CN101121305B - Reproduced stone preparing method - Google Patents
Reproduced stone preparing method Download PDFInfo
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- CN101121305B CN101121305B CN2006100892413A CN200610089241A CN101121305B CN 101121305 B CN101121305 B CN 101121305B CN 2006100892413 A CN2006100892413 A CN 2006100892413A CN 200610089241 A CN200610089241 A CN 200610089241A CN 101121305 B CN101121305 B CN 101121305B
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- gypsum
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Abstract
The present invention discloses a building material product and the manufacturing method, in particular to an agglomerated stone and the manufacturing method. The structure of the agglomerated stone comprises a color sand decorative layer, a structural solidification layer and a strutting piece layer; the inside of the color sand decorative layer is laid with the structural solidification layer and the structural solidification layer is used for solidifying the agglomerated stone chip; the strutting piece layer is equipped in the structural solidification layer and the strutting piece is used for implementing overall solidification of the agglomerated stone chip. The present invention solves the defects that the traditional method needs great weight; the temperature condition requirement is high; the quality is coarse and the color is singular; the product is prone to deforming and bearing; the present invention boasts of being waterproof, acid and alkali resistant and corrosion resistant; in addition, the present invention has great capability against blown sand; the present invention will cause no pollution, no radiation and can make full use of and recycle resources.
Description
Technical field:
The invention belongs to a kind of building material product and preparation method thereof, relate in particular to a kind of agglomerated stone and manufacture method thereof that is used for landscape constructions such as sculpture for city.
Background technology:
Along with to the improving constantly of landscaping and environmental requirement, in sculpture for city, view and building decoration, used increasing various ornament materials, as lithotome, sandstone, agglomerated stone or the like.These ornament materials not only will be considered the abundant and texture of form and color as much as possible near the natural stone goods, and what is more important will be in conjunction with corrosion-resistant, pollution-free and make full use of the outer loop characteristics of resources.
In existing agglomerated stone technology, mainly exist technical problem to be:
1, existing technology adopts benzene plate analogue formation; Employing cement is adhesive, because the characteristic of cement itself causes increase the hardening time of product, life cycle of the product is prolonged.
2, adopt the content of resin low in the existing agglomerated stone decorative layer raw material, often below 20, because low toughness and the less robust that often causes product of the content of resin, easily crisp and insecure, bonding force is poor, impact resistance is low, and often product is very thick and heavy, and product weight is big, very difficult carrying and increased the burden of building foundation.
3, the granularity of the stone flour that existing agglomerated stone is selected is big, adopts 20-60 purpose stone flour more, directly causes on color and the texture gap with lithotome to increase.
4, in decorative layer was made, prior art adopts monochromatic stone flour to make to turn over made behind the finished product colouring or adds mill base or natural stone-powder dyes in resin, and it is stiff also to make on agglomerated stone color and the texture, forms certain difference with lithotome.
5, in the surface treatment of agglomerated stone, prior art often adopts polishing to carry out surface treatment, and efficient promptly consuming time is low, and texture and color are inhomogeneous simultaneously.
6, in production, other agglomerated stones often have requirement to temperature, generally have steam-cured process, to being manufactured with certain requirement, the execution conditions height.
7, product quality is heavy and since the product thickness of existing agglomerated stone generally 20 millimeters to more than 50 millimeters, so weight is big, has increased the burden of building and increased the burden of building foundation.
To sum up, need a kind of agglomerated stone of research and development to overcome the technical problem that exists on the prior art.
Summary of the invention:
According to the technical problem that exists in the prior art, the present invention has researched and developed a kind of agglomerated stone, no matter is on products material, or has all overcome problems of the prior art in the preparation of product operation, has reached good technique effect.
Technical scheme of the present invention is:
Agglomerated stone is a sandwich construction, comprises successively: color sand decorative layer 1, structural strengthening layer 2 and support member layer 3; Be equipped with structural strengthening layer 2 in described color sand decorative layer 1 inboard, described structural strengthening layer 2 is used for reinforcing and reproduces flag; Described support member is arranged on described structural strengthening layer 2 inboard for 3 layers, and described support member 3 is used for carrying out integral body and taking solid reproducing flag.
