CN101191005A - 一种阻燃抗紫外型abs组合物 - Google Patents
一种阻燃抗紫外型abs组合物 Download PDFInfo
- Publication number
- CN101191005A CN101191005A CNA2006101185636A CN200610118563A CN101191005A CN 101191005 A CN101191005 A CN 101191005A CN A2006101185636 A CNA2006101185636 A CN A2006101185636A CN 200610118563 A CN200610118563 A CN 200610118563A CN 101191005 A CN101191005 A CN 101191005A
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- retardant
- flame retardant
- fire
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- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 239000003063 flame retardant Substances 0.000 claims abstract description 35
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 28
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004611 light stabiliser Substances 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000003112 inhibitor Substances 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 239000012964 benzotriazole Substances 0.000 claims description 5
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
- -1 ABS compound Chemical class 0.000 abstract 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 6
- 230000004075 alteration Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 230000031709 bromination Effects 0.000 description 2
- 238000005893 bromination reaction Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 230000000176 photostabilization Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000009966 trimming Methods 0.000 description 2
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
光照强度 | 0.3W/m2 |
光源 | Xenon arc |
温度 | 55±2℃. |
相对湿度 | 55±5% |
光照时间 | 300hours |
对照例 | 实施例1 | 实施例2 | 实施例3 | ||
基础树脂 | ABS747 | 710 | 710 | 700 | 740 |
主阻燃剂 | 溴化环氧2016 | 170 | 170 | 170 | 170 |
辅助阻燃剂 | 三氧化二锑 | 60 | 60 | 60 | 40 |
增韧剂 | HP4051 | 40 | 40 | 40 | 30 |
光屏蔽剂 | CR826 | 10 | 20 | 10 | |
CR834 | 10 | ||||
光吸收剂 | 327 | 3 | 3 | ||
328 | 3 | 5 | |||
光稳定剂 | 119 | 3 | |||
5050H | 3 | 5 | |||
770 | 3 | ||||
抗氧剂 | 168 | 3 | 2 | 3 | 3 |
抗氧剂 | 245 | 3 | 2 | 3 | 3 |
性能 | 对比例 | 实施例1 | 实施例2 | 实施例3 |
IZOD冲击 | NB | NB | NB | NB |
缺口冲击 | 12 | 10 | 10 | 10 |
阻燃1.6mm | V-0 | V-0 | V-0 | V-0 |
色差200h | 4.51 | 0.68 | 0.85 | 0.75 |
色差300h | 6.82 | 0.72 | 1.02 | 0.85 |
对照例 | 实施例1 | 实施例2 | 实施例3 | ||
基础树脂 | ABS747 | 710 | 710 | 700 | 740 |
主阻燃剂 | 溴化环氧3516 | 170 | 170 | 170 | 170 |
辅助阻燃剂 | 三氧化二锑 | 60 | 60 | 60 | 40 |
增韧剂 | HP4051 | 40 | 40 | 40 | 30 |
光屏蔽剂 | CR826 | 10 | 20 | 10 | |
CR834 | 10 | ||||
光吸收剂 | 327 | 3 | 3 | ||
328 | 3 | 5 | |||
光稳定剂 | 119 | 3 | |||
5050H | 3 | 5 | |||
770 | 3 | ||||
抗氧剂 | 168 | 3 | 2 | 3 | 3 |
抗氧剂 | 245 | 3 | 2 | 3 | 3 |
性能 | 对比例 | 实施例1 | 实施例2 | 实施例3 |
IZOD冲击 | NB | NB | NB | NB |
缺口冲击 | 16 | 15 | 16 | 16 |
阻燃1.6mm | V-0 | V-0 | V-0 | V-0 |
色差200h | 5.53 | 1.62 | 1.15 | 1.04 |
色差300h | 8.87 | 2.02 | 1.50 | 1.24 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2006101185636A CN101191005B (zh) | 2006-11-21 | 2006-11-21 | 一种阻燃抗紫外型abs组合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2006101185636A CN101191005B (zh) | 2006-11-21 | 2006-11-21 | 一种阻燃抗紫外型abs组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101191005A true CN101191005A (zh) | 2008-06-04 |
CN101191005B CN101191005B (zh) | 2012-06-06 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006101185636A Active CN101191005B (zh) | 2006-11-21 | 2006-11-21 | 一种阻燃抗紫外型abs组合物 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101191005B (zh) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101759954A (zh) * | 2010-03-05 | 2010-06-30 | 青岛国恩科技发展有限公司 | 空调风扇材料及制造方法 |
CN101638503B (zh) * | 2008-07-30 | 2011-09-14 | 广东顺威精密塑料股份有限公司 | 一种环保复合阻燃耐候abs |
CN103146133A (zh) * | 2013-04-10 | 2013-06-12 | 苏州旭光聚合物有限公司 | 一种具有抗光老化的纳米TiO2/ABS复合材料及其制备方法 |
CN103819867A (zh) * | 2014-02-19 | 2014-05-28 | 广东美的制冷设备有限公司 | 抗光腐蚀型abs组合物、透光板和空调器 |
