CN101191105A - Auxiliary agent for floor cleaning water - Google Patents
Auxiliary agent for floor cleaning water Download PDFInfo
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- CN101191105A CN101191105A CNA2007101961720A CN200710196172A CN101191105A CN 101191105 A CN101191105 A CN 101191105A CN A2007101961720 A CNA2007101961720 A CN A2007101961720A CN 200710196172 A CN200710196172 A CN 200710196172A CN 101191105 A CN101191105 A CN 101191105A
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- floor
- composition
- cleaning water
- water
- general formula
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 137
- 238000004140 cleaning Methods 0.000 title claims abstract description 119
- 239000012752 auxiliary agent Substances 0.000 title claims description 57
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 37
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 16
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010790 dilution Methods 0.000 claims abstract description 7
- 239000012895 dilution Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 98
- 239000004094 surface-active agent Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000003093 cationic surfactant Substances 0.000 claims description 15
- 125000006353 oxyethylene group Chemical group 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 12
- 125000005466 alkylenyl group Chemical group 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 3
- 241000282326 Felis catus Species 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 18
- 239000004615 ingredient Substances 0.000 abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 235000013599 spices Nutrition 0.000 description 17
- 239000000919 ceramic Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000013543 active substance Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 125000006177 alkyl benzyl group Chemical group 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- YHSUKCZOJPDYOC-UHFFFAOYSA-N N-methyl-N-tridecylhydroxylamine Chemical compound CCCCCCCCCCCCCN(C)O YHSUKCZOJPDYOC-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000003997 cyclic ketones Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The invention provides an accessory ingredient for floor-cleaning water, which is used with water dilution, characterized in good wetting property and being easy to dry. The accessory ingredient for floor-cleaning water uses one or more nonionic surfactans selected from the following general formulas (I), (II) as an active ingredient. One general formula is R<1>-O-(EO)p-H(I),wherein R<1> is an alkyl or an alkenyl which is a linear chain or a fork chain of 11-18 carbon atoms, EO is an epoxyethane base, p is the average number of addition mole of 15-200.The other general formula is R<2>-O-(EO)q/(PO)r-H (II), wherein R<2> is an alkyl or an alkenyl which is a linear chain or a fork chain of 11-18 carbon atoms, EO is an epoxyethane base, PO is a propene oxide base, q, r are respectively the average numbers of addition mole, wherein q is a number of 8-50, r is a number of 0.5-20, and EO and PO can be combined with a random bond or a block bond.
Description
Technical field
The present invention relates to auxiliary agent for floor cleaning water (assistant agent for floor-cleaningwater) and use this auxiliary agent floor cleaning water, use the method on the cleaning floor of above-mentioned floor cleaning water.
Background technology
The cleaning on floor typically uses suction cleaner, clear away or the method for water wiping carries out.The base plate cleaning uses rag to carry out wiping usually in traditional residences in Japan.In recent years, the situation on water wiping floor constantly reduces in general family, but in the communal facility headed by the school, hotel and arenas inlet and parlor, decorates exquisite floor in order to protect, even now also water come the wiping floor.In addition, in the general family with the country in Southeast Asia headed by the Indonesia, floor-cleaning also is to come the method for wiping to carry out by water usually.As auxiliary agent for floor cleaning water, known is the auxiliary agent of purpose with clearing power and sterilization.
Japanese kokai publication hei 3-182597 communique relates to contain the invention of the floor of nonionic surface active agent and cationic surfactant with liquid detergent composition, as nonionic surface active agent use HLB be more than 9, preferably use 11～13 nonionic surface active agent.
TOHKEMY 2001-311093 communique discloses the floor cleansing composition that contains nonionic surface active agent and cationic surfactant, in paragraph [0031], record the method for water wiping: after use floor-cleaning custom-built machine is cleaned operation, use the clean sewage of recovery such as suction vacuum machine, afterwards, use aqueous mop to wipe the residue that remains on the floor surface.
TOHKEMY 2006-111714 communique discloses the cleaning agent for hard surface composition that contains nonionic surface active agent such as alkyglycosides, in paragraph [0034], record the method for water wiping: use the floor to clean and clean operation with machine (being equipped with the polishing machine of car mat (floor pad) or floor brush etc.) or the automatic scrubber in floor, after cleaning last night, use the clean sewage of recovery such as suction vacuum machine, afterwards, use aqueous mop to wipe the residue that remains on the floor surface.
Summary of the invention
The invention provides following auxiliary agent as the means that solve problem.
(1) a kind of auxiliary agent for floor cleaning water is an effective constituent with the nonionic surface active agent more than a kind that is selected from following general formula (I), (II).
R
1-O-(EO)p-H (I)
[in the formula, R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200.]
R
2-O-(EO)q/(PO)r-H (II)
[in the formula, R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that the combination of propylene oxide base, EO and PO both can be closed by random bond, also can be closed by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.]
