Summary of the invention
The purpose of this invention is to provide a kind of can the realization under window or door closure state introduces the room outer air indoor; Simultaneously the air of indoor pollution is discharged to multifunctional thermal insulation aeration clearing window or door outside the room, and carry out the exchange of sensible heat and latent heat between the room outer air in scavenging period in the inlet chamber and the air of indoor eliminating, thereby in scavenging period, do not change indoor original temperature and humidity.
Another object of the present invention provides and a kind ofly can realize that dynamic bactericidal purifying handles room air, effectively improves the window or the door of IAQ (indoor air quality).
Technical scheme of the present invention is as follows:
Multifunctional thermal insulation aeration clearing window of the present invention or door comprise window, doorframe; Window or door leaf and switching mechanism etc. that window, Door leaf frame and glass are formed, be provided with at least one air heat-exchanging device in described window, doorframe or window, the Door leaf frame, wherein, described air heat-exchanging device can comprise: heat exchanger plate stacks with certain interval, thereby formed second air duct that first air duct that the room air that is discharged to outside the room passes through and the room outer air in the suction chamber are passed through successively, first corrugated sheet is placed in first air duct, thereby obtains the space that the permission room air passes through; Be placed in second air duct with second corrugated sheet, thereby obtain the space that permission room outer air is passed through; First ventilation stack that is connected with first air duct of described air heat-exchanging device is formed in described window, doorframe or described window, the Door leaf frame; Second ventilation stack that is connected with second air duct of described air heat-exchanging device is formed in described window, doorframe or described window, the Door leaf frame; Described first, second ventilation stack can be formed by the inwall of described window, doorframe or described window, Door leaf frame, also can be formed by pipe arrangement, and the inwall of described first, second ventilation stack can also add one deck heat insulating material; First air inlet port and first gas outlet of room air can be set on the described window, doorframe or the described window that form described first ventilation stack, Door leaf frame; Second air inlet port and second gas outlet of room outer air can be set on the described window, doorframe or the described window that form described second ventilation stack, Door leaf frame; Can be provided near described first air inlet port or first gas outlet that room air introduced described first ventilation stack and first air duct and be discharged to exhauster outside the room; And can be provided near described second air inlet port or second gas outlet that the room outer air is introduced described second ventilation stack and second air duct advances indoor lift pump side by side; In addition, also include the control device and the power supply of the running of described exhauster of control and lift pump.Like this, when lift pump, exhauster running, air outside the room will be introduced indoor by described second ventilation stack and second air duct, indoor contaminated air will be discharged to outside the room by described first ventilation stack and first air duct, in this process, air outside the air of indoor discharge and the room in the inlet chamber carries out the exchange of heat and humidity by described air heat-exchanging device, thereby guarantees indoorly to guarantee that in the interchange of air process original temperature and humidity is constant substantially.
Described air heat-exchanging device in the technical program comprises indoor, described first air duct and second air duct that the room outer air is passed through adjacent but that do not communicate, described first air duct and second air duct are communicated with described first ventilation stack and described second ventilation stack respectively, and an end of described first ventilation stack is communicated with described first air inlet port, and the other end is communicated with described first gas outlet; Be communicated with described second air inlet port with an end of described second ventilation stack, the other end is communicated with described second gas outlet, when described exhaust blower and suction fan work, room air is from entering first air duct of described air heat-exchanging device after described first air inlet port enters described first ventilation stack again, the room outer air enters second air duct that described second ventilation stack enters described air heat-exchanging device then from described second air inlet port, at this moment, room air and room outer air are carried out sensible heat and latent heat exchange in described air heat-exchanging device, by sensible heat and latent heat exchange heat in the room air and humidity are passed to the air that enters outside the room, after exchange is finished, in the described second gas outlet inlet chamber, indoor exhaust air is discharged to outside the room through described first gas outlet by described first ventilation stack air outside the room in the inlet chamber by described second ventilation stack.
The described heat exchange device for air of this programme can adopt can heat conduction leads wet material and makes, and furtherly, can adopt the composite material of can heat conduction leading wet paper material or having an identical function to make.Furtherly, described paper material can also contain bamboo charcoal or active bamboo.Because the beam tube fiber of bamboo communicates before and after being, the left and right sides is parallel, and therefore, bamboo has many trickle apertures fitly to be studded with along the beam tube fiber through behind the high temperature cabonization, thereby makes bamboo charcoal or active bamboo have good heat transfer damping effect.When containing wetly air when containing the mixture of bamboo charcoal or active bamboo, the many trickle aperture of bamboo charcoal or active bamboo will suck moisture, when the air of drying passed through bamboo charcoal or active bamboo, it can discharge the moisture that sucks in the trickle aperture air to drying again.Therefore, the Bamboo-carbon paper by paper material and bamboo charcoal or active bamboo are mixed and made into has good heat conductivity and wet conductibility, can improve indoor and the heat exchanger effectiveness room outer air; Simultaneously, because bamboo charcoal or active bamboo have antibiotic, antibacterial, anti-mite and superpower anti-static function, therefore, can make described heat exchange device for air have self-cleaning function again, prevent that various mushrooms adhere on it in the air.
In order further to improve the heat exchanger effectiveness of described heat exchange device for air, its structure can adopt the vertical corrugated board structures of handing over mutually (plate-fin structure), can certainly adopt other structure.
Can heat conduction the leading wet described paper material and can adopt of the described heat exchange device for air of this programme as the disclosed paper material of China Patent No. 97122545.1 patent specifications, also can adopt Chinese patent 93209878.9, name is called disclosed material in the patent documentation of " dismountable fibre paper film heat is changed interchanger ", can also adopt Chinese patent ZL200520129985.4, name is called in " the damp and hot switch of air " disclosed heat conduction and leads wet material, can also be to make, but paper material of the present invention be not limited only to above-mentioned material by the bamboo fibre paper that bamboo fiber is made.
Described lift pump of the technical program and exhauster can be to be driven by a coaxial motor, have therefore saved a motor, have simplified the structure of aeration clearing window of the present invention or door.
Described second air inlet port of the technical program and/or first air inlet port can be provided with the screen pack of demountable cleaning, so that filter out the dust granule in the room outer air and filter out the dust granule that room air enters air heat-exchanging device, guarantee to suck the quality of room air; In addition, screen pack or directly adopt the mode that numerous air vents are set to filter out dust in air also can be set in described first, second gas outlet on described window, doorframe or described window, Door leaf frame.Have again, described second air inlet port can also be provided with can disassembly, cleaning the high density filter device used of toilet making such as () HEPA filter materials, further improve the air quality in the inlet chamber.
Suction, the required power supply of exhauster can be common powers described in the technical program, also can be the solar-energy photo-voltaic cell power supplys, the glass on described sash or the door leaf can also be changed into the photoelectricity plastics, and the electric energy that is produced by the photoelectricity plastics provides then.
The surface of the inwall of described second ventilation stack in the technical program can process and form the Surface Machining layer, described Surface Machining layer can have degerming portion, described degerming portion can comprise optical semiconductor catalyst and/or apatite, therefore, it not only can capture, viral adsorption or germ, can also remove virus or germ etc. energetically.
In the technical program, near the described second ventilation stack downstream (described second gas outlet) can be provided with an air cleaning unit, described air cleaning unit can include a degerming portion, therefore, described air cleaning unit not only can capture, viral adsorption or germ, can also remove virus or germ etc. energetically.Described air air cleaning unit can be the downstream that is fixedly installed in described second ventilation stack, also can be the downstream that releasably is installed on described second ventilation stack, preferably releasably installs, and is convenient to maintain and replace like this.
Optical semiconductor catalyst can also be contained in described degerming portion.By the light of irradiation particular range of wavelengths, described semiconductor catalyst can be removed at least one side in airborne virus or the germ.In addition, the what is called here " semiconductor catalyst " is meant that with titanium oxide, strontium titanates, zinc oxide, tungsten oxide and iron oxide etc. be the metal oxide of representative; With C
60Deng fullerene is that the carbon of representative is optical semiconductor catalyst; Nitride, the oxynitride that forms by transition metal, apatite etc. with photo-catalysis function.In addition, can consider to adopt following method as the way that light is provided to this optical semiconductor catalyst: (1) is provided with light source in its vicinity; (2) can make the part of ventilation stack transparent, introduce outside the room or indoor light; (3) import outside the room or indoor light by reflecting plate etc.; Perhaps (4) are by LGP or optical fiber lead-in light etc.
Because optical semiconductor catalyst is contained in degerming portion in the air cleaning unit of the technical program, therefore, utilizes this air cleaning unit, if this optical semiconductor catalyst is shone the light of suitable wave-length coverage, just can remove virus removal or germ energetically.
In addition, the degerming portion of the technical program can further include the adsorption section, described adsorption section can absorbing pathogenic bacteria or virus at least one side.
