CN101142145B - Wear and texture coatings for components used in manufacturing glass light bulbs - Google Patents
Wear and texture coatings for components used in manufacturing glass light bulbs Download PDFInfo
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- CN101142145B CN101142145B CN2006800083718A CN200680008371A CN101142145B CN 101142145 B CN101142145 B CN 101142145B CN 2006800083718 A CN2006800083718 A CN 2006800083718A CN 200680008371 A CN200680008371 A CN 200680008371A CN 101142145 B CN101142145 B CN 101142145B
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- microns
- quench
- molds
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- 238000000576 coating method Methods 0.000 title claims abstract description 127
- 239000011521 glass Substances 0.000 title description 8
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 125
- 239000002245 particle Substances 0.000 claims abstract description 58
- 238000010791 quenching Methods 0.000 claims abstract description 35
- 229910052751 metal Inorganic materials 0.000 claims abstract description 33
- 239000002184 metal Substances 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 39
- 229910002804 graphite Inorganic materials 0.000 claims description 36
- 239000010439 graphite Substances 0.000 claims description 36
- 239000010432 diamond Substances 0.000 claims description 34
- 229910003460 diamond Inorganic materials 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052582 BN Inorganic materials 0.000 claims description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 239000003651 drinking water Substances 0.000 claims description 2
- 235000020188 drinking water Nutrition 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 21
- 239000010410 layer Substances 0.000 description 20
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 9
- 238000007747 plating Methods 0.000 description 9
- 239000007799 cork Substances 0.000 description 8
- 235000019587 texture Nutrition 0.000 description 8
- 230000003628 erosive effect Effects 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000012423 maintenance Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000007772 electroless plating Methods 0.000 description 4
- 239000013528 metallic particle Substances 0.000 description 4
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 3
- 229910001573 adamantine Inorganic materials 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 229930183489 erectone Natural products 0.000 description 3
- 235000019580 granularity Nutrition 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- 238000005844 autocatalytic reaction Methods 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- -1 norbide Chemical compound 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B9/00—Blowing glass; Production of hollow glass articles
- C03B9/12—Blowing glass; Production of hollow glass articles starting from a ribbon of glass; Ribbon machines
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B9/00—Blowing glass; Production of hollow glass articles
- C03B9/30—Details of blowing glass; Use of materials for the moulds
- C03B9/48—Use of materials for the moulds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1651—Two or more layers only obtained by electroless plating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1655—Process features
- C23C18/1662—Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/38—Coating with copper
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
Abstract
The present disclosure relates to a quench mold (22) that includes an interior cavity and a coating (20,21) on the interior cavity. The coating includes a plurality of particles (20) such as metal-coated particles, superabrasive particles or metal particles in a metal matrix.
Description
The cross reference of related application: the application requires the U.S. Provisional Patent Application No.60/662 that submitted on March 16th, 2005,292 right of priority, and comprise by reference described U. S. application.
Background
Use high speed ribbon machine (ribbonmachine) in the modern processing technique for the manufacture of various types of bulbs.On the high speed bulb making machine (bulb making machine) of ribbon machine and similar type, the main region of abrasion or parts are quench molds (quench mold).Although usually there is not significant directly contact between the internal surface of glass and quench molds, hot steam and heat join together to make superficial makings (texture) degeneration (degrade) of described mould.
With considerable time and labor capacity, sacrifice type coating is applied to quench molds.As describing in Figure 1A, mould section 10 can comprise shell (housing) 11 and inner chamber section 12.Internal cross section can comprise one or more hole (vent) 13 and coating, not only to keep moisture but also reduce the adhesion of glass to die cavity.Can make this coating by the exposed steel surface that resin (for example Toenol 1140) is coated onto in mould.When oil was also moistening, (tightlysized) granulated dust cork that can size is strict was sprinkling upon on oil reservoir.Then described oil is allowed to air-dryly, afterwards unnecessary cork is clapped from described coating.Described mould is placed in baking oven and 400
Toasted 3 to 4 hours.The coating that produces is very coarse and (convoluted) texture of height fold, has and is of value to the large surface-area of keeping or keeping water.Figure 1B and 1C amplify respectively 15 times and 150 times of Photomicrographs that illustrate the described prior art coating on bulb quench mold.
