CN107699976A - A kind of antistatic PET filament and preparation method thereof - Google Patents
A kind of antistatic PET filament and preparation method thereof Download PDFInfo
- Publication number
- CN107699976A CN107699976A CN201711057288.6A CN201711057288A CN107699976A CN 107699976 A CN107699976 A CN 107699976A CN 201711057288 A CN201711057288 A CN 201711057288A CN 107699976 A CN107699976 A CN 107699976A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- added
- taken
- preparation
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of antistatic PET filament, and it is made up of the raw material of following weight parts：Polyethylene terephthalate 110 130, antistatic solution 14 20, epoxy Linseed oil 24, zinc stearate 12, calgon 0.7 1, octyl phenyl cyclotetrasiloxane 0.1 0.3, calcium carbonate 68, its compatibility with polyethylene terephthalate is effectively raised, improves the stability_intensity of finished fiber material.
Description
Technical field
The invention belongs to terylene field, and in particular to a kind of antistatic PET filament and preparation method thereof.
Background technology
Polyester fiber is an important kind in synthetic fibers, is the trade name of China's polyester fiber.It is with essence
Terephthalic acid (TPA) or dimethyl terephthalate (DMT) and ethylene glycol be raw material through esterification or ester exchange with prepared by polycondensation reaction into
Fine high polymer-polyethylene terephthalate, through fiber made of spinning and post processing.Polyester fiber is that three big synthesis are fine
The simplest one kind of technique, price are also relatively cheap in dimension.Along with it has, durable, elasticity is good, is unlikely to deform, corrosion resistant
The features such as losing, insulating, be well-pressed and quick-drying washable, is liked by people.The species of polyester fiber fabric is more, is washed except the system of knitting is pure
Outside synthetic fibre fabric, the product of also many and various textile fabric blend polyesters or intertexture, the deficiency of pure dacron is compensate for, sent out
Shoot and preferably play performance；
At present, with the development of science and technology and the demand of Modern Live, new want it is also proposed to the performance of polyester fiber
Ask, for example polyester fiber will reach ultra-fine rank, it is such as super so as to realize some additional properties to produce larger ratio surface level
The performance such as strong water suction, decontamination, antistatic.
The content of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of antistatic PET filament and its system
Preparation Method.
To achieve the above object, the present invention uses following technical scheme：
A kind of antistatic PET filament, it is made up of the raw material of following weight parts：
Polyethylene terephthalate 110-130, antistatic solution 14-20, epoxy Linseed oil 2-4, zinc stearate
1-2, calgon 0.7-1, octyl phenyl cyclotetrasiloxane 0.1-0.3, calcium carbonate 6-8.
Described antistatic solution is made up of the raw material of following weight parts：
Lauric acid amide of ethanol 1-2, neopelex 2-4, castor oil acid calcium 0.1-0.2, borax 2-3.
The preparation method of described antistatic solution comprises the following steps：
(1) castor oil acid calcium is taken, is added in the absolute ethyl alcohol of 5-7 times of its weight, stirs；
(2) lauric acid amide of ethanol, neopelex mixing are taken, is added to 14-20 times of compound weight
In deionized water, stir；
(3) raw material for mixing above-mentioned preparation mixes, and stirs, and adds borax, the insulated and stirred 1-2 at 50-60 DEG C
Hour, ethanol is distilled off, produces the antistatic solution.
A kind of preparation method of antistatic PET filament, comprises the following steps：
(1) calcium carbonate, zinc stearate mixing are taken, the insulated and stirred 20-30 minutes at 65-70 DEG C, is added to above-mentioned anti-quiet
In electric solution, stir, obtain organic antistatic solution；
(2) calgon is taken, is added in the deionized water of 10-15 times of its weight, stirs, it is and above-mentioned organic anti-
Electrostatic solution mixes, and adds octyl phenyl cyclotetrasiloxane, ultrasonic 1-2 hours, obtains silane dispersion fluid；
(3) polyethylene terephthalate, the mixing of epoxy Linseed oil are taken, insulated and stirred 15-20 points at 85-90 DEG C
Clock, it is added in above-mentioned silane dispersion fluid, stirs, filter, precipitation is washed, air drying, heating melting, is extruded, spray
Silk shaping.
