CN101446659B - Flat component and flat roll for ink overlay film - Google Patents

Flat component and flat roll for ink overlay film Download PDF

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Publication number
CN101446659B
CN101446659B CN2008101730650A CN200810173065A CN101446659B CN 101446659 B CN101446659 B CN 101446659B CN 2008101730650 A CN2008101730650 A CN 2008101730650A CN 200810173065 A CN200810173065 A CN 200810173065A CN 101446659 B CN101446659 B CN 101446659B
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China
Prior art keywords
printing ink
overlay film
layer
ink overlay
mentioned
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Expired - Fee Related
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CN2008101730650A
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CN101446659A (en
Inventor
越智淳
杉谷信
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Sumitomo Rubber Industries Ltd
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Sumitomo Rubber Industries Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/34Printing on other surfaces than ordinary paper on glass or ceramic surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/201Filters in the form of arrays
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133516Methods for their manufacture, e.g. printing, electro-deposition or photolithography

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Optical Filters (AREA)
  • Liquid Crystal (AREA)
  • Printing Methods (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a flat component (1) for flatting the surface of ink overlay film formed on a transparent basal plate. The flat component (1) of the invention is capable of preventing ink inverse transfer printing and preventing the transmitting light of the transparent basal plate from generating nonuniform color. Thus, the flat component (1) includes a basis material layer (2), a striping layer (4) coinciding one side surface (3) of the basis material layer (2), and an elastic layer (6) coinciding the other side surface of the basis material layer (2). The arithmetic mean roughness height (Ra) of the striping layer surface (4) is 30 to 280 nm, the limitation surface tension of the striping layer (4) is less than 30mN/m, the thickness of the elastic layer (6) is 0.1 to 5 mm, the compression elasticity of the elastic layer (6) is 0.5 to 20 MPa.

Description

Printing ink overlay film planarizing unit and printing ink overlay film planarization roller
Technical field
The present invention relates to a kind of being used for the parts of printing ink overlay film planarization and the roller that has adopted above-mentioned parts.
Background technology
The color filter of display panels can be made through following operation, for example the operation of formation printing ink overlay film and heating and cured printing ink overlay film are to form the operation of painted filtering layer on transparency carrier, and wherein the printing ink overlay film is formed with printing ink by the painted filtering layer that forms of red (R), green (G) and blue (B) three looks.
Yet by the printing ink overlay film that printing forms, middle body has the section shape that circle is heaved usually, and its surface lacks flatness.When forming painted filtering layer under the situation of the flatness that can't guarantee the printing ink overlay film, diffusion can take place in the light that then sees through painted filtering layer.And so can produce the light transmission reduction of painted filtering layer, the irregular colour of color filter and the problems such as aligned liquid crystal layer reduction that on color filter, form.
Therefore, people's printing ink overlay film of attempting using roller or sheet material to push and being printed on the transparency carrier is with the flattening surface (patent documentation 1~6) of printing ink overlay film.
Patent documentation 1: Japanese kokai publication sho 62-280804 communique
Patent documentation 2: Japanese kokai publication hei 3-156419 communique
Patent documentation 3: Japanese kokai publication hei 3-154003 communique
Patent documentation 4: Japanese kokai publication hei 2-297502 communique
Patent documentation 5: Japanese kokai publication hei 8-234013 communique
Patent documentation 6: Japanese kokai publication hei 8-75914 communique
Yet, in the invention of patent documentation 1 and patent documentation 2 records, because therefore the glass substrate of the film of use PET etc. or abrading glass etc. can be created in the such defective of reverse seal of adhering to printing ink on the planarizing unit as the planarizing unit of printing ink overlay film.
In addition, in the invention of patent documentation 3 records, though by utilizing separating film to cover printing ink overlay film integral body, and across silicon rubber with air pressurize (with reference to Fig. 1 of the document), thus printing ink overlay film surface is applied uniform pressure, yet owing to exert pressure with face, therefore be difficult to the gap that landfill produces between separating film and printing ink overlay film, thereby have the defective that can't obtain the planarization effect fully by pressurization in printing ink overlay film integral body.
In addition, in the invention of patent documentation 4~6 records, as planarizing unit, use has: with blanket cylinder (patent documentation 4); Silicon chips etc. have covered the roller with suitable hardness (patent documentation 5) on surface; Surface-coated the metallic roll (patent documentation 6) etc. of the lower non-tackiness material of the surface energy of polyflon etc.Therefore, though can suppress printing ink to the reverse of planarizing unit seal, and carry out planarization, alleviate the such technical matters of irregular colour of color filter integral body for solution, its effect is still insufficient.
In addition, in recent years, display panels is not only maximization but also to the high precision int development, therefore strong hope suppresses the irregular colour of color filter effectively.
