CN101450845A - High negative ion tourmaline powder and preparation method thereof - Google Patents
High negative ion tourmaline powder and preparation method thereof Download PDFInfo
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- CN101450845A CN101450845A CNA2007101712925A CN200710171292A CN101450845A CN 101450845 A CN101450845 A CN 101450845A CN A2007101712925 A CNA2007101712925 A CN A2007101712925A CN 200710171292 A CN200710171292 A CN 200710171292A CN 101450845 A CN101450845 A CN 101450845A
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- tourmaline powder
- negative ion
- high negative
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- tourmalinite
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Abstract
The invention relates to high anion tourmaline powder and a preparation method thereof. The high anion tourmaline powder is prepared from the following compositions by weight percentage: 60 to 80 percent of tourmaline, 5 to 10 percent of cerium oxide, 2 to 5 percent of yttrium oxide, 5 to 10 percent of neodymium oxide and 5 to 15 percent of titania, wherein the D50 of the high anion tourmaline powder is less than or equal to 2 micrometers. Compared with the prior art, the high anion tourmaline powder can obviously improve the anion-generating capacity, is safe and reliable, contributes to adjust the physiological function of human body, eliminate fatigue and improve cardiovascular and cerebrovascular disease symptoms and the immunity of the human body, has obvious health-care effect, can be widely used in building materials such as a coating, an emulsion paint, lacquer putty, ceiling and a furniture coating, and can also be used in the fields of plastic, fiber and so on. Simultaneously, the method for preparing the high anion tourmaline powder has simple technique and low cost, and prepared products have stable performance.
Description
Technical field
The present invention relates to functional materials, especially relate to a kind of high negative ion tourmaline powder and preparation method thereof.
Background technology
Along with the raising of people's living standard, also more and more higher to the requirement of the level of comfort of health and living environment, and also also more and more stronger to the understanding of environment.Scientific research shows that negative ion keeps energetic and improve the human residential environment being very helpful to human body.
At present various anion generators are being studied, developed to the application of negative ion generally, also obtained good effect, but its shortcoming is: because of human and material resources, the financial resources of the cost of its institute higher, the cost height certainly will cause valuable product, therefore limited its range of application, and formed obstacle for the understanding of popularizing negative ion and application.
The CN1413921 patent documentation discloses a kind of anion ceramic material for water purifying, this material is made up of kaolin, tourmalinite, medical stone, bamboo charcoal powder etc., form stupalith through high-temperature roasting then, when itself and the pH value of adjusting water after water contacts, only be to increase important mineral substance in the water, do not increase the generating capacity of negative ion.
The CN198647 patent documentation discloses a kind of method of tourmaline powder modifying, comprises the steps: 1) grind: tourmaline powder is ground to D
90≤ 5 μ m; 2) slurrying: the powder after will grinding with deionized water is modulated into slurry, and powder and slurry weight are than being 10%-50%; 3) modification: slurry is put into the ultrasonic machining groove, and concussion is 1-12 hour under the 40-200kHz ultrasonic wave; 4) drying: the powder slip 100-200 ℃ of oven dry down, is sloughed the moisture in the slip; 5) grind again: be ground to D again
90≤ 5 μ m, can obtain the tourmaline powder of modification, the tourmalinite method of modifying energy consumption of this invention is low, working method is simple, modified effect is obvious, and can not introduce harmful heavy metal ion, radioactive substance is made property-modifying additive, but this method has only solved the processing problems of tourmalinite.
The CN1844289 patent documentation discloses a kind of nano functional anion materials and application thereof, form by inorganic materials such as shell, tourmalinite, medical stone, zeolite, polyamine salts, nano-scale particle size accounts for powder or slurry or the liquid of 10%-90%, this method has only solved the particulate fineness, does not increase the generating capacity of negative ion.
The CN1765802 patent documentation discloses a kind of ultra-fine efficient anion powder material and preparation method thereof, this powder body material comprises natural negative ion releasable material, excitation material and transmission ofenergy material, to have added radioelement be excitation material to reality in this patent, has the radiological safety problem.
