CN107266875A - A kind of automobile door handle PBT material and preparation method thereof - Google Patents
A kind of automobile door handle PBT material and preparation method thereof Download PDFInfo
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- CN107266875A CN107266875A CN201710549984.2A CN201710549984A CN107266875A CN 107266875 A CN107266875 A CN 107266875A CN 201710549984 A CN201710549984 A CN 201710549984A CN 107266875 A CN107266875 A CN 107266875A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Compositions Of Macromolecular Compounds (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Abstract
The invention discloses a kind of automobile door handle PBT material and preparation method thereof, the PBT material, in terms of parts by weight, including following components：30 40 parts of 28 35 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO225 32 parts of composite, 6 12 parts of PPDO, 14 19 parts of sepiolite fibre, 12 parts of octadecanol APEO, 9 11 parts of phase solvent, 11 17 parts of toughener, 8 15 parts of filler, 27 parts of coupling agent, 12 parts of antioxidant.PBT material prepared by the application has good mechanical property, and rigidity is stronger, and with good anti-microbial property, is very suitable for as automobile door handle materials'use.
Description
Technical field
The present invention relates to PBT material field, more particularly to a kind of automobile door handle PBT material and preparation method thereof.
Background technology
Polybutylene terephthalate (PBT) is a kind of crystal type line style saturated polyester resin, with excellent mechanics, electricity
Gas, resistant to chemical etching and agent of low hygroscopicity energy, are a kind of plastics of high comprehensive performance.PBT resin also has easily crystallization, shaping
Speed is fast；There is nothing in good physical property, high mechanical strength, dimensionally stable, the advantages of fatigue resistance is preferable, and strand
Double bond, weatherability, the characteristics of abrasion resistance properties are excellent.Therefore, the development of PBT material since the advent of the world is quite rapid, in electricity
The fields such as sub- electrical equipment, auto industry, machinery, instrument and meter and household electrical appliance, which have, to be widely applied.
The application of PBT material in the automotive industry in recent years gradually increases, and PBT material can not only reduce the matter of parts
Amount, can also reduce purchase cost.In automobile manufacturing field, PBT has been widely used in production door handle, ashtray, door
Lock system, Che Jing, car light frame, bumper, windshield wiper handle, connector, car light socket etc..Wherein automobile door handle, which is not only, opens and closes
The function part of door, is also ornamental part, it is desirable to which it, which prepares material, has the spies such as strong weatherability, antibiotic property and rigidity height
Property.But PBT material still has some shortcomings, such as notch impact strength is low, anti-flammability is not high, heat distortion temperature is compared with low and high temperature
The problems such as lower poor dimensional stability, by being modified to it, it is necessary to be made with more preferable combination property.
Chinese patent CN201510313904.4 discloses a kind of for the PBT based composites of automobile and its preparation side
Method, the PBT composite, its parts by weight, which is constituted, is：PBT35~60 part, 6~10 parts of POM, 15~20 parts of alumina silicate fibre, resistance
Fire 10~15 parts of agent, 0.5~1 part of stabilizer, 1~6 part of toughener, 5~8 parts of POE-g-MAH, 0.2~0.7 part of antioxidant, stream
Dynamic 1~6 part of accelerator, 0.3~0.8 part of dispersant, 1.5~2 parts of antistatic additive.The PBT bases for automobile that the invention is provided
The anti-hydrolytic performance of composite preferably, can keep preferable performance under hot and humid environment, but it does not have antibiotic property,
It is not very suitable for preparing automobile door handle and uses.
The content of the invention
It is an object of the invention to provide a kind of automobile door handle PBT material and preparation method thereof, the PBT material has good
Good mechanical property, rigidity is stronger, and with good anti-microbial property, is very suitable for as automobile door handle materials'use.
