CN112796001A - Anti-wrinkle antibacterial polyester staple fiber - Google Patents
Anti-wrinkle antibacterial polyester staple fiber Download PDFInfo
- Publication number
- CN112796001A CN112796001A CN202110131578.0A CN202110131578A CN112796001A CN 112796001 A CN112796001 A CN 112796001A CN 202110131578 A CN202110131578 A CN 202110131578A CN 112796001 A CN112796001 A CN 112796001A
- Authority
- CN
- China
- Prior art keywords
- parts
- wrinkle
- agent
- polyester staple
- staple fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Abstract
The invention relates to the technical field of fiber preparation, in particular to anti-wrinkle antibacterial polyester staple fiber; the composition comprises the following raw materials in parts by weight: 95-110 parts of PET slices, 1.8-3.5 parts of maleic anhydride grafted styrene, 3.6-4.5 parts of an antibacterial agent, 1.0-1.6 parts of a nano mixture, 0.8-1.3 parts of an antistatic agent, 0.6-1.0 part of an anti-aging agent, a proper amount of an oil agent and an anti-wrinkle finishing liquid; the compound mixture in the crease-resistant finishing agent can be accelerated to permeate into the polyester staple fibers by the matching use of the crease-resistant finishing liquid and the plasma treatment process; the crease resistance of the prepared polyester staple fiber is effectively improved; moreover, the ageing resistance of the prepared polyester staple fiber can be effectively improved by the matching use of the nano powder and the ageing resistant agent, and the service life of the polyester staple fiber is effectively prolonged; the antistatic agent enables the polyester staple fiber to have certain antistatic performance, and the quality of the prepared polyester staple fiber is effectively improved.
Description
Technical Field
The invention relates to the technical field of fiber preparation, in particular to anti-wrinkle antibacterial polyester staple fiber.
Background
Polyester fiber, commonly known as dacron. Chemical fibers are synthetic fibers. The synthetic fiber manufacturing industry is the largest-scale and most-branched sub-industry in the chemical fiber industry, and products of the synthetic fiber manufacturing industry comprise acrylic fibers, chinlon, spandex and the like besides polyester. In 2005, the yield of Chinese chemical fibers is 1629 ten thousand tons, which accounts for 37% of 4400 ten thousand tons of the world total yield. The synthetic fiber yield accounts for 92% of the total amount of the chemical fibers, and the polyester fibers account for 85% of the synthetic fibers. The terylene is divided into filaments and staple fibers, wherein the filaments account for about 62 percent, and the staple fibers account for about 38 percent. There are two methods for producing filaments and staple fibers: firstly, PTA and MEG are produced into slices, and the slices are melted and then are spun to form the fiber spinning material; one is that PTA and MEG are produced by direct spinning without slicing in the production process.
However, although the polyester staple fibers prepared by the existing process have certain mechanical strength and excellent mechanical properties, the polyester staple fibers have relatively poor antibacterial performance, so that the service life of the polyester staple fibers is shortened; moreover, the prepared fabric has certain crease resistance, but needs to be further improved, otherwise the quality of the polyester staple fiber fabric is seriously affected. Therefore, the anti-wrinkle antibacterial polyester staple fiber becomes a technical problem to be solved urgently by technical personnel in the field!
Disclosure of Invention
The invention aims to provide anti-wrinkle bacteriostatic polyester staple fiber, which not only has good bacteriostatic performance, but also prolongs the service life of the polyester staple fiber to a certain extent; in addition, the fabric has good antistatic performance and wrinkle resistance, and the prepared fabric has good wrinkle resistance, so that the quality of the fabric is effectively improved.
In order to achieve the purpose, the invention provides the following technical scheme:
the anti-wrinkle antibacterial polyester staple fiber is composed of the following raw materials in parts by weight: 95-110 parts of PET slices, 1.8-3.5 parts of maleic anhydride grafted styrene, 3.6-4.5 parts of an antibacterial agent, 1.0-1.6 parts of a nano mixture, 0.8-1.3 parts of an antistatic agent, 0.6-1.0 part of an anti-aging agent, a proper amount of an oil agent and an anti-wrinkle finishing liquid.
Furthermore, the oil agent is prepared by mixing 60-80 parts by weight of hydrogenated paraffin base oil, 10-15 parts by weight of octyl phenol polyoxyethylene ether-3 OP-3, 1.5-3.0 parts by weight of lauryl alcohol and 2.5-3.6 parts by weight of aminopropanol kojic acid phosphate.