Advantages of the present invention：
Added in the fiber of the present invention using lauric acid amide of ethanol, neopelex as the antistatic of raw material
Agent, the antistatic property of finished fiber can be effectively improved, expand the application of fiber, the present invention disperses calcium carbonate
Into antistatic solution, organic-treating is carried out using zinc stearate, effectively raises itself and polyethylene terephthalate
The compatibility of ester, improve the stability_intensity of finished fiber material.
Embodiment
Embodiment 1
A kind of antistatic PET filament, it is made up of the raw material of following weight parts：
Polyethylene terephthalate 130, antistatic solution 20, epoxy Linseed oil 4, zinc stearate 2, hexa metaphosphoric acid
Sodium 1, octyl phenyl cyclotetrasiloxane 0.3, calcium carbonate 8.
Described antistatic solution is made up of the raw material of following weight parts：
Lauric acid amide of ethanol 2, neopelex 4, castor oil acid calcium 0.2, borax 3.
The preparation method of described antistatic solution comprises the following steps：
(1) castor oil acid calcium is taken, is added in the absolute ethyl alcohol of 7 times of its weight, stirs；
(2) take lauric acid amide of ethanol, neopelex mixing, be added to 20 times of compound weight go from
In sub- water, stir；
(3) raw material for mixing above-mentioned preparation mixes, and stirs, addition borax, insulated and stirred 2 hours at 60 DEG C,
Ethanol is distilled off, produces the antistatic solution.
A kind of preparation method of antistatic PET filament, comprises the following steps：
(1) calcium carbonate, zinc stearate mixing are taken, insulated and stirred 30 minutes at 70 DEG C, is added to above-mentioned antistatic solution
In, stir, obtain organic antistatic solution；
(2) calgon is taken, is added in the deionized water of 15 times of its weight, stirs, it is and above-mentioned organic anti-quiet
Electric solution mixing, adds octyl phenyl cyclotetrasiloxane, ultrasound 2 hours, obtains silane dispersion fluid；
(3) polyethylene terephthalate, the mixing of epoxy Linseed oil are taken, insulated and stirred 20 minutes, add at 90 DEG C
Enter into above-mentioned silane dispersion fluid, stir, filter, will precipitation washing, air drying, heating melting, extruding, spinneret into
Type.
Embodiment 2
A kind of antistatic PET filament, it is made up of the raw material of following weight parts：
Polyethylene terephthalate 110, antistatic solution 14, epoxy Linseed oil 2, zinc stearate 1, hexa metaphosphoric acid
Sodium 0.7, octyl phenyl cyclotetrasiloxane 0.1, calcium carbonate 6.
Described antistatic solution is made up of the raw material of following weight parts：
Lauric acid amide of ethanol 1, neopelex 2, castor oil acid calcium 0.1, borax 2.
The preparation method of described antistatic solution comprises the following steps：
(1) castor oil acid calcium is taken, is added in the absolute ethyl alcohol of 5 times of its weight, stirs；
(2) take lauric acid amide of ethanol, neopelex mixing, be added to 14 times of compound weight go from
In sub- water, stir；
(3) raw material for mixing above-mentioned preparation mixes, and stirs, addition borax, insulated and stirred 1 hour at 50 DEG C,
Ethanol is distilled off, produces the antistatic solution.
