CN101397198A - Composite blending material for concrete and preparation method thereof - Google Patents

Composite blending material for concrete and preparation method thereof Download PDF

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Publication number
CN101397198A
CN101397198A CNA2008102019721A CN200810201972A CN101397198A CN 101397198 A CN101397198 A CN 101397198A CN A2008102019721 A CNA2008102019721 A CN A2008102019721A CN 200810201972 A CN200810201972 A CN 200810201972A CN 101397198 A CN101397198 A CN 101397198A
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concrete
composite
fly ash
cement
flyash
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Inventor
杨佳俊
陆文雄
曹栋樑
李小亮
庄燕
周海文
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Shanghai Haili Industry & Trading Co Ltd
University of Shanghai for Science and Technology
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Shanghai Haili Industry & Trading Co Ltd
University of Shanghai for Science and Technology
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Priority to CNA2008102019721A priority Critical patent/CN101397198A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0079Rheology influencing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/46Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/22Carbonation resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to a composite admixture used in concrete that incineration fly ash of urban living garbage, fly ash, slag powder and natural mineral powder are taken as the main raw materials and a preparation method thereof, and pertains to the technical field of building material preparation technique. The composition and weight percent of the composite admixture in the invention are: incineration fly ash, 10-30%; fly ash, 20-40%; slag powder, 30-50%; and natural mineral powder, 5-15%. The composite admixture of the invention can replace 30-50% of use volume of the cement in concrete; the prepared concrete can not only improve the grade of the grains of the concrete system, but also improve fluidity, cohesiveness and moisture capacity of concrete mixture, and can improve slump constant, anti-sulfate performance and anti-carbonization performance of the concrete; and the durability performance of the concrete can also be improved. The waste such as incineration fly ash, industrial slag, and the like, can be recycled, thus being in favor of environmental protection, and saving cement, sources and energy.

Description

Composite blending material for concrete and preparation method thereof
Technical field
The present invention relates to a kind of is the composite blending material for concrete of main raw material with fly ash from burning city domestic garbage, flyash, slag micropowder, natural ore powder, belongs to material of construction fabricating technology field.
Background technology
Along with the quickening of urban construction, also increasing to concrete demand and consumption, concrete has become one of manufactured construction materials of contemporary consumption maximum.And in concrete several starting material, cement is again an indispensable part.Utilizing industrial residue and solid waste to prepare composite blending material for concrete, in order to replace a part of cement in the concrete, is the needs of useless admittedly resource utilization and recycling economy, also is the needs of concrete material scientific development.
Fly ash from burning city domestic garbage and cement are more approaching on main chemical compositions, and its main chemical compositions is: SiO 2, CaO, Al 2O 3, Fe 2O 3Deng.The flying ash fine particles, specific surface area is big, is alkalescence, has gelation activity, can be used as the feedstock production composite blending material for concrete, substitutes a part of cement.Simultaneously, China's burning city domestic garbage facture is obtaining application more and more widely, with regard to Shanghai, Pudong drives and handles the domestic refuse ability bridge garbage burning factory day about 1000 tons, handle the domestic refuse ability Xijiang River, Pu bridge rubbish factory's day about 1500 tons, the ignorant bridge garbage burning factory of planning to build and the day output of north suburb garbage burning factory are all about 500 tons.If have 2%~4% flying dust to generate by burning 1 ton of domestic refuse, then four factories operate simultaneously then that flying dust output has 100~180 tons every day, and year output reaches 4~60,000 tons.It is strong to burn a large amount of flying dust contaminatives that produce, and must deal carefully with.Flying dust mainly shows Organic pollutants such as heavy metal contamination, dissolved salt pollution and dioxin to the harm of environment.Harmless treatment requirement to flying dust, through carrying out landfill after the curing/stabilizing, yet arrange the processing costs of landfill very high, the disposing capacity of landfill yard is also limited, and the processing power of existing flying dust security landfill has been difficult to adapt to the quick growth of incineration of refuse flyash.Therefore,, seek the approach of suitable incineration of refuse flyash resource utilization, become the task of top priority that solves flying dust according to the theory of recycling economy.Is incineration of refuse flyash flying dust resource utilization approach preferably as one of raw material preparation composite blending material for concrete, can minimizing, resource utilization, harmless treatment flying dust, from environment, technology, economic dispatch angle flying dust is carried out stabilization treatment and recycling.
