispersion agent or tensio-active agent in aqueous medium.Preferred dispersing agent comprises the dispersion agent that generally is used for the preparation of dispersible pigment dispersion, for example, and polymeric dispersant.
The same with the yellow ink composition, green ink composition according to the present invention for example preferably contains, organic solvent, tensio-active agent, pH regulator agent, sanitas and mould inhibitor.Its specific examples and add-on can be identical with in the yellow ink composition those.
Orange composition for ink
Be used for orange composition for ink according to ink group of the present invention comprise be selected from the group of forming by C.I. pigment orange 64, C.I. pigment orange 43 and C.I. pigment orange 71 at least a pigment as tinting material.The orange composition for ink that comprises the C.I. pigment orange 64 in these pigment is particularly preferred.Comprise the orange composition for ink of this specific orange pigments and being used in combination of above yellow ink composition, above magenta ink composition, above cyan composition and above green ink composition, can be implemented on photostabilization and the water tolerance, and special good image excellent on form and aspect.
The orange composition for ink that constitutes the ink group among the present invention comprises water and at least with paint.The amount that joins the pigment in the composition for ink can be implemented on photostabilization and the water tolerance, and suitably determines in the scope of excellent good figure amount like this on form and aspect.Yet preferably, the add-on of pigment for example is, is not more than 6 weight %.
The same with the yellow ink composition, preferably the form of orange composition for ink pigment with dispersible pigment dispersion joined in the composition for ink, described dispersible pigment dispersion is by preparing colo(u)rant dispersion by means of dispersion agent or tensio-active agent in aqueous medium.Preferred dispersing agent comprises the dispersion agent that generally is used for the preparation of dispersible pigment dispersion, for example, and polymeric dispersant.
The same with the yellow ink composition, orange composition for ink according to the present invention for example preferably contains, organic solvent, tensio-active agent, pH regulator agent, sanitas and mould inhibitor.Its specific examples and add-on can be identical with in the yellow ink composition those.
The ink group
Ink group according to the present invention comprises above composition for ink.In the present invention, preferably, the concentration of the green pigment in the cyan composition, and the concentration of the magenta pigment in the magenta ink composition is lower than the concentration of the yellow ultramarine in the yellow ink composition.The color reproduction of image can become the value littler than the concentration of yellow ultramarine by the concentration with the concentration of green pigment and magenta pigment and further improve.
In addition, in the present invention, preferably, the concentration of the magenta pigment in the magenta ink composition is greater than the concentration of the green pigment in the cyan composition, and the concentration of the yellow ultramarine in the yellow ink composition is greater than the concentration of the magenta pigment in the magenta ink composition.When yellow ink composition, magenta ink composition, orange or green ink composition and cyan composition have high pigment levels, the second high pigment concentration, the 3rd high pigment concentration and minimum pigment concentration respectively, can realize better color reproduction.
In a preferred embodiment of the invention, in ink group according to the present invention, the concentration of the pigment in whole composition for ink is not more than 6 weight %, and the concentration of the pigment in the cyan composition (weight %), the concentration of the pigment in the magenta ink composition (weight %), the concentration of the pigment in the yellow ink composition (weight %), ratio between the concentration (weight %) of the pigment in concentration of the pigment in the green ink composition (weight %) and the orange composition for ink is preferably: the pigment concentration of cyan composition: the pigment concentration of magenta ink composition: the pigment concentration of yellow ink composition: the pigment concentration of green ink composition: the pigment concentration of orange composition for ink=2.0 to 5.0:2.5 to 5.5:3.5 to 6.0:2.0 to 5.0:2.0 to 5.0, more preferably 2.5 to 5.0:3.5 to 5.5:4.0 to 6.0:2.0 to 5.0:2.0 to 5.0.According to this embodiment, can realize having the image of the form and aspect of further improvement.
Ink group according to the present invention can be to comprise other the colored recording ink group of other composition for ink of above-mentioned various composition for ink and one or more.In the case, only otherwise sacrifice the effect of the present invention, for example, the type of other composition for ink is not particularly limited, and the composition for ink that can be generally used for conventional ink-vapor recording is as other composition for ink as the ink group.