Although the cork coating of prior art plays a role well, in the continuous production on ribbon machine, such coating can only continue 2 to 5 days usually.
Some problems during the disclosure that this paper comprises is intended to address the above problem at least.
Summary of the invention
In embodiments, the disclosure relates to a kind of quench molds, and described quench molds can comprise inner chamber and the coating on described inner chamber, and wherein said coating can comprise the particle of a plurality of metallic cover.In embodiments, described particle can comprise that superabrasive particles and described metal can comprise titanium, chromium, nickel, cobalt, copper, tantalum, iron or silver.In embodiments, described particle can comprise graphite granule.In various embodiments, the particle of described metallic cover can also coat with superabrasive material.In further embodiment, described particle can comprise that graphite and described metal with superabrasive coating material can comprise copper or nickel.Described coating can have approximately 50 microns to the about total thickness of 500 microns, and can keep the water of certain volume, the glassware for drinking water of described certain volume have every cubic millimeter of coating approximately 40 cubic millimeters to the about volume of 90 cubic millimeters.
In interchangeable embodiment, described coating can comprise a plurality of superabrasive particles in metallic matrix.Described superabrasive particles can have approximately 0.1 micron to the about diameter of 1.0 microns, and described metallic matrix can comprise nickel, chromium, copper, cobalt or its alloy.Described coating can have approximately 50 microns to the about thickness of 500 microns.In another embodiment, described coating can comprise a plurality of metallic particles in metallic matrix.Described particle comprises copper, steel, brass, bronze or cobalt.
Description of drawings
This patent or application documents comprise at least one secondary with the colored accompanying drawing of drawing.Should ask and after paying essential expense, official will provide this patent with color drawings or the copy of patent application.
Figure 1A illustrates exemplary glass light bulb quench mold.
Figure 1B amplifies the Photomicrograph of 15 times of diagram prior art coating.
Fig. 1 C amplifies the Photomicrograph of 150 times of diagram prior art coating.
Fig. 2 illustrates the exemplary elements (element) of various coating of the present disclosure.
Fig. 3 illustrates the exemplary elements of interchangeable coating of the present disclosure.
Fig. 4 illustrates the 3rd embodiment of coating of the present disclosure.
Fig. 5 illustrates the 4th embodiment of coating of the present disclosure.
Fig. 6 illustrates the 5th embodiment of coating of the present disclosure.
Fig. 7 illustrates the initial water maintenance dose of various coating.
Fig. 8 illustrates the microgram of the diamond coating of titanium coating of the present disclosure.
The microgram of compound, nickel-graphite particle coating that coat of the present disclosure when Fig. 9 diagram is applied to die surface (mold set surface).
The microgram of compound, nickel-graphite particle coating that coat of the present disclosure when Figure 10 diagram is applied to the die surface of texture.
Figure 11 illustrates the microgram of nickel-graphite coating of the present invention.
Figure 12 illustrates the microgram of compound, the nickel-graphite particle coating that coats of the present disclosure.
Embodiment
Superabrasive material is anyly to have greater than approximately 3000 kilograms/cubic millimeter or alternatively greater than the about material of Vickers' hardness of 3200 kilograms/cubic millimeter.In various embodiments, we have found that some parts that superabrasive matrix material (for example using those materials of diamond or cubic boron nitride (cBN)) is applied in the glass bulb complete processing can reduce abrasion, shut-down maintenance (maintenance shutdown) and total cost of production when the tolerance by more effectively keeping critical equipment (tolerance) improves energy efficiency.Particularly, we have found that diamond or cBN matrix material can provide lasting and erosion resistant coating, described coating can keep high water yield level for for example bulb quench mold.This can allow to coat quench molds with lasting coating, and this can allow quench molds to play more consistent and more permanent effect in the bulb manufacturing processed.This paper describes that the composite coating (including but not limited to the superabrasive coating) of several types is to provide the component capabilities of improvement., based on the disclosure, those skilled in the art will recognize that and can also use other superabrasive coating.
