CN101426584A - Method and unit for the extremely fine dispersal and discharge of an irritant or warfare agent - Google Patents
Method and unit for the extremely fine dispersal and discharge of an irritant or warfare agent Download PDFInfo
- Publication number
- CN101426584A CN101426584A CNA2006800541114A CN200680054111A CN101426584A CN 101426584 A CN101426584 A CN 101426584A CN A2006800541114 A CNA2006800541114 A CN A2006800541114A CN 200680054111 A CN200680054111 A CN 200680054111A CN 101426584 A CN101426584 A CN 101426584A
- Authority
- CN
- China
- Prior art keywords
- stimulant
- gas
- war agent
- war
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/14—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means with multiple outlet openings; with strainers in or outside the outlet opening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/26—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/26—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device
- B05B7/262—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device a liquid and a gas being brought together before entering the discharge device
- B05B7/267—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device a liquid and a gas being brought together before entering the discharge device the liquid and the gas being both under pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H9/00—Equipment for attack or defence by spreading flame, gas or smoke or leurres; Chemical warfare equipment
- F41H9/04—Gas-blowing apparatus, e.g. for tear gas
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Catching Or Destruction (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nozzles (AREA)
- Air Bags (AREA)
Abstract
Method and unit for the dispersal and discharge of an irritant or warfare agent. With the invention, solid and liquid warfare agents and irritants are sprayed in large indoor and outdoor areas by means of a propellant gas (1) via a system of lines (3 to 9). The substances are transported in liquid form in liquefied gas solutions, or liquid gas emulsions, to their outlet openings (10 to 15) and emerge with the kinetic energy of a liquid, in order to disperse the irritant or warfare agent extremely finely by evaporation and the accompanying expansion of the liquefied gas.
Description
The present invention relates to be used for by pipe-line system war agent solid-state and liquid state or stimulant being distributed in subtly a kind of method and a kind of equipment of big room area or outdoor area for people's defence.
Background technology
Known stimulant and war agent sprinkling equipment use boost gas, and propane/butane mix for example is perhaps by known boost gas R 134 A of sprayer, so that stimulant and war agent are extruded from tank.
In this process, boost gas evaporation, and near discharge near tank perhaps are directed to outlet as gas.
Discharge on tank is because the jet length of each tank only allows limited spray regime.With regard to follow-up pipeline, boost gas absorbs energy from tank and valve and pipeline for its evaporation and heating, thereby can only have very short release at interval, to avoid icing.The usefulness of this equipment is confined to few relatively burst size.
Contain war agent or stimulant boost gas follow-up pipeline since war agent or stimulant in pipeline deposition and because gas is flowed through the less throughput of pipe-line system and very limited.
Be used to distribute with regard to the follow-up pipeline of admixture with regard to gas and release portion thereof, another shortcoming be gas with the proportional little kinetic energy in follow-up pipeline surface, this can be because of surrounding air causes very strong eddy current and causes deceleration thus, and wherein determined admixture distribution precision is inaccuracy very.For example can produce the droplet that condenses.
Because admixture deposition and these two kinds of physical characteristics of air whirl, the use length of known pipeline compartment system (depending on gas and pressure) is extremely limited, and it is also very short to discharge coverage.
Therefore, DE 44 24 772 A1 have put down in writing a kind of irritative gas spraying equipment that is used for warning system automatically, wherein mechanically open bottle, thereby irritative gas are discharged to the surrounding air directly from this bottle.Be not provided with the follow-up pipeline of gas.
Utility model document DE 202 01 265 U1 have put down in writing a kind of automatic CS gas atomization mechanism, and wherein irritative gas, and is discharged to the irritative gas mixture in the surrounding air by air blast via short nozzle ejection from tank.Therefore this equipment also be not suitable in big room area and the distribution in the outdoor area.
Equally, at utility model document DE 299 23948 U1 that record the device that is used for preventing the criminal, irritative gas directly is discharged to the surrounding air from the deposit bottle.
A kind of propellant compartment system that is used at the medicament of the sprinkling in big space has been proposed in EP 0524313 B1.In this solution, the boosting medium is pressed into the pipeline that is used for distributing with being gaseous state equally, to such an extent as to can not realize coverage far away at the injection nozzle place, this is undesirable equally certainly.
At last, EP 0425300 B1 has put down in writing a kind of quantitative and discharge system that is used for additive spray (insecticide).Boosting medium (preferably carbon dioxide) will enter into pipe-line system with liquid state, and mix with additive by mixed circuit.