The CN1699453 patent documentation discloses the application of a kind of high-negative ion powder, tourmaline powder, refers in particular to high-negative ion powder, the application of tourmaline powder in hair decorations is made, and the high-negative ion powder contains radioelement equally, has the radiological safety problem.
Summary of the invention
Purpose of the present invention is exactly that a kind of anion-generating capacity height, safe and reliable high negative ion tourmaline powder and preparation method thereof are provided in order to overcome the defective that above-mentioned prior art exists.
Purpose of the present invention can be achieved through the following technical solutions: a kind of high negative ion tourmaline powder, it is characterized in that, this high negative ion tourmaline powder is according to following weight percent compatibility: tourmalinite 60%-80%, cerium oxide 5%-10%, yttrium oxide 2%-5%, Neodymium trioxide 5%-10%, titanium dioxide 5%-15%, the D of described tourmalinite
50≤ 1 micron.
The mean particle size of this high negative ion tourmaline powder≤2 micron.
A kind of preparation method of high negative ion tourmaline powder is characterized in that, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D with alligator
50≤ 1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains D
50The tourmalinite ultra-fine micropowder of≤1 micron depolymerization;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 60%-80% that step (1) obtains, cerium oxide 5%-10%, yttrium oxide 2%-5%, Neodymium trioxide 5%-10%, titanium dioxide 5%-15%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 2-4 hour at 600-800 ℃, obtained work in-process;
(5) work in-process are crushed to D with micronizer mill
50≤ 2 microns, promptly obtain high negative ion tourmaline powder.
Compared with prior art, high negative ion tourmaline powder of the present invention can significantly improve anion-generating capacity, negative aeroion can play and promote smog, formaldehyde to decompose, the effect that purifies air is regulated human physiological functions, Ginseng Extract, improve the cardiovascular and cerebrovascular diseases symptom, improve body immunity etc., have remarkable health care, safe and reliable.The present invention can be widely used in the material of construction such as coating, emulsion paint, putty, top ceiling, furniture coating, also can be used for fields such as plastics, fiber, simultaneously, high negative ion tourmaline powder making method technology of the present invention is simple, cost is low, and the product performance that make are stable.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
A kind of preparation method of high negative ion tourmaline powder, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm with alligator, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D50≤1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains the tourmalinite ultra-fine micropowder of the depolymerization of D50≤1 micron;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 70% that step (1) obtains, cerium oxide 5%, yttrium oxide 2%, Neodymium trioxide 10%, titanium dioxide 13%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 4 hours at 600 ℃, obtained work in-process;
(5) work in-process are crushed to D50≤2 micron with micronizer mill, promptly obtain high negative ion tourmaline powder.
Embodiment 2
A kind of preparation method of high negative ion tourmaline powder, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm with alligator, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D50≤1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains the tourmalinite ultra-fine micropowder of the depolymerization of D50≤1 micron;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 75% that step (1) obtains, cerium oxide 5%, yttrium oxide 5%, Neodymium trioxide 5%, titanium dioxide 10%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 3 hours at 700 ℃, obtained work in-process;
(5) work in-process are crushed to D50≤2 micron with micronizer mill, promptly obtain high negative ion tourmaline powder.
Embodiment 3
A kind of preparation method of high negative ion tourmaline powder, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm with alligator, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D50≤1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains the tourmalinite ultra-fine micropowder of the depolymerization of D50≤1 micron;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 60% that step (1) obtains, cerium oxide 10%, yttrium oxide 5%, Neodymium trioxide 10%, titanium dioxide 15%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 2 hours at 800 ℃, obtained work in-process;
(5) work in-process are crushed to D50≤2 micron with micronizer mill, promptly obtain high negative ion tourmaline powder.
