CN101111964A - Fuel cell generator - Google Patents

Abstract

A fuel cell power generation device using a hydrogen producing device that is capable of supplying hydrogen easily to a fuel cell, capable of producing hydrogen-containing gas continuously at low temperature, and not requiring large energy. A fuel cell power generation device at least has a fuel cell (30) for generating electric power by hydrogen and oxidizing agent supplied to the cell and a hydrogen producing device (10) for producing hydrogen-containing gas to be supplied to the fuel cell (30). The hydrogen producing device (10) is a device for producing the hydrogen-containing gas by decomposition of organic matter-containing fuel and having a partition film (11), a fuel electrode (12) provided on one side of the partition film (11), a means for supplying fuel containing the organic matters and water to the fuel electrode (12), an oxidizing electrode (14) provided on the other side of the partition film (11), a means for supplying the oxidizing agent to the oxidizing electrode (14), and a means for causing the hydrogen-containing gas to be produced from the fuel electrode (12) side and taking out the gas.

Description

Fuel cell power generating system

Technical field

The present invention relates to and the combined fuel cell power generating system of apparatus for reforming of fuel (hydrogen producing apparatus), particularly the improving technology of the hydrogen producing apparatus that uses in the fuel cell power generating system of box fuel cell power generating system etc.

Background technology

In recent years, consider environmental problem, there is motion to propose to have made up the Blast Furnace Top Gas Recovery Turbine Unit (TRT) (supply unit) of fuel cell, when using such fuel cell power generating system as moving with power supply or on-the-spot when using power supply, for the ease of carrying and installation, use a kind of fuel cell power generating system of box, this device be with each machine that constitutes Blast Furnace Top Gas Recovery Turbine Unit (TRT) integrated and in be loaded in the metal packing casing and form.For example, this fuel cell power generating system, when using hydrocarbon based fuel such as town gas as crude fuel, be used to be restructured as based on the apparatus for reforming of fuel of the fuel of hydrogen by in be contained in the packing casing (Cell).In packing casing (Cell), in addition, the interior direct current of having adorned fuel cell main body, fuel cell being produced changes the Aided Machine classes (for example with reference to patent documentation 1～5) such as pump, air blast of the power inverter of power supply output pattern, the control device of all controlling, and setting with fuel cell relevant into.

Patent documentation 1: Japanese kokai publication hei 5-290868 communique

Patent documentation 2: Japanese kokai publication hei 10-284105 communique

Patent documentation 3: TOHKEMY 2002-170591 communique

Patent documentation 4: TOHKEMY 2003-217635 communique

Patent documentation 5: TOHKEMY 2003-297409 communique

Apparatus for reforming of fuel becomes device, CO remover etc. by reformer, CO usually and constitutes, and fills the catalyst of regulation in these machines respectively, and these catalyst all need to make it at high temperature to bring into play the heating of effect.Therefore, in reformer, also burner to be set, when starting by the burner combustion crude fuel, with the catalyzer temperature-elevating to 650 in the reformer～700 ℃.Perhaps, be accompanied by the intensification of reformer, CO becomes device, CO and goes out the catalyst of device and also slowly heat up, but because the reformed gas instability when starting, therefore direct fueling battery and deliver to PG burner burn (paragraph of patent documentation 5 [0003]).

On the other hand, because control device is made of a plurality of electronic units, therefore must avoid suffering the high heat that produces from apparatus for reforming of fuel.For this reason, developed such technology, as the technology that thermal insulation board is set patent documentation 1 and 3, as coming the technology of cooling controller etc., influence as patent documentation 4 and 5 to dispose technology of control device etc. carrying out forced ventilation by hair-dryer or ventilation fan in the casing patent documentation 1 and 2 for heat that apparatus for reforming of fuel does not take place between apparatus for reforming of fuel and control device.

As mentioned above, the problem that exists when the apparatus for reforming of fuel that uses in the past is in order to prevent this thermal impact, must adopt various measures.

In addition, as the box fuel cell power generating system that does not use the high-temperature fuel reformer, known have steel cylinder of will fill hydrogen bearing alloy (storage hydrogen steel cylinder) and a fuel cell integrated Blast Furnace Top Gas Recovery Turbine Unit (TRT) (for example referring to patent documentation 6 and 7).

Patent documentation 6: Japanese kokai publication hei 6-60894 communique

Patent documentation 7: Japanese kokai publication hei 10-92456 communique

Patent documentation 6 and 7 fuel cell power generating system, although be used to prevent the various devices of thermal impact when not needing to use apparatus for reforming of fuel in the past, but because the dispose procedure of the hydrogen of hydrogen bearing alloy is the endothermic reaction, therefore, when supplying with hydrogen fuel, the temperature of hydrogen bearing alloy descends, the releasability that is accompanied by the hydrogen of decrease of temperature hydrogen bearing alloy also descends, therefore, in order to ensure the flow of sufficient hydrogen, the thermal steering that fuel cell main body produced need be added thermal hydrogen storage alloy to storage hydrogen steel cylinder, in addition, owing to used steel cylinder, also had the limited problem of generating dutation.

In addition, known also have by electrochemical reaction produce the invention (with reference to patent documentation 8,10) of method of hydrogen and the invention (with reference to patent documentation 9～11) that utilizes the fuel cell of the hydrogen that produces by electrochemical method.

Patent documentation 8: No. 3328993 communique of Japan's special permission

Patent documentation 9: No. 3360349 communique of Japan's special permission

Patent documentation 10: United States Patent (USP) the 6th, 299, No. 744 specifications, the 6th, 368, No. 492 specifications of United States Patent (USP), the 6th, 432, No. 284 specifications of United States Patent (USP), the 6th, 533, No. 919 specifications of United States Patent (USP), No. 2003/0226763 communique of U.S. Patent Publication

Patent documentation 11: TOHKEMY 2001-297779 communique

In above-mentioned patent documentation 8, put down in writing following invention (claim 1): " hydrogen production method; it is characterized by; on cation-exchange membrane two faces in opposite directions, pair of electrodes is set; make the fuel that contains the first alcohol and water at least contact the electrode that contains catalyst that is arranged on the face; to derive electronics by described pair of electrodes is applied voltage from described electrode; on described electrode, carry out by described methyl alcohol and the hydrionic reaction of water generates, on the electrode that is provided with on another face on a described cation-exchange membrane opposite in opposite directions, the described hydrogen ion that will produce by the supply electronics changes hydrogen molecule into ".In addition, also disclose: supply with water or steam to fuel simultaneously with electrode and the methyl alcohol that acts as a fuel, connect external circuit and apply voltage and derive electronics with electrode, thereby carry out CH with electrode at fuel from fuel ₃OH+2H ₂O → CO ₂+ 6e ^-+ 6H ⁺Reaction, make consequent hydrogen ion by cation-exchange membrane, pass through 6H in electrode side in opposite directions ⁺+ 6e ^-→ 3H ₂And selectivity generates hydrogen (paragraph [0033]～[0038]).And then, in patent documentation 9, put down in writing the invention (paragraph [0052]～[0056]) that utilizes the fuel cell of the hydrogen that produces by this method.

According to patent documentation 8 and 9 inventions of being put down in writing, can under low temperature, produce hydrogen (paragraph [0080] of the paragraph of patent documentation 8 [0042], patent documentation 9), but must apply voltage in order to produce hydrogen, in addition, the generation of hydrogen is in the in opposite directions electrode side of fuel with electrode (fuel electrodes), do not supply with oxidant to electrode in opposite directions, thus obviously different with the employed hydrogen producing apparatus of fuel cell power generating system of the present invention.

The invention of record is also same with above-mentioned patent documentation 8 and 9 inventions of being put down in writing in the above-mentioned patent documentation 10, its proton that is the anode 112 at the utmost point that acts as a fuel generates sees through barrier film 110, produce hydrogen at negative electrode 114 as counterelectrode, but its with fuel very anode, be negative electrode and apply voltage with the counterelectrode by DC power supply 120, organic substance fuel such as electrolysis methyl alcohol, and the generation of hydrogen is the counterelectrode side in fuel electrodes, do not supply with oxidant to counterelectrode, thus obviously different with the employed hydrogen producing apparatus of fuel cell power generating system of the present invention.

Put down in writing in the above-mentioned patent documentation 11 the hydrogen generation utmost point (claim 1) that produces hydrogen has been set in fuel cell system, also put down in writing and " supplied with the liquid fuel that contains alcohol and water to porous electrode (fuel electrodes) 1; to gas-diffusion electrode (oxidizing agent pole) 2 air supplies of opposition side; when between the terminal of the terminal of porous electrode 1 and gas-diffusion electrode 2, keeping load; from the positive pole of MEA2 with common fuel cell function is that gas-diffusion electrode 2 applies positive potential by load to porous electrode 1, thereby can form such electrical connection.Consequently alcohol generates carbon dioxide and hydrogen ion with the water reaction, and the hydrogen ion of generation produces hydrogen through dielectric substrate 5 on the gas-diffusion electrode 6 of central authorities.On gas-diffusion electrode 6, reacting with the interface generating electrodes of another dielectric substrate 7, form hydrogen ion once again and in dielectric substrate 7, move arrival gas-diffusion electrode 2.On gas-diffusion electrode 2, generate water with the reaction of airborne oxygen " (paragraph [0007]); thereby; patent documentation 11 is to utilize the electric energy that is produced by fuel cell to produce the utmost point (gas-diffusion electrode 6) at hydrogen to produce hydrogen; again with its fueling battery; and; in the generation of hydrogen is this point of counterelectrode side in fuel electrodes, identical with above-mentioned patent documentation 8～10.

In addition, also known have a following invention: adopt the reaction unit with barrier film that clips proton-conductive films (ion-conducting material) and formed anode (electrode A) and negative electrode (electrode B), by applying or not applying voltage, the perhaps method (with reference to patent documentation 12 and 13) of when deriving electric energy, coming oxidation alcohol (methyl alcohol), but all being about using the technology (product be carbonic diester, formalin, methyl formate, dimethoxymethane etc.) of electrochemical cell with pure oxidation, is not by the technology of alcohol generation as the hydrogen of reduzate.

Patent documentation 12: Japanese kokai publication hei 6-73582 communique (claim 1～3, paragraph [0050])

Patent documentation 13: Japanese kokai publication hei 6-73583 communique ( claim 1,8, paragraph [0006])

Summary of the invention

Problem of the present invention is to address the above problem, provide a kind of the use easily to supply with hydrogen to fuel cell, can make hydrogen-containing gas continuously at low temperature, and not need the fuel cell power generating systems such as box (box self-contained type) fuel cell power generating system of the hydrogen producing apparatus of a large amount of electric energy.

In order to solve above-mentioned problem, adopted following scheme among the present invention.

(1) a kind of fuel cell power generating system, it is characterized by, it possesses at least by supplying with the fuel cell that hydrogen and oxidant generate electricity, and the hydrogen producing apparatus of making the hydrogen-containing gas be used to supply with above-mentioned fuel cell, described hydrogen producing apparatus is to contain the device that organic fuel is made hydrogen-containing gas by decomposition, and it has barrier film, the fuel electrodes that on a face of above-mentioned barrier film, is provided with, supply with the device of the fuel that contains organic substance and water to described fuel electrodes, the oxidation utmost point that on the another side of described barrier film, is provided with, supply with the device of oxidant to the described oxidation utmost point, produce hydrogen-containing gas and with the device of its derivation from the fuel electrodes side.

(2) a kind of fuel cell power generating system, it is characterized by, its in casing at least in the fuel cell that generates electricity by supply hydrogen and oxidant of dress, manufacturing is used to supply with the hydrogen producing apparatus of the hydrogen-containing gas of above-mentioned fuel cell, the direct current that fuel cell is sent is converted to the power inverter of regulation electric power and the fuel cell power generating system of control device that whole Blast Furnace Top Gas Recovery Turbine Unit (TRT) are controlled, described hydrogen producing apparatus is to contain the device that organic fuel is made hydrogen-containing gas by decomposition, and it has barrier film, the fuel electrodes that on a face of above-mentioned barrier film, is provided with, supply with the device of the fuel that contains organic substance and water to described fuel electrodes, the oxidation utmost point that on the another side of described barrier film, is provided with, supply with the device of oxidant to the described oxidation utmost point, produce the device of hydrogen-containing gas and derivation from the fuel electrodes side.

(3) as the fuel cell power generating system of above-mentioned (1) or (2), it is characterized by, described hydrogen producing apparatus is not have from the hydrogen manufacturing battery that constitutes hydrogen producing apparatus to derive the device of electric energy and make the open circuit that battery applies the device of electric energy by the outside to described hydrogen to the outside.

(4) as the fuel cell power generating system of above-mentioned (1) or (2), it is characterized by, described hydrogen producing apparatus have with described fuel very negative pole, with described oxidation very anodal derive the device of electric energy to the outside.

(5) as the fuel cell power generating system of above-mentioned (1) or (2), it is characterized by, described hydrogen producing apparatus have with described fuel very negative electrode, with described oxidation very anode apply the device of electric energy by the outside.

(6) as the fuel cell power generating system of above-mentioned (1) or (2), it is characterized by, be used in combination the two or more hydrogen producing apparatus of selecting by in following three kinds of hydrogen producing apparatus: do not have and make battery from the hydrogen that constitutes hydrogen producing apparatus and derive the device of electric energy and make the hydrogen producing apparatus of open circuit that battery applies the device of electric energy to described hydrogen by the outside to the outside, have with described fuel negative pole very, with described oxidation very anodal derive the hydrogen producing apparatus of the device of electric energy to the outside, and have with described fuel negative electrode very, with described oxidation very anode apply the hydrogen producing apparatus of the device of electric energy by the outside.

(7) as the fuel cell power generating system of above-mentioned (1) or (2), it is characterized by, the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 200～1000mV.

(8) as the fuel cell power generating system of above-mentioned (3), it is characterized by, the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 300～800mV.

(9) as the fuel cell power generating system of above-mentioned (4), it is characterized by, the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 200～600mV.

(10) as the fuel cell power generating system of above-mentioned (4) or (9), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the electric energy of adjusting described derivation.

(11) as the fuel cell power generating system of above-mentioned (5), it is characterized by, the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 300～1000mV.

(12) as the fuel cell power generating system of above-mentioned (5) or (11), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described electric energy that applies.

(13) as each fuel cell power generating system of above-mentioned (1)～(12), it is characterized by, in the described hydrogen producing apparatus, adjust the generating capacity of described hydrogen-containing gas by adjusting voltage between the described fuel electrodes and the described oxidation utmost point.

(14) as each fuel cell power generating system of above-mentioned (1)～(13), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the quantity delivered of adjusting described oxidant.

(15) as each fuel cell power generating system of above-mentioned (1)～(14), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the concentration of adjusting described oxidant.

(16) as each fuel cell power generating system of above-mentioned (1)～(15), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described quantity delivered that contains the fuel of organic substance and water.