Furthermore, the anti-wrinkle finishing liquid is prepared by mixing, by weight, deionized water, a compound mixture accounting for 8-12% of the weight of the anti-wrinkle finishing liquid, 0.6-1.2% of aluminum sulfate, 3.5-5.6% of organosilicon softener TF902, 0.8-1.5% of methylene bisacrylamide, 0.7-1.0% of triethanolamine and 0.4-0.7% of penetrant JFC.
Furthermore, the compound mixture is prepared by mixing galacturonic acid, theanine and xanthorrhizol according to the mass ratio of 2-3: 1-2.
Further, the preparation method of the antibacterial agent comprises the following steps:
I. putting the weighed chitosan into an acetic acid solution with the concentration of 1-3% according to the solid-to-liquid ratio of 0.04-0.08 g/mL, and then putting hydrogen peroxide with the mass of 8-12% of the acetic acid solution into the solution; heating the obtained mixed components to 60-70 ℃, hydrolyzing for 1-2 h at the temperature, and after the hydrolysis is finished, sequentially carrying out vacuum concentration, suction filtration, neutralization, vacuum freeze drying on the obtained mixed components to obtain the modified chitosan;
II. Dissolving the modified chitosan into deionized water with the mass being 10-15 times of that of the modified chitosan and the temperature being 50-60 ℃, and then respectively adding glutaraldehyde and carbon tetrachloride accounting for 8-12% of the mass of the modified chitosan into the deionized water by 25-35%; ultrasonically mixing the obtained mixed liquid phase for 10-20 min; then slowly dripping the mixed solution into a sodium hydroxide solution with the temperature of 38-42 ℃ and the concentration of 3-5%; after the dropwise addition, mixing and stirring for 10-15 min, washing and drying the obtained product, and storing the obtained solid particles for later use;
and III, putting the obtained solid particles into acetone with the mass 7-10 times of that of the solid particles, adding a proper amount of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane, ultrasonically mixing for 5-10 mnin, reacting for 5-8 hours at the temperature of 45-55 ℃, washing for 3-4 times after the reaction is finished, and drying to obtain the finished antibacterial agent.
Furthermore, when the product obtained in the step II is washed, the product is washed for 2-3 times by using glacial acetic acid, and then washed for 1-2 times by using an ethanol solution with the concentration of 50-60%.
Furthermore, the nano mixture is prepared by mixing nano titanium dioxide and nano zinc oxide according to the mass ratio of 1: 2-3.
Furthermore, the antistatic agent TF-480 is selected.
Furthermore, the aging-resistant agent is any one of ultraviolet absorbers UV-531, UV-326 and UV-327.
A preparation method of anti-wrinkle antibacterial polyester staple fibers comprises the following steps:
s1, weighing the raw materials according to the formula, placing the weighed PET slices in a vacuum drying oven, and drying at the temperature of 100-150 ℃ for 4-8 hours; storing the dried PET slices for later use;
s2, uniformly mixing the dried PET slices with maleic anhydride grafted styrene, an antibacterial agent, a nano mixture, an antistatic agent and an anti-aging agent, and transferring the mixture into a melt spinning machine for melt extrusion; wherein the melting temperature is set to 270-290 ℃, and the screw extrusion pressure is 6.5-7.8 MPa;
s3, cooling and oiling the melt extrusion materials in sequence, spinning in a drawing machine, and drawing by the drawing machine; in the stretching process, the speed of a heating roller during first stretching is 2800-3600 m/min, the speed of a heating roller during second stretching is 4600-5200 m/min, stretching is carried out between two heating rollers, and winding is carried out on a winding head of a second stretching heating roller;
s4, placing the obtained polyester fibers in an antibacterial finishing liquid according to a bath ratio of 20-25: 1, carrying out crease-resistant treatment at the temperature of 60-70 ℃ for 50-70 min, then fishing out the polyester fibers, washing with clear water for 2-3 times, and then drying in the air;
s5, placing the dried polyester fiber in plasma equipment, and carrying out plasma treatment on the polyester fiber for 6-10 min under the conditions that the discharge power is 80-100W and the discharge frequency is 12.5-13.5 MHz; and after drying, immersing the polyester fiber in an oil agent with the mass 10-20 times of that of the polyester fiber, and then sequentially drying, shaping and cutting the polyester fiber to obtain the finished product of the anti-wrinkle antibacterial polyester staple fiber.
