CN101284940B - Wet-method base processing agent - Google Patents

Wet-method base processing agent Download PDF

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Publication number
CN101284940B
CN101284940B CN2008100243084A CN200810024308A CN101284940B CN 101284940 B CN101284940 B CN 101284940B CN 2008100243084 A CN2008100243084 A CN 2008100243084A CN 200810024308 A CN200810024308 A CN 200810024308A CN 101284940 B CN101284940 B CN 101284940B
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CN
China
Prior art keywords
wet
bayes
portions
processing agent
synthetic leather
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Application number
CN2008100243084A
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Chinese (zh)
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CN101284940A (en
Inventor
时云刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Baoze Polymer Materials Co Ltd
Original Assignee
SUZHOU BAOZE MACROMOLECULE MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN2008100243084A priority Critical patent/CN101284940B/en
Publication of CN101284940A publication Critical patent/CN101284940A/en
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Abstract

The invention relates to a wet bayes bubble regulator. The compositions in portion by weight of the wet bayes bubble regulator are: 45 to 50 portions of propanediol block polyether, 30 to 35 portions of polypropylene glycol, 8 to 12 portions of fatty acid ester and 1 to 6 portions of dimethyl silicon oil. The wet bayes bubble regulator can be used in production of wet synthetic leather and wet PU resin to improve the air permeability and the moisture permeability of bayes and the synthetic leather; moreover, the bayes can be made to be straighter and have better rebound resilience.

Description

Wet-method base processing agent
Technical field
The invention belongs to the wet-method synthetic leather field, particularly relate to a kind of be used to the regulate size of abscess on the wet-method synthetic leather bass and the abscess conditioning agent that distributes.
Background technology
The wet type synthetic leather is meant the synthetic leather that adopts the preparation of wet type processing method, promptly go in woven or the woven cloth with the DMF solution impregnation of polyurethane resin composition or coating in the above, it is immersed in the water precipitation bath then, after reaching required setting time, through washing, after taking out oven dry the wet method bass.From the bass forming process as can be known, when PU coating liquid is impregnated in the precipitation bath, double diffusive process has taken place, promptly water is to coating liquid internal diffusion, and DMF is out-diffusion in the precipitation bath simultaneously, and dope layer solidifies.In process of setting, undergo phase transition at first and what solidify is epidermal area, because the raising of epidermal area PU solid content, its density is increasing, and the aperture diminishes, and makes the bidirectional diffusion resistance increase, it is slack-off that coating inside reaches the speed of gelation, PU molecular aggregates, winding make the place formation of close base cloth increase than the probability of big abscess, and hole wall thickens, the coat-thickness attenuation, apparent density increases thereupon, so its breaking tenacity improves, the breathable moisture permeability of bass decreases.
Summary of the invention
Technical problem to be solved by this invention provides a kind of Wet-method base processing agent, and this abscess conditioning agent is added in the PU coating liquid, can make the wet method bass form dense uniform vesicular structure near the place of base cloth.
For solving above technical problem, the present invention takes following technical scheme:
A kind of Wet-method base processing agent, by weight, its prescription is as follows;
45~50 parts of propylene glycol block polyethers;
30~35 parts of polypropylene glycols;
8~12 parts of fatty acid esters;
1~6 part of dimethyl silicone oil.
Because the enforcement of above technical scheme, the present invention compared with prior art has following advantage:
The present invention can be used in wet-method synthetic leather production and the wet method PU production of resins, delay the setting rate on synthetic leather surface in the wet method operation, make the wet method bass form dense uniform vesicular structure, thereby improve the breathable moisture permeability of bass and synthetic leather near the place of base cloth; In addition, the present invention also can make bass more very scrape, and rebound resilience is better.
Embodiment
The present invention will be further described in detail below in conjunction with specific embodiment.
Prescription according to the Wet-method base processing agent of present embodiment is;
Propylene glycol block polyether 45 grams;
Polypropylene glycol 35 grams;
Fatty acid ester 10 grams;
Dimethyl silicone oil 1 gram.
The preparation process of above-mentioned Wet-method base processing agent is:
Above-mentioned each component of weighing formula ratio, (stirring velocity 1450rpm) dispersed with stirring and heating to 60 ℃ promptly makes abscess conditioning agent product after 60 minutes at a high speed, and this product is a weak yellow liquid, and effective constituent is more than or equal to 99%.
The consumption of product of the present invention is:
When the PU resin of solid content 30% was 100 parts, addition was 0.3~1.0 part (promptly 1 ton of PU resin adds 3~10 kilograms).
The present invention is used for wet-method synthetic leather production, and the bass that makes is well-pressed, and rebound resilience is good, and breathable moisture permeability is good, and the synthesising leather performance of production is good.
The present invention is applicable to space leather, ball leather, luggage leather, clothing leather, rubs in the products such as line leather.

Claims (1)

1. Wet-method base processing agent, it is characterized in that: by weight, its prescription is as follows;
45~50 parts of propylene glycol block polyethers;
30~35 parts of polypropylene glycols;
8~12 parts of fatty acid esters;
1~6 part of dimethyl silicone oil.
CN2008100243084A 2008-05-19 2008-05-19 Wet-method base processing agent Active CN101284940B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008100243084A CN101284940B (en) 2008-05-19 2008-05-19 Wet-method base processing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008100243084A CN101284940B (en) 2008-05-19 2008-05-19 Wet-method base processing agent

Publications (2)

Publication Number Publication Date
CN101284940A CN101284940A (en) 2008-10-15
CN101284940B true CN101284940B (en) 2010-08-04

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ID=40057358

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008100243084A Active CN101284940B (en) 2008-05-19 2008-05-19 Wet-method base processing agent

Country Status (1)

Country Link
CN (1) CN101284940B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031739A (en) * 2011-09-29 2013-04-10 昆山协兴合成革有限公司 Production method of glove leather

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006063235A1 (en) * 2004-12-10 2006-06-15 Hercules Incorporated Defoamer emulsion compositions for pulp mill applications
CN1966851A (en) * 2006-10-27 2007-05-23 海宁杰玛高科涂层织物有限公司 Method for preparing sofa leather with strong wear resistant property and flame retardant property
CN101062468A (en) * 2006-04-27 2007-10-31 深圳市海川实业股份有限公司 Defoaming agent composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006063235A1 (en) * 2004-12-10 2006-06-15 Hercules Incorporated Defoamer emulsion compositions for pulp mill applications
CN101062468A (en) * 2006-04-27 2007-10-31 深圳市海川实业股份有限公司 Defoaming agent composition
CN1966851A (en) * 2006-10-27 2007-05-23 海宁杰玛高科涂层织物有限公司 Method for preparing sofa leather with strong wear resistant property and flame retardant property

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031739A (en) * 2011-09-29 2013-04-10 昆山协兴合成革有限公司 Production method of glove leather

Also Published As

Publication number Publication date
CN101284940A (en) 2008-10-15

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GR01 Patent grant
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Owner name: JIANGSU BAOZE POLYMER MATERIAL CO., LTD.

Free format text: FORMER NAME: SUZHOU BAOZE MACROMOLECULE MATERIALS CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: 215436 Taicang City, Jiangsu province Liuhe Town Xintang Wanan Village

Patentee after: Jiangsu Baoze Polymer Material Co., Ltd.

Address before: 215436 Taicang City, Jiangsu province Liuhe Town Xintang Wanan Village

Patentee before: Suzhou Baoze Macromolecule Materials Co., Ltd.