CN101340891A - Dye remover compositon - Google Patents
Dye remover compositon Download PDFInfo
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- CN101340891A CN101340891A CNA2006800480712A CN200680048071A CN101340891A CN 101340891 A CN101340891 A CN 101340891A CN A2006800480712 A CNA2006800480712 A CN A2006800480712A CN 200680048071 A CN200680048071 A CN 200680048071A CN 101340891 A CN101340891 A CN 101340891A
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Abstract
A dye remover composition which removes a dye based on the reductional action of a reducing agent. When applied to the scalp, the composition is less irritative to the scalp and can prevent air oxidation after a dye removal treatment. The dye remover composition is used for removing the dye from fibers dyed with an oxidation dye containing an aminated dye intermediate. It contains a reducing agent and removes the dye from the fibers based on the reductional action of the reducing agent. This dye remover composition further contains a reducing sugar. Examples of the reducing sugar include xylose and dihydroxyacetone.
Description
Technical field
The present invention relates to a kind of dye remover compositon, it can suppress fiber and handle the back variable color taking off to dye.
Background technology
Comprise the dye carrier material that contains for example oxidation dye and ammonia and be the known typical hair dye that makes stock-dyes such as hair as the hair coloring preparation composition of the oxidant of hydrogen peroxide and so on.Have now to be used to make by the painted fiber of hair coloring preparation composition and take off the known dye remover compositon that dyes, wherein this dye remover compositon comprises Reducing agent.The reduction of this dye remover compositon by Reducing agent takes off fiber to dye.To taking off the fiber that dyes through this dye remover compositon, there is the fiber problem of variable color again, for example, dye back several hrs or several days taking off, fiber is because of the oxidation blackening of air.Patent documentation 1 discloses the dye remover compositon that contains alpha-oxo-carboxyl acid (α-oxocarboxylic acid).Because the effect of alpha-oxo-carboxyl acid, this dye remover compositon prevent fiber and handle the back because of the air oxidation variable color taking off to dye.
Patent documentation 1:11-310521 Japanese Patent Application Publication
Summary of the invention
Yet the alpha-oxo-carboxyl acid of the variable color that being used in the dye remover compositon of record prevents that air oxidation from causing in the patent documentation 1 is a strong acid.Therefore, this dye remover compositon is kept low pH value.So, there is such problem: when using this to take off stain, can scalp irritation when dye remover compositon is applied to hair.Stimulate to lower if set the content of lower alpha-oxo-carboxyl acid simply, just can not suppress the fading of fiber that air oxidation causes fully.
The careful research of process, the inventor finds, when containing the dyestuff intermediate of band amino in the oxidation dye, can address the above problem by add reducing sugar in dye remover compositon, thereby realize the present invention.The purpose of this invention is to provide a kind of reduction by Reducing agent and take off the dye remover compositon that dyes, wherein this dye remover compositon has lowered when being applied to scalp the stimulation to scalp, and can prevent the air oxidation after anti-avulsion is dyed processing.
According to an aspect of the present invention, provide a kind of and be used to make the painted fiber of oxidation dye of the amino dyestuff intermediate of involved band to take off the dye remover compositon that dyes, it comprises Reducing agent, and carries out fiber by the reduction of this Reducing agent and take off and dye.This dye remover compositon also comprises reducing sugar.
Described reducing sugar is monosaccharide preferably.Described monosaccharide preferably is selected from least a in xylose and the dihydroxy acetone.Described Reducing agent is at least a in ascorbic acid, TGA, aminothiopropionic acid, sulfhydryl compound, sulphite, bisulfites and the thiosulfate preferably.
Described dye remover compositon preferably also contains the hair penetrating agent.Described hair penetrating agent is aromatic alcohol preferably.Preferably, described reducing sugar is an xylose, and the mass ratio of xylose and hair penetrating agent is 0.1～5.Preferably, the content of xylose in dye remover compositon is 0.5～30 quality %.And preferably, described reducing sugar is a dihydroxy acetone, and the mass ratio of dihydroxy acetone and hair penetrating agent is 0.05～5.Preferably, the content of dihydroxy acetone in dye remover compositon is 0.05～30 quality %.
The specific embodiment
Below, the embodiment with reference to concrete dye remover compositon is described in detail the present invention.Dye remover compositon in the present embodiment is used to make hair to take off to dye, and this hair is just as by the painted fiber of hair coloring preparation composition.This hair coloring preparation composition is formed by first dose and second dose.
First dose of＜hair coloring preparation composition 〉
First dose of hair coloring preparation composition comprises, for example, and oxidation dye and alkaline agent.Oxidation dye be can be by being included in the oxidant in second dose of this hair coloring preparation composition oxidation polymerization induce the chemical compound that develops the color, it is divided into dyestuff intermediate and cross-linking agent.This oxidation dye comprises dyestuff intermediate at least, and wherein this dyestuff intermediate has amino.
The example of the dyestuff intermediate that band is amino comprises: p-phenylenediamine (PPD), Toluene-2,4-diisocyanate, 5-diamidogen, N-phenyl-p-phenylenediamine (PPD), 4,4 '-diamino-diphenylamine, para-aminophenol, o-aminophenol, p-methylaminophenol, N, N-two (2-ethoxy)-p-phenylenediamine (PPD), 2-ethoxy-p-phenylenediamine (PPD), adjacent chlorine p-phenylenediamine (PPD), the amino metacresol of 4-, 2-amino-4-hydroxyethylamino methyl phenyl ethers anisole, 2,4-diaminophenol and their salt.Above-claimed cpd both can contain separately, but also two or more combinations contain.