To achieve the above object, the present invention uses following technical scheme：
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
30-40 parts of 28-35 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO225-32 parts of composite, gathers to two
6-12 parts of oxygen cyclohexanone, 14-19 parts of sepiolite fibre, 1-2 parts of octadecanol APEO, 9-11 parts of phase solvent, toughener
11-17 parts, 8-15 parts of filler, 2-7 parts of coupling agent, 1-2 parts of antioxidant；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, is added dropwise under the conditions of 40-60 DEG C
The mixture of glacial acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, 630
6h is calcined under the conditions of DEG C, SiO is made2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite.
It is preferred that, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mol ratio be 3：2.
It is preferred that, the phase solvent is TMPTA.
It is preferred that, the toughener is ethylene-methyl acrylate copolymer.
It is preferred that, the filler is deposition hard charcoal black earth.
It is preferred that, the coupling agent is titanate coupling agent.
It is preferred that, the antioxidant is the mixture of irgasfos 168 and antioxidant 264.
A kind of preparation method of automobile door handle PBT material, comprises the following steps：
(1) octadecanol APEO is dissolved in the water, after stirring, regulation pH is 5-6.5, is added thereto
Ag+/SiO2/TiO2Composite and sepiolite fibre, carry out the scattered 2-4h of ultrasonic wave, afterwards thereto under the conditions of 40-60 DEG C
Coupling agent is added, after stirring, is centrifuged, after 110 DEG C of drying of solid matter, modified solid mixture is made；
(3) PBT, ABS, EMA and compatilizer are put into high mixer and carried out under the conditions of 80-90 DEG C after mixing 3-4h,
After modified solid mixture is well mixed made from addition step (1) thereto, then PPDO is added thereto, increase
Tough dose, filler, antioxidant；It is well mixed, feed the mixture into double screw extruder, after melt blending, extruding pelletization, i.e.,
Obtain the automobile door handle PBT material.
It is preferred that, the extrusion temperature is 260 DEG C, and screw speed is 240rpm.
The invention has the advantages that,
Blending and modifying is carried out to PBT by ABS and EMA materials, the shock resistance of PBT material is enhanced, extends PBT
The service life of material.By Ag+It is carried on porous SiO2In material, and by SiO2With TiO2Material is connected so that Ag+Can be with
With TiO2It is in contact, is catalyzed TiO2The anti-microbial property of material can be presented under no light condition.Inorganic Ag is utilized in the application+/SiO2/TiO2Composite is used in conjunction with each other with organic two kinds of antiseptics of PPDO, expands antibacterial model
Enclose, impart the stronger anti-microbial property of prepared PBT material.Sepiolite fibre is that the mineral using sepiolite as main component are fine
Dimension, with good decay resistance, the resistance to chemical corrosion of PBT material can be effectively strengthened by adding sepiolite fibre
Can, improve the weatherability of material.
Embodiment
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
30 parts of 28 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO225 parts of composite, PPDO 6
Part, 14 parts of sepiolite fibre, 1 part of octadecanol APEO, TMPTA9 parts, 11 parts of ethylene-methyl acrylate copolymer sinks
8 parts of white carbon of product, 2 parts of titanate coupling agent, 1 part of antioxidant, antioxidant is the mixture of irgasfos 168 and antioxidant 264；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice is added dropwise under the conditions of 40 DEG C
The mixture of acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, at 630 DEG C
Under the conditions of calcine 6h, be made SiO2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mole
Than for 3：2.
The preparation method of the automobile door handle PBT material, comprises the following steps：
(1) octadecanol APEO is dissolved in the water, after stirring, regulation pH is 5, and Ag is added thereto+/
SiO2/TiO2Composite and sepiolite fibre, the scattered 2h of ultrasonic wave is carried out under the conditions of 40 DEG C, coupling is added thereto afterwards
Agent, after stirring, is centrifuged, and after 110 DEG C of drying of solid matter, modified solid mixture is made；
(3) PBT, ABS, EMA and compatilizer are put into high mixer and carried out under the conditions of 90 DEG C after mixing 3h, thereto
Add after modified solid mixture is well mixed made from step (1), then add PPDO thereto, toughener,
Filler, antioxidant；It is well mixed, feed the mixture into double screw extruder, after melt blending, extruding pelletization, extrusion temperature
Spend for 260 DEG C, screw speed is 240rpm, produce the automobile door handle PBT material.
