CN101429416B - Adhesion agent composition for environment-friendly water transfer printing volume label - Google Patents
Adhesion agent composition for environment-friendly water transfer printing volume label Download PDFInfo
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- CN101429416B CN101429416B CN200710166105.4A CN200710166105A CN101429416B CN 101429416 B CN101429416 B CN 101429416B CN 200710166105 A CN200710166105 A CN 200710166105A CN 101429416 B CN101429416 B CN 101429416B
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- ester
- acrylate
- methacrylate
- methacrylic acid
- vinylformic acid
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- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
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Abstract
The invention relates to an adhesive composition, which comprises acrylic polymer and a cross linker. The invention also relates to an environment-friendly water transfer printing label prepared by the composition, which only uses purified water at room temperature to activate the adhesive of the water transfer printing label during transfer printing, does not need to add any solvent, has favorable initial adhesive force, and keeps favorable transparency under high temperature treatment after the label is subjected to transfer printing.
Description
Technical field
The present invention relates to a kind of adhesion agent composition that comprises acrylate copolymer and linking agent, and utilize the prepared environment-friendly water transfer printing label of described composition.
Background technology
The production method of general water transfer label is to using the resinous polymer that screen painting mode has release effect by one deck to be coated on the paper or film as bottom lining layer; then with the mode of printing of half tone or lithographic plate, required ink logo is applied on described resinous polymer layer and forms ink layer; with printing process described above, tackiness agent is applied on described ink layer again, finally covers a separate-type paper to protect described tackiness agent.
The feature of water transfer label is to can be applicable to the body surface that shape is more complicated, irregular or volume is larger, has been widely used in the transfer printing of the products such as bicycle, golf club, pottery, toy.
According to prior art, the contained tackiness agent of water transfer label has different applicabilitys.World patent case discloses a kind of waterborne compositions for the manufacture of transfer printing stamp No. 02/051649, and described waterborne compositions can replace the solvent-based compositions of generally using and reduce and in manufacturing processed, discharge volatile organic compounds.Taiwan patent discloses provides a kind of composition of transfer film design for No. 200728103, and it adds and anti-ly after-tacks agent in right amount in specific component, makes transfer film can avoid pattern to stick damage at scroll bar or when overlapped.
Therefore the tackiness agent of tradition water transfer label can, in the process of transfer printing, must be elevated to water temperature more than 40 ℃ owing to storing and losing its viscosity for a long time, adds solvent with the tackiness agent of activated water transfer label in water simultaneously.In general, first water transfer label is immersed in to the several seconds in the cosolvent system that contains water and solvent (as 2-fourth oxyethanol), make to have resinous polymer swelling and the dissolving of release effect, again water transfer label is placed on the object of wanting transfer printing, press described label to get rid of unnecessary water and solvent, then remove bottom lining layer, the process of last drying again and sclerosis is to complete transfer printing.
Application product through transfer printing sometimes needs to pass through pyroprocessing in manufacturing processed again, as baking vanish, through the tackiness agent of transfer label because non-refractory produces yellow.
This case contriver finds, water transfer label of the present invention, in the process of transfer printing, only utilizes the pure water of room temperature to carry out the tackiness agent of activated water transfer label, need not add any solvent, there is good initial stage clinging power, and under pyroprocessing, also keep the good transparency through the label of transfer printing.
Summary of the invention
The object of this invention is to provide a kind of adhesion agent composition, it comprises:
(1) acrylate copolymer; With
(2) linking agent.
Another object of the present invention is to provide a kind of water transfer label, and it comprises
(a) bottom lining layer;
(b) be applied to the water-soluble polymers on described bottom lining layer;
(c) be applied to the ink layer on described water-soluble polymers; With
(d) be applied to the adhesion agent composition according to claim 1 on described ink layer.
Another object of the present invention is to provide a kind of water transfer label that can screen painting.
Accompanying drawing explanation
Fig. 1 represents the schematic diagram of water-transfer printing paper of the present invention.