In order to make agglomerated stone firm in structure, be provided with color sand in color sand architectural surface 4 inboards of described color sand decorative layer 1 and decorate thickening layer 5, promptly spray again or apply one to three layer of color sand in order to thickening surface layer 4 in architectural surface 4 back; Comprise structure pulling force layer 6 in the described structural strengthening layer 2, pulling force layer 6 is meant in thickening layer 5 backs and adds one deck that resin is laid with glass fabric that its effect is the pulling force that increases finished product.
In order to realize the technical scheme of above-mentioned agglomerated stone, the preparation method of described agglomerated stone comprises:
A) agglomerated stone pattern making procedure:
I. formpiston is made: the sculpture clay formpiston of making agglomerated stone of sculpture clay; The manufacturing process of concrete formpiston is as follows: at first rise and fall in proportion with making sculpture skeletons and fixing solid such as reinforcing bar, iron wire, timber according to design size and moulding, it is outer and hit tight with flitch to be paved with skeleton with sculpture clay then, progressively makes details with instruments such as sculpture knifes then.
Ii. formpiston turns over system: according to the form of above-mentioned sculpture clay formpiston, turn over system gypsum formpiston with gypsum; Concrete formpiston duplicating is as follows: at first water and land plaster mix (in 1: 1 ratio), rise and fall according to moulding then the calcium plaster of becoming reconciled is coated onto the sculpture clay male mold surfaces with the even bullet of hand and reaches certain thickness (about 1-4 centimetre), treat that gypsum solidifies the mahjong flitch of using the calcium plaster of becoming reconciled in the back fully and is connected with the gypsum former to reinforce plaster mold, then the sculpture clay formpiston is dug out and cleans gypsum former and water and land plaster (about 4: 6) and repair bubble and the flaw that produces because of the system of turning over, the calcium plaster of taking advantage of wet water and land plaster (about 1: 1) then and will becoming reconciled is coated onto the gypsum female mold surfaces with the even bullet of hand and reaches certain thickness (about 1-4 centimetre) and treats after gypsum solidifies fully the gypsum former to be knocked out reservation gypsum formpiston with the woodcarving cutter, repairs details at last.
Iii. the silicon rubber former is made: according to above-mentioned gypsum formpiston, turn over silicon rubber and to make the silicon rubber former; Silicon rubber former manufacturing process is as follows: at first be stained with silicon rubber liquid with the clean oil paintbrush then and evenly be applied to the gypsum male mold surfaces and treat to brush after ground floor solidifies one deck again and brush the pulling force that can add grid cloth in the middle of the layer 2-4 and increase silicon rubber so repeatedly and make the protection cover die to protect silicon rubber mould indeformable outside the silica gel mould with gypsum or fiberglass then the gypsum formpiston is fixing.
B) color sand decorative layer production process:
I. color sand decorative layer feedstock production: natural colour sand, unsaturated-resin, catalyst, curing agent, auxiliary agent and filler are uniformly mixed in proportion, be made into the mixed material of color sand decorative layer;
Ii. color sand decorative layer applies: with the mixed material spraying of color sand decorative layer or brush active surface at described silicon rubber former (1-3 all over) repeatedly; The thickness of brushing is 0.5 centimetre-1.5 centimetres;
Iii. color sand decorative layer solidifies: after coating procedure finished, the flag that reproduces that needs to include color sand decorative layer left standstill curing;
C) structural strengthening layer and support member layer production process:
I. laying structure back-up coat: evenly whole closely being laid on of glass fabric applied the reproducing on the flag of color sand decorative layer;
Ii. fastening structure back-up coat: after unsaturated-resin, curing agent and catalyst evenly stirred, be coated on the glass fabric, and be pressed into the glass fabric impregnated with resin and conformal is adjacent to brush;
Iii. repeat step I in the c operation and ii1-3 time;
Iv. bonding support member layer: the glass fabric of support member with impregnated with resin is bonded on the structural strengthening layer of agglomerated stone; Described support member is angle steel or flitch.
D) agglomerated stone finished product stripping process: after treating above-mentioned each layer curing, agglomerated stone finished product and silicon rubber former are broken away from.
