CN101450873B - Method for producing black glaze gold drip glaze and product thereof - Google Patents
Method for producing black glaze gold drip glaze and product thereof Download PDFInfo
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- CN101450873B CN101450873B CN2007101938743A CN200710193874A CN101450873B CN 101450873 B CN101450873 B CN 101450873B CN 2007101938743 A CN2007101938743 A CN 2007101938743A CN 200710193874 A CN200710193874 A CN 200710193874A CN 101450873 B CN101450873 B CN 101450873B
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Abstract
The invention relate to a black glaze gold drop glaze material. The glaze material is characterized in that the glaze material comprises the following components by weight percentage: 12 to 18 percent of Mudaikou violet gold clay, 28 to 14 percent of yellow glaze soil, 30 to 20 percent of Badu glaze clay, 5 to 8 percent of talcum powder, 15 to 20 percent of limestone, and 10 to 20 percent of ferric oxide; and the black glaze gold drop glaze material takes black as a substrate and gold yellow as decoration, and has wide adaptability and good thermal stability. The invention also provides a method for preparing a black glaze gold drop product through the black glaze gold drop glaze material. The method is characterized by the control on the glaze material preparation, the ceramic cog bisquefiring, the glaze burning time and temperature, and the glazing process and thickness. The method is scientific and reasonable and is easy to be implemented. The black glaze gold drop product made through the method has high yield, and good ceramic quality. Therefore, the glaze layer is turned into priming glaze and overglaze; and the priming glaze is black and bright and the overglaze has gold yellow drops, thereby bringing about three-dimensional effect.
Description
Technical field
The present invention relates to a kind of ceramic industrial art field, especially relate to the making method of a kind of black glaze gold drip glaze and products thereof.
Background technology
The black glaze product of high temperature is added mysterious black since ancient times because of its glaze colours uniqueness, gloss, soft, fine and smooth, gives unlimited reverie, therefore for common people treasure, and the golden mysterious effect that will deceive glaze especially of black glaze pushed to ultimate attainment.It is to utilize black glaze product in sintering process that the black glaze gold drips production of products technology, and the iron in the glaze becomes degree of saturation and the control of burning till heating curve, causes that transmutation has formed irregular decorative pattern; It is a ground-coat enamel with the black glaze, intersperses to form flavous dribs and drabs naturally, has abysmal mystique; Give the harmonious aesthetic feeling of magnificent noble quality and two color dot faces again, and every product all has the artistic effect of its unique uniqueness, still; Adopt traditional method to fire " the black glaze gold drips ", its glaze is selected difficult, and firing temperature is wayward; So yield rate is low, the technology difficulty of therefore firing " the black glaze gold drips " is big.
Summary of the invention
In order to solve the technical problem of above-mentioned existence, the object of the present invention is to provide a kind of black glaze gold drip glaze prescription, this glaze is done the end with black, decorates wide adaptability, Heat stability is good with golden yellow; The present invention also provides the method for making a black glaze gold product with this black glaze gold drip glaze, and this methodological science is reasonable, and is easy to implement, makes the black glaze gold with this method and drips finished product rate height, and the product porcelain is good.
Black glaze gold drip glaze of the present invention; Its ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil (place of production is wood Dai Kou village, Yang town on Zhejiang Province's Longquan City) 12～18%; Yellow
glaze soil (place of production is yellow
mountain, Yang town on Zhejiang Province's Longquan City) 28～14%; Eight glaze soil (place of production be under the high hill, Longquan City Ba Dou town, Zhejiang Province afterwards mountain) 30～20% all; Talcum powder 5～8%; Wingdale 15～20%, red oxide of iron 10～20%.
The glaze chemical constitution % of content unit
| Title | SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | TiO 2 | Burn and lose |
| Wood Mount Tai mouth Zijin soil | 65.5 | 17.44 | 5.79 | 0.18 | 0.86 | 4.01 | 1.51 | ＜0.01 | 5.08 |
Yellow
 |
71.73 | 16.57 | 0.55 | 0.2 | 0.3 | 5.13 | 0.98 | ＜0.01 | 4.55 |
| Eight glaze soil all | 71 | 21.3 | 1.05 | 0.38 | 0.21 | 2.30 | 1.28 | 0.01 | 3.41 |
(Data Source: ceramic mass supervision and inspection station, Jiangxi Province survey report, 1. wooden Mount Tai mouth Zijin soil survey report page 1; 2. yellow
glaze soil survey report page 2; 3. eight glaze soil survey report page 3 all.)
