CN104891834B - A kind of graft-modification method of Antimicrobial preservative flyash - Google Patents
A kind of graft-modification method of Antimicrobial preservative flyash Download PDFInfo
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- CN104891834B CN104891834B CN201510253491.5A CN201510253491A CN104891834B CN 104891834 B CN104891834 B CN 104891834B CN 201510253491 A CN201510253491 A CN 201510253491A CN 104891834 B CN104891834 B CN 104891834B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The invention discloses a kind of graft-modification method of Antimicrobial preservative flyash, the present invention utilizes 3 aminopropyltriethoxywerene werenes, make the mix surface silylation obtained by flyash, then butyl methacrylate is grafted on to the silylation surface of compound, improve the stability, water-resistance and cohesive of system；The present invention uses nitric acid modified by silver scolecite, adsorption antibacterial is strong, the sym-closene of addition, α bromo cinnamaldehydes etc. further increase overall antibacterial seemingly effect, the finished product of the present invention is applied to wall brick, plastics etc., a small amount of addition can reach raising intensity, the effect to increase the service life.
Description
Technical field
The present invention relates to a kind of method that flyash recycles, more particularly to a kind of grafting of Antimicrobial preservative flyash to change
Property method.
Background technology
Flyash, is the fine ash that catching is got off from the flue gas after coal combustion, and flyash is the main of coal-burning power plant's discharge
Solid waste.The main oxides of power plants flyash form:SiO2、Al2O3、FeO、Fe2O3、CaO、TiO2Deng.Powder
Coal ash is one of larger industrial residue of the current discharge capacity in China, and with the development of power industry, the flyash of coal-burning power plant discharges
Amount increases year by year.Substantial amounts of flyash is untreated, will produce airborne dust, pollutes air;River can be caused to become silted up if being discharged into water system
Plug, and toxic chemical substance therein can also damage to human body and biology.Other flyash can be as the blending of concrete
Material.
China is a big coal country, using coal as power generation substantially fuel.The energy industry stable development in China, generate electricity
Ability annual growth is 7.3%, and power industry develops rapidly, brings sharply increasing for flyash discharge capacity, Hazards in Power Plant
The flyash total amount discharged every year increases year by year, and nineteen ninety-five flyash discharge capacity is up to 1.25 hundred million tons, 2000 about 1.5 hundred million
Ton, was up to 300,000,000 tons, the development of the national economy and ecological environment to China cause huge pressure by 2010.On the other hand,
China is the limited country of a per capita resource reserve again, the comprehensive utilization of flyash, turns waste into wealth, turns bane into boon,
It is to solve China's power generation environmental pollution, resource shortage as an important techno-economic policy in economic construction of China
Between contradiction important means, and power generation faces one of task of solution.By exploitation, flyash is being built work, built
The all departments such as material, water conservancy are widely used.
In the 1970s, exhaustion of worldwide energy crisis, environmental pollution and mineral resources etc. consumingly excites
The research and development of utilization of fly ash, international flyash meeting is repeatedly held, research work is increasingly deep, and application aspect also has
Significant progress.Flyash turns into noticeable aboundresources, cheap, the new construction brought good to and remove all evil on international market
The raw material of material raw material and chemical products, is favored by people.Research work to flyash is mostly turned to by theoretical research should
With research, important Resource analysis and utilization are particularly.The product produced using flyash is being continuously increased, and technology exists
Constantly update.Domestic and international total utilization of PCA work, there occurs great change, is mainly shown as compared with the past:Powder
The guiding theory that coal ash is administered is the comprehensive regulation, recycling from past simple environment angle change;Flyash integrates
The approach utilized is outside the application of past roadbed, embankment, concrete admixture, soil remediation etc., to develop into water
Mud raw material, cement mixture, Large Hydro-Junction engineering, pump concrete, mass concrete product, advanced filler etc. are advanced
Change utilization ways.
