CN101319147A - Biological diesel oil for diesel engine and preparation method thereof - Google Patents
Biological diesel oil for diesel engine and preparation method thereof Download PDFInfo
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- CN101319147A CN101319147A CNA2008100101505A CN200810010150A CN101319147A CN 101319147 A CN101319147 A CN 101319147A CN A2008100101505 A CNA2008100101505 A CN A2008100101505A CN 200810010150 A CN200810010150 A CN 200810010150A CN 101319147 A CN101319147 A CN 101319147A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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Abstract
The present invention relates to the liquid fuel technical field, in particular to biological diesel oil for a diesel engine and a preparation method thereof. The compositions in portion by weight of the biological diesel are: 30 to 45 portions of oleyl alcohol, 30 to 45 portions of heavy hydrocarbon, 20 to 30 portions of vegetable oil, 0.1 to 1 portions of peroxide, 0.05 to 0.1 portions of sulphonate, and 1 to 6 portions of water, wherein, the heavy hydrocarbon is hydrocarbon between C17 and C23, the vegetable oil is colza oil, groundnut oil or bean oil, the oxide is peroxide with a molecular weight between 30 and 100, the water content of the oleyl alcohol is on more than 10 percent, the peroxide is TBPO, hyperis or acetone hydrogen peroxide, and the vegetable oil is colza oil, rice oil, groundnut oil or bean oil. The preparation method comprises the following steps of: a) mixing the oleyl alcohol and the water with stirring for 10 minutes, and sealing for further use; b) mixing the heavy hydrocarbon and the vegetable oil with stirring for 10 minutes, and sealing for further use; and c) mixing the mixture obtained in the step a) and the mixture obtained in the step b), then adding the peroxide and the sulphonate, with stirring for 10 minutes, and then sealing for 24 hours, and thus the product is obtained.
Description
Technical field
The present invention relates to liquid fuel technology field, particularly a kind of biological diesel oil for diesel engine and preparation method thereof.
Background technology
Present use for diesel engine fuel exists and consumes a large amount of non-renewable natural resourcess, and raw material is limited, so price is soaring day by day, reaches the degree that is difficult to bear, and drawback such as also pollute the environment after the burning.And present use for diesel engine fuel preparation method is very complicated, and equipment used is various, the production cost height.Simultaneously, also there is the unsafe problem of transportation in this use for diesel engine fuel.In order to protect non-renewable natural resources, reduce environmental pollution, reduce production costs, solve the transportation safety problem, promote the well-being of mankind, must a kind of novel use for diesel engine fuel of exploitation.
Summary of the invention
The object of the present invention is to provide a kind of reproducible, can reduce biological diesel oil for diesel engine environmental pollution, that reduce production costs, solve the transportation safety problem, promote the well-being of mankind.
Another object of the present invention provides a kind of preparation method who prepares described biological diesel oil for diesel engine.
The objective of the invention is to realize by following technical proposals:
Biological diesel oil for diesel engine of the present invention is characterized in that being made up of the parts by weight of following component: 30～45 parts of oleyl alcohol, 30～45 parts of heavy hydrocarbons, 20～30 parts of vegetables oil, 0.1～1 part of superoxide, 0.05～0.1 part in sulfonate, 1～6 part in water, described heavy hydrocarbon are C
17～C
23Between hydrocarbon, described vegetables oil is rapeseed oil, Rice pollard oil, peanut oil or soya-bean oil, described oxide compound is the superoxide of molecular weight between 30～100, the water content of described oleyl alcohol is no more than 10%.
Described superoxide is tertbutyl peroxide, hyperis or acetone hydrogen peroxide.
Described heavy hydrocarbon is C
17～C
23Between hydrocarbon, heavy hydrocarbon derives from the refining benzene in extraction oil in the petroleum by-product, heavy aromatics, the coal tar, described vegetables oil is rapeseed oil, Rice pollard oil, peanut oil or soya-bean oil.