The floor that the present invention also provides the floor cleaning water, the floor-cleaning method of using above-mentioned auxiliary agent (1) that contain above-mentioned auxiliary agent (1), contain above-mentioned auxiliary agent (1) with cleansing composition, contain above-mentioned auxiliary agent (1) floor use retouching agent composition, use the cleaning retouching method on the floor of above-mentioned auxiliary agent (1).
Embodiment
Wish when water wiping floor that aquagenic wettability is good, dry easily and do not need the back wiping after the water wiping.But, use when containing commercially available floor with the water of treatment agent, poor to the floor wettability of the surface, the surface after the processing forms spot (spot) easily.Its reason may be that the wettability of floor base mateiral itself is poor because the influence that is caused by waxing is big.
In addition, contain the commercially available product of sterilization, so compare with situation only, wettability is poorer with water treatment with cationic surfactant because in the general family of country in Southeast Asia, use.In addition, in daily use, do not wish in the water wiping process to bubble, and because do not carry out rinsing (flushing) or secondary wiping, so gradation composition and cooperation concentration will be restricted.
Problem of the present invention is to provide the drying property after a kind of, water wiping good to the floor wettability of the surface also well, not need the auxiliary agent for floor cleaning water of back wiping and uses the floor cleaning water of this auxiliary agent, uses the floor-cleaning method of above-mentioned floor cleaning water.
Auxiliary agent for floor cleaning water of the present invention, when using at dilute with water and as floor cleaning water, since good to the wettability on floor, so on the floor, be coated with out (spreadable) easily.Therefore, former state is placed and just can be made it rapid drying after the wiping, does not also need the back to wipe.
The present invention is included in preferred configuration (2)～(4) of following record.
(2) auxiliary agent for floor cleaning water that also contains (1) record of (b) cationic surfactant.
(3) contain the auxiliary agent for floor cleaning water of (1) or (2) record and the floor cleaning water of water.
(4) behind the floor cleaning water wiping floor of use (3) record, make it exsiccant floor-cleaning method.
In addition, as the solution of other problem, the present invention also provides the invention of following (5)～(6).
(5) containing the nonionic surface active agent more than a kind that (a) is selected from following general formula (I), (II), is floor cleansing compositions of 3～10 at 25 ℃ pH.
R
1-O-(EO)p-H (I)
[in the formula, R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200.]
R
2-O-(EO)q/(PO)r-H (II)
[in the formula, R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that propylene oxide base, EO and PO both can close by random bond, also can close by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.]
(6) a kind of floor-cleaning method comprises: (i) the described floor of dilute with water (5) operation of cleansing composition with the preparation floor cleaning water; (ii) use the operation on floor cleaning water wiping floor; (iii) make floor exsiccant operation.
Further, as the solution of other problem, the present invention also provides the invention of following (7)～(8).
(7) a kind of floor use retouching agent composition, it contains the nonionic surface active agent more than a kind that (a) is selected from following general formula (I), (II), and the pH of said composition in the time of 25 ℃ is 3～10.
R
1-O-(EO)p-H (I)
[in the formula, R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200.]
R
2-O-(EO)q/(PO)r-H (II)
[in the formula, R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that propylene oxide base, EO and PO both can close by random bond, also can close by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.]
(8) a kind of floor-cleaning retouching method, it is characterized in that, on the floor, use the floor use retouching agent composition that contains (7) and water and (a) concentration of composition be 50～1000ppm, and the pH in the time of 25 ℃ is that 3～10 water-based retouching liquid cleans the retouching floor surface.
＜auxiliary agent for floor cleaning water 〉
Auxiliary agent for floor cleaning water of the present invention, it contains the nonionic surface active agent more than a kind that is selected from following general formula (I), (II) as (a) composition and effective constituent.Auxiliary agent for floor cleaning water of the present invention both can be Powdered, also can be concentrate aqueous.
R
1-O-(EO)p-H (I)
[in the formula, R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200.]
R
2-O-(EO)q/(PO)r-H (II)
[in the formula, R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are the propylene oxide bases, and q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.]
The nonionic surface active agent of general formula (I) both can be R
1In the different mixture of carbonatoms, also can be the mixture of straight chain and side chain.
In general formula (I), from the viewpoint of wettability and drying property, R
1Preferably carbonatoms 11～18, be more preferably the side chain of carbonatoms 11～13.
In general formula (I), p preferably 15～200, be more preferably 15～50.P preferably 4～10 when cooperating the compound of general formula (I) in order to improve clearing power.But, in order to obtain the preferred p of sufficient wettability be more than 15 in the present invention, preferred especially p is 18～50.
In addition, in general formula (II), from the viewpoint of wettability and drying property, R
2Preferably carbonatoms 11～18, be more preferably the side chain of carbonatoms 11～13.
In general formula (II), q preferably 8～50, be more preferably 8～20.In addition, r preferably 0.3～20, to be more preferably 0.5～10, to be more preferably be 0.5～5.
The nonionic surface active agent of general formula (II) preferably is selected from the nonionic surface active agent more than a kind of following general formula (II-1), (II-2).In general formula (II-1), (II-2), EO and PO both can be random combinations, also can be the block combination.