Flyash be coal dust formed after high-temp combustion one kind like pozzolana mixed material.It is the generating of burning coal
Factory wears into coal less than 100 microns of coal dust, and spray into burner hearth with preheated air is burnt into suspended state, and generation is contaminated with largely not
The high-temperature flue gas of combustion things, flyash is just obtained through dust collect plant trapping.The chemical composition of flyash is similar to clayey, mainly
Composition is silica, alundum (Al2O3), di-iron trioxide, calcium oxide and uncompleted burned carbon.Flyash is mainly used to produce fine coal
Ash concrete, flyash brick, fly ash silicate building block, powder ash air-entrained concrete and other construction materials, also act as agricultural
Fertilizer and soil conditioner, reclaim the raw material of industry and make environmentally conscious materialses.Flyash answering in cement industry and concrete works
With:Flyash replaces raw clay production cement, made of Portland clinker and flyash addition proper amount of gypsum are levigate
Hydraulic binder materials, cement industry can utilize unburnt carbon therein using flyash dispensing;Flyash makees cement mixture;Powder
Coal ash produces low-temperature synthesizing water mud, and production principle is that the steam curing of batch elder generation is generated into hyrate, then through dehydration and low temperature
Solid phase reaction forms cement minerals;Flyash makes clinker-free cement, including lime fly ash cement and pure fly ash cement, stone
Grey pulverized fuel ash cement is the quick lime or calcium hydroxide and a small amount of gypsum combined grinding that dry flyash is mixed to 10%-30%, or
Remixed after levigate respectively uniformly made of hydraulic cementing materials;Flyash makees the admixture of mortar or concrete, in coagulation
Adding coal ash replaces part of cement or fine aggregate in soil, can not only reduce cost, and can improve the workability of concrete, carry
High waterproof, gas, Sulphate-resistant property and chemistry-resistant characteristic, the resistance to elevated temperatures for reducing the heat of hydration, improving concrete,
Mitigate particle separation and bleed phenomenon, the contraction of reduction concrete and cracking and suppress stray electrical current to reinforcement in concrete
Corrosion.Application of the flyash in building product:Flyash brick is steamed, with fly ash in electric power plant and quick lime or other alkaline excitations
Agent is primary raw material, can also mix appropriate gypsum, and adds the aggregates such as a certain amount of cinder or water-granulated slag, by processing,
A kind of materials for wall formed after stirring, digestion, rolling, compressing, normal pressure or autoclave curing;Sintered coal ash
Brick, using flyash, clay and other industrial wastes as raw material, brick is made through Raw material processing, stirring, shaping, drying, roast;Steam
Pressure production foam powder coal ash insulating brick, using flyash as primary raw material, add a certain amount of lime and foaming agent, by dispensing,
A kind of novel insulating brick that stirring, burning injection forming and steam pressure form;Fly ash silicate building block, using flyash, lime, gypsum as
Binder materials, cinder, blast-furnace cinder etc. is aggregate, the materials for wall for adding water stirring, vibration moulding, steam curing to form;Fine coal
Ash aerated concrete, using flyash as raw material, quick lime, cement, gypsum and aluminium powder are added in right amount, add water stirring in slurry, injection
A kind of steam-cured porous light construction material formed of mould;Lytag, using flyash as primary raw material, mix a small amount of bond
Agent and solid fuel, blended, balling-up, high temperature roast and a kind of artificial lightweight aggregate made;Coal ash light heat insulation brick,
It is to be carried out dispensing with flyash, scoria, soft soil and wood chip and formed, has insulating efficiency high, refractoriness is done, and thermal conductivity is small, energy
Mitigate furnace wall thickness, shorten firing time, reduce fuel consumption, improve the thermal efficiency, reduce cost.Flyash make agricultural fertilizer and
Soil conditioner:Flyash has good physicochemical properties, can be widely used in transform rich clay, the raw-soil, acid soil and
Saline-alkali soil, the defects of its thin plate of acid is viscous is made up, contains battalion necessary to the crops such as a large amount of solubility in citric acid silicon-calcium-magnesium phosphorus in flyash
Element is supported, therefore agricultural fertilizer can be used as.Reclaim the raw material of industry:Reclaiming coal resource, using floatation in the flyash containing coal
Floating agent is added in grey pulp-water, then using air flotation technology, coal grain is adhered to bubble floating and is separated with lime-ash;Reclaim metal
Contain Fe in material flyash2O3、Al2O3And a large amount of rare metals;Cenosphere is sorted, cenosphere has quality small, high
Intensity, high temperature resistant and good insulating, it can be used for the ideal filler of plastics, for lightweight refracrory and thermal insulation material,
For petro chemical industry, for military industry field, tank brake.Make environment-friendly materials:Molecular sieve, flocculation can be manufactured using flyash
The environment-friendly materials such as agent and sorbing material;Flyash can also be used to handle fluoride waste, electroplating wastewater and the waste water of example containing heavy metal
And oily waste water, the Al contained in flyash2O3, CaO isoreactivity components, can with fluorine produce complex or production have flocculation to fluorine
The colloid ion of effect, also containing zeolite, mullite, carbon granule and silica gel etc., there is inorganic ions commutativity and adsorption bleaching
Effect.
