CN101433802A - Integral baffle bioreactor waste gas treatment equipment and waste gas treatment method - Google Patents
Integral baffle bioreactor waste gas treatment equipment and waste gas treatment method Download PDFInfo
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- CN101433802A CN101433802A CNA2007101772108A CN200710177210A CN101433802A CN 101433802 A CN101433802 A CN 101433802A CN A2007101772108 A CNA2007101772108 A CN A2007101772108A CN 200710177210 A CN200710177210 A CN 200710177210A CN 101433802 A CN101433802 A CN 101433802A
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Abstract
The invention belongs to a device for treating waste gas by making use of a bioreactor, and in particular relates to an integral waste gas treatment device by making use of a reflection bioreactor, and a method for treating the waste gas. The device is to add a gas-liquid separation zone between a suspension type biological reaction zone and a fixed type biological reaction zone of a downward flow type biological odor treatment device of a composite type biological odor treatment device, wherein the top part of the suspension type biological reaction zone is butted with the gas-liquid separation zone; a clapboard is arranged between the two zones; the lateral wall of the gas-liquid separation zone is provided with an exhaust port and a water outlet, the exhaust port is higher than the water outlet, and the top part of the exhaust port is butted with the fixed type biological reaction zone; a perforated plate is arranged between the two zones; and two ore more air pipes are arranged in the fixed type biological reaction zone and are communicated with the suspension type biological reaction zone. The integral waste gas treatment device not only keeps the advantages of the composite type biological odor treatment device, but also is easy to separate gas and water, prevents stuffing from running off and prevents the air pipe from being blocked; and the spraying and gas treatment can be performed at the same time.
Description
Technical field
The invention belongs to the equipment that utilizes bioreactor for treatment waste gas, particularly a kind of integral baffle bioreactor waste gas treatment equipment and waste gas processing method.
Background technology
Human being's production, life activity or nature are discharged all contaminations to atmosphere, the present scale that whole world every year has reached 2,000 ten thousand t/a to the VOC and the odorant of airborne release, the discharging of China's volatile organic contaminant and odorant also increases year by year along with the development of industrial and agricultural production.These volatile organic contaminants and odorant spill in the atmosphere, not only cause the pollution in some areas, and air quality is worsened, owing to along with the diffuses flow of air arrives everywhere, also can bring regional influence.
Be the protection atmospheric environment, some developed countries have worked out relevant environmental protection law, the discharging of pollutant in the strict control waste gas, and require enterprise before discharging pollutants, should take corresponding control measures.China in 1993 and country's " odorant pollutant discharge standard " of coming into effect in 1997 (GB14554-93) and " discharge standard of air pollutants " strict regulation has been made in the discharging of volatile organic contaminant and odorant in (GB16297-1996).
Compare with other physical chemistry waste gas processing method, bioremediation has advantages such as cost is low, easy and simple to handle, technology cleaning, non-secondary pollution because of it, and the nineties becomes the focus of current research later on.Biological ratio juris is to utilize the biological oxidation of microorganism that the smelly material in volatile organic contaminant or the foul gas is converted into carbon dioxide, water and the low process that does harm to the class material.Microbial suspension in the bioreactor is grown in the solution as activated sludge, or apposition growth is in inorganic filler (as: gravel, haydite, active carbon) or organic filler (as: bark, wood chip, compost, resin etc.).