Another big source of pollution---industrial residue (flyash, slag) after treatment as active admixture, not only helps the concrete hydrating effect, strengthen degree of compactness and workability, lower porosity, improve concrete pore structure, and bigger effect is all arranged improving concrete durability.
Therefore, it is main raw material with fly ash from burning city domestic garbage, flyash, slag micropowder, natural ore powder etc. that the researchist invents a kind of, and the preparation composite blending material for concrete is produced concrete in order to a part of cement in the replacement concrete.
Summary of the invention
The purpose of this invention is to provide a kind of is main raw material with domestic waste, flying ash, flyash, slag micropowder, natural ore powder etc., be mixed with the composite blend that a kind of concrete is used, in order to the part cement in the replacement concrete, and make high performance concrete.
A kind of composite blending material for concrete of the present invention is characterized in that the composition of this composite blend and weight percent thereof are:
Flying ash 10~30%;
Flyash 20~40%;
Slag micropowder 30~50%;
Natural ore powder 5~15%;
Described flying ash is that its chemical ingredients is: (wt%) through washing pretreated flying ash
SiO 222.7,Al 2O 34.1,Fe 2O 35.5,CaO?20.2,
MgO?1.9,SO 37.44,Na 2O?0.2,K 2O?0.1,
Cl -0.78; Loss on ignition 12.04; , density 2.60g/cm 3Specific surface area 980m 2/ kg;
Described flyash is: fineness is 45 μ m square hole sieve surplus≤20%; Loss on ignition≤8%; Water demand ratio≤105%; SO 3≤ 3%; Water content≤1%;
The chemical ingredients of described slag micropowder is: (wt%)
Fe 2O 3?0.25,CaO?41.1,SiO 2?33.5,Al 2O 3?15.4,
MgO?8.0,TiO 2?0.62,P 2O 5?0.005,S?0.79,
MnO 0.32; Density 2.93g/cm 2Specific surface area 524m 2/ kg;
Its ore of described natural ore powder be in Wingdale, zeolite, the kaolin any or any two, need levigate to specific surface area be 400m 2/ kg.
The preparation method of composite blending material for concrete of the present invention is characterized in that having following preparation process:
The per distribution ratio of forming by above-mentioned raw materials carries out weighing and burden, take by weighing flying ash, levigated flyash, slag micropowder and levigated natural ore powder respectively, by the traditional technology method, above-mentioned each raw material is put into mixing machine, after fully mixing, promptly obtain composite blending material for concrete.
Characteristics of the present invention and advantage are as described below:
The present invention is a main raw material owing to adopting incineration of refuse flyash, industrial residue (flyash, slag micropowder), natural ore powder, so cost is low, and production technique is simple, helps suitability for industrialized production and applies.
The purposes of composite blending material for concrete of the present invention is the cement that replaces in the concrete, but 30~50% cement in the equivalent replacement concrete prepares a kind of high-performance environmentally-friendly type concrete.
In composite blending material for concrete, add fly ash from burning city domestic garbage, industrial residue and natural ore powder, come the part place of cement, the high performance concrete that is mixed with, can not only improve the grain composition of concrete system, the particle packing that makes system is more closely with rationally, thereby improve serviceabilitys such as concrete mix flowability, cohesiveness, water-retentivity, and the structure of maturing, guarantee its safe handling.And can improve the concrete slump, sulfate resistance performance, resistance of chloride ion penetration energy, anti-carbonation properties, and durability of concrete.Can also economize on resources and the energy, the regeneration flying ash is saved cement, helps environment protection, improves the ecological environment.Heavy metal in more can the stable curing flying dust can reach and reduce the purpose that hazard component leaches in the flying dust, and it can not impacted environment.Open up new approach for the recycling of domestic garbage incineration flyash and industrial residue, had good social effect and economic benefits.
Embodiment
After now specific embodiments of the invention being described in.
Embodiment one: proportioning at first in accordance with regulations takes by weighing 13.5kg flying ash, levigated flyash 40.5kg, slag micropowder 67.5kg and levigated natural ore powder 13.5kg, above-mentioned admixtion is put into mixing machine, after fully mixing, can obtain composite blending material for concrete.
Above-mentioned composite blend is mixed with cement mortar, and does strength trial.