(17) as each fuel cell power generating system of above-mentioned (1)～(16), it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described concentration that contains the fuel of organic substance and water.

(18) as each fuel cell power generating system of above-mentioned (1)～(17), it is characterized by, the operating temperature of described hydrogen producing apparatus is smaller or equal to 100 ℃.

(19) as the fuel cell power generating system of above-mentioned (18), it is characterized by, described operating temperature is 30～90 ℃.

(20) as each fuel cell power generating system of above-mentioned (1)～(19), it is characterized by, supply with the one or more kinds of organic substances of described organic substance for from alcohol, aldehyde, carboxylic acid and ether, selecting of the fuel electrodes of described hydrogen producing apparatus.

(21) as the fuel cell power generating system of above-mentioned (20), it is characterized by, described alcohol is methyl alcohol.

(22) as each fuel cell power generating system of above-mentioned (1)～(21), it is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is oxygen-containing gas or oxygen.

(23) as the fuel cell power generating system of above-mentioned (22), it is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is the air exhaust that described fuel cell or other described hydrogen producing apparatus are discharged.

(24) as each fuel cell power generating system of above-mentioned (1)～(21), it is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is the liquid that contains hydrogen peroxide.

(25) as each fuel cell power generating system of above-mentioned (1)～(24), it is characterized by, the barrier film of described hydrogen producing apparatus is the proton conductive solid electrolyte film.

(26) as the fuel cell power generating system of above-mentioned (25), it is characterized by, described proton conductive solid electrolyte film is that perfluorocarbon sulfonic acid is a solid electrolyte film.

(27) as each fuel cell power generating system of above-mentioned (1)～(26), it is characterized by, the catalyst of the fuel electrodes of described hydrogen producing apparatus is the catalyst that has supported the Pt-Ru alloy on carbon dust.

(28) as each fuel cell power generating system of above-mentioned (1)～(27), it is characterized by, the catalyst of the oxidation utmost point of described hydrogen producing apparatus is the catalyst that has supported Pt on carbon dust.

(29) as each fuel cell power generating system of above-mentioned (1)～(28), it is characterized by, described hydrogen producing apparatus has the fuel electrodes barrier film that is provided with the stream ditch that is used for mobile described fuel and is provided with the oxidation utmost point barrier film of the stream ditch that is used for mobile described oxidant.

(30) as the fuel cell power generating system of above-mentioned (29), it is characterized by, the two the stream ditch of the fuel electrodes barrier film of described hydrogen producing apparatus and oxidation utmost point barrier film that is crisscross arranged makes that the ridge part (offering part) beyond the stream ditch of stream ditch and described oxidation utmost point barrier film of described fuel electrodes barrier film is relative to small part.

(31) as each fuel cell power generating system of above-mentioned (1)～(28), it is characterized by, described hydrogen producing apparatus has the oxidant barrier film of the stream ditch that is provided with the described oxidant that is used for flowing, and does not have the fuel electrodes barrier film.

(32) as each fuel cell power generating system of above-mentioned (1)～(31), it is characterized by, the described circulating device that contains the fuel of organic substance and water is set on described hydrogen producing apparatus.

(33) as each fuel cell power generating system of above-mentioned (1)～(32), it is characterized by, on described hydrogen producing apparatus, be provided for absorbing the carbon dioxide absorption portion of the carbon dioxide that is included in the described hydrogen-containing gas.

(34) as each fuel cell power generating system of above-mentioned (1)～(33), it is characterized by, do not cool off the described hydrogen-containing gas that produces by described hydrogen producing apparatus and supply with described fuel cell.

(35) as each fuel cell power generating system of above-mentioned (1)～(34), it is characterized by, be not provided for blocking the heat-insulating material of the heat that described hydrogen producing apparatus sends.

At this, the hydrogen producing apparatus that uses in the fuel cell power generating system of above-mentioned (3)～(5), the device with fueling and oxidant, this device can use pump, hair-dryer etc.In addition, the situation in above-mentioned (4) has the discharge control device that is used for making from hydrogen battery derivation electric energy; Situation in above-mentioned (5) has the electrolysis unit that is used for applying to hydrogen manufacturing battery electric energy.Situation in above-mentioned (3), it is not have to be used for making the open-circuit condition that battery is derived the discharge control device of electric energy and is used for applying to hydrogen manufacturing battery the electrolysis unit of electric energy from hydrogen.And employed hydrogen producing apparatus comprises the hydrogen producing apparatus that uses in the fuel cell power generating system of above-mentioned (3)～(5) in the box fuel cell power generating system of the fuel cell power generating system of above-mentioned (1) and above-mentioned (2).These hydrogen producing apparatus can make up two with on use.And then, the electric energy (situations of above-mentioned (5)) that these hydrogen producing apparatus can be controlled the quantity delivered of fuel and oxidant or the electric energy of concentration and derivation (situations of above-mentioned (4)) or apply by the growing amount that monitoring hydrogen is made the voltage (open circuit voltage or running voltage) of battery and/or hydrogen-containing gas.Here, the basic structure that constitutes the hydrogen manufacturing battery of hydrogen producing apparatus is, have and fuel electrodes is set on a face of barrier film is used for structure, and the structure that the oxidation utmost point is used for supplying with to the above-mentioned oxidation utmost point oxidant is set on another face of above-mentioned barrier film to above-mentioned fuel electrodes fueling.

Fuel cell power generating system of the present invention; since used can from room temperature to smaller or equal to 100 ℃ of such hydrogen producing apparatus of comparing fuel reforming under the significantly reduced temperature with reforming temperature in the past; therefore not only can shorten the needed time that starts; can also reduce the energy that is used to improve the reformer temperature; can not need to be used for to block the heat-insulating material of the heat that reformer produces; particularly; no longer need to be used for the control device of interior dress in the casing is carried out special devices the such as heat-insulating material of heat protection; and the hydrogen-containing gas that does not need hydrogen producing apparatus is produced cools off fueling battery easily.

In addition, owing to do not contain CO in the hydrogen-containing gas that hydrogen producing apparatus produced, so do not need CO to remove device.

In addition, the employed hydrogen producing apparatus of fuel cell power generating system of the present invention is not made the battery supply of electrical energy from the outside to hydrogen and can be produced hydrogen, even under the situation with the device of deriving electric energy, under situation, also can produce hydrogen with the device that applies electric energy from the outside.

Under situation,, therefore, remarkable from the angle effect of effective use of energy sources because this electric energy can be used for auxiliary machineries such as driving pump, hair-dryer etc. with the device of deriving electric energy.

Even under situation with the device that applies electric energy from the outside, supply with a spot of electric energy by making battery to hydrogen from the outside, also can realize producing quite or surpassing the effect of the hydrogen of the electric energy that drops into.

And then, for any situation, make the voltage of battery and/or the growing amount of hydrogen-containing gas by monitoring hydrogen, can carry out technology controlling and process, owing to can realize the densification of hydrogen producing apparatus, therefore can realize reducing the effect of fuel cell power generating system manufacturing cost.

Description of drawings

Fig. 1 (a) is the schematic diagram of an example of the structure of expression box fuel cell power generating system of the present invention.

Fig. 1 (b) is the schematic diagram of the relation of expression hydrogen producing apparatus of box fuel cell power generating system of the present invention and fuel cell.

Fig. 2 is the skeleton diagram that the hydrogen among the embodiment 1 is made battery (not from outside supply of electrical energy).

Fig. 3 is the figure (hydrogen Production Example 1-1) of the relation of the following air mass flow of expression different temperatures (30～70 ℃) and hydrogen formation speed and open circuit voltage.

Fig. 4 is the figure (hydrogen Production Example 1-1) of the relation of following open circuit voltage of expression different temperatures (30～70 ℃) and hydrogen formation speed.

Fig. 5 is the figure (hydrogen Production Example 1-2) of the relation (70 ℃ of temperature) of air mass flow and hydrogen formation speed and open circuit voltage under the different fuel flow rate of expression.

Fig. 6 is the figure (hydrogen Production Example 1-2) of the relation (70 ℃ of temperature) of open circuit voltage and hydrogen formation speed under the different fuel flow rate of expression.

Fig. 7 is the figure (hydrogen Production Example 1-3) of the relation (70 ℃ of temperature) of air mass flow and hydrogen formation speed and open circuit voltage under the different fuel concentration of expression.

Fig. 8 is the figure (hydrogen Production Example 1-3) of the relation (70 ℃ of temperature) of open circuit voltage and hydrogen formation speed under the different fuel concentration of expression.

The figure (hydrogen Production Example 1-4) of the relation of air mass flow and hydrogen formation speed and open circuit voltage when Fig. 9 is the dielectric film of expression different-thickness.

The figure (hydrogen Production Example 1-4) of the relation of open circuit voltage and hydrogen formation speed when Figure 10 is the dielectric film of expression different-thickness.

Figure 11 is the figure (hydrogen Production Example 1-5) of the relation of the following air mass flow of expression different temperatures (30～90 ℃) and hydrogen formation speed and open circuit voltage.

Figure 12 is the relation (oxidant: figure air) (hydrogen Production Example 1-5) of following open circuit voltage of expression different temperatures (30～90 ℃) and hydrogen formation speed.

Figure 13 is the figure (hydrogen Production Example 1-6) of the relation (50 ℃ of temperature) of air mass flow and hydrogen formation speed and open circuit voltage under the expression different fuel flow.

Figure 14 is the figure (hydrogen Production Example 1-6) of the relation (50 ℃ of temperature) of open circuit voltage and hydrogen formation speed under the expression different fuel flow.

Figure 15 is the figure (hydrogen Production Example 1-7) of the relation (50 ℃ of temperature) of air mass flow and hydrogen formation speed and open circuit voltage under the expression different fuel concentration.

Figure 16 is the figure (hydrogen Production Example 1-7) of the relation (50 ℃ of temperature) of open circuit voltage and hydrogen formation speed under the expression different fuel concentration.

Figure 17 is the figure (hydrogen Production Example 1-8) of the relation (50 ℃ of temperature) of oxidizing gas flow and hydrogen formation speed and open circuit voltage under the expression different oxygen concentrations.

Figure 18 is the figure (hydrogen Production Example 1-8) of the relation (50 ℃ of temperature) of open circuit voltage and hydrogen formation speed under the expression different oxygen concentrations.

Figure 19 is expression different temperatures (30～90 ℃) H down ₂O ₂The figure of the relation of flow and hydrogen formation speed and open circuit voltage (hydrogen Production Example 1-10).

Figure 20 is the relation (oxidant: H of following open circuit voltage of expression different temperatures (30～90 ℃) and hydrogen formation speed ₂O ₂) figure (hydrogen Production Example 1-10).

Figure 21 is the schematic diagram that the hydrogen among the embodiment 2 is made battery (having the device of deriving electric energy).

Figure 22 is that the current density that derives under the different air mass flows of expression (is discharged: figure 50 ℃ of temperature) (hydrogen Production Example 2-1) with the relation of running voltage.

Figure 23 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is discharged: figure 50 ℃ of temperature) (hydrogen Production Example 2-1).

Figure 24 is that the current density that derives under the different air mass flows of expression (is discharged: figure 30 ℃ of temperature) (hydrogen Production Example 2-2) with the relation of running voltage.

Figure 25 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is discharged: figure 30 ℃ of temperature) (hydrogen Production Example 2-2).

Figure 26 is that the current density that derives under the different air mass flows of expression (is discharged: figure 70 ℃ of temperature) (hydrogen Production Example 2-3) with the relation of running voltage.

Figure 27 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is discharged: figure 70 ℃ of temperature) (hydrogen Production Example 2-3).

Figure 28 is that the current density that derives under the different air mass flows of expression (is discharged: figure 90 ℃ of temperature) (hydrogen Production Example 2-4) with the relation of running voltage.

Figure 29 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is discharged: figure 90 ℃ of temperature) (hydrogen Production Example 2-4).

Figure 30 is that the current density that derives under the expression different temperatures (is discharged: figure air mass flow 50ml/ branch) with the relation of running voltage.

Figure 31 is that the relation of running voltage and hydrogen formation speed under the expression different temperatures (is discharged: figure air mass flow 50ml/ branch).

Figure 32 is that the current density that derives under the expression different temperatures (is discharged: figure air mass flow 100ml/ branch) with the relation of running voltage.

Figure 33 is that the relation of running voltage and hydrogen formation speed under the expression different temperatures (is discharged: figure air mass flow 100ml/ branch).

Figure 34 is the relation (discharge: figure 50 ℃ of temperature) (hydrogen Production Example 2-5) of expression different fuel the flow current density that derives down and the voltage that turns round.

Figure 35 is the relation (discharge: figure 50 ℃ of temperature) (hydrogen Production Example 2-5) of expression different fuel flow following running voltage and hydrogen formation speed.

Figure 36 is that the current density that derives under the expression different fuel concentration (is discharged: figure 50 ℃ of temperature) (hydrogen Production Example 2-6) with the relation of running voltage.

Figure 37 is that running voltage (discharges: figure 50 ℃ of temperature) (hydrogen Production Example 2-6) with the relation of hydrogen formation speed under the expression different fuel concentration.

Figure 38 is that the current density that derives under the expression different oxygen concentrations (is discharged: figure 50 ℃ of temperature) (hydrogen Production Example 2-7) with the relation of running voltage.

Figure 39 is that the relation of running voltage and hydrogen formation speed under the expression different oxygen concentrations (is discharged: figure 50 ℃ of temperature) (hydrogen Production Example 2-7).

Figure 40 is that the current density that derives under the expression different temperatures (is discharged: oxidant H with the relation of running voltage ₂O ₂) figure (hydrogen Production Example 2-8).

Figure 41 is that the relation of running voltage and hydrogen formation speed under the expression different temperatures (is discharged: oxidant H ₂O ₂) figure (hydrogen Production Example 2-8).

Figure 42 is the schematic diagram that the hydrogen among the embodiment 3 is made battery (having the device that applies electric energy from the outside).

Figure 43 is that the current density that expression applies under the different air mass flows (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-1) with the relation of hydrogen formation speed.

Figure 44 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-1).

Figure 45 is that the current density that applies under the different air mass flows of expression (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-1) with the relation of running voltage.

Figure 46 is that the relation of running voltage and energy efficiency under the different air mass flows of expression (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-1).

Figure 47 is that the current density that expression applies under the different air mass flows (is charged: figure 30 ℃ of temperature) (hydrogen Production Example 3-2) with the relation of hydrogen formation speed.

Figure 48 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is charged: figure 30 ℃ of temperature) (hydrogen Production Example 3-2).

Figure 49 is that the relation of running voltage and energy efficiency under the different air mass flows of expression (is charged: figure 30 ℃ of temperature) (hydrogen Production Example 3-2).

