CN101229110A - Inoxidability permanent natural black hair-dyeing and preparing method thereof - Google Patents

Inoxidability permanent natural black hair-dyeing and preparing method thereof Download PDF

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Publication number
CN101229110A
CN101229110A CNA2007101732825A CN200710173282A CN101229110A CN 101229110 A CN101229110 A CN 101229110A CN A2007101732825 A CNA2007101732825 A CN A2007101732825A CN 200710173282 A CN200710173282 A CN 200710173282A CN 101229110 A CN101229110 A CN 101229110A
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hair
dyeing
deionized water
dye
takes
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CNA2007101732825A
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CN100563627C (en
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周飞骏
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Shanghai Jiaotong University
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Shanghai Jiaotong University
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Abstract

The invention relates to a non-oxidative permanent type natural melanoid hair water and a preparation method thereof. The melanoid hair water is prepared with natural materials and is formed by No. 1 hair dye and No. 2 hair dye. The No. 1 hair dye takes clove as an osmotic agent, takes cysteine as a reducing agent, takes nutgall, myrobalan and gallnut as the paints and takes angelica as a nutrition component; the No. 2 hair dye takes copperas as a visualization reagent and leads the copperas to be aggregated with the dye component of the No. 1 hair dye into a black paint giant molecule. The invention, on the basis of the application of a traditional Chinese medicine osmotic agent, also applies a natural reducing agent of the cysteine to cut off a hair keratin disulfide and increase the hair fasciola clearances, to lead the traditional Chinese medicine paint molecule to be easier to enter the hair fasciola clearances and lead the melanoid hair to be blacker and firmer; while the hair dye is easy to wash when contacting the scurf and can be used only by heating for one time. The invention is easyto be accepted by more consumers.