Black glaze gold of the present invention drips the production of products method, mainly is technical process such as the preparation of base glaze, moulding, refine, drying, biscuiting, glazing, loading of kiln, glaze firing.
The objective of the invention is to realize: the preparation black glaze gold drip glaze through following technical scheme; Its ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil 12～18%; Yellow
glaze soil 28～14%; Eight glaze soil 30～20% all; Talcum powder 5～8%, Wingdale 15～20%, red oxide of iron 10～20%.To various glaze by the meticulous selection of prescription requirement back uniform mixing, with ballstone: glaze: the water ratio is: 1.5: 1: 0.8, the grinding plant of packing into ground to form glaze slip and gets final product.
After the black tire porcelain base drying with moulding, go into kiln through the biscuiting of 8～10 hour time, stop after burning 830～860 ℃ of temperature slowly with warm fire, naturally cooling is the biscuit kiln discharge after 15～20 hours.After this biscuit was removed dust, the biscuit glazing divided inside and outside glaze two processes, dripped glaze slip furnishing water content to the black glaze gold 38～45% earlier, and with swinging the interior glaze of secondary biscuit on the glaze method, the gauge control of glaze layer is at 1.8～2.1 millimeters; Will drain the moisture content of biscuit after the interior glaze of biscuit is first-class, with dipping in the outer glaze of secondary biscuit on the glaze method, the gauge control of glaze layer is at 1.8～2.1 millimeters again.The biscuit that inside and outside glaze is all first-class, the plane pin can be gone into kiln and carried out glaze firing.Glaze firing will be through evaporation, reduction, become porcelain, insulation four-stage, and at evaporation stage: first hour is from the igniting beginning, is warming up to 450～500 ℃ and ends; Biscuit water evaporates in the kiln is done; Second hour be that the kiln temperature is warming up to 800～850 ℃ from 450～500 ℃ and ends, be incubated 15～25 minutes, use 60～80 minutes again; The kiln temperature is warming up to 960～to 960～1000 ℃, is incubated 1.5～2 hours from 800～850 ℃.At reduction phase: the kiln temperature is warming up to 1120～1150 ℃ from 960～1000 ℃ in first hour, and kiln temperature rise temperature slowed down a little in second hour, rose to 1210～1250 ℃ from 1120～1150 ℃.Becoming the porcelain stage: in this stage kiln temperature rise temperature, PM will be controlled 1～1.6 ℃ of intensification degree, and the time was controlled in 50～60 minutes, and the kiln temperature is risen to till 1290～1310 ℃ from 1210～1250 ℃.At holding stage: when the kiln temperature reaches 1290～1310 ℃, stop to heat up, from then on begin to be incubated 15～20 minutes, stop burning things which may cause a fire disaster then, let kiln temperature naturally cooling 15～20 hours, the finished product kiln discharge.
A black glaze gold product of the present invention burns till and adopts shuttle kiln to burn till, and burns till fuel heavy oil, LPG liquefied petroleum gas, water-gas.
Situation about not introducing in detail among the present invention is identical with conventional celadon production method, does not state tired.
The invention has the beneficial effects as follows: the biscuit through first-class glaze is in the high-temperature melting process; Make the air in the glaze can not the emersion glaze, and in glaze, form many small bubbles, when firing temperature is controlled at 1290～1310 ℃; Make the not molten ferric oxide particles of remaining some amount in the glaze; Form the red stone crystallization of some amount, these small bubbles, ferric oxide particles and quicklime crystallization get into the glaze layer saturated degree take place, thereby make the glaze layer become ground-coat enamel and cover-coat enamel; Thereby form the flavous cover-coat enamel of as black as jet ground-coat enamel and dribs and drabs, have the spatial visual effect.
Embodiment
Below in conjunction with embodiment the present invention is described further implementation result.
Embodiment 1
Embodiment glaze ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil 12%; Yellow
glaze soil 28%; Eight glaze soil 30% all; Talcum powder 5%, Wingdale 15%, red oxide of iron 10%.Various glaze are mixed after by the meticulous selection of prescription requirement, and again with ballstone: glaze: the water ratio is: 1.5: 1: 0.8, the grinding plant of packing into ground to form glaze slip.