Composite type bioreactor waste gas processing equipment (number of patent application: 01141503.7) constitute by floated bioreactor and fixed type biological reactor, in two parts reactor, the microorganism of pollutant is inequality in the degraded waste gas, they are the water miscible difference according to pollutant in the waste gas, cultivate selectively.Microorganism in the floated bioreactor is to be suitable for suspension growth bacterium in water, that help hydrophily contaminant degradation in the waste gas; Fill filler at the fixed type biological inside reactor, the microorganism of degradation of contaminant is the fungi of apposition growth on filler.Cultivate fungi and replace bacterium, help the removal of hydrophobic contaminant in the waste gas.Therefore, composite type bioreactor waste gas processing equipment can be removed hydrophily in the waste gas and hydrophobic contaminant effectively simultaneously.Thereby the purpose that realization is removed the multiple pollutant in the waste gas simultaneously effectively.And, can realize simultaneously in the floated bioreactor that aeration, gas are prewetted and transfer and the degraded of pollutant from the gas phase to the water soluble in water, reduce auxiliary equipment.Replace bacterial degradation waste gas with fungi in the fixed type biological reactor.On the one hand, fungi can generate mycelia in air, mycelia to around distribute and form the mycelia net, help to increase the contact area of pollutant and mushroom in the gas phase, pollutant in the gas phase is directly fully contacted with fungi in bioreactor, finish mass transport process better.Particularly for some organic exhaust gas, the degradation capability of fungi is higher than bacterium.On the other hand, fungi is stronger to the adaptability of humidity and pH value.Treatment facility spray number of times is few, reduces energy consumption.Composite type bioreactor waste gas processing equipment has compact conformation, structure is succinct, floor space is little, operation and the simple advantage of maintenance.
But, composite type bioreactor waste gas processing equipment following to the biological odor treatment device of streaming, the lower end of its fixed type biological reaction zone only is provided with an exhaust outlet, there is not delivery port, to the microorganism spraying nutrient solution on the filler of fixed type biological reaction zone the time, excess liquid is also discharged from exhaust outlet.During draining, usually hinder gas purging.Therefore, during the spray operation, air pump must cut out usually, make waste gas treatment equipment be in halted state, cause treatment of waste gas not carry out continuously like this.The filler of fixed type biological reaction zone bottom also usually can be discharged exhaust outlet with water, causes the loss of filler.In addition, be positioned near the filler of air communicating pipe import and can enter into communicating pipe, cause the communicating pipe blocking problem.
Summary of the invention
The objective of the invention is to overcome the following defective that exists to the biological odor treatment device of streaming of combined biological waste gas treatment equipment, provide a kind of not only can be easy and simple to handle, energy consumption is lower, can be effectively that concentration range is big, the hydrophily and the lyophobic dust that contain in the waste gas remove simultaneously, and gas, spray liquid are effectively separated, prevent that filler runs off and breather pipe stops up, the integral baffle bioreactor waste gas treatment equipment that spray operation and exhaust-gas treatment can be carried out simultaneously.
Another object of the present invention provides utilizes the integral baffle bioreactor waste gas treatment equipment to carry out the method for exhaust-gas treatment.
Integral baffle bioreactor waste gas treatment equipment of the present invention is that (number of patent application: following improvement to the biological odor treatment device of streaming 01141503.7) comprises the floated bio-reaction zone that is used for the solution that ccontaining bacterial micro-organism suspends, is used for the fixed type biological reaction zone and the gas-liquid separation zone of the filler that ccontaining fungi microbe adheres to the combined biological odor treatment device.
