JPH09188853A - Floor cleaning and lustering agent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a floor cleaning and lustering agent compsn. which suppresses the slipperiness of a floor during walking thereon. SOLUTION: This compsn. contains a water-insol. polymer emulsion, a polyolefin wax, a surfactant, a hydrophilic solvent, a perfume, and a water, and the polyolefin wax comprises 60-10% polyethylene and/or its deriv. and 40-90% polyprolpylene.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a floor cleaning and polishing agent composition capable of simultaneously cleaning and polishing a floor and protecting the floor surface after the processing from slipping.

[0002]

2. Description of the Related Art Wooden flooring materials are often used as flooring materials for houses. The surface of wooden floor materials is usually painted for makeup and protection, but compared to plastic floor materials, wooden floor materials have the original beauty (such as luster) in a short period of time. ) Tends to lose. In order to protect them for a long time, a lusterless oil wax product is used. And, recently, a polish composition having a cleaning function (hereinafter, referred to as a wash polish composition) has been used. The present invention relates to improvements in floor cleaning polish compositions. A typical cleaning and polishing composition for floors is disclosed in JP-A-6-7.
It is disclosed in Japanese Patent No. 3400, Japanese Patent Laid-Open No. 6-108011, and the like. These are obtained by dispersing a wax emulsion or a polymer emulsion in an aqueous medium and further adding a detersive surfactant, a cleaning aid, a solvent and the like. When these floor cleaning and polishing compositions are used to wipe floors, both cleaning and polishing effects are certainly obtained. Further, it is desirable that the beautiful and glossy surface can be maintained for as long as possible even after the floor surface is washed and polished. Wax emulsions are used to meet this need. When a wax emulsion is used, the floor surface can be protected, but it becomes very slippery and requires careful walking. In particular, it is highly conceivable that an elderly person or a toddler may cause an accident such as slipping his / her foot while walking and falling.

[0003]

SUMMARY OF THE INVENTION An object of the present invention is to provide a floor cleaning and polishing composition having cleaning and polishing properties and suppressing slipperiness during walking.

[0004]

Means for Solving the Problems The inventors of the present invention have completed the present invention by conducting intensive research to solve the above problems. That is, according to the present invention, (A) a water-insoluble polymer emulsion, (B) a polyolefin wax,
In a floor cleaning polish composition containing (C) a surfactant, (D) a hydrophilic solvent, (E) a fragrance, and (F) water, the polyolefin wax of (B) is polyethylene and / or a derivative thereof. And polypropylene and / or
There is provided a floor cleaning and polish composition comprising a mixture of the derivatives, the mixing ratio of which is in the range of 60:40 to 10:90 with the total wax being 100.

[0005]

DETAILED DESCRIPTION OF THE INVENTION The composition of the present invention contains a water-soluble polymer emulsion, preferably 7 to 15% by weight of the cleaning polish composition. The polymer emulsion is the main component that forms a film on the floor and gives it gloss. Typical examples of the film-forming polymer include styrene resin emulsions, styrene / acrylic resin emulsions, and acrylic resin emulsions. Specific examples of these resins include styrene, vinyltoluene, acrylonitrile, methacrylonitrile, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, and acrylic. A homopolymer or a copolymer obtained by emulsion polymerization using a monomer such as 2-ethylhexyl acid, methacrylic acid, acrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, acrylamide or dimethylacrylamide can be mentioned. Furthermore, these styrene resin emulsions, styrene / acrylic resin emulsions, and acrylic resin emulsions can be used alone or in any combination of two or more.

The composition of the present invention contains a polyolefin wax, preferably 0.3 to 3 of the cleaning polish composition.
% By weight. The polyolefin wax imparts water repellency and durability to the flooring material and can suppress slipperiness. Specific examples of the polyolefin wax include a molecular weight of 1,000 to 10,000.
Polyethylene wax and derivatives thereof and polypropylene wax and derivatives thereof can be mentioned. The polyolefin wax can be used as an emulsion if necessary. In order to further exert the effect of the present invention, the mixing ratio of polyethylene and / or its derivative and polypropylene and / or its derivative is 60: by weight.
40 to 10:90, preferably 50:50 to 10:90
It is. If the proportion of polyethylene exceeds this range or is less than this range, the floor surface becomes slippery and the effect decreases.

The composition of the present invention contains 0.1 to 10% of a surfactant.
0.5 wt%, preferably 0.2 to 0.4 wt%. As the surfactant, a nonionic surfactant is preferable. Among these nonionic surfactants, polyoxyethylene alkyl ether, polyoxyethylene higher alcohol ether, polyoxyethylene hydrogenated castor oil,
It is more preferable to use an ethylene oxide addition type nonionic surfactant such as polyoxyethylene castor oil, polyoxyethylene nonylphenyl ether, and polyoxyethylene octyl ether. The ethylene oxide addition mole number of this nonionic surfactant is suitably 10 to 60. Of the ethylene oxide addition type nonionic surfactants, the polyoxyethylene alkyl ether type nonionic surfactants are the best. The nonionic surfactant imparts water repellency to the polish composition. The nonionic surfactant exhibits an effect of further improving water repellency when used in combination with a fragrance. Specifically, in a long-chain alkyl ether type surfactant, the alkyl group has 10 to 18 carbon atoms.
The range of alcohol. Excellent results are obtained when the number of moles of ethylene oxide added is 20 to 60.