, as represented in Fig. 2, in the first embodiment, can use the method for electroless plating or electrolysis will comprise that the layer of diamond and/or cBN particle 20 and metal 21 is plated on the internal surface of quench molds 22.Described coating can be that highly abrasion-resistant damages, and can form smooth surface, can anti-ly corrode, and not only heat conduction but also conduct electricity.For example in U.S. Patent No. 4,997, suitable method for plating has been described in general manner in 686 and No.5,145,517, the disclosure of above-mentioned two pieces of each patents is included as a whole in this article by reference.Because described coating can be applied to structured material (for example steel, reinforced composite, pottery or plastics), so can reduce the bust in use.Due to improved wear resistance, erosion resistance and erosion resistance that described coating is given, part life can extend.The diameter thickness (diameter thickness) that the layer of described diamond or cBN can have the mean sizes that is equal to or greater than a superabrasive particles, and described metal can include but not limited to nickel, chromium, cobalt or copper or its alloy.The average particle size particle size of the superabrasive particles of using in the scope of maximum outside diameter from approximately 0.1 micron to 50 microns, perhaps alternatively in the scope of diameter from approximately 0.25 micron to approximately 1.0 microns.Other sizes are possible.In various embodiments, preferred (although being optional) coating thickness scope can be from approximately 50 microns to approximately 500 microns, perhaps from 100 microns to approximately 200 microns.
As represented in Fig. 3, in the second embodiment, can use electroless plating or electrolysis method for coating with the copper in continuous metal matrix 31 or other metallic particles 30 the layer codeposition (co-deposit) on quench molds 32.This coating can highly abrasion-resistant damages, and can form the surface of coarse and fold, can anti-ly corrode, and not only heat conduction but also conduct electricity, and can keep the surface-moisture of a great deal of.Because described coating can be applied to structured material (for example steel, reinforced composite, pottery or plastics), so can reduce the bust in use.Due to improved wear resistance, erosion resistance and erosion resistance that described coating is given, part life can extend.But may not extend to the same with the life-span of the similar coating that uses diamond particles long.This softer coating may be still hard than cork, but it can make glass component not be exposed to the diamond that may cause potentially minute scratch marks.The metallic particles layer can include but not limited to copper, steel, brass, bronze or cobalt, and described metallic particles layer can have the thickness of at least one particle.The continuous metal matrix can include but not limited to nickel or copper.The same with the first embodiment, in the second embodiment, preferred (but optional) size range can be from approximately 0.1 micron to approximately 50 microns, perhaps from approximately 0.25 micron to approximately 1.0 microns.Preferably (but optional) coating thickness scope can be from approximately 50 microns to 500 microns, perhaps from approximately 100 microns to approximately 200 microns.
As represented in Fig. 4, in the 3rd embodiment, the method that can use electroless plating or electrolysis is plated to the layer of in metallic matrix 41, diamond metallic cover or cBN particle 40 on the internal surface of quench molds 42.Lip-deep metal cover 43 at diamond or cBN particle 40 can allow coating layer of the present disclosure to obtain the function of expectation, described metal cover 43 can include but not limited to titanium, chromium, nickel, cobalt, copper, tantalum, iron, silver or its combination, perhaps is a plurality of layers that consist of any materials in above-mentioned materials.The layer of described coating can have the thickness greater than a superabrasive particles, and metallic matrix can include but not limited to nickel or copper.For example, the layer thickness of preferred (but optional) granularity and coating can be described similar with the first and second embodiments for top.The lip-deep metal cover of superabrasive particles can coat or can not coat the whole surface of each particle.Preferably, the maximum ga(u)ge that has of described metal cover is less than the maximum diameter of superabrasive particles.