Summary of the invention
Therefore, the objective of the invention is to: provide a kind of being used for to be formed on the planarizing unit of the flattening surface of the printing ink overlay film on the transparency carrier, a kind of reverse seal that prevents printing ink promptly is provided, and can be suppressed at seeing through of above-mentioned transparency carrier produces irregular colour in the light printing ink overlay film planarizing unit and printing ink overlay film planarization roller.
To achieve these goals, printing ink overlay film planarizing unit of the present invention, it is the surface that presses on the coloring printing ink overlay film that is formed on the transparency carrier, and make the planarizing unit that has an even surface of above-mentioned printing ink overlay film, it is characterized in that: possess: have flexible substrate layer, be laminated in the release layer of above-mentioned substrate layer one side surface and be laminated in the elastic layer on above-mentioned substrate layer opposite side surface, the arithmetic average roughness (R on the surface of a side opposite of above-mentioned release layer with above-mentioned substrate layer side a) be 30~280nm, and limitation table surface tension (γ c) be below the 30mN/m.
In addition, be preferably, the thickness of above-mentioned elastic layer is 100~5000 μ m, and elasticity of compression rate (E c) be 0.5~20MPa.
In addition, above-mentioned substrate layer, its thickness can be 50~500 μ m.And the surfaceness of substrate layer is preferably, with arithmetic average roughness (R a) count 20~500nm.
According to this printing ink overlay film planarizing unit, can suppress because of above-mentioned release layer be formed on substrate on the printing ink overlay film the reverse seal that contacts the printing ink that is caused and follow therewith the defective that the printing ink overlay film is produced.And, even if adhered to foreign matter with the elastic layer side surface of planarizing unit or between supporting printing ink overlay film is with the means of pushing of the roller of planarizing unit etc. and the elastic layer side surface of printing ink overlay film with planarizing unit, sneaked under the situation of foreign matter at the printing ink overlay film, because above-mentioned elastic layer is cushion, therefore can prevent with above-mentioned foreign matter as concavo-convex and transfer printing on the printing ink overlay film.
In addition, recognizing for example irregular colour in the color filter of display panels, is owing to the small thickness difference that is formed on the printing ink overlay film on the transparency carrier causes.Particularly, recognize under the situation in the zone to a certain degree that is conceived to transparency carrier that because the inclination of the thickness of the inclination of the printing ink overlay film thickness in this zone and the printing ink overlay film in other zone produces difference, so irregular colour is further remarkable.Therefore, only that the thickness of each printing ink overlay film is even, or make thickness equalization at the printing ink overlay film of color filter integral body, the effect of then eliminating irregular colour is insufficient.On the other hand, with planarizing unit, utilize to possess the parts that arithmetic average roughness is set in the release layer of specialized range and carried out after the planarization, then can form same extremely small concavo-convex on the surface of printing ink overlay film as above-mentioned printing ink overlay film.In addition, even if thus for example between the inclination of the inclination of the printing ink overlay film thickness in certain zone of color filter and the printing ink overlay film thickness in other zone, the difference that irregular colour takes place in generation, because by formed trickle concavo-convex on the planarization printing ink overlay film with suitably scattering of light, therefore can make the border between above-mentioned each zone not remarkable, thereby can suppress the generation of irregular colour.
Therefore, according to printing ink overlay film planarizing unit of the present invention, can suppress the reverse seal of printing ink, and then suppress the concavo-convex transfer printing that causes by foreign matter, and will be formed on the printing ink overlay film planarization on the transparency carrier, produce irregular colour thereby be suppressed at seeing through in the light of above-mentioned transparency carrier.
With in the planarizing unit, it is the overlay film that the painted filtering layer by color filter forms with printing ink that above-mentioned coloring printing ink overlay film is preferably at printing ink overlay film of the present invention.That is, printing ink overlay film planarizing unit of the present invention is preferably as the planarizing unit that is used for the painted filtering layer of liquid crystal color filter.
Printing ink overlay film planarization roller of the present invention, it is characterized in that possessing: cylinder and above-mentioned printing ink overlay film planarizing unit, above-mentioned printing ink overlay film planarizing unit, with with the surface of above-mentioned elastic layer side relative with above-mentioned cylinder to mode, be fixed on the outer peripheral face of above-mentioned cylinder.
According to this printing ink overlay film planarization roller, same with printing ink overlay film of the present invention with planarizing unit, the reverse seal that can suppress the printing ink that release layer and contacting of printing ink overlay film cause, and follow in the defective of this printing ink overlay film generation, with the concavo-convex transfer printing that prevents to cause to the elastic layer surface attachment to the printing ink overlay film because of foreign matter, and can push the printing ink overlay film equably, and can be implemented in the reduction of surfaceness of printing ink overlay film and the homogenising of thickness.In addition, according to above-mentioned printing ink overlay film planarization roller, even particularly adhered under the situation of foreign matter between the outer peripheral face of cylinder and printing ink overlay film are with planarizing unit, it is concavo-convex to prevent that also the printing ink overlay film from producing.
