CN106082974A - A kind of ceramic ware for daily use easy to clean - Google Patents
A kind of ceramic ware for daily use easy to clean Download PDFInfo
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- CN106082974A CN106082974A CN201610460746.XA CN201610460746A CN106082974A CN 106082974 A CN106082974 A CN 106082974A CN 201610460746 A CN201610460746 A CN 201610460746A CN 106082974 A CN106082974 A CN 106082974A
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- deionized water
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- 239000000919 ceramic Substances 0.000 title claims abstract description 28
- 230000003670 easy-to-clean Effects 0.000 title claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000010881 fly ash Substances 0.000 claims abstract description 16
- 235000012054 meals Nutrition 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000006063 cullet Substances 0.000 claims abstract description 9
- 244000269722 Thea sinensis Species 0.000 claims abstract description 8
- 235000009569 green tea Nutrition 0.000 claims abstract description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 7
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N Boron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 241000238557 Decapoda Species 0.000 claims abstract description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- SXQXMCWCWVCFPC-UHFFFAOYSA-N aluminum;potassium;dioxido(oxo)silane Chemical compound [Al+3].[K+].[O-][Si]([O-])=O.[O-][Si]([O-])=O SXQXMCWCWVCFPC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011425 bamboo Substances 0.000 claims abstract description 7
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 7
- 229910052878 cordierite Inorganic materials 0.000 claims abstract description 7
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 7
- 229910052907 leucite Inorganic materials 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 229960002152 Chlorhexidine Acetate Drugs 0.000 claims abstract description 6
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Exidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N Tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 239000004575 stone Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 230000000844 anti-bacterial Effects 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000004005 microsphere Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 241001330002 Bambuseae Species 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 235000015895 biscuits Nutrition 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000001476 alcoholic Effects 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 230000000845 anti-microbial Effects 0.000 claims description 3
- 239000004599 antimicrobial Substances 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000007885 magnetic separation Methods 0.000 claims description 3
- 239000006148 magnetic separator Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 2
- 230000001954 sterilising Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 240000003917 Bambusa tulda Species 0.000 abstract 1
- 238000010304 firing Methods 0.000 description 7
- 229910052573 porcelain Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 230000036740 Metabolism Effects 0.000 description 1
- 241000238040 Panulirus Species 0.000 description 1
- 241000927735 Penaeus Species 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000002070 germicidal Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000035786 metabolism Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
- 229910001929 titanium oxide Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
- C04B33/1352—Fuel ashes, e.g. fly ash
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/10—Eliminating iron or lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/425—Graphite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a kind of ceramic ware for daily use easy to clean, be made up of the raw material of following weight portion: Graphene 35, titanium dioxide 45, hargil 13 15, leucite 14 17, cordierite 10 14, hydroxyl starch 34, Radix Sophorae Flavescentis extractive liquid 46, iridium powder 12, chlorhexidine acetate 23, bamboo pulp fiber 68, boron oxide 68, flyash 40 45, white glaze ball 35 40, cullet 68, Maifanitum 10 14, green tea 21 25, Pericarpium citri sinensis 14 17, conch meal 68, shrimp shell meal 46, polyvinyl alcohol 0.2 0.3, tributyl phosphate 0.2 0.3, deionized water are appropriate；The present invention has splendid anti-very hot performance and room temperature high temperature break resistant intensity, and preparation method is simple, and energy-saving effect is notable, reduces energy consumption, and has good sterilization, bacteriostasis property, meets the outward appearance of consumer and appreciates and requiring and safety in utilization, is worthy to be popularized.
Description
Technical field
The present invention relates to domestic ceramics technical field, particularly relate to a kind of ceramic ware for daily use easy to clean.
Background technology
China's not only rich in mineral resources, is also coal production state maximum in the world and consumption of coal state, in recent years simultaneously
Coming, China's thermal power generation quickly grows, and wherein great majority are with coal as fuel, and generated energy reaches 1.3 hundred million kW h, shared by thermal power generation
Ratio has reached 79.6%, thus causes flyash discharge capacity to increase year by year.In the end of the year 2010, discharge capacity reaches nearly 300,000,000 tons, in a large number
The discharge of flyash have received to be paid close attention to the most widely.China started just to how utilizing flyash as resource from 1987
The breach of comprehensive utilization, comprehensively utilizes it, becomes a long-range policy of economy and social development.Cullet class thing
Its chemical stability of matter is extremely strong, without putrefaction, does not burns, can not degrade, and substantial amounts of cullet both took up an area, and polluted again environment, reclaimed
Being to save the energy, the optimal path of protection environment with utilizing, and have good economy, the main component of glass is dioxy
SiClx, it is possible to promote the sintering of pottery.In Production of Ceramics, firing temperature is the highest, and firing time is the longest, and energy consumption is the highest, according to
Heat Balance Calculation, firing temperature often reduces by 100 DEG C, then unit product heat consumption can reduce by more than 10%, and firing time often shortens 10%,
Then yield increases by 10%, and heat consumption reduces by 4%, so reduction firing temperature and time have significant energy-saving and emission-reduction social meaning.