Figure 50 is that the current density that expression applies under the different air mass flows (is charged: figure 70 ℃ of temperature) (hydrogen Production Example 3-3) with the relation of hydrogen formation speed.

Figure 51 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is charged: figure 70 ℃ of temperature) (hydrogen Production Example 3-3).

Figure 52 is that the relation of running voltage and energy efficiency under the different air mass flows of expression (is charged: figure 70 ℃ of temperature) (hydrogen Production Example 3-3).

Figure 53 is that the current density that expression applies under the different air mass flows (is charged: figure 90 ℃ of temperature) (hydrogen Production Example 3-4) with the relation of hydrogen formation speed.

Figure 54 is that the relation of running voltage and hydrogen formation speed under the different air mass flows of expression (is charged: figure 90 ℃ of temperature) (hydrogen Production Example 3-4).

Figure 55 is that the relation of running voltage and energy efficiency under the different air mass flows of expression (is charged: figure 90 ℃ of temperature) (hydrogen Production Example 3-4).

Figure 56 is that the current density that expression applies under the different temperatures (is charged: figure air mass flow 50ml/ branch) with the relation of hydrogen formation speed.

Figure 57 is that the relation of running voltage and hydrogen formation speed under the expression different temperatures (is charged: figure air mass flow 50ml/ branch).

Figure 58 is that the relation of running voltage and energy efficiency under the expression different temperatures (is charged: figure air mass flow 50ml/ branch).

Figure 59 is that the current density that applies under the expression different fuel flow (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-5) with the relation of hydrogen formation speed.

Figure 60 is the relation (charging: figure 50 ℃ of temperature) (hydrogen Production Example 3-5) of expression different fuel flow following running voltage and hydrogen formation speed.

Figure 61 is the relation (charging: figure 50 ℃ of temperature) (hydrogen Production Example 3-5) of expression different fuel flow following running voltage and energy efficiency.

Figure 62 is that the current density that applies under the expression different fuel concentration (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-6) with the relation of hydrogen formation speed.

Figure 63 is that running voltage (charges: figure 50 ℃ of temperature) (hydrogen Production Example 3-6) with the relation of hydrogen formation speed under the expression different fuel concentration.

Figure 64 is that running voltage (charges: figure 50 ℃ of temperature) (hydrogen Production Example 3-6) with the relation of energy efficiency under the expression different fuel concentration.

Figure 65 is that the current density that expression applies under the different oxygen concentrations (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-7) with the relation of hydrogen formation speed.

Figure 66 is that the relation of running voltage and hydrogen formation speed under the expression different oxygen concentrations (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-7).

Figure 67 is that the relation of running voltage and energy efficiency under the expression different oxygen concentrations (is charged: figure 50 ℃ of temperature) (hydrogen Production Example 3-7).

Figure 68 is that the current density that expression applies under the different temperatures (is charged: oxidant H with the relation of hydrogen formation speed ₂O ₂) figure (hydrogen Production Example 3-8).

Figure 69 is that the relation of running voltage and hydrogen formation speed under the expression different temperatures (is charged: oxidant H ₂O ₂) figure (hydrogen Production Example 3-8).

Figure 70 is that the relation of running voltage and energy efficiency under the expression different temperatures (is charged: oxidant H ₂O ₂) figure (hydrogen Production Example 3-8).

Figure 71 is the relation (open circuit: figure 50 ℃ of temperature) (embodiment 8) of expression air mass flow and hydrogen formation speed.

Figure 72 is the relation (open circuit: figure 50 ℃ of temperature) (embodiment 8) of expression open circuit voltage and hydrogen formation speed.

Figure 73 is the relation (open circuit: figure no fuel electrodes barrier film) (embodiment 9) of expression air mass flow and hydrogen formation speed.

Figure 74 is the relation (open circuit: figure no fuel electrodes dividing plate) (embodiment 9) of expression open circuit voltage and hydrogen formation speed.

Symbol description

10: hydrogen is made battery, 11: barrier film, 12: fuel electrodes, 13: the stream that is used for the fuel (methanol aqueous solution) that the fueling utmost point 12 contains organic substance and water, 14: the oxidation utmost point (air pole), 15: the stream that is used for supplying with oxidant (air) to the oxidation utmost point (air pole) 14,16: petrolift, 17: air blowing fan, 18: fuel flow control valve, 19: air flow rate adjustment valve, 20: fuel tank, 21: the fuel adjusting groove, 22: voltage regulator, 23: gas-liquid separator (separating the hydrogen-containing gas and the unreacted methanol aqueous solution), 24: the hydrogen jar, 25: the conduit that is used for the unreacted methanol aqueous solution is returned fuel adjusting groove 21,26: the hydrogen flow control valve, 27: gas-liquid separator (from the air exhaust, separating the water and the unreacted methanol aqueous solution that generates), 28: the co 2 removal device, 29: the conduit that is used for the unreacted methanol aqueous solution is returned fuel adjusting groove 21,30: fuel cell, 31: solid polyelectrolyte membrane, 32: the hydrogen utmost point, 33: the stream of hydrogen being supplied with the hydrogen utmost point 32,34: air pole, 35: with the stream of the air air supply utmost point 34,36: the direct current that fuel cell 30 is sent is converted to the power inverter of regulation electric power, 37: the control device that Blast Furnace Top Gas Recovery Turbine Unit (TRT) is all controlled, 38: packing case.

Embodiment

Following illustration is used to implement the specific embodiment of the present invention.

Particularly, the hydrogen producing apparatus that uses in the fuel cell power generating system of the present invention is new basically, only execution mode of the following stated, and the present invention is not limited thereto.

Fig. 1 (a) and (b) mode of expression fuel cell power generating system of the present invention, i.e. an example of box fuel cell power generating system.

The basic structure of box fuel cell power generating system of the present invention has been adorned the control device (37) all controlled by the hydrogen of supplying with fuel cell (30) that hydrogen and oxidant generate electricity, making the hydrogen-containing gas that is used for fueling battery (30) is made battery (10), direct current that fuel cell (30) is sent is converted to regulation electric power power inverter (36), to Blast Furnace Top Gas Recovery Turbine Unit (TRT) and petrolift (16), air blowing fan Aided Machines such as (17) at least in the packing casing shown in Fig. 1 (a).

For box fuel cell power generating system of the present invention make battery (10) and move at low temperatures owing to constitute the hydrogen of hydrogen producing apparatus, therefore different with apparatus for reforming of fuel in the past, control device (37) can be configured in hydrogen manufacturing battery (10) near.In addition, can not need to be used to protect control device (37) to avoid the heat-insulating material that hydrogen is made the heat that battery (10) produced.

In the figure, adorned fuel tank (20) and fuel adjusting groove (21) in the packing casing, also can be in dress they and by the outside fueling (methanol aqueous solution) of casing, regulating tank (21) also can be in casing charges in only.

In addition, make also direct fueling battery (10) of hydrogen-containing gas that battery (10) produced by hydrogen, but the hydrogen jar (24) of storing hydrogen-containing gas preferably is set, by hydrogen jar (24) fueling battery (30).

And, the gas-liquid separator (23) that separates the hydrogen-containing gas and the unreacted methanol aqueous solution preferably is set, make the unreacted methanol aqueous solution make circulation in the battery (10) at hydrogen.In addition, the water of separation generation from the air exhaust and the gas-liquid separator (27) of the unreacted methanol aqueous solution also can be set.

In addition, do not show among the figure, but in addition reserve battery can also be set.

The hydrogen producing apparatus that uses in the box fuel cell power generating system of the present invention shown in Fig. 1 (b), has hydrogen manufacturing battery (10) and the auxiliary machinery of the hydrogen producing apparatus that is used to turn round.

The structure that hydrogen is made battery (10) is as follows: on a face of barrier film (11) fuel electrodes (12) is set, has the stream 13 that is used for supplying with the fuel (methanol aqueous solution) that contains organic substance and water to fuel electrodes (12), and the oxidation utmost point (14) is set on another face of barrier film (11), has the stream (15) that is used for supplying with oxidant (air) to the oxidation utmost point (14).

As the auxiliary machinery of the hydrogen producing apparatus that is used to turn round, be provided with petrolift (16) from methanol aqueous solution to fuel electrodes (12) that supply with.The stream of fuel electrodes (13) is connected with flow control valve (18) and by conduit by petrolift (16).

Fuel (100% methyl alcohol) is stored in the fuel tank (20), is shifted into fuel adjusting groove (21) then, mixes with water in fuel adjusting groove (21), for example is adjusted to about 3% methanol aqueous solution and supplies to fuel electrodes (12).

In addition, as same Aided Machine air blowing fan (17) is set, can be directly to the oxidation utmost point (14) air supply, but in the figure, supply with air by air blowing fan (17) to fuel cell (30), utilize the unreacted air (air exhaust) of discharging from fuel cell (30).

Wherein, make battery (10) by flowing to hydrogen by the air exhaust that the air pole of fuel cell (30) is discharged, thereby do not need hydrogen to make the air blowing fan of battery (10) usefulness.The stream of the oxidation utmost point (15) is connected with air blowing fan (17) by flow control valve (19), fuel cell (30).

And; because this air exhaust has the essentially identical temperature of working temperature (about 80 ℃) with fuel cell (30); therefore, when protection control device (37) is avoided fuel cell (30) heat, can utilize the heat of air exhaust to be used as heating the thermal source that hydrogen is made battery (10).

In addition, when being used in combination 2 above hydrogen producing apparatus, the air of supplying with as the oxidation utmost point (14) from battery (10) a to hydrogen that make can utilize the air exhaust of being made battery (10) discharge by another hydrogen.

For hydrogen producing apparatus with said structure, make it running to petrolift (16) and air blowing fan (17) supply of electrical energy, and when opening flow control valve (18), methanol aqueous solution is supplied to fuel electrodes (12) from fuel adjusting groove (21) by stream (13) by petrolift (16); In addition, when opening flow control valve (19), make air supply to the oxidation utmost point (14) by stream (15) by fuel cell (30) by air blowing fan (17).

Thus, in fuel electrodes and the oxidation utmost point (air pole) generation reaction as described later, produce hydrogen-containing gas by fuel electrodes (12) side.

In addition, make the voltage regulator (22) of the voltage of battery (10) (open circuit voltage or running voltage) and control quantity delivered or the electric energy of concentration and derivation or the electric energy that applies of fuel and air by being provided for monitoring hydrogen, thereby can regulate the growing amount of hydrogen-containing gas.

The hydrogen-containing gas that produces is separated into the hydrogen-containing gas and the unreacted methanol aqueous solution by gas-liquid separator (23), and hydrogen-containing gas is stored in the hydrogen jar (24).

The unreacted methanol aqueous solution after the part or all of separation returns fuel adjusting groove (21) by conduit (25) and circulates.According to circumstances also can outside system, supply with water.

In the air exhaust by the hydrogen producing apparatus discharge, contain the water of generation and because of " infiltration " phenomenon unreacted methanol aqueous solution from the methanol aqueous solution that fuel electrodes sees through, therefore, gas-liquid separator (27) is passed through in this air exhaust, the water that generates is separated with the unreacted methanol aqueous solution,, be discharged in the atmosphere behind the co 2 removal by co 2 removal device (28).

The water of the generation after the some or all of separation and the unreacted methanol aqueous solution turn back in the fuel adjusting groove (21) by conduit (29) and to circulate.

On the hydrogen utmost point (32) of fuel cell (30), supply with the hydrogen that is stored in hydrogen jar (24) by flow control valve (26), on the air pole (34), by the air of flow control valve (19) supply from air blowing fan (17), reaction in the hydrogen utmost point one side and air pole one side difference production (1) and formula (2), the reaction of whole fuel cell generating polynomial (3) forms water (steam), produces electricity (direct current).

H ₂→2H ⁺+2 ^e-......(1)

2H ⁺+2e ^-+(1/2)O ₂→H ₂O......(2)

H ₂+(1/2)O ₂→H ₂O......(3)

For fuel cell (30), if fuel is hydrogen, then can use any kind of, preferably at the polymer electrolyte fuel cell (PEFC) that can turn round smaller or equal to 100 ℃ low temperature.For polymer electrolyte fuel cell, can adopt a plurality of fuel cell packs that are laminated of known monocell.Single monocell have be called as Nafion (trade mark of E.I.Du Pont Company) solid polyelectrolyte membrane (31), its both sides of clamping as the hydrogen utmost point (32) of diffusion electrode and air pole (34) and from both sides with 2 barrier films of two electrode clampings etc.Form concavo-convexly on the two sides of barrier film, between the hydrogen utmost point and air pole of clamping, form gas flow path (33), (35) in the monocell.Wherein, and the hydrogen utmost point between circulation is supplied with in the gas flow path (33) in the monocell that forms hydrogen, in addition, and air pole between flow through air in the gas passage (35) in the monocell that forms.

Fuel cell (30) generating can be accompanied by heating.Under the situation of above-mentioned polymer electrolyte fuel cell (PEFC), polyelectrolyte membrane is in saturation state, shows proton-conducting, therefore along with the heating of fuel cell, the polyelectrolyte membrane drying, the internal resistance of fuel cell increases if moisture content descends, and generating capacity descends.Therefore, in order to prevent the drying of polyelectrolyte membrane, essential cooled fuel cell keeps suitable operating temperature (about 80 ℃).On the other hand, hydrogen producing apparatus, shown in the embodiment, the formation efficiency of the high more then hydrogen of temperature is high more as described later, therefore, the device heating of doing hydrogen producing apparatus of the heating of this fuel cell being carried out heat exchange is set preferably.

In the past, in order to keep polyelectrolyte membrane at moisture state, reformed gas and/or reaction air are carried out fueling battery body behind the humidification, but hydrogen producing apparatus used in the present invention, from having supplied with the fuel electrodes one side output hydrogen-containing gas of the fuel (methanol aqueous solution etc.) that contains organic substance and water, owing to hydrogen has been carried out humidification, thereby can no longer need humidifier.And, make the hydrogen-containing gas that battery (10) produces by hydrogen, owing to the reformed gas that does not resemble reformer manufacturing in the past, be high-temperature gas, therefore need not cool off can fueling battery (30).

In addition, as the fuel of fueling battery, the situation that can consider only to supply with the situation of the hydrogen that is produced by hydrogen manufacturing battery (10) and supply with hydrogeneous methanol aqueous solution.Contain the situation of the methanol aqueous solution of hydrogen for supply, then do not need gas-liquid separator (23).

By the direct current that fuel cell (30) is sent, be input to power inverter (36), by DC/DC converter (converter) boost or change alternating current into by DC/AC inverter (inverter) after export.In addition, by Aided Machine with converter the direct current after stable, can be used as the driving power of petrolift (16), air blowing fan auxiliary machineries such as (17), alternating current can be used as the driving power of household electrical appliance.

For this a series of generator operation, by control device (37) to hydrogen make voltage adjuster (22), fuel cell (30), power inverter (36), the petrolift (16) of battery (10), the action of air blowing fan auxiliary machineries such as (17) is controlled.