Cross-linking agent develops the color by combining with dyestuff intermediate.The example of cross-linking agent comprises: the amino orthoresol of 5-, m-aminophenol, 5-(2-hydroxyethylamino)-2-cresol, m-diaminobenzene., 2,4-diaminobenzene oxyethanol, Toluene-3,4-dithiol, 4-diamidogen, 2,6-diamino-pyridine, diphenylamines, N, N-diethyl-m-aminophenol, benzyl pyrrolinone and their salt.These materials can contain separately, perhaps can contain two or more combination.Preferably, this oxidation dye is made up of at least a dyestuff intermediate and at least a cross-linking agent that is selected from described object lesson that is selected from described object lesson.Like this, can change the tone of hair in every way.
Preferably, the content of oxidation dye in hair coloring preparation composition is 0.02～25 quality %, more preferably, is 0.2～15 quality %.If the content of oxidation dye less than 0.02 quality %, will be difficult to obtain sufficient dyeability.Even the content of oxidation dye surpasses 25 quality %, can further not improve dyeability yet.Therefore, the business efficiency of coloring hairs can descend.
Preferably, the content of the dyestuff intermediate in the described hair coloring preparation composition is 0.01～15 quality %, more preferably, is 0.1～10 quality %.If the content of dyestuff intermediate less than 0.01 quality %, will be difficult to obtain sufficient dyeability.Even the content of dyestuff intermediate surpasses 15 quality %, can further not improve dyeability yet.Therefore, the business efficiency of coloring hairs can descend.
Preferably, the content of cross-linking agent is 0.01～10% in the hair coloring preparation composition, more preferably, is 0.1～5 quality %.If the content of cross-linking agent less than 0.01 quality %, will be difficult to obtain sufficient dyeability.Even the content of cross-linking agent surpasses 10 quality %, dyeability can further not improve yet.Therefore, the business efficiency of coloring hairs can descend.First dose can randomly comprise, for example, and at least a direct dyes that is selected from the dyestuff of conduct except that the oxidation dyestuff that records in oxidation dye and " medicine part outer article raw material specification " (Japanese medicine thing day newspaper office, in June, 1991 distribution).
Alkaline agent by promoting to be included in the oxidant in second dose of hair coloring preparation composition effect and by making the hair swelling improve the permeability of dyestuff to hair, improve dyeability.The example of alkaline agent comprises: ammonia, alkanolamine, organic amine, inorganic base, basic amino acid and their salt.The example of organic amine comprises 2-amino-2-methyl-1, ammediol and guanidine.The example of inorganic base comprises sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate.The example of basic amino acid comprises arginine and lysine.The example of salt comprises ammonium salt.These alkaline agents can be individually or are contained with the form of two or more combination.
Preferably, the content of alkaline agent is that to make the pH value of the agent of winning be 8～12.If first dose pH value less than 8, just has such situation: when first dose and second dose mix, not have fully promotion to be included in second dose effect as the hydrogen peroxide of oxidant.If first dose pH value is higher than 12, when hair coloring preparation composition is applied to hair, just may cause the problem such as making damaged hair.
This first dose can randomly comprise contained component, for example oiliness composition or surfactant in second dose of described dye remover compositon except that reducing sugar.Also have, preferably, this first dose comprises polymerization inhibitor, and generating the polymer with oligomerization ratio during by oxidant generation oxidation polymerization at oxidation dye, this polymer is easy to take off with dye remover compositon and dyes.The example of described polymerization inhibitor comprises: as the ascorbic acid and the sulphite of Reducing agent.In this first dose in first dose of the object lesson of contained ascorbic acid and dye remover compositon the object lesson of contained ascorbic acid identical.This state of first dose is not particularly limited, and object lesson comprises: liquid, colloid, foam and body of paste.The example of liquid comprises aqueous solution, dispersion and emulsion.
Second dose of＜hair coloring preparation composition 〉
Second dose of hair coloring preparation composition comprises oxidant.Described oxidant takes off melanin contained in the hair to dye, and contained oxidation dye develops the color in by this hair coloring preparation composition of oxidation first dose.The example of described oxidant comprises Potassium bromate., sodium bromate, Dexol and hydrogen peroxide.When described second dose total amount was made as 100 quality %, preferably, the content of oxidant was 0.1～15.0 quality % in second dose.
This second dose comprises in second dose of oxide hair dye composition contained component usually, as the component outside the oxidant.This second dose can randomly comprise the contained component except that described oxidation dye and alkaline agent in first dose of hair coloring preparation composition.When this second dose hydrogen peroxide that comprises as oxidant, preferably, this second dose comprises that stabilizing agent is to suppress the decomposition of hydrogen peroxide.The example of stabilizing agent comprises: carbamide, Phenacetin, sodium stannate, ethylene glycol phenyl ether, oxine and phosphoric acid.Second dose dosage form has no particular limits, and its example can comprise liquid, colloid, foam and body of paste.The example of liquid comprises aqueous solution, dispersion and emulsion.
＜hair coloring preparation composition 〉
By with described first dose and second dose of mixed, prepare hair coloring preparation composition to be scheduled to.The dosage form of this hair coloring preparation composition has no particular limits, and its example can comprise liquid, body of paste, colloid and foam.
Next, described dye remover compositon is described.This dye remover compositon is formed by first dose and second dose.
