CN101205063A - Activated char activating furnace and technique for producing activated char by employing the same - Google Patents
Activated char activating furnace and technique for producing activated char by employing the same Download PDFInfo
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- CN101205063A CN101205063A CNA2007101396824A CN200710139682A CN101205063A CN 101205063 A CN101205063 A CN 101205063A CN A2007101396824 A CNA2007101396824 A CN A2007101396824A CN 200710139682 A CN200710139682 A CN 200710139682A CN 101205063 A CN101205063 A CN 101205063A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention discloses an activating furnace for activated carbon and a technique thereof for utilizing the furnace to produce the activated carbon. A preheating combustion chamber is arranged on one end of the activating furnace body; a flue gas secondary combustion chamber, a boiler and a chimney are arranged on the other end of the activating furnace body. A carbonization section, an activation section and a discharging mouth are arranged in sequence under a feeding trough. The carbonization section and the activation section consist of a flow gate and a flue respectively; wherein, the flow gate is interconnected; a flue gas via hole is arranged on wall of the flue of the carbonization section; the flue and the flow gate are interconnected; the activation section is made of refractory brick; arrays of the flue and the flow gate are formed; top and bottom of the activation section as well as a barrier between two layers of the flue are made of the refractory brick with via holes that a steam passage is formed. The furnace has reasonable structure, energy-saving, environment protection, high producing efficiency and steady product quality; furthermore, heat source in the process of producing the activated carbon is not supplied by coal and electricity, which greatly reduces emission of the flue gas.
Description
Technical field
The present invention relates to a kind of Activated Carbon Production equipment, particularly relate to a kind of absorbent charcoal activation furnace and utilize this stove to produce the processing method of gac
Background technology
Gac is the important materials of multiple industry and environmental protection industry (epi), and market demand grows with each passing day, and particularly shell class gac is more well sold and in short supply.The main process of producing shell class gac is that raw material is carried out charing and activation at a certain temperature, makes it reach the regulation physical and chemical index.At present, mostly activation furnace is to be built into by refractory materials, its structure comprises charging opening, the charing section, activation section, discharge port and steam plenum system and flue system, the method of used heating generally has two kinds: the one, and coal, the one,, with coal as heating material, gac per ton need consume 1.2 tons in coal, and a large amount of fume emissions are arranged, and to the severe contamination that periphery causes, electricity consumption is as heater means, except that current consumption greatly, because furnace binding is unreasonable, fruit stone discharges a large amount of smog in combustion processes, and environmental pollution is more serious, several activation furnaces commonly used now, as the smoldering stove, Si Liepu ature of coal activation furnace and 288 type activation furnaces etc. all are high energy consumptions, seriously polluted, investment is big, the product cost height, the baroque type of furnace.Wherein, seriously polluted problem is the main contents that local government requires rectification.For this reason, with serious pollution problem is the main task that manufacturing enterprise faces in the solution Activated Carbon Production process, does not also find to have the disclosed related data of this respect at present both at home and abroad.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of absorbent charcoal activation furnace is provided and utilizes this stove to produce the processing method of gac, technical problem to be solved is by improving charing section in the body of heater, the structure of activation section and steam plenum system and flue structure, make in the gac normal productive process without coal, electricity provides thermal source, carry out charing and activation by the fruit stone spontaneous combustion, sufficient combustion, reduce the discharging of flue gas greatly, improve the quality of products, this furnace structure is reasonable, energy-conservation, environmental protection, the production efficiency height, constant product quality, the technical solution used in the present invention is as follows: the present invention is by body of heater, intake chute, the charing section, activation section, flue, the steam plenum system, discharge port is formed, one end of body of heater is the preheated burning chamber, the other end is the flue gas secondary combustion chamber, boiler and