The hydrogen of the employed hydrogen producing apparatus of fuel cell power generating system of the present invention is made battery (10) and is formed following basic structure as mentioned above: the fuel electrodes (12) that is provided with on the face of barrier film (11), barrier film (11) and the oxidation utmost point (14) that is provided with on another face of barrier film (11).For example, as such structure, the MEA (electrolyte/assembly of electrode) that can adopt picture in direct methanol fuel cell, to be adopted.

Manufacture method for MEA is unqualified, can make in the two sides of barrier film joint fuel electrodes and the such method same of the oxidation utmost point (air pole) by utilizing hot pressing.

The MEA that makes as mentioned above is clipped between fuel electrodes barrier film and the oxidation utmost point barrier film, constitute hydrogen producing apparatus, wherein said fuel electrodes barrier film is the fuel electrodes barrier film that is provided with the stream ditch (13) of the fuel contain organic substance and water of being used for flowing on fuel electrodes, and described oxidation utmost point barrier film is the oxidation utmost point barrier film that is provided with the stream ditch (15) of the oxidant that is used for flowing in oxidation extremely.

In order to be easy to produce hydrogen, preferably to small part is relative the two stream ditch of fuel electrodes barrier film and oxidation utmost point barrier film is crisscross arranged according to the ridge part beyond the stream ditch of the stream ditch that makes the fuel electrodes barrier film and the oxidation utmost point.

In addition, when not using the fuel electrodes barrier film, the stream of the fuel contain organic substance and water of also can being provided for flowing on fuel electrodes only makes up oxidation utmost point barrier film and constitutes hydrogen manufacturing battery with MEA.

Barrier film can use the proton conductive solid electrolyte film that is used as polyelectrolyte membrane in fuel cell.As the proton conductive solid electrolyte film, Nafion film that preferably uses E.I.Du Pont Company etc. has sulfonic perfluorocarbon sulfonic acid mesentery.

The electrode that the fuel electrodes and the oxidation utmost point (air pole) preferably have conductivity, have catalytic activity, for example, can make by painting catalyst slurry and drying on gas diffusion layers, described catalyst pulp contains the material that adhesives such as the catalyst that supported noble metal on the carrier of being made by carbon dust etc., PTFE resin and Nafion solution etc. are used to give ionic conductivity.

The layer that preferably constitutes as gas diffusion layers by the carbon paper that has carried out hydrophobic treatment (carbon paper) etc.

The electrode catalyst that acts as a fuel can use any material, but preferably uses the catalyst that has supported the Pt-Ru alloy on carbon dust.

Can use any material as the air pole catalyst, but preferably use the catalyst that on carbon dust, has supported Pt.

In the hydrogen producing apparatus of above-mentioned formation, supply with organic fuel such as containing methanol aqueous solution to fuel electrodes, and when oxidants such as the oxidation utmost point (air pole) air supply, oxygen, hydrogen peroxide, under given conditions, can produce hydrogen-containing gas in fuel electrodes.

The hydrogen production method of the hydrogen producing apparatus that uses in the fuel cell power generating system of the present invention is different fully with the hydrogen production method in the hydrogen producing apparatus in the past, in addition, also is difficult to illustrate its mechanism at present.The below present supposition of explanation can't be negated the possibility that produces brand-new reaction.

The hydrogen producing apparatus that uses in the fuel cell power generating system of the present invention, as described later, under 30～90 ℃ low temperature, and by the fuel electrodes side generation hydrogen-containing gas of supplying with the first alcohol and water.In situation from the battery supply of electrical energy to hydrogen that do not make, can produce the gas of the hydrogen concentration about 70～80% from the outside; Making the situation that battery applies electric energy from the outside to hydrogen, can produce gas more than or equal to 80% hydrogen concentration.And the generation of knowing this gas depends on the open circuit voltage or the running voltage at the two poles of the earth.Infer following hydrogen mechanism of production from such result.Below, for mechanism is described simply, under open-circuit condition, describe.

For example, identical when using methyl alcohol to act as a fuel in the hydrogen producing apparatus that uses in the fuel cell power generating system of the present invention with the situation of direct methanol fuel cell, can think at first to generate proton by catalyst in fuel electrodes.

CH ₃OH+H ₂O→CO ₂+6H ⁺+6e ^-......(1)

In the situation of using Pt-Ru as catalyst, reaction for above-mentioned (1), can think that methyl alcohol is adsorbed on the Pt surface, electrochemical oxidation reactions as described below takes place successively, carry out (" the battery brief guide third edition " February 20 calendar year 2001 of Japanese publication by generating the absorption chemical seed that firmly is adsorbed on the surface, ball kind (strain) distribution, the 406th page).

CH ₃OH+Pt→Pt-(CH ₃OH) _ads

→Pt-(CH ₂OH) _ads+H ⁺+e ^-

Pt-(CH ₂OH) _ads→Pt-(CHOH) _ads+H ⁺+e ^-

Pt-(CHOH) _ads→Pt-(COH) _ads+H ⁺+e ^-

Pt-(COH) _ads→Pt-(CO) _ads+H ⁺+e ^-

Above-mentioned Pt-(CO) _AdsIf further oxidation, then need be by the absorption OH of water generation.

Ru+H ₂O→Ru-(H ₂O) _ads

→Ru-(OH) _ads+H ⁺+e ^-

Ru-(OH) _ads+Pt-(CO) _ads→Ru+Pt+CO ₂+H ⁺+e ^-

In the situation of direct methanol fuel cell, by the H that fuel electrodes generates that is reflected at of (1) formula ⁺(proton) moves in the proton conductive solid electrolyte film, thereby at the oxidation utmost point and the gas that contains aerobic or the oxygen that supply to the oxidation utmost point following reaction takes place.

3/2O ₂+6H ⁺+6e ^-→3H ₂O......(2)

Employed hydrogen producing apparatus is under the situation of open circuit in the fuel cell power generating system of the present invention, the e that is generated by the reaction of (1) formula ^-Do not supply to the oxidation utmost point by external circuit, thereby in order to produce the reaction of (2) formula, need other take place at the oxidation utmost point and react and supply with e ^-

On the other hand, in direct methanol fuel cell, as the situation of using proton conductive solid electrolyte films such as Nafion, known CH ₃" infiltration " phenomenon that OH sees through to oxidation utmost point side from fuel electrodes.The electrolytic oxidation reaction of following infiltration methyl alcohol can take place most probably in oxidation.

CH ₃OH+H ₂O→CO ₂+6H ⁺+6e ^-......(3)

If the reaction of (3) formula takes place, by the e of this reaction generation ^-Be supplied to, can produce the reaction of (2) formula.

Subsequently, the H that reaction generated by (3) formula ⁺Move in the proton conductive solid electrolyte film, the reaction below fuel electrodes takes place produces hydrogen.

6H ⁺+6e ^-→3H ₂......(4)

At this, by the H that fuel electrodes generates that is reflected at of (1) formula ⁺And e ^-To moving and the H that the oxidation utmost point is generated that is reflected at by (3) formula of the oxidation utmost point ⁺And e ^-Be considered to cancel each other on apparent to fuel electrodes mobile.

Can be estimated as in this case, at the oxidation utmost point because the H that reaction generated by (3) formula ⁺And e ^-Produce the reaction of (2) formula, the H that reaction generated in fuel electrodes because by (1) formula ⁺And e ^-The reaction of (4) formula of generation.

Suppose the reaction of on fuel electrodes, carrying out (1) formula and (4) formula, when in oxidation extremely, carrying out the reaction of (2) formula and (3) formula, can think that on the whole following (5) formula sets up.

2CH ₃OH+2H ₂O+3/2O ₂→2CO ₂+3H ₂O+3H ₂......(5)

The theoretical efficiency of this reaction is 59% (thermal discharge of the thermal discharge of 3mol hydrogen/2mol methyl alcohol).

But, for above-mentioned reaction, (1) the standard electrode potential E0=0.046V of the reaction of formula, (4) the standard electrode potential E0=0.0V of the reaction of formula is when making up the two, because the situation of (1) formula corresponds to positive pole under standard state, (4) situation of formula corresponds to negative pole, thereby (1) reaction of formula is carried out to the left side, and the reaction of (4) formula is also carried out to the left side, does not therefore produce hydrogen.

At this, for the reaction that makes (1) formula is also carried out to the right to the reaction of the right, (4) formula, it is essential making the corresponding negative pole of (1) formula, the corresponding positive pole of (4) formula, when the integral body of supposing fuel electrodes is equipotential, need makes the methanol oxidation current potential change or make hydrogen produce current potential and change to hot side to low potential side.

But, be not equipotential situation in fuel electrodes, in fuel electrodes from methyl alcohol and water generates H ⁺The reaction and the H of (1) formula ⁺With e ^-Reaction in conjunction with (4) formula that forms hydrogen may be carried out simultaneously.

As described in the embodiment of back, the high situation of operating temperature is from being easy to generate the angle of hydrogen, is supplied to from the reaction heat of outside, carries out to the right as the reaction meeting of (1) and (3) formula of the endothermic reaction.

For methyl alcohol, except the reaction of (1) and (3) formula, because phenomenon of osmosis, the methyl alcohol that sees through from fuel electrodes can produce by the following side reaction of oxygen institute oxidation on the surface of air pole catalyst.

CH ₃OH+3/2O ₂→CO ₂+2H ₂O......(6)

Because the reaction of (6) formula of being somebody's turn to do is exothermic reaction, can be understood as, the heat of the reaction of (1) and (3) formula is supplied to by this heat release.

The situation of employed hydrogen producing apparatus in the fuel cell power generating system of the invention that the application's claim 3 is related (hereinafter referred to as " open-circuit condition "), by embodiment described later as can be known, if the quantity delivered of oxygen (air) tails off, open circuit voltage reaches 300～800mV, then can produce hydrogen, this is estimated to be, and the methyl alcohol that sees through the air pole side is suppressed the H of (3) formula by the oxidized situation of (6) formula ⁺Reaction of formation becomes dominance, thereby produces hydrogen by the reaction of (4) formula.

In addition, in embodiment described later, make battery as hydrogen, use and the identical structure of representational direct methanol fuel cell, can think, the stream ditch of oxidant (air) owing on the oxidation utmost point (air pole) barrier film, be provided for flowing, therefore, many in the part circulation of air of stream ditch, what make (2) and (6) is reacted into the reaction of taking as the leading factor property, and under the situation that the quantity delivered of air reduces, part air (oxygen) deficiency beyond the stream ditch, the H of (3) formula ⁺Reaction of formation just becomes dominance.

The situation of the hydrogen producing apparatus that uses in the fuel cell power generating system of the invention that the application's claim 4 is related (hereinafter referred to as " discharging condition "), can think with open-circuit condition under the similar mechanism of hydrogen mechanism of production produce hydrogen.But, different with the situation of open-circuit condition since with a considerable amount of H of discharging current ⁺Moving to the oxidation Ghandler motion from fuel electrodes, therefore the cell integrated electroneutrality condition of essential maintenance can think that the reaction of (1) formula is better than (4) formula on fuel electrodes, and the reaction of extremely going up (2) formula in oxidation is better than (3) formula.

From embodiment described later as can be known, discharging current becomes big (to oxidation huge amount supply e ^-), when discharge voltage is lower than 200mV, not producing hydrogen, this is estimated to be, and does not produce hydrogen owing to reach the necessary voltage of electrolysis of methanol aqueous solution.

In addition, at a large amount of oxygen (air) of supplying with, perhaps discharge voltage is higher than the situation of 600mV, does not also produce hydrogen, and this is estimated to be, because it is oxidized by (6) formula to see through the methyl alcohol of air pole side, thereby does not carry out the H of (3) formula ⁺Reaction of formation.

On the other hand, in the few situation of quantity delivered of oxygen (air), if discharging current reduces, discharge voltage (running voltage) is 200～600mV, then produces hydrogen, and this is estimated to be, the methyl alcohol that sees through the air pole side is suppressed the H of (3) formula by the oxidized situation of (6) formula ⁺Reaction of formation becomes dominance, thereby produces hydrogen by the reaction of (4) formula.

In addition, under the discharging condition, identical with the situation of open-circuit condition, can think, because many in the part circulation of air of the stream ditch of air pole barrier film, what make (2) and (6) is reacted into the reaction of taking as the leading factor property, and under the situation of the quantity delivered minimizing of air, part air (oxygen) deficiency beyond the stream ditch, the H of (3) formula ⁺Reaction of formation just becomes dominance.

The situation of the hydrogen producing apparatus that uses in the fuel cell power generating system of the invention that the application's claim 5 is related (hereinafter referred to as " charge condition "), also can think with open-circuit condition under the similar mechanism of hydrogen mechanism of production produce hydrogen.But, different with the situation of open-circuit condition since with a considerable amount of H of Faradaic current ⁺Move to fuel electrodes from the oxidation utmost point, therefore the cell integrated electroneutrality condition of essential maintenance can think that the reaction of (4) formula is better than (1) formula on fuel electrodes, and the reaction of extremely going up (3) formula in oxidation is better than (2) formula.

That is, the situation of charge condition of the present invention since with fuel electrodes as negative electrode, apply electric energy as anode from the outside with the oxidation utmost point and (provide e to fuel electrodes from the outside ^-), therefore, basically electrolysis can take place, by embodiment described later as can be known,, then can produce many hydrogen if increase the electric energy (applying voltage) that applies, this can think, the e that supplies with to fuel electrodes from the outside ^-Change is many, has promoted the electrolytic oxidation reaction of methyl alcohol of (3) formulas and the reaction 6H of (4) formula ⁺+ 6e ^-→ 3H ₂

But, as hereinafter described, few and when applying voltage (running voltage) and being the low like this scope of 400～600mV, energy efficiency increases in the quantity delivered of oxygen (air).This moment, in this scope, as previously mentioned, even not under the open-circuit condition or discharging condition of outside supply of electrical energy, can infer the methyl alcohol that sees through in the air pole side and be subjected to inhibition by (6) formula oxidized, part air (oxygen) deficiency beyond the stream ditch of air pole dividing plate, the H of (3) formula ⁺Reaction of formation becomes dominance, passes through the H of (4) formula on the fuel electrodes of its opposition side ⁺Reaction of formation produces hydrogen, but under charge condition, infers to be, apply electric energy by the outside and produce hydrogen, in addition, with the situation of above-mentioned open-circuit condition or discharging condition under similarly produce hydrogen.

At this, have any meaning at the current potential of battery and describe.In general the ion that the voltage of battery that clips dielectric film and constitute gas electrode at the two poles of the earth conducts electricity in owing to electrolyte produces in the difference of the chemical potential at the two poles of the earth.