Fig. 2 represents the better enforcement aspect schematic diagram of water-transfer printing paper of the present invention.
Embodiment
Be applicable to the acrylate copolymer as component (1) in adhesion agent composition of the present invention and comprise methyl acrylate, vinylformic acid, methacrylic acid, methyl methacrylate, ethyl propenoate, β-dimethyl-aminoethylmethacrylate, butyl acrylate, butyl methacrylate, isobutyl acrylate, Propenoic acid, 2-methyl, isobutyl ester, the just own ester of vinylformic acid, the just own ester of methacrylic acid, 2-EHA, ethylhexyl methacrylate, the positive heptyl ester of vinylformic acid, the positive heptyl ester of methacrylic acid, methacrylic acid 2-meptyl ester, Isooctyl acrylate monomer, Octyl methacrylate, Isooctyl methacrylate, methacrylic acid ester in the positive ninth of the ten Heavenly Stems, methacrylic acid ester in the different ninth of the ten Heavenly Stems, decyl-octyl methacrylate, isodecyl acrylate, isodecyl methacrylate, methacrylic dodecyl gallate, the different camphane ester of methacrylic acid, lauryl methacrylate(LMA), lauryl acrylate, tridecyl acrylate, methacrylic acid 13 esters, octadecyl acrylate, stearyl methacrylate, vinylformic acid methoxyl group ethyl ester, glytidyl methacrylate, methacrylic acid acetoacetyl 2-ethoxyethyl acetate, vinylformic acid acetoacetyl 2-ethoxyethyl acetate, methacrylic acid acetoacetyl oxygen propyl ester, vinylformic acid acetoacetyl oxygen propyl ester, diacetone acrylamide, acrylamide, Methacrylamide, hydroxyethyl methylacrylate, Hydroxyethyl acrylate, allyl methacrylate(AMA), Tetrahydrofurfuryl Methacrylate, vinylformic acid tetrahydrofuran (THF) methyl esters, cyclohexyl methacrylate, cyclohexyl acrylate, vinylformic acid 2-ethoxy ethyl ester, 2-ethoxyethyl methacrylate, isodecyl methacrylate, isodecyl acrylate, vinylformic acid 2-methoxyethoxy ester, methacrylic acid 2-methoxyethoxy ester, vinylformic acid 2-(2-ethoxy ethoxy) ethyl ester, vinylformic acid 2-ethyl phenoxy, methacrylic acid 2-ethyl phenoxy, the different camphane ester of vinylformic acid, the different camphane ester of methacrylic acid, vinylformic acid caprolactone, methacrylic acid caprolactone, polypropylene glycol one acrylate, polypropylene glycol monomethyl acrylate, polyoxyethylene glycol (400) acrylate, polyoxyethylene glycol (400) methacrylic ester, benzyl acrylate, benzyl methacrylate, vinyl cyanide or its mixture.
In the present composition, the content of acrylate copolymer, in integrally combined thing gross weight, for approximately 10.00 % by weight are to approximately 99.99 % by weight, better approximately 15.00 % by weight are to approximately 50.00 % by weight.
According to a specific embodiment of the present invention, acrylate copolymer used in the present invention is 2-EHA and acrylic acid mixture.According to the present invention, the weight ratio of described mixture is approximately 10 to approximately 99.
The component of the present composition (2) is linking agent.Aforesaid propylene acid polymer can be by comprising that the ordinary method of chemistry, ion, physics or induced emission method completes crosslinked.Details about the formula of these type adhesives can be seen in " Handbook of Pressure Sensitive Adhesive Technology; Second Edition; chapter 13 (D.Sataseditor, Van Nostrand Reinhold publisher, N.Y.) ".Being applicable to linking agent of the present invention comprises, but be not limited to, the functional group with carboxyl, hydroxyl, epoxy group(ing), allyl double bonds, acid amides, amine, isocyanic ester or its combination, is preferably 2 ethyl hexanoic acid chromium, trimeric cyanamide, saturated oiliness vibrin or isocyanic ester.