With black tire heart bowl of mud dry forming, go into kiln after the drying, through time biscuiting in 8 hour, burn temperature slowly with warm fire and stop for 830 ℃, naturally cooling is kiln discharge after 15 hours.After this biscuit was removed dust, glazing divided inside and outside glaze two processes, and elder generation 38%, goes up glaze in this biscuit of secondary to glaze slip furnishing water content earlier with swinging the glaze method, and the gauge control of glaze layer is at 1.8 millimeters; Will drain the moisture content in the biscuit after the interior glaze of this biscuit is first-class, with dipping in the outer glaze of this biscuit of secondary on the glaze method, the gauge control of glaze layer is at 1.8 millimeters again.The biscuit of first-class inside and outside glaze, the plane pin can be gone into kiln and carried out glaze firing, and glaze firing will be through pervaporation, reduction, one-tenth porcelain, insulation four-stage; At evaporation stage: first hour is to begin to be warming up to 450 ℃ from igniting, and the biscuit water evaporates in the kiln is done, and second hour is that the kiln temperature is warming up to 820 ℃ from 450 ℃ and ends; Be incubated 15 minutes; Use 60 minutes again, the kiln temperature rises to 960 ℃ from 800 ℃, is incubated 1.5 hours.At reduction phase: the kiln temperature is warming up to 1120 ℃ from 960 ℃ in first hour, and kiln temperature rise temperature slowed down a little in second hour, was warming up to 1210 ℃ from 1120 ℃.Becoming the porcelain stage: in this stage kiln temperature rise temperature, PM will be controlled 1.6 ℃, and the time was controlled in 50 minutes, make the kiln temperature when 1210 ℃ are warming up to 1290 ℃ till.At holding stage: when the kiln temperature reaches 1290 ℃, stop to heat up, from then on begin to be incubated 15 minutes, stop burning things which may cause a fire disaster then, let kiln temperature naturally cooling 15 hours, the finished product kiln discharge.
Originally burn till in shuttle kiln and carry out, burning till fuel is oil liquefied gas.
Embodiment 2
Embodiment glaze ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil 18%; Yellow
glaze soil 14%; Eight glaze soil 20% all; Talcum powder 8%, Wingdale 20%, red oxide of iron 20%.Various glaze are mixed after by the meticulous selection of prescription requirement, and again with ballstone: glaze: the water ratio is: 1.5: 1: 0.8, the grinding plant of packing into ground to form glaze slip.
With black tire ears jar of mud dry forming, go into kiln after the drying, the biscuiting through 10 hour time burns temperature slowly with warm fire and stops for 860 ℃, and naturally cooling is kiln discharge after 20 hours.After this biscuit was removed dust, the biscuit glazing divided inside and outside glaze two processes, and elder generation 45%, adopts glaze slip furnishing moisture content then and swings the upward interior glaze of secondary biscuit of glaze method elder generation, and the thickness of glaze layer is 2.1 millimeters; Will drain the moisture content of biscuit after the interior glaze of biscuit is first-class, employing is dipped in the glaze method and is gone up the outer glaze of secondary biscuit again, and the gauge control of glaze layer is at 2.1 millimeters.First-class inside and outside glaze biscuit, the plane pin can be gone into kiln and carried out glaze firing, and glaze firing will be through pervaporation, reduction, one-tenth porcelain, insulation four-stage.At evaporation stage: first hour is to be warming up to 500 ℃ from igniting, and the biscuit water evaporates in the kiln is done, and second hour is only to be raised to 850 ℃ of kiln temperature from 500 ℃, is incubated 25 minutes, uses 80 minutes again, and the kiln temperature rises to 1000 ℃ from 850 ℃, is incubated 2 hours.At reduction phase: the kiln temperature rises to 1150 ℃ from 1000 ℃ in first hour, and kiln temperature rise in second hour slows down a little, rises to 1250 ℃ from 1150 ℃.Becoming the porcelain stage: in this stage kiln temperature rise temperature, PM will be controlled 1 ℃, and the time was controlled in 60 minutes, and the kiln temperature is risen to till 1310 ℃ from 1250 ℃.At holding stage: when the kiln temperature reaches 1310 ℃, stop to heat up, from then on begin to be incubated 20 minutes, stop burning things which may cause a fire disaster then, let kiln temperature naturally cooling 20 hours, the finished product kiln discharge.
Originally burn till in shuttle kiln and carry out, burning till fuel is oil liquefied gas.
Claims (2)
1. black glaze gold drip glaze; It is characterized in that this glaze ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil 12～18%; Yellow
glaze soil 28～14%; Eight glaze soil 30～20% all; Talcum powder 5～8%, Wingdale 15～20%, red oxide of iron 10～20%.