First dose of＜dye remover compositon 〉
First dose of dye remover compositon comprises Reducing agent, and for example also can comprise at least a in good fortune horse acid and the dispersant.This first dose is powdery.Described Reducing agent is the polymer of the oxidation dye oxidation polymerization generation of reason dyed hair also.More specifically, described Reducing agent can utilize its reduction polymer of depolymerization or off-resonanceization (off-resonate, non-Gong Narutoization) oligomerization ratio easily.The example of Reducing agent comprises ascorbic acid, TGA, cysteine, sulfhydryl compound, sulphite, bisulfites and thiosulfate.
The example of ascorbic acid comprises ascorbic acid, arabo-ascorbic acid and their salt and derivant.The example of Ascorbate and erythorbate comprises sodium ascorbate, potassium ascorbate, calcium ascorbate, ascorbic acid ammonium, ascorbic acid monoethanolamine, ascorbic acid diethanolamine and sodium erythorbate.
The example of ascorbic acid derivates and arabo-ascorbic acid derivant comprises ascorbic acid sulfuric ester disodium, arabo-ascorbic acid sulfuric ester disodium, magnesium L-ascorbyl-2-phosphate, ascorbyl palmitate, ascorbyl stearate, the ascorbic acid acid dipalmitate, ascorbic acid four 2-hexadecane acid esters, the ascorbic acid myristate, the ascorbic acid laurate, the ascorbic acid acetas, the ascorbic acid propionic ester, the ascorbic acid tartrate, the ascorbic acid citrate, the ascorbic acid succinate, the ascorbic acid benzoate, Ascorbic acid 2-phosphate Renascin potassium salt (potassium (ascorbyl/tocopheryl) phosphate), the ethyl ascorbic acid, the allantoin Ascorbate, the chitosan Ascorbate, methyl-monosilane alcohol ascorbic acid, the own ester of ascorbic acid myristyl (ascorbyltetradecylhexyl), the aminopropyl ascorbic acid phosphoric acid esters, the ascorbic acid polypeptide, ascorbate glucoside and ascorbic acid methyl-monosilane alcohol fruit jelly ester (ascorbyl methylsilanolpectinate).
The example of TGA comprises TGA, thioglycolate salt and mercaptoacetate.The example of thioglycolate salt comprises ammonium mercaptoacetate and sodium thioglycolate.The example of mercaptoacetate comprises TGA glyceride.The example of cysteine comprises cysteine, cysteine hydrochloride and N-acetyl-L-cysteine.
The example of sulfhydryl compound comprises thioglycerin, 2-mercaptopropionic acid, mercaptosuccinic acid. and mercaptoethylmaine.The example of sulphite comprises sulfurous acid, ammonium sulfite, sodium sulfite.The example of bisulfites comprises ammonium bisulfite and sodium sulfite.The example of thiosulfate comprises thiosulfuric acid and sodium thiosulfate.The Reducing agent of these object lessons can contain separately, and perhaps two or more combinations contain.
In the Reducing agent of object lesson, preferred ascorbic acid.Ascorbic acid has excellent effect to oligomerization than the depolymerization or the off-resonanceization of polymer.And, because of containing ascorbic acid, can reduce foul smell, and can reduce to take off to dye and handle the damage of back hair from first dose and dye remover compositon effusion as Reducing agent.
Good fortune horse acid suppresses by oligomerization than the reoxidizing of the chemical compound of the depolymerization of polymer or off-resonance generation, and it is painted again to suppress hair.Dispersant suppresses forming of the state of aggregation that produced by the ascorbic acid that for example bonds, and when first dose and second dose of dye remover compositon mixes first dose of dispersibility in second dose of improvement.The example of dispersant comprises stearic slaine, Talcum, crystalline cellulose, low-substituted hydroxypropyl cellulose and dextrin.The example of stearic slaine comprises calcium stearate and magnesium stearate.
Second dose of＜dye remover compositon 〉
Second dose of dye remover compositon comprises reducing sugar, and this second dose is liquid, colloid or body of paste form.Described reducing sugar prevents that hair from handling the back because of the air oxidation variable color taking off to dye.Described reducing sugar has aldehyde radical or ketone group, and wherein this group is free or retrained by hemiacetal linkage, and can play Maillard reaction with for example aminoacid or proteinic amino.The example of reducing sugar comprises free monosaccharide, reducing disaccharides and reproducibility oligosaccharide.
The example of free monosaccharide comprises triose, tetrose, pentose, hexose and heptose.The example of triose comprises glyceraldehyde, dihydroxy acetone.The example of tetrose comprises erythrose.The example of pentose comprises ribose, xylose and arabinose.The example of hexose comprises glucose, galactose, mannose and fructose.The example of heptose comprises sedoheptulose.
The example of reducing disaccharides comprises equal hexobiose (homobiose), dissident's disaccharide.All the example of hexobiose comprises maltose, cellobiose, dextrinose and gentiobiose.The example of dissident's disaccharide comprises close disaccharide, lactose, maltulose and lactulose.
The example of reproducibility oligosaccharide comprises maltotriose, and it is the α-Dian Fenmei catabolite of starch or glycogen.Reducing sugar in these object lessons can use separately, but perhaps two or more are used in combination.In these object lessons, preferred free monosaccharide is because it has high effect that prevents variable color and high unit mass reducing power.More preferably xylose and dihydroxy acetone obtain because they have the higher effect that prevents variable color and are easy to.