Take by weighing cement 315kg, the composite blend 135kg that the foregoing description makes, weight 450kg altogether; Cement in cement mortar and for the cementitious composite adulterant between the two ratio be 70:30;
Take by weighing sand 1350kg in addition, making the glue in the cement mortar and the ratio of sand is glue: sand=1:3.
Be mixed with after cement mortar is mortar, make block sample and do strength trial.
The proportioning of cement mortar and strength trial the results are shown in following table 1.
Table 1 cement mortar proportioning and strength trial result
Figure A200810201972D00051
Embodiment two: proportioning at first in accordance with regulations takes by weighing 20.25kg flying ash, levigated flyash 54kg, slag micropowder 54kg and levigated natural ore powder 6.75kg, above-mentioned admixtion is put into mixing machine, after fully mixing, can obtain composite blending material for concrete.
Above-mentioned composite blend is mixed with cement mortar, and does strength trial.
Take by weighing cement 315kg, the composite blend 135kg that the foregoing description makes, weight 450kg altogether; Cement in cement mortar and for the cementitious composite adulterant between the two ratio be 70:30;
Take by weighing sand 1350kg in addition, making the glue in the cement mortar and the ratio of sand is glue: sand=1:3.
Be mixed with after cement mortar is mortar, make block sample and do strength trial.
The proportioning of cement mortar and strength trial the results are shown in following table 2.
Table 2 cement mortar proportioning and strength trial result
Figure A200810201972D00061
Be made into concrete performance test: with prepared composite blend in the foregoing description, the cement that replaces part in the former concrete, be about to mix the part composite blend in the cement, add a certain amount of sand again, a certain amount of rubble and water, fully after stirring in the mixing machine, make the concret block sample, do some salient features tests.The concrete that will replace simultaneously behind the cement is done performance test relatively with the concrete that does not replace cement.
To not replace the concrete of cement, A0 represents with numbering; The composite blend of embodiment 1 gained is replaced the clay concrete that gets of portion water, and A1 represents with numbering; The composite blend of embodiment 2 gained is replaced the clay concrete that gets of portion water, and A2 represents with numbering.
Each mix proportion sees the following form 3.
Each mix proportion of table 3
Wherein:
Cement: conch 42.5 ordinary Portland cements.
Sand: fineness modulus is 2.38, and grating is good.
Stone: 5~31.5mm rubble.
Water reducer, the polycarboxylic acid high efficiency water reducing agent, its density is 1.13g/cm 3, solid content is 40%, pH value: neutrality.
Each concrete serviceability and ultimate compression strength see the following form 4.
Table 4 each concrete serviceability and ultimate compression strength
Numbering Slump mm 7 days ultimate compression strength MPa 28 days ultimate compression strength MP3
A0 153 35.85 47.36
A1 165 32.62 46.43
A2 170 31.60 45.35
Prepared concrete has favorable working performance, and particle is tight, and can improve the concrete slump.In addition, its sulfate resistance performance is good, resistance of chloride ion penetration energy, anti-carbonation properties, and durability of concrete increases.
The heavy metal leaching test
The heavy metal leaching test carries out according to " solid waste leaches the toxicity leaching method: horizontal succusion " (5086.221997).Mass concentrations such as Cu, the Cd of experiment employing Perkin-Elmer 5100PC atomic absorption flame sectional light absorbance technique determining leach liquor, Cr, Zn, Pb.
Maintenance sees the following form 5 to the heavy metal leaching toxicity that contains adulterant mortar bodies such as flying dust in each length of time.
Table 5 maintenance to the flying dust adulterant mortar body weight metal that contains in each length of time leaches toxicity (mg/l)
Heavy metal Pb Zn Cd Cr Cu
Admittedly useless GB 3 50 0.3 10 50
Composite blend 7d 0.021 0.017 0.015 0.039 0.015
Composite blend 28d 0.009 0.008 0.006 0.023 0.008
Composite blend 56d 0.003 0.001 0.005 0.009 0.006
By result in the table can find to adopt the heavy metal ion of the mortar body that contains flying ash that the horizontal succusion of national standard tests out can the leaching amount all much smaller than the emission request of national solid waste emission standard.Prolongation along with curing age, each mortar body strengthens greatly to the constraint ability of heavy metal element, heavy metal leaches toxicity to be reduced greatly, to curing age be after 56 days in each mortar body heavy metal to leach toxic concentration almost very little, illustrate to add after the composite blend that the mortar cured body is stronger to the constraint ability of heavy metal, heavy metal is solidificated in the mortar body firmly, be difficult to leach, be significantly less than the useless admittedly emission standard of country.Illustrate that composite blending material for concrete of the present invention has feasibility and development prospect, for the utilization of solid refuse flying ash and industrial residue also open an approach, and help environment protection.