2. the black glaze gold production method of dripping; Form by the preparation of base glaze, moulding, refine, drying, biscuiting, glazing, loading of kiln, glaze firing operation, it is characterized in that glaze preparation and the biscuiting of porcelain base, time, temperature and the glazing process of glaze firing, the control of thickness; The preparation black glaze gold drip glaze; Its ingredients by weight percentage composition: wooden Mount Tai mouth Zijin soil 12～18%; Yellow
glaze soil 28～14%, eight is glaze soil 30～20% all, talcum powder 5～8%; Wingdale 15～20%, red oxide of iron 10～20%; To various glaze by the meticulous selection of prescription requirement back uniform mixing, with ballstone: glaze: the water ratio is: 1.5: 1: 0.8, the grinding plant of packing into ground to form glaze slip and gets final product; After the black tire porcelain base drying with moulding, go into kiln through the biscuiting of 8～10 hour time, stop after burning 830～860 ℃ of temperature slowly with warm fire, naturally cooling is the biscuit kiln discharge after 15～20 hours; After this biscuit is removed dust; The biscuit glazing divides inside and outside glaze two processes, drips glaze slip furnishing water content to the black glaze gold 38～45% earlier, with swinging the interior glaze of secondary biscuit on the glaze method; The gauge control of glaze layer is at 1.8～2.1 millimeters; Will drain the moisture content of biscuit after the interior glaze of biscuit is first-class, with dipping in the outer glaze of secondary biscuit on the glaze method, the gauge control of glaze layer is at 1.8～2.1 millimeters again; The biscuit that inside and outside glaze is all first-class, the plane pin can be gone into kiln and carried out glaze firing, and glaze firing will be through evaporation, reduction, one-tenth porcelain, insulation four-stage; At evaporation stage: first hour is from the igniting beginning, is warming up to 450～500 ℃ and ends, and the biscuit water evaporates in the kiln is done; Second hour be that the kiln temperature is warming up to 800～850 ℃ from 450～500 ℃ and ends, be incubated 15～25 minutes, use 60～80 minutes again; The kiln temperature is warming up to 960～1000 ℃ from 800～850 ℃, is incubated 1.5～2 hours; At reduction phase: the kiln temperature is warming up to 1120～1150 ℃ from 960～1000 ℃ in first hour, and kiln temperature rise temperature slowed down a little in second hour, rose to 1210～1250 ℃ from 1120～1150 ℃; Becoming the porcelain stage: in this stage kiln temperature rise temperature, PM will be controlled 1.6～1 ℃ of intensification degree, and the time was controlled in 50～60 minutes, and the kiln temperature is risen to till 1290～1310 ℃ from 1210～1250 ℃; At holding stage: when the kiln temperature reaches 1290～1310 ℃, stop to heat up, from then on begin to be incubated 15～20 minutes, stop burning things which may cause a fire disaster then, let kiln temperature naturally cooling 15～20 hours, the finished product kiln discharge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101938743A CN101450873B (en) | 2007-11-30 | 2007-11-30 | Method for producing black glaze gold drip glaze and product thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101938743A CN101450873B (en) | 2007-11-30 | 2007-11-30 | Method for producing black glaze gold drip glaze and product thereof |
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| CN101450873A CN101450873A (en) | 2009-06-10 |
| CN101450873B true CN101450873B (en) | 2012-01-18 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101973787B (en) * | 2010-10-26 | 2014-07-02 | 陕西科技大学 | Method for preparing split-phase coloring iron black glaze |
| CN105439641B (en) * | 2016-01-11 | 2018-06-22 | 福建省德化友盛陶瓷有限公司 | Golden yellow crow drop reduction furnace transmutation glaze and the golden yellow crow drop reduction transmutation glazed pottery ceramic products and preparation method with its preparation |
| CN112374909A (en) * | 2020-11-23 | 2021-02-19 | 王建勋 | Firing process of black gold bowl |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1459436A (en) * | 2002-05-23 | 2003-12-03 | 叶小春 | Celadon ice crack enamel and its product |
| CN1715229A (en) * | 2004-07-03 | 2006-01-04 | 陈根 | Longquan celadon frostwork glaze and its producing method for product |
| CN1765817A (en) * | 2004-10-31 | 2006-05-03 | 王晓朝 | Green glaze ink color ceramics production method |
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2007
- 2007-11-30 CN CN2007101938743A patent/CN101450873B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1459436A (en) * | 2002-05-23 | 2003-12-03 | 叶小春 | Celadon ice crack enamel and its product |
| CN1715229A (en) * | 2004-07-03 | 2006-01-04 | 陈根 | Longquan celadon frostwork glaze and its producing method for product |
| CN1765817A (en) * | 2004-10-31 | 2006-05-03 | 王晓朝 | Green glaze ink color ceramics production method |
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Granted publication date: 20120118 Termination date: 20131130 |