The content of reducing sugar is determined by reducing power that measure to form saccharide residue in the dye remover compositon, more specifically, is to measure reducing end under neutral group in the reducing sugar molecule (carbonyl or easily change into the functional group of carbonyl).The content of reducing sugar also can be determined by the reducing power of analytical unit quality reducing sugar in the dye remover compositon.When reducing sugar was the pentose of xylose and so on, preferably, the content of reducing sugar was 0.5～30 quality %, more preferably, is 1～20 quality %, is preferably 2～10 quality %.If less than 0.5 quality %, will being difficult to fully suppress hair, the content of reducing sugar handles the back variable color taking off to dye.If the content of reducing sugar surpasses 30 quality %, can bond because of for example making hair, and make hair sense of touch variation.
In addition, when reducing sugar was the trisaccharide of dihydroxy acetone and so on, preferably, the content of reducing sugar was 0.05～30 quality %, more preferably, is 0.1～20 quality %, is preferably 0.2～10 quality %.If less than 0.05 quality %, will being difficult to suppress fully hair, the content of reducing sugar handles the back variable color taking off to dye.If the content of reducing sugar surpasses 30 quality %, can bond because of for example making hair, and make hair sense of touch variation.
Preferably, second dose comprises the hair penetrating agent, with active component that improves dye remover compositon such as the permeability that reducing sugar is waited until hair.The example of hair penetrating agent comprises lower alcohol, glycol, glycerol, aromatic alcohol, ethyl carbitol, phenethyl alcohol, N-Methyl pyrrolidone, N-ethyl pyrrolidone, ethyl carbonate and Allyl carbonate.The example of lower alcohol comprises ethanol and isopropyl alcohol.The example of glycol comprises propylene glycol, 1,3 butylene glycol, Isopropanediol, hexanediol, Polyethylene Glycol and polypropylene glycol.The example of glycerol comprises by deutero-two glycerol of glycerol self.The example of aromatic alcohol comprises benzylalcohol and benzyloxy alcohol.These alcohol can use separately, but perhaps two or more are used in combination.Wherein, preferred fragrance alcohol is because it has the effective ingredient permeability of high dye remover compositon.More preferably benzylalcohol and benzyloxy alcohol are because they are easy to obtain.
Preferably, the content of hair penetrating agent is 1～30 quality % in the dye remover compositon, more preferably, is 2～20 quality %, is preferably 3～15 quality %.If the content of hair penetrating agent less than 1 quality %, will be difficult to obtain the effective ingredient hair infiltration facilitation of dye remover compositon.If the content of hair penetrating agent greater than 30 quality %, can make hair sense of touch variation.The bad stability that also may cause dye remover compositon.
For obtain to prevent the effect of variable color by the cooperative effect of reducing sugar and hair penetrating agent, when reducing sugar is xylose, preferably, xylose and hair penetrating agent ratio are 1: 0.1～1: 5 in the dye remover compositon, more preferably, be 1: 0.1～1: 3, be preferably 1: 0.2～1: 2.The ratio of supposing xylose and hair penetrating agent is 1: 0.1～1: 5, and the mass ratio of expression xylose and hair penetrating agent is 0.1～5.
Similarly, when reducing sugar was dihydroxy acetone, preferably, the ratio of dihydroxy acetone and hair penetrating agent was 1: 0.05～1: 5 in the dye remover compositon, more preferably, is 1: 0.05～1: 3, is preferably 1: 0.1～1: 2.The ratio of supposing dihydroxy acetone and hair penetrating agent content is 1: 0.05～1: 5, and the mass ratio of then representing dihydroxy acetone and hair penetrating agent is 0.05～5.In the Reducing agent of specifically giving an example, except that xylose and dihydroxy acetone, the ratio of reducing sugar and hair penetrating agent by measure forming saccharide residue (the reducing end under neutral group in the reducing sugar molecule) reducing power or the reducing power of the reducing sugar of unit mass determine.
As required, second dose can comprise at least a in the following substances: for example (herbal extract gives birth to for water, water solublity high polymeric compound, surfactant, oiliness composition, polyhydric alcohol, antiseptic, chelating agen, stabilizing agent, pH regulator agent, plant extract, herbal extract
Extract), vitamin, spice and ultraviolet absorber.
Water plays the effect of the solvent of Reducing agent.The water solublity high polymeric compound plays the effect of viscosity intensifier, and it makes takes off stain and have suitable viscosity.The example of the high polymer compound of water solublity comprises arabic gum, POLY-karaya, tragacanth, sodium alginate, xanthan gum, cellulose derivative, cross linked polyacrylate and many chlorinations dimethylated methylene base piperidolate (polychlorinated dimethylmethylenepiperidium).
The oiliness composition provides humidity for hair.Therefore, second dose preferably includes the oiliness composition.The example of oiliness composition comprises fat, wax, higher alcohol, hydrocarbon, higher fatty acids, alkyl glycerylether, ester and silicone.
The example of fat comprises olive oil, Camellia oil, Adeps Bovis seu Bubali resin, almond oil, Oleum Camelliae, oil tea oil, safflower oil, sunflower oil, Oleum Glycines, Oleum Gossypii semen, Oleum sesami, Adeps Bovis seu Bubali, cocoa butter, Semen Maydis oil, Oleum Arachidis hypogaeae semen, rapeseed oil, Testa oryzae oil, rice embryo oil, wheat germ oil, Semen Coicis oil, Oleum Vitis viniferae, American Avocado Tree oil, carrot oil, macadamia oil, Oleum Ricini, Semen Lini oil, cocos nucifera oil, ermine oil and egg oil.The example of described wax comprises Cera Flava, candelilla wax, Brazil wax, Jojoba oil and lanoline.