Compared with the prior art, the invention has the beneficial effects that:
1. under the action of maleic anhydride grafted styrene, the antibacterial agent, the nano mixture, the antistatic agent and the aging resistant agent can be uniformly dispersed into a molten liquid formed after PET chips are melted; the method comprises the following steps of preparing an antibacterial agent, modifying chitosan to form water-soluble chitosan, and carrying out chemical reaction on the modified chitosan and glutaraldehyde to crosslink under the action of glutaraldehyde, carbon tetrachloride and other substances, so that the three-dimensional network structure of the chitosan is greatly expanded. Finally, the microsphere structure with the surface porous structure is manufactured under the action of carbon tetrachloride, so that the porosity and the specific surface area of the prepared solid particles are greatly improved. And then through the use of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane, the Y- (2, 3-epoxypropoxy) propyl trimethoxy silane and related groups on the surface of chitosan are subjected to chemical reaction to form bonds, so that the hydrophobicity of the prepared solid particles is further improved, the solid particles and PET slices are finally favorably and fully mixed with the PET slices, and the antibacterial performance of the prepared polyester staple fibers is effectively improved.
2. By using the crease-resistant finishing liquid and the plasma treatment process in a matching way, the compound mixture in the crease-resistant finishing agent can be accelerated to permeate into the polyester staple fibers. The crease resistance of the prepared polyester staple fiber is effectively improved. Moreover, the ageing resistance of the prepared polyester staple fiber can be effectively improved by the matching use of the nano powder and the ageing resistant agent, and the service life of the polyester staple fiber is effectively prolonged. The antistatic agent enables the polyester staple fiber to have certain antistatic performance, and the quality of the prepared polyester staple fiber is effectively improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The anti-wrinkle antibacterial polyester staple fiber is composed of the following raw materials in parts by weight: 95 parts of PET slices, 1.8 parts of maleic anhydride grafted styrene, 3.6 parts of an antibacterial agent, 1.0 part of a nano mixture, 0.8 part of an antistatic agent, 0.6 part of an anti-aging agent, a proper amount of an oil agent and an anti-wrinkle finishing liquid.
The oil agent is prepared by mixing 60 parts of hydrogenated paraffin-based oil, 10 parts of octyl phenol polyoxyethylene ether-3 OP-3, 1.5 parts of lauryl alcohol and 2.5 parts of aminopropanol kojic acid phosphate.
The anti-wrinkle finishing liquid is prepared by mixing deionized water, a compound mixture accounting for 8 percent of the weight of the anti-wrinkle finishing liquid, 0.6 percent of aluminum sulfate, 3.5 percent of organosilicon softener TF902, 0.8 percent of methylene bisacrylamide, 0.7 percent of triethanolamine and 0.4 percent of penetrating agent JFC.
The compound mixture is prepared by mixing galacturonic acid, theanine and xanthorrhizol according to the mass ratio of 2: 1.
The preparation method of the antibacterial agent comprises the following steps:
I. putting the weighed chitosan into an acetic acid solution with the concentration of 1% according to the solid-to-liquid ratio of 0.04g/mL, and then putting hydrogen peroxide with the mass of 8% of the acetic acid solution into the solution; heating the obtained mixed components to 60 ℃, hydrolyzing for 1h at the temperature, and after the hydrolysis is finished, sequentially carrying out vacuum concentration, suction filtration, neutralization and vacuum freeze drying on the obtained mixed components to obtain the modified chitosan;
II. Dissolving the modified chitosan in deionized water with the mass 10 times of that of the modified chitosan and the temperature of 50 ℃, and respectively adding glutaraldehyde and carbon tetrachloride with the mass 8% of that of the modified chitosan into the deionized water by 25%; ultrasonically mixing the obtained mixed liquid phase for 10 min; then slowly dripping the mixed solution into a sodium hydroxide solution with the temperature of 38 ℃ and the concentration of 3 percent; after the dropwise adding, mixing and stirring for 10min, washing and drying the obtained product, and storing the obtained solid particles for later use;
and III, putting the obtained solid particles into acetone with the mass 7 times that of the solid particles, adding a proper amount of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane into the acetone, ultrasonically mixing for 5min, reacting the mixture at the temperature of 45 ℃ for 5h, washing the mixture for 3 times after the reaction is finished, and drying to obtain the finished product of the antibacterial agent.
When the product obtained in the step II is washed, the product is washed for 2 times by glacial acetic acid and then washed for 1 time by 50 percent ethanol solution.
The nano mixture is prepared by mixing nano titanium dioxide and nano zinc oxide according to the mass ratio of 1: 2.
Antistatic agent TF-480 is selected for antistatic.
The aging resistant agent is ultraviolet absorbent UV-531.