Embodiment 4
A kind of preparation method of high negative ion tourmaline powder, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm with alligator, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D50≤1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains the tourmalinite ultra-fine micropowder of the depolymerization of D50≤1 micron;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 80% that step (1) obtains, cerium oxide 6%, yttrium oxide 3%, Neodymium trioxide 6%, titanium dioxide 5%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 4 hours at 680 ℃, obtained work in-process;
(5) work in-process are crushed to D50≤2 micron with micronizer mill, promptly obtain high negative ion tourmaline powder.
Claims (3)
1. a high negative ion tourmaline powder is characterized in that, this high negative ion tourmaline powder is according to following weight percent compatibility: tourmalinite 60%-80%, cerium oxide 5%-10%, yttrium oxide 2%-5%, Neodymium trioxide 5%-10%, titanium dioxide 5%-15%, the D of described tourmalinite
50≤ 1 micron.
2. a kind of high negative ion tourmaline powder according to claim 1 is characterized in that, the mean particle size of this high negative ion tourmaline powder≤2 micron.
3. the preparation method of a high negative ion tourmaline powder is characterized in that, this method may further comprise the steps:
(1) selects the electric stone ore of crystal attitude, remove impurity, reach more than 95% to purity, be crushed to 1-10cm, enter the roller milling machine and be crushed to more than 300 orders, adopt the stirring ball mill superfine grinding again, to D with alligator
50≤ 1 micron, dry, beater grinder is pulverized, micronizer mill is pulverized, and obtains D
50The tourmalinite ultra-fine micropowder of≤1 micron depolymerization;
(2) press column weight amount per-cent compatibility: the tourmalinite ultra-fine micropowder 60%-80% that step (1) obtains, cerium oxide 5%-10%, yttrium oxide 2%-5%, Neodymium trioxide 5%-10%, titanium dioxide 5%-15%;
(3) compatibility is good raw material disperses with micronizer mill;
(4) abundant dispersive mixture was calcined 2-4 hour at 600-800 ℃, obtained work in-process;
(5) work in-process are crushed to D with micronizer mill
50≤ 2 microns, promptly obtain high negative ion tourmaline powder.
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| CN102702826A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Antibacterial negative ion putty powder |
| CN102702827A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Multifunctional putty for building |
| CN104594048A (en) * | 2014-09-17 | 2015-05-06 | 李忠 | Yarn comprising negative ion particles for producing microcurrent |
| CN104610835A (en) * | 2015-02-10 | 2015-05-13 | 宁波高新区巴艺新材料科技有限公司 | Weather-resistant powder paint |
| CN104695672A (en) * | 2015-02-10 | 2015-06-10 | 宁波高新区巴艺新材料科技有限公司 | Environmental protection construction method for toilet ground |
| CN104689707A (en) * | 2015-02-10 | 2015-06-10 | 宁波高新区巴艺新材料科技有限公司 | Negative ion powder for building |
| CN104712123A (en) * | 2015-02-10 | 2015-06-17 | 宁波高新区巴艺新材料科技有限公司 | Environmental protection construction method of wall surface tiling |
| CN104712113A (en) * | 2015-02-10 | 2015-06-17 | 宁波高新区巴艺新材料科技有限公司 | Anion painting method of wall surface |
| CN105944742A (en) * | 2016-05-11 | 2016-09-21 | 沈平 | Nano anion functional material for photocatalyst and preparation method of nano anion functional material |
| CN107811758A (en) * | 2017-11-30 | 2018-03-20 | 潘柏霖 | A kind of AGMA with antibacterial mite-removing effect |
| CN108975806A (en) * | 2018-07-13 | 2018-12-11 | 安徽钰锦生态木材料有限公司 | A kind of construction material purifying air |