The content of the invention
The object of the invention just there is provided a kind of graft-modification method of Antimicrobial preservative flyash.
The present invention is achieved by the following technical solutions：
A kind of graft-modification method of Antimicrobial preservative flyash, it is characterised in that comprise the following steps：
（1）Flyash is crushed, 200-300 mesh sieves is crossed, is mixed with the aqueous solution of its weight 3-5% activator, in 70-
Insulated and stirred 2-3 hours at 80 DEG C, drying remove water, and are calcined at 800-900 DEG C 1-2 hours, cooling, obtain flyash dry powder；
（2）Scolecite is taken, is added in the sodium hydroxide solution that concentration is 16-20% and soaks 1-2 hours, filtering, by filter residue
Washing 2-3 time, drying are milled, add its weight 0.6-1% alpha-bromo-cinnamaldehyde, its weight 20-30% 2-3mol/l nitre
The silver-colored solution of acid, the insulated and stirred 1-2 hours at 60-65 DEG C, obtains Antimicrobial preservative liquid additive；
（3）It is 2-3 by mass ratio:1 sym-closene, benzotriazole mixing, are stirring evenly and then adding into compound
Quick lime, the Antimicrobial preservative liquid additive of 10-20 times of weight, rise temperature is 80-86 DEG C, is heated to water and does, with flyash dry powder
Mixing, ball milling；
（4）Take above-mentioned steps（3）Obtained ball milling material, add its weight 50-60% 3- aminopropyl triethoxysilicanes
Alkane, insulated and stirred 10-20 hours at 20-30 DEG C, obtain alkylation batch mixing；
（5）Polyvinyl alcohol is taken, is added in 20-30 times of water of its weight, stirs, adds abovementioned alkyl batch mixing, is adjusted
It is 60-70 DEG C to save temperature, under the protection of nitrogen, sequentially adds butyl methacrylate, divinylbenzene, azodiisobutyronitrile,
Stirring reaction 6-7 hours, reaction are washed successively after terminating with ethanol, deionized water, press filtration, vacuum drying, are produced.
A kind of graft-modification method of Antimicrobial preservative flyash, step（3）Described in flyash dry powder, scolecite, life
The weight ratio of lime is 100: 13-17：3-4.
A kind of graft-modification method of Antimicrobial preservative flyash, step（5）Described in polyvinyl alcohol, methacrylic acid fourth
Ester, divinylbenzene, the weight ratio of azodiisobutyronitrile and alkylation batch mixing are 3-4：17-20：1-2：0.1-0.14：16-30.
A kind of graft-modification method of Antimicrobial preservative flyash, step（1）Described in the aqueous solution of activator be under
State the raw material mixing composition of parts by weight：Prodan 7-10 parts by weight, sodium chloride 2-3 parts by weight, phytic acid 0.2-0.4
Parts by weight, the parts by weight of deionized water 100.
It is an advantage of the invention that：
The present invention utilizes APTES, makes the mix surface silylation obtained by flyash,
Then butyl methacrylate is grafted on to the silylation surface of compound, improve the stability of system, water-resistance and viscous
Conjunction property；
The present invention uses nitric acid modified by silver scolecite, and adsorption antibacterial is strong, the sym-closene of addition, alpha-brominated Chinese cassia tree
Aldehyde etc. further increases overall antibacterial seemingly effect, and finished product of the invention is applied to wall brick, plastics etc., a small amount of addition
Reach raising intensity, the effect to increase the service life.