CN104559031A (zh) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | 一种阻燃abs材料及其制备方法 |
CN105295287A (zh) * | 2015-10-14 | 2016-02-03 | 佛山市顺德区美的洗涤电器制造有限公司 | 高效阻燃耐候白色abs材料及其制备方法、洗碗机 |
CN108623982A (zh) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | 一种高光泽阻燃智能坐便洁身器专用料及其制备方法 |
CN111534039A (zh) * | 2020-05-18 | 2020-08-14 | 五行科技股份有限公司 | 一种耐候阻燃abs材料及其制备方法 |
CN115322488A (zh) * | 2022-08-11 | 2022-11-11 | 金发科技股份有限公司 | 一种阻燃聚丙烯复合材料及其制备方法和应用 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4011650B2 (ja) * | 1996-06-14 | 2007-11-21 | 大日本印刷株式会社 | バリア−性フィルム、それを使用した積層体および包装用容器 |
TW455603B (en) * | 1996-12-23 | 2001-09-21 | Ciba Sc Holding Ag | Light-stabilised flameproof styrene homopolymers and copolymers |
KR100590718B1 (ko) * | 2004-01-13 | 2006-06-15 | 주식회사 엘지화학 | 열안정성과 내후성이 우수한 고무변성 스티렌 수지 조성물및 그 제조방법 |
CN1290922C (zh) * | 2004-09-09 | 2006-12-20 | 广州金发科技股份有限公司 | 一种无卤阻燃abs类树脂及其制备方法 |
-
2006
- 2006-11-21 CN CN2006101185636A patent/CN101191005B/zh active Active
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101638503B (zh) * | 2008-07-30 | 2011-09-14 | 广东顺威精密塑料股份有限公司 | 一种环保复合阻燃耐候abs |
CN101759954A (zh) * | 2010-03-05 | 2010-06-30 | 青岛国恩科技发展有限公司 | 空调风扇材料及制造方法 |
CN101759954B (zh) * | 2010-03-05 | 2011-06-22 | 青岛国恩科技发展有限公司 | 空调风扇材料及制造方法 |
CN103146133A (zh) * | 2013-04-10 | 2013-06-12 | 苏州旭光聚合物有限公司 | 一种具有抗光老化的纳米TiO2/ABS复合材料及其制备方法 |
CN103819867A (zh) * | 2014-02-19 | 2014-05-28 | 广东美的制冷设备有限公司 | 抗光腐蚀型abs组合物、透光板和空调器 |
CN104559031A (zh) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | 一种阻燃abs材料及其制备方法 |
CN105295287A (zh) * | 2015-10-14 | 2016-02-03 | 佛山市顺德区美的洗涤电器制造有限公司 | 高效阻燃耐候白色abs材料及其制备方法、洗碗机 |
CN108623982A (zh) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | 一种高光泽阻燃智能坐便洁身器专用料及其制备方法 |
CN111534039A (zh) * | 2020-05-18 | 2020-08-14 | 五行科技股份有限公司 | 一种耐候阻燃abs材料及其制备方法 |
CN115322488A (zh) * | 2022-08-11 | 2022-11-11 | 金发科技股份有限公司 | 一种阻燃聚丙烯复合材料及其制备方法和应用 |
CN115322488B (zh) * | 2022-08-11 | 2023-10-31 | 金发科技股份有限公司 | 一种阻燃聚丙烯复合材料及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN101191005B (zh) | 2012-06-06 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SHANGHAI PRET COMPOSITES CO., LTD. Free format text: FORMER NAME: PULIT COMPOSITE MATERIAL CO., LTD., SHANGHAI |
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CP01 | Change in the name or title of a patent holder |
Address after: 200081, building 20, No. 421, Siping Road, Siping Road, Shanghai, Hongkou District, 2 Patentee after: Shanghai Pret Compound Material Co., Ltd. Address before: 200081, building 20, No. 421, Siping Road, Siping Road, Shanghai, Hongkou District, 2 Patentee before: Pulit Composite Material Co., Ltd., Shanghai |
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ASS | Succession or assignment of patent right |
Owner name: CHONGQING PULITE NEW MATERIAL CO., LTD. Effective date: 20131112 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20131112 Address after: 200081, building 20, No. 421, Siping Road, Siping Road, Shanghai, Hongkou District, 2 Patentee after: Shanghai Pret Compound Material Co., Ltd. Patentee after: CHONGQNG PRET NEW MATERIAL CO., LTD. Address before: 200081, building 20, No. 421, Siping Road, Siping Road, Shanghai, Hongkou District, 2 Patentee before: Shanghai Pret Compound Material Co., Ltd. |
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CP03 | Change of name, title or address |
Address after: 402560 Longyun Road, Pulu Industrial Park, Tongliang District, Chongqing Co-patentee after: Shanghai Pret Compound Material Co., Ltd. Patentee after: CHONGQNG PRET NEW MATERIAL CO., LTD. Address before: 200081 2nd Floor, 421 Lane, Siping Road, Hongkou District, Shanghai Co-patentee before: CHONGQNG PRET NEW MATERIAL CO., LTD. Patentee before: Shanghai Pret Compound Material Co., Ltd. |
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CP03 | Change of name, title or address |