The example of described higher alcohol comprises dodecanol, tetradecanol, hexadecanol (hexadecanol), octadecanol, 16 octadecanols, aralkyl alcohol, tadenan, 2-hexyldecanol, isooctadecane alcohol, 2-octyldodecanol, decyl tetradecanol, oleyl alcohol, inferior oleyl alcohol, linolenyl alcohol and lanolin alcohol.
The example of described hydrocarbon comprises: alpha-olefin low polymers, light isoparaffins, light liquid isoparaffin, synthetic squalane, plant squalane, squalane, polybutene, liquid isoparaffin, liquid paraffin, ceresine, ceresin, paraffin, polyethylene powders, microwax and vaseline.
The example of described higher fatty acids comprises: lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, isostearic acid, hydroxy stearic acid, 12-hydroxy stearic acid, oleic acid, 9-undecylenic acid, linoleic acid, castor oil acid and lanolin fatty acid.The example of described alkyl glycerylether comprises: batilol (single batiolum) .alpha.-hexadecylglyceryl ether (single cetyl glycerin ether), selachyl alcohol (single oleyl glycerin ether) and isooctadecane base glycerol ether.
The example of described ester comprises: diisopropyl adipate, diisobutyl adipate, dioctyl adipate, adipic acid 2-hexyl ester in the last of the ten Heavenly stems, adipic acid two isooctadecanol adipate esters, isopropyl myristate, sad hexadecyl ester, isooctanoic acid hexadecyl ester, isononyl isononanoate, different isodecyl pelargonate, Crodamol TN, Dermol DIPS, myristic acid octyl group ten diester, isopropyl palmitate, butyl stearate, stearyl stearate, lauric acid hexyl ester, myristyl myristate, decyl oleate, the sad hexyl of dimethyl ester in the last of the ten Heavenly stems, myristic acid three isodecyl esters, the isooctadecanol myristinate, Palmic acid 2-Octyl Nitrite, ricinoleic acid octyl group ten diester, fatty acid (C10-30) (cholesterol/lanosterol) ester, the lauryl alcohol lactate, the hexadecanol lactate, the tetradecanol lactate, the octyldodecanol lactate, the lanonol acetate, 2-Methylpentadecane alcohol stearate, 2-Methylpentadecane alcohol isostearate, 12-hydroxy stearic acid cholesterol ester, two-2 ethyl hexanoic acid second diester, the dipentaerythritol fatty acid ester, N-alkyl glycol list isostearate, the hexadecanol decanoin, decanoin, the neopentyl glycol dicaprate, two isooctadecanol malates, and lanolin derivative.
The example of described silicone comprises that dimethyl polysiloxane, tolyl polysiloxanes, decamethylcyclopentasiloxane, ten diformazan basic rings, six siloxanes, polyether modified silicone, average degree of polymerization are 650～10,000 high silicone, amino modified silicone, betanin modified silicone, alkyl-modified silicone, alkoxy-modified silicone, sulfhydryl modified silicone, carboxy-modified silicone and fluorine modified silicone.These oily components can be separately or are contained with the form of two or more combinations.
The example of described polyhydric alcohol comprises glycols and glycerol class.The example of described glycols comprises ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoamyl glycol and 1,3 butylene glycol.The example of described glycerol class comprises glycerol, two glycerol and polyglycerol.
Surfactant plays the effect of emulsifying agent or solubilizing agent, keeps first dose stability of dye remover compositon.The example of surfactant comprises non-ionic surface active agent, cationic surfactant, anion surfactant and amphoteric surfactant.
The example of non-ionic surface active agent comprises polyoxyethylene (hereinafter claiming POE) alkyl ether, POE alkyl phenyl ether, POE polyoxypropylene alkyl ether, POE sorbitan fatty acid ester, POE methyl glycol fatty acid ester and aliphatic chain alkanolamine.
The example of described cationic surfactant comprises Dodecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, octadecyl trimethyl ammonium chloride, the octadecyl trimethylammonium bromide, INCROQUAT TMC-80 ECONOL TM22 (behenyl trimethylammonium chloride), the two trimethylammonium bromides of two octadecyls, cetyl trimethyl ammonium bromide, docosyl trimethyl methylsulfuric acid ammonium (behenyltrimethylammonium methylsulfate), octadecyl trimethyl ammonium benzoyl imines (stearyltrimethylammonium saccharin), with octadecyl trimethyl ammonium benzoyl imines (cetyltrimethylammonium saccharin).
Described examples of anionic surfactants comprises alkyl sulfate, POE alkyl sulfate, alkyl sulfate salt, methyl stearoyl sodium aurate, DBSA triethanolamine, tetradecene sodium sulfonate, POE Laurel ether phosphate and salt thereof, N-dodecanoyl glutamate, Glu and N-dodecanoyl methyl-Beta-alanine.The example of alkyl sulfate comprises sodium lauryl sulphate.The example of POE alkyl sulfate comprises sodium lauryl tri(oxyethyl) sulfate.The example of alkyl sulfate salt comprises the lauryl sulphate acid triethanolamine.
The example of amphoteric surfactant comprises 2-undecyl-N-carboxymethyl-N-hydroxyethyl imidazole quinoline betanin, cocamido propyl betaine (cocamidopropyl betaine), dodecyl dimethylamino acetic acid betanin.