A preparation method of anti-wrinkle antibacterial polyester staple fibers comprises the following steps:
s1, weighing the raw materials according to the formula, placing the weighed PET slices in a vacuum drying oven, and drying at 100 ℃ for 4 h; storing the dried PET slices for later use;
s2, uniformly mixing the dried PET slices with maleic anhydride grafted styrene, an antibacterial agent, a nano mixture, an antistatic agent and an anti-aging agent, and transferring the mixture into a melt spinning machine for melt extrusion; wherein the melting temperature is set to 270 ℃, and the screw extrusion pressure is 6.5 MPa;
s3, cooling and oiling the melt extrusion materials in sequence, spinning in a drawing machine, and drawing by the drawing machine; in the stretching process, the speed of a heating roller during first stretching is 2800-3600 m/min, the speed of a heating roller during second stretching is 4600-5200 m/min, stretching is carried out between two heating rollers, and winding is carried out on a winding head of a second stretching heating roller;
s4, placing the obtained polyester fibers in an antibacterial finishing liquid according to a bath ratio of 20-25: 1, carrying out crease-resistant treatment at the temperature of 60-70 ℃ for 50-70 min, then fishing out the polyester fibers, washing with clear water for 2-3 times, and then drying in the air;
s5, placing the dried polyester fiber in plasma equipment, and carrying out plasma treatment on the polyester fiber for 6-10 min under the conditions that the discharge power is 80-100W and the discharge frequency is 12.5-13.5 MHz; and after drying, immersing the polyester fiber in an oil agent with the mass 10-20 times of that of the polyester fiber, and then sequentially drying, shaping and cutting the polyester fiber to obtain the finished product of the anti-wrinkle antibacterial polyester staple fiber.
Example 2
The anti-wrinkle antibacterial polyester staple fiber is composed of the following raw materials in parts by weight: 100 parts of PET slices, 3.0 parts of maleic anhydride grafted styrene, 4.0 parts of antibacterial agent, 1.4 parts of nano mixture, 1.0 part of antistatic agent, 0.8 part of anti-aging agent, a proper amount of oil agent and anti-wrinkle finishing liquid.
The oil agent is prepared by mixing 70 parts of hydrogenated paraffin-based oil, 12 parts of octyl phenol polyoxyethylene ether-3 OP-3, 2.0 parts of lauryl alcohol and 3.0 parts of aminopropanol kojic acid phosphate.
The anti-wrinkle finishing liquid is prepared by mixing deionized water, a compound mixture with the weight of 10 percent of the anti-wrinkle finishing liquid, 0.8 percent of aluminum sulfate, 4.8 percent of organosilicon softener TF902, 1.2 percent of methylene bisacrylamide, 0.8 percent of triethanolamine and 0.6 percent of penetrating agent JFC according to the weight components.
The compound mixture is prepared by mixing galacturonic acid, theanine and xanthorrhizol according to the mass ratio of 2.5: 1: 1.5.
The preparation method of the antibacterial agent comprises the following steps:
I. putting the weighed chitosan into an acetic acid solution with the concentration of 2% according to the solid-to-liquid ratio of 0.06g/mL, and then putting hydrogen peroxide with the mass of 10% of the acetic acid solution into the solution; heating the obtained mixed components to 65 ℃, hydrolyzing for 1h at the temperature, and after the hydrolysis is finished, sequentially carrying out vacuum concentration, suction filtration, neutralization, vacuum freeze drying on the obtained mixed components to obtain the modified chitosan;
II. Dissolving the modified chitosan in deionized water with the mass being 12 times of that of the modified chitosan and the temperature being 55 ℃, and respectively adding glutaraldehyde and carbon tetrachloride with the mass being 10% of that of the modified chitosan into the deionized water by 30%; ultrasonically mixing the obtained mixed liquid phase for 15 min; then slowly dripping the mixed solution into a sodium hydroxide solution with the temperature of 40 ℃ and the concentration of 4 percent; after the dropwise adding, mixing and stirring for 10min, washing and drying the obtained product, and storing the obtained solid particles for later use;
and III, putting the obtained solid particles into acetone with the mass 8 times that of the solid particles, adding a proper amount of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane into the acetone, ultrasonically mixing for 5min, reacting the mixture at the temperature of 50 ℃ for 6h, washing the mixture for 3 times after the reaction is finished, and drying to obtain the finished product of the antibacterial agent.
When the product obtained in the step II is washed, the product is washed for 2 times by glacial acetic acid and then washed for 1 time by 55 percent ethanol solution.
The nano mixture is prepared by mixing nano titanium dioxide and nano zinc oxide according to the mass ratio of 1: 2.5.
