CN101235580B - 纤维素长丝纺粘织物的制造方法和装置 - Google Patents
纤维素长丝纺粘织物的制造方法和装置 Download PDFInfo
- Publication number
- CN101235580B CN101235580B CN2007103062635A CN200710306263A CN101235580B CN 101235580 B CN101235580 B CN 101235580B CN 2007103062635 A CN2007103062635 A CN 2007103062635A CN 200710306263 A CN200710306263 A CN 200710306263A CN 101235580 B CN101235580 B CN 101235580B
- Authority
- CN
- China
- Prior art keywords
- cooling
- diffuser
- long filament
- air
- cooling chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000004744 fabric Substances 0.000 title description 26
- 238000001816 cooling Methods 0.000 claims abstract description 94
- 229920002678 cellulose Polymers 0.000 claims abstract description 33
- 239000001913 cellulose Substances 0.000 claims abstract description 33
- 239000012736 aqueous medium Substances 0.000 claims abstract description 19
- 238000009987 spinning Methods 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000007921 spray Substances 0.000 claims description 15
- 239000004745 nonwoven fabric Substances 0.000 claims description 10
- 238000009792 diffusion process Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 150000003512 tertiary amines Chemical class 0.000 claims description 6
- 229920000433 Lyocell Polymers 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000002609 medium Substances 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 239000012080 ambient air Substances 0.000 abstract 2
- 239000003570 air Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 15
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000005086 pumping Methods 0.000 description 5
- 230000001112 coagulating effect Effects 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000024287 Areas Species 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical group ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/013—Regenerated cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/14—Stretch-spinning methods with flowing liquid or gaseous stretching media, e.g. solution-blowing
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/015—Natural yarns or filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
- Treatment Of Fiber Materials (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06026730.9A EP1936017B1 (de) | 2006-12-22 | 2006-12-22 | Verfahren und Vorrichtung zur Herstellung eines Spinnvlieses aus cellulosischen Filamenten |
| EP06026730.9 | 2006-12-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101235580A CN101235580A (zh) | 2008-08-06 |
| CN101235580B true CN101235580B (zh) | 2013-03-27 |
Family
ID=38512139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007103062635A Expired - Fee Related CN101235580B (zh) | 2006-12-22 | 2007-12-21 | 纤维素长丝纺粘织物的制造方法和装置 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20090026647A1 (enExample) |
| EP (1) | EP1936017B1 (enExample) |
| JP (1) | JP5065873B2 (enExample) |
| KR (1) | KR100987743B1 (enExample) |
| CN (1) | CN101235580B (enExample) |
| AR (1) | AR064408A1 (enExample) |
| BR (1) | BRPI0704975A (enExample) |
| CA (1) | CA2615148C (enExample) |
| DK (1) | DK1936017T3 (enExample) |
| ES (1) | ES2434019T3 (enExample) |
| IL (1) | IL188097A (enExample) |
| MX (1) | MX2007016424A (enExample) |
| RU (1) | RU2399702C2 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302862A (ja) * | 2001-04-06 | 2002-10-18 | Mitsui Chemicals Inc | 不織布の製造方法及び装置 |
| ATE524585T1 (de) * | 2007-07-25 | 2011-09-15 | Oerlikon Textile Components | Vorrichtung zur behandlung eines multifilen fadens |
| WO2009031868A2 (en) * | 2007-09-07 | 2009-03-12 | Kolon Industries, Inc. | Lyocell filament fiber and cellulose based tire cord |
| DK2128320T3 (da) * | 2008-05-29 | 2014-01-13 | Reifenhaeuser Gmbh & Co Kg | Fremgangsmåde og indretning til fremstilling af filterdug af filamenter |
| TWI385286B (zh) * | 2009-08-13 | 2013-02-11 | Taiwan Textile Res Inst | 製造不織布的設備 |