Described biological diesel oil for diesel engine liquid fuel is made up of the parts by weight of following component: 35～35 parts of oleyl alcohol, 40～45 parts of heavy hydrocarbons, 20～25 parts of vegetables oil, 0.2～0.8 part of superoxide, sulfonate 0.06～0.09,2～5 parts in water.
Described biological diesel oil for diesel engine is made up of the parts by weight of following component: 40～45 parts of oleyl alcohol, 35～40 parts of heavy hydrocarbons, 25～28 parts of vegetables oil, 0.3～0.7 part of superoxide, sulfonate 0.065～0.085,2.5～4.5 parts in water.
Described biological diesel oil for diesel engine is made up of the parts by weight of following component: 35～40 parts of oleyl alcohol, 30～35 parts of heavy hydrocarbons, 28～30 parts of vegetables oil, 0.4～0.6 part of superoxide, sulfonate 0.07～0.08,3～4 parts in water.
A kind of preparation method of described biological diesel oil for diesel engine is characterized in that in envrionment temperature being to prepare according to the following step under 0～20 ℃ of condition:
A) 30～45 parts of oleyl alcohol of mass fraction are mixed the back with 1～6 water and stirred 10 minutes, seal stand-by,
B) 30～45 parts of heavy hydrocarbons mixed with 20～30 parts of vegetables oil stirred 10 minutes, seal stand-by,
C) with a) step gained mixture and b) step gained mixture mixes, and adds 0.1～1 part of superoxide and 0.05～0.1 sulfonate then, stirs after 10 minutes sealing 24 hours, promptly gets product of the present invention.More than the used container of operation can be a ceramic pot for not producing the electrostatic container, also can be the iron or the stainless steel metal jar of electrostatic grounding.
Water plays the dispersion agent effect in prescription, help simultaneously reducing cost, and helps the secondary energy utilization, and used oleyl alcohol and water total content must not surpass 20%; Belong to renewable resources; The molecular weight of superoxide is between 30～100.Biological diesel oil for diesel engine of the present invention can reduce environmental pollution, reduce production costs, solves the transportation safety problem.
Embodiment
Further specify the specific embodiment of the present invention below in conjunction with embodiment.
Biological diesel oil for diesel engine of the present invention is characterized in that being made up of the parts by weight of following component: 30～45 parts of oleyl alcohol, 30～45 parts of heavy hydrocarbons, 20～30 parts of vegetables oil, 0.1～1 part of superoxide, 0.05～0.1 part in sulfonate, 1～6 part in water, described heavy hydrocarbon are C
17～C
23Between hydrocarbon, described vegetables oil is rapeseed oil, peanut oil or soya-bean oil, described oxide compound is the superoxide of molecular weight between 30～100, the water content of described oleyl alcohol is no more than 10%.
Described superoxide is tertbutyl peroxide, hyperis or acetone hydrogen peroxide, and described heavy hydrocarbon is C
17～C
23Between hydrocarbon, heavy hydrocarbon derives from the refining benzene in raffinating oil in the petroleum by-product, heavy aromatics, the coal tar, described vegetables oil is rapeseed oil, Rice pollard oil, peanut oil or soya-bean oil.
Embodiment 1
Described biological diesel oil for diesel engine is made up of the parts by weight of following component: 30～35 parts of oleyl alcohol, 40～45 parts of heavy hydrocarbons, 20～25 parts of vegetables oil, 0.2～0.8 part of superoxide, sulfonate 0.06～0.09,2～5 parts in water.
Embodiment 2
Described biological diesel oil for diesel engine is made up of the parts by weight of following component: 40～45 parts of oleyl alcohol, 35～40 parts of heavy hydrocarbons, 25～28 parts of vegetables oil, 0.3～0.7 part of superoxide, sulfonate 0.065～0.085,2.5～4.5 parts in water.
Embodiment 3
Described biological diesel oil for diesel engine is made up of the parts by weight of following component: 35～40 parts of oleyl alcohol, 30～35 parts of heavy hydrocarbons, 28～30 parts of vegetables oil, 0.4～0.6 part of superoxide, sulfonate 0.07～0.08,3～4 parts in water.