Antistatic agent TF-480 is selected for antistatic.
The aging resistant agent is ultraviolet absorbent UV-326.
A preparation method of anti-wrinkle antibacterial polyester staple fibers comprises the following steps:
s1, weighing the raw materials according to the formula, placing the weighed PET slices in a vacuum drying oven, and drying at 120 ℃ for 6 hours; storing the dried PET slices for later use;
s2, uniformly mixing the dried PET slices with maleic anhydride grafted styrene, an antibacterial agent, a nano mixture, an antistatic agent and an anti-aging agent, and transferring the mixture into a melt spinning machine for melt extrusion; wherein the melting temperature is set to 280 ℃, and the screw extrusion pressure is 7.0 MPa;
s3, cooling and oiling the melt extrusion materials in sequence, spinning in a drawing machine, and drawing by the drawing machine; in the stretching process, the speed of a heating roller during first stretching is 3200m/min, the speed of a heating roller during second stretching is 5000m/min, stretching is carried out between two heating rollers, and winding is carried out on a winding head of a second stretching heating roller;
s4, placing the obtained polyester fiber in an antibacterial finishing liquid according to a bath ratio of 23: 1, carrying out crease-resistant treatment at a temperature of 65 ℃ for 60min, taking out the polyester fiber, washing the polyester fiber with clear water for 2 times, and then airing the polyester fiber;
s5, placing the dried polyester fiber in plasma equipment, and carrying out plasma treatment for 8min under the conditions that the discharge power is 90W and the discharge frequency is 13.0 MHz; after drying treatment, immersing the polyester fiber in oil solution with the mass 15 times of that of the polyester fiber, and then sequentially drying, shaping and cutting the polyester fiber to obtain the finished product of the anti-wrinkle antibacterial polyester staple fiber.
Example 3
The anti-wrinkle antibacterial polyester staple fiber is composed of the following raw materials in parts by weight: 110 parts of PET slices, 3.5 parts of maleic anhydride grafted styrene, 4.5 parts of an antibacterial agent, 1.6 parts of a nano mixture, 1.3 parts of an antistatic agent, 1.0 part of an aging resistant agent, a proper amount of an oil agent and an anti-wrinkle finishing liquid.
The oil agent is prepared by mixing 80 parts by weight of hydrogenated paraffin-based oil, 15 parts by weight of octyl phenol polyoxyethylene ether-3 OP-3, 3.0 parts by weight of lauryl alcohol and 3.6 parts by weight of aminopropanol kojic acid phosphate.
The anti-wrinkle finishing liquid is prepared by mixing deionized water, a compound mixture with the weight of 12 percent of the anti-wrinkle finishing liquid, 1.2 percent of aluminum sulfate, 5.6 percent of organosilicon softener TF902, 1.5 percent of methylene bisacrylamide, 1.0 percent of triethanolamine and 0.7 percent of penetrating agent JFC according to the weight components.
The compound mixture is prepared by mixing galacturonic acid, theanine and xanthorrhizol according to the mass ratio of 3: 1: 2.
The preparation method of the antibacterial agent comprises the following steps:
I. putting the weighed chitosan into an acetic acid solution with the concentration of 3% according to the solid-to-liquid ratio of 0.08g/mL, and then putting hydrogen peroxide with the mass of 12% of the acetic acid solution into the solution; heating the obtained mixed components to 70 ℃, hydrolyzing for 2h at the temperature, and after the hydrolysis is finished, sequentially carrying out vacuum concentration, suction filtration, neutralization, vacuum freeze drying on the obtained mixed components to obtain the modified chitosan;
II. Dissolving the modified chitosan in deionized water with the mass 15 times of that of the modified chitosan and the temperature of 60 ℃, and respectively adding 12% of glutaraldehyde and 35% of carbon tetrachloride into the deionized water; ultrasonically mixing the obtained mixed liquid phase for 20 min; then slowly dripping the mixed solution into a sodium hydroxide solution with the temperature of 42 ℃ and the concentration of 5 percent; after the dropwise adding, mixing and stirring for 15min, washing and drying the obtained product, and storing the obtained solid particles for later use;
and III, putting the obtained solid particles into acetone with the mass 10 times that of the solid particles, adding a proper amount of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane into the acetone, ultrasonically mixing the mixture for 10min, reacting the mixture at the temperature of 55 ℃ for 8h, washing the mixture for 4 times after the reaction is finished, and drying the mixture to obtain the finished product of the antibacterial agent.
When the product obtained in the step II is washed, the product is washed for 3 times by glacial acetic acid and then washed for 2 times by 60 percent ethanol solution.