| WO2016173828A1 (de) * | 2015-04-25 | 2016-11-03 | Oerlikon Textile Gmbh & Co. Kg | Verfahren und vorrichtung zum schmelzspinnen und abkühlen von multifilen fäden |
| DE102016119866A1 (de) * | 2016-10-18 | 2018-04-19 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Verfahren und Anlage zur Erzeugung eines Vlieses aus Fasern |
| AT519489B1 (de) * | 2016-10-21 | 2021-11-15 | Chemiefaser Lenzing Ag | Verfahren und Vorrichtung zum Herstellen von Vliesen auf Cellulosebasis, die direkt aus Lyocell-Spinnlösung gebildet werden |
| EP3382080B1 (de) * | 2017-03-28 | 2019-08-07 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Verfahren und vorrichtung zur herstellung eines vlieses aus fasern |
| SI3382081T1 (sl) * | 2017-03-31 | 2020-01-31 | Reifenhaeuser Gmbh & Co. Kg Maschinenfabrik | Naprava za proizvodnjo tkanih polsti iz brezkončnih filamentov |
| EP3382082B1 (de) * | 2017-03-31 | 2019-08-07 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Vorrichtung zur herstellung von spinnvliesen aus endlosfilamenten |
| US11091861B2 (en) * | 2018-01-31 | 2021-08-17 | Fibertex Personal Care A/S | Spunbonded nonwoven with crimped fine fibers |
| DK3575468T3 (da) * | 2018-05-28 | 2020-11-02 | Reifenhaeuser Masch | Indretning og fremgangsmåde til fremstilling af filterduge af endeløse filamenter |
| ES2841727T3 (es) * | 2018-05-28 | 2021-07-09 | Reifenhaeuser Masch | Dispositivo de fabricación de velos de hilatura a base de filamentos continuos |
| TW202031950A (zh) * | 2018-12-05 | 2020-09-01 | 奧地利商蘭仁股份有限公司 | 在纖維素紡黏非織物的製造中回收再利用溶劑及纖維素的方法 |
| IT201900023235A1 (it) * | 2019-12-06 | 2021-06-06 | Ramina S R L | Impianto per la produzione di tessuto non tessuto |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168159A (zh) * | 1995-01-10 | 1997-12-17 | 考脱沃兹纤维(控股)有限公司 | 挤出制品的制造 |
| CN1441104A (zh) * | 2002-02-28 | 2003-09-10 | 赖芬豪泽机械工厂股份有限公司 | 连续制造无纺织物料幅的设备 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3959421A (en) * | 1974-04-17 | 1976-05-25 | Kimberly-Clark Corporation | Method for rapid quenching of melt blown fibers |
| US4141913A (en) * | 1978-01-23 | 1979-02-27 | American Carbonyl, Inc. | Method of generating lower alkyl and cycloalkyl isocyanates |
| US4318774A (en) * | 1980-05-01 | 1982-03-09 | Powell Corporation | Composite nonwoven web |
| AT402741B (de) * | 1995-10-13 | 1997-08-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer fasern |
| DE19620379C2 (de) * | 1996-05-21 | 1998-08-13 | Reifenhaeuser Masch | Anlage zur kontinuierlichen Herstellung einer Spinnvliesbahn |
| US6235392B1 (en) * | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
| GB9625634D0 (en) * | 1996-12-10 | 1997-01-29 | Courtaulds Fibres Holdings Ltd | Method of manufacture of nonwoven fabric |
| US6773648B2 (en) * | 1998-11-03 | 2004-08-10 | Weyerhaeuser Company | Meltblown process with mechanical attenuation |
| US20050048152A1 (en) * | 1999-06-24 | 2005-03-03 | Luder Gerking | Device for spinning materials forming threads |
| DE10023391A1 (de) * | 2000-05-12 | 2001-03-15 | Lurgi Zimmer Ag | Verfahren und Vorrichtung zur zugspannungsfreien Förderung von Endlosformkörpern |
| DE10025231A1 (de) * | 2000-05-22 | 2000-11-02 | Lurgi Zimmer Ag | Verfahren zum Extrudieren eines Endlosformkörpers |
| US7244497B2 (en) * | 2001-09-21 | 2007-07-17 | Outlast Technologies, Inc. | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
| GB2368342A (en) * | 2000-10-12 | 2002-05-01 | Tencel Ltd | Lyocell fibre and its production |
| US6607624B2 (en) * | 2000-11-20 | 2003-08-19 | 3M Innovative Properties Company | Fiber-forming process |
| DE10065859B4 (de) * | 2000-12-22 | 2006-08-24 | Gerking, Lüder, Dr.-Ing. | Verfahren und Vorrichtung zur Herstellung von im Wesentlichen endlosen feinen Fäden |
| JP4187532B2 (ja) * | 2001-03-26 | 2008-11-26 | マイクレックス コーポレーション | 不織布を用いるワイピング |
| JP2002302862A (ja) * | 2001-04-06 | 2002-10-18 | Mitsui Chemicals Inc | 不織布の製造方法及び装置 |