Boost gas is carried continuously under liquid state via system and still can't be realized.Because the pressure in the sampling cylinder reduces widely, pipeline just freezes immediately before the build-up pressure balance.The throttle point that inserts not only can cause this problem, and it can additionally reduce exhaust energy.In addition, all the additive of amount must be mixed before being expelled to environment.
Summary of the invention
The objective of the invention is, proposition is used for meticulous distribution and discharges stimulant or a kind of method and a kind of equipment of war agent, even wherein also can realize coverage far away in the open by means of boost gas, realize the meticulous distribution of stimulant and war agent, so that can add minimum active principle to a large amount of air, even pipeline can not produce the pressure reduction than long yet, even and discharge icing than the long pipeline of yet can avoiding at interval.
This purpose is achieved with the equipment with feature of claim 11 according to the method for the feature with claim 1.Useful improvement and design are the themes of dependent claims.
By the present invention, war agent solid-state and liquid state and stimulant can spray with coverage far away in big room area or outdoor area by pipe-line system, its mode is, stimulant or war agent form with liquid state in boost gas solution that liquefies or liquid gas emulsion are delivered to its outlet, the kinetic energy that utilizes liquid is then discharged from outlet or injection nozzle, stimulant or war agent so that the evaporation of the gas by liquefaction and the expansion followed distribute subtly.
Meticulous distribution is following distribution: wherein the size of this droplet is under the value that is commonly referred to mist.
For stimulant and war agent are incorporated in the liquid boost gas, stimulant or war agent must be dissolved in the gas of liquefaction in advance or be dissolved in the solvent, and solvent is dissolved in again in the gas of liquefaction.But also can mix itself insoluble stimulant or war agent with emulsion form.
For stimulant or war agent with liquid state are mixed in the boost gas that is in liquid state, be provided with blender, this blender form with metering when equipment starts is added stimulant or war agent in the liquid boost gas to.
Can be by spraying into pump or utilizing another liquid that is dissolved with stimulant or war agent that is under the pressure to mix.
The size of the pipeline cross section of blender and whole pipe-line system should make and pressure drop can not occur, also can not occur pipeline thus and freeze.
In order not produce pressure drop, premature evaporation can not occur thus, and can not occur pipeline yet and freeze, the pipeline cross section narrows down than the initial cross section from the pipeline of pressurization-gas cascade input towards the direction of injection nozzle.That is to say that the size of all distribution mechanism and branch should make that all the intake line cross section equals the summation of follow-up pipeline cross section at least.Guarantee to produce the dynamic head of the evaporation that can prevent to form undesirable bubble thus and guarantee that liquid neither can produce eddy current and also can not gasify during it is delivered to injection nozzle.Just producing the injection mist after the nozzle ejection, the stimulant utilization is sprayed mist and is distributed in the surrounding air subtly.
By making environment temperature very high about the evaporating temperature of the boost gas of liquid state, can realize contacting with the direct of big surface between the boost gas of liquid state and the surrounding air that is used to heat, it is attended by strong energy exchange.Stimulant or war agent are at the injection nozzle of liquid gas beam on the whole length of liquid gas beam of ejection carries out the evaporation and the meticulous distribution of burst type by high-intensity heating.
The stimulant cloud of the generation like this of liquid gas beam or war agent cloud are thrown in the space out and away owing to their high liquid kinetic energy (initial kinetic energy).
By towards the injection nozzle narrowed cross-section, the evaporation of the boost gas of the liquid state that causes owing to previous pressure drop is prevented.
Because the kinetic energy of boost gas greater than liquid or greater than liquid mist, is compared realization discharge distance far away with the gas conveying with less kinetic energy.By the evaporation of the burst type of liquid gas in surrounding air freely, stimulant or war agent are distributed with expansive force by the high energy exchange in surrounding air is snobbish.
The specific embodiment
To contrast accompanying drawing 1 and describe the preferred embodiments of the present invention in detail.
Block diagram shown in Figure 1 illustrates stimulant or war agent distribution apparatus, and wherein the pipe- line system 3,4,5,6,7,8,9 by branch flows to a plurality of injection nozzles 10 to 15 with stimulant or war agent from tank 2.Be provided with two groups of injection nozzles 10,11,12 and 13,14,15 in this embodiment.These groups can trigger by 2/2 reversal valve 19,20 selectively.
By 2/2 reversal valve 18, liquid boost gas is pressed into the pipeline 3 from liquefied gas cylinder 1, and flows to blender 16.At the inlet of blender 16, at branch point 21, a part of boost gas is used for being branched at the check-valves 22 that stimulant container 2 pressure are set up via pipeline 4 from pipeline 3.Check-valves 22 is used for making and can reflux for essential boosting dielectric gas the pressure of stimulant or war agent container 2 is set up.