The nano mixture is prepared by mixing nano titanium dioxide and nano zinc oxide according to the mass ratio of 1: 3.
Antistatic agent TF-480 is selected for antistatic.
The aging resistant agent is ultraviolet absorbent UV-327.
A preparation method of anti-wrinkle antibacterial polyester staple fibers comprises the following steps:
s1, weighing the raw materials according to the formula, placing the weighed PET slices in a vacuum drying oven, and drying at 150 ℃ for 8 h; storing the dried PET slices for later use;
s2, uniformly mixing the dried PET slices with maleic anhydride grafted styrene, an antibacterial agent, a nano mixture, an antistatic agent and an anti-aging agent, and transferring the mixture into a melt spinning machine for melt extrusion; wherein the melting temperature is set to 290 ℃, and the screw extrusion pressure is 7.8 MPa;
s3, cooling and oiling the melt extrusion materials in sequence, spinning in a drawing machine, and drawing by the drawing machine; in the stretching process, the speed of a heating roller during first stretching is 3600m/min, the speed of a heating roller during second stretching is 5200m/min, the stretching is carried out between two heating rollers, and the stretching is carried out on a winding head of a second stretching heating roller;
s4, placing the obtained polyester fiber in an antibacterial finishing liquid according to a bath ratio of 25: 1, carrying out crease-resistant treatment at the temperature of 70 ℃ for 70min, then fishing out the polyester fiber, washing the polyester fiber with clear water for 3 times, and then airing the polyester fiber;
s5, placing the dried polyester fiber in plasma equipment, and carrying out plasma treatment on the polyester fiber for 10min under the conditions that the discharge power is 100W and the discharge frequency is 13.5 MHz; after drying treatment, immersing the polyester fiber in oil solution with the mass 20 times of that of the polyester fiber, and then sequentially drying, shaping and cutting the polyester fiber to obtain the finished product of the anti-wrinkle antibacterial polyester staple fiber.
Comparative example 1: the polyester staple fiber prepared by the preparation method provided by the embodiment 1 of the invention is different in that the antibacterial agent provided by the invention is not used;
comparative example 2: the polyester staple fiber prepared by the preparation method provided by the embodiment 1 of the invention is different in that the crease-resistant finishing liquid provided by the invention is not used;
performance testing
Respectively manufacturing polyester staple fibers prepared in examples 1-3 and comparative examples 1-2 of the invention into polyester fabrics, and respectively marking the polyester staple fibers as experimental examples 1-3 and comparative examples 1-2; then, the following performance tests are respectively carried out on the polyester fabrics provided in the experimental examples 1-3 and the comparative examples 1-2:
1. the national standard GB/T20944.3-2008 < evaluation of antibacterial properties of textiles part 3: the oscillation method is used for measuring the antibacterial performance of the polyester fabric samples, and the obtained data is recorded in the table 1;
2. measuring the surface charge areal density of each group of polyester fabric samples according to GB/T12703.2-2009 static test method for textiles, and recording the obtained data in Table 1;
3. and (3) testing the wrinkle resistance and the flatness: wrinkle recovery according to IS09867 fabric using a wrinkle testing machine: grading the appearance smoothness, standing for 24h at constant temperature and constant humidity, and obtaining test data shown in table 1;
TABLE 1
As can be seen from the relevant data in Table 1, the polyester staple fiber prepared according to the invention not only has good bacteriostatic performance, but also prolongs the service life of the polyester staple fiber to a certain extent. In addition, the fabric has good antistatic performance and wrinkle resistance, and the prepared fabric has good wrinkle resistance, so that the quality of the fabric is effectively improved. Therefore, the polyester staple fiber prepared by the method has wider market prospect and is more suitable for popularization.
In the description herein, reference to the description of the terms "one embodiment," "an example," "a specific example," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.