In the present composition, the content of linking agent, in integrally combined thing gross weight, for approximately 0.01 % by weight is to approximately 90.00 % by weight, better approximately 50.00 % by weight are to approximately 85.00 % by weight.
The present composition can at room temperature make by mixed composition (1) and (2), and preferably mixing temperature is 15 to 40 ℃.
Figure 1 shows that the specific embodiment of water transfer label of the present invention.Water transfer label 1 of the present invention is generally a kind of sandwich structure, and it comprises bottom lining layer 11, water-soluble polymers 12, ink layer 13 and adhesion agent composition 14.
Be applicable in water transfer label 1 of the present invention that bottom lining layer 11 as component (a) is preferably transparent or semitransparent paper or film comprises, for example, but be not limited to, by made lamination paper or films such as polyester, polyethylene, polyvinyl chloride, polypropylene, polymeric amide, cellulose acetates.
The component of water transfer label of the present invention (b) is water-soluble polymers 12.Be applicable to water-soluble polymers of the present invention and include, but not limited to derivatived cellulose, xanthan gum, gum arabic, gelatin, Yelkin TTS or its multipolymer.
The component of water transfer label of the present invention (c) is ink layer 13, and it can be used for showing the typographic(al) mark of figure, word, symbol or the numeral of identification of product, advertisement, warning, decoration or out of Memory.
Be applicable to comprising printing and applying and be with the conventional paint-on techniques such as painting such as spraying, pattern for spreading the method for described ink layer.Can realize ink layer printing by methods such as intaglio printing, lithography, letterpress, flexographic printing, the stippled printing of flexographic printing, laser printing and screen paintings.In addition, can print dissimilar ink.These comprise that one and two component ink, oxidation are dried and ultraviolet is dried ink, dissolved ink, disperse ink and 100% ink set.
The component of water transfer label of the present invention (d) is adhesion agent composition 14.The method that is suitable for spreading described adhesion agent composition comprises printing and applies and the conventional paint-on technique such as band painting such as spraying, pattern.Can realize adhesion agent composition printing with intaglio printing, lithography, flexographic printing and half-tone screen printing method.
In addition, Figure 2 shows that the preferred embodiment of water transfer label of the present invention, it comprises bottom lining layer 21, water-soluble polymers 22, polishes layer 23, ink layer 24 and adhesion agent composition 25.Wherein, the object of polishes layer 23 is to be applied to the ink layer 24 on described polishes layer in protection, with avoid ink layer 24 storing, transport, transfer printing or to add man-hour impaired.
According to preferred embodiment of the present invention, the adhesion agent composition using for the water transfer label of screen painting at room temperature has by approximately 1000 viscosity to about 5000cps, better approximately 2000 to about 4000cps viscosity; And described water transfer label has the initial stage clinging power by approximately 5 to approximately 50 grams/inch.
Water transfer label of the present invention may be used on the various substrate surfaces that surface can be greater than 37 dynes per centimeter, as polymeric material, sheet metal, coating or glass, is preferably polyethylene terephthalate, acrylic coating or aluminium foil.
The present invention will further be described in detail via the following example, only described narration is only in order to exemplary illustration the present invention, rather than the scope of the invention is imposed any restrictions, the modification that any those skilled in the art can carry out easily and change include in the scope of this case specification sheets disclosure and appended claims scope.
Embodiment
Example 1 to 11
Example 1 to 11 is to be mixed with according to detailed composition and the content shown in table 1 adhesion agent composition forming, and according to conventional methods example 1 to 11 adhesion agent composition is made to water transfer label with screen painting.Before testing, described water transfer label is infiltrated in the pure water of room temperature, after waiting label moistening, in water, take out and be placed into the substrate surface of wanting transfer printing, after light pressure, remove bottom lining layer, complete the transfer printing of label.Utilize the label assembly of above-mentioned transfer printing to carry out following every test.