chimney, intake chute is positioned at the body of heater top, the intake chute bottom is provided with the opening for feed of some amount, be the charing section successively under the intake chute, activation section, discharge port, charing section and activation section all are made up of material road and flue, its material road communicates, form material road from top to bottom, the top is facing to opening for feed, the below is facing to discharge port, the flue of charing section and the flue of activation section are separated up and down, it is characterized in that charing section flue wall is provided with equally distributed smoke ventilator, flue is communicated with the material road, the one end sealing of charing section flue, the other end communicates with the preheated burning chamber by the hole on the furnace body wall respectively, activation section is formed by several heterotypic fire bricks system of building, form number smoke-uptake and material road, wherein expect it is autonomous channel one by one, and communicate with charing section material road, quantity is consistent with opening for feed and discharge port, top and feeding inlet, the below communicates with discharge port, flue then is positioned at material both sides, road, every smoke-uptake has several layers from top to bottom, one end of the first layer flue communicates with the preheated burning chamber, the other end communicates with the lower floor flue, so be recycled to orlop one flue, the basecoat flue then communicates with secondary combustion chamber, interlayer between the top of activation section first smoke-uptake and bottom and the two-layer flue is built into the refractory brick that has through hole, form several vapour passages from top to bottom, one end shutoff of passage, the other end communicates with steam boiler with pipeline, the refractory brick of every band through hole is equipped with a pore, this pore communicates with activation section material road, interlayer between the top of second smoke-uptake and bottom and the two-layer flue is built into solid refractory brick, interlayer between the top of the 3rd smoke-uptake and bottom and the two-layer flue also is built into the refractory brick that has through hole, form several vapour passages from top to bottom, one end shutoff of passage, the other end links to each other with boiler with pipeline, the refractory brick of every band through hole is equipped with a pore, and this pore communicates with activation section material road.
The present invention can also be built into the top of above-mentioned activation section first smoke-uptake and the 3rd smoke-uptake and the interlayer between bottom and the two-layer flue with solid refractory brick, and the interlayer between the top of second smoke-uptake and bottom and the two-layer flue is built into the refractory brick that has through hole, form several vapour passages from top to bottom, one end shutoff of passage, the other end links to each other with boiler with pipeline, the refractory brick of every band through hole is equipped with two pores, and pore communicates with the activation section material road on both sides respectively.
The used refractory brick that has through hole of interlayer between the top of above-mentioned second smoke-uptake and bottom and the two-layer flue is the single-pass pore structure, make every layer of interlayer form a vapour passage, the refractory brick of every band through hole is equipped with two pores, and pore communicates with the activation section material road on both sides respectively.
The used refractory brick doubled via structure that has through hole of interlayer between the top of above-mentioned second smoke-uptake and bottom and the two-layer flue, make every layer of interlayer form two independently vapour passages, the refractory brick of every band through hole is equipped with two pores, two pores communicate with two through holes respectively, and vapour passage is communicated with the activation section material road on both sides.
Utilize the processing method of above-mentioned activation furnace production gac as follows:
One, raw material is prepared
Selecting for use moisture content to be lower than 15% various shell skins is raw material, and screening, removal of impurities;
Two, pre-heat drying furnace when furnace temperature is raised to 600 ℃, is closed discharge port, material is sent to each fire door of stove, and when activation section middle part temperature surpassed 700 ℃, observing in the stove activation section combustion chamber had 2/3 to be burnt when red, begin to feed in raw material, charing section and activation section raw material are filled it up with till;
Three, charing, carbonization temperature are 400-700 ℃;
Four, activation, activation temperature is 700-1100 ℃;
Five, every blanking in 30-80 minute once, make the product after the activation enter cooling section, discharging after cooling off according to different material and quality product.