Printing ink overlay film according to the present invention can suppress the reverse seal of printing ink with planarizing unit and printing ink overlay film planarization roller, and then suppresses the concavo-convex transfer printing that causes because of foreign matter, and will be formed on the flattening surface of the printing ink overlay film on the transparency carrier.And by like this with the flattening surface of printing ink overlay film, produce irregular colour thereby can be suppressed at seeing through in the light of above-mentioned transparency carrier.Such printing ink overlay film is with planarizing unit and printing ink overlay film planarization roller, for example is applicable to the formation etc. of the painted filtering layer of liquid crystal color filter.
Description of drawings
Fig. 1 is the fragmentary perspective cross sectional view of expression printing ink overlay film of the present invention with planarizing unit one embodiment.
Fig. 2 is the local amplification view of expression printing ink overlay film shown in Figure 1 with the layer structure of planarizing unit.
Fig. 3 schematically represents the key diagram of printing ink overlay film of the present invention with an example of the user mode of planarizing unit.
Fig. 4 schematically represents the key diagram of printing ink overlay film of the present invention with another example of the user mode of planarizing unit.
Embodiment
Fig. 1 is the fragmentary perspective cross sectional view of expression printing ink overlay film of the present invention with planarizing unit one embodiment.Fig. 2 is the local amplification view of expression printing ink overlay film shown in Figure 1 with the layer structure of planarizing unit.Fig. 3 schematically represents the key diagram of printing ink overlay film of the present invention with an example of the user mode of planarizing unit.Below, with reference to Fig. 1~3 the present invention is described.In addition, in the following description, part identical or similar in a plurality of embodiments is represented identical symbol.
With reference to Fig. 1, the printing ink overlay film possesses with planarizing unit 1: substrate layer 2, coincide with substrate layer 2 one side surfaces 3 release layer 4, coincide with the elastic layer 6 of substrate layer another side 5.
Substrate layer 2 is supporting substrates of release layer 4.As described later, be thin layer about number μ m because release layer 4 is a thickness, so the flatness of release layer 4 flatness of left and right sides substrate layer 2 to a great extent.Therefore, the surfaceness of substrate layer 2, corresponding with the degree of release layer 4 desired surfacenesses as described later, be set in suitable scope.
In addition, it is flexible to require substrate layer 2 to have.Because it is flexible that substrate layer 2 has, therefore can avoid the printing ink overlay film with planarizing unit 1, with printing surface contacting under flat state, can prevent between the printing ink overlay film is with planarizing unit 1 and printing ink overlay film, to produce the gap as the planarization object.And, owing to possess and have flexible substrate layer 2, for example, the printing ink overlay film can be wound on the outer peripheral face of cylinder with planarizing unit 1, formation roller shape and using.
In addition, because substrate layer 2 is supporting substrates of release layer 4,, and require to have suitable physical strength and to the good stickability of release layer 4 therefore for the damage that prevents release layer 4 with peel off.
Substrate layer 2, when considering physical parameters such as its surfaceness, physical strength,, and can obtain to select to get final product in the material of sufficient adhesion strength from good with the compatibility of release layer 4, particularly, for example can enumerate film or the sheet material that forms by resin, metal etc.Wherein, as resin, can enumerate for example engineering plastics, particularly, for example polyethylene terephthalate (PET), polybutylene are to the polyester resin of titanate resin etc., for example imines resinoid, propylene resin etc.In addition, as metal, can enumerate for example aluminium, nickel, stainless steel, iron, copper etc.The material of substrate layer 2 especially preferably uses the PET film in the above-mentioned material.
The surfaceness of substrate layer 2 can suitably be set according to material, thickness and the release layer 4 desired surfacenesses etc. of release layer 4.Therefore, though the surfaceness of substrate layer 2 is not limited to this, yet with arithmetic average roughness R aExpression is preferably 20~500nm.Arithmetic average roughness R when substrate layer 2 aWhen being lower than above-mentioned scope, then the surfaceness of release layer 4 may be lower than the numerical value of expectation.Otherwise, as the arithmetic average roughness R of substrate layer 2 aWhen being higher than above-mentioned scope, then the surfaceness of release layer 4 became thick.And in order to reduce the thickness of the just necessary thickening release layer 4 of surfaceness.
The thickness of substrate layer 2, flexible, the physical strength etc. of considering substrate layer 2 is suitably set and is got final product, though particular determination not, be preferably 50~500 μ m, 80~200 μ m more preferably.When the thickness of substrate layer 2 is lower than above-mentioned scope, then be difficult to handle.In addition, also physical strength might can't be guaranteed.Otherwise, when the thickness of substrate layer 2 is higher than above-mentioned scope, then might damage flexible.
Release layer 4, the layer that contacts with the printing ink overlay film when being planarization.Therefore, require release layer 4 to have superior release property (being that printing ink is difficult to adhere to), and require superior surface smoothness the printing ink overlay film.