By the perforated plate that has a plurality of holes and the dividing plate that has a hole integral baffle bioreactor waste gas treatment equipment inner chamber is divided into the floated bio-reaction zone that is used for the solution that ccontaining bacterial micro-organism suspends, is used for the fixed type biological reaction zone and the gas-liquid separation zone of the filler that ccontaining fungi microbe adheres to; Wherein, zone between the roof of perforated plate and integral baffle bioreactor waste gas treatment equipment is the fixed type biological reaction zone, zone between perforated plate and the dividing plate is a gas-liquid separation zone, and the zone between the diapire of dividing plate and integral baffle bioreactor waste gas treatment equipment is floated bio-reaction zone;
One sidewall of described floated bio-reaction zone bottom has an air inlet, at the place, the inner of air inlet the porous perforated pipe is installed; Another sidewall of floated bio-reaction zone bottom is provided with delivery port, and delivery port is higher than the air inlet that the porous perforated pipe is installed, and the sidewall on delivery port top is provided with water inlet, and the place, the inner of water inlet is equipped with the water pipe that has a plurality of liquid spraying heads;
One sidewall of described gas-liquid separation zone is provided with exhaust outlet, be provided with delivery port on another sidewall of gas-liquid separation zone, and exhaust outlet is higher than delivery port;
The inside of described fixed type biological reaction zone is provided with two or many breather pipes, be provided with elbow on breather pipe top or with the top bending of breather pipe as breather pipe outlet, and the exit at breather pipe is provided with stainless steel cloth, the other end of breather pipe passes perforated plate and docks with the hole on the dividing plate, and the fixed type biological reaction zone is communicated with floated bio-reaction zone by breather pipe;
The inside of described fixed type biological reaction zone is filled with filler, and upper portion side wall is provided with the spray liquid import, at the place, the inner of spray liquid import the water pipe that has a plurality of liquid spraying heads is installed.
The aperture in the hole on the described perforated plate is 30~100mm.
The aperture in the hole on the described perforated pipe is 1~10mm.
The following difference to the biological odor treatment device of streaming of the present invention and existing combined biological waste gas treatment equipment is except having floated bio-reaction zone and fixed type biological reaction zone, also to be provided with a gas-liquid separation zone between two districts.
Exit at breather pipe is provided with stainless steel cloth, and its stainless steel cloth can prevent effectively that filler from entering breather pipe, avoids breather pipe to stop up.Perforated plate between fixed type biological reaction zone and the gas-liquid separation zone had both played the effect of support filler, filler and gas, water can be separated again, avoided the fritter filler to enter exhaust outlet or delivery port, when avoiding filler to run off, made exhaust, water outlet unimpeded.
The method of utilizing the integral baffle bioreactor waste gas treatment equipment to carry out exhaust-gas treatment of the present invention is: waste gas enters in the floated bio-reaction zone from the air inlet of floated bio-reaction zone, upwards flow, material soluble in water in the waste gas is absorbed degraded by the microorganism in the floated bio-reaction zone water; Gas is prewetted simultaneously; The hydrophobic contaminant that is not degraded enters in the fixed type biological reaction zone from top through breather pipe, flows downward, and is attached the fungi microbe degraded on filler; Purified gas passes perforated plate and enters gas-liquid separation zone, discharges from the exhaust outlet of gas-liquid separation zone upper portion side wall.
Delivery port, water inlet in the floated bio-reaction zone and the water pipe that has a plurality of liquid spraying heads connect by circulating pump, make the liquid circulation flow in the floated bio-reaction zone moving, increase the contact area of liquid and gas, the raising removal effect.
The spray liquid import at fixed type biological reaction zone top and the water pipe that has a plurality of liquid spraying heads regularly spray carbon-free nutrient liquor to filler, excessive nutrient solution and water flow into gas-liquid separation zone from perforated plate, and discharge from the delivery port of gas-liquid separation zone bottom, or flow in the floated bio-reaction zone with the water inlet of circulating pump through floated bio-reaction zone, for the microorganism in the floated bio-reaction zone provides nutrition, excess liquid is discharged through the delivery port of floated bio-reaction zone.
Equipment of the present invention not only has all advantages of combined biological waste gas treatment equipment, but also has following advantage:
1. equipment of the present invention is two bio-reaction zones, gas-liquid separation zone combination, and compact conformation, structure is succinct, floor space is little, operation with safeguard simple.
2. gas-liquid separation zone side is provided with exhaust outlet, be provided with delivery port in the another side, and exhaust outlet is higher than delivery port, gas is discharged from the exhaust outlet of upper end, unnecessary spray liquid is discharged from the delivery port of bottom, and gas, spray liquid are effectively separated at gas-liquid separation zone.Spray operation and exhaust-gas treatment can be carried out simultaneously.