A kind of preparation method of antistatic PET filament, comprises the following steps：
(1) calcium carbonate, zinc stearate mixing are taken, insulated and stirred 20 minutes at 65 DEG C, is added to above-mentioned antistatic solution
In, stir, obtain organic antistatic solution；
(2) calgon is taken, is added in the deionized water of 10 times of its weight, stirs, it is and above-mentioned organic anti-quiet
Electric solution mixing, adds octyl phenyl cyclotetrasiloxane, ultrasound 1 hour, obtains silane dispersion fluid；
(3) polyethylene terephthalate, the mixing of epoxy Linseed oil are taken, insulated and stirred 15 minutes, add at 85 DEG C
Enter into above-mentioned silane dispersion fluid, stir, filter, will precipitation washing, air drying, heating melting, extruding, spinneret into
Type.
Performance test：
Dry-hot shrinkage is 53-55%, fiber strength 2.1-2.5cn/dtex；Surface resistivity reaches 108Ω。
Claims (4)
1. a kind of antistatic PET filament, it is characterised in that it is made up of the raw material of following weight parts：
Polyethylene terephthalate 110-130, antistatic solution 14-20, epoxy Linseed oil 2-4, zinc stearate 1-2,
Calgon 0.7-1, octyl phenyl cyclotetrasiloxane 0.1-0.3, calcium carbonate 6-8.
2. a kind of antistatic PET filament according to claim 1, it is characterised in that described antistatic solution is under
State the raw material composition of parts by weight：
Lauric acid amide of ethanol 1-2, neopelex 2-4, castor oil acid calcium 0.1-0.2, borax 2-3.
A kind of 3. antistatic PET filament according to claim 2, it is characterised in that the preparation of described antistatic solution
Method comprises the following steps：
(1) castor oil acid calcium is taken, is added in the absolute ethyl alcohol of 5-7 times of its weight, stirs；
(2) take lauric acid amide of ethanol, neopelex mixing, be added to 14-20 times of compound weight go from
In sub- water, stir；
(3) raw material for mixing above-mentioned preparation mixes, and stirs, addition borax, the insulated and stirred 1-2 hours at 50-60 DEG C,
Ethanol is distilled off, produces the antistatic solution.
4. a kind of preparation method of antistatic PET filament as claimed in claim 1, it is characterised in that comprise the following steps：
(1) calcium carbonate, zinc stearate mixing are taken, the insulated and stirred 20-30 minutes at 65-70 DEG C, is added to above-mentioned antistatic molten
In liquid, stir, obtain organic antistatic solution；
(2) calgon is taken, is added in the deionized water of 10-15 times of its weight, stirs, it is and above-mentioned organic antistatic
Solution mixes, and adds octyl phenyl cyclotetrasiloxane, ultrasonic 1-2 hours, obtains silane dispersion fluid；
(3) polyethylene terephthalate, epoxy Linseed oil is taken to mix, the insulated and stirred 15-20 minutes at 85-90 DEG C,
Be added in above-mentioned silane dispersion fluid, stir, filter, will precipitation washing, air drying, heating melting, extruding, spinneret into
Type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711057288.6A CN107699976A (en) | 2017-11-01 | 2017-11-01 | A kind of antistatic PET filament and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711057288.6A CN107699976A (en) | 2017-11-01 | 2017-11-01 | A kind of antistatic PET filament and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107699976A true CN107699976A (en) | 2018-02-16 |
Family
ID=61177505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711057288.6A Pending CN107699976A (en) | 2017-11-01 | 2017-11-01 | A kind of antistatic PET filament and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107699976A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108532017A (en) * | 2018-04-09 | 2018-09-14 | 温州市赢创新材料技术有限公司 | A kind of antistatic hard fibre and preparation method thereof |
| CN110306283A (en) * | 2019-06-14 | 2019-10-08 | 福建七匹狼实业股份有限公司 | A kind of antistatic knitting fabric |