Apatite is contained in described adsorption section.Here so-called " apatite " is to be that (wherein, A represents various metallic atoms such as Ca, Co, Ni, Cu, Al, La, Cr, Fe, Mg to Ax (BOy) zXa with the chemical formula; B represents atoms such as P, S; X represents that (OH) or the material of halogen atom (for example, F, Cl etc.) expression, its representative substances has hydroxyapatite, fluor-apatite and chlorapatite, and calcium phosphate and calcium monohydrogen phosphate etc. with hydroxyl.Wherein, use Ca
10(PO
4)
6(OH)
2The calcium hydroxy apetite of expression because of cation exchange and all generations easily of anion exchange, so have abundant adsorptivity, particularly has excellent adsorption capacity to organic matters such as protein.In addition, known calcium hydroxy apetite can suppress the propagation of these mushrooms and virus by strong absorption mould, bacterium and virus etc.
In the technical program, known this apatite shows the high characterization of adsorption to virus or germ etc.This is main because apatite has electric charge, and easy and virus or germ etc. form hydrogen bond or ionic bond etc.Therefore, degerming portion viral adsorption or germ etc. securely.So, utilize this air cleaning unit, can further improve efficient except that virus removal or bacterium etc.
In the technical program, described apatite can also be the apatite with photo-catalysis function.In addition, so-called here " apatite with photo-catalysis function " is that for example the part calcium atom in the hydroxyapatite is replaced as the apatite of titanium atom, i.e. titanium apatite etc. by methods such as ion-exchanges.
Generally, use the mixture etc. of adsorbents such as zeolite and titanium dioxide as optical semiconductor catalyst always.On the other hand, known apatite is to the characterization of adsorption height of virus or germ.Therefore, consider to use apatite as the effect of adsorbent with raising degerming portion.But, even with such apatites mixed in optical semiconductor catalyst, also only be that near virus the two acidifying titaniums that are adsorbed in the performance photo-catalysis function or germ etc. are had effect, and for by apatite adsorbed but near do not have two acidifying titaniums to exist virus or germ, these viruses or germ can not be removed.But in the technical program, apatite is the apatite with photo-catalysis function.That is to say that absorption position itself just has photo-catalysis function, like this, just can remove nearly all virus that is adsorbed or germ etc.So, utilize this air cleaning unit can further improve efficient except that virus removal or germ etc., guarantee the purified treatment quality that enters room air.
In the technical program, the upstream side of described air cleaning unit can also further be furnished with charged elements, and this charged elements can be so that at least one side in germ and the germ be charged.Generally, apatite has the adsorption capacity to virus or germ, and this is because apatite is considered to have electric charge, the reason that can combine with formation static such as virus that has weak charge or germs, and this charged elements has played this effect just.
In the technical program, apatite is contained in degerming portion, and the upstream side that flows at degerming portion air is provided with charged elements.Therefore, virus or germ are before reaching apatite, be endowed stronger electric charge in described charged elements, like this, charged virus or germ are adsorbed by apatite when reaching apatite easilier, thereby improve the capture rate of air cleaning unit to virus or germ, therefore, can further improve air purification ability of the present invention.
In second ventilation stack of the technical program, can also further be furnished with the active substance delivery device.The active substance delivery device can be arranged near the downstream (second gas outlet) of described second ventilation stack, thereby provides active material in will introducing indoor air.In addition, so-called here " active substance delivery device " can be negative oxygen ion generator.Negative oxygen ion is called as human body " air vitamin ", can enter human body by human skin cell's gap, but can prevent skin aging and relieving fatigue.Simultaneously, remaining particle and harmful organic molecule in anion and the room air, for example, benzene molecular, formaldehyde molecule bumps against, make it charged, this charged particle and harmful organic molecule are easy to by the absorption of things such as wall in the room and ceiling, thereby indoor air is further purified.In addition, described active substance delivery device also can be arranged on the upstream side of described air cleaning unit, at this moment, the radical type material that the energy level that described active substance delivery device discharged is very high etc. can activate air cleaning unit in described optical semiconductor catalyst or have the photo-catalysis function of the apatite of photo-catalysis function, thereby quicken optical semiconductor catalyst or have the photocatalysis response speed of the apatite of photo-catalysis function, its result will cause described air cleaning unit can further remove virus removal or germ and other harmful organic molecules efficiently.
As a kind of improvement of technical solution of the present invention, it may further include: be communicated with described first and second ventilation stacks and be furnished with the 3rd ventilation stack of described air cleaning unit, the member that forms described the 3rd ventilation stack can be removably; Be arranged at the upstream side of described second ventilation stack, second switching mechanism of described second ventilation stack of switching; The 3rd switching mechanism with the connecting portion that is arranged at described first ventilation stack and described the 3rd ventilation stack, described first ventilation stack of switching and described the 3rd ventilation stack; Described second switching mechanism and described the 3rd switching mechanism can link.
In the technical program, the inner wall surface of described the 3rd ventilation stack can be processed and be formed the Surface Machining layer, described Surface Machining layer can have degerming portion, described degerming portion can comprise optical semiconductor catalyst and/or apatite, therefore, it not only can capture, viral adsorption or germ, can also remove virus or germ etc. energetically.In addition, the inwall of described the 3rd ventilation stack can also add one deck heat insulating material, and described degerming portion is formed on side outside the described heat insulating material, so both can remove the loss that virus or germ can also avoid heat energetically.
The described lift pump of the technical program, exhauster do not use coaxial motor to drive, but control respectively, in addition, described air cleaning unit can no longer be set in the downstream of described second ventilation stack.
The technical program is except that having increased described the 3rd ventilation stack and having formed member, the described second and the 3rd switching mechanism, other structure, the structure and the aforementioned schemes of first and second ventilation stacks, described heat exchange device for air, described first, second air inlet port and described first, second gas outlet are basic identical as described, repeat no more herein.
The described air cleaning unit of the technical program can include a degerming portion, and therefore, described air cleaning unit not only can capture, viral adsorption or germ, can also remove virus or germ etc. energetically.
Optical semiconductor catalyst can also be contained in described degerming portion.By the light of irradiation particular range of wavelengths, described semiconductor catalyst can be removed at least one side in airborne virus or the germ.In addition, the what is called here " optical semiconductor catalyst " is meant that with titanium oxide, strontium titanates, zinc oxide, tungsten oxide and iron oxide etc. be the metal oxide of representative; With C
60Deng fullerene is that the carbon of representative is optical semiconductor catalyst; Nitride, the oxynitride that forms by transition metal, apatite etc. with photo-catalysis function.In addition, can consider to adopt following method as the way that light is provided to this optical semiconductor catalyst: (1) is provided with light source in its vicinity; (2) can make the part of ventilation stack transparent, introduce outside the room or indoor light; (3) import outside the room or indoor light by reflecting plate etc.; Perhaps (4) are by LGP or optical fiber lead-in light etc.The technical program preferably is provided with a uviol lamp in the formation member of described the 3rd ventilation stack, described uviol lamp sends and is used for the catalytic reaction of activation light semiconductor catalyst.
Because optical semiconductor catalyst is contained in degerming portion in the air cleaning unit of the technical program, therefore, utilizes this air cleaning unit, if this optical semiconductor catalyst is shone the light of suitable wave-length coverage, just can remove virus removal or germ energetically.
In addition, the degerming portion of the technical program also further comprises the adsorption section, described adsorption section can absorbing pathogenic bacteria or virus at least one side.
Apatite is contained in described adsorption section.Here so-called " apatite " is to be that (wherein, A represents various metallic atoms such as Ca, Co, Ni, Cu, Al, La, Cr, Fe, Mg to Ax (BOy) zXa with the chemical formula; B represents atoms such as P, S; X represents that (OH) or the material of halogen atom (for example, F, Cl etc.) expression, its representative substances has hydroxyapatite, fluor-apatite and chlorapatite, and calcium phosphate and calcium monohydrogen phosphate etc. with hydroxyl.Wherein, use Ca
10(PO
4)
6(OH)
2The calcium hydroxy apetite of expression because of cation exchange and all generations easily of anion exchange, so have abundant adsorptivity, particularly has excellent adsorption capacity to organic matters such as protein.In addition, known calcium hydroxy apetite can suppress the propagation of these mushrooms and virus by strong absorption mould, bacterium and virus etc.
In the technical program, apatite is contained in described adsorption section.Known this apatite shows the high characterization of adsorption to virus or germ etc.This is main because apatite has electric charge, and easy and virus or germ etc. form hydrogen bond or ionic bond etc.Therefore, degerming portion viral adsorption or germ etc. securely.So, utilize this air cleaning unit, can further improve efficient except that virus removal or bacterium etc.
In the technical program, described apatite can be the apatite with photo-catalysis function.In addition, so-called here " apatite with photo-catalysis function " is that for example the part calcium atom in the hydroxyapatite is replaced as the apatite of titanium atom, i.e. titanium apatite etc. by methods such as ion-exchanges.
Generally, use the mixture etc. of adsorbents such as zeolite and titanium dioxide as optical semiconductor catalyst always.On the other hand, known apatite is to the characterization of adsorption height of virus or germ.Therefore, consider to use apatite as the effect of adsorbent with raising degerming portion.But, even with such apatites mixed in optical semiconductor catalyst, also only be that near virus the two acidifying titaniums that are adsorbed in the performance photo-catalysis function or germ etc. are had effect, and for by apatite adsorbed but near do not have two acidifying titaniums to exist virus or germ, these viruses or germ can not be removed.But in the technical program, apatite is the apatite with photo-catalysis function.That is to say that absorption position itself just has photo-catalysis function, like this, just can remove nearly all virus that is adsorbed or germ etc.So, utilize this air cleaning unit can further improve efficient except that virus removal or germ etc., further guarantee the depuration quality of room air.