Described examples of preservatives comprises p-Hydroxybenzoate.The example of chelating agen comprises disodiumedetate (EDTA-2Na).The example of stabilizing agent comprises phenacetin, oxine, acetanilide, tetrasodium pyrophosphate, barbiturates, uric acid and tannin.The example of pH regulator agent comprises phosphoric acid, citric acid, sulphuric acid, acetic acid, lactic acid, tartaric acid and malic acid.
＜dye remover compositon 〉
Mix first dose and second dose with preset ratio, prepare dye remover compositon.In this process, the Reducing agent in first dose is dissolved in second dose.With the coating utensil of brush or comb and so on dye remover compositon is applied to the chromogenic reaction of the polymer that the oxidation polymerization by oxidation dye produces and painted hair.In this process, make the polymer of coloring hairs be reduced the reduction depolymerization (degraded) or the off-resonanceization of agent.After this takes off and dyes processing, remain in the hair from oxidation dye composition for hair dying, that change into monomer or low molecular weight substance.Reducing sugar inhibited oxidation dyestuff in the dye remover compositon is because of the air oxidation oxypolymer.Therefore, can suppress the variable color of hair.More specifically, Maillard reaction takes place, the aldehyde radical or the ketone group combination of wherein staying the amino and the reducing sugar of the dyestuff intermediate in the hair.Therefore, suppress the repolymerization of the dyestuff intermediate that causes because of air oxidation, thereby suppressed the variable color of hair.
The following describes the advantage of present embodiment.
(1) in the present embodiment, be applied to the dye remover compositon that contains the painted hair of oxidation dye of being with amino dyestuff intermediate and comprise reducing sugar.Therefore, can prevent air oxidation after anti-avulsion is dyed.More specifically, take off dye processing after, aldehyde radical by reducing sugar or ketone group with stay hair in the combining of the amino that changes into monomer or low molecular weight substance dyestuff intermediate, the depolymerization (variable color) of the dyestuff intermediate that causes because of airborne oxygen is suppressed.
(2) dye remover compositon of present embodiment comprises the neutral reduction sugar that substitutes the strong acid alpha-oxo-carboxyl acid.Therefore, when dye remover compositon is applied to scalp, can lower stimulation to scalp.
(3) in the present embodiment, when using monomer, use a spot of reducing sugar can obtain advantage of the present invention as reducing sugar.This is because the reducing power of the reducing power of the composition saccharide residue of monosaccharide or unit mass is higher than the reducing power of composition saccharide residue of reducing disaccharides or reproducibility oligosaccharide or the reducing power of unit mass.For example, as the maltose of reducing disaccharides, because as sugar composed two glucose molecules, promptly constitute two glucose molecules of maltose, in the reducing end group of a molecule be used to bonding, therefore, maltose only has a reducing end under neutral group.Therefore, compare with the glucose as monosaccharide, the sugar composed reducing power of maltose or the reducing power of unit mass are approximately half.For obtain with as the suitable reducing power of the glucose of monosaccharide, for maltose, its requirement approximately is the twice (quality %) of glucose.
(4) in the present embodiment, at least a when the reducing sugar in will being selected from xylose and dihydroxy acetone uses a small amount of reducing sugar just can obtain advantage of the present invention.This is because the reducing power of the xylose of unit mass and dihydroxy acetone is higher than the reducing power of the hexose and the heptose of unit.In addition, compare with other monosaccharide, xylose and dihydroxy acetone are cheap and be easy to obtain.
(5) in the present embodiment, at least a when the Reducing agent when with in ascorbic acid, TGA, cysteine, sulfhydryl compound, sulphite, bisulfites and the thiosulfate is easy to take off and dyes operation.This is because Reducing agent has the effect than polymer of good depolymerization or off-resonance oligomerization.
(6) when the dye remover compositon of present embodiment contains the hair penetrating agent, reducing sugar is improved, prevents that to the permeability of hair the effect of variable color is able to further raising.
(7) when using xylose in the present embodiment as reducing sugar, by xylose content in the dye remover compositon is set at 0.5～30 quality %, for example because of the situation that makes the hair sense of touch variation that hair bonding causes is suppressed, and be fully suppressed in the hair variable color of taking off after dying processing.
(8) when using dihydroxy acetone as reducing sugar in the embodiment of the present invention, be set at 0.05～30 quality % by content with the dihydroxy acetone in the dye remover compositon, for example because of the situation that makes the hair sense of touch variation that hair bonding causes is suppressed, and be fully suppressed in the hair variable color of taking off after dying processing.
Can do following change to present embodiment.
In the above-described embodiment, dye remover compositon is applied to hair.Yet, also dye remover compositon can be applied to the fiber of the available oxidation dyeing outside the hair, as people's hair, Pilus Caprae seu Ovis or the feather outside the hair.To this, can prevent the air oxidation after anti-avulsion is dyed processing.
The dye remover compositon of above-mentioned embodiment is formed by first dose and second dose, and first dose and second dose is mixed before using dye remover compositon immediately.But dye remover compositon also can be made up of the single prescription of the solution composition that comprises the contained whole components of dye remover compositon.In addition, also can will in water, be prepared into dye remover compositon as the solid, shaped components dissolved of Reducing agent and reducing sugar and so on, then this dye remover compositon will be applied to hair by the user who uses dye remover compositon.The example of solid, shaped Reducing agent comprises Powdered ascorbic acid.By at random cutting apart first dose and second dose that forms dye remover compositon, dye remover compositon can be made up of three or more prescriptions.For example, reducing sugar can be got rid of outside first dose and second dose.Mix first dose and second dose prepare dye remover compositon after, reducing sugar can be added this mixture.