As the formation material of release layer 4, can enumerate: for example the silicon class release agent that forms by silicon rubber, silicon elastic-like material, silicones etc., for example fluorine class release agent that forms by fluororubber, fluorine elastic-like material, fluororesin etc. etc.They are surface free energy (limitation table surface tension) materials with smaller, therefore printing ink are had superior release property.The material of release layer 4 especially preferably uses the silicon class release agent in the above-mentioned material, more preferably silicones.
The surfaceness of release layer 4 is with arithmetic average roughness R aBe expressed as 30~280nm, be preferably 50~250nm.Arithmetic average roughness R when release layer 4 aWhen being in the above-mentioned scope, for example, with the candy strip planarization of the painted filtering layer of three looks in the color filter time, can form trickle concavo-convex on the surface of printing ink overlay film, and in the planarization of printing ink overlay film, can suppress the generation of the irregular colour of color filter.
The surface tension of release layer 4 can consider that the release property of 4 pairs of printing ink overlay films of release layer is set.Particularly, as the limitation table surface tension γ of release layer 4 c, below 30mN/m, be preferably 10~25mN/m.As limitation table surface tension γ cWhen being higher than above-mentioned scope, then when planarization, produce the reverse seal that printing ink is attached to release layer 4.Limitation table surface tension γ cLower limit, though particular determination not, yet the limitation table surface tension γ of the release materials of market sale c, be generally more than the 10mN/m.
The thickness of release layer 4 is considered the physical strength, elasticity of release layer 4 etc., suitably sets to get final product, though particular determination not, be preferably below the 30 μ m 2~15 μ m more preferably.When the thickness of release layer 4 was higher than above-mentioned scope, then the elasticity of release layer 4 increased, might be insufficient to pushing of printing ink overlay film.In addition, in this case, for example, might reduce the effect of printing ink overlay film planarization, the according to circumstances different reverse seals that might produce printing ink in that the printing ink overlay film has been applied with planarizing unit 1 under the situation of detrusion.The lower limit of the thickness of release layer 4, though be particular determination, in order to form the superior release layer of flatness 4, be preferably thickness more than 2 μ m.
Elastic layer 6 is the layers that play a role with the cushion of planarizing unit as the printing ink overlay film, is used for the layer so that the mode of the pressure of printing ink overlay film even action is adjusted.In addition, this elastic layer 6, be used to prevent trickle foreign matter to outstanding and remarkableization of release layer 4 side surfaces layer, above-mentioned trickle foreign matter is meant, is attached to the surperficial of elastic layer 6 or is attached to foreign matter between elastic layer 6 and the cylinder 7.Therefore, elastic layer 6 requires to have appropriate elasticity and thickness.
The material of elastic layer 6 can be enumerated for example soft resin, rubber, resilient material etc.These resins, rubber and resilient material can be that expansion type also can be non-expansion type.Wherein preferably can enumerate urethane resin.
The thickness of elastic body 6, the formation material of consideration elastic layer 6, extent of elasticity etc., that is, and can be abundant at resiliency, and suitably select in the scope that the degree of compression deformation can be not excessive.Particularly, the thickness of elastic body 6 is 100~5000 μ m, is preferably 500~1000 μ m.When the thickness of elastic body 6 is lower than above-mentioned scope, then can't absorbs the projection that causes because of the foreign matter that is attached to elastic body 6 surfaces, thereby when planarization, produce concavo-convex on the surface of printing ink overlay film.On the other hand, too small to printing ink overlay film applied pressure when planarization when the thickness of elastic body 6 is higher than above-mentioned scope, thus can't give full play to the effect of planarization.
The spring rate of elastic body 6 can be abundant at resiliency, and suitably select in the scope that degree of the compressed distortion can be not excessive.Particularly, the elasticity of compression rate E of elastic body 6 cBe 0.5~20MPa, be preferably 1~10MPa, as the elasticity of compression rate E of elastic body 6 cWhen being lower than above-mentioned scope, then too small to printing ink overlay film applied pressure when planarization, thus can't bring into play the effect of planarization fully.Otherwise, as the elasticity of compression rate E of elastic body 6 cWhen being higher than above-mentioned scope, then can't absorbing the projection that causes because of the foreign matter that is attached to elastic body 6 surfaces, thereby when planarization, produce concavo-convex on the surface of printing ink overlay film.
Above-mentioned printing ink overlay film can be made in the following way with planarizing unit 1, promptly for example on a side surface 3 of substrate layer 2, applying release layer forms material and makes it solidify to form release layer 4, on the opposite side surface 5 of substrate layer 2, apply elastic layer and form material and make it solidify to form elastic layer 6.The formation order of release layer 4 and elastic layer 6 does not limit, and can be and above-mentioned opposite order yet.