Claims (2)

1. composite blending material for concrete is characterized in that the composition of this composite blend and weight percent thereof are:
Flying ash 10~30%;
Flyash 20~40%;
Slag micropowder 30~50%;
Natural ore powder 5~15%;
Described flying ash is that its chemical ingredients is: (wt%) through washing pretreated flying ash
SiO 2?22.7,Al 2O 3?4.1,Fe 2O 3?5.5,CaO?20.2,
MgO?1.9,SO 3?7.44,Na 2O?0.2,K 2O?0.1,
Cl -0.78; Loss on ignition 12.04; , density 2.60g/cm 3Specific surface area 980m 2/ kg;
Described flyash is: fineness is 45 μ m square hole sieve surplus≤20%; Loss on ignition≤8%; Water demand ratio≤105%; SO 3≤ 3%; Water content≤1%;
The chemical ingredients of described slag micropowder is: (wt%)
Fe 2O 3?0.25,CaO?41.1,SiO 2?33.5,Al 2O 3?15.4,
MgO?8.0,TiO 2?0.62,P 2O 5?0.005,S?0.79,
MnO 0.32; Density 2.93g/cm 2Specific surface area 524m 2/ kg;
Its ore of described natural ore powder be in Wingdale, zeolite, the kaolin any or any two, need levigate to specific surface area be 400m 2/ kg.
2. the preparation method of a composite blending material for concrete, it is characterized in that having following preparation process: the per distribution ratio of forming by above-mentioned raw materials carries out weighing and burden, take by weighing flying ash, levigated flyash, slag micropowder and levigated natural ore powder respectively, by the traditional technology method, above-mentioned each raw material is put into mixing machine, after fully mixing, promptly obtain composite blending material for concrete.
CNA2008102019721A 2008-10-30 2008-10-30 Composite blending material for concrete and preparation method thereof Pending CN101397198A (en)

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Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102329119A (en) * 2010-09-30 2012-01-25 深圳市陆基投资有限公司 High performance concrete admixture and preparation method thereof
CN102390938A (en) * 2011-07-28 2012-03-28 暨南大学 Method for preparing concrete reinforcing agent from garbage burned fly ash
CN103553469A (en) * 2013-10-31 2014-02-05 攀枝花学院 High titania blast furnace slag mortar double-doped with micro powder
CN103998391A (en) * 2011-11-22 2014-08-20 施蒂雅格电力矿产有限责任公司 Construction material mixture, a method for producing same, and use thereof
CN104072028A (en) * 2013-03-25 2014-10-01 中国矿业大学 Method for preparing concrete from industrial waste residue fine aggregate
CN104310880A (en) * 2014-09-29 2015-01-28 同济大学 Method for improving freeze-thaw resistance of concrete by using waste incineration fly ash pre-treated by washing
CN104591638A (en) * 2015-02-28 2015-05-06 冯乃谦 Method for producing multifunctional concrete from household garbage power generation waste residues
CN105669064A (en) * 2016-03-10 2016-06-15 重庆三峰环境产业集团有限公司 Clean application of household garbage incineration fly ash after cement granulation and secondary treatment
CN105693123A (en) * 2016-03-10 2016-06-22 重庆三峰环境产业集团有限公司 Method for realizing co-granulation of household garbage incineration fly ash as well as cement, silica fume and coal ash and clean application of household garbage incineration fly ash to asphalt pavement
CN105859173A (en) * 2016-03-29 2016-08-17 首钢环境产业有限公司 Domestic garbage incineration furnace slag modified composite mineral admixture and preparation method thereof
CN106186774A (en) * 2016-07-12 2016-12-07 潍坊百汇特新型建材有限公司 A kind of concrete impervious additive of self-cure type, preparation method and using method
CN106565166A (en) * 2016-10-27 2017-04-19 南京工业大学 Process for preparing cementing material from household garbage incineration fly ash
CN103288389B (en) * 2013-05-16 2017-04-26 镇江港和新型建材有限公司 Fly ash containing concrete and preparation method thereof
CN107793057A (en) * 2017-11-22 2018-03-13 天津天盈新型建材有限公司 A kind of Desulphurization flying dust flyash complex mineral blending material and preparation method thereof