3. the perforated plate between fixed type biological reaction zone and the gas-liquid separation zone had both played the effect of support filler, filler and gas, water can be separated again, avoided the fritter filler to stop up exhaust outlet or delivery port, made exhaust, the water outlet of equipment keep unimpeded.
4. the inside of fixed type biological reaction zone is provided with two or many breather pipes, a breather pipe upwards end is provided with elbow or with the top bending of breather pipe, exit at breather pipe is provided with stainless steel cloth, stainless steel cloth can separate filler and breather pipe, avoid the fritter filler to enter breather pipe, make breather pipe keep unimpeded.
Description of drawings
Fig. 1. the schematic diagram of present device.
Reference numeral
1. perforated pipe 2. air inlets 3. floated bio-reaction zone 4. exhaust outlets
5. breather pipe 6. fillers 7. elbows
8. have the water pipe 9. spray liquid imports of a plurality of liquid spraying heads
10. fixed type biological reaction zone 11. dividing plates 12. perforated plates
13. delivery port 14. water inlets 15. circulating pumps 16. delivery ports
17. have the water pipe 18. integral baffle bioreactor waste gas treatment equipments of a plurality of liquid spraying heads
19. gas-liquid separation zone 20. shower nozzles
The specific embodiment
See also Fig. 1.
The integral baffle bioreactor waste gas treatment equipment 18 that plastic plate is made, its length is respectively 2.20m, 1.10m, 1.70m, and cumulative volume is 4.1m
3By the perforated plate 12 that has a plurality of holes (aperture be 30~100mm) and the dividing plate 11 that has a hole integral baffle bioreactor waste gas treatment equipment inner chamber is divided into the floated bio-reaction zone 3 that is used for the solution that ccontaining bacterial micro-organism suspends, is used for the fixed type biological reaction zone 10 and the gas-liquid separation zone 19 of the filler that ccontaining fungi microbe adheres to; Wherein, zone between the roof of perforated plate and integral baffle bioreactor waste gas treatment equipment is a fixed type biological reaction zone 10, zone between perforated plate 12 and the dividing plate 11 is a gas-liquid separation zone 19, and the zone between the diapire of dividing plate 11 and integral baffle bioreactor waste gas treatment equipment is floated bio-reaction zone 3;
One sidewall of described floated bio-reaction zone 3 bottoms has an air inlet 2, at the place, the inner of air inlet porous perforated pipe 1 is installed, and the aperture is 5~10mm; Another sidewall of floated bio-reaction zone bottom is provided with delivery port 16, and delivery port is higher than the air inlet that the porous perforated pipe is installed, sidewall on delivery port 16 tops is provided with water inlet 14, and the place, the inner of water inlet is equipped with the water pipe 17 that has a plurality of liquid spraying heads;
One sidewall of described gas-liquid separation zone 19 is provided with exhaust outlet 4, be provided with delivery port 13 on another sidewall of gas-liquid separation zone 19, and exhaust outlet is higher than delivery port;
The inside of described fixed type biological reaction zone 10 is provided with two or many breather pipes 5, be provided with elbow 7 on breather pipe top as the breather pipe outlet, and be provided with stainless steel cloth in the elbow exit, the other end of breather pipe passes perforated plate 12 and docks with the hole on the dividing plate, and fixed type biological reaction zone 10 is communicated with floated bio-reaction zone by breather pipe;
The inside of described fixed type biological reaction zone 10 is filled with filler 6 (among the figure with * display part), and upper portion side wall is provided with spray liquid import 9, at the place, the inner of spray liquid import the water pipe 8 that has a plurality of liquid spraying heads is installed.
Utilize above-mentioned integral baffle bioreactor waste gas treatment equipment to carry out exhaust-gas treatment.Room temperature condition is operation down, and activated sludge is housed in the floated bio-reaction zone, and filler is inorganic filler such as gravel, haydite or active carbon; Or organic filler such as bark, wood chip, compost or resin etc.