R
2-O-(EO)s-(PO)t-H (II-1)
[in the formula, R
2, EO, PO implication and general formula (II) in identical, s, t represent average addition mole number respectively, s is that 8～50 number, t are 0.5～12 numbers.]
R
2-O-(EO)u-(PO)v-(EO)w-H (II-2)
[in the formula, R
2, EO, PO implication identical with general formula (II), u, v, w represent average addition mole number respectively, u is that 5～30 number, v are that 0.5～12 number, w are that 5～30 number, u+w are the numbers below 50.]
The nonionic surface active agent of general formula (II-1), (II-2) both can be R
2In the different mixture of carbonatoms, also can be the mixture of straight chain and side chain.
In general formula (II-1), (II-2), from the viewpoint of wettability and drying property, R
2Preferably carbonatoms 11～18, be more preferably the side chain of carbonatoms 11～13.
In general formula (II-1), s preferably 8～50, be more preferably 8～15.T preferably 0.5～20, to be more preferably be 0.5～5.
In general formula (II-2), u preferably 5～30, be more preferably 5～10.V preferably 0.5～12, be more preferably 0.5～5.W preferably 0.5～30, be more preferably 0.5～10.In addition, u+w is below 50, preferably below 20.
Use in treatment agent and the detergent on floor in the past, cooperate sterilant in order to give clean feel.These products are especially regional welcome with the life of light pin such as country in Southeast Asia.Mainly use cationic surfactant as such sterilant.Cationic surfactant significantly descends the wettability of floor surface, but of the present invention containing (a) composition auxiliary agent for floor cleaning water, even contain under the situation of cationic surfactant the also excellent wettability of performance.
Therefore, [being called (b) composition] also can solve problem of the present invention even auxiliary agent for floor cleaning water of the present invention contains cationic surfactant again.(b) composition single-long-chain alkyl type quaternary ammonium salt preferably for example can be enumerated the single-long-chain alkyl type quaternary ammonium salt of representing with following general formula.
(in the formula, R
11Be alkyl, the R of carbonatoms 8～18
12, R
13Be respectively alkyl, the R of carbonatoms 1～3
14The alkyl or the benzyl of expression carbonatoms 1～3, X represents negatively charged ion such as chlorine, bromine.)
The alkyl benzyl dimethyl ammonium chloride of the carbonatoms of preferred alkyl in 8～18 scopes.
In addition, in auxiliary agent for floor cleaning water, can also cooperate and be selected from (c) tackifier, more than a kind of (d) spices.(c) tackifier of composition improve the viscosity of auxiliary agent for floor cleaning water, make the user feel dense, and the metering when making use becomes easy.In addition, (d) spices of composition is in use and give clean feel, salubrious sense after using.
(c) tackifier of composition Mierocrystalline cellulose series compound preferably can be enumerated Walocel MT 20.000PV, Natvosol, carboxymethyl cellulose, these salt etc., preferred Natvosol.The Natvosol that can compatibly use is, the aqueous solution of its 1% concentration is about 100～5000mPas 25 ℃ viscosity, and alkyl degree of exchange (DS) is in 0.8～1.5 scope.
(d) spices of composition both can use independent fragrance component, also can use the flavor compositions that contains multiple fragrance component with specified proportion.Can use the fragrance component of in " flavor chemistry " (serial, the clear and distribution on September 16th, 58 of industry chemistry is compiled by the bright work of red star, Japanization association), " synthetic perfume chemistry and knowledge of goods " (seal rattan unit one work, chemical industry day newspaper office, distribution on March 6th, 1996), " rudimentary knowledge of spices and blending " (middle island your work of base, industry books (strain), distribution on June 21 nineteen ninety-five), putting down in writing as fragrance component.
As the upperseat concept of preferred perfume ingredients, can enumerate hydrocarbon system row spices, pure serial spices, ether series spices, aldehyde series spices, ketone series spices, ester series spices, lactone series spices, cyclic ketones series spices, nitrogenous serial spices.
As other composition, can cooperate the alkaline agent of the hydrotropic agent, aliphatics hydramine etc. of the sequestrant, lower alcohol etc. of ethylene dinitrilotetra-acetic acid salt etc., (b) sterilant, pigment and the water etc. beyond the composition.
In the auxiliary agent for floor cleaning water of the present invention, the content range of above-mentioned (a)～(d) composition, other composition is adjusted to, and (, when being made into floor cleaning water) became proper concn when dilution was used in water.Therefore, as the water yield that is diluted to floor cleaning water auxiliary agent for floor cleaning water before is arbitrarily, but, as mentioned above, because (b) composition has the tendency that the wettability effect that makes (a) composition descends, thus mass ratio (b)/(a) is below 0.7, preferably 0.05～0.7, be more preferably 0.1～0.6.When cooperating (b) composition for germicidal action,, wish to cooperate more than 0.05 in order to bring into play effective bactericidal properties.In addition, (c) composition and (d) composition be adjusted to, under the prerequisite that does not hinder effect of the present invention by cooperating (c) composition and (d) composition to bring into play desired effect.