, as represented in Fig. 5, in the 4th embodiment, can use the layer of the graphite granule 50 of metallic cover to coat quench molds inner chamber 51.Can apply described layer to quench molds 51 by thermospray (thermal spray) technique.Those skilled in the art will understand and can apply this layer with other technique.In addition, the metal cover on particle 52 can include but not limited to nickel or copper.The bed of graphite particles of the metallic cover of applying in this technology can be relative porous and short texture (open-structure), and can keep the water of a great deal of.In some embodiments, the size range of graphite granule 50 can be from approximately 10 microns to approximately 500 microns.In another embodiment, can obtain the particle 50 of from 50 to 150 microns of size ranges.Other granularities are possible.This granular layer can have approximately 0.001 inch to the about thickness between 0.050 inch.Replacedly, this granular layer can have approximately 0.1 micron to approximately 500 microns, approximately 50 microns to approximately 500 microns, approximately 100 microns to the about total thickness of 200 microns or other appropriate sizes.The weight percent of metal and graphite can be about about 15% the graphite of 85% metal pair.In interchangeable embodiment, the weight percent of metal and graphite can be respectively approximately 60% and approximately 40%.Interchangeable scope can comprise approximately approximately 25% graphite of 75% metal pair, perhaps about about 20% the graphite of 80% metal pair.Other solid lubricants are (as hexagonal boron nitride (hBN), talcum, MoS
2Or other materials) can be used for substituting graphite.Except the porous attribute of metal-graphite coating, can also provide the non-wetted surface of opposing molten glass with the graphite granule of coating.This character can prevent that molten glass from adhering to described coating before quenching.
As represented in Fig. 6, in the 5th embodiment, the layer of metal-graphite particle 60 as above can comprise the coating 61 of extra superabrasive material (for example diamond or cubic boron nitride).Described extra coating 61 can be applied in quench molds 63 with reinforcement metal-graphite coating 62 and improve wear resistance.The composite coating 61 that adds this metal-graphite coating 62 to can be thin, is for example approximately 1 micron to approximately 25 microns, perhaps approximately 2 microns to approximately 10 microns, thus the Integrate porous of metal-graphite coating 62 and water hold facility can significantly not reduce.Because metal-graphite coating 62 can have short texture, so alternatively, this extra coating 61 can coat the metal-graphite coating 62 of all exposures equably.Compound outer covering layer (overcoat) 61 can also improve the adhesivity between metal-graphite coating 62 and relevant graphite granule 60.
In use carried out the compound coating method of codeposition grit (for example superabrasive or silicon carbide, norbide, aluminum oxide or other particles) without electrochemical process (electroless chemistry), the described particle without electrochemical process that is suspended for wherein said particle may be inertia.For example, the diamond particles that is suspended in electroless plating bath may not be autocatalysis the nickel in being dissolved in solution, and nickel may not can be deposited on adamantine surface.When the codeposition of nickel and diamond particles occurred in this case, the composite bed of generation may be uniformly, and the substrate (substrate) that may conformal (conform to) in this coating, be applied to.For example, if with comprising that granularity is that approximately composite coating clad surface roughness (roughness) Ra of diamond particles of 8 microns is the about steel plate of 0.1 micron, the surfaceness of the coating that produces of plating may be approximately 0.8 micron like this.
Yet when metal level was deposited on superabrasive particles or graphite granule surface, this layer may become autocatalysis to the nickel in plating bath or other coating metals.Can use chemical vapour deposition (CVD) and/or physical vapor deposition (PVD) technology with the veneer of titanium and/or chromium on described diamond or cBN particle.Alternatively, the coating on each particle can comprise less than 50% of each particle overall diameter.In each embodiment, coating thickness can be less than approximately 20%, 10%, 5% or even 1% of total particle size.Those skilled in the art will understand can use other technologies.In this case, when interpolation comprised the particulate of metal cover (for example titanium or chromium) in plating bath, the surface-area of described metal cover may be used for the surface-area of described bath stable operation significantly greater than normal recommended.When thereby described bath was suitably driven self-catalyzed deposition from described plating solution generation metal, the metal in solution started to carry out plating with two-forty, is mainly due to the large surface-area that can be coated to the metal on particle.The particle of metallic cover can be captured on the substrate surface that just is being wrapped by, but owing to consuming rapidly metal from plating solution, so coating layer can form rapidly, and the tubercle (nodule) that can have the form that much constructs cork and resin surface.The surface characteristic of this coating that produces can have the approximately surfaceness of 40 microns, the about peak valley height of 250 microns, and the about average peak valley distance of 200 microns, and can have the ability that keeps surface-moisture.Each value, the deviation of +/-50% is possible in these values.Although other sizes are possible, the total thickness of composite coating can approximately 200 arrive the approximately order of magnitude of 500 microns in this case, and this composite coating is thicker than the composite coating made from the particle that does not have metal cover.Also noteworthy is that, the diameter of the tubercle feature that the fast decoupled by plating bath forms can for approximately 50 microns to the about order of magnitude of 300 microns.Other sizes are possible.