| EP1396567B2 (de) * | 2002-08-09 | 2011-04-20 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Verfahren zur Herstellung einer Spinnvliesbahn aus Bikomponenten-Filamenten |
| US20040110442A1 (en) * | 2002-08-30 | 2004-06-10 | Hannong Rhim | Stretchable nonwoven materials with controlled retraction force and methods of making same |
| US20090233075A1 (en) * | 2002-10-01 | 2009-09-17 | Freudenberg Nonwovens Limited Partnership | Flame Blocking Liner Materials |
| DE10314878A1 (de) * | 2003-04-01 | 2004-10-28 | Zimmer Ag | Verfahren und Vorrichtung zur Herstellung nachverstreckter Cellulose-Spinnfäden |
| US20050056956A1 (en) * | 2003-09-16 | 2005-03-17 | Biax Fiberfilm Corporation | Process for forming micro-fiber cellulosic nonwoven webs from a cellulose solution by melt blown technology and the products made thereby |
| US7459015B2 (en) * | 2004-04-16 | 2008-12-02 | Birla Research Institute For Applied Sciences | Process for the preparation of a cellulose solution for spinning of fibres, filaments or films therefrom |
| DE102004024029A1 (de) * | 2004-05-13 | 2005-12-08 | Zimmer Ag | Lyocell-Verfahren und -Vorrichtung mit Steuerung des Metallionen-Gehalts |
| ES2432014T3 (es) * | 2004-07-29 | 2013-11-29 | Suominen Corporation | Método para fabricar telas no tejidas particularmente blandas y tridimensionales y telas no tejidas obtenidas de este modo |
| US20060070008A1 (en) * | 2004-09-29 | 2006-03-30 | Microsoft Corporation | Preserving browser window integrity |
| US20080058748A1 (en) * | 2006-08-29 | 2008-03-06 | Seifert Kathy P | Disposable absorbent article having a graphic adapted to facilitate discretionary use of said article |
| US8277711B2 (en) * | 2007-03-29 | 2012-10-02 | E I Du Pont De Nemours And Company | Production of nanofibers by melt spinning |
| TWI337634B (en) * | 2007-12-27 | 2011-02-21 | Taiwan Textile Res Inst | Apparatus and method for manufacturing nonwoven fabric |
-
2006
- 2006-12-22 EP EP06026730.9A patent/EP1936017B1/de not_active Not-in-force
- 2006-12-22 DK DK06026730.9T patent/DK1936017T3/da active
- 2006-12-22 ES ES06026730T patent/ES2434019T3/es active Active
-
2007
- 2007-12-12 IL IL188097A patent/IL188097A/en not_active IP Right Cessation
- 2007-12-17 CA CA2615148A patent/CA2615148C/en not_active Expired - Fee Related
- 2007-12-18 AR ARP070105683A patent/AR064408A1/es active IP Right Grant
- 2007-12-19 MX MX2007016424A patent/MX2007016424A/es active IP Right Grant
- 2007-12-20 US US12/004,446 patent/US20090026647A1/en not_active Abandoned
- 2007-12-20 KR KR1020070134233A patent/KR100987743B1/ko not_active Expired - Fee Related
- 2007-12-20 JP JP2007328121A patent/JP5065873B2/ja not_active Expired - Fee Related
- 2007-12-21 CN CN2007103062635A patent/CN101235580B/zh not_active Expired - Fee Related
- 2007-12-21 RU RU2007147960/12A patent/RU2399702C2/ru not_active IP Right Cessation
- 2007-12-26 BR BRPI0704975-7A patent/BRPI0704975A/pt not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168159A (zh) * | 1995-01-10 | 1997-12-17 | 考脱沃兹纤维(控股)有限公司 | 挤出制品的制造 |
| CN1441104A (zh) * | 2002-02-28 | 2003-09-10 | 赖芬豪泽机械工厂股份有限公司 | 连续制造无纺织物料幅的设备 |
Non-Patent Citations (1)
| Title |
|---|
| MJ Hayhurst.SPUNDBOND CELLULOSE.《the 45th Dornbirn Man-Made Fibers Congress》.2006, * |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2007147960A (ru) | 2009-06-27 |
| ES2434019T3 (es) | 2013-12-13 |
| CA2615148C (en) | 2011-06-28 |
| JP5065873B2 (ja) | 2012-11-07 |
| IL188097A (en) | 2011-05-31 |
| IL188097A0 (en) | 2008-12-29 |
| DK1936017T3 (da) | 2013-11-04 |
| KR20080059055A (ko) | 2008-06-26 |
| EP1936017A1 (de) | 2008-06-25 |
| CA2615148A1 (en) | 2008-06-22 |
| RU2399702C2 (ru) | 2010-09-20 |
| MX2007016424A (es) | 2008-10-28 |
| AR064408A1 (es) | 2009-04-01 |
| KR100987743B1 (ko) | 2010-10-18 |
| CN101235580A (zh) | 2008-08-06 |
| JP2008163540A (ja) | 2008-07-17 |
| BRPI0704975A (pt) | 2008-08-12 |
| US20090026647A1 (en) | 2009-01-29 |
| EP1936017B1 (de) | 2013-08-21 |
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