Over nearly 20 years, ceramic industry enters developmental stage with rapid changepl. never-ending changes and improvements, new technique, a large amount of uses of new equipment, pottery
Porcelain yield also increases by a fairly big margin.New ceramics, as a kind of new material, solely sets one with the performance of its excellence at Material Field
Flag, is paid much attention to by people.Domestic ceramics occupies an important position at Material Field as traditional ceramics material, because it
Relating to the every aspect of people's life, the development of domestic ceramics is more wanted along with the raising of people's living standard proposes
Asking, the most antibacterial is to propose most common requirement at present.Due to the wilderness demand of porcelain, a large amount of exploitations of china clay resource are just with frightened
The speed of people reduces, and is non-renewable resources, if can not find alternate resources, it is likely that can face No Assets later
The difficult situation that can adopt.Yang Yuwei et al. is at " utilizing the industrial wastes such as flyash to prepare the research of a domestic ceramics " literary composition middle finger
Go out, utilize the flyash of power plant emission, a large amount of useless saggars of ceramic industry generation, useless porcelain powder to utilize Orthogonal Experiment and Design to join
Side, develops cleaning and produces the formula of domestic ceramics, wherein flyash, useless saggar, the content of useless porcelain powder be 10% respectively, 10%,
8%, applying this technology can be that enterprise brings considerable economic benefit, and the recycling for flyash finds an exit, although carry
High Social benefit and economic benefit, but a lot of performance is not reaching to the requirement of people, the most antibacterial, high temperature resistance, freeze proof etc.
The shortcoming that performance is the highest, service life is not grown.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of ceramic ware for daily use easy to clean.
The present invention is achieved by the following technical solutions:
A kind of ceramic ware for daily use easy to clean, is made up of the raw material of following weight portion: Graphene 3-5, titanium dioxide 4-
5, hargil 13-15, leucite 14-17, cordierite 10-14, hydroxyl starch 3-4, Radix Sophorae Flavescentis extractive liquid 4-6, iridium powder 1-2, acetic acid are washed
Must safe 2-3, bamboo pulp fiber 6-8, boron oxide 6-8, flyash 40-45, white glaze ball 35-40, cullet 6-8, Maifanitum 10-14,
Green tea 21-25, Pericarpium citri sinensis 14-17, conch meal 6-8, shrimp shell meal 4-6, polyvinyl alcohol 0.2-0.3, tributyl phosphate 0.2-0.3,
Deionized water is appropriate.
Described a kind of ceramic ware for daily use easy to clean, is made up of following concrete steps:
(1) being mixed by the deionized water of hydroxyl starch, Radix Sophorae Flavescentis extractive liquid and 40-50 times amount, heated and stirred forms pastel, then adds
Enter chlorhexidine acetate, bamboo pulp fiber, boron oxide continuation stirring, grind the even complex antimicrobials that obtains, drying for standby after vacuum defoamation；
(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second
In alcoholic solution, decoct 20-30min when 50-60 DEG C, be continuously heating to when 90-100 DEG C decoct 10-20min, be cooled to room temperature
After carry out centrifugation, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30-40min, knot
While being stirred continuously slurry with direct current drive blender after bundle, it is standby that spray drying makes nano medical stone microsphere；
(3) cullet is cleaned up post-drying to crush, be then added to ground 100-200 mesh sieve in colloid mill, by glass
Glass powder and flyash, Graphene, titanium dioxide, hargil, leucite are mixed to get dry material, add and account for dry material gross mass 40-
The deionized water of 50%, obtained the slurry of 300-400 mesh through ball mill pulverizing；
(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry
It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100-200 DEG C, at 1210-
Carrying out at a temperature of 1260 DEG C calcining 5-7h, after being cooled to room temperature, polishing is scraped standby；
(5) antibacterial mixing white glaze ball, cordierite, iridium powder and step (1) obtained, is added in ball mill carry out wet method ball
Mill, adds the deionized water of material gross weight 45-55%, the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, goes the removal of impurity
And coarse granule, obtain thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), at 1160-1250 DEG C, sinter 4-5h；
(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2-3:1 ratio, are coated in
Ceramic surface prepared by step (5), after drying in the shade, at 120-140 DEG C, constant temperature 2h is the most available.