In addition, when measuring the titanium dioxide of similar face and titanium apatite to organic capacity of decomposition, titanium apatite demonstrates the decomposability higher than titanium dioxide, but, when measuring the titanium dioxide of equivalent weight and titanium apatite to organic decomposability, titanium dioxide demonstrates the capacity of decomposition higher than titanium apatite.The former little degree that can not make titanium apatite from manufacturing techniques available of its reason to the titanium dioxide particle diameter.That is to say, the specific area of titanium dioxide is bigger than the specific area of titanium apatite, so, when being subjected to the restriction of weight of the optical semiconductor catalyst that described air cleaning unit can load, only adopt titanium apatite as optical semiconductor catalyst, may go down organic capacity of decomposition.
But in the technical program, described air cleaning unit also contains optical semiconductor catalyst, and therefore, the optical semiconductor catalyst that particle diameters such as titanium dioxide are little enters the gap of titanium apatite, and the activity that can make photocatalysis reflection is crypto set more.In addition, because titanium apatite has replenished the low absorbability of titanium dioxide,, can remove virus or germ etc. efficiently so can realize like this, utilizing this air cleaning unit than titanium dioxide or the more excellent capacity of decomposition of apatite monomer.
Can also further be furnished with charged elements in the air cleaning unit of the technical program.Described charged elements can be set at the upstream side that degerming portion air flows.In addition, this charged elements can be so that at least one side in germ and the germ be charged.Generally, apatite has the adsorption capacity to virus or germ, and this is because apatite is considered to have electric charge, the reason that can combine with formation static such as virus that has weak charge or germs, and this charged elements has played this effect just.
In the technical program, apatite is contained in degerming portion, and the upstream side that flows at degerming portion air is provided with charged elements.Therefore, virus or germ are before reaching apatite, be endowed stronger electric charge in described charged elements, like this, charged virus or germ are adsorbed by apatite when reaching apatite easilier, thereby improve the capture rate of described air cleaning unit to virus or germ, therefore, can further improve this air purification disposal ability.
Can also further be furnished with the active substance delivery device in described the 3rd ventilation stack of the technical program.Described active substance delivery device can be arranged on the upstream side of the described air cleaning unit in described the 3rd ventilation stack, at this moment, the radical type material that the energy level that described active substance delivery device discharged is very high etc. can activate air cleaning unit in described optical semiconductor catalyst or have the photo-catalysis function of the apatite of photo-catalysis function, thereby quicken optical semiconductor catalyst or have the photocatalysis response speed of the apatite of photo-catalysis function, its result will cause described air cleaning unit can further remove virus removal or germ and other harmful organic molecules efficiently.In addition, described active substance delivery device can also be arranged near the mobile downstream (the 3rd gas outlet) of air of described the 3rd ventilation stack, thereby provides active material in will introducing indoor air or air cleaning unit.In addition, so-called here " active substance delivery device " can be negative oxygen ion generator.Negative oxygen ion is called as human body " air vitamin ", can enter human body by human skin cell's gap, but can prevent skin aging and relieving fatigue.Simultaneously, remaining particle and harmful organic molecule in anion and the room air, for example, benzene molecular, formaldehyde molecule bumps against, make it charged, this charged particle and harmful organic molecule are easy to by the absorption of things such as wall in the room and ceiling, thereby indoor air is further purified.In addition, " active substance delivery device " here can be for example glow discharge device, barrier discharge device or streamer discharge device.Here " active material " can be for example radical type material such as high-velocity electrons, ion, ozone, hydroxyl radical free radical or its molecule that excites etc.
In the technical program,, an active material resolving cell can also be set in order to control the injury that excessive active material that the active substance delivery device decomposed may cause human body.Active material resolving cell herein can be active carbon filtering device of for example ozone decomposition etc.
The technical program can realize two kinds of operational modes, and first kind is two-way ventilatory pattern, and the air purification effect of this pattern is identical with above-described technical scheme.Second kind is circulation mode in the air chamber, and this pattern is to utilize the interior circulation of room air, by the degerming portion that is arranged on the air cleaning unit in window frame or the window Door leaf frame or be arranged on described the 3rd ventilation stack inwall room air is carried out sterilizing.Because SARS or influenza is popular, need carry out sterilization processing at room air, therefore, when the technical program is implemented, described exhauster is idle, so, exhauster in the technical program and lift pump can not use coaxial motor, when lift pump is worked, room air enters described first ventilation stack by described first air inlet port, enter described the 3rd ventilation stack again by described first air duct then, finish sterilization and disinfection room air through the air cleaning unit in described the 3rd ventilation stack or the degerming portion on described the 3rd ventilation stack inwall of being arranged on.
The switching of two kinds of operational modes of the technical program can realize by the interlock of described second, third switching mechanism of described control device control.
In sum, multifunctional thermal insulation aeration clearing window of the present invention or door have the following advantages, and (1) can remove interior air pollution effectively by the interchange of air outside indoor and the room, the cleaning of assurance room air and pure and fresh; (2) exchange of sensible heat and latent heat be can between indoor and room outer air, carry out, thereby indoor original temperature and humidity, energy conservation guaranteed in the indoor air-changing process, not change; (3) when SARS or influenza pandemic take place in the society, aeration clearing window of the present invention can inlet chamber in the air circulation sterilization mode, room air is carried out effective bactericidal purifying handles; (4) avoided windowing or opening the door ventilating and changed excessive indoor secondary pollution that causes and room temperature; (5) its is simple in structure, and cost is low, is convenient to install and does not influence indoor attractive in appearance, and (6) are convenient to maintenance.
Other purpose of the present invention, advantage and outstanding characteristics will be from below in conjunction with becoming more obvious the detailed description of accompanying drawing to best mode for carrying out the invention.
The specific embodiment
Hereinafter, in conjunction with the accompanying drawings the multifunctional thermal insulation aeration clearing window of the present invention's first to the 5th exemplary embodiment is done detailed description.The structure of multifunctional thermal insulation aeration clearing door of the present invention is all identical with multifunctional thermal insulation aeration clearing window with principle, no longer is repeated in this description here.
Introduce the multifunctional thermal insulation aeration clearing window of the present invention's first exemplary embodiment below.
Fig. 1 is the schematic diagram of one of multifunctional thermal insulation aeration clearing window of the present invention or door window, and Fig. 2 is the two-way ventilation partial schematic diagram of the present invention's first exemplary embodiment multifunctional thermal insulation aeration clearing window.
As shown in Figure 1 and Figure 2, multifunctional thermal insulation aeration clearing window 1 can comprise window frame 102; Sash or door leaf and switching mechanism (not shown) etc. that window sash frame 103 and glass 104 are formed can be provided with one or more air heat-exchanging devices 105 (105 ') (present embodiment is 3) in the window frame 102; First ventilation stack 108 and second ventilation stack 109 that are formed by the inwall of window frame 102 can be provided with first air inlet port 110 and be provided with first gas outlet 111 in the downstream at the upstream side of first ventilation stack 108; Upstream side at second ventilation stack 109 can be provided with second air inlet port 112 and can be provided with second gas outlet 113 in the downstream, comprises on the window frame 102 that at least one is used for the exhauster 106 that room air is discharged to outside the room is used for the room outer air is introduced indoor lift pump 107 with at least one; A filter 114 that is installed in second air inlet port, 112 places, in addition, multifunctional thermal insulation aeration clearing window 1 also comprises the power supply that exhauster 106 and lift pump 107 power are provided and controls exhauster 106 and the control device (not shown) of lift pump 107 runnings.
[formation of air heat-exchanging device]
As shown in Figure 9, air heat-exchanging device 105 comprises that heat exchanger plate 105a stacks with certain interval, thereby formed the second air duct 105c that the first air duct 105b that the room air that is discharged to outside the room passes through and the room outer air in the suction chamber are passed through successively, the first corrugated sheet 105d is placed among the first air duct 105b, thereby obtains the space that the permission room air passes through; Be placed among the second air duct 105c with the second corrugated sheet 105e, thereby obtain the space that permission room outer air is passed through.The first corrugated sheet 105d and the formed air of the second corrugated sheet 105e can be square crossings by space (passage).
The heat exchanger plate 105a of heat exchange device for air 105 and/or first, second corrugated sheet 105d, 105e can adopt and can heat conduction lead wet material and make, furtherly, can adopt the extrusion coating paper material of can heat conduction leading wet paper material or having an identical function to make.As adopting the disclosed paper material of China Patent No. 97122545.1 patent specifications, also can adopt Chinese patent 93209878.9, name to be called disclosed material in the patent documentation of " dismountable fibre paper film heat is changed interchanger ", can also adopt Chinese patent ZL200520129985.4, name to be called in " the damp and hot switch of air " disclosed heat conduction and lead wet material.Like this, as room air PA and room outer air OA during by heat exchange device for air 105, room air PA and room outer air OA will carry out sensible heat and latent heat exchange, promptly the heat exchanger plate 105a that is made by paper material can pass to room outer air OA with heat among the room air PA and humidity, thereby guarantees that indoor original temperature and humidity remains unchanged in the scavenging period.