, because metal cover adheres to described mould substrate, so being highly abrasion-resistant, damages described composite coating.Described coating can be applied to the structured material such as steel, reinforced composite, pottery or plastics, and therefore can reduce the bust in use.Due to improved wear resistance, erosion resistance and erosion resistance that described coating is given, part life can extend.
The coating of describing herein can provide suitable porousness and water preserving property.For example, in some embodiments, in will being immersed in water with the quench molds of coating after, these goods with coating can keep the water of certain volume, the volume of the water of described maintenance reaches approximately 0.4 cubic millimeter to approximately 0.9 cubic millimeter of every cubic millimeter of coating.
Embodiment
The major function of bulb quench mold is to keep moisture for the surface at coating and hole.The efficiency of quench molds is directly proportional with the water yield that can remain in coating.Develop a kind of technology and measured the moisture maintenance dose of the coating on the steel sheet of using composite diamond coating (CDC) to coat.Carry out a series of lab investigation, wherein used CDC-8, CDC-15, CDC-Ti (as described in more detail below) and above mentioned cork coating to coat the steel plate of several little (2 inches * 3 inches).
Having used based on the patent No. is 6 as the multiple technologies of the United States Patent (USP) of RE33767 and use in the patent No., 306, the technology of describing in 466 United States Patent (USP) with CDC-8 ,-15 and-the Ti coating is applied on described steel plate, the disclosure of above-mentioned United States Patent (USP) is incorporated herein by reference.The CDC-8 coating is made by 8 micron diamond particles in the electroless nickel phosphorous matrix, and the thickness of this coating is roughly 0.002 inch.The CDC-15 coating is made by 15 micron diamond particles in the electroless nickel phosphorous matrix, and the thickness of this coating is roughly 0.002 inch.The CDC-Ti coating is made by 8 micron diamond particles in the electroless nickel phosphorous matrix, have the titanium coating on described adamantine skin, and the thickness of this composite coating is greater than 0.004 inch.
Embodiment 1Cork/resin board is weighed on balance, and tare weight is corrected for zero, then is dipped into water with common level height in a beaker of water.Unnecessary water is shaken off, and described plate is weighed immediately and recorded the weight of the moisture that keeps.Then described plate is allowed to erect one minute in vertical position and then be weighed.A series of setting and weighing operation are repeated seven minutes.Can find out as the result from Fig. 7, the cork coating for the standard coating that uses in quench molds has kept 0.48 gram water a few days ago.
Embodiment 2Plate coats with the composite diamond coating that 8 micron diamonds (CDC-8) and 15 microns (CDC-15) diamonds are made, and weigh on balance and tare weight is corrected for zero, then is dipped into water with common level height in a beaker of water.Unnecessary water is shaken off, and described plate is weighed immediately and recorded the weight of the moisture that keeps.Then described plate is allowed to erect one minute in vertical position and then be weighed.A series of setting and weighing operation are repeated seven minutes.Can find out as the result from Fig. 7, comprise the adamantine composite diamond coating of CDC-8 and CDC-15 on described plate and kept approximately 0.10 gram water.
Embodiment 3The plate that the composite diamond coating that 8 micron diamonds that coat in order to thin titanium layer (titanium content is determined as 30% weight) are made coats is weighed on balance and tare weight is corrected for zero, then is dipped into water with common level height in a beaker of water.Unnecessary water is shaken off, and described plate is weighed immediately and recorded the weight of the moisture that keeps.Then described plate is allowed to erect one minute in vertical position and then be weighed.A series of setting and weighing operation are repeated seven minutes.Fig. 8 illustrates the microgram of the diamond coating of titanium coating of the present disclosure.Can find out as the result from Fig. 7, the composite diamond coating with diamond particles (CDC-Ti) that titanium coats has kept approximately 0.26 gram water.