That is, do not consider when the polarization at the two poles of the earth that owing to use proton (hydrogen ion) conductive solid electrolyte film as electrolyte, therefore, the voltage of observation represents that battery is the poor of so-called hydrogen dividing potential drop in the chemical potential of the hydrogen at the two poles of the earth.

In the present invention, as described in the embodiment of back, the voltage between the fuel electrodes and the oxidation utmost point produces hydrogen by the fuel electrodes side when certain limit; When the difference of the chemical potential of the hydrogen at the two poles of the earth is certain limit, can infer the reaction of carrying out above-mentioned (1)～(6) formula, produce hydrogen.

The hydrogen producing apparatus that uses in the fuel cell power generating system of the present invention, even derive electric energy and do not make under the situation of battery supply of electrical energy to the outside not making battery from the outside to hydrogen from hydrogen, making battery from hydrogen under the situation of outside derivation electric energy, and applying under the situation of electric energy from the outside to hydrogen manufacturing battery, also all can regulate the growing amount of hydrogen-containing gas by the voltage between the fuel metering utmost point and the oxidation utmost point (air pole) (open circuit voltage or running voltage).

By embodiment described later as can be known, in the situation of open-circuit condition, open circuit voltage is that 300～800mV produces hydrogen; In the situation of discharging condition, discharge voltage (running voltage) is that 200～600mV produces hydrogen; In the situation of charge condition, applying voltage (running voltage) is that 300～1000mV (energy efficiency height under 400～600mV) produces hydrogen, therefore, by regulating open circuit voltage or running voltage, can regulate the growing amount of hydrogen-containing gas in this scope.

Shown in the embodiment described as follows, the growing amount (hydrogen formation speed) of open circuit voltage or running voltage and/or hydrogen-containing gas, quantity delivered, the concentration (oxygen concentration in the oxygen-containing gas) of regulating oxidant that can be by regulating oxidant (oxygen-containing gas or oxygen, contain the liquid of hydrogen peroxide), regulate the supply that contains organic fuel, the concentration that adjusting contains organic fuel is regulated.

In addition, except above-mentioned, situation at discharging condition, by the electric energy (electric current that adjusting to outside derive, the power supply that also have use can control constant voltage be so-called potentiostat regulate voltage to outside derivation) of adjusting to the outside derivation, situation at charge condition, by the electric energy (electric current that adjusting applies, the power supply that also has use can control constant voltage are that so-called potentiostat is regulated the voltage that applies) that adjusting applies, can regulate the growing amount of running voltage and/or hydrogen-containing gas.

In the employed hydrogen producing apparatus, owing to can contain organic fuel smaller or equal to 100 ℃ of decomposition, the operating temperature that therefore can make hydrogen producing apparatus is smaller or equal to 100 ℃ in fuel cell power generating system of the present invention.Operating temperature is preferably 30～90 ℃.By at 30～90 ℃ range regulation operating temperature, embodiment described as follows is described, can regulate the growing amount of open circuit voltage or running voltage and/or hydrogen-containing gas.

In addition, in the past must be in reformation technology more than or equal to 100 ℃ of runnings, water becomes steam, contain organic fuel gasization, under such condition, even produce hydrogen, also need to adopt in addition the equipment of separation of hydrogen, thereby the present invention is favourable in this.

But, if contain organic fuel in temperature decomposition more than or equal to 100 ℃, then have above-mentioned shortcoming, but the present invention does not negate an employed hydrogen producing apparatus in surpassing 100 ℃ of fuel cell power generating systems of the present invention that to a certain degree yet can turn round under the situation of temperature.

Consider from the principle of inferring, as containing organic fuel can be to see through proton conductive barrier film, oxidized and generate the liquid or the gaseous fuel of proton with electrochemical means, preferably contain alcohol such as methyl alcohol, ethanol, ethylene glycol, isopropyl alcohol, aldehyde such as formaldehyde, carboxylic acids such as formic acid, the liquid fuel of ethers such as diethyl ether.Because containing organic fuel is supplied to water, therefore, contains in the solution of these liquid fuels and water, preferably contain the aqueous solution of alcohol, especially methanol in water.Here, be the solution that contains the first alcohol and water at least as the methanol in water that contains of an example of above-mentioned fuel, in the field that produces hydrogen-containing gas, its concentration can be selected arbitrarily.

Can using gases or the oxidant of liquid as oxidant.Preferably contain the gas of aerobic or oxygen as gaseous oxidant.The oxygen concentration that contains the gas of aerobic is preferably more than especially and equals 10%.The liquid that preferably contains hydrogen peroxide is as liquid oxidizer.

In the present invention, owing to put into fuel disposable being consumed in this device of hydrogen producing apparatus, the ratio that resolves into hydrogen is low, and therefore the recycle unit of fuel preferably is set, and improves the transfer ratio to hydrogen.

The employed hydrogen producing apparatus of fuel cell power generating system of the present invention has the device of the hydrogen-containing gas that takes out the generation of fuel electrodes side, and it is the device that is used for reclaiming hydrogen, preferably also reclaims carbon dioxide.Owing to be under smaller or equal to 100 ℃ of such low temperature, to turn round, therefore the carbon dioxide absorption portion that is included in the carbon dioxide in the hydrogen-containing gas that absorbs can be set by easy device.

Below, expression embodiments of the invention (hydrogen Production Example) can be to the ratio of catalyst, PTFE, Nafion etc., and the thickness of catalyst layer, gas diffusion layers, dielectric film etc. suit to change, and is not limited to these embodiment.

Embodiment 1

Below the example of the situation of hydrogen is made in expression according to the employed hydrogen producing apparatus of fuel cell power generating system (open-circuit condition) of the related invention of the application's claim 3.

Hydrogen Production Example 1-1

Embodiment 1 (make battery and form and the identical structure of representational direct methanol fuel cell by the hydrogen among the Production Example 1-1～1-10).

The summary of this hydrogen manufacturing battery as shown in Figure 2.

Promptly, the proton conductive dielectric film (Nafion115) that uses E.I.Du Pont Company's system is as electrolyte, carbon paper (East レ is made) in the polytetrafluoroethyldispersion dispersion of 5% concentration behind the dipping, burn till and carry out hydrophobic treatment at 360 ℃, coating air pole catalyst pulp on one face, thereby on air pole, form the gas diffusion layers that has the air pole catalyst, described air pole catalyst pulp is by mixing air electrode catalyst (support the carbon of platinum, Tanaka's noble metal is made), PTFE micropowder and 5% Nafion solution (ア Le De リ Star チ manufacturing) and make.At this, the weight ratio of air pole catalyst, PTEF, Nafion is 65%:15%:20%.To be converted into platinum be 1mg/cm to the catalytic amount of the air pole of Zhi Zuoing like this ²

And then, making uses the same method carries out hydrophobic treatment to carbon paper, on one face, be coated with the fuel electrode catalyst slurry then, thereby form the gas diffusion layers that has fuel electrode catalyst, described fuel electrode catalyst slurry is made by the Nafion solution of fuel combination electrode catalyst (support the carbon of Pt-Ru, Tanaka's noble metal make), PTFE micropowder and 5%.At this, the weight ratio of fuel electrode catalyst, PTEF, Nafion is 55%:15%:30%.To be converted into Pt-Ru be 1mg/cm to the catalytic amount of the fuel electrodes of Zhi Zuoing like this ²

With above-mentioned dielectric film, have the air pole catalyst gas diffusion layers, have the gas diffusion layers of fuel electrode catalyst at 40 ℃, 100kg/cm ²Down by the incompatible making of thermo-compressed MEA.So the active electrode area of the MEA that makes is 60.8cm ²(long 80mm, wide 76mm).The thickness of the gas diffusion layers of the air pole after the making and the catalyst layer of fuel electrodes, air pole and fuel electrodes is respectively about 30 μ m and 170 μ m, and basic identical separately.

Be provided for the stream of ventilating air and circulation fuel respectively, and then in order to prevent gas leakage, the air pole dividing plate and the above-mentioned MEA of fuel electrodes dividing plate clamping of the graphite system by soaking into phenolic resins, thus constitute monocell.This moment, with in the past representational direct methanol fuel cell (for example, TOHKEMY 2002-208419 communique, paragraph [0020], Fig. 1; TOHKEMY 2003-123799 communique, paragraph [0015], situation Fig. 1) is identical, is processing ditch on the air baffle He on the fuel electrodes dividing plate, as the stream that is used for ventilating air and circulation fuel.The thickness of arbitrary air pole dividing plate and fuel electrodes dividing plate is 2mm.The stream that is used for ventilating air of air pole dividing plate is to crawl (number of times of turning back: 8 times) and form 3 ditches arranged side by side (furrow width: 2mm, the width of ridge portion: 1mm, ditch depth: 0.6mm) from the top of dividing plate to the diagonal of bottom.The dividing plate of fuel electrodes be used to circulate the stream of fuel be from the bottom of dividing plate to the diagonal on top crawl (number of times of turning back: 10 times) and form 3 ditches arranged side by side (furrow width: 1.46mm, the width of ridge portion: 0.97mm, ditch depth: 0.6mm).In addition, in order to prevent fuel and leakage of air, the encapsulation of silicon rubber system is set at peripheral part of MEA.

In this case, on the air pole dividing plate and the position of the ditch of fuel electrodes dividing plate and ridge portion relation will change the generation of hydrogen.That is, as previously mentioned,, cause the H of (3) formula because the last methyl alcohol of part (ridge part) of inferring beyond the stream ditch of air pole barrier film spreads ⁺Therefore reaction of formation, if when the ridge part of air pole barrier film is positioned in opposite directions on the same position of the ridge of fuel electrodes barrier film part, can hinder the diffusion from the methyl alcohol of fuel electrodes, is difficult to produce hydrogen.Here, the ditch of air pole and fuel electrodes (ridge portion) is arranged on the position of a small amount of dislocation.

The hydrogen of making is like this made battery to be arranged in the electric furnace of hot air circulation type, under 30～70 ℃ of battery temperatures (operating temperature), at the traffic flow air of air pole side with 0～400ml/ branch, the methanol aqueous solution (fuel) of the traffic flow 0.5M～2M that divides with 2～15ml/ in the fuel electrodes side, the gas flow, the gas composition that produce to the voltage difference (open circuit voltage) of the fuel electrodes of this moment and air pole, in the fuel electrodes side are studied.

At first, the constant flow that makes the methanol aqueous solution (fuel) that flows to battery changes air mass flow at the 8ml/ branch at each temperature at 30 ℃, 50 ℃, 70 ℃, measures the growing amount of the gas that is produced by the fuel electrodes side.Make the mid-method of changing of water measure gas generating amount.In addition, use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

Its result as shown in Figure 3.

Thus, at each temperature,, can confirm to produce hydrogen by the fuel electrodes side of battery by reducing air mass flow.In addition we know, temperature is high more, and the hydrogen formation speed is big more.And then, studied the relation between the open circuit voltage (open voltage) of air mass flow and battery, find to be accompanied by the minimizing of air mass flow, there is the tendency that descends in the open circuit voltage of battery.

Result with Fig. 3 among Fig. 4 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and hydrogen formation speed (hydrogen growing amount) demonstrates the tendency that depends on open circuit voltage, is to produce hydrogen under 400～600mV at open circuit voltage.In addition, under any temperature, all near 450mV, observe the peak value of hydrogen formation speed.

Then, under the condition that 70 ℃ of temperature, fuel flow rate 8ml/ branch, air mass flow 120ml/ divide, produce gas, utilize the hydrogen concentration in the gas chromatography determination gas.

Its result can confirm, contains have an appointment 70% hydrogen, about 15% carbon dioxide in the generation gas.In addition, do not detect CO.

Hydrogen Production Example 1-2

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, then, change air mass flow respectively under the condition of be 2,8 at methanol aqueous solution (fuel) flow of 70 ℃ of battery temperatures, concentration 1M, 15ml/ dividing, the relation of the open circuit voltage of fuel flow rate, air mass flow and the hydrogen formation speed of expression this moment, battery among Fig. 5.

Hence one can see that, fuel flow rate hour, and the hydrogen formation speed is big.

Result with Fig. 5 among Fig. 6 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on open circuit voltage.In addition, under any fuel flow rate, 1-1 is same with the hydrogen Production Example, all observes the peak value of hydrogen formation speed near 450mV.

And then, in this Production Example, similarly utilize gas chromatography to obtain condition (70 ℃ of operating temperatures, fuel concentration 1M, fuel flow rate 2ml/ branch, air mass flow 100ml/ branch) when obtaining the open circuit voltage 442mV that maximum hydrogen formation speed 14.48ml/ divides with hydrogen Production Example 1-1 and produce hydrogen concentration in the gas down, the result is about 70%.

Hydrogen Production Example 1-3

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, then, be 0.5,1 at constant flow rate, fuel concentration that 70 ℃ of battery temperatures, methanol aqueous solution (fuel) divide for 8ml/, change air mass flow respectively under the condition of 2M, the relation of the open circuit voltage of fuel flow rate, air mass flow and the hydrogen formation speed of expression this moment, battery among Fig. 7.

Hence one can see that, and when fuel concentration hanged down, the hydrogen formation speed was big.

Result with Fig. 7 among Fig. 8 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on open circuit voltage, produces hydrogen under 300～600mV.In addition, under any fuel concentration, 1-1 is same with the hydrogen Production Example, all observes the peak value of hydrogen formation speed near 450mV.

Hydrogen Production Example 1-4

Then, studied of the influence of the thickness of dielectric film to gas generating amount.

In hydrogen Production Example 1-1～1-3, the Nafion115 (thickness is 130 μ m) that adopts E.I.Du Pont Company's system is as dielectric film, Nafion112 (thickness is 50 μ m) with same E.I.Du Pont Company's system constitutes same hydrogen manufacturing battery, under the condition that 70 ℃ of temperature, fuel concentration 1M, fuel flow rate 8ml/ are divided, change air mass flow respectively, studied the relation of open circuit voltage of fuel flow rate, air mass flow and hydrogen formation speed, the battery of this moment.

Nafion115 and Nafion112 are same material, have studied the influence of the thickness of dielectric film purely at this.Result of study as shown in Figure 9.

Result with Fig. 9 among Figure 10 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and for any dielectric film, the hydrogen formation speed is all equal substantially.As seen from the figure, the hydrogen formation speed under condition separately depends on open circuit voltage, still observes the peak value of hydrogen formation speed near 450mV.

Hydrogen Production Example 1-5

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, hydrogen is made in the electric furnace that battery is arranged on the hot air circulation type, at battery temperature is under 30 ℃, 50 ℃, 70 ℃, 90 ℃, is that 0～250ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is divide the to flow methanol aqueous solution (fuel) of 1M of 5ml/ with the flow, the open circuit voltage of the battery of research this moment, the hydrogen formation speed that produces in the fuel electrodes side.

Figure 11 has represented the relation between air mass flow and the hydrogen formation speed.