Other the color inks composition in the ink group be can be included in, light cyan, shallow magenta, dark yellow, redness, blueness and purple composition for ink comprised." shallow magenta " composition for ink and " light cyan " composition for ink are respectively to consider the quality of improving printed images by concentration adjustment, reduce the magenta ink composition and the cyan composition of its colorant concentration separately usually." dark yellow " composition for ink is to consider the color reproduction that improves the dead color in the shade for example, uses the yellow ink composition that has than the tinting material (pigment) of lower lightness of described yellow ink composition and colourity." redness ", " blueness ", " purple " composition for ink are to consider the composition for ink that improves the color reproduction scope and use as the various integrants of the middle shade of yellow, magenta and cyan.
According to ink group of the present invention can with conventional ink group in identical mode constitute, and can be used as ink in the various conventional recording methods.Particularly, in the present invention, can be with relatively cheap equipment high speed printing high resolving power and high-quality image.Therefore, ink group according to the present invention is applicable to ink-vapor recording, that is, be applicable to make ink droplets flight and be deposited on for example application to print on the paper of recording medium.
The ink-vapor recording method
Use comprises with method according to the ink-vapor recording of ink group of the present invention: spray the drop of described composition for ink, and this drop is deposited on the recording medium of heating, to print.The example of method that is used to spray the drop of each composition for ink comprises: wherein use electrostriction element that electrical signal is converted into mechanical signal, spraying the ink be housed in the nozzle head off and on, thus on the surface of recording medium the method for shorthand or symbol; And wherein heat the ink that its part is preserved in the nozzle head near injection portion very much rapidly, to produce bubble and to spray ink off and on, with the method for shorthand or symbol on the surface of recording medium by the volumetric expansion that produces by bubble.In a preferred embodiment of the invention, in the ink jet recording method that uses electrostriction element, adopt described ink group.The injection of the drop of each composition for ink is preferably undertaken by record-header, and described record-header sprays ink droplets by the mechanical effect of utilizing piezoelectric element.
In addition, according to the present invention, also provide a kind of record thing by above recording method record.
[embodiment]
The following example further specifies the present invention.Yet, should be noted in the discussion above that to the invention is not restricted to these embodiment.
The preparation of composition for ink
According to the prescription shown in the table 1 various compositions are mixed, and the film filter of this mixture by 10 μ m filtered, with the preparation ink.The content (weight %) of the various compositions of numeric representation in the described table in ink.
Estimate 1: color reproduction
As shown in table 3, with the various composition for ink combinations that obtain like this, to constitute ink group 1 to 10.For each ink group, with 400 (patch) special-purpose output patterns of ink-jet printer PX-G900 (making) printing by Seiko EpsonCorporation.Whole print to obtaining like this carries out described colour measurement, and calculates L
*a
*Volume in the 3d space of b.By calculating definite gamut volume (Gumat volume) is nondimensional.According to following standard, estimate color reproduction by the gamut volume value of determining.
A: be not less than 830,000
B: be not less than 780,000 and less than 830,000
C: be not less than 730,000 and less than 780,000
D: less than 730,000
Described in the result such as table 3 who estimates.
Estimate 2: the photostabilization of ink group
As shown in following table 3, with the composition for ink combination of above preparation, to constitute the ink group.For each ink group, with estimate mode identical in 1 and print 400 special-purpose output patterns.Resulting print is incorporated into light fastness test machine (luminescent lamp light fastness test machine, by Suga TestInstruments Co., Ltd. in the chamber manufacturing), and it was placed 40 days in the environment of 24 ℃ of temperature and humidity 60%, subsequently the whole sheets in the print are carried out colour measurement, to calculate L
*a
*Volume in the 3d space of b.The gamut volume of calculating is nondimensional.Retention rate is determined by equation (1), and based on this result, is determined photostabilization according to following judgement criteria.Employed luminescent lamp light fastness test machine is made up of 60 luminescent lamps, and can be used for wherein the illumination of printing surface being adjusted in the exposure test of 70,000 Luxs.
Retention rate=[gamut volume of calculating in 1-{ (estimating the gamut volume of calculating in gamut volume (the A)-evaluation 2 of calculating in 1 (B))/evaluation 1 (A) }] * 100 (1)
AA: be not less than 95% retention rate
A: be not less than 90% retention rate
B: be not less than 80% retention rate
C: be not less than 70% retention rate
Described in the result such as table 3 who estimates.