As a further improvement on the present invention, to lead in the wet stock can also be that Bamboo-carbon paper with paper material mixings bamboo charcoal or active bamboo formation is made to the heat conduction used of heat exchange device for air 105.Because the beam tube fiber of bamboo communicates before and after being, the left and right sides is parallel, therefore, has many trickle apertures fitly to be studded with along the beam tube fiber after the carbonization, thereby makes bamboo charcoal or active bamboo have good heat transfer damping effect.When containing wetly air when containing the mixture of bamboo charcoal or active bamboo, the many trickle aperture of bamboo charcoal or active bamboo will suck moisture, when the air of drying passed through bamboo charcoal or active bamboo, it can discharge the moisture that sucks in the trickle aperture air to drying again.Therefore, the Bamboo-carbon paper that paper material and bamboo charcoal or active bamboo are mixed and made into, conductibility with better heat and humidity, simultaneously, again because bamboo charcoal or active bamboo have antibiotic, antibacterial, anti-mite and superpower anti-static function, therefore, the heat exchange device for air 105 that uses Bamboo-carbon paper to make has self-cleaning function, prevents that various mushrooms adhere on it in the air.
Further improve as of the present invention, it can also be that bamboo fibre paper by bamboo fiber is made is made that the heat conduction that heat exchange device for air 105 uses is led in the wet stock.
The bamboo fiber natural bamboo that has drawn from, the bamboo of preferred 3-5 boils into bamboo pulp through high temperature, extracts bamboo fibre then and makes bamboo fibre paper.The paper technology of its manufacturing process and common wood fibre is basic identical, repeats no more here.Owing to be covered with big and small hole on the bamboo fibre cross section, height hollow can freely absorb also transpiring moisture, and therefore, its conductivity of heat, hygroscopicity, wet putting, gas permeability are all better than the fiber of any other material.Simultaneously, scientist finds, antibacterial material-" the bamboo a kind of jade " that has a kind of uniqueness in the bamboo, and this material has natural antibiotic and deodorization functions, and therefore, this bamboo fibre paper also has antibiotic, antibacterial, anti-mite and superpower antistatic property.Like this, the heat exchange device for air of being made by bamboo fibre paper 105 has following outstanding advantage: (1) can improve the exchange efficiency of sensible heat and latent heat greatly; (2) superpower antistatic behaviour can prevent that micronic dust from adsorbing on it; (3) can carry out sterilization processing for the bacterium and the virus of adsorbing on it, make heat exchange device for air 105 have self-cleaning function, further guarantee by the air quality in its inlet chamber; (4) because the speed of growth of bamboo is that all plant classes are the fastest, therefore, can reduce the manufacturing cost of heat exchange device for air 105.
Therefore, heat exchanger plate 105a in the heat exchange device for air 105 and/or first, second corrugated sheet 105d, 105e then can further improve sensible heat efficient and latent heat efficient as adopting Bamboo-carbon paper or bamboo fibre paper, simultaneously, also make heat exchange device for air 105 have self-cleaning function.But heat conduction of the present invention is led wet stock and is not limited only to above-mentioned material.
In order to improve the heat exchanger effectiveness of heat exchange device for air 105, its structure can adopt the vertical corrugated board structures of handing over mutually (also claiming plate-fin structure) as shown in Figure 9, can certainly adopt other structure.The cross section of first, second air duct 105b and 105c preferably adopts the equilateral triangle structure, and the thickness of heat exchanger plate 105a is preferably between the 20 μ m-90 μ m, and the thickness of first, second corrugated sheet 105d, 105e is preferably between the 0.1mm-0.5mm.
The cross section of certain first and second air ducts also can adopt as shown in figure 10 heat exchange device for air 105 ' shown in square structure.
In addition, the sensible heat when flowing through heat exchange device for air 105 (105 ') and the exchange efficiency of latent heat in order further to improve room air PA and room outer air OA, the available ventilation cross-sectional area of the first air duct 105b that can make heat exchange device for air 105 (105 ') is greater than the available ventilation cross-sectional area of the second air duct 105c, like this, the flowing velocity of room air PA in the first air duct 105b will be faster than the flowing velocity of room outer air OA in the second air duct 105c, therefore, room outer air OA in the inlet chamber can absorb heat and the humidity among the room air PA more fully, improves the exchange efficiency of sensible heat and latent heat.
Have again, heat exchange device for air 105 (105 ') putting in first and second ventilation stacks 108,109 can be as shown in Figure 2, word order is placed in the window frame 102 even its diagonal angle links to each other, wherein cornerwise one of them diagonal angle away from word order contacts with the inwall that is in the indoor of window frame 102, and another cornerwise diagonal angle away from word order contacts with the inwall that window frame 102 is in the outside, room.Certainly, the present invention can also have other aligning method.
[formation of ventilation system]
(1) first ventilation stack and second ventilation stack
As Fig. 2, shown in Figure 9, first ventilation stack 108 and second ventilation stack 109 are formed at respectively in the window frame 102.First ventilation stack 108 and second ventilation stack 109 can be made of the inwall of window frame 102, also can by pipe arrangement respectively (not shown) constitute.When first ventilation stack 108 and second ventilation stack 109 are made of the inwall of window frame 102, the inwall that forms the window frame 102 of first ventilation stack 108 is connected with upstream extremity 115 and the downstream 116 of the first air duct 105b of heat exchange device for air 105 (105 ') respectively, formation is discharged to air channel outside the room, i.e. PA hollow arrow direction along the line among Fig. 2 with room air PA; Second ventilation stack 109 is connected with upstream extremity 117 and the downstream 118 of the second air duct 105c of heat exchange device for air 105 (105 '), forms room outer air OA is introduced indoor air channel, i.e. OA hollow arrow direction along the line among Fig. 2.When first ventilation stack 108 and second ventilation stack 109 are made of pipe arrangement, the pipe arrangement that forms first ventilation stack 108 is connected respectively with upstream extremity 115 and the downstream 116 of the first air duct 105b of heat exchange device for air 105 (105 '), formation is discharged to air channel outside the room with room air PA, and the pipe arrangement that forms second ventilation stack 109 is connected with the second air duct 105c upstream extremity 117 and the downstream 118 of heat exchange device for air 105 (105 '), forms room outer air OA is introduced indoor air channel.
Above-mentioned ventilation stack of the present invention can be formed in the upper end frame of window frame 102 as shown in Figure 1, but ventilation stack of the present invention not only is confined to be formed in the upper end frame of window frame 102, for example, can also be formed in the left side or right frame of window frame 102.In addition, can also be formed in the combination of upper end frame+left frame of window frame 102, or in the combination of the upper end frame+right frame of window frame 102, or in the upper end frame+left frame of window frame 102+lower end frame, or in the combination of the upper end frame+right frame of window frame 102+lower end frame.In addition, can also be formed in doorframe, window sash frame or the Door leaf frame, or the conversion of their similar above-mentioned window frame combination.But the window frame inwall that forms above-mentioned ventilation stack should seal.
Can be provided with the heat insulating material (not shown) on the inwall of above-mentioned first ventilation stack 108 of the present invention and second ventilation stack 109, the inwall that is preferably in the outside, room of second ventilation stack 109 is provided with heat insulating material, can prevent the thermal loss of room outer air OA after the process interchange of heat like this.
The material of window frame 102 can be aluminium alloys, plastic-steel, steel, wooden etc., but the present invention is not limited only to above-mentioned material.
(2) air inlet port and gas outlet
Shown in Fig. 2,9, form indoor on upstream side 115 directions of first ventilation stack 108 at window frame 102 first gas outlet 111 that first air inlet port 110 that room air PA enters and the outside, the room on 116 directions of downstream can be provided with the room air PA ' discharge after overheated, wet exchange can be set; First air inlet port 110 and first gas outlet 111 are connected with the upstream and downstream of first ventilation stack 108 respectively and are interlinked to the outside with indoor and room respectively; Form at window frame 102 that the outside, room on upstream side 117 directions of second ventilation stack 109 can be provided with that second air inlet port 112 of introducing room outer air OA and the indoor on 118 directions of downstream can be provided with second gas outlet, 113, the second air inlet ports 112 in room outer air OA ' inlet chamber after overheated, wet exchange and second gas outlet 113 is connected with the upstream and downstream of second ventilation stack 109 respectively and respectively with the room outer with indoor communicating.In addition, air inlet port of the present invention and gas outlet can be arranged on the position of window frame 102 as shown in Figure 1, but air inlet port of the present invention and gas outlet also can be arranged on other position of window frame 102.Further, can also adopt the form of pipe arrangement to extend to the outside or the outside of window frame 102.
The shape of first air inlet port 110 of the present invention, first gas outlet 111 and second air inlet port 112, second gas outlet 113 can be circular, also can be square, but the shape of air inlet port of the present invention and gas outlet is not limited only to circle and square.