Thermal stability testing method
The made water transfer label of example 1 to 5 adhesion agent composition is attached to the iron pipe surface of coated coating, and under the environment of 160 or 220 ℃ standing 30,60 or 180 minutes, the variation of its surface transparency observed.Acquired results is presented in table 2.
Initial stage clinging power test
The made water transfer label of example 10 adhesion agent compositions is attached to the iron pipe surface of coated coating, standard method of test A according to the pressure-sensitive adhesive tape described in ASTM (American Society for Testing and Materials) D3300, tests the label assembly of transfer printing.Acquired results is presented in table 3.
Hundred lattice (Cross-cut) test
The made water transfer label of example 1 to 11 adhesion agent composition is attached to the iron pipe surface of coated coating, standard method of test B according to described in ASTM (American Society for Testing and Materials) D3359, carries out hundred lattice adhesive tape tests to the label assembly of transfer printing.In addition, example 6 and the made water transfer label of 7 adhesion agent compositions are attached to polyethylene terephthalate film, aluminium foil and glass surface, according to aforesaid method, test.Acquired results is presented in table 4.
Hundred lattice tests (aging)
Example 4 and the made water transfer label of 5 adhesion agent compositions are attached to the iron pipe surface of coated coating, by the label assembly of transfer printing at 35 ℃ (95
) lower aging 7 days, and utilize every day aforesaid method to carry out hundred lattice adhesive tape tests.Acquired results is presented in table 5.
Table 1
Table 2
Table 3
Table 4
Table 5
Claims (12)
1. a water transfer label, it comprises:
(a) bottom lining layer;
(b) be applied to the water-soluble polymers on described bottom lining layer;
(c) be applied to the ink layer on described water-soluble polymers; With
(d) be applied to the adhesion agent composition on described ink layer, wherein said adhesion agent composition comprises:
(1) acrylate copolymer, it is to be selected from by polymerization the material that following material obtains: methyl acrylate, vinylformic acid, methacrylic acid, methyl methacrylate, ethyl propenoate, β-dimethyl-aminoethylmethacrylate, butyl acrylate, butyl methacrylate, isobutyl acrylate, Propenoic acid, 2-methyl, isobutyl ester, the just own ester of vinylformic acid, the just own ester of methacrylic acid, 2-EHA, ethylhexyl methacrylate, the positive heptyl ester of vinylformic acid, the positive heptyl ester of methacrylic acid, methacrylic acid 2-meptyl ester, Isooctyl acrylate monomer, Octyl methacrylate, Isooctyl methacrylate, methacrylic acid ester in the positive ninth of the ten Heavenly Stems, methacrylic acid ester in the different ninth of the ten Heavenly Stems, decyl-octyl methacrylate, isodecyl acrylate, isodecyl methacrylate, methacrylic dodecyl gallate, the different camphane ester of methacrylic acid, lauryl methacrylate(LMA), lauryl acrylate, tridecyl acrylate, methacrylic acid 13 esters, octadecyl acrylate, stearyl methacrylate, vinylformic acid methoxyl group ethyl ester, glytidyl methacrylate, methacrylic acid acetoacetyl 2-ethoxyethyl acetate, vinylformic acid acetoacetyl 2-ethoxyethyl acetate, methacrylic acid acetoacetyl oxygen propyl ester, vinylformic acid acetoacetyl oxygen propyl ester, diacetone acrylamide, acrylamide, Methacrylamide, hydroxyethyl methylacrylate, Hydroxyethyl acrylate, allyl methacrylate(AMA), Tetrahydrofurfuryl Methacrylate, vinylformic acid tetrahydrofuran (THF) methyl esters, cyclohexyl methacrylate, cyclohexyl acrylate, vinylformic acid 2-ethoxy ethyl ester, 2-ethoxyethyl methacrylate, isodecyl methacrylate, isodecyl acrylate, vinylformic acid 2-methoxyethoxy ester, methacrylic acid 2-methoxyethoxy ester, vinylformic acid 2-(2-ethoxy ethoxy) ethyl ester, vinylformic acid 2-ethyl phenoxy, methacrylic acid 2-ethyl phenoxy, the different camphane ester of vinylformic acid, the different camphane ester of methacrylic acid, vinylformic acid caprolactone, methacrylic acid caprolactone, polypropylene glycol one acrylate, polypropylene glycol monomethyl acrylate, polyoxyethylene glycol (400) acrylate, polyoxyethylene glycol (400) methacrylic ester, benzyl acrylate, benzyl methacrylate, vinyl cyanide and its mixture,
(2) linking agent.