| CN111334133A (en) * | 2020-04-02 | 2020-06-26 | 汉中木头人科技信息咨询有限公司 | Graphene antistatic coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101748507A (en) * | 2008-12-05 | 2010-06-23 | 东丽纤维研究所（中国）有限公司 | Lasting anti-static polyester fiber and production method thereof |
| CN103397401A (en) * | 2013-08-15 | 2013-11-20 | 苏州龙杰特种纤维股份有限公司 | Polyester fiber |
| CN105542404A (en) * | 2016-01-18 | 2016-05-04 | 苏州法斯特信息科技有限公司 | Novel anti-static textile material and preparation method thereof |
-
2017
- 2017-11-01 CN CN201711057288.6A patent/CN107699976A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101748507A (en) * | 2008-12-05 | 2010-06-23 | 东丽纤维研究所（中国）有限公司 | Lasting anti-static polyester fiber and production method thereof |
| CN103397401A (en) * | 2013-08-15 | 2013-11-20 | 苏州龙杰特种纤维股份有限公司 | Polyester fiber |
| CN105542404A (en) * | 2016-01-18 | 2016-05-04 | 苏州法斯特信息科技有限公司 | Novel anti-static textile material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108532017A (en) * | 2018-04-09 | 2018-09-14 | 温州市赢创新材料技术有限公司 | A kind of antistatic hard fibre and preparation method thereof |
| CN110306283A (en) * | 2019-06-14 | 2019-10-08 | 福建七匹狼实业股份有限公司 | A kind of antistatic knitting fabric |
| CN111334133A (en) * | 2020-04-02 | 2020-06-26 | 汉中木头人科技信息咨询有限公司 | Graphene antistatic coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107699976A (en) | A kind of antistatic PET filament and preparation method thereof | |
| CN107033564B (en) | Long fine and polylactic acid blend composite material the preparation method of bamboo fibre after surface-modified | |
| CN101481494B (en) | Thermoplastic polyester alloy nano composite material and preparation thereof | |
| CN103541039A (en) | Multifunctional modified polyester staple fiber and preparation method of same | |
| CN102978744B (en) | Method for manufacturing conductive polyester fibers | |
| CN105442079A (en) | Environment-friendly high-strength polyester fibers | |
| CN102828274B (en) | Anti-ultraviolet functional polyester staple fibers containing coffee carbon and preparation method thereof | |
| CN106120013B (en) | A kind of static resistant polyamide fiber applied to underwear | |
| CN102953147B (en) | Coffee carbon-containing anti-flaming polyester staple fiber and preparation method thereof | |
| CN105008459A (en) | Polylactic resin composition, molded product, and method for producing polylactic resin composition | |
| CN104514041A (en) | Degradable fiber and preparation method thereof | |
| CN106317390B (en) | A kind of preparation method of moisture absorption antistatic polyester and fiber | |
| CN1869290A (en) | Sea-island composite superfine staple and its preparation method | |
| CN106543713A (en) | A kind of polytetrafluoroethylmodified modified wear-resisting type glass fiber reinforced PA66 electric armour clamp material and preparation method thereof | |
| CN109440223A (en) | A kind of wet fiber material preparation method of spiral porous structure | |
| CN106566241A (en) | Insulation flame-retardant glass fiber reinforced PA66/PPS/PES power fitting material and preparation method thereof | |
| CN109735916A (en) | A kind of preparation method of modified synthetic fibers | |
| CN112663167A (en) | Flame-retardant polyester fiber and preparation method thereof | |
| CN107266875A (en) | A kind of automobile door handle PBT material and preparation method thereof | |
| CN107604467A (en) | A kind of gel polyester fiber and preparation method thereof | |
| CN108753157A (en) | A kind of novel environment friendly coatings and preparation method thereof | |
| CN107502967A (en) | A kind of new composite polyester fiber | |
| CN107630263A (en) | A kind of flame retardant polyester fiber and preparation method thereof | |
| CN107475810A (en) | A kind of chemical polyester fiber | |
| CN109082010A (en) | A kind of halogen-free expanded flame-retardant fibre reinforced acrylic resin composite material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180216 |