Compare with other type of furnace and production technique, the present invention has following advantage: (one), energy-conservation: existing one ton of gac of common activation furnace production is generally used 1.2 tons in coal, during ordinary production of the present invention, do not need coal, electricity that thermal source is provided, the heat that produces when utilizing the body of heater charing provides thermal source, the heat that production process produces is produced the needs except that satisfying, and can also utilize 50% remaining heat energy to carry out heat supply or bathing; (2), environmental protection: in process of production, with the naked eye can't see any flue dust, realize non-pollution discharge, meet national regulation fully; (3), cost is low: produce one ton of gac that iodine number is 1100-1200mg/g, 6.4 tons of required shell raw materials are produced stove than the conventional physical reactivity and (are comprised smouldering furnace, Stepple furnace, the rake stove) 20%-30% that can economize in raw materials reduces cost of labor and reaches 70%, and labor strength significantly descends; (4), product performance height: produce gac with the present invention and can reach following main products capability and performance: (1) Yamamoto Methylene Blue ZF 90-120ml/g; (2) iodine number 1100-1200mg/g; (3) apparent density 0.38-0.45mg/ml
3(4) intensity＞95%; (5), other performance: adsorptive power of (1) gac and sweetening power improve 20%-30%; (2) activated carbon product even aperture distribution; (3) physical strength height, prolong work-ing life; (4) the activated carbon product yield improves 20%-30%.
Description of drawings
Accompanying drawing 1 is a front view of the present invention
Accompanying drawing 2 is vertical views of the present invention
Accompanying drawing 3 is left views of the present invention
Accompanying drawing 4 is activation section structure enlarged views of the present invention
Accompanying drawing 5 is single-pass hole firebrick structure figure
Specific embodiments
Activation furnace of the present invention is by body of heater 5, intake chute 10, charing section 5, activation section 6, flue, the steam plenum system, discharge port 1 is formed, one end of body of heater is preheated burning chamber 2, the other end is a flue gas secondary combustion chamber 13, boiler 14 and chimney 15, intake chute is positioned at the body of heater top, the intake chute bottom is provided with four row's opening for feeds 9, seven of every rows, totally two ten eight, be the charing section successively under the intake chute, activation section, discharge port, charing section and activation section all are made up of material road and flue, its material road communicates, form material road from top to bottom, the top is facing to opening for feed, the below is facing to discharge port, the flue 17 of charing section is separated up and down with the flue 4 of activation section, be provided with five flues in the charing section, its flue wall 18 is provided with equally distributed smoke ventilator 11, flue is communicated with the material road, the one end sealing of charing section flue, the other end communicates with the preheated burning chamber by the hole on the furnace body wall 19 respectively, activation section is formed by several heterotypic fire bricks system of building, the centre is separated by partition wall 20, form six smoke-uptakes and four billot roads, wherein expect to form autonomous channel 23 one by one, and communicate with charing section material road, quantity is consistent with opening for feed and discharge port, it all is 28, material road and the feeding inlet of top in the charing section, the below communicates with discharge port, flue then is positioned at material both sides, road, every smoke-uptake has five layers from top to bottom, one end of the first layer flue 4 communicates with preheated burning chamber 2 by hole 3, the other end communicates with the lower floor flue, so be recycled to orlop one flue, the basecoat flue then communicates with secondary combustion chamber 13 by hole 16, interlayer between the top of activation section first smoke-uptake and bottom and the two-layer flue is built into the refractory brick 6 that has through hole, form a steam channel 7, one end shutoff of passage, the other end links to each other with steam boiler with pipeline 12, be equipped with tensimeter on every pipeline, the refractory brick of every band through hole is equipped with a pore 8, this pore communicates with activation section material road, second smoke-uptake then adopts solid refractory brick 22, the 3rd smoke-uptake is the same with first row, and the like.
The present invention can also be built into the top of above-mentioned activation section first smoke-uptake and the 3rd smoke-uptake and the interlayer between bottom and the two-layer flue with solid refractory brick, and the interlayer between the top of second smoke-uptake and bottom and the two-layer flue is built into the refractory brick that has through hole, form several vapour passages from top to bottom, one end shutoff of passage, the other end links to each other with boiler with pipeline, the refractory brick of every band through hole is equipped with two pores, and pore communicates with the activation section material road on both sides respectively.
Interlayer between the top of above-mentioned second smoke-uptake and bottom and two-layer flue single-pass pore structure refractory brick 24, make every layer of interlayer form a vapour passage, the refractory brick of every band through hole is equipped with two pores, and pore communicates with the activation section material road on both sides respectively.