Identical with the situation of hydrogen Production Example 1-1, at each temperature,, can confirm to produce hydrogen by the fuel electrodes side of battery by reducing air mass flow.In addition we know, temperature is high more, and the hydrogen formation speed is big more.And then, studied the relation of the open circuit voltage of air mass flow and battery, can confirm to be accompanied by the minimizing of air mass flow, the open circuit voltage of battery has the tendency of decline.

Result with Figure 11 among Figure 12 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed depends on open circuit voltage, produces hydrogen under 300～700mV.In addition, under 30～70 ℃, near 470～480mV, observe the peak value of hydrogen formation speed; Under 90 ℃, near 440mV, observe the peak value of hydrogen formation speed.

Hydrogen Production Example 1-6

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, at battery temperature is to change air mass flow respectively under the condition that 50 ℃, fuel flow rate are 1.5,2.5,5.0,7.5,10.0ml/ divides, the relation of fuel flow rate, air mass flow and the hydrogen formation speed of expression this moment among Figure 13.

Hence one can see that, different with 70 ℃ the result of above-mentioned hydrogen Production Example 1-2, fuel flow rate for a long time, the hydrogen formation speed has the tendency of increase.

Result with Figure 13 among Figure 14 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on open circuit voltage, produces hydrogen under 300～700mV.In addition, near 450～500mV, observe the peak value of hydrogen formation speed.

Calculating is methanol consumption amount and the hydrogen formation speed in the fuel when changing fuel flow rate, uses following formula to calculate the energy efficiency of open-circuit condition (this energy efficiency is different with the energy efficiency of the charge condition that calculating formula by paragraph [0119] calculates).Its result is that the energy efficiency of open-circuit condition is 17% at fuel flow rate for the 5.0ml/ timesharing, is 22% in the 2.5ml/ timesharing.

The energy efficiency of open-circuit condition (%)

=(enthalpy change of the methyl alcohol of the standard enthalpy change/consumption of the hydrogen of generation) * 100

Hydrogen Production Example 1-7

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, be at battery temperature that constant flow rate, fuel concentration that 50 ℃, methanol aqueous solution (fuel) divide for 5ml/ are 0.5,1,2, change air mass flow respectively under the condition of 3M, the air mass flow of expression this moment and the relation of hydrogen formation speed among Figure 15.

Along with fuel concentration reduces, air mass flow diminishes, and observes the peak value of hydrogen formation speed.

Result with Figure 15 among Figure 16 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on open circuit voltage, produces hydrogen under 300～700mV.In addition, under any fuel concentration, all near 470mV, observe the peak value of hydrogen formation speed.

Hydrogen Production Example 1-8

Use the hydrogen manufacturing battery (but air pole form the oxidation utmost point of flow oxidizing gas) same with hydrogen Production Example 1-1, at battery temperature is that 50 ℃, fuel concentration are that 1M, fuel flow rate are that 5ml/ branch, oxygen concentration are to change the oxidizing gas flow respectively under 10,21,40,100% the condition, the oxidizing gas flow of expression this moment and the relation between the hydrogen formation speed among Figure 17.At this, the gas of oxygen concentration 21% uses air, and the gas of oxygen concentration 10% uses the gas that mixes nitrogen and modulate in air, and the gas of oxygen concentration 40% uses mixture of oxygen (oxygen concentration 100%) in air and the gas of modulation.

Along with oxygen concentration improves, the oxidizing gas flow descends, and observes the peak value of hydrogen formation speed.

Result with Figure 17 among Figure 18 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on open circuit voltage, produces hydrogen under 400～800mV.In addition, near 490～530mV, observe the peak value of hydrogen formation speed.

Hydrogen Production Example 1-9

Use the hydrogen manufacturing battery same with hydrogen Production Example 1-1, at battery temperature is under 50 ℃, in the air pole side is that 60ml/ divides the air that flows with the flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 2.6ml/ divides the 1M that flows with the flow, thereby generation gas, sampling 200cc uses the CO concentration in the gas chromatography determination gas.Consequently, from sample, do not detect CO (smaller or equal to 1ppm).Here, the battery open circuit voltage under this condition is 477mV, and the hydrogen formation speed is about the 10ml/ branch.

Hydrogen Production Example 1-10

Use the hydrogen manufacturing battery (but air pole form oxidation utmost point of working fluid hydrogen peroxide) same with hydrogen Production Example 1-1, hydrogen is made in the electric furnace that battery is arranged on the hot air circulation type, at battery temperature is under 30 ℃, 50 ℃, 70 ℃, 90 ℃, is the H that 1～8ml/ divides the 1M that flows in oxidation utmost point side with flow ₂O ₂(hydrogen peroxide) is divide the to flow methanol aqueous solution (fuel) of 1M of 5ml/ with the flow in the fuel electrodes side, the hydrogen formation speed of having studied the open circuit voltage of the battery of this moment, having produced in the fuel electrodes side.

Represented H among Figure 19 ₂O ₂Relation between flow and the hydrogen formation speed.

Identical with the situation of hydrogen Production Example 1-1, reducing H at each temperature ₂O ₂Flow can be confirmed to produce hydrogen by the fuel electrodes side of battery.In addition we know, temperature is high more, and the hydrogen formation speed is big more.And then, studied H ₂O ₂The relation of the open circuit voltage of flow and battery can be confirmed along with H ₂O ₂The minimizing of flow, the open circuit voltage of battery has the tendency of decline.

Result with Figure 19 among Figure 20 puts in order as the relation of open circuit voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on open circuit voltage, produces hydrogen under open circuit voltage 300～600mV.In addition, under 30～50 ℃, near 500mV, observe the peak value of hydrogen formation speed; Under 70～90 ℃, near 450mV, observe the peak value of hydrogen formation speed.

Here focus on, from the outside hydrogen is not made battery and apply all electric currents or voltage in the foregoing description 1, only measure open circuit voltage with internal resistance more than or equal to the potentiometer of 1G Ω, the while is fueling and oxidant only.

In other words, make battery, except fueling and oxidant,, just the part of fuel can be converted to hydrogen not from outside energize for the hydrogen of embodiment 1.

And, it is the reformation under 30～90 ℃ of so surprising low temperatures, can think the brand-new hydrogen producing apparatus that in the past do not have, thereby this hydrogen producing apparatus is used on the interior box fuel cell power generating system of having adorned the control device that need avoid high heat that effect is remarkable.

Embodiment 2

Below employed hydrogen producing apparatus (discharging condition) is made the example of the situation of hydrogen in the fuel cell power generating system of expression according to the related invention of the application's claim 4.

Hydrogen Production Example 2-1

Figure 21 represents that (hydrogen that has the electric energy let-off gear(stand) among the Production Example 2-1～2-8) is made the schematic diagram of battery to embodiment 2.

Except with fuel negative pole, very anodal and be provided with the device of deriving electric energy with air very, to make battery structure identical with the hydrogen of hydrogen Production Example 1-1.

This hydrogen is made battery to be arranged in the electric furnace of hot air circulation type, at battery temperature (operating temperature) is under 50 ℃, is that 10～100ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, change the electric current circulate between air pole and fuel electrodes this moment, gas flow, the gas composition that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side simultaneously studied.In addition, utilize gas chromatography that the hydrogen concentration that produces in the gas is analyzed, obtain the hydrogen formation speed.

In this test, the relation between the current density of derivation and running voltage as shown in figure 22.

Along with air mass flow diminishes, running voltage reduces, and observes the limiting current density that can discharge and descends.

Result with Figure 22 among Figure 23 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and hydrogen formation speed (hydrogen growing amount) demonstrates the tendency that depends on running voltage, is to produce gas under 300～600mV at running voltage.In addition we know, air mass flow is easy to produce hydrogen most in 50～60ml/ timesharing.And then air mass flow is difficult to produce hydrogen during more than this flow, when being the 100ml/ timesharing, produces hydrogen hardly.

Then,, temperature 50 ℃ big, fuel flow rate 5ml/ branch, air mass flow 60ml/ branch, current density 8.4mA/cm at the hydrogen formation speed ²Condition under produce gas, utilize the hydrogen concentration in the gas chromatography determination gas.

Its result shows, produces to contain 74% the hydrogen of having an appointment in the gas, and the hydrogen formation speed is the 5.1ml/ branch.In addition, do not detect CO.

Hydrogen Production Example 2-2

Use the hydrogen manufacturing battery same with hydrogen Production Example 2-1, at battery temperature is under 30 ℃, is that 30～100ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, change the electric current circulate between air pole and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side is studied simultaneously.

In this test, the relation between the current density of derivation and running voltage as shown in figure 24.

Along with air mass flow diminishes, running voltage reduces, and observes the limiting current density that can discharge and descends.

Result with Figure 24 among Figure 25 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, is to produce hydrogen under 200～540mV at running voltage.In addition we know, be that 30～70ml/ timesharing produces hydrogen in air mass flow.When being the 100ml/ timesharing, produce hydrogen hardly.

Hydrogen Production Example 2-3

Use the hydrogen manufacturing battery same with hydrogen Production Example 2-1, at battery temperature is under 70 ℃, is that 50～200ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, change the electric current circulate between air pole and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side is studied simultaneously.

In this test, the relation between the current density of derivation and running voltage as shown in figure 26.

Along with air mass flow diminishes, running voltage reduces, and observes the limiting current density that can discharge and descends.

Result with Figure 26 among Figure 27 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, is to produce hydrogen under 200～500mV at running voltage.In addition we know, be that 50～100ml/ timesharing is easy to produce hydrogen in air mass flow.When air mass flow increases to picture 150,200ml/ timesharing, produce hydrogen hardly.

Hydrogen Production Example 2-4

Use the hydrogen manufacturing battery same with hydrogen Production Example 2-1, at battery temperature is under 90 ℃, is that 50～250ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, change the electric current circulate between air pole and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side is studied simultaneously.

In this test, the relation between the current density of derivation and running voltage as shown in figure 28.

Along with air mass flow diminishes, running voltage reduces, and observes the limiting current density that can discharge and descends.

Result with Figure 28 among Figure 29 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, is to produce hydrogen under 200～500mV at running voltage.In addition we know, be that 50～100ml/ timesharing is easy to generate hydrogen in air mass flow.When being the 250ml/ timesharing, produce hydrogen hardly.

Then, the current density that the air mass flow at each temperature of hydrogen Production Example 2-1～2-4 is derived for the 50ml/ timesharing is shown among Figure 30 with the relation of running voltage, and the relation of running voltage and hydrogen formation speed is shown among Figure 31.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on temperature, when temperature is high, will produce hydrogen under low running voltage, and the hydrogen growing amount increases.

And then the current density that the air mass flow at each temperature of hydrogen Production Example 2-1～2-4 is derived for the 100ml/ timesharing is shown among Figure 32 with the relation of running voltage, and the relation of running voltage and hydrogen formation speed is shown among Figure 33.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on temperature, when temperature is high, will produce hydrogen under low running voltage, and the hydrogen growing amount increases.In addition, air mass flow increases to picture 100ml/ timesharing, under 30 ℃ of temperature, 50 ℃ of such low temperature, produces hydrogen hardly.

Hydrogen Production Example 2-5

Use the hydrogen manufacturing battery same with hydrogen Production Example 2-1, at battery temperature is under 50 ℃, in the air pole side is that 50ml/ divides the air that flows with the flow, change in the fuel electrodes side that fuel flow rate is 1.5,2.5,5.0,7.5, the 10.0ml/ branch, change the electric current circulate between air pole and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side is studied simultaneously.

In this test, the relation between the current density of derivation and running voltage as shown in figure 34.

Change even can observe fuel flow rate, the limiting current density that can discharge does not have big variation yet.

Result with Figure 34 among Figure 35 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on running voltage, produces hydrogen under 300～500mV.In addition, it is big to observe the hydrogen formation speed near 450～500mV.

Can know that the hydrogen formation speed not too depends on fuel flow rate.

Hydrogen Production Example 2-6

Use the hydrogen manufacturing battery same with hydrogen Production Example 2-1, at battery temperature is under 50 ℃, in the air pole side is that 50ml/ divides the air that flows with the flow, at fuel electrodes side fuel is the constant flow rate that 5ml/ divides, change fuel concentration and be 0.5,1,2,3M, change the electric current circulate between air pole and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side is studied simultaneously.

In this test, the relation between the current density of derivation and running voltage as shown in figure 36.

Along with the increase of fuel concentration, running voltage reduces, and observes the limiting current density that can discharge and descends.

Result with Figure 36 among Figure 37 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on running voltage, produces hydrogen under 300～600mV.

When fuel concentration is 1M, be easy to produce hydrogen most.

Hydrogen Production Example 2-7

Use the hydrogen manufacturing battery (but air pole form the oxidation utmost point of flow oxidizing gas) same with hydrogen Production Example 2-1, at battery temperature is under 50 ℃, at the fuel of fuel electrodes side with the fuel concentration of the mobile 1M of constant flow rate of 5ml/ branch, at the traffic flow oxidizing gas of oxidation utmost point side with the 14.0ml/ branch, changing oxygen concentration is 10,21,40,100%, change the electric current circulate between the oxidation utmost point and fuel electrodes this moment, the formation speed of the hydrogen that produces to the running voltage of the fuel electrodes and the oxidation utmost point, in the fuel electrodes side is studied simultaneously.Here, the gas of oxygen concentration 21% uses air, and the gas of oxygen concentration 10% is modulated by mix nitrogen in air, and the gas of oxygen concentration 40% is modulated by mix oxygen (oxygen concentration 100%) in air.

In this test, the relation between the current density of derivation and running voltage as shown in figure 38.

When oxygen concentration hanged down, running voltage reduced, and observed the limiting current density that can discharge and descended.

Result with Figure 38 among Figure 39 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed under condition separately depends on running voltage, produces hydrogen under 300～600mV.

When oxygen concentration is high, observe the tendency that the hydrogen formation speed increases.

Hydrogen Production Example 2-8

Use the hydrogen manufacturing battery (but air pole form oxidation utmost point of working fluid hydrogen peroxide) same with hydrogen Production Example 2-1, hydrogen is made in the electric furnace that battery is arranged on the hot air circulation type, battery temperature is 30 ℃, 50 ℃, 70 ℃, 90 ℃, at the methanol aqueous solution (fuel) of fuel electrodes side, at the H of oxidation utmost point side with the traffic flow 1M of 2.6～5.5ml/ branch with the traffic flow 1M of 5ml/ branch ₂O ₂(hydrogen peroxide) changes the electric current circulate this moment between the oxidation utmost point and fuel electrodes, the formation speed of the hydrogen that produces to the running voltage of the fuel electrodes and the oxidation utmost point, in the fuel electrodes side is studied simultaneously.At this, with the Flow-rate adjustment of hydrogen peroxide to being roughly 500mV at open circuit voltage at each temperature.

In this test, the relation between the current density of derivation and running voltage as shown in figure 40.