In order to reach the purpose that improves toughness of products and robustness, improve the color and the texture effect of product simultaneously, the material described in the color sand decorative layer feedstock production in above-mentioned steps b is unsaturated polyester resin, 40 orders-120 purpose natural colour sand, cobalt naphthenate, methyl ethyl ketone peroxide, auxiliary agent, filler;
And the mixed proportion of each mixture is (by ratio of weight and the number of copies):
Unsaturated polyester resin 30-40
Natural colour sand: 50-60
Cobalt naphthenate: 2-9
Methyl ethyl ketone peroxide: 2-5
Auxiliary agent: 1-3
Filler: 1-3
Concrete described unsaturated polyester resin is unsaturated polyester resin 191 or unsaturated polyester resin 196 in above-mentioned, and auxiliary agent is aluminium hydroxide or tributyl phosphate, and filler is light-storing material such as fluorescent material or toner;
And the optimum ratio of each mixture is (by ratio of weight and the number of copies) in color sand decorative layer feedstock production:
Unsaturated polyester resin 196:35
80 orders-120 order natural colour sand: 55
Cobalt naphthenate: 3
Methyl ethyl ketone peroxide: 3
Auxiliary agent: 2
Filler: 2.
In order to improve the quality of product, described preparation method also comprises:
E) integer operation: the agglomerated stone product after the demoulding is repaired through side cut, method for repairing and mending.
Product surface rest and reorganization efficient is hanged down and the problem of weak effect in order to solve, and described preparation method also comprises:
F) sandblast operation: quartz sand evenly is injected in the good finished surface of trimming with mechanical means.
In order to make the product surface cleaning, described preparation method also comprises:
G) matting: with the contaminant removal of finished surface.
The present invention utilizes sculpture clay and gypsum to make formpiston, has replaced the benzene plate, makes product hard not yielding.In addition, replacing cement employing resin is adhesive, makes shorten the hardening time of product, and life cycle of the product is shortened.The present invention adopts the content of resin at 30-40, has improved the toughness and the robustness of product greatly, and bonding force is big, and impact resistance is strong, and product weight alleviates greatly simultaneously.The granularity of the stone flour that the present invention is selected is little, adopts 80-120 purpose stone flour more, makes that the gap with lithotome is very little on color and the texture.In decorative layer was made, the present invention was directly with natural colour sand and a small amount of toner toning, also made nature on agglomerated stone color and the texture, to lithotome and similar.In the surface treatment of agglomerated stone, the present invention adopts sandblast to carry out surface treatment, and texture and color are even.In production, other agglomerated stones often have requirement to temperature, generally have steam-cured process, to being manufactured with certain requirement, the execution conditions height.Product of the present invention above zero all can solidify, and execution conditions require low.Lighter in weight, since the product thickness of existing agglomerated stone generally 20 millimeters to more than 50 millimeters, product thickness of the present invention is at 5 millimeters to 10 millimeters, because product rear portion sticking glass fabric and steel structure, so have the high lightweight characteristics of intensity, alleviated the burden of building.
Description of drawings:
Fig. 1 is the cross-sectional view of product.
Fig. 2 is this production process chart.
Below in conjunction with concrete embodiment each accompanying drawing is described.
The specific embodiment:
Fig. 1 is the cross-sectional view of product.
Agglomerated stone is a sandwich construction, comprises successively: color sand decorative layer 1, structural strengthening layer 2 and support member layer 3; Be equipped with structural strengthening layer 2 in described color sand decorative layer 1 inboard, described structural strengthening layer 2 is used for reinforcing and reproduces flag; Described support member is arranged on described structural strengthening layer 2 inboard for 3 layers, and described support member 3 is used for carrying out integral body and taking solid reproducing flag.
In order to make agglomerated stone firm in structure, be provided with color sand in color sand architectural surface 4 inboards of described color sand decorative layer 1 and decorate thickening layer 5, promptly spray again or apply one to three layer of color sand in order to thickening surface layer 4 in architectural surface 4 back; Comprise structure pulling force layer 6 in the described structural strengthening layer 2, pulling force layer 6 is meant in thickening layer 5 backs and adds one deck that resin is laid with glass fabric that its effect is the pulling force that increases finished product.
Fig. 2 is this production process chart.
The preparation method of described agglomerated stone comprises:
A) agglomerated stone pattern making procedure:
I. formpiston is made: the sculpture clay formpiston of making agglomerated stone of sculpture clay; The manufacturing process of concrete formpiston is as follows: at first rise and fall in proportion with making sculpture skeletons and fixing solid such as reinforcing bar, iron wire, timber according to design size and moulding, it is outer and hit tight with flitch to be paved with skeleton with sculpture clay then, progressively makes details with instruments such as sculpture knifes then.