Embodiment
The present invention is described in further detail with reference to embodiment：
Embodiment 1：
A kind of graft-modification method of Antimicrobial preservative flyash, it is characterised in that comprise the following steps：
（1）Flyash is crushed, 300 mesh sieves is crossed, mixes with the aqueous solution of the activator of its weight 3%, be incubated at 80 DEG C
Stirring 2 hours, drying remove water, and are calcined 1 hour at 900 DEG C, cool down, obtain flyash dry powder；
（2）Scolecite is taken, is added in the sodium hydroxide solution that concentration is 16-20% and soaks 1 hour, filter, by filter residue water
Wash 2 times, drying milling, add the alpha-bromo-cinnamaldehyde of its weight 0.6%, its weight 20% 2mol/l silver nitrate solution,
Insulated and stirred 1 hour at 65 DEG C, obtains Antimicrobial preservative liquid additive；
（3）It is 2 by mass ratio:1 sym-closene, benzotriazole mixing, are stirring evenly and then adding into compound weight
Quick lime, the Antimicrobial preservative liquid additive of 10 times of amount, rise temperature is 86 DEG C, is heated to water and does, with flyash dry powder blend, ball milling
Uniformly；
（4）Take above-mentioned steps（3）Obtained ball milling material, adds the APTES of its weight 60%, and 20
Insulated and stirred 20 hours at DEG C, obtain alkylation batch mixing；
（5）Polyvinyl alcohol is taken, is added in 30 times of water of its weight, stirs, adds abovementioned alkyl batch mixing, regulation temperature
Spend for 70 DEG C, under the protection of nitrogen, sequentially add butyl methacrylate, divinylbenzene, azodiisobutyronitrile, stirring reaction
6 hours, reaction was washed successively after terminating with ethanol, deionized water, press filtration, vacuum drying, was produced.
A kind of graft-modification method of Antimicrobial preservative flyash, step（3）Described in flyash dry powder, scolecite, life
The weight ratio of lime is 100: 15：3.
A kind of graft-modification method of Antimicrobial preservative flyash, step（5）Described in polyvinyl alcohol, methacrylic acid fourth
Ester, divinylbenzene, azodiisobutyronitrile are 3 with the weight ratio for being alkylated batch mixing：20：1：0.14：30.
A kind of graft-modification method of Antimicrobial preservative flyash, step（1）Described in the aqueous solution of activator be under
State the raw material mixing composition of parts by weight：The parts by weight of prodan 9, the parts by weight of sodium chloride 2, the parts by weight of phytic acid 0.28,
The parts by weight of deionized water 100.
Embodiment 2
A kind of graft-modification method of Antimicrobial preservative flyash, it is characterised in that comprise the following steps：
（1）Flyash is crushed, 300 mesh sieves is crossed, mixes with the aqueous solution of the activator of its weight 4%, be incubated at 80 DEG C
Stirring 2 hours, drying remove water, and are calcined 2 hours at 900 DEG C, cool down, obtain flyash dry powder；
（2）Scolecite is taken, is added in the sodium hydroxide solution that concentration is 20% and soaks 2 hours, filter, filter residue is washed 2
It is secondary, drying milling, add the alpha-bromo-cinnamaldehyde of its weight 0.6%, its weight 30% 2mol/l silver nitrate solution, at 65 DEG C
Lower insulated and stirred 1 hour, obtains Antimicrobial preservative liquid additive；
（3）It is 2 by mass ratio:1 sym-closene, benzotriazole mixing, are stirring evenly and then adding into compound weight
Quick lime, the Antimicrobial preservative liquid additive of 10 times of amount, rise temperature is 86 DEG C, is heated to water and does, with flyash dry powder blend, ball milling
Uniformly；
（4）Take above-mentioned steps（3）Obtained ball milling material, adds the APTES of its weight 60%, and 30
Insulated and stirred 19 hours at DEG C, obtain alkylation batch mixing；
（5）Polyvinyl alcohol is taken, is added in 25 times of water of its weight, stirs, adds abovementioned alkyl batch mixing, regulation temperature
Spend for 66 DEG C, under the protection of nitrogen, sequentially add butyl methacrylate, divinylbenzene, azodiisobutyronitrile, stirring reaction
6 hours, reaction was washed successively after terminating with ethanol, deionized water, press filtration, vacuum drying, was produced.
A kind of graft-modification method of Antimicrobial preservative flyash, step（3）Described in flyash dry powder, scolecite, life
The weight ratio of lime is 100: 17：3.