Embodiment 4In the belt glass formation machine of the full scale production for the manufacture of conventional incandescent-lamp bulb (full-scale production), master unit interested and that test is bulb quench mold.In test, from the stock of the large similar mould (mold) for a large amount of standard lamps, obtain two new dies.This test comprises the composite diamond coating is put on a mould.This coating is so that roughly 40% diamond volume density and the thickness of 0.001 inch (25 microns) utilize 8 micron diamonds.For another mould, the internal surface of mould at first by laser sculpture to give texture like the texture classes with existing sacrifice type coating.After this mould is carved, applied the similar composite diamond coating that uses in the first mould.For mould 1 produce surperficial shown in Figure 9, and surperficial shown in Figure 10 for mould 2 generations.
Embodiment 5Coat steel plate with the nickel-graphite coating.Before coating, with the surface of alcohol wash plate to remove any surperficial grease, then with the described plate plate of #30 aluminum oxidation powder sandblasting face to produce surfaceness.With 0.002 inch basic unit that applies Metco 450 thermospray coating roughly, with in conjunction with this nickel-graphite layer.The nickel-graphite powder that uses is can be from the 307NS of Sulzer Metco with the commercial system acquisition.Apply this powder with 5P type spray gun, described 5P type spray gun uses oxy-acetylene gas with the system parameter that Sulzer Metco recommends.Described nickel-graphite layer applies with 0.004 inch and 0.015 inch.Figure 11 is the microgram of the nickel-graphite coating on steel plate.Carry out water and keep test on this nickel-graphite plate, and measured the total Water that keeps in described coating.As shown in Figure 7, a side is wrapped by the water yield that the steel plate of (thermospray) keeps and is roughly 0.72 gram.
Embodiment 6Further process by the composite coating that applies as described in Example 2 the steel plate that is obtained from embodiment 5.Composite coating in this embodiment uses 2 micron diamond particles in the electroless nickel plating matrix.Approximately 10 microns of the thickness of described coating.As can see from Figure 12, diamond, graphite granule and Ni substrate are high-visible.Also having carried out water on this plate and other test panels from before embodiment keeps and wear testing.Water keeps the result (TS+CDC) shown in Figure 7 of test, can see that wherein this plate has kept the approximately water of 0.38 gram.
Although the disclosure provides a large amount of details with reference to some preferred embodiment of the present invention, other variants are possible.Therefore, the spirit and scope of appended claims should not be restricted to description and the preferred version that comprises in this specification sheets.
Claims (11)
1. quench molds comprises:
Inner chamber; And
Lip-deep coating at described inner chamber; wherein said coating comprises the bed of graphite particles of metallic cover; the bed of graphite particles of wherein said metallic cover also comprises that superabrasive material coating and described superabrasive material are diamond particles or cubic boron nitride particle, and the bed of graphite particles that wherein has a described metallic cover of described superabrasive material coating has porous loose structure.
2. quench molds as claimed in claim 1, wherein the lip-deep described coating at described inner chamber also comprises metallic matrix.
3. quench molds as claimed in claim 1, wherein said metal comprise metal cover or its a plurality of layers of titanium, chromium, nickel, cobalt, copper, tantalum, iron, silver or its combination.
4. quench molds as claimed in claim 1, wherein keep the water of certain volume at the lip-deep coating of described inner chamber, the glassware for drinking water of described certain volume has the volume of 0.4 cubic millimeter to 0.9 cubic millimeter of every cubic millimeter of coating.
5. quench molds as claimed in claim 3, wherein said metal cover comprises copper or nickel.
6. quench molds as claimed in claim 2, wherein, described metallic matrix comprises nickel, chromium, copper, cobalt or its alloy.
7. quench molds as claimed in claim 1, wherein, have the total thickness of 50 microns to 500 microns at the lip-deep coating of described inner chamber.