Ii. formpiston turns over system: according to the form of above-mentioned sculpture clay formpiston, turn over system gypsum formpiston with gypsum; Concrete formpiston duplicating is as follows: at first water and land plaster mix (in 1: 1 ratio), rise and fall according to moulding then the calcium plaster of becoming reconciled is coated onto the sculpture clay male mold surfaces with the even bullet of hand and reaches certain thickness (about 1-4 centimetre), after treating that gypsum solidifies fully, mahjong flitch with the calcium plaster of becoming reconciled is connected with the gypsum former to reinforce plaster mold, then the sculpture clay formpiston is dug out and cleans gypsum former and water and land plaster (about 4: 6) and repair bubble and the flaw that produces because of the system of turning over, the calcium plaster of taking advantage of wet water and land plaster (about 1: 1) then and will becoming reconciled is coated onto the gypsum female mold surfaces with the even bullet of hand and reaches certain thickness (about 1-4 centimetre) and treats after gypsum solidifies fully the gypsum former to be knocked out reservation gypsum formpiston with the woodcarving cutter, repairs details at last.
Iii. the silicon rubber former is made: according to above-mentioned gypsum formpiston, turn over silicon rubber and to make the silicon rubber former; Silicon rubber former manufacturing process is as follows: at first be stained with silicon rubber liquid with the clean oil paintbrush then and evenly be applied to the gypsum male mold surfaces and treat to brush after ground floor solidifies one deck again and brush the pulling force that can add grid cloth in the middle of the layer 2-4 and increase silicon rubber so repeatedly and make the protection cover die to protect silicon rubber mould indeformable outside the silica gel mould with gypsum or fiberglass then the gypsum formpiston is fixing.
B) color sand decorative layer production process:
I. color sand decorative layer feedstock production: natural colour sand, unsaturated-resin, catalyst, curing agent, auxiliary agent and filler are uniformly mixed in proportion, be made into the mixed material of color sand decorative layer;
Ii. color sand decorative layer applies: with the mixed material spraying of color sand decorative layer or brush active surface at described silicon rubber former (1-3 all over) repeatedly; The thickness of brushing is 0.5 centimetre-1.5 centimetres;
Iii. color sand decorative layer solidifies: after coating procedure finished, the flag that reproduces that needs to include color sand decorative layer left standstill curing;
C) structural strengthening layer and support member layer production process:
I. laying structure back-up coat: evenly whole closely being laid on of glass fabric applied the reproducing on the flag of color sand decorative layer;
Ii. fastening structure back-up coat: after unsaturated-resin, curing agent and catalyst evenly stirred, be coated on the glass fabric, and be pressed into the glass fabric impregnated with resin and conformal is adjacent to brush;
Iii. repeat step I in the c operation and ii1-3 time;
Iv. bonding support member layer: the glass fabric of support member with impregnated with resin is bonded on the structural strengthening layer of agglomerated stone; Described support member is angle steel or flitch.
D) agglomerated stone finished product stripping process: after treating above-mentioned each layer curing, agglomerated stone finished product and silicon rubber former are broken away from.
E) integer operation: the agglomerated stone product after the demoulding is repaired through side cut, method for repairing and mending.
F) sandblast operation: quartz sand evenly is injected in the good finished surface of trimming with mechanical means.
G) matting: with the contaminant removal of finished surface.
In order to reach the purpose that improves toughness of products and robustness, improve the color and the texture effect of product simultaneously, the material described in the color sand decorative layer feedstock production in above-mentioned steps b is unsaturated polyester resin 191 or unsaturated polyester resin 196,40 order-120 purpose natural colour sands, cobalt naphthenate, methyl ethyl ketone peroxide, auxiliary agent, filler; Described auxiliary agent is aluminium hydroxide or tributyl phosphate, and filler is light-storing material such as fluorescent material or toner; This product recycles rate in order to improve product, and described natural colour sand can be replaced by agglomerated stone and pulverize building stones.
And the mixed proportion of each mixture is (by ratio of weight and the number of copies):
Unsaturated polyester resin 196:35
80 orders-120 order natural colour sand: 55
Cobalt naphthenate: 3
Methyl ethyl ketone peroxide: 3
Auxiliary agent: 2
Filler: 2.