Interlayer between the top of above-mentioned second smoke-uptake and bottom and two-layer flue doubled via structure fire resistance brick 25, make every layer of interlayer form two independently vapour passages, the refractory brick of every band through hole is equipped with two pores, pore communicates with two through holes respectively, and vapour passage is communicated with the activation section material road on both sides.Complete processing operating process of the present invention is as follows:
One, raw material is prepared
Generally being lower than 15% various shell skins with moisture content is raw material, through screening, removal of impurities fed to boiler, the first step preheating, the second step charing, the activation of the 3rd step, feed water vapour after, come out of the stove by production quality product the requirements different time of employing.
Two, charing working specification:
Want the scrutiny equipment components before the start, guarantee that crane is in normal service condition, guarantee raw material abundance in the intake chute, check the vision slit (seeing the position of normal temps in the stove) at each position, check the gentle pressure of feedwater, guarantee boiler water yield abundance, guarantee the used quantity of steam of boiler.
Three, activation act rules:
This stove is a kind of novel furnace, is the novel vertical type stove of collection charing, activation integral, adopts raw materials for production directly into stove, provides thermal source and power without coal, electricity etc. during ordinary production, is smokeless environment-friendly type stove.But the burning fume that the charing stage produces enters activation section and burns, and makes the temperature of activation section in the stove reach 900-1100 ℃, promotes that the charing raw material fully activates in the activation section.Utilize the waste heat of stove itself that steam boiler is heated up simultaneously, the activated media (water vapour) that steam boiler produces returns activation section activation pore-creating in the stove, improves the activated carbon product quality.The compound combustible gases such as carbon monoxide that activation stage produces enter and carry out secondary after flue and the combination with oxygen and fully burn, and have thoroughly solved the traditional burner problem not up to standard of discharging fume.
Furnace structure: stove physical dimension (length * wide * height) is about 935 * 328 * 698mm, being respectively quarl, common refractory brick and ordinary red brick from inside to outside is built into, be with the fastening body of heater of joist steel and channel-section steel outward, stove divides from function: mainly contain six parts such as preheating section, charing section, activation section, heat accumulation chamber, combustion chamber, quirk and form.
Activated bath: be the position of carrying out charing, priming reaction in the Activated Carbon Production process, have 28 in the stove by the brick activated bath that becomes of quarl and king's word, four is one group, clean long 0.58 * 0.08 * 245mm of each activated bath * 4, the activated bath end opening is communicated with dump box, and dump box has twice plate up and down, manufactures with steel plate, at the bottom of activated bath and the position, upper end of dump box, be provided with the superheated vapour import.
Combustion chamber and quirk system: the combustion chamber is at the body of heater opposite side, in be built into refractory brick, external application common brick, 80 * 210mm cigarette duct of combustion chamber, every flue divides the upper, middle and lower composition, in the stove in two sub-sections, upper flue divides five flue groups, enters the combustion chamber respectively, flue from combustion chamber branch twice cigarette enters, from top to down, enter down the combustion chamber one, flue gas enters boiler and fully burns and make vapour from the combustion chamber, enters in the high chimney that is built into ordinary red brick more than 25 meters again.
Charing, activated gas system: in charing, reactivation process, produce a large amount of mixed gass based on hydrogen, carbon monoxide, carbonic acid gas etc., by entering horizontal flue, quirk in the activated bath slit, in flue and quirk, burn required temperature when guaranteeing charing, activation.
The steam steam-supplying system: pressure is 176.56-294.2 K
p2 water vapour is heated to through steam boiler and produces the activated media high-temperature vapor about 200-500 ℃, high-temperature vapor enters in the activated bath by 28 overheated steam pipes in the quirk again, can with the raw material adverse current, also can following current add, promote the carrying out of priming reaction.