If temperature is 70～90 ℃, the relation of the decline of running voltage and the increase of current density is basic identical, and when temperature was reduced to 30 ℃, running voltage sharply reduced, and observes the limiting current density that can discharge and descends.

Result with Figure 40 among Figure 41 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, produces hydrogen under 300～500mV.In addition, when temperature is 90 ℃, be easy to produce hydrogen most, when temperature is hanged down, do not improve running voltage then can not produce hydrogen if observe.

Here emphasis is to make battery to outside derived current from hydrogen in the foregoing description 2.In other words, make battery,, can change the part of fuel into hydrogen when electric energy is derived in the outside for the hydrogen of embodiment 2.And, it is the reformation under 30～90 ℃ of so surprising low temperatures, can think the brand-new hydrogen producing apparatus that in the past do not have, thereby this hydrogen producing apparatus is used on the interior box fuel cell power generating system of having adorned the control device that need avoid high heat that effect is remarkable.

Embodiment 3

The example of below representing the situation of employed hydrogen producing apparatus (charge condition) manufacturing hydrogen in the fuel cell power generating system according to the related invention of the application's claim 5.

Hydrogen Production Example 3-1

Figure 42 represents that (hydrogen that has the equipment that applies electric energy from the outside among the Production Example 3-1～3-8) is made the schematic diagram of battery to embodiment 3.

Except with fuel very negative electrode, with above-mentioned oxidation very anode and be provided with apply the equipment of electric energy from the outside, to make battery structure identical with the hydrogen of hydrogen Production Example 1-1.

This hydrogen is made battery to be arranged in the hot air circulation type electric furnace, at battery temperature (operating temperature) is under 50 ℃, is that 10～80ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, use DC power supply and change the electric current that circulates this moment between air pole and fuel electrodes from the outside, gas flow, the gas composition that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side simultaneously studied.Here, the chemical energy of the hydrogen that generates is set at the energy efficiency of charge condition with respect to the ratio of the electric energy of input.In addition, utilize gas chromatography that the hydrogen concentration that produces in the gas is analyzed, obtain the hydrogen formation speed.

The energy efficiency of charge condition (hereinafter referred to as " energy efficiency ") is calculated by following calculating formula.

Calculating formula:

Energy efficiency (%)=(H ₂The electric energy of the combustion heat/apply) * 100

The H that generates in 1 minute ₂The combustion heat (KJ)=(H ₂Formation speed ml/ branch/24.47/1000) * 286KJ/mol[HHV]

The electric energy that applies in 1 minute (KJ)=[voltage mV/1000 * electric current A * 60sec] Wsec/1000

At this, for the purpose of prudent, to put down in writing, but the objective of the invention is to obtain the hydrogen of chemical energy more than or equal to the electric energy of input, this is not to ignore the determined energy conservation criteria of thermodynamics.As a whole, because partial organic substances fuel is oxidized,, then be smaller or equal to 100% if comprise the chemical energy that is consumed by the organic substance fuel oxidation in the electric energy of input.In the present invention, in order clearly to make the different of hydrogen with water electrolysis in the past, energy efficiency is expressed as energy efficiency with the chemical energy of the hydrogen that generates with respect to the ratio of the electric energy of input.

In this test, the relation between current density that applies and the hydrogen formation speed as shown in figure 43.

In current density smaller or equal to 40mA/cm ²Condition under, hydrogen produces efficient (producing the electric weight efficient of hydrogen) and has zone more than or equal to 100% (dot among Figure 43 hydrogen produce efficient be 100% line), if in this zone running, then can obtain the hydrogen more than or equal to the input electric energy.

Result with Figure 43 among Figure 44 puts in order as the relation of running voltage and hydrogen formation speed.

Hence one can see that, hydrogen formation speed (hydrogen growing amount) demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 400mV at running voltage, and the hydrogen formation speed is certain substantially more than or equal to 600mV the time, air mass flow hour, hydrogen formation speed big (being easy to produce hydrogen).

The relation of current density that applies and running voltage as shown in figure 45.

The hydrogen generation efficient of confirming in Figure 43 is among Figure 45 less than the running voltage that equals 600mV more than or equal to 100% zone.

In addition, the relation of running voltage and energy efficiency as shown in figure 46.

Can know, though running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the situation that the voltage that particularly turns round divides smaller or equal to 600mV, air mass flow 30～50ml/, energy efficiency height.

Then, at energy efficiency height (1050%), 50 ℃ of temperature, fuel flow rate 5ml/ branch, air mass flow 50ml/ branch, current density 4.8mA/cm ²Condition under produce gas, utilize the hydrogen concentration in the gas chromatography determination gas.Its result shows, produces to contain 86% the hydrogen of having an appointment in the gas, and the hydrogen formation speed is the 7.8ml/ branch.In addition, do not detect CO.

Hydrogen Production Example 3-2

Use the hydrogen manufacturing battery same with hydrogen Production Example 3-1, at battery temperature is 30 ℃, is that 10～70ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, use DC power supply and change the electric current that circulates this moment between air pole and fuel electrodes from the outside, formation speed, the energy efficiency of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side are studied simultaneously.

In this test, the relation between current density that applies and the hydrogen formation speed as shown in figure 47, the relation of running voltage and hydrogen formation speed is as shown in figure 48.

Hence one can see that, and hydrogen formation speed (growing amount of hydrogen) demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 400mV at running voltage, and air mass flow hour is easy to produce hydrogen.When air mass flow is the situation that 10ml/ divides, the hydrogen formation speed is certain substantially more than or equal to 600mV the time; When air mass flow is the situation that 30ml/ divides, more than or equal to 800mV the time, demonstrate the tendency of increase; When air mass flow than its higher situation, just not can not produce hydrogen if do not improve running voltage.

In addition, the relation of running voltage and energy efficiency as shown in figure 49.

Can know that even turn round voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is the situation that 30ml/ divides smaller or equal to 600mV, air mass flow, the energy efficiency height.

Hydrogen Production Example 3-3

Except making battery temperature is 70 ℃, to test with the condition identical with hydrogen Production Example 3-2, formation speed, the energy efficiency of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side are studied.

In this test, the relation between current density that applies and the hydrogen formation speed as shown in figure 50, the relation of running voltage and hydrogen formation speed is shown in Figure 51.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 400mV at running voltage, and air mass flow hour is easy to produce hydrogen.When air mass flow is the situation that 10ml/ divides, the hydrogen formation speed is certain substantially more than or equal to 600mV the time; When air mass flow is the situation that 30ml/ divides, more than or equal to 800mV the time, demonstrate the tendency of increase; When air mass flow than its higher situation, just not can not produce hydrogen if do not improve running voltage.

In addition, the relation of running voltage and energy efficiency is shown in Figure 52.

Can know, though running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the situation that the voltage that particularly turns round divides smaller or equal to 600mV, air mass flow 10～30ml/, energy efficiency height.

Hydrogen Production Example 3-4

Use the hydrogen manufacturing battery same with hydrogen Production Example 3-1, at battery temperature is under 90 ℃, is that 10～200ml/ divides the air that flows in the air pole side with flow, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the 1M that flows with the flow, use DC power supply and change the electric current that circulates this moment between air pole and fuel electrodes from the outside, formation speed, the energy efficiency of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side are studied simultaneously.

In this test, the relation between current density that applies and the hydrogen formation speed is shown in Figure 53, and the relation of running voltage and hydrogen formation speed is shown in Figure 54.

Hence one can see that, the hydrogen formation speed demonstrates the tendency that depends on running voltage, produce hydrogen during more than or equal to 300mV at running voltage, air mass flow hour is easy to produce hydrogen, and when air mass flow is the situation that 10ml/ divides, the hydrogen formation speed is certain substantially more than or equal to 500mV the time, when air mass flow is the situation that 50～100ml/ divides, more than or equal to 800mV the time, demonstrate the tendency of increase, when air mass flow is the situation that 200ml/ divides, equals 800mV and just can not produce hydrogen if be not more than.

In addition, the relation of running voltage and energy efficiency is shown in Figure 55.

Can know that even turn round voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is the 50ml/ timesharing smaller or equal to 500mV, air mass flow, the energy efficiency height.

Then, the current density that the air mass flow at each temperature of hydrogen Production Example 3-1～3-4 is applied for the 50ml/ timesharing and the relation of hydrogen formation speed are shown among Figure 56, and the relation of running voltage and hydrogen formation speed is shown among Figure 57.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on temperature, when operating temperature is high, just produces hydrogen under low running voltage, and the hydrogen formation speed is also big.

In addition, the relation of running voltage and energy efficiency is shown in Figure 58.

Can know, though running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is during smaller or equal to 600mV, the energy efficiency height.

Hydrogen Production Example 3-5

Use the hydrogen manufacturing battery same with hydrogen Production Example 3-1, at battery temperature is under 50 ℃, in the air pole side is that 50ml/ divides the air that flows with the flow, the fuel flow rate that changes the fuel electrodes side is 1.5,2.5,5.0,7.5, the 10.0ml/ branch, under this condition, use DC power supply and change the electric current that circulates this moment between air pole and fuel electrodes from the outside, formation speed, the energy efficiency of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side are studied simultaneously.

In this test, the relation between current density that applies and the hydrogen formation speed is shown in Figure 59, and the relation of running voltage and hydrogen formation speed is shown in Figure 60.

Hence one can see that, the hydrogen formation speed demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 400mV at running voltage, and fuel flow rate is easy to produce hydrogen for a long time, for the situation of any fuel flow rate, all observe the tendency that more than or equal to 800mV time hydrogen formation speed has increase.

In addition, the relation of running voltage and energy efficiency is shown in Figure 61.

Can know, for the situation of any fuel flow rate, even running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is during smaller or equal to 600mV, the energy efficiency height.

Hydrogen Production Example 3-6

Use the hydrogen manufacturing battery same with hydrogen Production Example 3-1, at battery temperature is under 50 ℃, in the air pole side is that 50ml/ divides the air that flows with the flow, at fuel electrodes side fuel is the constant flow rate that 5ml/ divides, change fuel concentration and be 0.5,1,2,3M, under this condition, use DC power supply from the outside and change the electric current that between air pole and fuel electrodes, circulates this moment, formation speed, the energy efficiency of the hydrogen that produces to the running voltage of fuel electrodes and air pole, in the fuel electrodes side are studied simultaneously.

In this test, the relation between current density that applies and the hydrogen formation speed is shown in Figure 62, and the relation of running voltage and hydrogen formation speed is shown in Figure 63.

Hence one can see that, for any fuel concentration, more than or equal to 0.02A/cm ²The zone, current density that applies and hydrogen formation speed are proportional substantially.

In addition, the hydrogen formation speed demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 400mV at running voltage, when fuel concentration is high, also is easy to produce hydrogen even running voltage is low.For fuel concentration is the situation of 2M, 3M, and the hydrogen formation speed sharply increases when 400～500mV; When fuel concentration is the situation of 1M, the hydrogen formation speed is certain substantially when 400～800mV, demonstrates the tendency of increase more than or equal to 800mV the time; Than its lower situation, just not can not produce hydrogen at fuel concentration if do not improve running voltage.

In addition, the relation of running voltage and energy efficiency is shown in Figure 64.

Can know, except fuel concentration is the situation of 0.5M, even running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is during smaller or equal to 600mV, when fuel concentration is 1,2, the situation of 3M, the energy efficiency height.In addition, fuel concentration is the situation of 0.5M, owing to do not produce hydrogen at low-voltage region, the performance of energy efficiency is different fully with the situation of other conditions.

Hydrogen Production Example 3-7

Use the hydrogen manufacturing battery (but air pole form the oxidation utmost point of flow oxidizing gas) same with hydrogen Production Example 3-1, at battery temperature is under 50 ℃, fuel at fuel electrodes side concentration 1M is the constant flow rate that 5ml/ divides, at oxidation utmost point side oxidizing gas is the flow that 14.0ml/ divides, changing oxygen concentration is 10,21,40,100%, under this condition, use DC power supply and change the electric current that circulates this moment between the oxidation utmost point and fuel electrodes from the outside, simultaneously to the running voltage of the fuel electrodes and the oxidation utmost point, the formation speed of the hydrogen that produces in the fuel electrodes side, energy efficiency is studied.Here, the gas of oxygen concentration 21% uses air, and the gas of oxygen concentration 10% is modulated by mix nitrogen in air, and the gas of oxygen concentration 40% is modulated by mix oxygen (oxygen concentration 100%) in air.

In this test, the relation between current density that applies and the hydrogen formation speed is shown in Figure 65, and the relation of running voltage and hydrogen formation speed is shown in Figure 66.

Hence one can see that, for any oxygen concentration, more than or equal to 0.03A/cm ²The zone, current density that applies and hydrogen formation speed are proportional substantially.

In addition, the hydrogen formation speed demonstrates the tendency that depends on running voltage, produce hydrogen during more than or equal to 400mV at running voltage, when oxygen concentration is high, even hanging down, running voltage also is easy to produce hydrogen, the hydrogen formation speed is certain substantially when 400～800mV, demonstrates the tendency of increase more than or equal to 800mV the time.

In addition, the relation of running voltage and energy efficiency is shown in Figure 67.

Can know that even apply voltage near 1000mV, energy efficiency particularly applies voltage smaller or equal to 600mV, when oxygen concentration is high, the energy efficiency height also more than or equal to 100%.

Hydrogen Production Example 3-8

Use the hydrogen manufacturing battery (but air pole form oxidation utmost point of working fluid hydrogen peroxide) same with hydrogen Production Example 3-1, hydrogen is made in the electric furnace that battery is arranged on the hot air circulation type, battery temperature is 30 ℃, 50 ℃, 70 ℃, 90 ℃, in the fuel electrodes side is the methanol aqueous solution (fuel) that 5ml/ divides the concentration 1M that flows with the flow, is the H that 2.6～5.5ml/ divides the 1M that flows in oxidation utmost point side with flow ₂O ₂(hydrogen peroxide) uses DC power supply from the outside and change the electric current that circulates between the oxidation utmost point and fuel electrodes this moment, and formation speed, the energy efficiency of the hydrogen that produces to the running voltage of the fuel electrodes and the oxidation utmost point, in the fuel electrodes side are studied simultaneously.

At this, the flow of adjusting hydrogen peroxide open circuit voltage extremely at each temperature is 500mV substantially.

In this test, the relation between current density that applies and the hydrogen formation speed is shown in Figure 68, and the relation of running voltage and hydrogen formation speed is shown in Figure 69.

Hence one can see that, and the hydrogen formation speed demonstrates the tendency that depends on running voltage, produces hydrogen during more than or equal to 500mV at running voltage, demonstrates the tendency of increase more than or equal to 800mV the time, is easy to produce hydrogen when operating temperature is high.

In addition, the relation of running voltage and energy efficiency is shown in Figure 70.