Description

Inoxidability permanent natural black hair-dyeing and preparation method thereof
Technical field
The present invention relates to a kind of Inoxidability permanent natural black hair-dyeing and preparation method thereof, prepare a kind of natural hair-dyeing hair-blackening liquor that does not add any chemical pigment and hydrogen peroxide, belong to the cosmetics industry technical field.
Background technology
It is more and more that hair dyeing person worried the people of poisonous pair of effect of chemistry hair dyeing in recent years, and corresponding natural hair dyeing product is also favored by consumer more and more, and still, also there are many problems in natural in the market hair dyeing product.To really replace chemical hair dye, have got long long way to go.At present the domestic natural hair dyeing product that does not contain any chemical dye and hydrogen peroxide divides two big classes, and a class is according to reducing the natural hair dyeing product that principle develops, as publication number be CN120999ZA the Chinese patent introduction be the hair dye of dyestuff with the red sorghum pigment.This class hair dye divides three doses, and first dose is Reducing agent, and two sulfur are strong in the keratin of cut-out hair, and expansion hair hair small pieces lay the first stone for big natural dye molecule enters hair hair small pieces.Reducing agent uses cysteine mostly, the use hydroxyacetic acid that also has.Second dose is pigment agent, and the 3rd dose is developer, generally uses iron salt.This series products has three problems, one, the fastness standard that do not reach permanent type hair dyeing promptly have hair dyed the back keep 40-50 days colour-fast.Two, using inconvenience: need under the condition of heating, dye 3 three times. hair dye is run into skin, and skin is dry easily.
Other has a class is the natural prodcuts of developing according to penetration theory, and as Chinese invention patent ZL02136428.1 record is the non-oxidative permanent Chinese medicine hair-dyeing hair-blackening liquor of penetrating agent with the Flos Caryophylli.It is divided into two doses, and potion is a dying agent, and potion is a developer.Because it is big that the chemical relatively dye molecule of Chinese medicine molecular dye molecule is wanted, and is difficult for entering in the hair hair small pieces.This class hair dye is that penetrating agent makes the Chinese medicine dyestuff enter hair hair small pieces by the Chinese medicine Flos Caryophylli.The hair dyeing fastness Billy of this class hair dye is eager to excel with reduction principle hair dyeing fastness, reaches permanent type hair dyeing product level.Can keep after the hair dyeing 40 days-50 days colour-fast.Also convenient relatively during use, use secondary to use for three less important lacking once than the hair dye of utilization reduction principle manufacturing.
Though, natural hair dye by the penetration theory manufacturing has solved problem not hypersensitive, even the allergy sufferers of seriously having hair dyed is not owing to contain any chemical pigment in the prescription, do not contain hydrogen peroxide, need not to do skin test before the hair dyeing, can be not irritated, and can not cause chromosomal aberration, in general cell mutation does not exist potential carcinogenic danger.Also there are two problems but be to use, the one, hair dye is run into scalp and is difficult for washing off, and hair dyeing needs professional standards.The 2nd, the secondary of need heating.Although have more than 20,000 person-time to use this hair dye every year in Shanghai so far, because the problem of above-mentioned existence has objectively still influenced product promotion.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of Inoxidability permanent natural black hair-dyeing and preparation method thereof is provided, keeping on the non-oxide permanent hair dyeing fastness basis, making rinse run into scalp washes off easily, reduce and use the heating number of times, it is more convenient that product is used, and accepted by more consumers easily.
For realizing such purpose, in the technical solution of the present invention, hair-dyeing hair-blackening liquor adopts the natural material preparation, by No. 1 rinse and No. 2 supporting uses of rinse, No. 1 rinse is penetrating agent with the Flos Caryophylli, and cysteine is a Reducing agent, and Galla Chinensis, Fructus Chebulae, Galla Turcica (Galla Helepensis) are pigment, when being classified as nutritional labeling, it is formulated to add deionized water.No. 2 rinse is a developer with the Melanteritum, makes the dyestuff composition of itself and No. 1 rinse aggregate into the pigment macromole of black.
Particular content of the present invention is:
The component of No. 1 rinse and mass percent are:
Flos Caryophylli 2~6%, cysteine 3~7.5%, Galla Chinensis 3~10%, Fructus Chebulae 2~6%, Galla Turcica (Galla Helepensis) 1~4%, Radix Angelicae Sinensis 0.5~2%, antiseptic Kazon (cy-1) 0.0015%, antioxidant sodium sulfite 0.5%, all the other are deionized water.
The component of No. 2 rinses and mass percent are:
Melanteritum 0.3~1%, antiseptic Kazon (cy-1) 0.0015%, all the other are deionized water.
No. 1, No. 2 rinses of the present invention are independent respectively formulated, and concrete preparation method is as follows:
No. 1 rinse:
Chinese herbal medicine Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Galla Turcica (Galla Helepensis), Radix Angelicae Sinensis are mixed, add deionized water, stir and heat, kept filter and remove residue 24 hours to 45~60 ℃ with the Chinese herbal medicine submergence.In filtrate, add cysteine, antiseptic cy-1, antioxidant sodium sulfite then, add deionized water to 100% while stirring, be cooled to room temperature, check, packing.
No. 2 rinses:
Melanteritum, antiseptic Kazon cy-1 are mixed, add deionized water to 100% again, heat while stirring, kept 20~30 minutes, be cooled to room temperature, check, packing then to 40 ℃.
Hair-dyeing hair-blackening liquor using method of the present invention is:
No. 1 rinse of use was heated ten minutes for 38 ℃ earlier, dashed gently with low amounts of water then to get final product.No. two rinses of repaste, need not to heat this moment again, kept ten minutes, and the flush away loose colour gets final product.
The present invention has changed invention formerly and has used the Chinese medicine penetrating agent relatively large Chinese medicine dye molecule to be thrown into the thinking of hair hair small pieces, on utilization Chinese medicine penetrating agent basis, cut off the strong hair hair small pieces gap of strengthening of hair keratin two sulfur in conjunction with utilization natural reducing agent cysteine again, make the Chinese medicine pigment molecule can enter hair hair small pieces gap easilier, make institute's dyeing hair more black, more firm.
Compare with existing patent of invention (ZL02136428.1) product, hair-dyeing hair-blackening liquor of the present invention is keeping on the non-oxide permanent hair dyeing fastness basis, obtained three new development: 1, the rinse of former invention, to run into scalp and be difficult for washing off, present rinse is run into scalp and can be washed off.2, the rinse of the former invention secondary of need heating.Now only need heat once.Because these two progress, consumer can have hair dyed in the own home, need not rely on the professional of barber shop, uses more convenient, easily by the acceptance of more consumers.3, the rinse of former invention institute dyeing hair color and luster is a blue-black, and the rinse institute dyeing hair of existing invention is that nature is black, liked by consumer.
The specific embodiment
Below by specific embodiment technical scheme of the present invention is further described.Following examples do not constitute limitation of the invention.
Embodiment 1
The component of No. 1 rinse and mass percent are:
Flos Caryophylli 6%, cysteine 3%, Galla Chinensis 10%, Fructus Chebulae 3%, Galla Turcica (Galla Helepensis) 1%, Radix Angelicae Sinensis 2%, antiseptic Kazon (cy-1) 0.0015%, antioxidant sodium sulfite 0.5%, all the other are deionized water.
The component of No. 2 rinses and mass percent are:
Melanteritum 0.3%, antiseptic Kazon (cy-1) 0.0015% adds deionized water to 100%.
Embodiment 2
The component of No. 1 rinse and mass percent are:
Flos Caryophylli 4%, cysteine 5%, Galla Chinensis 8%, Fructus Chebulae 4%, Galla Turcica (Galla Helepensis) 2%, Radix Angelicae Sinensis 1.5%, antiseptic Kazon (cy-1) 0.0015%, antioxidant sodium sulfite 0.5%, all the other are deionized water.
The component of No. 2 rinses and mass percent are:
Melanteritum 0.6%, antiseptic Kazon (cy-1) 0.0015% adds deionized water to 100%.
Embodiment 3
The component of No. 1 rinse and mass percent are:
Flos Caryophylli 3%, cysteine 7%, Galla Chinensis 6%, Fructus Chebulae 5%, Galla Turcica (Galla Helepensis) 3%, Radix Angelicae Sinensis 2%, antiseptic Kazon (cy-1) 0.0015%, antioxidant sodium sulfite 0.5%, all the other are deionized water.
The component of No. 2 rinses and mass percent are:
Melanteritum 0.8%, antiseptic Kazon (cy-1) 0.0015% adds deionized water to 100%.
No. 1, No. 2 rinses among the above embodiment are independent respectively formulated.
For No. 1 rinse, Chinese herbal medicine Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Galla Turcica (Galla Helepensis), Radix Angelicae Sinensis are mixed, add deionized water with the Chinese herbal medicine submergence, stir and heat to 45~60 ℃, kept filter and remove residue 24 hours.Add cysteine, antiseptic cy-1, antioxidant sodium sulfite then in filtrate, add deionized water to 100% while stirring, be cooled to room temperature, check, packing get final product.
For No. 2 rinses, Melanteritum, antiseptic Kazon cy-1 are mixed, add deionized water to 100% again, heat while stirring to 40 ℃, kept 20~30 minutes, be cooled to room temperature, check, packing then and get final product.
During use, No. 1 rinse of use was heated ten minutes for 38 ℃ earlier, dashed gently with low amounts of water then to get final product.No. two rinses of repaste, need not to heat this moment again, kept ten minutes, and the flush away loose colour gets final product.
Hair-dyeing hair-blackening liquor of the present invention can keep 40~50 days colour-fast, be not stained with skin, not irritated.Try exhausted client and generally reflect better than existing rinse hair dyeing effect, color and luster is more true to nature.Owing to be not stained with skin, consumer can buy back in the own home has hair dyed, and need not rely on the professional of barber shop, makes natural hair dyeing product of the present invention more hold easy for consumers to accept simultaneously.