(3) exhauster and lift pump
As Fig. 2, shown in Figure 9, a room air PA ' after being used for room air PA being introduced first ventilation stack 108 and the first air duct 105b and will finishing heat, wet exchange can be set near first air inlet port 110 of window frame 102 be discharged to exhauster 106 outside the room; Be used for room outer air OA introduced second ventilation stack 109 and the second air duct 105c and with the indoor lift pump 107 of air OA ' introducing after heat, the wet exchange can being provided with one near second air inlet port 112 of window frame 102.Exhauster 106 and lift pump 107 can adopt the coaxial motor (not shown) to drive, and can simplify the structure of aeration clearing window of the present invention like this, but also can to adopt be independent respectively control running for exhauster 106 of the present invention and lift pump 107.Exhauster 106 of the present invention and lift pump 107 can adopt small-sized axial flow fan, also can adopt small-sized fans formula blower fan, centrifugal fan, can also be the blower fans of other form.Exhauster 106 of the present invention and lift pump 107 can be according to being installed in the window frame 102 as shown in Figure 2, but exhauster of the present invention 106 and lift pump 107 also can be installed in the outside or outside with first air inlet port 110 and second air inlet port, 112 corresponding window frames 102 as required.In addition, the installation site of exhauster 106 and lift pump 107 is not limited only to above-mentioned position, can also be installed in other air inlet port or gas outlet.
When exhauster 106 and lift pump 107 work, room air PA is introduced into first ventilation stack 108 by first air inlet port 110 and enters the first air duct 105b again; Room outer air OA introduces second ventilation stack 109 by second air inlet port 112 and enters the second air duct 105c again; Room air PA and room outer air OA are square crossing and flow and carry out sensible heat and latent heat exchange in the first air duct 105b and the second air duct 105c, will finish heat, wet exchange back room air PA ' and room outer air OA ' then and be discharged to outside the room by first ventilation stack 108 and second ventilation stack 109 through first gas outlet 111 and second gas outlet 113 respectively and introduce indoor.
(4) air filter
Multifunctional thermal insulation aeration clearing window 1 of the present invention can be provided with the air filter of a demountable cleaning in second air inlet port 112 and/or first air inlet port 110, first gas outlet 111, further, can be provided with at second air inlet port, 112 places one can be provided with can disassembly, cleaning the high density filter device 114 used of toilet, filter 114 can be, for example HEPA strainer or ulpa filter.This toilet can capture very little dust with high density filter device 114.Generally, virus or germ etc. are mostly attached on the dust, so use this high density filter device 114 will introduce the dust the indoor air OA and remove energetically attached to virus on the dust or germ outside the room.In addition, also can be provided with at first gas outlet 111, first air inlet port, 110 places one can disassembly, cleaning the airstrainer (not shown), to stop outside the room and indoor dust enters in first and second ventilation stacks 108,109.Certainly, this screen pack also can be realized by with the corresponding position of first air inlet port 110, first gas outlet 111 and second gas outlet 113 numerous air vent (as shown in Figure 1) is set on window frame 102.
[power supply and control device]
The power supply (not shown) provides power for exhauster 106 and lift pump 107 etc., and it can be common power supply, because the power of exhauster 106 and lift pump 107 is little, considers safety factor, preferably adopts low-voltage safety power supply.In addition, also can adopt the environmental protection power supply, as utilize solar-energy photo-voltaic cell to provide power for exhauster 106 and lift pump 107.Have again, the glass 104 of sash can also be replaced by the photoelectricity plastics, as, the plastics photoelectric material that U.S. Konarka company produces.This photoelectricity plastics light transmission and simple glass are very nearly the same, it is to absorb the sunshine or the light of indoor light source by one deck organic semiconducting materials, produce both hole and electron, described both hole and electron is delivered to two electrodes by semi-conducting material itself and the football alkene that wherein mixes respectively, thereby transform light energy is become electric energy, and this electric energy can provide electrical source of power for exhauster 106 and lift pump 107.
The control device (not shown) can be arranged on the window frame 102, also can be arranged on the outside of window frame 102; Can be that line traffic control is arranged, can also be controlled in wireless.Control device can be set the operational mode of exhauster 106 and lift pump 107 as required, realizes the automatic operation of exhauster 106 and lift pump 107, for example, move and stops 1 hour after 2 hours, reruns afterwards 2 hours, so circulates.Also can set a running time, then shutdown or the like automatically.In addition, also can be the running of controlling exhauster 106 and lift pump 107 manually fully.
Above-described heat exchange device for air 105 (105 '), exhauster 106 and lift pump 107, power supply and control device (need be installed in window frame in time) can be packed in the window frame 102 by the mode of offering dismountable panel 102a on the non-construction and installation face on window frame 102 as shown in Figure 1, and dismountable panel 102a can be fixedlyed connected by the screw (not shown) on the interior projection of screw 102b and window frame 102.When needing repairing, can pull down panel 102a, keep in repair.Certainly, said apparatus of the present invention also can be installed in the window frame 102 by other modes.
During the work of the present invention's first exemplary embodiment multifunctional thermal insulation aeration clearing window, at first start exhauster 106 and lift pump 107 by control device, like this, the running of indoor contaminated air by exhauster 106 generates air stream PA, and is admitted to first ventilation stack 108 by first air inlet port 110 and enters (the PA hollow arrow direction indication among Fig. 2) among the first air duct 105b again; The running of room outer air by lift pump 107 generates air stream OA, and is introduced into second ventilation stack 109 by second air inlet port 112 and enters (the OA hollow arrow direction indication among Fig. 2) among the second air duct 105c again; Because, the heat exchanger plate 105a of heat exchange device for air 105 (105 ') and/or the first and second corrugated sheet 105d, 105e adopts the material that can transmit heat and humidity to make, therefore, room air PA and room outer air OA are in the first air duct 105b of heat exchange device for air 105 (105 ') and the second air duct 105c in the process that square crossing flows not only can carry out the sensible heat exchange, can also carry out the latent heat exchange, be that room air PA passes through the heat exchanger plate 105a and the first and second corrugated sheet 105d with its heat and humidity, 105e passes to the air OA in the inlet chamber outside the room, and room air PA became PA ' and was discharged to outside the room this moment; It is indoor that room outer air OA becomes OA ' introducing, thereby guarantee that indoor original temperature and humidity does not change in scavenging period.Heating installation room in the winter time, room air PA transmits hot gas and humidity to room outer air OA, thereby indoor original hot temperature and humidity is not changed; In the summer air-conditioning room, room air PA transmits cold air and carries out the humidity exchange to room outer air OA, thereby indoor original cold temperature and humidity is not changed.For example, summer is when entering in the heat exchange device for air 105 (105 ') as the too high room outer air OA of humidity, heat exchanger plate 105a absorbs too much moisture among the room outer air OA, and be delivered in the inwall of the first air duct 105b, like this, room air PA will absorb these moisture among the first air duct 105b and is discharged to outside the room when the first air duct 105b, thus make room outer air OA in heat exchange device for air 105 (105 '), fall earlier wet back introduce indoor.Generally in the winter time, the exchange process of humidity is just in time opposite, and promptly outer air OA in room is indoor in introducing behind the first humidification in heat exchange device for air 105 (105 '), and indoor original humidity is not changed.
In order further to guarantee to suck the quality of room air, room outer air till anti-, cause secondary pollution for the air in the suction chamber as the pollution of micronic dust, vehicle exhaust etc., the present invention can be provided with an air filter 114 at second air inlet port, 112 places, air filter 114 can be a high density filter device that the detachable toilet of cleaning uses, and for example can be HEPA strainer or ulpa filter.This toilet can capture very little dust with high density filter device 114.Generally, organic molecule, virus or germ etc. are mostly attached on the micronic dust, so use this high density filter device 114 will introduce the dust the indoor air OA and remove energetically attached to the organic molecule on the dust, virus or germ outside the room.
In addition, when heat exchange device for air 105 of the present invention (105 ') is made during by Bamboo-carbon paper or bamboo fibre paper, because it has the conductibility of better heat and humidity, simultaneously, again because bamboo charcoal or active bamboo have antibiotic, antibacterial, anti-mite and superpower anti-static function, therefore, the heat exchange device for air 105 (105 ') that uses Bamboo-carbon paper or bamboo fibre paper to make has self-cleaning function, can prevent that various mushrooms adhere on it in the air.
Have, the cost that constitutes above-mentioned parts of the present invention is not high, therefore again, multifunctional thermal insulation aeration clearing window of the present invention or door can solve the room air pollution problem at low cost, the environment that purifies the air of a room ensures and the health of human body can realize the energy-conservation of building simultaneously.
Fig. 3 is the partial schematic diagram of the two-way aeration clearing of the present invention's second exemplary embodiment multifunctional thermal insulation aeration clearing window.
Referring to Fig. 3, compare with first exemplary embodiment of multifunctional thermal insulation aeration clearing window of the present invention, second exemplary embodiment has increased an air cleaning unit 201 in the downstream of second ventilation stack 109, other structure is identical with first exemplary embodiment, structure with the first exemplary embodiment same section, no longer be repeated in this description in the present embodiment, below emphasis air cleaning unit 201 is described.