Claims (8)
1. The anti-wrinkle antibacterial polyester staple fiber is characterized by comprising the following raw materials in parts by weight: 95-110 parts of PET slices, 1.8-3.5 parts of maleic anhydride grafted styrene, 3.6-4.5 parts of an antibacterial agent, 1.0-1.6 parts of a nano mixture, 0.8-1.3 parts of an antistatic agent, 0.6-1.0 part of an anti-aging agent, a proper amount of an oil agent and an anti-wrinkle finishing liquid;
the preparation method of the antibacterial agent comprises the following steps:
I. putting the weighed chitosan into an acetic acid solution with the concentration of 1-3% according to the solid-to-liquid ratio of 0.04-0.08 g/mL, and then putting hydrogen peroxide with the mass of 8-12% of the acetic acid solution into the solution; heating the obtained mixed components to 60-70 ℃, hydrolyzing for 1-2 h at the temperature, and after the hydrolysis is finished, sequentially carrying out vacuum concentration, suction filtration, neutralization, vacuum freeze drying on the obtained mixed components to obtain the modified chitosan;
II. Dissolving the modified chitosan into deionized water with the mass being 10-15 times of that of the modified chitosan and the temperature being 50-60 ℃, and then respectively adding glutaraldehyde and carbon tetrachloride accounting for 8-12% of the mass of the modified chitosan into the deionized water by 25-35%; ultrasonically mixing the obtained mixed liquid phase for 10-20 min; then slowly dripping the mixed solution into a sodium hydroxide solution with the temperature of 38-42 ℃ and the concentration of 3-5%; after the dropwise adding is finished, mixing and stirring for 10-15 min, washing and drying the obtained product, and storing the obtained solid particles for later use;
III, putting the obtained solid particles into acetone with the mass 7-10 times of that of the solid particles, adding a proper amount of Y- (2, 3-epoxypropoxy) propyl trimethoxy silane, ultrasonically mixing for 5-10 min, reacting at the temperature of 45-55 ℃ for 5-8 h, washing for 3-4 times after the reaction is finished, and drying to obtain the finished antibacterial agent;
the preparation method of the anti-wrinkle bacteriostatic polyester staple fiber is characterized by comprising the following steps of:
s1, weighing the raw materials according to the formula, placing the weighed PET slices in a vacuum drying oven, and drying at the temperature of 100-150 ℃ for 4-8 hours; storing the dried PET slices for later use;
s2, uniformly mixing the dried PET slices with maleic anhydride grafted styrene, an antibacterial agent, a nano mixture, an antistatic agent and an anti-aging agent, and transferring the mixture into a melt spinning machine for melt extrusion; wherein the melting temperature is set to 270-290 ℃, and the screw extrusion pressure is 6.5-7.8 MPa;
s3, cooling and oiling the melt extrusion materials in sequence, spinning in a drawing machine, and drawing by the drawing machine; in the stretching process, the speed of a heating roller during first stretching is 2800-3600 m/min, the speed of a heating roller during second stretching is 4600-5200 m/min, stretching is carried out between two heating rollers, and winding is carried out on a winding head of the second stretching heating roller;
s4, mixing the raw materials according to a bath ratio of 20-25: 1, placing the obtained polyester fiber in an antibacterial finishing liquid, carrying out crease-resistant treatment at the temperature of 60-70 ℃ for 50-70 min, then fishing out the polyester fiber, washing with clear water for 2-3 times, and then drying in the air;
s5, placing the dried polyester fiber in plasma equipment, and carrying out plasma treatment on the polyester fiber for 6-10 min under the conditions that the discharge power is 80-100W and the discharge frequency is 12.5-13.5 MHz; and after drying, immersing the polyester fiber in an oil agent with the mass 10-20 times of that of the polyester fiber, and then sequentially drying, shaping and cutting the polyester fiber to obtain the finished product of the anti-wrinkle antibacterial polyester staple fiber.
2. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 1, wherein the oil agent is prepared by mixing 60-80 parts by weight of hydrogenated paraffin-based oil, 10-15 parts by weight of octyl phenol polyoxyethylene ether-3 OP-3, 1.5-3.0 parts by weight of lauryl alcohol and 2.5-3.6 parts by weight of aminopropanol kojic acid phosphate.
3. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 1, wherein the anti-wrinkle finishing liquid is prepared by mixing, by weight, deionized water, 8-12% of a compound mixture, 0.6-1.2% of aluminum sulfate, 3.5-5.6% of an organic silicon softener TF902, 0.8-1.5% of methylene bisacrylamide, 0.7-1.0% of triethanolamine and 0.4-0.7% of a penetrant JFC.
4. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 3, which is characterized in that: the compound mixture is prepared from galacturonic acid, theanine and xanthorrhizol according to a mass ratio of 2-3: 1: 1-2.
5. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 4, which is characterized in that: and when the product obtained in the step II is washed, the product is washed for 2-3 times by using glacial acetic acid, and then washed for 1-2 times by using an ethanol solution with the concentration of 50-60%.
6. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 5, which is characterized in that: the nano mixture is prepared by mixing nano titanium dioxide and nano zinc oxide according to the mass ratio of 1: 2-3.
7. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 1, which is characterized in that: the antistatic agent TF-480 is selected.