In addition, cooperate (a) and (b) in addition tensio-active agent might reduce effect of the present invention, and might produce and steep and it is remained on the floor surface.So, relative (a) composition, (a) and (b) ratio of tensio-active agent in addition by quality ratio, preferably less than 1, be more preferably below 0.5, most preferably be below 0.1.
Convenient use composed as follows of auxiliary agent for floor cleaning water of the present invention.In the present invention, be called the concentrated solution type.
When containing the nonionic surface active agent more than a kind that is selected from following general formula (I), (II) as (a) composition in the auxiliary agent for floor cleaning water, its content be 0.1～5.0 quality %, preferably 0.5～4 quality %, be more preferably 1～3 quality %.
In auxiliary agent for floor cleaning water of the present invention as (b) when composition contains cationic surfactant, its content preferably 0.05～2.5 quality %, to be more preferably 0.25～2.0 quality %, to be more preferably be 0.5～1.5 quality %.But ratio (b)/(a) satisfies aforementioned proportion.
As (c) when composition contains tackifier, preferably 2.0 quality % are following, to be more preferably 0.1～1.5 quality %, to be more preferably be 0.1～0.6 quality % for its content in auxiliary agent for floor cleaning water of the present invention.
As (d) when composition contains spices, preferably 2.0 quality % are following, to be more preferably 0.1～1.0 quality %, to be more preferably be 0.1～0.6 quality % for its content in the auxiliary agent for floor cleaning water of the present invention.
When containing beyond (a)～(d) composition composition in the auxiliary agent for floor cleaning water as above-mentioned concentrated solution type, its content is in the solid deal, preferably 1.0 quality % following, be more preferably that 0.8 quality % is following, to be more preferably be below the 0.5 quality %.In addition, in auxiliary agent for floor cleaning water, (a) and (b) tensio-active agent in addition preferably 1 quality % following, be more preferably 0.5 quality % following, most preferably be below the 0.1 quality %.
When naked hand uses, reduce the reason of pH value to the influence of skin, the pH of auxiliary agent for floor cleaning water (25 ℃) preferably 3～10, be more preferably 6～9.
Adding water becomes the auxiliary agent for floor cleaning water of concentrated solution type, is not separated, excellent in stability.And, dilution auxiliary agent for floor cleaning water in domestic waters such as tap water and when using, the effect of performance extender, easily with metering such as container cover or in water, dissolve easily, so are preferred formulations as goods.Preferably use ion exchanged water when containing the concentrated liquid type making, it can not exert an influence to stability in storage.
The knowledge of above-described relevant auxiliary agent for floor cleaning water, the floor that also goes for above-mentioned (5) represented as other problem solution is with cleansing composition (at this moment, auxiliary agent for floor cleaning water replaces with the floor cleansing composition).Floor of the present invention cleansing composition needn't water wiping floor after cleaning the floor.Similarly, the knowledge of above-described relevant auxiliary agent for floor cleaning water, also go for the floor use retouching agent composition (at this moment, auxiliary agent for floor cleaning water replaces with floor use retouching agent composition) of above-mentioned (7) represented as other problem solution.
＜floor cleaning water 〉
Floor cleaning water of the present invention is meant, contains the floor cleaning water of above-mentioned auxiliary agent for floor cleaning water and water, the floor cleaning water when perhaps using with domestic water dilution auxiliary agent for floor cleaning water.(a) content of composition be 40～1000ppm, preferably 40～500ppm, be more preferably 50～300ppm.
When floor cleaning water of the present invention contains (b) composition cationic surfactant, its content preferably 25～500ppm, to be more preferably 25～250ppm, to be more preferably be 25～150ppm.Mass ratio in addition, (b)/(a) is identical with ratio in the auxiliary agent for floor cleaning water.
When floor cleaning water of the present invention contained (c) composition tackifier, preferably 100ppm was following, to be more preferably 10～80ppm, to be more preferably be 10～50ppm for its content.
When floor cleaning water of the present invention contained (d) composition spices, preferably 100ppm was following, to be more preferably 10～80ppm, to be more preferably be 10～50ppm for its content.
When floor cleaning water of the present invention contained beyond (a)～(d) composition and the water composition, its content was in the solid deal, preferably 50ppm following, be more preferably 40ppm following, most preferably be below the 30ppm.(a) and (b) in addition the cooperation of tensio-active agent in addition, (a) composition relatively, mass ratio preferably less than 1, be more preferably below 0.5; In floor cleaning water, (a) and (b) tensio-active agent in addition preferably 50ppm following, be more preferably 25ppm following, most preferably be below the 5ppm.
The pH (25 ℃) that contains the floor cleaning water of auxiliary agent for floor cleaning water and water preferably 3～10, be more preferably 6～9.