Be subjected to 2/2 reversal valve 17 and pressure limiting valve 23 controls, boost gas pressure is pressed into liquid irritative gas in the blender 16 via pipeline 5.In order effectively stimulant or war agent to be mixed with boost gas, at the inlet of pipeline 3, in blender 16, be provided with the decompression nozzle, this decompression nozzle reduces the size of pressure, as in point 21 place branches.
The following in the present embodiment structure of this equipment: perhaps the nozzle sets 13,14,15 on You Bian the nozzle sets 10,11,12 or the left side can trigger.For this reason, must simultaneously valve 17,18,19 or valve 17,18,20 be opened.
By to this set of pipeline 3 to 9 and corresponding size design, boost gas can be fed to injection nozzle 10 to 15 with the form of liquid state from stimulant or war agent container 2 from boost gas bottle 1 and stimulant or war agent.Because the Incoercibility of liquid is not so produce the pressure loss.
[reference numerals list]
1 is used for the gas bottle of boost gas, pressurization-gas cascade
2 stimulants or war agent container
3 boost gas transfer pipelines
4 boost gas branch lines
5 irritative gas transfer pipelines
6 lead to the pipeline of left side valve group
7 lead to the pipeline of the right valve group
8 lead to the pipeline of left side injection nozzle
9 lead to the pipeline of the right injection nozzle
10 injection nozzles
11 injection nozzles
12 injection nozzles
13 injection nozzles
14 injection nozzles
15 injection nozzles
16 blenders
17 2/2 reversal valves
18 2/2 reversal valves
19 2/2 reversal valves
20 2/2 reversal valves
21 mixed circuit branch points
22 check-valves
23 pressure limiting valves
24 mixed circuits
Claims (17)
1. be used to distribute and discharge the method for stimulant or war agent, wherein spray described stimulant or war agent, it is characterized in that by boost gas,
-described boost gas form with liquid state from deposit pressure vessel (1) is removed, and is continued to carry by pipeline (3-9), thereby the amount that is used to spray of taking-up is dispensed on proportional a plurality of injection nozzles of quantity (10-15) with the pipeline (3-9) of branch from described deposit pressure vessel (1);
-be distributed to described injection nozzle (10-15) before, in the boost gas of described liquid state, mix the stimulant or the war agent that exist with liquid form;
-for described stimulant or war agent are distributed in the surrounding air subtly, utilize liquid gas in (10 to 15) evaporation of locating of described injection nozzle and the expansion of following.
2. the method for claim 1 is characterized in that, described stimulant or war agent are dissolved in the gas of liquefaction.
3. the method for claim 1 is characterized in that, described stimulant or war agent dissolving ground are present in the solvent.
4. as claim 2 and 3 described methods, it is characterized in that the stimulant of described liquefaction or war agent are dissolved in the gas of liquefaction.
5. method as claimed in claim 4 is characterized in that, insoluble stimulant or war agent are added in the gas of liquefaction by solvent as emulsion.
6. the method for claim 1 is characterized in that, when causing course of injection, with the form of liquid state described stimulant or war agent metering ground is added in the boost gas that is in liquid state.
7. method as claimed in claim 6 is characterized in that, a part of boost gas is used to metering ground as the boosting medium and adds described stimulant or war agent.
8. method as claimed in claim 6 is characterized in that, described stimulant or war agent spray into by pump.
9. the method for claim 1 is characterized in that, environment temperature is with respect to the evaporating temperature height of the boost gas of described liquid state, thereby is in stimulant in the described boost gas or war agent in order to ensure distributing subtly and carries out the evaporation of burst type.
10. the method for claim 1 is characterized in that, utilizes big kinetic energy, and described boost gas is located to penetrate as the liquid beam at described injection nozzle (10-15), and immediately expands.
11. an equipment is used to utilize the pipe-line system (3-9) of boost gas by branch that stimulant or war agent are distributed and is expelled to a plurality of injection nozzles (10-15), it is characterized in that,
-described boost gas from pressurization-gas cascade (1), and described stimulant and war agent from stimulant bottle (2), under liquid state, can be fed to described pipe-line system (3-9), and can carry by described pipe-line system (3-9);
The cross section of-pipeline (6-9) narrows down towards described injection nozzle (10-15) from described pressurization-gas cascade (1), is used to realize dynamic head;
-be provided with for introduction into the blender the described boost gas (16) at pipeline (3) from described pressurization-gas cascade (1) input.