A kind of graft-modification method of Antimicrobial preservative flyash, step（5）Described in polyvinyl alcohol, methacrylic acid fourth
Ester, divinylbenzene, azodiisobutyronitrile are 3 with the weight ratio for being alkylated batch mixing：20：1-2：0.14：21.
A kind of graft-modification method of Antimicrobial preservative flyash, step（1）Described in the aqueous solution of activator be under
State the raw material mixing composition of parts by weight：The parts by weight of prodan 9, the parts by weight of sodium chloride 2, the parts by weight of phytic acid 0.3, go
The parts by weight of ionized water 100.
Claims (2)
1. a kind of graft-modification method of Antimicrobial preservative flyash, it is characterised in that comprise the following steps：
(1) flyash is crushed, crosses 200-300 mesh sieves, mixed with the aqueous solution of its weight 3-5% activator, at 70-80 DEG C
Lower insulated and stirred 2-3 hours, drying remove water, and are calcined at 800-900 DEG C 1-2 hours, cooling, obtain flyash dry powder；
(2) scolecite is taken, is added in the sodium hydroxide solution that concentration is 16-20% and soaks 1-2 hours, filtering, by filter residue water
Wash 2-3 times, drying milling, add its weight 0.6-1% alpha-bromo-cinnamaldehyde, its weight 20-30% 2-3mol/l nitre
The silver-colored solution of acid, the insulated and stirred 1-2 hours at 60-65 DEG C, obtains Antimicrobial preservative liquid additive；
(3) it is 2-3 by mass ratio:1 sym-closene, benzotriazole mixing, are stirring evenly and then adding into compound weight
10-20 times of quick lime, Antimicrobial preservative liquid additive, rise temperature is 80-86 DEG C, is heated to water and does, and flyash dry powder blend,
Ball milling；
(4) the ball milling material for taking above-mentioned steps (3) to obtain, its weight 50-60% APTES is added,
Insulated and stirred 10-20 hours at 20-30 DEG C, obtain alkylation batch mixing；
(5) polyvinyl alcohol is taken, is added in 20-30 times of water of its weight, stirs, adds abovementioned alkyl batch mixing, regulation temperature
Spend for 60-70 DEG C, under the protection of nitrogen, sequentially add butyl methacrylate, divinylbenzene, azodiisobutyronitrile, stir
React 6-7 hours, reaction is washed successively after terminating with ethanol, deionized water, press filtration, vacuum drying, is produced；
The aqueous solution of activator described in step (1) is made up of the raw material mixing of following weight parts：Prodan 7-10
Parts by weight, sodium chloride 2-3 parts by weight, phytic acid 0.2-0.4 parts by weight, the parts by weight of deionized water 100；
The weight ratio of flyash dry powder, scolecite, quick lime described in step (3) is 100:13-17：3-4.
2. the graft-modification method of a kind of Antimicrobial preservative flyash according to claim 1, it is characterised in that in step (5)
Described polyvinyl alcohol, butyl methacrylate, divinylbenzene, the weight ratio of azodiisobutyronitrile and alkylation batch mixing are 3-4：
17-20：1-2：0.1-0.14：16-30.
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| CN106431042B (en) * | 2016-09-08 | 2018-11-06 | 东南大学 | A kind of dispersion of nanosize mineral admixture and surface treatment method |
| CN108745297A (en) * | 2018-06-25 | 2018-11-06 | 合肥艾飞新材料有限公司 | A kind of preparation method of modified scolecite sorbing material |
| CN109874813B (en) * | 2019-03-27 | 2021-08-20 | 中国能源建设集团安徽省电力设计院有限公司 | Method for preparing antibacterial agent by mechanically ball-milling fly ash |
| CN110746672B (en) * | 2019-09-18 | 2022-06-17 | 安徽理工大学 | Method for preparing antibacterial master batch by using waste and/or waste plastics as raw materials |
| CN117211008B (en) * | 2023-11-09 | 2024-01-30 | 龙帛生物科技有限公司 | Degradable non-woven fabric material and preparation method thereof |
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| CN103102545A (en) * | 2012-11-14 | 2013-05-15 | 安徽金桥电缆有限公司 | Cable sheath insulating material for computer and preparation method thereof |
| CN103880338B (en) * | 2014-01-22 | 2016-01-06 | 陕西理工学院 | A kind of preparation method of coal ash heat-preservation decorative integrated plate |
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