A kind of preparation method of described biological diesel oil for diesel engine is characterized in that in envrionment temperature being to prepare according to the following step under 0～20 ℃ of condition:
A) 30～45 parts of oleyl alcohol of mass fraction are mixed the back with 1～6 water and stirred 10 minutes, seal stand-by,
B) 30～45 parts of heavy hydrocarbons mixed with 20～30 parts of vegetables oil stirred 10 minutes, seal stand-by,
C) with a) step gained mixture and b) step gained mixture mixes, and adds 0.1～1 part of superoxide and 0.05～0.1 sulfonate then, stirs after 10 minutes sealing 24 hours, promptly gets product of the present invention.More than the used container of operation can be a ceramic pot for not producing the electrostatic container, also can be the iron or the stainless steel metal jar of electrostatic grounding.
Water plays the dispersion agent effect in prescription, help simultaneously reducing cost, and helps the secondary energy utilization, and used oleyl alcohol and water total content must not surpass 20%; Heavy hydrocarbon is C
17～C
23Between hydrocarbon, heavy hydrocarbon derives from the refining benzene in extraction oil in the petroleum by-product, heavy aromatics, the coal tar, vegetables oil is rapeseed oil, Rice pollard oil or peanut oil or soya-bean oil; The molecular weight of superoxide is between 30～100.
Preparation method's specific embodiment 1:
In envrionment temperature is under 0 ℃ of condition: a) 35 gram oleyl alcohol are mixed the back with 2 gram water and stirred 10 minutes.Seal stand-by; B) with 40 gram C
17Heavy hydrocarbon mixes the back with 22.85 gram rapeseed oils and stirred 10 minutes, seals stand-by; C) with a) step gained mixture and b) step gained mixture mixes, and adds .0.1 gram superoxide and 0.05 gram sulfonate then, stirs after ten minutes and seals 24 hours, promptly gets product of the present invention.
Preparation method's specific embodiment 2:
In envrionment temperature is under 20 ℃ of conditions: a) 30 gram oleyl alcohol are mixed the back with 4 gram water and stirred 10 minutes.Seal stand-by; B) with 44 gram C
23Heavy hydrocarbon mixes the back with 20.9 gram peanut oil and stirred 10 minutes, seals stand-by; C) with a) step gained mixture and b) step gained mixture mixes, and adds the 1 gram tertiary butyl then and crosses fosterization hydrogen and 0.1 and restrain sulfonate, stirs after ten minutes and seals 24 hours, promptly gets product of the present invention.
Preparation method's specific embodiment 3:
In envrionment temperature is under 10 ℃ of conditions: a) parts by weight 40 gram oleyl alcohol are mixed the back with 4 gram water and stirred 10 minutes.Seal stand-by; B) with 30.42 gram C
18Heavy hydrocarbon mixes the back with 25 gram soya-bean oil and stirred 10 minutes, seals stand-by; C) with a) step gained mixture and b) step gained mixture mixes, and adds 0.5 gram sec.-propyl then and crosses fosterization hydrogen and 0.08 and restrain sulfonate, stirs after ten minutes and seals 24 hours, promptly gets product of the present invention.
Claims (6)
1, a kind of biological diesel oil for diesel engine is characterized in that being made up of the parts by weight of following component: 30～45 parts of oleyl alcohol, 30～45 parts of heavy hydrocarbons, 20～30 parts of vegetables oil, 0.1～1 part of superoxide, 0.05～0.1 part in sulfonate, 1～6 part in water, described heavy hydrocarbon are C
17～C
23Between derive from refining benzene in extraction oil in the petroleum by-product, heavy aromatics, the coal tar, described vegetables oil is rapeseed oil, Rice pollard oil, peanut oil or soya-bean oil, described oxide compound is the superoxide of molecular weight between 30～100, the water content of described oleyl alcohol is no more than 10%, and described superoxide is tertbutyl peroxide, hyperis or acetone hydrogen peroxide.