It is preferable to use a hydrophilic solvent in the composition of the present invention. Among the hydrophilic solvents, the use of alkylene glycol ether gives good results. The hydrophilic solvent is preferably 3 to 3 of the polish composition.
It is better to contain 10 wt%, more preferably 5 to 8 wt%. The hydrophilic solvent has the effect of lowering the film forming temperature. Particularly preferable examples thereof include ethyl carbitol, acetylethyl carbitol, butyl carbitol, acetyl butyl carbitol, texanol, dimethyl carbitol, diethyl carbitol, and methyl ethyl carbitol.

The composition of the present invention preferably contains a fragrance in an amount of 0.05 to 0.5% by weight, and more preferably 0.2 to 0.4% by weight of the polish composition. Hydrophobic perfumes give a more preferable effect in terms of improving water repellency. The specific fragrances are as follows. Aldehyde C ₈ ~ C
₂₀ , anisaldehyde, acetal R, acetophenone, acetyl acedrene, adoxal, allyl amyl glycolate, allyl cyclohexane propionate,
Alpha Damascon, Beta Damascon, Delta Damascon, Ambrette lid, Ambroxane, Amyl cinnamic aldehyde, Amyl cinnamic aldehyde dimethyl acetal, Amyl valerianate, Amyl salicylate, Isoamyl acetate, Isoamyl salicylate, Anisaldehyde, Oranthiol, Acetyl eugenol, bagdanol, benzyl acetate,
Benzyl alcohol, benzyl benzoate, benzyl salicylate, bergamyl acetate, bornyl acetate, butyl butyrate, paratertiary butyl cyclohexanol, paratertiary butyl cyclohexyl acetate, benzaldehyde, benzyl formate, caryophyllene, casimeran, cedro amber,
Cedryl acetate, cedrol, celestrid, cinnamic alcohol, cinnamic aldehyde, cis jasmon, citral, citral dimethyl acetal, citrasar, citronellal, citronellol,
Citronellyl acetate, Citronellyl formate,
Citronellyl nitrile, Shikurasetto, cyclamen aldehyde, Shikurapuroppu, Caron, coumarin, cinnamyl acetate, diethyl phthalate, dipropylene glycol, gamma decalactone, delta C ₆ -C ₁₃ lactones, dimethyl benzyl carbinol, dihydrojasmonate, dihydro linalool , Dihydromyrcenol, dimethol, dimyrcetol, diphenyl oxide, ethyl vanillin, eugenol, fluitet, fentyl alcohol, phenylethylphenylacetate,
Garakisoritto, gamma -C ₆ -C ₁₃ lactones, geraniol, geranyl acetate, geranyl formate,
Geranyl nitrile, hedion, helion, heliotropin, cis-3-hexenol, cis-3-hexenyl cetate, hexylcinnamic aldehyde, hexyl salicylate, hyacinth dimethyl acetal,
Hydrotropic alcohol, hydroxycitronellal, hercoline, indole, ionone, isobornyl acetate, isocyclocitral, isoE super, isoeugenol, isononyl acetate, isobutylquinoline, jasmar, jasmolactone, jasmophilane, coabon, Ligtral, Liliar, Lime Oxide, Limonene, Linalool, Linalool Oxide, Linalyl Acetate, Linal, Manzanate, Mayol, Mentha Anneal Acetate, Mensonate, Methyl Anthranilate, Methyl Eugenol, Alpha Methyl Ionone, Beta Methyl Ionone, Gamma Methyl Ion Non, methylisoeugenol,
Methyl lavender ketone, methyl salicylate, mugealdehyde, mugol, musk TM-II, musk 78
1, musk C14, musk T, musk ketone, musk tibetin, musk moskene, miracaldehyde, methylphenylacetate, nerol, neryl acetate,
Nopeel sacetate, Nopeal alcohol, neobergamate, oakmoss No. 1, Oribon, oxyphenylone, para-cresol methyl ether, pentalide,
Phenylethyl alcohol, phenylethyl acetate, alpha pinene, luvafuran, patchon, rose phenone, rose oxide, sandaroa, sandera,
Santarex, Bagdanol, Styralyl Acetate, Styralyl Propionate, Terpineol, Terpinyl Acetate, Tetrahydrolinalol, Tetrahydrolinalyl Acetate, Tetrahydrogeraniol, Tetrahydrogeranyl Acetate, Tonalid, Traseolide, Tripral, Thymol, crocodile, beramos, belldogs, yarayala, acetyleugenol, anise oil, bay oil, boad rose oil, cananga oil, cardamom oil, cassia oil, cedarwood oil,
Orange oil, mandarin oil, tangerine oil, basil oil, nutmeg oil, citronella oil, clove oil, coriander oil, elemi oil, eucalyptus oil, fennel oil, carbam oil, geranium oil, hiba oil, jasmine oil, lavandin oil, lavender oil , Lemon oil, lemongrass oil, lime oil, neroli oil, oak moss oil, okothia oil, orange oil, patchouli oil, peppermint oil, perilla oil, petitgrain oil, pine oil, rose oil, rosemary oil, soy sauce oil, aromatic Oil, clary sage oil, sandalwood oil, spearmint oil, spike lavender oil, star anise oil, thyme oil, tonka beans, turpentine oil, vanilla beans, vetiver oil, ylang ylang oil, grapefruit oil, benzoyl, peruvian balsam, troy balsam, Tuberose oil, Muskkinki, Mosquito Thorium tincture, civet tincture, mention may be made of ambergris tincture. These can be used alone or in combination of two or more.