The knowledge of above-described relevant floor cleaning water, also go for the floor cleaning water (at this moment, auxiliary agent for floor cleaning water replaces with the floor cleansing composition) that uses in the floor-cleaning method of above-mentioned (6) represented as other problem solution.Similarly, the knowledge of above-described relevant floor cleaning water, also go for the water-based retouching liquid that uses in the floor-cleaning retouching method of above-mentioned (8) represented as other problem solution (at this moment, auxiliary agent for floor cleaning water replaces with floor use retouching agent composition, and floor cleaning water replaces with water-based retouching liquid).
＜floor-cleaning method 〉
Floor-cleaning method of the present invention is, use above-mentioned floor cleaning water, with common mop, rag artificially or use the floor to clean with machine (being equipped with the polishing machine of car mat or floor brush etc.) or floor scrubber and mechanically behind the wiping floor, exsiccant method automatically with making it former state.Dry also can blowing over by the force air that makes room temperature or heat finished, but in the present invention, behind the wiping floor, only just can finish dry very rapidly by placement at room temperature.
In floor-cleaning method of the present invention, because floor cleaning water is good to the wettability of floor, so during with wiping floors such as mops, floor cleaning water is coated on the floor equably.Therefore, the wiping after drying well, does not need the back wiping yet.Therefore, in the floor-cleaning method of above-mentioned (6) represented as other problem solution, the operation that the floor cleaning water of preparing in using operation (i) comes the wiping floor (ii) after, can make floor exsiccant operation under the situation of washing floor cleaning water (iii) not rinsing.In addition, method of the present invention can be used as final floor-cleaning retouching processing and implements, and described in above-mentioned (8), can be applied to use the method for the water-based retouching liquid of regulation to the retouching of floor surface enforcement cleaning.As the floor of the method that can be suitable for the invention described above, can enumerate floor with hard surface, for example ceramic tile, synthetic resin series flooring material, floor are with the wooden series of floor of material etc., stone floor etc.
Embodiment
Illustrate in greater detail the present invention below by embodiment.Embodiment only is an illustration of the present invention, is not limitation of the invention.
(a) composition [(a1), (a2)] that is blended in table 1, the table 2 expression becomes to grade and water with (b)～(d), obtains auxiliary agent for floor cleaning water (concentrated solution type).Embodiment and comparative example are carried out following each test.Ecbatic in table 1.
1. wettability evaluation method
With 0.7ml/100cm
2Ratio, (production of INAX society, SP-100,10cm * 10cm) are gone up to drip each auxiliary agent are become 1% floor cleaning water [(a) concentration of composition is 200ppm] with the water dilution, and are coated with at all surfaces with absorbent cotton to the semiporcelain ceramic tile of cleaning surfaces.Wettability according to following standard evaluation ceramic tile surface.
◎=ceramic tile all surfaces is wetted equably
The almost all surfaces of zero=ceramic tile is wetted equably, but few hydrophobic nature is arranged
Zero △=ceramic tile surface about 80～90% wetted equably, but hydrophobic nature is arranged
About 50% left and right sides of △=ceramic tile surface is hydrophobic in nature
*=ceramic tile surface about hydrophobic in nature more than 90%
2. rate of drying evaluation method
With 0.7ml/100cm
2Ratio, (production of INAX society, SP-100,10cm * 10cm) are gone up to drip each auxiliary agent are become 1% floor cleaning water [(a) concentration of composition is 200ppm] with the water dilution, and are coated with at all surfaces with absorbent cotton at the semiporcelain ceramic tile of cleaning surfaces.Measure the time (second) of water till ceramic tile surface evaporates fully the time.To count 100 the time of drying when ceramic tile surface only is coated with water distribution, obtain the relatively dry time that each cooperates example.
Calculating formula: the time of drying (second) * 100 of time of drying (the second)/water of relatively dry time=each agent
3.pH
The pH of this agent is by sodium hydroxide and hydrochloric acid adjustment.In addition, the mensuration of pH is measured under the temperature by the program of JIS Z8802 7.2 (measuring methods), at 25 ℃ and is carried out.