Embodiment 2
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
40 parts of 35 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO232 parts of composite, PPDO 12
Part, 19 parts of sepiolite fibre, 2 parts of octadecanol APEO, TMPTA11 parts, 17 parts of ethylene-methyl acrylate copolymer,
15 parts of white carbon of deposition, 7 parts of titanate coupling agent, 2 parts of antioxidant, antioxidant is the mixing of irgasfos 168 and antioxidant 264
Thing；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice is added dropwise under the conditions of 60 DEG C
The mixture of acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, at 630 DEG C
Under the conditions of calcine 6h, be made SiO2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mole
Than for 3：2.
Embodiment 3
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
40 parts of 28 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO225 parts of composite, PPDO 12
Part, 14 parts of sepiolite fibre, 2 parts of octadecanol APEO, TMPTA9 parts, 17 parts of ethylene-methyl acrylate copolymer sinks
8 parts of white carbon of product, 7 parts of titanate coupling agent, 1 part of antioxidant, antioxidant is the mixture of irgasfos 168 and antioxidant 264；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice is added dropwise under the conditions of 50 DEG C
The mixture of acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, at 630 DEG C
Under the conditions of calcine 6h, be made SiO2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mole
Than for 3：2.
The preparation method of the automobile door handle PBT material, as described in Example 1.
Embodiment 4
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
30 parts of 35 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO232 parts of composite, PPDO 6
Part, 19 parts of sepiolite fibre, 1 part of octadecanol APEO, TMPTA11 parts, 11 parts of ethylene-methyl acrylate copolymer,
15 parts of white carbon of deposition, 2 parts of titanate coupling agent, 2 parts of antioxidant, antioxidant is the mixing of irgasfos 168 and antioxidant 264
Thing；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice is added dropwise under the conditions of 60 DEG C
The mixture of acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, at 630 DEG C
Under the conditions of calcine 6h, be made SiO2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mole
Than for 3：2.
The preparation method of the automobile door handle PBT material, as described in Example 1.
Embodiment 5
A kind of automobile door handle PBT material, in terms of parts by weight, including following components：
100 parts of PBT, ABS30 parts, 36 parts of EMA, Ag+/SiO2/TiO229 parts of composite, PPDO 9
Part, 16 parts of sepiolite fibre, 2 parts of octadecanol APEO, TMPTA10 parts, 13 parts of ethylene-methyl acrylate copolymer,
11 parts of white carbon of deposition, 3 parts of titanate coupling agent, 1 part of antioxidant, antioxidant is the mixing of irgasfos 168 and antioxidant 264
Thing；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice is added dropwise under the conditions of 55 DEG C
The mixture of acetic acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, at 630 DEG C
Under the conditions of calcine 6h, be made SiO2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, drying, washes
Wash, dry, Ag is made in grinding+/SiO2/TiO2Composite, the Ag+/SiO2/TiO2SiO in composite2And TiO2Mole
Than for 3：2.
The preparation method of the automobile door handle PBT material, as described in Example 1.