Claims (2)

1. an Inoxidability permanent natural black hair-dyeing is made up of No. 1 rinse and No. 2 rinses, it is characterized in that the component of described No. 1 rinse and mass percent are: Flos Caryophylli 2~6%; Cysteine 3~7.5%; Galla Chinensis 3~10%; Fructus Chebulae 2~6%; Galla Turcica (Galla Helepensis) 1~4%; Radix Angelicae Sinensis 0.5~2%; Antiseptic Kazon cy-1 0.0015%, antioxidant sodium sulfite 0.5%, all the other are deionized water; The component of No. 2 rinses and mass percent are: Melanteritum 0.3~1%, and antiseptic Kazon cy-10.0015%, all the other are deionized water.
2. the preparation method of the Inoxidability permanent natural black hair-dyeing of a claim 1, when it is characterized in that preparing No. 1 rinse, Chinese herbal medicine Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Galla Turcica (Galla Helepensis), Radix Angelicae Sinensis are mixed, add deionized water with the Chinese herbal medicine submergence, stir and heat, kept 24 hours to 45~60 ℃, filter and remove residue, in filtrate, add cysteine, antiseptic Kazon cy-1, antioxidant sodium sulfite then, add deionized water to 100% while stirring, cooling back test package; When preparing No. 2 rinses, Melanteritum, antiseptic Kazon cy-1 are mixed, add deionized water to 100% again, heat while stirring, kept 20~30 minutes, cooling back test package to 40 ℃.
CNB2007101732825A 2007-12-27 2007-12-27 Inoxidability permanent natural black hair-dyeing and preparation method thereof Expired - Fee Related CN100563627C (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102144959A (en) * 2011-04-19 2011-08-10 广州好迪集团有限公司 Bath foam with nourishing and moisturizing functions
CN102258444A (en) * 2010-05-27 2011-11-30 喻昕 Non-toxic hair-dyeing paste made of natural medicines
CN102379837A (en) * 2011-11-04 2012-03-21 广州绿蒎生物科技有限公司 Non-allergic plant hair dye without para-phenylene diamine and hydrogen peroxide
CN102481461A (en) * 2009-08-21 2012-05-30 荷兰联合利华有限公司 Hair treatment composition
CN101642418B (en) * 2008-08-05 2012-08-08 沈立 Group of Chinese medicament hair dye
CN105326771A (en) * 2015-12-07 2016-02-17 吴文玉 Healthy and safe traditional Chinese medicine hair colorant
CN105326772A (en) * 2015-12-07 2016-02-17 吴文玉 Traditional Chinese medicine hair dye with more lasting dyeing effect
CN106265333A (en) * 2016-09-11 2017-01-04 桂林理工大学 A kind of Chinese medicament hair dye and preparation and application thereof
CN108158940A (en) * 2018-02-23 2018-06-15 广州市骄子日化有限公司 A kind of natural botanical hair dye and preparation method thereof
CN110731940A (en) * 2019-11-21 2020-01-31 南通大学 Preparation method of traditional Chinese medicine hair dye black hair agent added with natural transdermal absorption penetration enhancer as dyeing penetration agent
CN111529437A (en) * 2020-01-19 2020-08-14 浙江天一堂医药管理有限公司 Pure traditional Chinese medicine natural hair blackening cream and application method thereof
CN112515983A (en) * 2019-09-17 2021-03-19 澳集商贸(荆门)有限公司 Traditional Chinese medicine hair dyeing agent and using method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101642418B (en) * 2008-08-05 2012-08-08 沈立 Group of Chinese medicament hair dye
CN102481461A (en) * 2009-08-21 2012-05-30 荷兰联合利华有限公司 Hair treatment composition
CN102258444A (en) * 2010-05-27 2011-11-30 喻昕 Non-toxic hair-dyeing paste made of natural medicines
CN102144959A (en) * 2011-04-19 2011-08-10 广州好迪集团有限公司 Bath foam with nourishing and moisturizing functions
CN102144959B (en) * 2011-04-19 2012-07-04 广州好迪集团有限公司 Bath foam with nourishing and moisturizing functions
CN102379837A (en) * 2011-11-04 2012-03-21 广州绿蒎生物科技有限公司 Non-allergic plant hair dye without para-phenylene diamine and hydrogen peroxide
CN105326771A (en) * 2015-12-07 2016-02-17 吴文玉 Healthy and safe traditional Chinese medicine hair colorant
CN105326772A (en) * 2015-12-07 2016-02-17 吴文玉 Traditional Chinese medicine hair dye with more lasting dyeing effect
CN106265333A (en) * 2016-09-11 2017-01-04 桂林理工大学 A kind of Chinese medicament hair dye and preparation and application thereof
CN108158940A (en) * 2018-02-23 2018-06-15 广州市骄子日化有限公司 A kind of natural botanical hair dye and preparation method thereof
CN112515983A (en) * 2019-09-17 2021-03-19 澳集商贸(荆门)有限公司 Traditional Chinese medicine hair dyeing agent and using method thereof
CN112515983B (en) * 2019-09-17 2024-02-23 澳集商贸(荆门)有限公司 Traditional Chinese medicine hair-blackening agent and application method thereof
CN110731940A (en) * 2019-11-21 2020-01-31 南通大学 Preparation method of traditional Chinese medicine hair dye black hair agent added with natural transdermal absorption penetration enhancer as dyeing penetration agent
CN111529437A (en) * 2020-01-19 2020-08-14 浙江天一堂医药管理有限公司 Pure traditional Chinese medicine natural hair blackening cream and application method thereof
CN111529437B (en) * 2020-01-19 2022-09-13 浙江天一堂医药管理有限公司 Pure traditional Chinese medicine natural hair blackening cream and application method thereof

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