Concentration is 327mg/m
3Ortho-xylene waste gas enters in the floated bio-reaction zone 3 from the air inlet 2 of floated bio-reaction zone, upwards flows, and the time is 1~3mins.Material soluble in water in the waste gas is absorbed degraded by the microorganism in the floated bio-reaction zone water; Gas is prewetted simultaneously; The hydrophobic contaminant that is not degraded enters in the fixed type biological reaction zone 10 from top through breather pipe 5, flows downward, and is attached the fungi microbe degraded on filler 6; Purified gas passes perforated plate 12 and enters gas-liquid separation zone 19, discharges from the exhaust outlet 4 of gas-liquid separation zone 19 upper portion side wall; The ortho-xylene concentration of exhaust outlet is 8.6mg/m
3, being lower than the discharge standard of air pollutants that country formulates, clearance reaches 97.4%.
The spray liquid import 9 at fixed type biological reaction zone 10 tops and the water pipe 8 that has a plurality of liquid spraying heads regularly spray carbon-free nutrient liquor to filler 6, excessive nutrient solution and water flow into gas-liquid separation zone 19 from perforated plate 12, and discharge from the delivery port 13 of gas-liquid separation zone 19 bottoms, or flow in the floated bio-reaction zone 3 with the water inlet 14 of circulating pump 15 through floated bio-reaction zone 3, for the microorganism in the floated bio-reaction zone 3 provides nutrition, excess liquid is discharged through the delivery port of floated bio-reaction zone 3.During the spray operation, gas, spray liquid can effectively be separated, and need not to close air pump, and treatment of waste gas is carried out continuously.
Embodiment 2:
See also Fig. 1.
The integral baffle bioreactor waste gas treatment equipment 18 that plastic plate is made, its length is respectively 2.0m, 0.9m, 1.7m, and effective volume is 2.52m
3Device structure reaches waste gas processing method with embodiment 1.
Utilize above-mentioned integral baffle bioreactor waste gas treatment equipment to carry out exhaust-gas treatment.Room temperature condition is operation down, and activated sludge is housed in the floated bio-reaction zone, and filler is inorganic filler such as gravel, haydite or active carbon; Or organic filler such as bark, wood chip, compost or resin etc.
The mix waste gas that contains hydrogen sulfide, ethyl mercaptan, ethyl sulfide enters integral baffle bioreactor 3 from air inlet 2, and the time of staying is 1~3mins.The inlet gas concentration of hydrogen sulfide, ethyl mercaptan and ethyl sulfide is respectively: 0.037mg/m
3, 0.098mg/m
3And 0.081mg/m
3, the concentration of giving vent to anger is respectively 0.0018mg/m
3, 0.0092mg/m
3And 0.0122mg/m
3, being lower than the odorant pollutant discharge standard that country formulates, clearance reaches 95.1%, 90.6% and 85.0% respectively.