The invention have the advantage that the present invention utilizes waste resource flyash as Ceramic Material, reduce the dirt to environment
Dye, and wherein silicon oxide, alumina content are higher, and specific grain surface is long-pending big in loose structure, easily grinds, can reduce system
The firing temperature of product, reaches energy-conservation purpose, and discarded glass, with flyash sintering process, melts at low temperatures, is formed
Glass phase, plays the effect of bonding agent, reduces firing temperature, and it is smooth, freeze proof, easy to clean, anti-to improve ceramic surface
The performance of the aspects such as impact, by the antibacterial of synthesis and glaze mixing glazing on biscuit of ceramics surface, improves ceramic antibacterial
Performance, reduces the danger coefficient that the mankind are ill, and uses the decoction of green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal to extract trace
Element Maifanitum cladding forms nano medical stone microsphere, utilizes binding agent to be bonded in ceramic surface, solvable by being heated for a long time
Going out the multiple trace element useful to human body, the body for people provides nutrition, building body, regulates metabolism, to human body
Benefiting, the present invention has splendid anti-very hot performance and room temperature high temperature break resistant intensity, and preparation method is simple, energy-conservation effect
Fruit is notable, reduces energy consumption, and has good sterilization, bacteriostasis property, meets the outward appearance of consumer and appreciates and require and use safety
Property, it is worthy to be popularized.
Detailed description of the invention
A kind of ceramic ware for daily use easy to clean, is made up of the raw material of following weight portion (kilogram): Graphene 3, two
Titanium oxide 4, hargil 13, leucite 14, cordierite 10, hydroxyl starch 3, Radix Sophorae Flavescentis extractive liquid 4, iridium powder 1, chlorhexidine acetate 2, bamboo pulp
Fiber 6, boron oxide 6, flyash 40, white glaze ball 35, cullet 6, Maifanitum 10, green tea 21, Pericarpium citri sinensis 14, conch meal 6, Crusta Penaeus seu Panulirus
Powder 4, polyvinyl alcohol 0.2, tributyl phosphate 0.2, deionized water are appropriate.
Described a kind of ceramic ware for daily use easy to clean, is made up of following concrete steps:
(1) being mixed by the deionized water of hydroxyl starch, Radix Sophorae Flavescentis extractive liquid and 40 times amount, heated and stirred forms pastel, adds
Chlorhexidine acetate, bamboo pulp fiber, boron oxide continue stirring, grind the even complex antimicrobials that obtains, drying for standby after vacuum defoamation；
(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second
In alcoholic solution, decoct 20min when 50 DEG C, when being continuously heating to 90 DEG C, decoct 10min, be centrifuged after being cooled to room temperature point
From, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30min, after terminating, use unidirectional current
Slurry is stirred continuously by dynamic blender, and it is standby that spray drying makes nano medical stone microsphere；
(3) cullet is cleaned up post-drying to crush, be then added to ground 100 mesh sieves in colloid mill, by glass dust
It is mixed to get dry material with flyash, Graphene, titanium dioxide, hargil, leucite, adds and account for going of dry material gross mass 40%
Ionized water, obtained the slurry of 300 mesh through ball mill pulverizing；
(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry
It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100 DEG C, 1210 DEG C of temperature
Under carry out calcine 5h, after being cooled to room temperature polishing scrape standby；
(5) antibacterial mixing white glaze ball, cordierite, iridium powder and step (1) obtained, is added in ball mill carry out wet method ball
Mill, adds the deionized water of material gross weight 45%, and the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, goes the removal of impurity and thick
Granule, obtains thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), sinters 4h at 1160 DEG C；
(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2:1 ratio, are coated in step
Suddenly the ceramic surface that prepared by (5), after drying in the shade, at 120 DEG C, constant temperature 2h is the most available.
Test data:
Product appearance is regular, and glaze is smooth；Thermal shock resistance test reaches heat exchange in 20 DEG C of water of 200 DEG C of inputs and does not splits；Machine
Tool intensity >=138mp2；Glaze vickers microhardness >=5.9GPa；Sunlight germicidal efficiency >=76% of lower 1 hour；Shock resistance is strong
Degree >=1.5J/cm2.