In order to form release layer 4, elastic layer 6 on the surface of substrate layer 2, for example, at first opposed two limits form a pair of dyke in the periphery of substrate layer 2.This dyke is for example gluedd joint band by overlapping stickup and is formed, and it highly cooperates release layer 4, elastic layer 6 desired thickness.Then, in the zone that a pair of dyke clips, inject release layer and form material and elastic layer formation material, in addition frotton is erected between a pair of dyke, rolls on the surface of dyke, make the thickness of release layer formation material and elastic layer formation material smooth equably by making this frotton.Like this, release layer is formed thickness that material and elastic layer form material adjust to height with dyke identical after, heating makes release layer form material and elastic layer forms material cured as required.
Release layer forms the condition of cure of material and elastic layer formation material, suitably is provided with according to the material that uses to get final product.
Above-mentioned printing ink overlay film for example as shown in Figure 3, is wound in the outer peripheral face of cylinder 7 with planarizing unit 1, uses with planarization roller 8 as the printing ink overlay film.
The printing ink overlay film possesses with planarization roller 8: cylinder 7 and above-mentioned printing ink overlay film be with planarizing unit 1, and the printing ink overlay film is with planarizing unit 1, with above-mentioned elastic layer 6 side surfaces and cylinder 7 relative to mode, be fixed on the side face of cylinder 7.
Though, yet for example can use the employed blanket cylinder of hectographic printing as cylinder 7 particular determination not.As the printing ink overlay film is fixed on method on the cylinder 7 with planarizing unit 1, for example can enumerate, by the elastic layer 6 of bonding printing ink overlay film, and be fixed on the method for the outer peripheral face of cylinder 7 with planarizing unit 1.In addition, use under the situation of blanket cylinder as cylinder 7, for example also can use to be used for the hectograph blanket is fixed on means on the blanket cylinder, fixedly printing ink overlay film usefulness planarizing unit 1.
When the printing ink overlay film is used under the situation of planarization roller 8 with planarizing unit 1 for the printing ink overlay film, the planarization of printing ink overlay film, for example as shown in Figure 3, by pushing on one side the surface of printing ink overlay film (being formed on the painted filtering layer 11 on the transparency carrier 10 of color filter 9), Yi Bian the printing ink overlay film that rolls is realized above-mentioned processing with planarization roller 8.
In addition, utilize the planarization of printing ink overlay film with 1 pair of printing ink overlay film of planarizing unit, as shown in Figure 4, with release layer 4 side surfaces of printing ink overlay film with planarizing unit 1, to the surface of printing ink overlay film 11, relatively to and dispose, and from the printing ink overlay film with elastic layer 6 sides of planarizing unit 1, with roller 12 the printing ink overlay film is pressed on the printing ink overlay film with planarizing unit 1, and realize above-mentioned processing by rolling roller 12.
Printing ink overlay film planarizing unit of the present invention, be preferably especially, according to printing ink overlay film planarization roller of the present invention, prevent printing ink reverse seal and to the printing ink overlay film produce concavo-convex, and, thereby can realize reducing the surfaceness of printing ink overlay film and the homogenising of thickness with the planarization of printing ink overlay film.Therefore, printing ink overlay film planarizing unit of the present invention, and printing ink overlay film planarization roller, the planarization of the painted filtering layer during the color filter that for example is applicable to display panels is made etc.
Embodiment:
Next, enumerate embodiment and comparative example the present invention is described in further detail.
In following embodiment and comparative example, the arithmetic average roughness R of release layer and substrate layer aWith the thickness of release layer and elastic layer, utilize contact pin type surface profile measuring instrument (trade name: " ア Le Off ア ス テ Star プ (probe-type contourgraph) 500 ", ケ-エ Le エ-テ Application コ-Le (KLA-Tencor) (strain) is made) to measure.In addition, only the thickness of substrate layer is the standard value of product.
In following embodiment and comparative example, represented that as the surface tension of release layer release layer forms the limitation table surface tension γ of material cValue (measure temperature 25 ℃).Full-automatic contact angie type measuring instrument (trade name: " DropMaster DM-700 ", consonance interface science (strain) are made) has been used in the capillary measurement of release layer.
In addition, as the spring rate of elastic layer, represented that elastic layer forms the elasticity of compression rate E of material cValue (measure temperature 25 ℃).Form by two or more elastic layers under the situation that mixtures of material forms at elastic layer, form the elasticity of compression rate E of material according to each elastic layer cValue and contain proportionally, calculate elasticity of compression rate E as elastic layer cValue.
Release layer forms the surfaceness of material, be with contact pin type surface profile measuring instrument (above-mentioned trade name: " ア Le Off ア ス テ Star プ (probe-type contourgraph) 500 "), the release layer side surface separately in the following planarizing unit that embodiment and comparative example obtained has been carried out the value of measuring (measuring 25 ℃ of temperature).
The manufacturing of planarizing unit of printing ink overlay film:
Embodiment 1:
As the substrate layer of printing ink overlay film, used to be cut to vertical (L with planarizing unit 1) 300mm, horizontal stroke (L 2) rectangular shape of 400mm, thickness 100 μ m, arithmetic average roughness R aThe PET film of 380nm (trade name: " テ イ ジ Application, テ ト ロ Application (registered trademark) Off イ Le system (TeijinDuPont Films) U4 " Supreme Being people's (strain) makes) (with reference to Fig. 1).