Material flow: the blanking pond of raw material being mentioned furnace roof by chain bucket, through preheating, drying (300-400 ℃), enter charing section (400-700 ℃), activation section (700-1100 ℃) again, (30-80 minute) blanking once at regular intervals according to different material and quality product.Product after the activation can carry out processing treatment through technologies such as aftertreatments again to cooling section (1100-200 ℃) product discharging after cooling off.
Specific operation process:
A, start-up of the furnace and rules:
Baker operation and rules: baker is to keep charing, activation furnace normally to move, and increases the service life and important measures, newly builds after stove and the blowing out blow-on again and all will carry out baker, and is particularly important with the baker of new block stove.Will unscrew the screw of all fastening bodies of heater before the baker, the flange of various pipelines is laid down, and furnace roof cover plate (opening for feed) discharge opening and inspection port is all opened, to guarantee that the intravital moisture of stove is discharged smoothly.For stove is damaged, when heating stove, requirement to slowly heat, and strict (heating curve is according to the physico-chemical property of refractory materials and the coefficient of expansion, furnace binding and gross weight by heating curve, determine the temperature measurement location of baker, factors such as block stove seasoning time are formulated) heat up.Will prevent in the baker process that furnace temperature from descending, baker begins with little fiery baker, treat that furnace temperature rises to a certain degree after, add big fire and heat up.
Loading operation and rules: when furnace temperature is raised to 600 ℃, close discharge port, reinforced each fire door that is sent to stove, temperature is above 700 ℃ in the middle part of activation section, and the activation section combustion chamber has 2/3 to be burnt when red in the observation stove, begins to feed in raw material, till charing section and activation section raw material are filled it up with.It is fast that when filling with substance is wanted, and will be rapidly heated after feeding in raw material, red when the raw material burning, can feed a small amount of water vapor, along with the rising of temperature is filled it up with raw material gradually, when activation temperature reaches more than 900 degree, changes normal running over to.At this moment, stop using the combustion chamber, add sealing immediately behind the fuel, the gas in the activation section by the chimney nature draft send into the quirk internal combustion, the activation certain hour is determined the discharging time for the first time according to temperature, off quality returning reactivates.
Discharging operation and rules: the discharging personnel will open upper flashboard earlier according to quality product blanking on time during discharging, charcoal is discharged on the lower flashboard, turn off upper flashboard then, open lower flashboard again.To in time turn off lower flashboard after unloading charcoal, should feed in raw material immediately after the discharging, check boiler water level, water vapour pressure etc.
B. normal running and rules:
Activation temperature should strict be regulated and control by processing requirement, in order to make the activation furnace temperature remain on certain limit, should adjust each air intlet and steam valve according to the furnace temperature situation, empirical evidence: the temperature of overheated steam has remarkably influenced to the adsorptive power of gac, the temperature of activator is high more, the adsorptive power of gac is high more, therefore wishes that the temperature of water vapour is high more good more.But the water vapor temperature of superheat often is subjected to the restriction of steam superheating sealing material.
Soak time: determine to unload the charcoal time according to the difference of product absorption property, it is 30-80 minute that each activated bath is adorned charcoal pitch time at every turn.
Claims (5)
1. environmental protection, energy-conservation, efficient activation oven for active fruit shell carbon, by body of heater, intake chute, the charing section, activation section, flue, the steam plenum system, discharge port is formed, one end of body of heater is the preheated burning chamber, the other end is the flue gas secondary combustion chamber, boiler and chimney, it is characterized in that intake chute is positioned at the body of heater top, the intake chute bottom is provided with the opening for feed of some amount, be the charing section successively under the intake chute, activation section, discharge port, charing section and activation section all are made up of material road and flue, its material road communicates, form material road from top to bottom, the top is facing to opening for feed, the below is facing to discharge port, the flue of charing section and the flue of activation section are separated up and down, charing section flue wall is provided with equally distributed smoke ventilator, flue is communicated with the material road, the one end sealing of charing section flue, the other end communicates with the preheated burning chamber by the hole on the furnace body wall respectively, activation section is formed by several heterotypic fire bricks system of building, form number smoke-uptake and material road, wherein expect it is autonomous channel one by one, and communicate with charing section material road, quantity is consistent with opening for feed and discharge port, top and feeding inlet, the below communicates with discharge port, flue then is positioned at material both sides, road, every smoke-uptake has several layers from top to bottom, one end of the first layer flue communicates with the preheated burning chamber, the other end communicates with the lower floor flue, so be recycled to orlop one flue, the basecoat flue then communicates with secondary combustion chamber, interlayer between the top of activation section first smoke-uptake and bottom and the two-layer flue is built into the refractory brick that has through hole, form a vapour passage, one end shutoff of passage, the other end links to each other with boiler with pipeline, the refractory brick of every band through hole is equipped with a pore, and this pore communicates with activation section material road, and second smoke-uptake then adopts solid refractory brick, the 3rd smoke-uptake is the same with first row, and the like.