Table 1
| Embodiment | ||||||||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | ||||
| Auxiliary agent for floor cleaning water | Content (quality %) | (a1) | A1-1 (C16-18 straight chain EO=19 mole) | 2.0 | ||||||||||||||
| A1-2 (C11-13 side chain EO=35 mole) | 2.0 | |||||||||||||||||
| A1-3 (C16-18 straight chain EO=47 mole) | 2.0 | |||||||||||||||||
| A1-4 (C11-13 side chain EO=50 mole) | 1.5 | 2.0 | 2.0 | 2.0 | 3.0 | |||||||||||||
| (a2) | A2-1 (10 moles of C12-14 EO, 0.5 mole of PO) | 2.0 | ||||||||||||||||
| A2-2 (14 moles of C12-14 EO, 0.5 mole of PO) | 1.5 | 2.0 | 2.0 | 3.0 | 1.5 | 2.0 | ||||||||||||
| (b) | Cationic surfactant | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 0.5 | 1.0 | 1.0 | 1.0 | 0.5 | 1.0 | ||||
| (c) | The cellulose-type tackifier | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | - | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | ||
| (d) | Spices | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | - | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | ||
| Nonionic surface active agent 1 | ||||||||||||||||||
| Nonionic surface active agent 2 | ||||||||||||||||||
| Aniorfic surfactant 1 | ||||||||||||||||||
| Amphoterics 1 | ||||||||||||||||||
| Amphoterics 2 | ||||||||||||||||||
| Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |||
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | |||
| (b)/(a) [mass ratio] | 0.5 | 0.5 | 0.5 | 0.5 | 0.67 | 0.5 | 0.5 | 0.25 | 0.33 | 0.67 | 0.5 | 0.25 | 0.33 | - | - | |||
| pH(20℃) | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | |||
| The wettability of floor cleaning water | ○ | ◎ | ○ | ○ | ○ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | |||
| The relatively dry time of floor cleaning water | 83 | 71 | 77 | 77 | 87 | 69 | 71 | 69 | 71 | 77 | 71 | 71 | 71 | 71 | 71 | |||
Table 2
| Comparative example | |||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | ||||
| Auxiliary agent for floor cleaning water | Content (quality %) | (a1) | A1-1 (C16-18 straight chain EO=19 mole) | ||||||||
| A1-2 (C11-13 side chain EO=35 mole) | |||||||||||
| A1-3 (C16-18 straight chain EO=47 mole) | |||||||||||
| A1-4 (C11-13 side chain EO=50 mole) | |||||||||||
| (a2) | A2-1 (10 moles of C12-14 EO, 0.5 mole of PO) | ||||||||||
| A2-2 (14 moles of C12-14 EO, 0.5 mole of PO) | |||||||||||
| (b) | Cationic surfactant | 1.5 | 2.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | |||
| (c) | The cellulose-type tackifier | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |||
| (d) | Spices | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | |||
| Nonionic surface active agent 1 | 2.0 | ||||||||||
| Nonionic surface active agent 2 | 2.0 | ||||||||||
| Aniorfic surfactant 1 | 2.0 | ||||||||||
| Amphoterics 1 | 2.0 | ||||||||||
| Amphoterics 2 | 2.0 | ||||||||||
| Water | Surplus | Surplus | 100 | Surplus | Surplus | Surplus | Surplus | Surplus | |||
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | |||
| (b)/(a) [mass ratio] | - | - | - | - | - | - | - | - | |||
| pH(20℃) | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | |||
| The wettability of floor cleaning water | × | × | ○△ | × | × | × | × | × | |||
| The relatively dry time of floor cleaning water | 167 | 167 | 100 | 167 | 167 | 167 | 167 | 167 | |||
(a) composition
A1-1: in general formula (I), R
1Straight chained alkyl, the p that is carbonatoms 16～18 is 19 nonionic surface active agent
A1-2: in general formula (I), R
1Branched-chain alkyl, the p that is carbonatoms 11～13 is 35 nonionic surface active agent
A1-3: in general formula (I), R
1Straight chained alkyl, the p that is carbonatoms 16～18 is 47 nonionic surface active agent
A1-4: in general formula (I), R
1Branched-chain alkyl, the p that is carbonatoms 11～13 is 50 nonionic surface active agent
A2-1: in general formula (II-2), R
2Straight chained alkyl, the u that is carbonatoms 12～14 is 5, v is 0.5, w is 5 nonionic surface active agent
A2-2: in general formula (II-2), R
2Straight chained alkyl, the u that is carbonatoms 12～14 is 7, v is 0.5, w is 7 nonionic surface active agent
(b) composition
Cats product: chemical name is alkyl benzyl dimethyl ammonium chloride (carbonatoms of alkyl is 12～16)
(c) composition
Cellulose-type tackifier: hydroxyethyl ether cellulose (trade(brand)name HEC-SE850K, DaicelChemical Industries, Ltd. produces)
(other composition)
Nonionic surface active agent 1: polyoxyethylene lauryl ether (the average addition mole number of oxyethylene group is 12)
Nonionic surface active agent 2: alkyglycosides (carbonatoms of alkyl is 12,14 straight chain, and sugared condensation degree on average is 1.35)
Aniorfic surfactant 1: the carbonatoms of alkyl is 12 linear alkylbenzene sulphonic acid
Amphoterics 1: lauryl dimethyl amine oxide (lauryldimethylaminoxide)
Amphoterics 2: dodecanamide propyl sultaine (lauric acidamidopropyl sulfobetaine)
Claims (20)
1. an auxiliary agent for floor cleaning water is characterized in that,
Containing (a) composition as effective constituent, should (a) composition be more than one the nonionic surface active agent that is selected from following general formula (I), (II),
R
1-O-(EO)p-H (I)
In the formula (I), R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200,
R
2-O-(EO)q/(PO)r-H (II)
In the formula (II), R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that propylene oxide base, EO and PO both can close by random bond, also can close by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.