Claims (6)
1. ink for inkjet recording group, described ink group comprises cyan composition, magenta ink composition, yellow ink composition, green ink composition and orange composition for ink, wherein
Described cyan composition comprises and is selected from the pigment Blue 15 by C.I.: 3 and the C.I. pigment Blue 15: at least a pigment in 4 groups of forming is as tinting material,
Described magenta ink composition comprises at least a pigment that is selected from the group of being made up of C.I. pigment red 122, C.I. Pigment red 202, C.I. Pigment red 209 and C.I. pigment violet 19 as tinting material,
Described yellow ink composition comprises C.I. Pigment Yellow 73 213 as tinting material,
Described green ink composition comprises at least a pigment that is selected from the group of being made up of C.I. pigment Green 7 and C.I. pigment green 36 as tinting material, and
Described orange composition for ink comprises at least a pigment that is selected from the group of being made up of C.I. pigment orange 64, C.I. pigment orange 43 and C.I. pigment orange 71 as tinting material.
2. ink group according to claim 1, the concentration of the described green pigment in the wherein said cyan composition, and the concentration of the described magenta pigment in the described magenta ink composition is lower than the concentration of the described yellow ultramarine in the described yellow ink composition.
3. ink group according to claim 1 and 2, the concentration of the described magenta pigment in the wherein said magenta ink composition is greater than the concentration of the described green pigment in the described cyan composition, and the concentration of the described yellow ultramarine in the described yellow ink composition is greater than the concentration of the described magenta pigment in the described magenta ink composition.
4. according to each described ink group in the claim 1 to 3, the concentration of the described pigment in wherein whole described composition for ink is not more than 6 weight %, and the concentration (weight %) of the described pigment in the described cyan composition, the concentration of the described pigment in the described magenta ink composition (weight %), the concentration (weight %) of the described pigment in the described yellow ink composition, ratio between the concentration (weight %) of the described pigment in the described green ink composition and the concentration (weight %) of the described pigment in the described orange composition for ink is: the pigment concentration of cyan composition: the pigment concentration of magenta ink composition: the pigment concentration of yellow ink composition: the pigment concentration of green ink composition: the pigment concentration of orange composition for ink=2.0 to 5.0:2.5 to 5.5:3.5 to 6.0:2.0 to 5.0:2.0 to 5.0.
5. ink-vapor recording method, described method comprises the drop that sprays composition for ink, and described drop is deposited on the recording medium to print, wherein use at least a composition for ink that is comprised according in each the ink group in the claim 1 to 4.
6. one kind is write down thing, and described record thing is to print with method by the ink-vapor recording according to claim 5.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-340510 | 2007-12-28 | ||
| JP2007340510 | 2007-12-28 | ||
| JP2007340510 | 2007-12-28 | ||
| JP2008171305 | 2008-06-30 | ||
| JP2008-171305 | 2008-06-30 | ||
| JP2008171305A JP2009173853A (en) | 2007-12-28 | 2008-06-30 | Ink set for inkjet recording and inkjet recording method |
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| CN101469150A true CN101469150A (en) | 2009-07-01 |
| CN101469150B CN101469150B (en) | 2012-03-28 |
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| CN102086321A (en) * | 2009-12-04 | 2011-06-08 | 精工爱普生株式会社 | Ink set, recording apparatus, and recording method |
| CN101654573B (en) * | 2009-08-14 | 2011-11-30 | 天津兆阳纳米科技有限公司 | Yellow pigment jet ink |
| CN102492327A (en) * | 2011-12-08 | 2012-06-13 | 天津兆阳纳米科技有限公司 | Printing article red ink |
| CN102532986A (en) * | 2011-12-22 | 2012-07-04 | 天津兆阳纳米科技有限公司 | Orange ink for ink-jet printing |
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| DE102005021160A1 (en) * | 2005-05-06 | 2006-11-09 | Clariant Produkte (Deutschland) Gmbh | Pigment preparation based on an azo pigment |
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| JP2008075067A (en) * | 2006-08-22 | 2008-04-03 | Seiko Epson Corp | Photocurable ink set, and printing method, printing apparatus and printed matter each using the same |
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2008
- 2008-06-30 JP JP2008171305A patent/JP2009173853A/en not_active Withdrawn
- 2008-12-19 CN CN2008101885134A patent/CN101469150B/en not_active Expired - Fee Related
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| CN101469150B (en) | 2012-03-28 |
| JP2009173853A (en) | 2009-08-06 |
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