Claims (7)
1. the preparation method of an agglomerated stone, it is characterized in that: the preparation method of described agglomerated stone comprises:
A) agglomerated stone pattern making procedure:
I. formpiston is made: the sculpture clay formpiston of making agglomerated stone of sculpture clay;
Ii. formpiston turns over system: according to the form of above-mentioned sculpture clay formpiston, turn over system gypsum formpiston with gypsum;
Iii. the silicon rubber former is made: according to above-mentioned gypsum formpiston, turn over silicon rubber and to make the silicon rubber former;
B) color sand decorative layer production process:
I. color sand decorative layer feedstock production: natural colour sand, unsaturated polyester resin, cobalt naphthenate, methyl ethyl ketone peroxide, auxiliary agent and filler are uniformly mixed in proportion, be made into the mixed material of color sand decorative layer, wherein auxiliary agent is aluminium hydroxide or tributyl phosphate, and filler is a light-storing material;
Ii. color sand decorative layer applies: with the mixed material spraying or the brushing repeatedly of color sand decorative layer;
Iii. color sand decorative layer solidifies: after coating procedure finished, the flag that reproduces that needs to include color sand decorative layer left standstill curing;
C) structural strengthening layer and support member layer production process:
I. laying structure back-up coat: evenly whole closely being laid on of glass fabric applied the reproducing on the flag of color sand decorative layer;
Ii. fastening structure back-up coat: after unsaturated-resin, curing agent and catalyst evenly stirred, be coated on the glass fabric, and be pressed into the glass fabric impregnated with resin and conformal is adjacent to brush;
Iii. repeat step I in the c operation and ii1-3 time;
Iv. bonding support member layer: the glass fabric of support member with impregnated with resin is bonded on the structural strengthening layer of agglomerated stone;
D) agglomerated stone finished product stripping process: after treating above-mentioned each layer curing, agglomerated stone finished product and silicon rubber former are broken away from.
2. the preparation method of a kind of agglomerated stone according to claim 1 is characterized in that:
In described agglomerated stone pattern making procedure
I. the manufacturing process of described formpiston is as follows: at first rise and fall in proportion with reinforcing bar or iron wire or timber making sculpture skeleton and fixing solid according to design size and moulding, it is outer and hit tight with flitch to be paved with skeleton with sculpture clay then, progressively makes details with instruments such as sculpture knifes then;
Ii. the formpiston duplicating is as follows: at first water and land plaster mix in 1: 1 ratio, rise and fall according to moulding then the calcium plaster of becoming reconciled is coated onto the sculpture clay male mold surfaces and reaches certain thickness with the even bullet of hand: 1-4 centimetre, treat that gypsum solidifies the mahjong flitch of using the calcium plaster of becoming reconciled in the back fully and is connected with the gypsum former to reinforce plaster mold, the sculpture clay formpiston being dug out and cleans gypsum former and water and land plaster ratio then is 4: 6; Repair the bubble and the flaw that produce because of the system of turning over, taking advantage of wet water and land plaster ratio then is 1: 1; And the calcium plaster that will become reconciled to be coated onto the gypsum female mold surfaces and to reach certain thickness with the even bullet of hand be 1-4 centimetre; Treat after gypsum solidifies fully the gypsum former to be knocked out reservation gypsum formpiston with the woodcarving cutter, repair details at last;
Iii. silicon rubber former manufacturing process is as follows: at first be stained with silicon rubber liquid with brush then and evenly be applied to the gypsum male mold surfaces and treat to brush after ground floor solidifies one deck again and brush the pulling force that can add grid cloth in the middle of the layer 2-4 and increase silicon rubber so repeatedly to make the protection cover die with gypsum or fiberglass outside the silica gel mould then indeformable with the protection silicon rubber mould the gypsum formpiston is fixing;
In the color sand decorative layer coating step in the color sand decorative layer of described b production process: the mixed material of color sand decorative layer is brushed repeatedly at described silicon rubber former active surface 1-3 time; The thickness of brushing is 1 centimetre-1.5 centimetres;
Described support member is angle steel or flitch.