In the above-described embodiment, reducing sugar can be contained in first dose of dye remover compositon but not dye remover compositon second dose.
The hair coloring preparation composition of above-mentioned embodiment is formed by first dose and second dose, and first dose and second dose is mixed before using hair coloring preparation composition immediately.Yet by at random cutting apart first dose and second dose that forms hair coloring preparation composition, hair coloring preparation composition can be made up of three or more prescriptions.For example, hair coloring preparation composition can by first dose of the oxidation dye that comprises the dyestuff intermediate that band is amino, comprise second dose of alkaline agent and comprise that the 3rd dose of oxidant form.In said composition, because oxidation dye separates with alkaline agent, the bin stability of oxidation dye is improved.And, whole components of forming hair coloring preparation composition can be separated instant these components of mixing before using hair coloring preparation composition.
In the above-mentioned specific embodiment, first dose of dye remover compositon is Powdered, to improve the stability of Reducing agent.Yet first dose state is not particularly limited, and can contain the solvent just like water and so in first dose, makes first dose to be liquid, colloid or body of paste.
Embodiment
Subsequent, in conjunction with the embodiments and comparative example, further specify above-mentioned embodiment.
Preparation first dose and second dose of hair coloring preparation composition, table 1 shows described first dose and second dose that comprises component.Representing the value in the row of each component in the table 1, is the components contents in the respective column, and its unit is quality %., with 1: 1 mass ratio mix first dose and second dose, make hair coloring preparation composition thereafter.Brown people's topknot (hereinafter referred topknot) in brush the gained hair coloring preparation composition being applied to, and left standstill 30 minutes in room temperature (25 ℃).Then, adhere to the hair coloring preparation composition of topknot at the water flush away after, topknot handles twice with shampoo, and uses hair conditioner once to topknot.Then, topknot left standstill one day after using the warm braw drying.
Table 1
| ＜the first dose 〉 | |
| 28% ammonia | 5 |
| Ascorbic acid | 0.5 |
| Sodium sulfite | 0.2 |
| Sodium lauryl sulphate | 2 |
| Stearyl alcohol | 10 |
| POE (30) stearyl ether | 10 |
| The EDTA disodium | 0.5 |
| P-phenylenediamine (PPD) | 0.5 |
| 2,4-diaminobenzene oxyethanol hydrochlorate | 1 |
| Pure water | Surplus |
| Amount to | 100 |
| ＜the second dose 〉 | |
| 35% hydrogen peroxide | 16 |
| Sodium stannate | 0.1 |
| EDTA | 0.5 |
| Hexadecanol | 5 |
| Sodium lauryl sulphate | 1 |
| Pure water | Surplus |
| Amount to | 100 |
Then, prepare first dose and second dose of dye remover compositon, its invading the exterior 2 shows described first dose and second dose that comprises component.Value in the table 2 in the row of each component of expression is the components contents in the respective column, and unit is quality %.Then, make dye remover compositon for first dose and second dose by mass ratio mixing with 1: 10.With brush the dye remover compositon that obtains is applied to the topknot of handling through above-mentioned dyeing, and left standstill 30 minutes in room temperature (25 ℃).
Subsequent, wash the dye remover compositon of attachment removal with water in topknot, handle topknot twice with shampoo, and use hair conditioner once to topknot.Then, with the dry topknot of warm braw.With the spectral photometric colour measuring meter (Minolta company, model: CM-508d) measure through described take off the processing of dying processing after the L of topknot
*a
*b
*Value (L
1, a
1, and b
1).Also the pH of the dye remover compositon among each embodiment shown in the his-and-hers watches 2 and second dose measures.
＜air reoxidizes rate 〉
Topknot through above-mentioned take off dye handle to handle after, left standstill 24 hours under 40 ℃ of the water-bath control temperature, with spectral photometric colour measuring instrumentation amount L
*a
*b
*Value (L
2, a
2, and b
2).
With the topknot that is untreated, through taking off after the processing of dying processing topknot L separately behind the topknot and isothermal processes
*a
*b
*Value is calculated the topknot and through taking off (the Δ E of the aberration between the topknot after the processing of dying processing of being untreated by following formula (1)
1), and aberration (the Δ E between the topknot after be untreated topknot and the isothermal processes
2).
ΔE
i＝{(L
i-L
0)
2+(a
i-a
0)
2+(b
i-b
0)
2}
1/2...(1)
In formula (1), L
iExpression is taken off and is dyed the L that handles topknot after back topknot or the isothermal processes
*Value, a
iExpression is taken off and is dyed a that handles topknot after back topknot or the isothermal processes
*Value, b
iExpression is taken off and is dyed the b that handles topknot after back topknot or the isothermal processes
*Value, L
0, a
0And b
0The be untreated L of topknot of expression respectively
*Value, a
*Value and b
*Value.
Subsequent, from Δ E
1With Δ E
2, calculate air by following formula (2) and reoxidize rate [%].
Air reoxidizes rate [%]=(1-Δ E
1/ Δ E
2) * 100 ... (2)
It is low more that air reoxidizes rate, and the electrochromic variable of hair must be few more in the isothermal processes.The air that table 2 shows each embodiment reoxidizes the result of calculation of rate.