After tested, the mechanical property of embodiment 1-5 and comparative example is as shown in the table, wherein, comparative example is commercially available automobile
Door handle PBT material；
Impact strength is tested with reference to GB/T1843-1996, and impact strength is higher to show that performance is better；
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example | |
| Impact strength KJ/m2 | 73.3 | 76.2 | 83.1 | 79.5 | 77.8 | 55.4 |
Embodiment 1-5 and the anti-microbial property of comparative example are as shown in the table, wherein, comparative example is that commercially available automobile door handle is used
PBT material：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example | |
| Staphylococcus aureus antibiotic rate/% | 91.5 | 93.6 | 93.1 | 94.7 | 90.8 | 22.1 |
| Pseudomonas aeruginosa antibiotic rate/% | 90.1 | 92.5 | 91.4 | 96.6 | 92.3 | 18.9 |
| Escherichia coli antibiotic rate/% | 90.2 | 95.3 | 94.2 | 95.6 | 91.7 | 22.1 |
1-5 of embodiment of the present invention impact strength, obviously higher than comparative example, shows with preferable power with antibiotic property
Learn performance and anti-microbial property.
Claims (9)
1. a kind of automobile door handle PBT material, it is characterised in that in terms of parts by weight, including following components：
30-40 parts of 28-35 parts of 100 parts of PBT, ABS, EMA, Ag+/SiO2/TiO225-32 parts of composite, gathers to dioxy ring
6-12 parts of hexanone, 14-19 parts of sepiolite fibre, 1-2 parts of octadecanol APEO, 9-11 parts of phase solvent, toughener 11-17
Part, 8-15 parts of filler, 2-7 parts of coupling agent, 1-2 parts of antioxidant；
The Ag+/SiO2/TiO2The preparation method of composite, comprises the following steps：
Silester and butyl titanate are sequentially added in absolute ethyl alcohol, are stirred vigorously, ice vinegar is added dropwise under the conditions of 40-60 DEG C
The mixture of acid and absolute ethyl alcohol, forms vitreosol, is dried after standing 84h formation gels, grind into powder, in 630 DEG C of bars
6h is calcined under part, SiO is made2/TiO2Composite, impregnates 36h in silver nitrate solution after being vacuumized, dry, washing,
Dry, Ag is made in grinding+/SiO2/TiO2Composite.
2. automobile door handle PBT material according to claim 1, it is characterised in that：The Ag+/SiO2/TiO2It is compound
SiO in material2And TiO2Mol ratio be 3：2.
3. automobile door handle PBT material according to claim 1, it is characterised in that：The phase solvent is TMPTA.
4. automobile door handle PBT material according to claim 1, it is characterised in that：The toughener is ethylene-propylene
Sour methyl terpolymer.
5. automobile door handle PBT material according to claim 1, it is characterised in that：The filler is deposition white carbon
Soil.
6. automobile door handle PBT material according to claim 1, it is characterised in that：The coupling agent is that titanate esters are even
Join agent.
7. automobile door handle PBT material according to claim 1, it is characterised in that：The antioxidant is irgasfos 168
With the mixture of antioxidant 264.
8. the preparation method of the automobile door handle PBT material according to claim any one of 1-7, it is characterised in that bag
Include following steps：
(1) octadecanol APEO is dissolved in the water, after stirring, regulation pH is 5-6.5, and Ag is added thereto+/
SiO2/TiO2Composite and sepiolite fibre, the scattered 2-4h of ultrasonic wave is carried out under the conditions of 40-60 DEG C, is added thereto afterwards
Coupling agent, after stirring, is centrifuged, and after 110 DEG C of drying of solid matter, modified solid mixture is made；
(3) PBT, ABS, EMA and compatilizer are put into high mixer and carried out under the conditions of 80-90 DEG C after mixing 3-4h, Xiang Qi
After modified solid mixture made from middle addition step (1) is well mixed, then PPDO, toughness reinforcing are added thereto
Agent, filler, antioxidant；It is well mixed, feed the mixture into double screw extruder, after melt blending, extruding pelletization is produced
The automobile door handle PBT material.