2. water transfer label according to claim 1, it further comprises the polishes layer applying between between described water-soluble polymers and described ink layer.
3. water transfer label according to claim 1 and 2, wherein said water-soluble polymers is the group that selects free derivatived cellulose, xanthan gum, gum arabic, gelatin, Yelkin TTS and its multipolymer to form.
4. water transfer label according to claim 1 and 2, it is to be applied to have the base material that surface can be greater than 37 dynes per centimeter.
5. water transfer label according to claim 4, wherein said base material is formed by the polymeric material of at least one, sheet metal, coating and glass.
6. water transfer label according to claim 5, wherein said base material is polyethylene terephthalate.
7. water transfer label according to claim 5, wherein said base material is aluminium foil.
8. a water transfer label that can screen painting, it comprises:
(a) bottom lining layer;
(b) be applied to the water-soluble polymers on described bottom lining layer;
(c) be applied to the ink layer on described water-soluble polymers; With
(e) be applied to the adhesion agent composition on described ink layer, wherein said adhesion agent composition comprises:
(1) acrylate copolymer, it is to be selected from by polymerization the material that following material obtains: methyl acrylate, vinylformic acid, methacrylic acid, methyl methacrylate, ethyl propenoate, β-dimethyl-aminoethylmethacrylate, butyl acrylate, butyl methacrylate, isobutyl acrylate, Propenoic acid, 2-methyl, isobutyl ester, the just own ester of vinylformic acid, the just own ester of methacrylic acid, 2-EHA, ethylhexyl methacrylate, the positive heptyl ester of vinylformic acid, the positive heptyl ester of methacrylic acid, methacrylic acid 2-meptyl ester, Isooctyl acrylate monomer, Octyl methacrylate, Isooctyl methacrylate, methacrylic acid ester in the positive ninth of the ten Heavenly Stems, methacrylic acid ester in the different ninth of the ten Heavenly Stems, decyl-octyl methacrylate, isodecyl acrylate, isodecyl methacrylate, methacrylic dodecyl gallate, the different camphane ester of methacrylic acid, lauryl methacrylate(LMA), lauryl acrylate, tridecyl acrylate, methacrylic acid 13 esters, octadecyl acrylate, stearyl methacrylate, vinylformic acid methoxyl group ethyl ester, glytidyl methacrylate, methacrylic acid acetoacetyl 2-ethoxyethyl acetate, vinylformic acid acetoacetyl 2-ethoxyethyl acetate, methacrylic acid acetoacetyl oxygen propyl ester, vinylformic acid acetoacetyl oxygen propyl ester, diacetone acrylamide, acrylamide, Methacrylamide, hydroxyethyl methylacrylate, Hydroxyethyl acrylate, allyl methacrylate(AMA), Tetrahydrofurfuryl Methacrylate, vinylformic acid tetrahydrofuran (THF) methyl esters, cyclohexyl methacrylate, cyclohexyl acrylate, vinylformic acid 2-ethoxy ethyl ester, 2-ethoxyethyl methacrylate, isodecyl methacrylate, isodecyl acrylate, vinylformic acid 2-methoxyethoxy ester, methacrylic acid 2-methoxyethoxy ester, vinylformic acid 2-(2-ethoxy ethoxy) ethyl ester, vinylformic acid 2-ethyl phenoxy, methacrylic acid 2-ethyl phenoxy, the different camphane ester of vinylformic acid, the different camphane ester of methacrylic acid, vinylformic acid caprolactone, methacrylic acid caprolactone, polypropylene glycol one acrylate, polypropylene glycol monomethyl acrylate, polyoxyethylene glycol (400) acrylate, polyoxyethylene glycol (400) methacrylic ester, benzyl acrylate, benzyl methacrylate, vinyl cyanide and its mixture,
(2) linking agent.