12. equipment as claimed in claim 11 is characterized in that, the cross section of locating at described boost gas bottle (1) of described intake line (3) equals the summation of the cross section (3-9) of follow-up pipeline at least.
13. equipment as claimed in claim 11 is characterized in that, the amount of stimulant that exists with liquid form or war agent is controllable.
14. as claim 11 and 13 described equipment, it is characterized in that,, be provided with and spray into pump for described stimulant or war agent are incorporated in the described boost gas.
15. as claim 11 and 13 described equipment, it is characterized in that,, be provided with the mixed circuit (24) that has 2/2 reversal valve (17) and pressure limiting valve (23) in order to introduce and control the stimulant and the war agent of carrying from described stimulant bottle (2).
16. equipment as claimed in claim 11 is characterized in that, described stimulant or war agent are dissolved in the solvent, and described dissolution with solvents is in the gas of liquefaction.
17. equipment as claimed in claim 11 is characterized in that, insoluble stimulant or war agent are added in the gas of liquefaction by solvent as emulsion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006016286A DE102006016286B4 (en) | 2006-04-03 | 2006-04-03 | Method and system for distributing and discharging a stimulant or warfare agent |
| DE102006016286.2 | 2006-04-03 | ||
| PCT/DE2006/002296 WO2007112709A1 (en) | 2006-04-03 | 2006-12-18 | Method and unit for the extremely fine dispersal and discharge of an irritant or warfare agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101426584A true CN101426584A (en) | 2009-05-06 |
| CN101426584B CN101426584B (en) | 2013-02-06 |
Family
ID=38513361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200680054111.4A Expired - Fee Related CN101426584B (en) | 2006-04-03 | 2006-12-18 | Method and unit for the dispersal and discharge of an irritant or warfare agent |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2001599B1 (en) |
| CN (1) | CN101426584B (en) |
| AT (1) | ATE529191T1 (en) |
| DE (1) | DE102006016286B4 (en) |
| RU (1) | RU2418638C2 (en) |
| WO (1) | WO2007112709A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102209877B (en) * | 2008-09-08 | 2015-01-28 | 卡尔-海因茨·德尔格 | Device and method for distributing irritants or warfare agents |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007021267B4 (en) | 2007-05-03 | 2012-07-05 | Hans-Joachim Schubert | Method and system for metered release of irritants by means of a propellant in rooms for personal defense |
| DE102007027412B4 (en) * | 2007-06-11 | 2011-07-21 | Dräger, Karl-Heinz, 10117 | Method and device for delivering irritants and warfare agents |
| DE102008013291B4 (en) * | 2008-03-07 | 2010-06-10 | FÜRUS, Sven | Marine's security system |
| DE102008027145A1 (en) * | 2008-06-02 | 2009-12-03 | Carl Hoernecke Chem. Fabrik Gmbh & Co. Kg | Non-lethal self-defense device for use with robot in e.g. aircraft, has functional module comprising pressure vessel, and control device detached from functional module for controlling actuator, which is energized by energy storage |
| DE102009019672B4 (en) * | 2009-04-30 | 2012-05-31 | Krauss-Maffei Wegmann Gmbh & Co. Kg | Device for protecting an object or vehicle, in particular a military or police vehicle |
| FR2949749A1 (en) * | 2009-09-09 | 2011-03-11 | Rodellec Du Porzic Marc Etienne Anne Ignace Mar De | DEVICE FOR THE PROTECTION OF SHIPS AND MARITIME FACILITIES AGAINST PIRACY ACTS |
| RU2526326C2 (en) * | 2012-08-16 | 2014-08-20 | Федеральное государственное бюджетное учреждение "Всероссийский научно-исследовательский институт по проблемам гражданской обороны и чрезвычайных ситуаций МЧС России" (федеральный центр науки и высоких технологий) | Method for water transport facilities protection against terrorists and device for this method implementation |
| CN102765479B (en) * | 2012-08-20 | 2014-09-03 | 山东中泰新能源集团有限公司 | Aviation aircraft hijacking prevention system and method |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2161378A1 (en) * | 1971-12-10 | 1973-06-14 | Viktor Eckermann | ROOM PROTECTION DEVICE |