＜sensory stimuli 〉
The dye remover compositon of each embodiment and comparative example is applied to five experimenters upper arm separately.Used back 10 minutes, each experimenter makes feeling evaluation with following one to three scoring to excitement.More specifically, the experimenter gives a mark to excitement according to following methods of marking; 3 minutes (the stingless excitation of experimenter), 2 minutes (experimenter feels faint stimulation, as the sensation of faint pain or faint twinge) and 1 minute (experimenter feels intense stimulus, as severe pain or sensation of pricking).Calculate give a mark result's average mark of 5 experimenters.Then, as the evaluation of sensory stimuli, be equally divided into 2.6 or higher when what calculate, be defined as " well ",, be " poor slightly " when being equally divided into of calculating is not less than 1.6 to not being higher than 2.5, being equally divided into 1.5 or lower when what calculate, then is " poor ".Evaluation result is listed in table 2.
From result shown in the table 2, can find, because the dye remover compositon of embodiment 1～4 does not contain Biformyl acid (alpha-oxo-carboxyl acid), the pH of the dye remover compositon among the embodiment 1～4 (wherein second dose comprises that xylose, glucose or dihydroxy acetone are as reducing sugar) is higher than the pH of the dye remover compositon in comparative example 3 and 4.Therefore, the sensory stimuli evaluation of the dye remover compositon among the embodiment 1～4 remains " well ".In addition, when the sensory stimuli that keeps " well " was estimated, the dye remover compositon among the embodiment 1～4 reoxidized rate because of reducing sugar keeps low air.Second dose in the dye remover compositon among the embodiment 2 comprises Bian alcohol as the hair penetrating agent, reoxidizes rate with the air of dye remover compositon among the embodiment 1 and compares, and it keeps lower air to reoxidize rate.
On the other hand, it is low-level that the dye remover compositon in discovery comparative example 1 and the comparative example 2 can't make air reoxidize the rate maintenance, and wherein the compositions of comparative example 1 does not comprise reducing sugar, and the compositions of comparative example 2 comprises trehalose and non-reducing sugar.Dye remover compositon in the comparative example 3 contains Biformyl acid, though it can keep low air to reoxidize, it is good that the evaluation of stimulus to the sense organ fails to keep.When comparing with comparative example 3, when the content of the Biformyl acid in the comparative example 4 lowers with the attenuating sensory stimuli, to compare with comparative example 3, air reoxidizes rate and uprises.Therefore, find that Biformyl acid can't reoxidize rate by the attenuating air when lowering sensory stimuli.
Claims (10)
1. one kind is used to make through the painted fiber of oxidation dye and takes off the dye remover compositon that dyes, described oxidation dye comprises the dyestuff intermediate that band is amino, wherein said compositions comprises Reducing agent and carries out fiber by the reduction of described Reducing agent and take off and dye, it is characterized in that described dye remover compositon also comprises reducing sugar.
2. dye remover compositon as claimed in claim 1 is characterized in that, described reducing sugar is a monosaccharide.
3. dye remover compositon as claimed in claim 2 is characterized in that, described monosaccharide is to be selected from least a in xylose and the dihydroxy acetone.
4. as each the described dye remover compositon in the claim 1～3, it is characterized in that described Reducing agent is to be selected from least a in ascorbic acid, TGA, aminothiopropionic acid, sulfhydryl compound, sulphite, bisulfites and the thiosulfate.
5. as each the described dye remover compositon in the claim 1～4, also comprise the hair penetrating agent.
6. dye remover compositon as claimed in claim 5 is characterized in that, described hair penetrating agent is an aromatic alcohol.
7. as claim 5 or 6 described dye remover compositons, it is characterized in that described reducing sugar is an xylose, and the mass ratio of described xylose and described hair penetrating agent is 0.1～5.
8. as each the described dye remover compositon in the claim 1～7, it is characterized in that described reducing sugar is an xylose, the content of this xylose is 0.5～30 quality % in the described dye remover compositon.
9. as claim 5 or 6 described dye remover compositons, it is characterized in that described reducing sugar is a dihydroxy acetone, and the mass ratio of this dihydroxy acetone and described hair penetrating agent is 0.05～5.
10. as each the described dye remover compositon in claim 1～6 and 9, it is characterized in that described reducing sugar is a dihydroxy acetone, and the content of this dihydroxy acetone in described dye remover compositon is 0.05～30 quality %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005368622 | 2005-12-21 | ||
| JP368622/2005 | 2005-12-21 | ||
| JP234470/2006 | 2006-08-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101340891A true CN101340891A (en) | 2009-01-07 |
Family
ID=40214733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006800480712A Pending CN101340891A (en) | 2005-12-21 | 2006-12-21 | Dye remover compositon |
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|---|---|
| CN (1) | CN101340891A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020036269A1 (en) * | 2018-08-13 | 2020-02-20 | 장혜영 | Hair dye removing composition and preparation method therefor |
| CN112826758A (en) * | 2019-11-25 | 2021-05-25 | 株式会社爱茉莉太平洋 | Set for depigmenting hair |
-
2006
- 2006-12-21 CN CNA2006800480712A patent/CN101340891A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020036269A1 (en) * | 2018-08-13 | 2020-02-20 | 장혜영 | Hair dye removing composition and preparation method therefor |
| CN111989086A (en) * | 2018-08-13 | 2020-11-24 | 张蕙荣 | Composition for removing hair dye and preparation method thereof |
| US11141372B2 (en) | 2018-08-13 | 2021-10-12 | Hye Young Chang | Hair dye removing composition and preparation method therefor |
| CN112826758A (en) * | 2019-11-25 | 2021-05-25 | 株式会社爱茉莉太平洋 | Set for depigmenting hair |
| CN112826758B (en) * | 2019-11-25 | 2024-03-29 | 株式会社爱茉莉太平洋 | Kit for hair removal |
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