8. quench molds as claimed in claim 1, wherein said particle form 10% weight of described coating to 80% weight.
9. quench molds as claimed in claim 1, wherein additional described superabrasive material coating has the thickness of 1 micron to 25 microns.
10. quench molds as claimed in claim 3, wherein said metal cover form 60% weight of bed of graphite particles of described metallic cover to 80% weight.
11. quench molds as claimed in claim 3, wherein said metal cover has the thickness of 200 microns to 500 microns.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66229205P | 2005-03-16 | 2005-03-16 | |
| US60/662,292 | 2005-03-16 | ||
| PCT/US2006/009479 WO2006101956A1 (en) | 2005-03-16 | 2006-03-16 | Wear and texture coatings for components used in manufacturing glass light bulbs |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101142145A CN101142145A (en) | 2008-03-12 |
| CN101142145B true CN101142145B (en) | 2013-11-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2006800083718A Expired - Fee Related CN101142145B (en) | 2005-03-16 | 2006-03-16 | Wear and texture coatings for components used in manufacturing glass light bulbs |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1858814A1 (en) |
| CN (1) | CN101142145B (en) |
| BR (1) | BRPI0609821A2 (en) |
| WO (1) | WO2006101956A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7562858B2 (en) * | 2005-03-16 | 2009-07-21 | Diamond Innovations, Inc. | Wear and texture coatings for components used in manufacturing glass light bulbs |
| CN106119763B (en) * | 2016-08-19 | 2019-04-02 | 富耐克超硬材料股份有限公司 | Superhard composite coating layer cutter and preparation method thereof |
| CN106086760B (en) * | 2016-08-19 | 2019-04-02 | 富耐克超硬材料股份有限公司 | Wear-resisting composite coating and its preparation method and application |
| CN106591760B (en) * | 2016-12-26 | 2019-04-02 | 富耐克超硬材料股份有限公司 | Wear-resisting composite spraying micro mist and wear-resisting composite coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB835673A (en) * | 1957-09-16 | 1960-05-25 | Owens Illinois Glass Co | Improvements in or relating to the molding and finishing of hollow glass articles |
| GB1333055A (en) * | 1971-10-05 | 1973-10-10 | Glass Bulbs Ltd | Moulds for forming hollow glass articles |
| EP1010674A2 (en) * | 1998-12-14 | 2000-06-21 | Praxair S.T. Technology, Inc. | Release coating for glass molds |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2039879A (en) * | 1979-01-16 | 1980-08-20 | United Glass Ltd | Shaping glassware |
| JPH0735259B2 (en) * | 1986-10-14 | 1995-04-19 | 東洋製罐株式会社 | Mold for glass molding |
| JPH10330122A (en) * | 1997-05-27 | 1998-12-15 | Asahi Glass Co Ltd | Mold for glass molding |
| WO2004094685A2 (en) * | 2003-04-22 | 2004-11-04 | Diamond Innovations, Inc. | Method to provide wear-resistant coating and related coated articles |
-
2006
- 2006-03-16 BR BRPI0609821-5A patent/BRPI0609821A2/en not_active IP Right Cessation
- 2006-03-16 CN CN2006800083718A patent/CN101142145B/en not_active Expired - Fee Related
- 2006-03-16 WO PCT/US2006/009479 patent/WO2006101956A1/en active Application Filing
- 2006-03-16 EP EP06738531A patent/EP1858814A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB835673A (en) * | 1957-09-16 | 1960-05-25 | Owens Illinois Glass Co | Improvements in or relating to the molding and finishing of hollow glass articles |
| GB1333055A (en) * | 1971-10-05 | 1973-10-10 | Glass Bulbs Ltd | Moulds for forming hollow glass articles |
| EP1010674A2 (en) * | 1998-12-14 | 2000-06-21 | Praxair S.T. Technology, Inc. | Release coating for glass molds |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0609821A2 (en) | 2010-04-27 |
| EP1858814A1 (en) | 2007-11-28 |
| WO2006101956A1 (en) | 2006-09-28 |
| CN101142145A (en) | 2008-03-12 |
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