9. water transfer label according to claim 8, it further comprises the polishes layer applying between between described water-soluble polymers and described ink layer.
10. water transfer label according to claim 8 or claim 9, wherein said adhesion agent composition has by 1000 to 5000cps viscosity.
11. water transfer labels according to claim 10, wherein said adhesion agent composition has by 2000 to 4000cps viscosity.
12. water transfer labels according to claim 8 or claim 9, it has the initial stage clinging power by 5 to 50 grams/inch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710166105.4A CN101429416B (en) | 2007-11-07 | 2007-11-07 | Adhesion agent composition for environment-friendly water transfer printing volume label |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710166105.4A CN101429416B (en) | 2007-11-07 | 2007-11-07 | Adhesion agent composition for environment-friendly water transfer printing volume label |
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| Publication Number | Publication Date |
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| CN101429416A CN101429416A (en) | 2009-05-13 |
| CN101429416B true CN101429416B (en) | 2014-07-16 |
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| CN200710166105.4A Expired - Fee Related CN101429416B (en) | 2007-11-07 | 2007-11-07 | Adhesion agent composition for environment-friendly water transfer printing volume label |
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| CN102746722B (en) * | 2011-04-19 | 2015-01-21 | 顺安涂布科技(昆山)有限公司 | Composition for treating polyethylene (PE) film surface and PE film label |
| CN102140277A (en) * | 2011-04-25 | 2011-08-03 | 王泝舟 | Baking-curing high hardness water transfer printing ink without adopting varnish protection and printing process |
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| CN102964762A (en) * | 2011-09-02 | 2013-03-13 | 田菱精细化工（昆山）有限公司 | High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing |
| JP5891556B2 (en) * | 2011-10-19 | 2016-03-23 | 株式会社ユポ・コーポレーション | Water activated sheet, water activated label using the same sheet, method for producing the same label, label sticking device using the same label, and adherend with the same label |
| JP5770607B2 (en) * | 2011-11-21 | 2015-08-26 | 藤森工業株式会社 | Adhesive composition and surface protective film |
| CN102660206A (en) * | 2012-04-09 | 2012-09-12 | 番禺南沙殷田化工有限公司 | Optically-transparent adhesive composition and preparation method thereof |
| US9127188B2 (en) | 2012-12-27 | 2015-09-08 | Cheil Industries, Inc. | Adhesive film and optical display including the same |
| CN104163883A (en) * | 2014-07-31 | 2014-11-26 | 桐乡市正大涂料有限公司 | Resin for printing ink at 200 DEG C and preparation method thereof |
| CN104789134A (en) * | 2015-05-08 | 2015-07-22 | 南通长航船舶配件有限公司 | Automatic control cabinet for ship |
| CN104974310B (en) * | 2015-06-12 | 2017-09-05 | 长沙市汇华胶粘剂科技有限公司 | A kind of Decal peelable film oil resin and preparation method thereof |
| CN105153977A (en) * | 2015-10-23 | 2015-12-16 | 蓝星（成都）新材料有限公司 | Environment-friendly pressure-sensitive adhesive and preparation method thereof |
| CN106397718A (en) * | 2016-06-23 | 2017-02-15 | 汕头市东田转印有限公司 | UV resin capable of being dried by heating, a preparing process thereof and applications of the resin |
| DE102017109074A1 (en) * | 2017-04-27 | 2018-10-31 | Herma Gmbh | Activatable adhesive label |
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Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060234014A1 (en) * | 2005-04-14 | 2006-10-19 | Liu Yaoqi J | Patterned adhesives for tamper evident feature |
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