Air cleaning unit 201 is set at the air flow downstream side of second ventilation stack 109, and it mainly comprises plasma device and photocatalytic filter (not shown).The plasma device makes by forceful electric power lotus on the dust lane of containing among the room outer air OA after 114 filtrations of second air inlet port, 112 place's strainers.Optical catalyst filter can load titanium apatite and visible light line style optical semiconductor catalyst, but optical catalyst filter also can a load titanium apatite.Said herein titanium apatite is the apatite that has replaced the part calcium atom of calcium hydroxy apetite by methods such as ion-exchanges with titanium atom.In addition, said herein visible light line style optical semiconductor catalyst is for example titanium dioxide etc. to be improved, even also can bring into play the optical semiconductor catalyst of photocatalytic activity under visible rays.Have again, after the structure of this air cleaning unit 201 makes room outer air OA enter from second air inlet port 112, earlier by behind the filter 114 more successively by plasma device and optical catalyst filter.Because, filter 114 is configured in the upstream side of room outer air OA flow direction, and plasma device and optical catalyst filter are configured in the downstream of air-flow direction respectively, like this, this air cleaning unit 201 can further purify the air that carries out heat through air heat-exchanging device 105 (105 '), wet after exchanging, the generation SA1 that purifies air sends into indoor.Particularly pollute than serious area for the room outer air, this air cleaning unit 201 can further improve the quality of sending into indoor room outer air OA, improves the depuration quality that enters room air.
Certainly, this exemplary embodiment can also adopt the plain filter that is provided with at second air inlet port, 112 places, and the method for HEPA strainer or ulpa filter is set at the air upstream side of air cleaning unit 201, it is the method for HEPA strainer or ulpa filter+plasma device+photocatalytic filter, air is purified, and its effect is identical.
In addition, near the window frame 102 that this air cleaning unit 201 is installed (indoor or outside), can some be equipped with the transparent material (not shown), so just the light of indoor or outdoors can be imported air cleaning unit 201.
The kill performance of titanium apatite to germ and virus is described below, and its key data and experimental technique are from the experimental data of legal person's japanese food analysis center of Japanese interest group.
Titanium apatite sees the following form to the inactivation ratio of germ, virus and toxin.
Above-mentioned these inactivation ratios are in juridical person's japanese food analysis center, measure by the following method.
[to the inactivation ratio of influenza virus]
(1) experiment general introduction
To the strainer that scribbles titanium apatite (about 30mm * 30mm), drip the suspension of influenza virus, the viral communication ability is measured in [black light irradiation (distance of strainer and black light is about 20cm)] preservation after 24 hours under room temperature dark condition (lucifuge) and bright wisp spare.
(2) calculating of inactivation ratio
Inactivation ratio=100 * (1-10
B/ 10
A)
A: firm postvaccinal viral communication ability
B: the infection ability of virus in 24 hours after-filters is penetrated in illumination
(3) experimental technique
A. test is viral: influenza virus A type H1N1)
B. use cell: MDCK (NBL-2) cell ATCC CCL-34 strain [Dainippon Pharmaceutical Co., Ltd]
C. use culture medium
A) cell proliferation culture medium
The fresh calf serum of adding 10% among the Eagle MEM (containing the 0.06mg/ml kanamycins).
B) cell is kept culture medium
Use the following culture medium of forming.
Eagle?MEM 1000mL
10%?NaHCO
3 24~44mL
L-glutamine (30g/L) 9.8mL
100 * MEM vitamin liquid 30mL
10% albumin 20mL
Trypsase (5mg/mL) 2mL
D. the preparation of viral suspension
A) cultivation of cell
Use the cell proliferation culture medium, in tissue is cultivated with flask, mdck cell is carried out monolayer cultivation.
B) Bing Du inoculation
After the monolayer cultivation, in flask, remove the cell proliferation culture medium, inoculation test virus.Add cell then and keep culture medium, in 37 ℃ carbon dioxide incubator (CO
2Concentration: cultivated 2~5 days 5%).
C) preparation of viral suspension
After the cultivation, use inverted phase contrast microscope observation of cell form, think more than or equal to 80% cell generation metamorphosis (cell transformation effect).Centrifugation then (3000 rev/mins, 10 minutes) nutrient solution, with the supernatant that obtains as viral suspension.
E. the preparation of sample
With filter membrane (behind the moist heat sterilization (121 ℃, 15 minutes) of about 30mm * 30mm), air-dry 1 hour, put into plastic ware then, irradiation black light (parallel invisible blue light, the FL20SBL-B20W of 2 bundles), irradiation time is more than 12 hours or 12 hours, with this as sample.
F. test operation
In sample, splash into the 0.2mL viral suspension.Preserve in room temperature (distance of filter membrane and black light is about 20cm) under lucifuge and irradiation black light.In addition, with polyethylene sheeting sample in contrast, similarly test.
G. virus washes out
Preserve after 24 hours, keep culture medium with the 2mL cell and wash out viral suspension in the test film.
H. the mensuration of viral communication ability
Use the cell proliferation culture medium, in tissue is cultivated with microtest plate (96 hole), mdck cell is carried out monolayer cultivation, remove the cell proliferation culture medium then, add the 0.1mL cell in each hole and keep culture medium.Then, inoculate 4 holes simultaneously with eluate and its dilution of 0.1mL respectively, in 37 ℃ carbon dioxide incubator (CO
2Concentration: cultivated 4~7 days 5%).After the cultivation, no change (cell transformation effect) is arranged,, calculate the 50% (TCID of TCID according to the Reed-Muench method with inverted phase contrast microscope observation of cell form
50), and be converted into the viral communication ability that is equivalent to the 1mL eluate.
[to Escherichia coli (0-157), staphylococcus aureus and the mould inactivation ratio of branch spore]
(1) test general introduction
With reference to Japanese SIAA test method(s) " antimicrbial power evaluation test method III (calendar year 2001 degree version) the light irradiating film driving fit method of antibiotic fabricated product " (to call " light irradiating film driving fit method (anti-skill is assisted calendar year 2001 degree version) " in the following text), carry out the antimicrbial power test of strainer.
The test implementation step is as follows:
In sample, drip Escherichia coli, staphylococcus aureus and the mould bacterium liquid of branch spore, cover low-density polyethylene film above it, make its driving fit.(black light irradiation (distance of filter membrane and black light is about 20cm) is preserved, and measures viable count after 24 hours under room temperature (20~25 ℃), dark condition (lucifuge) and bright wisp spare with these samples.
(2) experimental technique
A. bacterium:
Escherichia coli IFO 3972 (Escherichia coli)
Staphylococcus aureus IFO12732 (Staphylococcus aureus subsp.aureus)
Mould:
Branch is embraced mould IFO 6348 (Cladosporium cladosporioides)
B. test medium
NA culture medium: plain agar culture medium (Eiken Chemical)
The 1/500NB culture medium: use phosphate buffer solution, the ordinary broth (Eiken Chemical) that is added with 0.2% meat extract is diluted to 500 times, regulating pH is 7.00 ± 0.2.
SCDLP culture medium: SCDLP culture medium (Nihon Pharmaceutical Co., Ltd.)
SA culture medium: standard agar medium (Rong Yan equipment Co., Ltd.)
PDA culture medium: potato dextrose agar culture medium (Rong Yan equipment Co., Ltd.)
C. the preparation of bacterium liquid
Bacterium:
Will with the NA culture medium 35 ℃, cultivate and to be inoculated into once more in the NA culture medium with interior test strain in 16~24 hours, at 35 ℃, cultivated 16~20 hours, this thalline is dispersed in the 1/500NB culture medium is prepared then, the bacterium number that makes every 1mL is 2.5 * 10
5~1.0 * 10
6
Mould:
Use the PDA culture medium, at 25 ℃, cultivate after 7~10 days, sporozoite (gonidium) is suspended in the 0.005% dioctyl sodium sulfosuccinate solution, use filtered through gauze, be prepared then, the sporozoite number that makes every 1mL is 2.5 * 10
5~1.0 * 10
6
D. the preparation of sample
With filter membrane (behind the moist heat sterilization (121 ℃, 15 minutes) of about 50mm * 50mm), air-dry 1 hour, put into plastic ware then, irradiation black light (parallel invisible blue light, the FL20SBL-B20W of 2 bundles), irradiation time is more than 12 hours or 12 hours, with this as sample.
E. test operation
In sample, splash into 0.4mL bacterium liquid, cover low-density polyethylene film (40mm * 40mm), make its driving fit above it.In room temperature (20~25 ℃), (distance of filter membrane and black light is about 20cm) preserves under lucifuge and irradiation black light.In addition, with polyethylene sheeting sample in contrast, similarly test.
F. the mensuration of viable count
Preserve after 24 hours, from sample, wash out residual viable bacteria with the SCDLP culture medium, wherein bacterium adopts the SA culture medium to cultivate (35 ℃, cultivated 2 days), mould adopts the PDA culture medium to cultivate (25 ℃, cultivated 7 days), then, release the viable count that plating method is measured described eluate by mixing, be converted into the viable count that is equivalent to each sample.In addition, measure firm postvaccinal viable count in contrast.
[inactivation ratio of enterotoxin]
(1) test general introduction
Inoculate SEA (being designated hereinafter simply as " SET-A ") in sample, (uitraviolet intensity is about 1mW/cm in room temperature (20~25 ℃), dark condition (lucifuge) and bright wisp spare
2Illumination penetrate down) preserve, after 24 hours, measure the concentration of SET-A, calculate resolution ratio.