2, biological diesel oil for diesel engine according to claim 1 is characterized in that being made up of the parts by weight of following component: 30～35 parts of oleyl alcohol, 40～45 parts of heavy hydrocarbons, 20～25 parts of vegetables oil, 0.2～0.8 part of superoxide, 0.06～0.09 part in sulfonate, 2～5 parts in water.
3, biological diesel oil for diesel engine according to claim 1 is characterized in that being made up of the parts by weight of following component: 40～45 parts of oleyl alcohol, 35～40 parts of heavy hydrocarbons, 25～28 parts of vegetables oil, 0.3～0.7 part of superoxide, 0.065～0.085 part in sulfonate, 2.5～4.5 parts in water.
4, biological diesel oil for diesel engine according to claim 1 is characterized in that being made up of the parts by weight of following component: 35～40 parts of oleyl alcohol, 30～35 parts of heavy hydrocarbons, 28～30 parts of vegetables oil, 0.4～0.6 part of superoxide, 0.07～0.08 part in sulfonate, 3～4 parts in water.
5, the preparation method of the described biological diesel oil for diesel engine of a kind of claim 1 is characterized in that in envrionment temperature being to prepare according to the following step under 0～20 ℃ of condition:
A) 30～45 parts of oleyl alcohol of parts by weight are mixed the back with 1～6 water and stirred 10 minutes, seal stand-by
B) 30～45 parts of heavy hydrocarbons of parts by weight mixed with 20～30 parts of vegetables oil stirred 10 minutes, seal stand-by,
C) with a) step gained mixture and b) step gained mixture mixes, add 0.1～1 part of superoxide of parts by weight and 0.05～0.1 sulfonate then, stir after 10 minutes and seal 24 hours, promptly get product of the present invention, more than the used container of operation is not for producing the electrostatic container: the iron of ceramic pot, electrostatic grounding or stainless cylinder of steel.
6, the preparation method of biological diesel oil for diesel engine according to claim 9 is characterized in that in envrionment temperature being to prepare according to the following step under 10 ℃ of conditions:
A) be 40 oleyl alcohol with parts by weight with parts by weight be that 4 water mixes the back and stirred 10 minutes, seal stand-by,
B) with parts by weight be 30.42 C
18Heavy hydrocarbon and parts by weight are that 25 soya-bean oil mixes the back and stirred 10 minutes, seal stand-by,
C) with a) step gained mixture and b) step gained mixture mixes, and adds ratio of weight and number then and be 0.5 hyperis and parts by weight and be 0.08 sulfonate, stirs after ten minutes sealing 24 hours, promptly gets product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100101505A CN101319147A (en) | 2008-01-18 | 2008-01-18 | Biological diesel oil for diesel engine and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100101505A CN101319147A (en) | 2008-01-18 | 2008-01-18 | Biological diesel oil for diesel engine and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101319147A true CN101319147A (en) | 2008-12-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100101505A Pending CN101319147A (en) | 2008-01-18 | 2008-01-18 | Biological diesel oil for diesel engine and preparation method thereof |
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| CN (1) | CN101319147A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103998582A (en) * | 2011-11-16 | 2014-08-20 | 联合引发剂有限责任两合公司 | Tert-butyl hydroperoxide (TBHP) as a diesel additive |
-
2008
- 2008-01-18 CN CNA2008100101505A patent/CN101319147A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103998582A (en) * | 2011-11-16 | 2014-08-20 | 联合引发剂有限责任两合公司 | Tert-butyl hydroperoxide (TBHP) as a diesel additive |
| US9303224B2 (en) | 2011-11-16 | 2016-04-05 | United Initiators Gmbh & Co. Kg | Tert-butyl hydroperoxide (TBHP) as a diesel additive |
| CN103998582B (en) * | 2011-11-16 | 2016-05-18 | 联合引发剂有限责任两合公司 | As the TBHP of diesel fuel additives |
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Open date: 20081210 |