By each ora terminalis in substrate layer one side surface, paste the splicing band of thickness 30 μ m, width 12mm, and formed the dyke of thickness 30 μ m at the circumference of a side surface of substrate layer.Then, in the zone that above-mentioned dyke surrounded, inject release agent (silicones, limitation table surface tension γ by a side surface of substrate layer c16mN/m, arithmetic average roughness R a8.7nm, trade name: " SEPA-COAT ", SHIN-ETSU HANTOTAI's chemical industry (strain) is made), after the stainless steel frotton of using diameter 12mm is smooth with release agent, place at normal temperatures.After release agent has lost flowability, remove from a side surface of substrate layer and to glued joint band, thereby and release agent is fully solidified and drying with 100 ℃ purification baking oven for heating, formed release layer.
Then, by circumference,, thereby formed the dyke of thickness 500 μ m along the splicing band of overlapping stickup ten layer thicknesses of each ora terminalis 50 μ m, width 12mm on substrate layer opposite side surface.Then, in the zone that above-mentioned dyke surrounded, inject casting mold urethane resin (elasticity of compression rate E by substrate layer opposite side surface c5.3MPa trade name: " KU-5550-9 ", Hitachi change into industry (strain) manufacturing), after the stainless steel frotton with diameter 12mm makes urethane resin smooth, place at normal temperatures, make it solidify to form elastic layer.
Can obtain laminar printing ink overlay film planarizing unit 1 like this, the printing ink overlay film possesses with planarizing unit 1: substrate layer 2; Coincide with the release layer 4 of these substrate layer 2 one side surfaces; Coincide with the elastic layer 6 (with reference to Fig. 1 and Fig. 2) on the opposite side surface of above-mentioned substrate layer.
Embodiment 2,3 and comparative example 1:
By regulating the injection rate IR of release agent, remove being set at 1 μ m in the thickness embodiment 2 after release layer 4 curing, be set at 0.7 μ m in the embodiment 3, be set in the comparative example 1 beyond the 0.7 μ m, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit.
Embodiment 4:
As substrate layer 2, remove to have used and be cut into minor face L 1Length 300mm, long limit L 2The rectangular shape of length 400mm, thickness 100 μ m, arithmetic average roughness R a66.8nm PET film (trade name " テ イ ジ Application テ ト ロ Application (registered trademark) Off イ Le system (Teijin DuPont Films) S " Supreme Being people's (strain) manufacturing) in addition, all same with embodiment 1, obtained laminar printing ink overlay film with planarizing unit 1.
Comparative example 2:
As the release agent that is used to form release layer 4, used trade name " SEPA-COAT " (silicones, limitation table surface tension γ c16mN/m, arithmetic average roughness R a8.7nm SHIN-ETSU HANTOTAI's chemical industry (strain) is made) and trade name " KS-837 " (silicones, limitation table surface tension γ c16mN/m, arithmetic average roughness R a38nm, SHIN-ETSU HANTOTAI's chemical industry (strain) is made), mix the material that obtains according to the weight ratio of 80:20.In addition, as substrate layer 2, used and be cut into vertical (L 1) 300mm, horizontal stroke (L 2) rectangular shape of 400mm, thickness 100 μ m, arithmetic average roughness R a11.5nm PET film (trade name: " Le ミ ラ-(Rumirer) " (registered trademark) T60) eastern レ (Toray) (strain) makes), except that having used above-mentioned release agent and substrate layer, all same with embodiment 1, obtained laminar printing ink overlay film planarizing unit 1.
Embodiment 5 and comparative example 3:
As the release agent that is used to form release layer 4, commodity in use name " SEPA-COAT " (silicones, limitation table surface tension γ c16mN/m, arithmetic average roughness R a8.7nm SHIN-ETSU HANTOTAI's chemical industry (strain) is made) and trade name " KS-830 " (silicones, limitation table surface tension γ c38mN/m, arithmetic average roughness R a10.5nm, SHIN-ETSU HANTOTAI's chemical industry (strain) manufacturing) potpourri, except blending ratio (weight ratio) with " SEPA-COAT " and " KS-830 ", in embodiment 5, be set at 40:60, in comparative example 3, be set at beyond the 20:80, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit 1.
Embodiment 6 and comparative example 4:
As the urethane resin that is used to form elastic layer 6, used trade name " KU-7002 " (elasticity of compression rate E c0.07MPa Hitachi changes into industry (strain) manufacturing) and trade name " KU-7008 " (elasticity of compression rate E c0.95MPa, Hitachi changes into industry (strain) and makes) potpourri, and except blending ratio (weight ratio) with " KU-7002 " and " KU-7008 ", in embodiment 6, be set at 50:50, in comparative example 4, be set at beyond the 40:60, similarly to Example 1, obtained laminar printing ink overlay film planarizing unit 1.