(2) test method
A. the preparation of standard stoste
With the 1% sodium chloride solution dissolving SET-A standard items (TOXINTECHNOLOGY) that contain 0.5% bovine serum albumin(BSA), be prepared into 5 μ m/mL workers' standard stoste.
B. calibration curve normal solution
With the cushioning liquid that VIDAS staphylococcal enterotoxin (SET) (fully-automatic analyzer) [biological Mei Liai (bioMerieux)] carries, dilution standard stoste, be prepared into the normal solution of 0.2ng/mL, 0.5ng/mL and 1ng/mL.
C. the preparation of sample
Filter membrane is cut into the size of 50mm * 50mm, and the distance irradiation black light from about 1cm shone 24 hours, with this as sample.
D. experimental implementation
Sample is put into plastic ware, the SET-A standard stoste of inoculation 0.4mL.Is about 1mw/cm with it in room temperature (20~25 ℃), lucifuge and irradiation ultraviolet radiation intensity
2Light (2 bundle parallel black light, FL20S BL-B20W) irradiation preserve down.
Preserve after 24 hours, the buffer solution with 10mL VIDAS staphylococcal enterotoxin (SET) [biological Mei Liai] carries washes out SET-A, as sample solution from sample.
In addition, do not put into the SET-A standard stoste of plastic ware inoculation 0.4mL of sample after, add the buffer solution that 10mL VIDAS staphylococcal enterotoxin (SET) [biological Mei Liai] carries, in contrast with this.
E. the making of calibration curve
Use VIDAS staphylococcal enterotoxin (SET) [biological Mei Liai), according to ELISA method (enzyme-linked immunosorbent assay), calibration curve is measured with normal solution, according to the concentration and the fluorescence intensity production standard curve of normal solution.
The mensuration of F.SET-A concentration and the calculating of resolution ratio
Use VIDAS staphylococcal enterotoxin (SET) [biological Mei Liai], according to ELISA method working sample fluorescence intensity of solution, the calibration curve of making by above-mentioned E is obtained the concentration of SET-A, calculates resolution ratio according to following formula.
Measured value * 100 of resolution ratio (%)=(measured value of the measured value-sample solution of contrast)/contrast
In sum, the titanium apatite that contains in the air cleaning unit 201 has the effect of airborne various bacteriums and germ being carried out sterilization processing, thereby guarantees to enter the indoor air purifying quality effectively.
Fig. 4 is the partial schematic diagram of the two-way aeration clearing of the present invention's the 3rd exemplary embodiment multifunctional thermal insulation aeration clearing window.
Compare with second exemplary embodiment of multifunctional thermal insulation aeration clearing window of the present invention, the 3rd exemplary embodiment is that (near second gas outlet 113) or upstream side have increased an active substance delivery device 301 in the downstream of air cleaning unit 201, other structure is identical with first and second exemplary embodiment, structure with first and second exemplary embodiment same section, no longer be repeated in this description in the present embodiment, below emphasis describe active substance delivery device 301 and the effect.
Active substance delivery device 301 can be arranged on mobile near the downstream (second gas outlet 113) or the upstream side of air of air cleaning unit 201, when active substance delivery device 301 during at upstream side, active substance delivery device 301 can provide active material in by air cleaning unit 201 cleaned air passes SA1, make it become the air SA2 that contains active material, introduce indoor through second air inlet port 113 again.Further, here so-called " active substance delivery device " can be glow discharge device, barrier discharge device or streamer discharge device etc., here so-called " active material " can be negative oxygen ion (ozone) etc. for example, known negative oxygen ion (ozone) can sterilization, simultaneously, an amount of negative oxygen ion is also referred to as human body " air vitamin ", can enter human body by human skin cell's gap, but can prevent skin aging and relieving fatigue.Simultaneously, remaining particle and harmful organic molecule in negative oxygen ion and the room air, for example, benzene molecular, formaldehyde molecule bumps against, make it charged, this charged particle and harmful organic molecule are easy to by the absorption of things such as wall in the room and ceiling, thereby indoor air is further purified.In addition, negative oxygen ion also can form static with virus that has weak charge or germ and combine, thereby reaches the purpose of degerming.
Certainly, active substance delivery device 301 also can be set at the mobile upstream side of air of air cleaning unit 201, at this moment, the radical type material that the energy level that active substance delivery device 301 discharges is very high etc. can activate the optical semiconductor catalyst in the air cleaning unit 201 or have the photo-catalysis function of the apatite of photo-catalysis function, thereby quicken optical semiconductor catalyst or have the photocatalysis response speed of the apatite of photo-catalysis function, its result will cause air cleaning unit 201 can further remove virus removal or germ and other harmful organic molecules efficiently.
In this exemplary embodiment, in order to control the injury that excessive active material that active substance delivery device 301 decomposed may cause human body, an active material resolving cell (not shown) can also be set, activated carbon filtration unit of ozone decomposition etc. for example, this active material resolving cell can be arranged on the mobile downstream of air of active substance delivery device 301, be used for controlling airborne quantity delivered in the active material inlet chamber, preventing excessive active material, enter in the room air and injury that human body is caused as ozone.
In addition, in this exemplary embodiment, photocatalytic filter load titanium apatite in the air cleaning unit 201 and visible light line style optical semiconductor catalyst, but titanium apatite and visible light line style optical semiconductor catalyst also can be coated on the optical catalyst filter by the fiber institute's load that forms photocatalytic filter or with it.Have, titanium apatite and visible light line style optical semiconductor catalyst can be coated in the one side of optical catalyst filter again, also can be coated in the two sides of optical catalyst filter.
Fig. 5, Fig. 6 are the two-way ventilation of the present invention's the 4th exemplary embodiment multifunctional thermal insulation aeration clearing window and the partial schematic diagram of room air circularly purifying pattern;
Referring to Fig. 5, Fig. 6, Fig. 9, to compare with first exemplary embodiment of the present invention, the 4th exemplary embodiment of the present invention has increased: the formation member 401a of the 3rd ventilation stack 401; On window frame 102 formation first ventilation stack 108, be provided with on the 3rd air inlet port 402 and second ventilation stack 109 and be provided with the 3rd gas outlet 403; Upstream side at second ventilation stack 109 is provided with the 3rd switching mechanism 405 that opens and closes second switching mechanism 404 of second ventilation stack 109 and switching first ventilation stack 108 and the 3rd ventilation stack 401 are set at the connecting portion of first ventilation stack 108 and the 3rd ventilation stack 401.Second switching mechanism 404 and the 3rd switching mechanism 405 can link, promptly when second switching mechanism 404 is closed second ventilation stack 109,405 of the 3rd switching mechanisms are opened the 3rd air inlet port 402 (the 3rd ventilation stack 401) and are closed the downstream of first ventilation stack 108 simultaneously, at this moment, the air PA that comes by first ventilation stack, 108 upstreams enters the 3rd ventilation stack 401 from the 3rd air inlet port 402, enter second ventilation stack 109 by the 3rd gas outlet 403 again, and then through air heat-exchanging device 105 (105 ') the second air duct 105c (see figure 9) enter second ventilation stack 109, enter indoor by second gas outlet 113 at last.Otherwise when second switching mechanism 404 was opened second ventilation stack 109,405 of the 3rd switching mechanisms were closed the 3rd air inlet port 402 (the 3rd ventilation stack 401).In addition, in the 3rd ventilation stack 401, also be provided with air cleaning unit 201.Have, lift pump 106 and exhauster 107 in the 4th exemplary embodiment of the present invention do not re-use coaxial motor again, and they can be controlled respectively.The air cleaning unit 201 that is arranged in the 3rd ventilation stack 401 is identical with second and third exemplary embodiment of the present invention, other structure is identical with first exemplary embodiment, with the structure of first, second and third exemplary embodiment same section, no longer be repeated in this description in the present embodiment.
The present invention's the 4th exemplary embodiment has two kinds of operational modes, first kind is two-way ventilatory pattern, under this pattern, second switching mechanism 404 is in first opened and closed positions, it is the position that 404 among Fig. 5 is in solid line, the 3rd switching mechanism 405 is in second opened and closed positions, it is the position that 405 among Fig. 5 is in solid line, under this operational mode, first ventilation stack 108, second ventilation stack 109 is opened fully, and the 3rd air inlet port 402 is by closed fully, like this, the 3rd ventilation stack 401 just has been closed, at this moment, when exhauster 106 and 107 work of lift pump, indoor contaminated air generates air stream PA by the running of exhauster 106, and be admitted in the heat exchange device for air 105 (105 ') by first air inlet port 110, simultaneously, the room outer air generates air stream OA by the running of lift pump 107, and be introduced in the heat exchange device for air 105 (105 ') by second air inlet port 112, because the heat exchanger plate 105a and the second corrugated sheet 105d of heat exchange device for air 105 (105 '), the 105e (see figure 9) is to adopt the material that can transmit heat and humidity to make, therefore, room air PA and room outer air OA are in the first air duct 105b of heat exchange device for air 105 (105 ') and the second air duct 105c in the process that square crossing flows not only can carry out the sensible heat exchange, can also carry out the latent heat exchange, be that room air PA passes through heat exchanger plate 105a and first with its heat and humidity, the second corrugated sheet 105d, 105e passes to the air OA in the inlet chamber outside the room, and room air PA became PA ' and was discharged to outside the room this moment; It is indoor that room outer air OA becomes OA ' introducing, thereby guarantee that indoor original temperature and humidity does not change in scavenging period.Heating installation room in the winter time, room air PA transmits hot gas and humidity to room outer air OA, thereby indoor original hot temperature and humidity is not changed; In the summer air-conditioning room, room air PA transmits cold air and carries out the humidity exchange to room outer air OA, thereby indoor original cold temperature and humidity is not changed.For example, summer is when entering in the heat exchange device for air 105 (105 ') as the too high room outer air OA of humidity, heat exchanger plate 105a absorbs too much moisture among the room outer air OA, and be delivered in the inwall of the first air duct 105b, like this, room air PA will absorb these moisture among the first air duct 105b and is discharged to outside the room when the first air duct 105b, thus make room outer air OA in heat exchange device for air 105 (105 '), fall earlier wet back introduce indoor.Generally in the winter time, the exchange process of humidity is just in time opposite, and promptly outer air OA in room is indoor in introducing behind the first humidification in heat exchange device for air 105 (105 '), and indoor original humidity is not changed.By the operation of this two-way ventilatory pattern, both can keep the cleaning of room air effectively, can avoid the excessive variation of indoor original temperature and humidity in scavenging period again.