8. The anti-wrinkle bacteriostatic polyester staple fiber according to claim 1, which is characterized in that: the aging resistant agent is any one of ultraviolet absorbers UV-531, UV-326 and UV-327.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110131578.0A CN112796001A (en) | 2021-01-30 | 2021-01-30 | Anti-wrinkle antibacterial polyester staple fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110131578.0A CN112796001A (en) | 2021-01-30 | 2021-01-30 | Anti-wrinkle antibacterial polyester staple fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112796001A true CN112796001A (en) | 2021-05-14 |
Family
ID=75813144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110131578.0A Withdrawn CN112796001A (en) | 2021-01-30 | 2021-01-30 | Anti-wrinkle antibacterial polyester staple fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112796001A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113417146A (en) * | 2021-05-26 | 2021-09-21 | 杭州叶茂纺织有限公司 | High-wear-resistance DTY and preparation method thereof |
| CN113529253A (en) * | 2021-07-08 | 2021-10-22 | 铭锋（福建）织造有限公司 | Crease-resistant silk-like fabric and processing technology thereof |
| CN115559049A (en) * | 2021-07-01 | 2023-01-03 | 江苏盛邦纺织品有限公司 | Antibacterial crease-resistant fabric and production method and application thereof |
| CN116180285A (en) * | 2023-02-01 | 2023-05-30 | 张家港市荣昌涤纶毛条有限公司 | Composite polyester ultra-soft long cilia strip and preparation method thereof |
-
2021
- 2021-01-30 CN CN202110131578.0A patent/CN112796001A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113417146A (en) * | 2021-05-26 | 2021-09-21 | 杭州叶茂纺织有限公司 | High-wear-resistance DTY and preparation method thereof |
| CN115559049A (en) * | 2021-07-01 | 2023-01-03 | 江苏盛邦纺织品有限公司 | Antibacterial crease-resistant fabric and production method and application thereof |
| CN113529253A (en) * | 2021-07-08 | 2021-10-22 | 铭锋（福建）织造有限公司 | Crease-resistant silk-like fabric and processing technology thereof |
| CN116180285A (en) * | 2023-02-01 | 2023-05-30 | 张家港市荣昌涤纶毛条有限公司 | Composite polyester ultra-soft long cilia strip and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112796001A (en) | Anti-wrinkle antibacterial polyester staple fiber | |
| CN103741258B (en) | A kind of hydrophilic polyester fibers and preparation method thereof | |
| CN113956420B (en) | Polyurethane yoga mat and preparation method thereof | |
| CN104264326A (en) | Method for preparing polyurethane glass fiber composite fiber cloth | |
| CN107043466B (en) | A kind of modification of chitosan-silicon dioxide composite aerogel material and its preparation method and application | |
| CN108795018B (en) | Preparation method of polyurethane/cellulose multifunctional shape memory polymer material | |
| CN112301505B (en) | Seamless down-filled down jacket fabric and production method thereof | |
| CN113957557A (en) | Efficient flame-retardant lyocell fiber and preparation method thereof | |
| CN113442529B (en) | Thermoplastic elastomer toughening film composite fabric | |
| CN111472193B (en) | Para-aramid nano-fiber mica paper and preparation method thereof | |
| CN113638132A (en) | Water-repellent oil-repellent high-strength antibacterial fabric and preparation method thereof | |
| CN109876547B (en) | High-performance filter material and preparation method thereof | |
| CN114197113A (en) | Antioxidant non-woven fabric and preparation method thereof | |
| CN110903606B (en) | Plant oil-based composite material and preparation method thereof | |
| CN116657314A (en) | Fragrant breathable antibacterial fabric | |
| CN112176444A (en) | Oxidation-resistant fiber containing taxus chinensis and preparation method thereof | |
| CN114990898A (en) | High-elasticity wear-resistant fabric and preparation method thereof | |
| CN111574070B (en) | Glass fiber impregnating compound and production method of glass fiber | |
| CN110028775B (en) | Preparation method of stretch-resistant strapping material | |
| CN113666880A (en) | Flame-retardant nylon 6 fiber and preparation method thereof | |
| CN109403101B (en) | Low-temperature stripping method for dyed fabric | |
| CN111621863A (en) | Processing technology of functional nano regenerated fiber | |
| CN109610035A (en) | Cage type polysilsesquioxane and nanometer Tai Ji stone are total to modified polyester fiber and preparation method thereof and textile | |
| CN110527342A (en) | A kind of extinguishing waterborn coating and preparation method thereof with metallic luster | |
| CN108467579A (en) | A kind of organic glass fiber composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20210514 |