| AU2842284A (en) * | 1983-05-19 | 1984-11-22 | Donald James Catchpoole | Spray apparatus |
| USH109H (en) * | 1984-02-06 | 1986-08-05 | The United States Of America As Represented By The Secretary Of The Army | Smoke generator |
| DE3517134A1 (en) * | 1985-05-11 | 1986-11-13 | Busemaä 4000 Düsseldorf Gabrit | Method and device for securing enclosed spaces or fenced-off free areas against entry by unauthorised persons |
| DE3921255A1 (en) * | 1989-06-29 | 1991-01-03 | Krebsoege Gmbh Sintermetall | METHOD FOR GENERATING A LIQUID MIST PROBABLE IN A CARRIER GAS FLOW AND DEVICE FOR CARRYING OUT THE METHOD |
| US5020689A (en) * | 1989-10-27 | 1991-06-04 | The Wellcome Foundation Limited | Metering and dispensing system |
| DE9014590U1 (en) * | 1990-10-22 | 1991-01-17 | Hofen, Florian von, 3000 Hannover | Evaporator fog machine |
| DK0524313T3 (en) * | 1991-02-01 | 1998-08-24 | Roussel Uclaf | Method of dosing and discharging an active ingredient and apparatus for carrying out the process |
| DE4424772A1 (en) * | 1993-07-12 | 1995-03-09 | Wolfgang Wenzel | Automatic irritant-gas spraying installation for alarm-installation systems |
| US5364030A (en) * | 1993-07-29 | 1994-11-15 | Murdock James L | Solution injector for underground sprinkler systems |
| JPH09147254A (en) * | 1995-11-24 | 1997-06-06 | Sanwa Kiko:Kk | Spraying device for crime prevention |
| CN2305646Y (en) * | 1997-01-17 | 1999-01-27 | 马水旺 | Anti-riot ejector |
| DE19711855C5 (en) * | 1997-03-21 | 2005-02-24 | Wilfried Wiegers | Device for discharging a substance dissolved or finely distributed in a liquid |
| DE19909144A1 (en) * | 1999-03-03 | 2000-09-14 | Daimler Chrysler Ag | Car protecting device for use by police, frontier guards and military comprises container containing smoke generating composition, smoke being led through system of pipes and emerging through outlets along bottom edges of car body |
| AT407619B (en) * | 1999-04-30 | 2001-05-25 | Voest Alpine Ind Anlagen | METHOD FOR DISTRIBUTING A FINE SPRAYED LIQUID, AND DEVICE THEREFOR |
| DE29923948U1 (en) * | 1999-09-27 | 2001-07-12 | Fladung, Peter, 26316 Varel | Device for inhibiting offenders, preferably to supplement an alarm system |
| DE10013150A1 (en) * | 2000-03-17 | 2001-10-04 | Wilfried Wiegers | Device for discharging a swirled mixture from a liquid, to which an active ingredient may have been added, and gas |
| DE20201265U1 (en) * | 2001-09-11 | 2002-06-13 | Gehrmann, Klaus, 39291 Lostau | Automatic alarm system with CS gas nebulization and circuitry to control the system |
| US6696928B1 (en) * | 2001-10-22 | 2004-02-24 | Birinder R. Boveja | Method and system for countering hostile activity aboard an airplane |
| DE10207823A1 (en) * | 2002-02-25 | 2003-09-04 | Joerg Bader | Safety device for a means of transport and stunning device |
| CN2526774Y (en) * | 2002-03-22 | 2002-12-18 | 马水旺 | Violence prevention jetting self-defense device |
| FR2859397B1 (en) * | 2003-09-10 | 2006-07-28 | Eisenmann France Sarl | POWER PLANT FOR AN ELECTROSTATIC POWDERING FACILITY |
-
2006
- 2006-04-03 DE DE102006016286A patent/DE102006016286B4/en not_active Expired - Fee Related
- 2006-12-18 RU RU2008143378/05A patent/RU2418638C2/en not_active IP Right Cessation
- 2006-12-18 CN CN200680054111.4A patent/CN101426584B/en not_active Expired - Fee Related
- 2006-12-18 WO PCT/DE2006/002296 patent/WO2007112709A1/en active Application Filing
- 2006-12-18 AT AT06828722T patent/ATE529191T1/en active
- 2006-12-18 EP EP06828722A patent/EP2001599B1/en not_active Not-in-force
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102209877B (en) * | 2008-09-08 | 2015-01-28 | 卡尔-海因茨·德尔格 | Device and method for distributing irritants or warfare agents |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2001599A1 (en) | 2008-12-17 |
| DE102006016286A1 (en) | 2007-10-11 |
| WO2007112709A1 (en) | 2007-10-11 |
| CN101426584B (en) | 2013-02-06 |
| EP2001599B1 (en) | 2011-10-19 |
| RU2418638C2 (en) | 2011-05-20 |
| ATE529191T1 (en) | 2011-11-15 |
| RU2008143378A (en) | 2010-05-10 |
| DE102006016286B4 (en) | 2009-03-12 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
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