The composition of the present invention contains an alkali-soluble resin, a defoaming property, a polyvalent metal compound and an ester plasticizer in order to improve the usability of the composition of the present invention such as spreadability, leveling property and peeling property. Agents and the like can be added. Examples of these specific substances include one selected from various silicone compounds, fluorochemical surfactants, carboxylic acid esters such as oleic acid ester, adipic acid ester, azelaic acid ester, and sebacic acid ester, or 2
More than one species can be blended. The blending amount of these is 0.
It is 4 to 2% by weight. In order to improve the storage stability and the like of the composition of the present invention, a preservative, an emulsifier, an ultraviolet absorber,
Ingredients selected from antioxidants and the like can be blended in appropriate amounts according to the purpose. Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. In order to confirm the effect of the composition of the present invention, a test for detergency, gloss and slip resistance was conducted. The specific details of the test and the evaluation criteria are as follows.

1. Detergency test Ten panelists brought back the sample and used it on the floor of each household to compare and use the composition of the present invention and a commercial product.
Evaluation was made at the stage. The detergency was calculated by averaging the results of the scores. When the composition of the present invention was superior to the commercially available product, it was rated as 5, when it was slightly superior, 4, when it was at an equivalent level, 2 when it was slightly inferior, and when it was clearly inferior.

2. Gloss test Based on JISZ8741, a sample was applied to a floor piece at a rate of 15 ml / m ² , a value after sufficiently drying was obtained, and the value was classified into three levels. When the glossiness of the sample is 80 or more, ○ When the glossiness of the sample is 70 or more, Δ When the glossiness of the sample is 60 or more, it is evaluated as ×.

3. Slip resistance test A sample of floor material was applied at a rate of 15 ml / m ² and dried sufficiently, then a surface tester (HEI
The frictional resistance was measured with a DON-14 type), the static friction coefficient was calculated, and classified into the following three stages according to the actual situation. A static friction coefficient of 0.44 or more according to the sample is ◯, a static friction coefficient of less than 0.44 to less than 0.37 is Δ, and a static friction coefficient of the sample is 0.37 or less is x.

Example 1 A composition of the present invention was prepared. The water-insoluble polymer emulsion in the composition is a polyacrylic emulsion manufactured by Rohm & Haas Company, NT2714, and the synthetic wax emulsion is manufactured by Toho Chemical Industry Co., Ltd. polyethylene derivative wax (trade name: Hitech E4B) and polypropylene derivative wax. (Product name: Hitech 433N) was used. The composition was stirred and mixed with a mixer to obtain a milky white uniform emulsion. The composition and the evaluation results are shown in Table 1.

[0015]

[Table 1]

[0016]

[Table 2]

Comparative Examples 1 and 3 As synthetic wax emulsions, a synthetic wax emulsion consisting only of the same polyethylene derivative as in Example 1 and a synthetic wax emulsion consisting only of the same polypropylene derivative as in Example 1 were prepared in the same manner as in Example 1. . The obtained products both had a milky white appearance and had the same detergency and glossiness as compared with the composition of the present invention of Example 1, but in the evaluation of the slip resistance, the products of Comparative Examples 1 and 3 were used. The product was slippery.

Comparative Example 2 A floor cleaning polish composition was prepared by the method of Example 1 in which only the ratio of the synthetic wax emulsion (1) and the synthetic wax emulsion (2) in Table 1 was changed. The resulting product was a milky white uniform emulsion and had the same detergency and gloss as the detersive polish composition of the present invention. However, in the evaluation of the slip resistance, it was evaluated as slippery.

[0019]

EFFECTS OF THE INVENTION The floor cleaning and polishing composition of the present invention has a floor cleaning property and a polishing effect, and can make the floor surface after application not slippery.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification number Office reference number FI technical display location C11D 3/50 C11D 3/50 17/08 17/08 (72) Inventor Masahiro Fukuda Sumida-ku, Tokyo Honjo 1-Chome 3-7 Inside Lion Corporation

Claims (1)

[Claims] 1. A water-insoluble polymer emulsion (A),
(B) polyolefin wax, (C) surfactant,
In a floor cleaning polish composition containing (D) a hydrophilic solvent, (E) a fragrance and (F) water, the polyolefin wax of (B) is polyethylene and / or its derivative and polypropylene and / or its It consists of a mixture of derivatives, and the mixing ratio is 6 when the total wax is 100.
A cleaning and polishing composition for floors, which is in the range of 0:40 to 10:90.