9. the preparation method of automobile door handle PBT material according to claim 8, it is characterised in that：The extrusion temperature
Spend for 260 DEG C, screw speed is 240rpm.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108047663A (en) * | 2017-12-15 | 2018-05-18 | 安徽悦尔伟塑料机械有限公司 | Automotive compounded door handle |
| CN108102269A (en) * | 2017-12-06 | 2018-06-01 | 安庆市可瑞实业有限公司 | A kind of bloom steam injection molded refrigerator door handle material |
| CN114479370A (en) * | 2020-10-27 | 2022-05-13 | 合肥杰事杰新材料股份有限公司 | High-glossiness modified ABS/PBT alloy material and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1072546A (en) * | 1996-06-28 | 1998-03-17 | Polyplastics Co | Thermoplastic resin composition |
| JP2002294054A (en) * | 2001-03-30 | 2002-10-09 | Polyplastics Co | Polybutylene terephthalate-based resin composition for optical housing member and molding |
| CN101205353A (en) * | 2006-12-20 | 2008-06-25 | 上海日之升新技术发展有限公司 | Impact property improved PBT and ABS alloy material |
| CN103044862A (en) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Material used for manufacturing handle of refrigerator door and preparation method thereof |
| CN103772883A (en) * | 2012-10-25 | 2014-05-07 | 合肥杰事杰新材料股份有限公司 | ABS/PBT material used by extrusion process and preparation method for ABS/PBT material |
| CN103849124A (en) * | 2012-11-30 | 2014-06-11 | 杜邦公司 | Toughening thermoplastic composition containing polyester |
| CN105400161A (en) * | 2015-12-25 | 2016-03-16 | 广东威林工程塑料有限公司 | Novel antibiosis and anti-warping reinforced PBT composite material and preparation method thereof |
| CN106835767A (en) * | 2017-03-01 | 2017-06-13 | 苏州威仕薄膜科技有限公司 | A kind of food packaging antibiotic colored polyester film and preparation method thereof |
-
2017
- 2017-07-07 CN CN201710549984.2A patent/CN107266875A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1072546A (en) * | 1996-06-28 | 1998-03-17 | Polyplastics Co | Thermoplastic resin composition |
| JP2002294054A (en) * | 2001-03-30 | 2002-10-09 | Polyplastics Co | Polybutylene terephthalate-based resin composition for optical housing member and molding |
| CN101205353A (en) * | 2006-12-20 | 2008-06-25 | 上海日之升新技术发展有限公司 | Impact property improved PBT and ABS alloy material |
| CN103044862A (en) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Material used for manufacturing handle of refrigerator door and preparation method thereof |
| CN103772883A (en) * | 2012-10-25 | 2014-05-07 | 合肥杰事杰新材料股份有限公司 | ABS/PBT material used by extrusion process and preparation method for ABS/PBT material |
| CN103849124A (en) * | 2012-11-30 | 2014-06-11 | 杜邦公司 | Toughening thermoplastic composition containing polyester |
| CN105400161A (en) * | 2015-12-25 | 2016-03-16 | 广东威林工程塑料有限公司 | Novel antibiosis and anti-warping reinforced PBT composite material and preparation method thereof |
| CN106835767A (en) * | 2017-03-01 | 2017-06-13 | 苏州威仕薄膜科技有限公司 | A kind of food packaging antibiotic colored polyester film and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102269A (en) * | 2017-12-06 | 2018-06-01 | 安庆市可瑞实业有限公司 | A kind of bloom steam injection molded refrigerator door handle material |
| CN108047663A (en) * | 2017-12-15 | 2018-05-18 | 安徽悦尔伟塑料机械有限公司 | Automotive compounded door handle |
| CN114479370A (en) * | 2020-10-27 | 2022-05-13 | 合肥杰事杰新材料股份有限公司 | High-glossiness modified ABS/PBT alloy material and preparation method thereof |
| CN114479370B (en) * | 2020-10-27 | 2023-11-03 | 合肥杰事杰新材料股份有限公司 | High-glossiness modified ABS/PBT alloy material and preparation method thereof |
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Application publication date: 20171020 |