| CN109265006A (en) * | 2018-10-26 | 2019-01-25 | 广东能强陶瓷有限公司 | A kind of Ceramic Tiles and preparation process capable of releasing negative ion |
| CN109796933A (en) * | 2019-03-14 | 2019-05-24 | 武汉长江日报创印科技有限公司 | It is a kind of efficiently to discharge tourmaline modified powder of anion and preparation method thereof |
| CN109898340A (en) * | 2019-01-04 | 2019-06-18 | 世联汽车内饰（苏州）有限公司 | A kind of synthetic leather and preparation method thereof of permanent efficiently release anion |
| CN111777827A (en) * | 2020-06-16 | 2020-10-16 | 佛山市顺德区怡德塑料制品有限公司 | Modified PVC material and preparation method thereof |
| CN112159102A (en) * | 2020-10-16 | 2021-01-01 | 内蒙古科技大学 | High-release-amount negative ion glass air purification material |
| CN115650764A (en) * | 2022-11-16 | 2023-01-31 | 福建师范大学泉港石化研究院 | Low-temperature sintered negative ion porous ceramic and preparation method thereof |
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| CN1253246C (en) * | 2002-12-26 | 2006-04-26 | 华东理工大学 | Process for processing nano grade super fine tourmaline micro crystal with negative ion generating function |
| CN1994960A (en) * | 2005-12-31 | 2007-07-11 | 西南科技大学 | Energy-containing particle excitated type highly efficient air negative ion material and its preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702826A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Antibacterial negative ion putty powder |
| CN102702827A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Multifunctional putty for building |
| CN104594048A (en) * | 2014-09-17 | 2015-05-06 | 李忠 | Yarn comprising negative ion particles for producing microcurrent |
| CN104610835B (en) * | 2015-02-10 | 2017-02-22 | 金华联创塑粉科技有限公司 | Weather-resistant powder paint |
| CN104610835A (en) * | 2015-02-10 | 2015-05-13 | 宁波高新区巴艺新材料科技有限公司 | Weather-resistant powder paint |
| CN104695672A (en) * | 2015-02-10 | 2015-06-10 | 宁波高新区巴艺新材料科技有限公司 | Environmental protection construction method for toilet ground |
| CN104689707A (en) * | 2015-02-10 | 2015-06-10 | 宁波高新区巴艺新材料科技有限公司 | Negative ion powder for building |
| CN104712123A (en) * | 2015-02-10 | 2015-06-17 | 宁波高新区巴艺新材料科技有限公司 | Environmental protection construction method of wall surface tiling |
| CN104712113A (en) * | 2015-02-10 | 2015-06-17 | 宁波高新区巴艺新材料科技有限公司 | Anion painting method of wall surface |
| CN105944742A (en) * | 2016-05-11 | 2016-09-21 | 沈平 | Nano anion functional material for photocatalyst and preparation method of nano anion functional material |
| CN107811758A (en) * | 2017-11-30 | 2018-03-20 | 潘柏霖 | A kind of AGMA with antibacterial mite-removing effect |
| CN108975806A (en) * | 2018-07-13 | 2018-12-11 | 安徽钰锦生态木材料有限公司 | A kind of construction material purifying air |
| CN109265006A (en) * | 2018-10-26 | 2019-01-25 | 广东能强陶瓷有限公司 | A kind of Ceramic Tiles and preparation process capable of releasing negative ion |
| CN109898340A (en) * | 2019-01-04 | 2019-06-18 | 世联汽车内饰（苏州）有限公司 | A kind of synthetic leather and preparation method thereof of permanent efficiently release anion |
| CN109796933A (en) * | 2019-03-14 | 2019-05-24 | 武汉长江日报创印科技有限公司 | It is a kind of efficiently to discharge tourmaline modified powder of anion and preparation method thereof |
| CN111777827A (en) * | 2020-06-16 | 2020-10-16 | 佛山市顺德区怡德塑料制品有限公司 | Modified PVC material and preparation method thereof |
| CN112159102A (en) * | 2020-10-16 | 2021-01-01 | 内蒙古科技大学 | High-release-amount negative ion glass air purification material |
| CN115650764A (en) * | 2022-11-16 | 2023-01-31 | 福建师范大学泉港石化研究院 | Low-temperature sintered negative ion porous ceramic and preparation method thereof |
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| CN101450845B (en) | 2011-09-14 |
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