Claims (2)
1. a ceramic ware for daily use easy to clean, it is characterised in that be made up of the raw material of following weight portion: Graphene 3-
5, titanium dioxide 4-5, hargil 13-15, leucite 14-17, cordierite 10-14, hydroxyl starch 3-4, Radix Sophorae Flavescentis extractive liquid 4-6, iridium
Powder 1-2, chlorhexidine acetate 2-3, bamboo pulp fiber 6-8, boron oxide 6-8, flyash 40-45, white glaze ball 35-40, cullet 6-8,
Maifanitum 10-14, green tea 21-25, Pericarpium citri sinensis 14-17, conch meal 6-8, shrimp shell meal 4-6, polyvinyl alcohol 0.2-0.3, tricresyl phosphate
Butyl ester 0.2-0.3, deionized water are appropriate.
A kind of ceramic ware for daily use easy to clean, it is characterised in that prepared by following concrete steps
Make:
(1) being mixed by the deionized water of hydroxyl starch, Radix Sophorae Flavescentis extractive liquid and 40-50 times amount, heated and stirred forms pastel, then adds
Enter chlorhexidine acetate, bamboo pulp fiber, boron oxide continuation stirring, grind the even complex antimicrobials that obtains, drying for standby after vacuum defoamation；
(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second
In alcoholic solution, decoct 20-30min when 50-60 DEG C, be continuously heating to when 90-100 DEG C decoct 10-20min, be cooled to room temperature
After carry out centrifugation, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30-40min, knot
While being stirred continuously slurry with direct current drive blender after bundle, it is standby that spray drying makes nano medical stone microsphere；
(3) cullet is cleaned up post-drying to crush, be then added to ground 100-200 mesh sieve in colloid mill, by glass
Glass powder and flyash, Graphene, titanium dioxide, hargil, leucite are mixed to get dry material, add and account for dry material gross mass 40-
The deionized water of 50%, obtained the slurry of 300-400 mesh through ball mill pulverizing；
(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry
It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100-200 DEG C, at 1210-
Carrying out at a temperature of 1260 DEG C calcining 5-7h, after being cooled to room temperature, polishing is scraped standby；
(5) antibacterial mixing white glaze ball, cordierite, iridium powder and step (1) obtained, is added in ball mill carry out wet method ball
Mill, adds the deionized water of material gross weight 45-55%, the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, goes the removal of impurity
And coarse granule, obtain thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), at 1160-1250 DEG C, sinter 4-5h；
(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2-3:1 ratio, are coated in
Ceramic surface prepared by step (5), after drying in the shade, at 120-140 DEG C, constant temperature 2h is the most available.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610460746.XA CN106082974A (en) | 2016-06-23 | 2016-06-23 | A kind of ceramic ware for daily use easy to clean |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610460746.XA CN106082974A (en) | 2016-06-23 | 2016-06-23 | A kind of ceramic ware for daily use easy to clean |
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| CN106082974A true CN106082974A (en) | 2016-11-09 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107365144A (en) * | 2017-07-26 | 2017-11-21 | 广东康世泰新材料科技股份有限公司 | A kind of ceramic of anti-Staphylococcus aureus and preparation method thereof |
| CN107555974A (en) * | 2017-08-18 | 2018-01-09 | 广东康世泰新材料科技股份有限公司 | It is a kind of to lift ceramic of sleep quality and preparation method thereof |
| CN108164141A (en) * | 2018-01-03 | 2018-06-15 | 广东净雨环保科技有限公司 | One type graphene enhances the preparation method of architectural pottery glaze paint |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038445A (en) * | 1988-06-11 | 1990-01-03 | 山东大学 | Dressing preparation of Chinese medical stone water container inner wall and firing process thereof |
| CN102875105A (en) * | 2012-09-04 | 2013-01-16 | 青岛保利康新材料有限公司 | Environment-friendly building material |
-
2016
- 2016-06-23 CN CN201610460746.XA patent/CN106082974A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038445A (en) * | 1988-06-11 | 1990-01-03 | 山东大学 | Dressing preparation of Chinese medical stone water container inner wall and firing process thereof |
| CN102875105A (en) * | 2012-09-04 | 2013-01-16 | 青岛保利康新材料有限公司 | Environment-friendly building material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107365144A (en) * | 2017-07-26 | 2017-11-21 | 广东康世泰新材料科技股份有限公司 | A kind of ceramic of anti-Staphylococcus aureus and preparation method thereof |
| CN107555974A (en) * | 2017-08-18 | 2018-01-09 | 广东康世泰新材料科技股份有限公司 | It is a kind of to lift ceramic of sleep quality and preparation method thereof |
| CN108164141A (en) * | 2018-01-03 | 2018-06-15 | 广东净雨环保科技有限公司 | One type graphene enhances the preparation method of architectural pottery glaze paint |
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Application publication date: 20161109 |