CN101293211B - 改性的eu-1沸石及其在芳香族c8化合物的异构化中的用途 - Google Patents

改性的eu-1沸石及其在芳香族c8化合物的异构化中的用途 Download PDF

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CN101293211B
CN101293211B CN2008100929898A CN200810092989A CN101293211B CN 101293211 B CN101293211 B CN 101293211B CN 2008100929898 A CN2008100929898 A CN 2008100929898A CN 200810092989 A CN200810092989 A CN 200810092989A CN 101293211 B CN101293211 B CN 101293211B
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Prior art keywords
zeolite
catalyst
modification
aluminium
metal
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Expired - Fee Related
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CN2008100929898A
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Chinese (zh)
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CN101293211A (zh
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E·吉隆
E·桑切斯
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7246—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7446—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/14—After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2008100929898A 2007-04-23 2008-04-22 改性的eu-1沸石及其在芳香族c8化合物的异构化中的用途 Expired - Fee Related CN101293211B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR07/02943 2007-04-23
FR0702943A FR2915113B1 (fr) 2007-04-23 2007-04-23 Zeolithe eu-1 modifiee et son utilisation en isomerisation des composes c8 aromatiques.

Publications (2)

Publication Number Publication Date
CN101293211A CN101293211A (zh) 2008-10-29
CN101293211B true CN101293211B (zh) 2012-11-07

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CN2008100929898A Expired - Fee Related CN101293211B (zh) 2007-04-23 2008-04-22 改性的eu-1沸石及其在芳香族c8化合物的异构化中的用途

Country Status (7)

Country Link
US (1) US7838456B2 (https=)
EP (1) EP1985363B1 (https=)
JP (1) JP5412050B2 (https=)
CN (1) CN101293211B (https=)
DE (1) DE602008002352D1 (https=)
FR (1) FR2915113B1 (https=)
ZA (1) ZA200802629B (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9309170B2 (en) * 2011-11-14 2016-04-12 Uop Llc Aromatics isomerization using a dual-catalyst system
CN104888848A (zh) * 2015-05-05 2015-09-09 陕西延长石油（集团）有限责任公司炼化公司 一种c8芳烃异构化催化剂及合成方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537754A (en) * 1980-06-12 1985-08-27 Imperial Chemical Industries Plc Zeolite EU-1 and a method of making zeolite EU-1
US4695667A (en) * 1980-11-04 1987-09-22 Teijin Petrochemical Industries, Ltd. Novel crystalline aluminosilicate zeolites and process for production thereof
CN1233531A (zh) * 1997-12-22 1999-11-03 法国石油公司 含有沸石euo的催化剂及该催化剂在每分子含8个碳的芳香化合物的异构化方法中的应用
CN1327945A (zh) * 2000-05-05 2001-12-26 法国石油公司 低Si/Al比的EUO结构类型沸石及其作为催化剂的应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013617B1 (en) 1979-01-10 1984-07-04 Beecham Group Plc Penicillin derivatives, process for their preparation and pharmaceutical compositions containing certain of these compounds
FR2477903A1 (fr) 1980-03-13 1981-09-18 Inst Francais Du Petrole Nouveau catalyseur zeolithique d'isomerisation des hydrocarbures alkylaromatiques
US4482773A (en) 1982-02-25 1984-11-13 Mobil Oil Corporation Catalyst for xylene isomerization
US4467129A (en) 1982-11-24 1984-08-21 Toray Industries, Inc. Conversion of xylenes containing ethylbenzene
US4723051A (en) 1986-02-06 1988-02-02 Cosden Technology, Inc. Xylene isomerization process
US4665258A (en) 1986-02-06 1987-05-12 Cosden Technology, Inc. Toluene disproportionation process
GB9116499D0 (en) * 1991-07-31 1991-09-11 British Petroleum Co Plc Treatment method for zeolites
FR2765209B1 (fr) * 1997-06-25 1999-10-22 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765206B1 (fr) 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
US20040054199A1 (en) * 2002-09-17 2004-03-18 Basf Aktiengesellschaft Process for epoxidation and catalyst to be used therein
EP1699556A2 (en) 2003-12-30 2006-09-13 Uop Llc Process and catalyst for c8 alkylaromatic isomerization
FR2887246B1 (fr) * 2005-06-16 2007-08-31 Inst Francais Du Petrole Zeolithe de type structural euo contenant le cation n,n-dimethyl-n,n-di(3,3-dimethylbutyl)ammonium et son procede de preparation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537754A (en) * 1980-06-12 1985-08-27 Imperial Chemical Industries Plc Zeolite EU-1 and a method of making zeolite EU-1
US4695667A (en) * 1980-11-04 1987-09-22 Teijin Petrochemical Industries, Ltd. Novel crystalline aluminosilicate zeolites and process for production thereof
CN1233531A (zh) * 1997-12-22 1999-11-03 法国石油公司 含有沸石euo的催化剂及该催化剂在每分子含8个碳的芳香化合物的异构化方法中的应用
CN1327945A (zh) * 2000-05-05 2001-12-26 法国石油公司 低Si/Al比的EUO结构类型沸石及其作为催化剂的应用

Also Published As

Publication number Publication date
US20080281138A1 (en) 2008-11-13
EP1985363A1 (fr) 2008-10-29
JP5412050B2 (ja) 2014-02-12
JP2008279440A (ja) 2008-11-20
CN101293211A (zh) 2008-10-29
EP1985363B1 (fr) 2010-09-01
FR2915113A1 (fr) 2008-10-24
US7838456B2 (en) 2010-11-23
FR2915113B1 (fr) 2009-06-26
DE602008002352D1 (de) 2010-10-14
ZA200802629B (en) 2008-12-31

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