3. the preparation method of a kind of agglomerated stone according to claim 1, it is characterized in that: the material described in the color sand decorative layer feedstock production in above-mentioned steps b is that unsaturated polyester resin, 40 orders-120 purpose natural colour sand, cobalt naphthenate, methyl ethyl ketone peroxide, auxiliary agent are aluminium hydroxide or tributyl phosphate, and filler is a light-storing material; And the mixed proportion of each mixture is by ratio of weight and the number of copies:
Unsaturated polyester resin 30-40
Natural colour sand: 50-60
Cobalt naphthenate: 2-9
Methyl ethyl ketone peroxide: 2-5
Aluminium hydroxide or tributyl phosphate: 1-3
Light-storing material: 1-3.
4. the preparation method of a kind of agglomerated stone according to claim 3, it is characterized in that: described unsaturated polyester resin is unsaturated polyester resin 191 or 196; The described auxiliary agent of unsaturated polyester resin is aluminium hydroxide or tributyl phosphate, and light-storing material is fluorescent material or toner; And the proportioning of each mixture is by ratio of weight and the number of copies in color sand decorative layer feedstock production:
Unsaturated polyester resin 196:35
80 orders-120 order natural colour sand: 55
Cobalt naphthenate: 3
Methyl ethyl ketone peroxide: 3
Aluminium hydroxide or tributyl phosphate: 2
Fluorescent material or toner: 2.
5. the preparation method of a kind of agglomerated stone according to claim 1, it is characterized in that: described preparation method also comprises:
E) integer operation: the agglomerated stone product after the demoulding is repaired through side cut, method for repairing and mending.
6. the preparation method of a kind of agglomerated stone according to claim 5, it is characterized in that: described preparation method also comprises:
F) sandblast operation: evenly spray the good finished surface of hair trimming with quartz sand with mechanical means.
7. the preparation method of a kind of agglomerated stone according to claim 6, it is characterized in that: described preparation method also comprises:
G) matting: with the contaminant removal of finished surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100892413A CN101121305B (en) | 2006-08-11 | 2006-08-11 | Reproduced stone preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100892413A CN101121305B (en) | 2006-08-11 | 2006-08-11 | Reproduced stone preparing method |
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| Publication Number | Publication Date |
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| CN101121305A CN101121305A (en) | 2008-02-13 |
| CN101121305B true CN101121305B (en) | 2010-08-04 |
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| CN2006100892413A Expired - Fee Related CN101121305B (en) | 2006-08-11 | 2006-08-11 | Reproduced stone preparing method |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102775094B (en) * | 2012-05-08 | 2017-11-07 | 冯春承 | A kind of production method of submount material |
| CN103895441A (en) * | 2014-04-18 | 2014-07-02 | 上海浦宇铜艺装饰制品有限公司 | Novel urban sculpture casting process |
| CN104589217A (en) * | 2014-12-31 | 2015-05-06 | 广州市新尚雕塑工艺品有限公司 | Surface effect treatment method of stone sculpture imitation products |
| CN107383885A (en) * | 2017-08-02 | 2017-11-24 | 江苏特福特建材有限公司 | A kind of Milan watt and its production method |
| CN111421990A (en) * | 2020-04-26 | 2020-07-17 | 桂林匠心雅石工艺品有限公司 | Artificial plastic-steel ceramic landscape stone and manufacturing method and application thereof |
| CN114804783A (en) * | 2022-05-25 | 2022-07-29 | 厦门海投建材有限公司 | High-strength concrete and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2180455Y (en) * | 1993-11-24 | 1994-10-26 | 罗光健 | Multi-purpose luxury high-intensity decoration plate |
| CN2281907Y (en) * | 1996-10-11 | 1998-05-20 | 段志勇 | Prefabricated decorative plate imitating natural stone dull digged mark |
| CN200957679Y (en) * | 2006-08-11 | 2007-10-10 | 马珺 | Artificial stone |
-
2006
- 2006-08-11 CN CN2006100892413A patent/CN101121305B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2180455Y (en) * | 1993-11-24 | 1994-10-26 | 罗光健 | Multi-purpose luxury high-intensity decoration plate |
| CN2281907Y (en) * | 1996-10-11 | 1998-05-20 | 段志勇 | Prefabricated decorative plate imitating natural stone dull digged mark |
| CN200957679Y (en) * | 2006-08-11 | 2007-10-10 | 马珺 | Artificial stone |
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| CN101121305A (en) | 2008-02-13 |
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