2. auxiliary agent for floor cleaning water as claimed in claim 1 is characterized in that,
With (a) composition nonionogenic tenside of general formula (II) expression is to be selected from more than one of following general formula (II-1), (II-2),
R
2-O-(EO)s-(PO)t-H (II-1)
In the formula (II-1), R
2, EO, PO implication identical with implication in the general formula (II), s, t represent average addition mole number respectively, s is that 8～50 number, t are 0.5～12 numbers,
R
2-O-(EO)u-(PO)v-(EO)w-H (II-2)
In the formula (II-2), R
2, EO, PO implication identical with implication in the general formula (II), u, v, w represent average addition mole number respectively, u is that 5～30 number, v are that 0.5～12 number, w are 5～30 numbers, u+w is the number below 50.
3. auxiliary agent for floor cleaning water as claimed in claim 1 or 2 is characterized in that,
Also contain (b) composition cationic surfactant.
4. auxiliary agent for floor cleaning water as claimed in claim 1 or 2 is characterized in that,
(a) content of composition is 0.1～5.0 quality %.
5. a floor cleaning water is characterized in that,
Contain auxiliary agent for floor cleaning water as claimed in claim 1 and water,
More than one the concentration of nonionic surface active agent that is selected from general formula (I), (II) as (a) composition is 50～1000ppm.
6. floor cleaning water as claimed in claim 5 is characterized in that,
Contain (a) composition and (b) composition with following concentration, mass ratio (b)/(a) is below 0.7,
(a) composition is selected from more than one the nonionic surface active agent of general formula (I), (II), and concentration is 40～1000ppm,
(b) concentration of composition cationic surfactant is 25～500ppm.
7. a floor-cleaning method is characterized in that,
Use as making this floor drying behind claim 5 or the 6 described floor cleaning water wiping floors.
8. a floor cleansing composition is characterized in that,
Contain more than one the nonionic surface active agent that (a) composition is selected from general formula (I), (II), this floor is 3～10 with cleansing composition at 25 ℃ pH,
R
1-O-(EO)p-H (I)
In the formula (I), R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200,
R
2-O-(EO)q/(PO)r-H (II)
In the formula (II), R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that propylene oxide base, EO and PO both can close by random bond, also can close by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.
9. floor as claimed in claim 8 cleansing composition is characterized in that,
Also contain (b) composition cationic surfactant.
10. floor cleansing composition as claimed in claim 8 or 9 is characterized in that mass ratio (b)/(a) is below 0.7.
11. the floor cleansing composition is characterized in that as claimed in claim 8 or 9,
(a) content of composition is 0.1～5.0 quality %.
12. the floor cleansing composition is characterized in that as claimed in claim 8 or 9, can directly make this floor drying after being used for the floor.
13. a floor-cleaning method is characterized in that,
Comprise:
(i) prepare the operation of floor cleaning water with cleansing composition by dilute with water floor as claimed in claim 8;
(ii) use the operation on floor cleaning water wiping floor;
(iii) make floor exsiccant operation.
14. the method on cleaning as claimed in claim 13 floor, it is characterized in that, in operation (i), floor cleaning water is to dispose with cleansing composition with water dilution floor, and makes more than one the concentration of nonionic surface active agent that is selected from general formula (I), (II) as (a) composition become 50～1000ppm.
15. the method as claim 13 or 14 described cleaning floors is characterized in that,
Operation (ii) after, do not rinse and wash floor cleaning water and carry out operation (iii).
16. a floor use retouching agent composition is characterized in that,
Containing (a) composition, should (a) composition be more than one the nonionic surface active agent that is selected from following general formula (I), (II), and described floor use retouching agent composition is 3～10 at 25 ℃ pH,
R
1-O-(EO)p-H (I)
In the formula (I), R
1Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, p are that average addition mole number represents 15～200,
R
2-O-(EO)q/(PO)r-H (II)
In the formula (II), R
2Alkyl or alkenyl, the EO that is the carbonatoms 11～18 of straight or branched is that oxyethylene group, PO are that propylene oxide base, EO and PO both can close by random bond, also can close by the block bond, q, r represent average addition mole number respectively, and q is that 8～50 number, r are 0.5～20 numbers.
17. floor as claimed in claim 16 use retouching agent composition is characterized in that, also contains (b) composition cats product.
18. floor as claimed in claim 17 use retouching agent composition is characterized in that mass ratio (b)/(a) is below 0.7.
19. any described floor use retouching agent composition as claim 16～18 is characterized in that,
(a) content of composition is 0.1～5.0 quality %.