2. a kind of environmental protection according to claim 1, energy-conservation, efficient activation oven for active fruit shell carbon, it is characterized in that the top of activation section first smoke-uptake and the 3rd smoke-uptake and the interlayer between bottom and the two-layer flue are built into solid refractory brick, interlayer between the top of second smoke-uptake and bottom and the two-layer flue is built into the refractory brick that has through hole, form several vapour passages from top to bottom, one end shutoff of passage, the other end links to each other with boiler with pipeline, the refractory brick of every band through hole is equipped with pore, and pore communicates with the activation section material road on both sides respectively.
3. a kind of environmental protection according to claim 1, energy-conservation, efficient activation oven for active fruit shell carbon, the top and the single-pass pore structure refractory brick (23) of the interlayer between bottom and the two-layer flue that it is characterized in that above-mentioned second smoke-uptake, make every layer of interlayer form a vapour passage, the refractory brick of every band through hole is equipped with two pores, and pore communicates with the activation section material road on both sides respectively.
4. a kind of environmental protection according to claim 1, energy-conservation, efficient activation oven for active fruit shell carbon, the top and the doubled via structure fire resistance brick (24) of the interlayer between bottom and the two-layer flue that it is characterized in that above-mentioned second smoke-uptake, make every layer of interlayer form two independently vapour passages, the refractory brick of every band through hole is equipped with two pores, pore communicates with two through holes respectively, and vapour passage is communicated with the activation section material road on both sides.
5. processing method of utilizing above-mentioned activation furnace to produce gac is characterized in that:
One, raw material is prepared
Selecting for use moisture content to be lower than 15% various shell skins is raw material, and screening, removal of impurities;
Two, pre-heat drying furnace when furnace temperature is raised to 600 ℃, is closed discharge port, material is sent to each fire door of stove, and when activation section middle part temperature surpassed 700 ℃, observing in the stove activation section combustion chamber had 2/3 to be burnt when red, begin to feed in raw material, charing section and activation section raw material are filled it up with till;
Three, charing, carbonization temperature are 400-700 ℃;
Four, activation, activation temperature is 700-1100 ℃;
Five, every blanking in 30-80 minute once, make the product after the activation enter cooling section, discharging after cooling off according to different material and quality product.