Embodiment 7 and comparative example 5:
As the urethane resin that is used to form elastic layer 6, commodity in use name " KU-5550-9 " (elasticity of compression rate E c5.3MPa Hitachi changes into industry (strain) manufacturing) and trade name " U-801A/B " (elasticity of compression rate E c32MPa, Hitachi changes into industry (strain) and makes) potpourri, and except blending ratio (weight ratio) with " KU-5550-9 " and " U-801A/B ", in embodiment 7, be set at 55:45, in comparative example 5, be set at beyond the 45:55, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit 1.
Comparative example 6:
As the formation material of elastic layer 6, silicones (the organic modified silicone resin of two solution curing types, trade name: " SCR-1011A/B ", elasticity of compression rate E have been used except replacing urethane resin c1400MPa, SHIN-ETSU HANTOTAI's chemical industry (strain) is made) in addition, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit 1.
Embodiment 8,9 and comparative example 7,8:
By regulating the injection rate IR of urethane resin, except the thickness after elastic layer 6 is solidified, in comparative example 7, be set at 80 μ m, in embodiment 8, be set at 100 μ m, in embodiment 9, be set at 4800 μ m, in comparative example 8, be set at beyond the 5200 μ m, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit 1.
Comparative example 9:
Except not forming elastic layer, all similarly to Example 1, obtained laminar printing ink overlay film planarizing unit.
That is, at first each ora terminalis in substrate layer one side surface is pasted the splicing band of thickness 30 μ m, width 12mm, thereby has formed the dyke of thickness 30 μ m at the circumference of substrate layer one side surface.Then, in the zone that above-mentioned dyke surrounded, inject release agent (silicones, limitation table surface tension γ by a side surface of substrate layer c16mN/m, arithmetic average roughness R a8.7nm trade name " SEPA-COAT ", SHIN-ETSU HANTOTAI's chemical industry (strain) is made), and with the stainless steel frotton of diameter 12mm with release agent smooth after, placement at normal temperatures.After release agent loses flowability, remove from a side surface of substrate layer and to glued joint band, thereby and release agent is fully solidified and drying with 100 ℃ purification baking oven for heating, formed release layer.Obtained laminar printing ink overlay film planarizing unit like this, this printing ink overlay film possesses substrate layer with planarizing unit, and the release layer of above-mentioned substrate layer one side surface coincidence.
The planarization of color filter:
Use: the painted filtering layer of red (R) that is modulated in the intaglio plate hectographic printing, green (G) and blue (B) three looks forms uses printing ink; The glass intaglio plate that possesses the striated recess of A/F 100 μ m, the degree of depth 7 μ m; The blanket cylinder of accurate printing usefulness (gross thickness 0.9mm, SRI research and development (strain) are made); Plate intaglio plate offset press (Na カ Application (Nakan) (strain) manufacturing) has printed the painted filtering layer of RGB three looks on the transparency carrier of color filter.Painted filtering layer, line width are about 100 μ m, and spacing is 100 μ m, and R, G, B candy strip are formed according to this series arrangement.
On the other hand, the printing ink overlay film with embodiment 1~9 and comparative example 1~8 is wound in the outer peripheral face of cylinder 7 with planarizing unit respectively, thereby obtains printing ink overlay film planarization roller 8.At this moment, the printing ink overlay film is with planarizing unit 1, be configured to so that the outer peripheral face of its elastic layer 6 side surfaces and cylinder 7 relative to mode, and by on the bonding outer peripheral face that is fixed on cylinder 7.In addition, the printing ink overlay film planarizing unit of comparative example 9, be configured to so that the outer peripheral face of the surface of the release layer opposition side in the substrate layer and cylinder 7 relative to mode, and by on the bonding outer peripheral face that is fixed on cylinder 7.
Evaluating characteristics:
(1) reverses seal
Painted filtering layer 11 to color filter 9 has carried out after the planarization, by the release layer side surface of visualization printing ink overlay film with planarizing unit (printing ink overlay film planarization roller), and according to following standard facing to the adhering to of chromogenic filter course release layer, promptly reverse seal and estimate.
Zero: do not observe and reverse seal.The printing ink overlay film has good printing ink release property with the release layer of planarizing unit.
*: observed the generation that reverses seal.The printing ink overlay film release layer of planarizing unit, the release property of printing ink is insufficient.
(2) the arithmetic average roughness R of painted filtering layer a
Painted filtering layer 11 to color filter 9 has carried out after the planarization, for uncured painted filtering layer 11, utilize contact pin type surface profile measuring instrument (trade name " ア Le Off ア ス テ Star プ (probe-type contourgraph) 500 " ケ-エ Le エ-テ Application コ-Le (KLA-Tencor) (strain) is made) to its arithmetic average roughness R aCarried out measuring (measuring 25 ℃ of temperature).
◎: surfaceness is minimum, and the flatness of painted filtering layer is fabulous.