20. a method that cleans the retouching floor is characterized in that,
By use the concentration contain just like any described floor use retouching agent composition of claim 16～18 and water, (a) composition on the floor is 50～1000ppm, and is that 3～10 water-based retouching liquid cleans the retouching floor surface at 25 ℃ pH.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006-325285 | 2006-12-01 | ||
| JP2006325285 | 2006-12-01 | ||
| JP2006325285 | 2006-12-01 | ||
| JP2007-279003 | 2007-10-26 | ||
| JP2007279003A JP5295548B2 (en) | 2006-12-01 | 2007-10-26 | Floor water wiping aid |
| JP2007279003 | 2007-10-26 |
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|---|---|
| CN101191105A true CN101191105A (en) | 2008-06-04 |
| CN101191105B CN101191105B (en) | 2014-01-15 |
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|---|---|---|---|
| CN200710196172.0A Expired - Fee Related CN101191105B (en) | 2006-12-01 | 2007-11-29 | Auxiliary agent for floor cleaning water |
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| Country | Link |
|---|---|
| JP (1) | JP5295548B2 (en) |
| CN (1) | CN101191105B (en) |
| MY (1) | MY147950A (en) |
| TW (1) | TWI433926B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102224231B (en) * | 2008-11-21 | 2014-01-01 | 花王株式会社 | Liquid detergent composition |
| CN110219939A (en) * | 2013-06-27 | 2019-09-10 | 三之星机带株式会社 | The manufacturing method of transmission belt and its fibrous structures and fibrous structures |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
| CN111454784A (en) * | 2020-04-30 | 2020-07-28 | 中山榄菊日化实业有限公司 | Floor cleaning agent and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5419799B2 (en) * | 2010-05-21 | 2014-02-19 | 花王株式会社 | Liquid detergent composition for floors |
| JP5666733B2 (en) * | 2013-05-27 | 2015-02-12 | 花王株式会社 | Cleaning composition for hard surface |
| JP2015007221A (en) * | 2013-05-29 | 2015-01-15 | 花王株式会社 | Hard surface detergent composition |
| JP7362305B2 (en) * | 2019-06-10 | 2023-10-17 | 花王株式会社 | Disinfectant composition for hard surfaces |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0967545A (en) * | 1995-08-30 | 1997-03-11 | Lion Corp | Water-base cleaning and lustering agent composition for floor |
| JP2001311093A (en) * | 2000-04-28 | 2001-11-09 | Rinrei:Kk | Detergent composition for floor |
| JP2006111714A (en) * | 2004-10-14 | 2006-04-27 | Kao Corp | Detergent composition for hard surface |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2608338B2 (en) * | 1989-12-12 | 1997-05-07 | 花王株式会社 | Liquid cleaning composition for floors |
| JPH09188853A (en) * | 1995-12-29 | 1997-07-22 | Lion Corp | Floor cleaning and lustering agent composition |
| TW349994B (en) * | 1996-12-02 | 1999-01-11 | Kao Corp | Surface activator composition |
| TW528798B (en) * | 1996-12-02 | 2003-04-21 | Kao Corp | Surfactant composition |
| US6048831A (en) * | 1996-12-02 | 2000-04-11 | Kao Corporation | Surfactant composition |
| JP5106717B2 (en) * | 2000-12-27 | 2012-12-26 | ライオン株式会社 | Cleaning composition |
| JP2003013094A (en) * | 2001-06-29 | 2003-01-15 | Lion Corp | Detergent composition |
| US6635609B2 (en) * | 2002-02-11 | 2003-10-21 | Johnsondiversey, Inc. | Surface maintenance composition |
| JP4578776B2 (en) * | 2003-01-31 | 2010-11-10 | 花王株式会社 | Disinfectant cleaning composition |
| JP2005040381A (en) * | 2003-07-23 | 2005-02-17 | Johnson Professional Co Ltd | Cleaning method and detergent solution used therefor |
| JP5000098B2 (en) * | 2004-04-19 | 2012-08-15 | ディバーシー株式会社 | Floor maintenance method |
-
2007
- 2007-10-26 JP JP2007279003A patent/JP5295548B2/en active Active
- 2007-11-27 TW TW96145033A patent/TWI433926B/en not_active IP Right Cessation
- 2007-11-29 MY MYPI20072130 patent/MY147950A/en unknown
- 2007-11-29 CN CN200710196172.0A patent/CN101191105B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0967545A (en) * | 1995-08-30 | 1997-03-11 | Lion Corp | Water-base cleaning and lustering agent composition for floor |
| JP2001311093A (en) * | 2000-04-28 | 2001-11-09 | Rinrei:Kk | Detergent composition for floor |
| JP2006111714A (en) * | 2004-10-14 | 2006-04-27 | Kao Corp | Detergent composition for hard surface |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102224231B (en) * | 2008-11-21 | 2014-01-01 | 花王株式会社 | Liquid detergent composition |
| CN110219939A (en) * | 2013-06-27 | 2019-09-10 | 三之星机带株式会社 | The manufacturing method of transmission belt and its fibrous structures and fibrous structures |
| CN110219939B (en) * | 2013-06-27 | 2021-07-30 | 三之星机带株式会社 | Transmission belt, fiber member thereof, and method for manufacturing fiber member |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
| CN111454784A (en) * | 2020-04-30 | 2020-07-28 | 中山榄菊日化实业有限公司 | Floor cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008156607A (en) | 2008-07-10 |
| JP5295548B2 (en) | 2013-09-18 |
| CN101191105B (en) | 2014-01-15 |
| TWI433926B (en) | 2014-04-11 |
| TW200846461A (en) | 2008-12-01 |
| MY147950A (en) | 2013-02-15 |
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