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| CNA2007101396824A CN101205063A (en) | 2007-11-01 | 2007-11-01 | Activated char activating furnace and technique for producing activated char by employing the same |
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| CNA2007101396824A CN101205063A (en) | 2007-11-01 | 2007-11-01 | Activated char activating furnace and technique for producing activated char by employing the same |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101639319B (en) * | 2009-05-04 | 2011-04-13 | 李观德 | Construction method of charcoal kiln and matrix tunnel type charcoal kiln |
| CN102249226A (en) * | 2011-06-13 | 2011-11-23 | 福建省龙岩龙能粉煤灰综合利用有限公司 | Zero-discharge and self-heating charring process for activated carbon preparation |
| CN102249225A (en) * | 2011-06-13 | 2011-11-23 | 福建省龙岩龙能粉煤灰综合利用有限公司 | System using biomass for heat supply for producing activated carbon by fly ash |
| CN102259854A (en) * | 2011-06-22 | 2011-11-30 | 李保东 | Steam-free operation device for activation furnace |
| CN102515159A (en) * | 2011-12-30 | 2012-06-27 | 承德绿世界活性炭有限公司 | Improved shell charcoal activation furnace |
| CN102642831A (en) * | 2012-04-23 | 2012-08-22 | 张鹏远 | Integrated stove |
| CN101993206B (en) * | 2009-08-25 | 2012-09-05 | 穆宝文 | Hot smoke indirect calcining continuous production lime furnace |
| CN104773733A (en) * | 2015-05-06 | 2015-07-15 | 福建鸿宇安生物科技有限公司 | Activated carbon boiler |
| CN105883784A (en) * | 2016-04-06 | 2016-08-24 | 东莞市凯金新能源科技股份有限公司 | Artificial graphite precursor hot kettle feeding method |
| CN108249436A (en) * | 2018-03-20 | 2018-07-06 | 浙江省林业科学研究院 | A kind of method and its vertical activation furnace with steam activation preparing active carbon |
| CN112299413A (en) * | 2019-08-02 | 2021-02-02 | 中冶长天国际工程有限责任公司 | Rotary activation furnace and activated carbon production system with same |
| WO2024148768A1 (en) * | 2023-01-13 | 2024-07-18 | 西安热工研究院有限公司 | Special-shaped brick and coke making furnace comprising same, system, and method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101639319B (en) * | 2009-05-04 | 2011-04-13 | 李观德 | Construction method of charcoal kiln and matrix tunnel type charcoal kiln |
| CN101993206B (en) * | 2009-08-25 | 2012-09-05 | 穆宝文 | Hot smoke indirect calcining continuous production lime furnace |
| CN102249225B (en) * | 2011-06-13 | 2013-08-07 | 福建省龙岩龙能粉煤灰综合利用有限公司 | System using biomass for heat supply for producing activated carbon by fly ash |
| CN102249225A (en) * | 2011-06-13 | 2011-11-23 | 福建省龙岩龙能粉煤灰综合利用有限公司 | System using biomass for heat supply for producing activated carbon by fly ash |
| CN102249226B (en) * | 2011-06-13 | 2013-06-12 | 福建省龙岩龙能粉煤灰综合利用有限公司 | Zero-discharge and self-heating charring process for activated carbon preparation |
| CN102249226A (en) * | 2011-06-13 | 2011-11-23 | 福建省龙岩龙能粉煤灰综合利用有限公司 | Zero-discharge and self-heating charring process for activated carbon preparation |
| CN102259854A (en) * | 2011-06-22 | 2011-11-30 | 李保东 | Steam-free operation device for activation furnace |
| CN102259854B (en) * | 2011-06-22 | 2012-12-26 | 李保东 | Steam-free operation device for activation furnace |
| CN102515159A (en) * | 2011-12-30 | 2012-06-27 | 承德绿世界活性炭有限公司 | Improved shell charcoal activation furnace |
| CN102642831A (en) * | 2012-04-23 | 2012-08-22 | 张鹏远 | Integrated stove |
| CN104773733A (en) * | 2015-05-06 | 2015-07-15 | 福建鸿宇安生物科技有限公司 | Activated carbon boiler |
| CN105883784A (en) * | 2016-04-06 | 2016-08-24 | 东莞市凯金新能源科技股份有限公司 | Artificial graphite precursor hot kettle feeding method |
| CN108249436A (en) * | 2018-03-20 | 2018-07-06 | 浙江省林业科学研究院 | A kind of method and its vertical activation furnace with steam activation preparing active carbon |
| CN112299413A (en) * | 2019-08-02 | 2021-02-02 | 中冶长天国际工程有限责任公司 | Rotary activation furnace and activated carbon production system with same |
| WO2024148768A1 (en) * | 2023-01-13 | 2024-07-18 | 西安热工研究院有限公司 | Special-shaped brick and coke making furnace comprising same, system, and method |
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Application publication date: 20080625 |