Zero: surfaceness is little, and the flatness of painted filtering layer is good.
*: surfaceness is big, and the flatness of painted filtering layer is insufficient.
(3) irregular colour
Painted filtering layer 11 to color filter 9 has carried out after the planarization, by color filter 9 is put into the purification baking oven, and 230 ℃ of heating 30 minutes down, thereby painted filtering layer 11 is solidified.Then, facing to chromogenic filter layer 11 irradiating and detecting sodium vapor lamp (Off Na テ Star Network (Funatech) (strain) manufacturing), by the extent of deviation of visualization thickness between the painted filtering layer of R, G and B three looks, and the degree of irregular colour is estimated according to following standard.
◎: do not observe the thickness deviation between the painted filtering layer of three looks, do not observe the irregular colour of painted filtering layer fully.
Zero: suppressed the thickness deviation between the painted filtering layer of three looks.Though observe the irregular colour of minimum painted filtering layer, when LCD is installed, for by visual can't detected degree.
*: the thickness deviation between the painted filtering layer of three looks remarkable.
(4) foreign matter is damaged
Painted filtering layer 11 to color filter 9 has carried out after the planarization, by the surface of the painted filtering layer 11 of observation by light microscope, observes painted filtering layer 11 and has or not foreign matter damaged, and estimate according to following standard.
◎: do not observe the defective of the painted filtering layer 11 that produces along with adhering to of foreign matter and concavo-convex fully.
Zero: though observe the defective of the painted filtering layer 11 that produces along with adhering to of foreign matter and concavo-convex slightly, yet by seeing through the observation generation irregular colour unconfirmed of light.
△: the defective of the painted filtering layer 11 that produces along with adhering to of foreign matter and concavo-convex is observed in the part.In addition, confirmed to have produced irregular colour by the observation of transmitted light in the part of painted filtering layer 11.
*: the defective of the painted filtering layer 11 that produces along with adhering to of foreign matter and concavo-convex generation are remarkable.In addition, confirmed the irregular colour of painted filtering layer 11 significantly by the observation of transmitted light.
(5) comprehensive evaluation
Based on the evaluation result of above-mentioned (1)~(4), carried out comprehensive evaluation according to following standard.
◎: fabulous.
Zero: good.
*: bad.
Above result is shown in table 1~3.
Table 1
Figure G2008101730650D00151
Table 2
Figure G2008101730650D00161
Table 3
Figure G2008101730650D00171
In table 1~3, " the alignment diagram surface roughness R on " release layer " hurdle a" and " limitation table surface tension γ c", " elasticity of compression rate E on " elastic layer " hurdle c" and the project of " thickness " in, be labeled as respectively at the measured value (calculated value) of projects: being " zero " under the situation in scope of the present invention, is " ◎ " to be " * " under extraneous situation of the present invention under the situation of preferable range.In addition at " the alignment diagram surface roughness R on " evaluating characteristics " hurdle a" project in, except that its measured value, gone back mark and utilized the evaluation of above-mentioned standard.
The present invention is not limited to the scope of above record, can carry out various design alterations in every protection domain of claim record.

Claims (6)

1. printing ink overlay film planarizing unit, it is the surface that presses on the coloring printing ink overlay film that is formed on the transparency carrier, and makes the planarizing unit that has an even surface of above-mentioned printing ink overlay film, it is characterized in that: possess:
Have flexible substrate layer, be laminated in the release layer of above-mentioned substrate layer one side surface and be laminated in the elastic layer on above-mentioned substrate layer opposite side surface,
The arithmetic average roughness R on the surface of a side opposite of above-mentioned release layer with above-mentioned substrate layer side aBe 30~280nm, and limitation table surface tension γ cBelow 30mN/m.
2. printing ink overlay film planarizing unit according to claim 1 is characterized in that, the thickness of above-mentioned elastic layer is 100~5000 μ m, and elasticity of compression rate E cBe 0.5~20MPa.
3. printing ink overlay film planarizing unit according to claim 2 is characterized in that, the thickness of above-mentioned substrate layer is 50~500 μ m.
4. printing ink overlay film planarizing unit according to claim 3 is characterized in that the surfaceness of above-mentioned substrate layer is with arithmetic average roughness R aCount 20~500nm.
5. according to any described printing ink overlay film planarizing unit in the claim 1 to 4, it is characterized in that above-mentioned coloring printing ink overlay film is the overlay film that the painted filtering layer by color filter forms with printing ink.
6. printing ink overlay film planarization roller, it is characterized in that, possess: any described printing ink overlay film planarizing unit in cylinder and the claim 1 to 4, above-mentioned printing ink overlay film planarizing unit, with with the surface of above-mentioned elastic layer side relative with above-mentioned cylinder to mode, be fixed on the outer peripheral face of above-mentioned cylinder.
CN2008101730650A 2007-11-27 2008-11-26 Flat component and flat roll for ink overlay film Expired - Fee Related CN101446659B (en)

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