CN108675745A (en) * 2018-07-12 2018-10-19 同济大学 A kind of autoclaved fly ash brick and preparation method thereof prepared using incineration of refuse flyash
CN109650829A (en) * 2018-12-25 2019-04-19 同济大学 Solid waste base autoclaved fly ash brick and preparation method thereof
CN109748559A (en) * 2019-03-26 2019-05-14 中国矿业大学(北京) A kind of Composite Cementing Materials Containing and preparation method thereof
CN109761515A (en) * 2018-12-30 2019-05-17 滨海金尼环保科技有限公司 A kind of preparation method using the cured activation flying dust production miberal powder cementitious material of industrial residue
CN110078436A (en) * 2019-04-03 2019-08-02 中交四航工程研究院有限公司 A kind of solid waste highly resistance folding concrete and preparation method thereof
CN111423178A (en) * 2020-04-02 2020-07-17 成都松立建材有限责任公司 Novel environment-friendly concrete and preparation process thereof
CN111454012A (en) * 2020-05-28 2020-07-28 重庆市水务资产经营有限公司 Clean application of water-washed domestic garbage incineration fly ash in cement stabilized macadam mixture
CN112876120A (en) * 2021-02-05 2021-06-01 上海复洁环保科技股份有限公司 Sludge incineration ash-based composite admixture and preparation method and application thereof
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CN113024135A (en) * 2021-05-11 2021-06-25 海南津桓建材科技有限公司 Method for preparing cementing material by using modified waste
CN113213794A (en) * 2021-04-13 2021-08-06 天津金石建材科技有限公司 Resource recycling method for preparing gelatinization material from incineration fly ash
CN113231447A (en) * 2021-05-25 2021-08-10 重庆建工住宅建设有限公司 Method for efficiently solidifying and stabilizing domestic garbage incineration fly ash by using alkali slag cement
CN113443872A (en) * 2021-06-24 2021-09-28 东南大学 Green environment-friendly type ultra-high performance concrete material and preparation method thereof
CN114804736A (en) * 2022-04-28 2022-07-29 武汉武新新型建材股份有限公司 Geopolymer prepared from fly ash and bottom ash generated by burning household garbage and preparation method thereof
CN115466070A (en) * 2022-11-02 2022-12-13 唐山学院 Ultra-low carbon silicon-rich mineral admixture for high-performance concrete and preparation method thereof

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102329119B (en) * 2010-09-30 2013-01-02 深圳市陆基投资有限公司 High performance concrete admixture and preparation method thereof
CN102329119A (en) * 2010-09-30 2012-01-25 深圳市陆基投资有限公司 High performance concrete admixture and preparation method thereof
CN102390938A (en) * 2011-07-28 2012-03-28 暨南大学 Method for preparing concrete reinforcing agent from garbage burned fly ash
CN102390938B (en) * 2011-07-28 2013-09-04 暨南大学 Method for preparing concrete reinforcing agent from garbage burned fly ash
CN103998391B (en) * 2011-11-22 2016-10-12 施蒂雅格电力矿产有限责任公司 Building materials mixture and the production method of this mixture and use
CN103998391A (en) * 2011-11-22 2014-08-20 施蒂雅格电力矿产有限责任公司 Construction material mixture, a method for producing same, and use thereof
CN104072028A (en) * 2013-03-25 2014-10-01 中国矿业大学 Method for preparing concrete from industrial waste residue fine aggregate
CN104072028B (en) * 2013-03-25 2016-06-01 中国矿业大学 A kind of fine aggregate concrete batching method of industrial residue
CN103288389B (en) * 2013-05-16 2017-04-26 镇江港和新型建材有限公司 Fly ash containing concrete and preparation method thereof
CN103553469A (en) * 2013-10-31 2014-02-05 攀枝花学院 High titania blast furnace slag mortar double-doped with micro powder
CN104310880A (en) * 2014-09-29 2015-01-28 同济大学 Method for improving freeze-thaw resistance of concrete by using waste incineration fly ash pre-treated by washing
CN104591638A (en) * 2015-02-28 2015-05-06 冯乃谦 Method for producing multifunctional concrete from household garbage power generation waste residues
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