Can know, though running voltage near 1000mV, energy efficiency is also more than or equal to 100%, the voltage that particularly turns round is smaller or equal to 800mV, when temperature is 90 ℃, the energy efficiency height.

Here emphasis is, the foregoing description 3 is to obtain from the hydrogen of outside more than the electric current that hydrogen manufacturing battery applies.In other words, make battery, can make hydrogen more than or equal to the energy of the electric energy that applies for the hydrogen of embodiment 3.And, it is the reformation under 30～90 ℃ of so surprising low temperatures, can think the brand-new hydrogen producing apparatus that in the past do not have, thereby this hydrogen producing apparatus is used on the interior box fuel cell power generating system of having adorned the control device that need avoid high heat that effect is remarkable.

In following embodiment, show and use methyl alcohol fuel in addition, make the example of hydrogen by employed hydrogen producing apparatus in the fuel cell power generating system of the present invention.

Embodiment 4

Use ethanol to be fuel, employed hydrogen producing apparatus (open-circuit condition) is made hydrogen in the fuel cell power generating system by the related invention of the application's claim 3.

Use the hydrogen identical to make battery with hydrogen Production Example 1-1, battery temperature is 80 ℃, fuel electrode one side flows through the ethanol water that concentration is 1M with the flow that 5ml/ divides, air pole one side flows through air with the flow that 65ml/ divides, and measures the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result is as shown in table 1.

Table 1

Air (ml/min)	Open circuit voltage (mV)	Gas formation speed (ml/min)	H 2Concentration (%)	H 2Formation speed (ml/min)
					65	478	0.6	65.2	0.39

As shown in table 1, when open circuit voltage 478mV, confirm to have produced hydrogen, but the formation speed of hydrogen is little.

Embodiment 5

Making spent glycol is fuel, and employed hydrogen producing apparatus (open-circuit condition) is made hydrogen in the fuel cell power generating system by the related invention of the application's claim 3.

Use the hydrogen identical to make battery with hydrogen Production Example 1-1, battery temperature is 80 ℃, fuel electrode one side flows through the glycol water that concentration is 1M with the flow that 5ml/ divides, air pole one side flows through air with the flow that 105ml/ divides, and measures the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result is as shown in table 2.

Table 2

Air (ml/min)	Open circuit voltage (mV)	Gas formation speed (ml/min)	H 2Concentration (%)	H 2Formation speed (ml/min)
					105	474	2.4	88.4	2.12

As shown in table 2, when open circuit voltage 474mV, confirm to have produced hydrogen, the formation speed of hydrogen is big when using ethanol water as fuel, but little when comparing the use methanol aqueous solution.

Embodiment 6

Use isopropyl alcohol to be fuel, employed hydrogen producing apparatus (open-circuit condition) is made hydrogen in the fuel cell power generating system by the related invention of the application's claim 3.

Use the hydrogen identical to make battery with hydrogen Production Example 1-1, battery temperature is 80 ℃, fuel electrode one side flows through the isopropanol water solution that concentration is 1M with the flow that 5ml/ divides, air pole one side flows through air with the flow that 35ml/ divides, and measures the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result is as shown in table 3.

Table 3

Air (ml/min)	Open circuit voltage (mV)	Gas formation speed (ml/min)	H 2Concentration (%)	H 2Formation speed (ml/min)
					35	514	3.96	95.6	3.78

As shown in table 3, when open circuit voltage 514mV, confirm to have produced hydrogen, the formation speed of hydrogen is big when using ethanol water, glycol water as fuel, near the situation of methanol aqueous solution.Particularly, produce the very high concentrations of hydrogen in the gas.

Embodiment 7

Use diethyl ether to be fuel, employed hydrogen producing apparatus (open-circuit condition) is made hydrogen in the fuel cell power generating system by the related invention of the application's claim 3.

Use the hydrogen identical to make battery with hydrogen Production Example 1-1, battery temperature is 80 ℃, fuel electrode one side flows through the diethyl ether aqueous solution that concentration is 1M with the flow that 5ml/ divides, air pole one side flows through air with the flow that 20ml/ divides, and measures the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result is as shown in table 4.

Table 4

Air (ml/min)	Open circuit voltage (mV)	Gas formation speed (ml/min)	H 2Concentration (%)	H 2Formation speed (ml/min)
					20	565	3.0	7.6	0.23

As shown in table 4, when open circuit voltage 565mV, confirm to have produced hydrogen, to compare when using alcohol as fuel, the hydrogen concentration in the generation gas is low, and the formation speed of hydrogen is also low.

Embodiment 8

Use formaldehyde, formic acid to be fuel, employed hydrogen producing apparatus (open-circuit condition) is made hydrogen in the fuel cell power generating system by the related invention of the application's claim 3.

Use the hydrogen identical to make battery with hydrogen Production Example 1-1, battery temperature is 50 ℃, it is the aqueous formic acid of 1M that the flow that fuel electrode one side is divided with 5ml/ flows through formalin, the concentration that concentration is 1M respectively, air pole one side flows through air with the flow that 0～100ml/ divides, and measures the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result who measures is when using methyl alcohol, shown in Figure 71,72.

Shown in Figure 71, use formaldehyde, formic acid, methyl alcohol is same with using, and confirms to have produced hydrogen by reducing air mass flow in fuel electrodes one example of battery.In addition, the formation speed of hydrogen is maximum with methyl alcohol, is followed successively by formaldehyde, formic acid, and, under this order,, just do not produce hydrogen if do not reduce air mass flow.

By Figure 72 as can be known, use formaldehyde, formic acid, methyl alcohol is same with using, and the formation speed of hydrogen (hydrogen generating capacity) shows the tendency that depends on open circuit voltage, and open circuit voltage finds to produce hydrogen when 200～800mV.In addition, when using formic acid, produce hydrogen than methyl alcohol, formaldehyde under lower open circuit voltage, the peak value of hydrogen formation speed is about 500mV for methyl alcohol, formaldehyde, and is lower open circuit voltage (about 350mV) for formic acid.

Embodiment 9

The hydrogen that changes embodiment 1～8 is made the structure of battery, makes hydrogen by employed hydrogen producing apparatus (open-circuit condition) in the fuel cell power generating system that uses claim 3 and 31 related inventions.

Remove fuel electrodes dividing plate in the dividing plate, only, in addition identical with hydrogen Production Example 1-1 by air pole dividing plate and MEA combination, make hydrogen and make battery.

Use the hydrogen of so making to make battery, battery temperature is 50 ℃, flow through the methanol aqueous solution that concentration is 1M in fuel electrodes one side with the flow that 5ml/ divides, flow through air with the flow that 0～150ml/ divides, measure the open circuit voltage of battery, the formation speed that the fuel electrodes side produces gas in air pole one side.Use the hydrogen concentration in the gc analysis generation gas, obtain the hydrogen formation speed.

The result who measures is shown in Figure 73.

Air mass flow is that 30～130ml/ timesharing produces hydrogen, and the hydrogen growing amount lacks during than the two dividing plate of use fuel electrodes and air pole.

The result of Figure 73 is organized into the relation of open circuit voltage and hydrogen formation speed, shown in Figure 74.

Hence one can see that, identical with the situation of hydrogen Production Example 1-1, and hydrogen formation speed (hydrogen growing amount) demonstrates the tendency that depends on open circuit voltage, produces hydrogen when open circuit voltage 400～600mV.In addition, the peak value of the formation speed of discovery hydrogen is near 470mV.

As mentioned above, employed hydrogen producing apparatus in the fuel cell power generating system of the present invention owing to can make hydrogen-containing gas containing organic fuel smaller or equal to 100 ℃ of decomposition, therefore, can easily be supplied with hydrogen to fuel cell.

The possibility of utilizing on the industry

In the fuel cell power generating system of the present invention; box fuel cell power generating system particularly; because the control device that does not need special device to receive for the protection of packing casing content is avoided the impact of the heat that hydrogen producing apparatus produces; and comprise that the whole heating of fuel cell device has also reduced; so when using with power supply with power supply or scene as movement, very favourable.

Claims (35)

1. fuel cell power generating system, it is characterized by, it possesses at least by supplying with the fuel cell that hydrogen and oxidant generate electricity, and the hydrogen producing apparatus of making the hydrogen-containing gas be used to supply with described fuel cell, described hydrogen producing apparatus is to contain the device that organic fuel is made hydrogen-containing gas by decomposition, and it has barrier film, the fuel electrodes that on a face of above-mentioned barrier film, is provided with, supply with the device of the fuel that contains organic substance and water to described fuel electrodes, the oxidation utmost point that on the another side of described barrier film, is provided with, supply with the device of oxidant to the described oxidation utmost point, produce the device of hydrogen-containing gas and derivation from the fuel electrodes side.

2. fuel cell power generating system as claimed in claim 1, it is characterized by, in casing, adorned the control device of all controlling by the power inverter of supplying with fuel cell that hydrogen and oxidant generate electricity, making the hydrogen producing apparatus of the hydrogen-containing gas that is used to supply with described fuel cell, direct current that described fuel cell is sent is converted to regulation electric power, to Blast Furnace Top Gas Recovery Turbine Unit (TRT) at least.

3. fuel cell power generating system as claimed in claim 1, it is characterized by, described hydrogen producing apparatus is not have by the hydrogen manufacturing battery that constitutes hydrogen producing apparatus to derive the device of electric energy and make the open circuit that battery applies the device of electric energy by the outside to described hydrogen to the outside.

4. fuel cell power generating system as claimed in claim 1 is characterized by, described hydrogen producing apparatus have with described fuel very negative pole with the very anodal device of deriving electric energy to the outside of described oxidation.

5. fuel cell power generating system as claimed in claim 1 is characterized by, described hydrogen producing apparatus have with described fuel very negative electrode with described oxidation very anode apply the device of electric energy by the outside.

6. fuel cell power generating system as claimed in claim 1 or 2, it is characterized by, be used in combination the two or more hydrogen producing apparatus of selecting by in following three kinds of hydrogen producing apparatus: do not have and make battery by the hydrogen that constitutes hydrogen producing apparatus and derive the device of electric energy and make the hydrogen producing apparatus of open circuit that battery applies the device of electric energy to described hydrogen by the outside to the outside, have with described fuel very negative pole derive the hydrogen producing apparatus of the device of electric energy so that described oxidation is very anodal to the outside, and have with described fuel very negative electrode with described oxidation very anode apply the hydrogen producing apparatus of the device of electric energy by the outside.

7. fuel cell power generating system as claimed in claim 1 or 2 is characterized by, and the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 200～1000mV.

8. fuel cell power generating system as claimed in claim 3 is characterized by, and the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 300～800mV.

9. fuel cell power generating system as claimed in claim 4 is characterized by, and the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 200～600mV.

10. as claim 4 or 9 described fuel cell power generating systems, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the electric energy of adjusting described derivation.

11. fuel cell power generating system as claimed in claim 5 is characterized by, the voltage between the described fuel electrodes of described hydrogen producing apparatus and the described oxidation utmost point is 300～1000mV.

12. as claim 5 or 11 described fuel cell power generating systems, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described electric energy that applies.

13. as any one described fuel cell power generating system of claim 1～5, it is characterized by, in the described hydrogen producing apparatus, adjust the generating capacity of described hydrogen-containing gas by adjusting voltage between the described fuel electrodes and the described oxidation utmost point.

14. as any one described fuel cell power generating system of claim 1～5, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the quantity delivered of adjusting described oxidant.

15. as any one described fuel cell power generating system of claim 1～5, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by the concentration of adjusting described oxidant.

16. as any one described fuel cell power generating system of claim 1～5, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described quantity delivered that contains the fuel of organic substance and water.

17. as any one described fuel cell power generating system of claim 1～5, it is characterized by, in the described hydrogen producing apparatus, adjust the voltage between the described fuel electrodes and the described oxidation utmost point and/or the generating capacity of described hydrogen-containing gas by adjusting the described concentration that contains the fuel of organic substance and water.

18. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the operating temperature of described hydrogen producing apparatus is smaller or equal to 100 ℃.

19. fuel cell power generating system as claimed in claim 18 is characterized by, described operating temperature is 30～90 ℃.

20. as any one described fuel cell power generating system of claim 1～5, it is characterized by, supply with the one or more kinds of organic substances of described organic substance for from alcohol, aldehyde, carboxylic acid and ether, selecting of the fuel electrodes of described hydrogen producing apparatus.

21. fuel cell power generating system as claimed in claim 20 is characterized by, described alcohol is methyl alcohol.

22. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is oxygen-containing gas or oxygen.

23. fuel cell power generating system as claimed in claim 22 is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is the air exhaust that described fuel cell or other described hydrogen producing apparatus are discharged.

24. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the described oxidant of supplying with the oxidation utmost point of described hydrogen producing apparatus is the liquid that contains hydrogen peroxide.

25. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the described barrier film of described hydrogen producing apparatus is the proton conductive solid electrolyte film.

26. fuel cell power generating system as claimed in claim 25 is characterized by, described proton conductive solid electrolyte film is that perfluorocarbon sulfonic acid is a solid electrolyte film.

27. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the catalyst of the fuel electrodes of described hydrogen producing apparatus is the catalyst that has supported the Pt-Ru alloy on carbon dust.

28. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the catalyst of the oxidation utmost point of described hydrogen producing apparatus is the catalyst that has supported Pt on carbon dust.

29. as any one described fuel cell power generating system of claim 1～5, it is characterized by, described hydrogen producing apparatus has the fuel electrodes barrier film that is provided with the stream ditch that is used for mobile described fuel and is provided with the oxidation utmost point barrier film of the stream ditch that is used for mobile described oxidant.

30. fuel cell power generating system as claimed in claim 29, it is characterized by, the two the stream ditch of the fuel electrodes barrier film of described hydrogen producing apparatus and oxidation utmost point barrier film that is crisscross arranged makes that the ridge part beyond the stream ditch of stream ditch and described oxidation utmost point barrier film of described fuel electrodes barrier film is relative to small part.

31. as any one described fuel cell power generating system of claim 1～5, it is characterized by, described hydrogen producing apparatus has the oxidant barrier film that is provided with the stream ditch that is used for mobile described oxidant, and does not have the fuel electrodes barrier film.

32. as any one described fuel cell power generating system of claim 1～5, it is characterized by, the described circulating device that contains the fuel of organic substance and water be set on described hydrogen producing apparatus.

33. as any one described fuel cell power generating system of claim 1～5, it is characterized by, on described hydrogen producing apparatus, be provided for absorbing the carbon dioxide absorption portion of the carbon dioxide that is included in the described hydrogen-containing gas.

34. as any one described fuel cell power generating system of claim 1～5, it is characterized by, do not cool off the described hydrogen-containing gas that produces by described hydrogen producing apparatus and supply with described fuel cell.

35. as any one described fuel cell power generating system of claim 1～5, it is characterized by, be not provided for blocking the heat-insulating material of the heat that described hydrogen producing apparatus sends.

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