If when running into popular or other reason of influenza or SARS and need carry out sterilization processing to room air, the present invention's the 4th exemplary embodiment can be cut second kind of operational mode, i.e. room air circularly purifying pattern by control device.
Fig. 6 is second kind of operational mode of the present invention's the 4th exemplary embodiment, referring to Fig. 6, under this operational mode, second switching mechanism 404 is in second opened and closed positions, i.e. 404 solid line positions that are among Fig. 6, and the 3rd switching mechanism 405 is in first opened and closed positions, it is the position that 405 among Fig. 6 is in solid line, under second kind of operational mode, the downstream of the upstream side of second ventilation stack 109 and first ventilation stack 108 is closed, and the 3rd air inlet port 402 is then opened fully.At this moment, have only exhauster 106 to work alone, lift pump 107 is not worked.Like this, when exhauster 106 is opened, the indoor running generation air stream PA that contains the air of various germs and bacterium by exhauster 106, and enter the first air duct 105b (see figure 9) in first ventilation stack 108 and the heat exchange device for air 105 (105 ') by first air inlet port 110, be admitted in the 3rd ventilation stack 401 by the 3rd air inlet port 402 then, because, be provided with air cleaning unit 201 in the 3rd ventilation stack 401, and by the description of front to air cleaning unit 201, we know that air cleaning unit 201 has the function of the air by it being carried out the degerming processing, therefore, when room air PA from the 3rd ventilation stack 401 during by air cleaning unit 201, can remove various germs contained in the air effectively, virus, second-hand-cigarette and various harmful organic molecule, at this moment, the air PA of indoor pollution has just become the SA1 that purifies air, and then by sending into second ventilation stack 109 and the second air duct 105c (see figure 9) enters second ventilation stack 109 at last and will send back to indoor through the air SA1 after the purified treatment through second gas outlet 113 in the 3rd gas outlet 403.
The formation member 401a that provides the way of light source can adopt at the 3rd ventilation stack 401 as the optical semiconductor catalyst in air cleaning unit 201 can some be equipped with the transparent material (not shown), so just the light outside the room can be imported in the air cleaning unit 201.
In addition, this exemplary embodiment can also provide light source for the optical semiconductor catalyst in the air cleaning unit 201 by the mode that a uviol lamp 406 is set as shown in Figure 7 in the 3rd ventilation stack 401, uviol lamp 406 sends the catalytic reaction that is used for activating optical semiconductor catalyst contained in the air cleaning unit 201.
Certainly, this exemplary embodiment method that light source is set is not limited only to this dual mode.
In this exemplary embodiment, can also add one deck heat insulating material (not shown) on the inwall of the 3rd ventilation stack 401, to avoid the loss of heat.
Have again, in this exemplary embodiment, the inwall of the 3rd ventilation stack 401 can also further be processed and form the Surface Machining layer, this Surface Machining layer can comprise the optical semiconductor catalyst in the above-described air cleaning unit 201, thereby make the 3rd ventilation stack 401 not only can capture, viral adsorption or germ etc., can also remove virus or germ energetically.
In this exemplary embodiment, the switching of above-mentioned first and second operational modes can be finished with manual mode, also can finish automatically by control device.
In this exemplary embodiment, the formation member 401a of the 3rd ventilation stack 401 removably is connected with window frame 102, is convenient to maintenance and replacing like this.In addition, preferentially the formation member 401a of the 3rd ventilation stack 401 is installed in the outside, room of window frame 102, is convenient to indoor attractive in appearance.
To sum up, this exemplary embodiment can be discharged to indoor contaminated air outside the room by first operational mode, introduce the air outside the room indoor simultaneously, and in the process of ventilation, do not change indoor original temperature and humidity, in addition, when influenza or SARS are popular, this exemplary embodiment can switch to second operational mode, at this moment, effectively room air is carried out sterilization processing, guarantee the cleaning of room air by the interior circulation of room air.
Fig. 8 is the partial schematic diagram of the room air circularly purifying of the present invention's the 5th exemplary embodiment multifunctional thermal insulation aeration clearing window, compare with the 4th exemplary embodiment, present embodiment on its basis, in the 3rd ventilation stack 501, increased an active substance delivery device 301, other structure is identical with the 4th exemplary embodiment with operational mode, no longer is repeated in this description here.
Active substance delivery device 301 can be arranged on the mobile downstream of air of air cleaning unit 201, but also can be arranged on upstream side, and Fig. 8 is arranged on the downstream.The effect of active substance delivery device 301 is identical with active substance delivery device 301 described in the present invention's the 3rd exemplary embodiment, also repeats no more here.In this exemplary embodiment and since the replenish air of active substance delivery device 301 in will inlet chamber as the active material of negative oxygen ion, therefore send into indoor air this moment and become the pure air SA2 that contains negative oxygen ion.
In addition, in this exemplary embodiment, in order to control the injury that excessive active material that active substance delivery device 301 decomposed may cause human body, an active material resolving cell (not shown) can also be set, activated carbon filtration unit of ozone decomposition etc. for example, this active material resolving cell can be arranged on the mobile downstream of air of active substance delivery device 301, be used for controlling airborne quantity delivered in the active material inlet chamber, preventing excessive active material, enter in the room air and injury that human body is caused as ozone.
Embodiments of the present invention can also have multiple variation example, as, the present invention can form above-mentioned structure on a plurality of limits of window frame 102 respectively, further, for example, top, the left side and/or the right at window frame 102, the bottom of window frame, the left side and/or the right independently are equipped with above-mentioned heat exchange device for air, air cleaning unit, suction, exhauster, active substance delivery device etc. separately, and for example, also can form machined layer on the inwall in second ventilation stack, this machined layer can comprise optical semiconductor catalyst; For another example, in the 4th exemplary embodiment, the air flow downstream side of second ventilation stack 109 can also be set up an air cleaning unit; The high density filter device that can use by the toilet such as, the air cleaning unit 201 in the 3rd ventilation stack 401 (501) also, for example HEPA strainer or ulpa filter substitute; Again such as, can also activate the catalytic reaction of optical semiconductor catalyst contained in the air cleaning unit 201 in second and third exemplary embodiment of the present invention by method at the downstream of second ventilation stack 109 configuration uviol lamp; Again such as, also can cancel second switching mechanism in the present invention's the 4th, the 5th exemplary embodiment, like this, when starting second operational mode, utilize high density filter device (HEPA) that the toilet that is arranged on the second air inlet port place on second ventilation stack uses to replace second switching mechanism to close the effect of the second ventilation stack upstream side to the hindrance function of air; For another example, the present invention can also be provided with an indoor air pollutants concentration inductor, when the pollutant that records room air when this inductor reaches a predefined numerical value, can open suction automatically, exhauster carries out two-way ventilation or the like.
In sum, multifunctional thermal insulation aeration clearing window of the present invention or door can be realized the air of indoor pollution is discharged to outside the room at low cost, introduce indoor through purifying the back room outer air simultaneously, and, in this process, the air of indoor discharge can fully and be introduced indoor air and carry out sensible heat and latent heat exchange by the heat exchange device for air that is arranged in window frame or the doorframe outside the room, guarantee that tangible change does not take place temperature and humidity indoor in scavenging period.In addition, if run into influenza or SARS is popular, multifunctional thermal insulation aeration clearing window of the present invention or door can also switch to the sterilization operational mode of room air circulation from two-way ventilatory pattern, thereby can remove various viruses, germ in the room air energetically, be the indoor air that purification is provided, ensure health.In addition, the present invention can also discharge negative oxygen ion in introducing indoor air, and negative oxygen ion is called as " the air vitamin " of human body, can enter human body by human skin cell's gap, thereby prevents skin aging and can alleviate the fatigue of human body.
Above-mentioned exemplary embodiment and advantage only are typical examples, and it can not be considered as limitation of the present invention.Technology of the present invention also can be applied to other similar device.Description to exemplary embodiment of the present invention is the scope that is used to illustrate rather than limit claim, and to those skilled in the art, clearly, the present invention also can make multiple changes and improvements.