Claims (6)
1. integral baffle bioreactor waste gas treatment equipment comprises the floated bio-reaction zone that is used for the solution that ccontaining bacterial micro-organism suspends, is used for the fixed type biological reaction zone and the gas-liquid separation zone of the filler that ccontaining fungi microbe adheres to; It is characterized in that:
By the perforated plate that has a plurality of holes and the dividing plate that has a hole integral baffle bioreactor waste gas treatment equipment inner chamber is divided into the floated bio-reaction zone that is used for the solution that ccontaining bacterial micro-organism suspends, is used for the fixed type biological reaction zone and the gas-liquid separation zone of the filler that ccontaining fungi microbe adheres to; Wherein, zone between the roof of perforated plate and integral baffle bioreactor waste gas treatment equipment is the fixed type biological reaction zone, zone between perforated plate and the dividing plate is a gas-liquid separation zone, and the zone between the diapire of dividing plate and integral baffle bioreactor waste gas treatment equipment is floated bio-reaction zone;
One sidewall of described floated bio-reaction zone bottom has an air inlet, at the place, the inner of air inlet the porous perforated pipe is installed; Another sidewall of floated bio-reaction zone bottom is provided with delivery port, and delivery port is higher than the air inlet that the porous perforated pipe is installed, and the sidewall on delivery port top is provided with water inlet, and the place, the inner of water inlet is equipped with the water pipe that has a plurality of liquid spraying heads;
One sidewall of described gas-liquid separation zone is provided with exhaust outlet, be provided with delivery port on another sidewall of gas-liquid separation zone, and exhaust outlet is higher than delivery port;
The inside of described fixed type biological reaction zone is provided with two or many breather pipes, be provided with elbow on breather pipe top or with the top bending of breather pipe as breather pipe outlet, and the exit at breather pipe is provided with stainless steel cloth, the other end of breather pipe passes perforated plate and docks with the hole on the dividing plate, and the fixed type biological reaction zone is communicated with floated bio-reaction zone by breather pipe;
The inside of described fixed type biological reaction zone is filled with filler, and upper portion side wall is provided with the spray liquid import, at the place, the inner of spray liquid import the water pipe that has a plurality of liquid spraying heads is installed.
2. equipment according to claim 1 is characterized in that: the aperture in the hole on the described perforated plate is 30~100mm.
3. equipment according to claim 1 is characterized in that: the aperture in the hole on the described perforated pipe is 1~10mm.
4. method of utilizing each described equipment of claim 1~3 to carry out exhaust-gas treatment, it is characterized in that: waste gas enters in the floated bio-reaction zone from the air inlet of floated bio-reaction zone, upwards flow, material soluble in water in the waste gas is absorbed degraded by the microorganism in the floated bio-reaction zone water; Gas is prewetted simultaneously; The hydrophobic contaminant that is not degraded enters in the fixed type biological reaction zone from top through breather pipe, flows downward, and is attached the fungi microbe degraded on filler; Purified gas passes perforated plate and enters gas-liquid separation zone, discharges from the exhaust outlet of gas-liquid separation zone upper portion side wall.
5. method according to claim 4, it is characterized in that: delivery port, water inlet in the described floated bio-reaction zone and the water pipe that has a plurality of liquid spraying heads connect by circulating pump, make the liquid circulation flow in the floated bio-reaction zone moving, increase the contact area of liquid and gas.
6. method according to claim 4, it is characterized in that: the spray liquid import at described fixed type biological reaction zone top and the water pipe that has a plurality of liquid spraying heads regularly spray nutrient solution to filler, excessive nutrient solution and water flow into gas-liquid separation zone from perforated plate, and discharge from the delivery port of gas-liquid separation zone bottom, or flow in the floated bio-reaction zone with the water inlet of circulating pump through floated bio-reaction zone, for the microorganism in the floated bio-reaction zone provides nutrition, excess liquid is discharged through the delivery port of floated bio-reaction zone.
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Cited By (6)
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CN102188898A (en) * | 2010-03-10 | 2011-09-21 | 中国科学院生态环境研究中心 | Combined biological deodorization integrated equipment and processing method of odorous gas |
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CN102188898A (en) * | 2010-03-10 | 2011-09-21 | 中国科学院生态环境研究中心 | Combined biological deodorization integrated equipment and processing method of odorous gas |
CN103601544A (en) * | 2013-11-22 | 2014-02-26 | 南开大学 | High-efficiency aerobic fermentation deodorization device and application |
CN103830986A (en) * | 2014-03-12 | 2014-06-04 | 南京航空航天大学 | Integrated dust removal-purification device and purification method of stationary diesel engine system |
CN111517458A (en) * | 2019-12-30 | 2020-08-11 | 安徽分创环保科技有限公司 | Centralized treatment device and treatment method for waste gas of sewage treatment plant |
CN113041789A (en) * | 2021-03-11 | 2021-06-29 | 黑龙江工业学院 | Formaldehyde removing device |
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